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The Lead
Rewarding Your Readership with Constant ImprovementApril 1, 2015 1:20 pm | by Jeff Reinke, Editorial director | Blogs | Comments
Thanks for sparing some time in your busy day to visit our site or check out one of our daily newsletters. In respect to that dynamic, I'll be brief in sharing some of the new things we're doing to improve the daily content mix.
Analyst: Decline in Cases Curbs Ebola Drug Clinical TrialsMarch 11, 2015 4:08 pm | by Andy Szal, Digital Reporter | News | Comments
The sharp decline in Ebola cases since the peak of the virus' largest-ever outbreak could hamper...
Packaging Entrepreneurs: Legacy Pharmaceutical PackagingFebruary 20, 2015 10:17 am | by Mike Auerbach, Editor-In-Chief | Articles | Comments
Legacy Pharmaceutical Packaging, in St. Louis, Missouri is proud of its entrepreneurial spirit,...
Does More Money Equal More Cures?February 18, 2015 3:30 pm | by Mike Auerbach, Editor-In-Chief | Blogs | Comments
In July of this year it will be six years since my father dies from pancreatic cancer. As I...
Pharmaceutical Processing's October 2014 IssueOctober 20, 2014 11:34 am | Digital Editions | Comments
The October issue of Pharmaceutical Processing describes Capsugel's merger with Bend Research and Encap to create a comprehensive solid dosage form solutions group. The issue also features articles on supply chain trends including how to reduce risk, managing a clinical supply chain, a look at the best printing and coding solutions, and the move to the fully connected enterprise. Other articles focus on particle size analysis, disposable chromatography technologies, and monitoring potency assays.
Pharmaceutical Processing's September 2014 IssueSeptember 29, 2014 1:48 pm | Digital Editions | Comments
The September issue of Pharmaceutical Processing profiles SAFC's new dry powder media manufacturing facility in Irvine, Scotland. In addition, coverage includes articles on highly toxic manufacturing and containment/isolator technologies. We also have a report on how CMOs are leading the adoption of new biopharm technologies. Other articles include a look at aseptic primary packaging, the challenges of scale-up and commercialization, optimizing vaccine processes, and the state of track and trace in the industry.
Pharmaceutical Processing's May 2014 EditionMay 9, 2014 12:00 am | Digital Editions | Comments
The May issue of Pharmaceutical Processing profiles PCI, a contract developer and manufacturer of custom NCEs, fine chemicals and generic APIs based in Newburyport, MA. We also take a look at the critical success factors clients evaluate when choosing a CMO. Our manufacturing services Q&A discusses current trends, issues and the future of pharmaceutical processing services. In addition we cover tablet coating, single-use technologies and QbD in test method development and validation.
Pharmaceutical Processing's April 2014 EditionApril 11, 2014 12:00 am | Digital Editions | Comments
The April issue of Pharmaceutical Processing profiles Reed-Lane, a contract packager of solid-dosage products based in Wayne, NJ. Additional articles on contract services and outsourcing topics include a look at the global biosimilars market and an update on solid dosage manufacturing services. In addition, the benefits of using ready-to-fill vials is explored. Other topics covered in this issue include packaging inspection, anti-counterfeiting technologies, lab design and expediting drug development.
Barrier Isolation - The "Must Have" Technology for 2014February 11, 2014 3:59 pm | by James Hirt, RA, Kezlo Group, LLC | Articles | Comments
Barrier isolator technology is one area of pharmaceutical manufacturing where the latest and greatest technology is becoming a driver of business necessity.
Pharmaceutical Processing's October 2013 IssueOctober 4, 2013 12:00 am | Digital Editions | Comments
The October issue of Pharmaceutical Processing profiles Catalent's new clinical biologics manufacturing facility in Madison, Wisconsin. The role of quality control and microscopy services for the industry is also featured in this issue as well as an article on Brazil's emerging pharmaceutical manufacturing industry.
High Shear Granulating: A look at advances in wet milling and controlled spraying in granulation operationsAugust 29, 2013 11:03 am | by Raja Krishnan and Michael Buzecky, Fluid Air, Inc. | Articles | Comments
High shear wet granulation is a cornerstone of the formulator's and process engineer's pharmaceutical manufacturing toolbox. It is used to increase the density and particle size of a composition to improve powder flow and compressibility on the tablet press when dry processing methods are insufficient to produce tablets or capsules with acceptable uniformity, hardness, and friability.
Pharmaceutical Processing July/August 2013 IssueJuly 11, 2013 12:00 am | Digital Editions | Comments
In the July/August 2013 issue of Pharmaceutical Processing we profile Impact Analytical's range of services for the pharmaceutical industry and its new facility in Midland, MI. Additional articles on contract services include a look at quality and reliability drivers for strategic outsourcing and a focus on packaging services. Our Special Report details how numerical simulations can be used to continuously process APIs. Other articles include a look at small parts handling, tablet manufacturing, pharmaceutical compliance and process validation.
The Magic Triangle of Blister PackagingJanuary 15, 2013 9:07 am | by Angela Roggenhofer, Sales & Marketing Manager, Tekni-Plex, Inc. | Articles | Comments
Blister packaging is not rocket science – or is it? Good blisters are the result of an optimized interaction between materials, equipment/tooling, and processing conditions. Neglecting just one is inviting trouble. Paying attention to all three cornerstones of this magic triangle will keep your line operators, purchasing personnel and customers happy.
Vaccine Production Using Single-Use Disposable TechnologyJanuary 15, 2013 6:23 am | by Nigel J. Smart PhD., Smart Consulting Group, West Chester, Pennsylvania | Articles | Comments
Current status and future prospects.
A Dose of PrecisionJanuary 14, 2013 9:53 am | by Jonnatha Mayberry, Associate Editor | Articles | Comments
Under the watchful eyes of regulators, aseptic filling undergoes a makeover.
Leveraging Experience and ExpertiseJanuary 14, 2013 6:45 am | by Mike Auerbach, Editor in Chief | Articles | Comments
Laureate Biopharma's history of excellence prepares them for the future.
2013 Pharmaceutical Industry Outlook: Post-Election Impact to Healthcare Reform & Health PolicyJanuary 2, 2013 6:28 am | by Peyton Howell, MHA, SVP, AmerisourceBergen Corporation and President, Global Sourcing and Manufacturer Relationships | Articles | Comments
The 2012 electio n was filled with tight races, close victories and upsets. Now that the votes are in, and the Obama Administration begins a second term in office, questions remain about the continued implementation of the Patient Protection and Affordable Care Act (ACA) and its impact on patient access.
New Year Predictions for 2013January 2, 2013 6:18 am | by Bikash Chatterjee, President and CTO, Pharmatech Associates | Articles | Comments
As we move forward into 2013 the global pharmaceutical market can be best described as transitory.
Compendial Water Systems: Biofilm Remediation and ControlOctober 25, 2012 8:01 am | by William V. Collentro | Articles | Comments
Many compendial water systems, particularly purified water systems, have distribution systems with a biofilm. Detection, removal, and control of biofilm in compendial water systems are extremely important.
2012 FDA Warning Letters: What Can Be Learned?October 25, 2012 7:22 am | by Mike Rozembajgier Vice President of Recalls, Stericycle ExpertRECALL™ | Articles | Comments
So far in 2012, the FDA has issued nearly 300 warning letters. More than half of those were sent to companies within the pharmaceutical, medical device and dietary supplement industries.
Dust Explosion Hazards in Pharmaceutical FacilitiesOctober 24, 2012 10:53 am | by Vahid Ebadat, Ph.D., Chilworth Technology, Inc. | Articles | Comments
Mitigating risks in oral solid dosage manufacturing operations
The Outsourcing RelationshipOctober 24, 2012 10:25 am | by Eric Langer, President and Managing Partner, BioPlan Associates, Inc. | Articles | Comments
CMOs say clients not communicating effectively - unrealistic timeframes also a common complaint
Modular Construction ConsiderationsOctober 23, 2012 11:32 am | by John Gilroy, PE, Senior Vice President & Principal and Gene Martini, PE, Senior Director, Operations & Principal, IPS-Integrated Project Services | Articles | Comments
The lean way to design and build pharmaceutical facilities.
Banishing Bacteria From Wall to WallOctober 23, 2012 9:42 am | by Jonnatha Mayberry, Associate Editor | Articles | Comments
FDA regulations provide a cleaning and sterilization roadmap for manufacturers, but companies are provided with some flexibility when it comes to the specifics. Today, new developments are giving manufacturers a wider variety of options, ranging from safer facility-wide decontamination methods to new autoclave technologies.
Step-by-Step SuccessOctober 16, 2012 10:57 am | by Jonnatha Mayberry, Associate Editor | Articles | Comments
Anteco Pharma registers big growth but retains its one-on-one approach.
Development of a Biopharmaceutical is - ComplexSeptember 26, 2012 11:42 am | by Sheila G. Magil, Julia Adam, Dawn Ecker, and Susan Dana Jones, BioProcess Technology Consultants, Inc. | Articles | Comments
Developing a biopharmaceutical is just like developing a traditional small molecule therapeutic…except it is not. While the types of data needed for regulatory filings is the same, the significantly increased size and molecular complexity of biopharmaceuticals compared to small molecule therapeutics has a significant impact on the strategies and activities required for development.
Single-Use in a Stainless Steel WorldSeptember 26, 2012 7:57 am | by Jeff Odum, CPIP, Biopharmaceutical Market Leader, IPS | Articles | Comments
There is a significant movement within the biotech industry to evaluate and implement single-use (SU) manufacturing systems in order to improve manufacturing efficiency, flexibility, and reduce costs.i The focus of many industry conferences and technical meetings centers on expanding the industry's body of knowledge around SU system design and applications.ii
Modern ProblemsSeptember 25, 2012 10:41 am | by Joerg Zimmermann, Vetter | Articles | Comments
Parenteral manufacturers face a host of challenges - many can be solved with a restricted access barrier system.
A Precursor to ApprovalSeptember 20, 2012 10:21 am | by Jonnatha Mayberry, Associate Editor | Articles | Comments
Preclinical contract research organizations are advancing to meet clients' new needs.
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Cody Asche belted his fourth home run of the season in a losing effort against the Brewers on Thursday.
Chad Billingsley was hit hard in his return to the Phillies starting rotation on Thursday, allowing six runs on 10 hits over his five innings of work.
Shawn Tolleson worked a perfect ninth inning against the Orioles on Thursday, protecting a two-run advantage to earn his 12th save of the season.
Leonys Martin broke up a scoreless tie with an RBI single in the ninth inning on Thursday, leading the Rangers to a 2-0 victory over the Orioles.
Yovani Gallardo extended his scoreless innings streak to 29 1/3 with another six shutout frames against the Orioles in a no-decision on Thursday.
David Lough was the lone bright spot on offense for the Orioles on Thursday, going 2-for-3 in a losing effort against the Rangers.
Kevin Gausman dazzled in a spot start against the Rangers on Thursday, racking up seven strikeouts over 6 1/3 scoreless innings.
Cameron Maybin delivered a walk-off RBI single in Thursday's 2-1 win over the Nationals.

subset: commoncrawl


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Mature Content Filter is On. The Artist has chosen to restrict viewing to deviants 18 and older.
Metal Slug Hentai by MatmordenWatch
©2011-2015 MatmordenMature Content
Two characters from the Metal Slug series (SNK) Before action Marco provides little entertainment for her girlfriend Eri x)) orginal picture [link]
Jaka poprawność polityczna zasłoniłeś dziurę w spodniach
glupie wymagania tej strony
Z tego co wiem to jak 12-to latek będzie chciał sobie pooglądać porno to Red Tube sobie włączy a nie będzie cudów na Dviancie szukał :S
Do prawdy
what is here wrong?? hmm? I gave the warning after
It's called the rules which can be viewed here FAQ #565: You prohibit the submission of 'pornographic imagery'; what do you consider this to be?
sorry now corresponds to the rules???
Should now. Have to watch it with the censoring a bit though. Can't link to uncensored material, and if the censoring is blatantly done so you can get away with it (blacking out parts of a penis and such), then they still can be removed.
thanks for help
I do not think he likes me


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Quick Ship Electronics via eBay again offers the open-box Apple iPad Air 32GB WiFi Tablet with Retina Display in White/Silver, model no. MD789LL/A, for $289.99 with free shipping. That's tied with our open-box mention from last month as the lowest total price we've seen for a 32GB iPad Air. (It's also $109 under the best price we could find for a new unit elsewhere.)
A 1-year Quick Ship Electronics warranty applies.
$290 free shippingShop Now
Open-Box Apple iPad Air 32GB WiFi Tablet


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Each Shimmy lamp has a three-tier shade. Several rows of 2.5" chrome framed round paper disks dangle from each tier. Disks rotate freely, catching light from inside and outside the shade. Stick body and flat round base are chrome. Three-way touch sensor switch (not compatible with compact fluorescent bulb). 23" in height. Base: 1" Thick, 8" Diameter. Shade: 19" Height. 5" Diameter top tier, 9" Diameter middle tier, 14" Diameter bottom tier. Tiers are 3" ...
2-Tier Sheer Smoke/Shantung Shade On-Off Switch Bulbs not included
This Pendant Lamp creates a classical lighting display with updated details 2 tiers of dangling faux crystals cast fragmented light for an elegant look Base is made of sturdy polyurethane and metal Requires 100W standard bulb UL listed
Roosevelt Brushed Nickel/Espresso One-Light Table Lamp with Sheer Snow/Shantung Two Tier Shade
The Cesti Collection is a modern interpretation of traditional light fixtures. The sumptuous tiers of curves are crowned with Clear Firenze crystal bobeches. Allegri's Firenzecrystals gracefully dangle to add sparkle and charm Wire Length: 72-Inch Bulb is not included Crystal Name: Firenze Clear
Sheer Snow/Shantung Two Tier Shade Materials: Metal/Fabric


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Titans SS Bernard Pollard has requested to be released.
Titans placed SS Bernard Pollard on injured reserve with a ruptured Achilles', ending his season.
Titans SS Bernard Pollard is done for the season with a ruptured Achilles'.
Titans SS Bernard Pollard left the stadium Sunday on crutches.
Titans re-signed SS Bernard Pollard to a two-year, $6.3 million contract.
The Nashville Tennessean reports the Titans are "in talks" with free agent SS Bernard Pollard.
Impending free agent SS Bernard Pollard expressed a desire to return to the Titans.
The Nashville Tennessean expects the Titans to start Bernard Pollard over George Wilson at strong safety.
Titans signed SS Bernard Pollard, formerly of the Ravens, to a one-year contract.
Free agent SS Bernard Pollard visited the Titans on Friday.
Ravens released SS Bernard Pollard.
Ravens SS Bernard Pollard says he played through six cracked ribs in Sunday's Super Bowl victory.
Ravens SS Bernard Pollard (chest) is active for Sunday's Wild Card Round game versus the Colts.
Ravens SS Bernard Pollard (ribs) practiced on a limited basis all week and is expected to play in Sunday's Wild Card game against the Colts.


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When do playoffs for MLB start?
Do you guys play in any keeper leagues? The league im in now we can keep players taken after the 3rd. Seems interesting....
Sir Thomas Richard Coughlin The Great
I played in a free one and never looked back at it.
I rather play a keeper for mney, but it's so hard to keep all of the same players/friends.


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a place for zinesters - writers and readers
207 members Latest Activity: Jun 27 A place for zinesters of the US East Coast to discuss zines, events, etc happening up and down that good ole' I-95 corridor.
31 members Latest Activity: Jan 16 For people in the metro Baltimore/DC area
200 members Latest Activity: on Wednesday This is a space to invite everybody to show their zine off_ Add pictures and descriptions_ I am trying to get a better idea of what people put in…
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For people who make zines out of photos, like to add photos to their zines, and like to look at photozines!
For people who make zines out of photos, like to add photos to their zines, and like to look at photozines!
210 members Latest Activity: Jun 28 A group for people who create comix/graphic zines/sequential art publications of all types.
345 members Latest Activity: yesterday Are you a queer zinester (broadly defined, of course)? Do you write about your genderfucking, transitioning, same-and-other-gender lovin'…
41 members Latest Activity: Apr 23 "We're not the first. Hope we're not the last"
85 members Latest Activity: on Wednesday I know there is a queer zinester group, but I think queer punk zines & queer punk zinsters need their own group
130 members Latest Activity: on Wednesday A place for vegan zinesters (and the veg-curious) to discuss veganism, vegan zines and how veganism is represented in the zine community.
33 members
Latest Activity: Sep 1, 2014
Check out our website at http://dczinefest.com/ for news and updates!
Check out our website at http://dczinefest.com/ for news and updates!
90 members Latest Activity: Apr 13 The weird, wonderful, spooky, creepy, gorey and horrific!!
93 members Latest Activity: Feb 16 This group is about zines or zinesters that spend any portion of their time in discussion about death.


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We are in the process of moving our training center, yet we will still be conducting private training and outdoor classes. We are looking for that just right location in the Chagrin Valley area and will announce soon.
We offer diverse curriculum to our students: Puppy Kindergarten, Elementary Basics, Elementary Grad, & 2, Canine Good Citizen, Beginning through Advanced Agility, Conformation, Therapy Dog preparation and testing, Run-Thru's. Our training philosophy focuses on positive motivation in order to gain and maintain a positive relationship between dog and owner/family and in turn improve the dog's success in training. Member of Association of Pet Dog Trainers, APDT. K9U is owned and managed by Amy Spence Gutmann.
Facility Virtual Tour


text: Friday April 25, 2014 View show Marie Howe is the author of three collections of poetry. She has received a Guggenheim Fellowship and a National Endowment for the Arts Fellowship. Brad Fowler/courtesy of the author hide caption itoggle caption Brad Fowler/courtesy of the author Poet Marie Howe On 'What The Living Do' After Loss "Poetry holds the knowledge that we are alive and that we know we're going to die," Howe says. Listen Loading… 20:47 Playlist Download Embed Embed Close embed modal <iframe src="http://www.npr.org/player/embed/306528499/306881335" width="100%" height="290" frameborder="0" scrolling="no"> Richard Blanco is the first Latino and openly gay inaugural poet. Blue Flower Arts hide caption itoggle caption Blue Flower Arts Inaugural Poet Richard Blanco: 'I Finally Felt Like I Was Home' Blanco, who read his poem "One Today" at Obama's second inauguration, is the first immigrant, Latino and openly gay poet chosen to read at an inauguration. Listen Loading… 15:45 Playlist Download Embed Embed Close embed modal <iframe src="http://www.npr.org/player/embed/306530056/306881338" width="100%" height="290" frameborder="0" scrolling="no"> A Poetry Reading: 'To My Oldest Friend, Whose Silence Is Like A Death' Fresh Air's classical music critic Lloyd Schwartz published a poem about friendship and loss on Poets.org. Listen Loading… 3:48 Playlist Download Embed Embed Close embed modal <iframe src="http://www.npr.org/player/embed/306535024/306881476" width="100%" height="290" frameborder="0" scrolling="no"> Tom Hardy plays the title character in the British film Locke — in which a man's life unravels in the course of a solo drive from Birmingham to London. He's the only person the audience sees in this film, written and directed by Steven Knight. A24 hide caption itoggle caption A24 Movie Reviews In 'Locke,' A Man's Life Unravels En Route To London Ivan Locke (Tom Hardy) is the only person the audience sees in this daring film by Steven Knight. Viewers spend an hour and a half in the car with him, on a solo drive from Birmingham to London. Listen Loading… 5:40 Playlist Download Embed Embed Close embed modal <iframe src="http://www.npr.org/player/embed/306774249/306881479" width="100%" height="290" frameborder="0" scrolling="no"> View show


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Town Square
Tolls may be raised at all seven Bay Area bridges
Original post made on Nov 6, 2009
Read the full story here Web Link posted Thursday, November 5, 2009, 4:56 PM
Comments (1)
a resident of Danville
on Nov 6, 2009 at 7:40 am
They should raise the bridge toll to $10.
Why not make the people who use the bridge pay for it rather than relying on taxpayer subsidies?
There's too much gridlock on our freeways. Maybe tolls could reduce that. I would gladly pay an extra $10 to get to my destination on time rather than sitting in traffic for hours.
If people can't afford the toll, maybe they'll start taking public transportation more often, or carpool.
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Bidding my Maverick Bye-Bye
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ACM SIGGRAPH's DIGITAL ARTS COMMUNITY (DAC)
Guide to questions to join the ACM SIGGRAPH Digital Arts Community
如何加入数字艺术社区 (Chinese)
デジタルアートコミュニティに参加する方法 (Japanese)
디지털 아트 커뮤니티에 가입 하는 방법 (Korean)
Mission of the Digital Arts Community Committee
Foster the evolution of a strong year round Digital Arts Community within the international organization and promote a dialogue between visual artists and the larger ACM SIGGRAPH community.
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Recent Polls
CBOE VIX shot up on Monday following news of Greece and Puerto Rico possibly defaulting. How much volatility to do you expect in the second half of the year?
Number of votes: 52
Date: June 29, 2015
What geopolitical risks are you monitoring as you manage your portfolios?
Number of votes: 56
Date: June 22, 2015
Speaking at GFOR, Larry Fink said the U.S. retirement crisis has the potential to be greater than the health care crisis. Do you agree?
Number of votes: 194


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Ink-jet-printable material in which a base is coated with a polymer of
(a) 50 to 99.5% by weight of at least one basic vinyl heterocycle having a pKa of at least 3.8,
(b) 0 to 49.5% by weight of a further copolymerizable monomer, and
(c) 0.5 to 10% by weight of a crosslinker.
1. A composition suitable for ink-jet printing, comprising
a base material selected from the group consisting of paper, cardboard and plastic film; and
a coating on said base material for binding anionic dyes of ink-jet inks to the base; said coating comprising
(a) 50 to 99.5% of a basic vinyl heterocycle selected from the group consisting of N-vinylimidazole, 2-methyl-1-vinylimidazole and a mixture thereof; said vinyl heterocycle having a pKa of at least 3.8;
(b) 0 to 49.5% by weight of a further copolymerizable monomer; and
(c) 0.5 to 10% by weight of a crosslinker.
2. The composition defined in claim 1, in which the further copolymerizable comonomer (b) is selected from the group consisting of N-vinylpyrrolidone, N-vinylcaprolactam, N-vinyl-1,4-dihydropyridine and a mixture thereof.
3. The composition defined in claim 1, in which the further copolymerizable crosslinker (c) is N,N'-divinylethyleneurea.
4. A method of producing a material suitable for ink-jet printing, which method comprises
coating a substrate selected from the group consisting of paper, cardboard and plastic film; said coating comprising
(a) 50 to 99.5% of a basic vinyl heterocycle having a pKa of at least 3.8;
(b) 0 to 49.5% by weight of a further copolymerizable monomer, and
(c) 0.5 to 10% by weight of a crosslinker.
5. The method of claim 4, wherein the polymer is prepared in the presence of a reducing agent.
6. The method of claim 4, wherein the polymer has a particle size of from 0.01 to 100 μm.
7. The method of claim 4, wherein the polymer is prepared in the presence of water at from 30 to 150� C.
8. The method of claim 4, wherein the basic vinyl heterocycle is selected from the group consisting of N-vinylimidazole, 2-methyl-1-vinylimidazole and a mixture thereof.
9. The method of claim 4, wherein the copolymerizable comonomer is selected from the group consisting of N-vinylpyrrolidone, N-vinylcaprolactam, N-vinyl-1,4-dihydropyridine and a mixture thereof.
10. The method of claim 4, wherein the copolymerizable croslinker is N,N'-divinylethyleneurea.
The invention relates to the use of a polymer based on a basic vinyl heterocycle having a pKa of at least 3.8 for coating printable materials, especially for coating plastic film and paper which is intended for ink-jet printing.
Ink-jet inks are solutions of anionic dyes in water or aqueous organic mixtures. To prepare a printed product, these inks are sprayed in dot form onto a printable surface. To prevent the size and shape of the applied ink dots altering as a result of the ink running, and to prevent the edges becoming indefinite, it is necessary to fix the inks immediately on their application. This is done by fixing the anionic dyes on polymers with which the printable materials have been coated beforehand. The ink binds to the polymers either ionically (cationic polymers) or by way of π--π interactions (neutral polymers).
Dye-fixing components used to date include soluble cationic polymers, predominantly of the quaternary ammonium compound type. These are formulated with absorbent pigments onto which they are absorbed.
JP 06143800 describes a silica gel in combination with a quaternary polyethyleneimine, where a two-layer structure of the components is intended.
JP 06092007 proposes at the actual papermaking stage using as filler a calcium carbonate treated with a formulation including a copolymer of trimethylammonium methacrylate and vinyl alcohol.
EP 487 349 describes silica gel particles which have been treated with a cationic polyamine (Cypro 514�).
JP 01009776 proposes for this purpose the cationic copolymer of diallyldimethylammonium chloride and acrylamide.
JP 63307979 proposes giving paper for ink-jet printing a coating of a hydrophilic soluble copolymer of vinylimidazole, vinylpyrrolidone and vinylbenzylsulfonic acid (60:30:10).
A disadvantage of the types of coating described above is that all of them require two components which accomplish dye binding and solvent fixation either by absorption into a three-dimensional, porous cavity system or by an increase in viscosity. In the case of JP 63307979, the porous system is produced by the crosslinking of gelatin with 1,4-butanediol diglycidyl ether. The key disadvantage is the reactivity of this constituent. Following the addition of water and the beginning of the crosslinking reaction, the formulation can be processed in the coating units for only a short time.
It is an object of the present invention, therefore, to provide polymers which are suitable for coating printable materials and do not possess the disadvantages mentioned above.
We have found that this object is achieved by the subject-matter of the invention, which provides for the use of a polymer of
(a) 50 to 99.5% by weight of at least one basic vinyl heterocycle having a pKa of at least 3.8,
(b) 0 to 49.5% by weight of a further copolymerizable monomer, and
(c) 0.5 to 10% by weight of a crosslinker for coating printable materials,
and by the embodiments set out further in the subclaims.
In EP-A-4 38 713, polymers of this kind are used to remove heavy metals from wine and similar beverages. As regards the preparation of the polymers, express reference is made to this document.
The basic vinyl heterocycles (a) are in this case saturated and aromatically unsaturated heterocycles having a vinyl group and at least one basic tertiary ring nitrogen, with a pKa of at least 3.8. In addition to vinyl, the ring may also carry alkyls of 1 to 4 carbons, phenyls or benzyls, or even a second, fused-on ring. Examples of such heterocycles (a) are N-vinylimidazole (VI) and derivatives thereof, such as 2-methyl-1-vinylimidazole, 4-methyl-1-vinylimidazole, 5-methyl-1-vinylimidazole, 2-ethyl-1-vinylimidazole, 2-propyl-1-vinylimidazole, 2-isopropyl-1-vinylimidazole, 2-phenyl-1-vinylimidazole and 1-vinyl-4,5-benzimidazole. Further examples of usable compounds are 2-vinylpyridine, 4-vinylpyridine and 2-methyl-5-vinylpyridine. It is of course also possible to employ mixtures of basic vinyl heterocycles with one another.
Preferred monomers (a) are N-vinylimidazole and 2-methyl-N-vinylimidazole.
The monomers (a) are employed in a proportion of 50-99.5%, preferably 60-96%, based on the overall polymer weight.
Suitable crosslinkers (c) are those whose molecule includes two or more free-radically copolymerizable vinyls, especially alkylenebisacrylamides, such as methylenebisacrylamide and N,N'-bisacryloylethylenediamine, N,N'-divinylethyleneurea, N,N'-divinylpropyleneurea, ethylidene-bis-3-(N-vinylpyrrolidone) and also N,N'-divinyldiimidazolyl-(2,2')- and 1,1'-bis(3,3'-vinylbenzimidazolid-2-one)-1,4-butane. Examples of other crosslinkers which can be used are alkylene glycol di(meth)acrylates, such as ethylene glycol di(meth)acrylate and tetramethylene glycol di(meth)acrylate, aromatic divinyl compounds, such as divinylbenzene and divinyltoluene, and also allyl acrylate, divinyldioxane, pentaerythritol triallyl ether, and mixtures thereof. When polymerization is carried out in the presence of water their suitability of course depends on their ability to dissolve in the aqueous monomer mixture.
The crosslinkers (c) are employed in a proportion of 0.5-10%, preferably 1-4% based on the weight of all monomers in the polymer.
The comonomers (b) are incorporated by polymerization in proportions of up to 49.5%, preferably up to 30%, particularly preferably up to 20%, based on the weight of the total monomer mixture. Examples of suitable comonomers (b) are styrene, acrylates, vinyl esters, acrylamides and N-vinyl-dihydropyridines. Comonomers (b) used with preference are N-vinyllactams such as 3-methyl-N-vinylpyrrolidone, especially N-vinylcaprolactam and N-vinylpyrrolidone (VP).
Particularly suitable polymers for use in accordance with the invention are those of N-vinylimidazole (VI), N-vinylpyrrolidone (VP) and N,N'-divinylethyleneurea (DVEU), especially those of 80-90% by weight VI, 5-15% by weight VP and 2-5% by weight DVEU.
For polymerization without solvent the monomer mixture, consisting of basic vinyl heterocycle, crosslinking agent and, if used, N-vinyllactam or another comonomer, is rendered inert by passing nitrogen in and is subsequently heated at 100-200� C., preferably 150-180� C. It is advantageous to continue to pass a gentle stream of nitrogen into the mixture. It is particularly advantageous if the batch is brought to boiling by applying reduced pressure. Depending on the monomers used and the temperature chosen, the mixture then polymerizes within 1-20 hours. For example, in the polymerization of 2-methyl-vinylimidazole with 2% of N,N'-divinylethyleneurea at 150� C. and at 310 mbar, where the batch is stirred with a powerful stirrer, the first polymer particles are formed after 2.5 h, and gradually increase until after 10 h the batch consists of a brownish powder, which is rinsed with water and dried to give yields of more than 90% of a coarse polymer powder.
A preferred preparation technique is that of precipitation polymerization in water. The monomer concentration of the reaction mixture is expediently chosen such that the batch remains readily stirrable throughout the reaction period. If there is too little water, the polymer particles in fact become sticky, so that stirring is even more difficult than if no water at all were present. In the case of the customary stirred vessels the expedient monomer concentration, based on the aqueous mixture, is from about 5 to 30% by weight, preferably from 8 to 15% by weight. It may be raised to 50% by weight if powerful stirrers are available. It can also be expedient to start the polymerization with a relatively concentrated solution and then to dilute it with water as the reaction progresses. Polymerization is advantageously carried out at a pH of more than 6 so as to avoid possible hydrolysis of the comonomers and/or crosslinkers. The pH can be established by adding small amounts of bases, such as sodium hydroxide or ammonia, or the customary buffer salts, such as sodium carbonate, bicarbonate or phosphate. Oxygen can be excluded by keeping the polymerization mixture at boiling and/or, as mentioned, with the aid of an inert gas such as nitrogen. The temperature of polymerization here may be from to 150� C., and is preferably from 40 to 100� C.
In some instances it may be advantageous, in order to remove completely any dissolved oxygen, to add small quantities--from 0.01 to 1% by weight, based on the monomer mixture--of a reducing agent such as sodium sulfite, sodium pyrosulfite, sodium dithionite, ascorbic acid or the like either prior to or at the beginning of polymerization.
In a particularly preferred embodiment of precipitation polymerization the water-soluble comonomer (preferably NVP or an N-vinyllactam), some of the crosslinker, water and, if used, a buffer and a reducing agent are heated in a gentle stream of nitrogen until the first polymer particles are formed. Then a mixture, which has been rendered inert beforehand by blowing in nitrogen, of the vinyl heterocycle and the rest of the crosslinker and, if used, water as diluent is added over a period of 0.2-6 hours.
The start of polymerization can often be brought forward by adding from 0.01 to 5% by weight, based on the monomer mixture, of a crosslinked polymer of low swellability which is based on basic vinyl heterocycles having a pKa of at least 3.8 or vinyllactams, especially N-vinylimidazole and N-vinylpyrrolidone.
The polymer produced can be isolated from the aqueous suspension by filtration or centrifugation, then rinsed with water and dried in customary apparatus such as a convection or vacuum oven, a paddle drier or a flow drier.
For use in accordance with the invention the polymer is generally employed in amounts of 0.5-90%, preferably 2-20%, based on the total dry mass of the coating formulation. The size distribution of the polymer particles normally encompasses a range from 0.01-100 μm, preferably 0.3-20 μm.
A further constituent of the coating formulation is a binder, highly suitable examples being polyvinyl alcohols or polyvinylpyrrolidones having K values from 60 to 90.
Other possible constituents of the coating formulation are the fillers known from papermaking, such as barium sulfate, calcium carbonate, kaolin, talc, titanium dioxide and silicates.
The constituents are suspended in a liquid medium, preferably water, to a solids content which is normally from 30 to 80% and a viscosity (Brookfield) of from 100 to 3000 mPas.
This suspension is used directly to coat the materials which are to be printed, ie. especially paper, cardboard and plastic films.
The printable materials do not generally require any pretreatment before the polymer-containing coating composition is applied.
The examples which follow illustrate the invention further.
In a stirred vessel with reflux condenser a mixture of 50 parts of N-vinylimidazole, 30 parts of 2-methyl-l-vinylimidazole and 30 parts of N-vinylpyrrolidone to which 3 parts of N,N'-divinylethyleneurea were added was heated at 160� C. and 250 mbar. After about 90 minutes the first insoluble polymer particles appeared. 2 hours' stirring later, the reaction batch consisted of a dry powder which was subsequently washed on a suction filter and dried at 60� C. in a convection oven. The yield was 93.5%.
A mixture of 4 parts of N-vinylpyrrolidone, 0.1 part of N,N'-divinylethyleneurea (DVEU), 50 parts of water and 0.5 part of 5% strength sodium hydroxide solution was placed in a stirred vessel and heated to 60� C. in a stream of nitrogen. 0.01 part of sodium dithionite was added and the mixture was stirred at 70� C. for 1 h. A suspension was obtained into which a solution of 37 parts of N-vinylimidazole and 1.2 parts of DVEU in 50 parts of water was metered over a period of 3 hours. The mixture was subsequently polymerized at 70� C. for 2 hours. The product was worked up by washing on a suction filter, rinsing with water and drying at 60� C. in a convection oven, to give fine white particles in a yield of 95%.
In a stirred apparatus fitted with a reflux condenser, a solution of a mixture of 15 parts of N-vinyl-1,4-dihydropyridine and 15 parts of N-vinylpyrrolidone in 200 parts of water, to which 0.6 part of N,N'-divinylethyleneurea was added, was first gassed with nitrogen while stirring, at 60� C., and then 1 part of sodium dithionite was added. One hour later, a solution of 70 parts of N-vinylimidazole and 1.4 parts of N,N'-divinylethyleneurea in 200 parts of water was added to the primary suspension obtained before. The batch was heated at 80� C. with stirring and polymerized for 8 hours. The resulting precipitated polymer was separated off on a suction filter, washed carefully with water and dried at 50� C. in a vacuum oven. The yield of fine white odor-neutral powder was 94.7%.
10 parts of the comminuted polymer of Example 2 were incorporated into 100 parts of water together with 80 parts of calcium carbonate (95%) with a particle diameter of less than 2 μm and with 10 parts of Luviskol K 90� (polyvinylpyrrolidone) and the mixture was homogenized.
The resulting dispersion was applied as a level coating on the paper by means of a roll doctor, a coating knife, a film press, an air brush or a coating press. The amount applied was 2-15 g per m2 of paper.
10 parts of the comminuted polymer of Example 2 were incorporated into 100 parts of water together with 75 parts of calcium carbonate (95%) with a particle diameter of less than 2 μm and with 10 parts of poly(trimethylammoniummethyl methacrylate) and 5 parts of polyvinyl alcohol Kurraray R1130� and the mixture was homogenized.
The resulting dispersion was applied as a level coating on the paper by means of a roll doctor, a coating knife, a film press, an air brush or a coating press. The amount applied was 2-15 g per m2 of paper.
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Kala "Kolohe" Hose will face Falaniko "Niko" Vitale for the X-1 middleweight title at "X-1 Heroes" this Saturday, Sept. 11, in Honolulu, Hawaii. Kala spoke to us about the upcoming fight. Read More »
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Pardon the Interruption
July 24, 2013
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Mike and Bob Ryan discuss the top sports stories including: their thoughts on Patriots head coach Bill Belichick's comments on former Patriots tight end Aaron Hernandez being arrested for murder; their thoughts on Alex Rodriguez's personal physician saying that Rodriguez isn't injured and is cleared to play, which contradicts the Yankees' team physician; their thoughts on the Dodgers' Matt Kemp saying that Ryan Braun should be stripped of his 2011 National League MVP award. Later Mike and Bob play What's the Word? Joe Maddon, Tampa Bay Rays manager, joins Mike and Bob for Five Good Minutes.moreless
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Happy Birthday: Karl Malone!
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Bette's legendary feud with Joan Crawford began when Bette was making the movie Dangerous with Franchot Tone. They were both having an affair with him and the other didn't know.
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· Even if you do not receive a discover of assessed worth on your BPP account, it is still vital to send a written discover of attraction or protest. The appraisal district does not have to ship a notice of your assessed worth if the value does not change by greater than $1,000. If the notice of assessed worth gets lost in the mail, and you do not send a protest discover, you lose your right to attraction for the current 12 months. (a) exposed for sale within the open market with an inexpensive time for the seller to discover a purchaser, Getting ready A Abstract For Your Hearing . Evaluation data
When sending a notice of appeal to the ARB, also ship the appraisal district a Home Bill 201 request. House Bill 201 refers to part forty one.461 of the Texas Property Tax Code that allows property homeowners to obtain a duplicate of any evidence the appraisal district plans to make use of on the ARB listening to 14 days earlier than the hearing. This request prohibits the appraisal district from using any info that was not offered to the property owner 14 days earlier than the ARB hearing. (c) Both the vendor and the purchaser seek to maximise their good points and neither is able to take advantage of the exigencies of the opposite. 386
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Assessed values for BPP accounts typically vary from ten-occasions to fifty-instances on a per square foot foundation for companies in the identical industry. For example, actual estate brokerage offices, which have 10,000 sq. feet of office space, might have assessments starting from $10,000-$500,000. It seems unlikely that the computer systems and furniture in one brokerage office are 50 occasions as useful as these in a competitor's agency on a per square foot foundation. · First meet with the appraiser and politely explain the basis in your adjustment. Give the appraiser a duplicate of your proof and explain it in a methodical manner. · Introduction of the two events on the listening to
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Todd Nolin
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If you have any comments, corrections, etc., I will be glad to add them. Also if you would like to create your own memorial for a loved one or would like for me to transfer ownership, please let me know. I mean absolutely no disrespect for your loved one. I do this to assist the many geneaologists who are unable to visit their ancestors.
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Todd, thank you so much for the transfer of Joseph L. Hammond.
Added by
on May 29, 2015 6:28 AM
Jim Fletcher
I would like to ask you to link these two records together. They were husband and wife.
Thanks for this and all of your efforts in the past.
Jim Fletcher
Acworth, GA
Added by
Jim Fletcher
on Aug 07, 2014 3:29 PM
Charlotte Hardamon Coble
Amanda Jane DAVIDSON Lovelace
Todd, I sent you an edit to LINK her parents and husband. Please DO NOT ACCEPT the request. I have the wrong mother. Her father Elias Davidson married a second time and she is a daughter from the second marriage. Let me do more research and I will resend my edit to you with the correct information. Thank you. Charlotte H Coble
Added by
Charlotte Hardamon Coble
on Jul 10, 2014 3:56 PM
Patricia J Cumbie
Re: Cumbee Transfer
Mr. Nolin,
Thank you so very much for the transfer and for all the work you added to this memorial page. I appreciate all the photos for this family's headstones, may I use them in our genealogy history. I will connect this one to his parents now. Thank again.
Added by
Patricia J Cumbie
on Jan 26, 2014 9:04 PM
Member #47700116
Thank you (Ezekiel Grace #24103721 )
Thank you VERY much for the links to parents and adding the bio information.
Ezekiel has been hard to find. Thank you for entering him into Find A Grave.
John Robertshaw
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Member #47700116
on Jan 16, 2014 1:43 PM
John Dickinson
Photo Use
May I have your permission to repost your Find A Grave photos (with attribution) to my family research site?
John Dickinson
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John Dickinson
on Aug 18, 2013 6:33 PM
Timothy DeBoor
Ann Elizabeth Burford Cotton
Hi Todd,
This is in reference to your Find A Grave Memorial# 26423022 for Ann Elizabeth Burford Cotton. Do you have any idea what the inscription is on the bottom of her headstone? Thanks
Added by
Timothy DeBoor
on Nov 20, 2012 6:30 PM
Mary Enzor Smith
Miller transfers
Todd, thanks much fior the Miller transfers. This is part of my Atkinson line. You are appreciated.
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Mary Enzor Smith
on Jul 19, 2012 7:57 AM
Susan Patton Hamersky
Wow, thank you for the transfers; that was so fast!
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Susan Patton Hamersky
on Jul 17, 2012 5:15 PM
Susan Patton Hamersky
Estelle Horsley Henderson 26422993
Hi again, If possible, please transfer to me. She is my great-aunt. Thank you! Susan Patton Hamersky (#47278530)
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Energy Dispersive SpectrometerJuly 8, 2011 4:10 am | Product Releases | Comments
JEOL's Centurio is a silicon drift detector (SDD) energy dispersive spectrometer (EDS) for fast and sensitive collection of X-rays through analysis with its scanning transmission electron microscopes (S/TEM).LISTED UNDER: X-Ray Equipment, Diffractometers | Spectrometers | Spectrometry/Spectroscopy
X-ray Diffraction System Aids Energy SectorJune 9, 2011 4:53 am | Product Releases | Comments
The PANalytical Empyrean X-ray diffraction (XRD) system is equipped with Anton Paar's HPC900, a non-ambient sample stage. This combination enables researchers to study the kinetics of reaction in situ , determine crystalline phases, and study structural changes in materials under extreme conditions.LISTED UNDER: X-Ray Equipment, Diffractometers
TOC AnalyzerJune 9, 2011 4:34 am | Product Releases | Comments
GE Analytical Instrument's SieverInnovOx total organic carbon (TOC) analyzers monitor high levels of dissolved solids, such as salts in the process water of large-scale technologies for the production of clean energy from low value fossil fuels to determine production yield efficiency.LISTED UNDER: Carbon Analyzers
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Global Water Instrumentation, an ITT Analytics company, has introduced the WE550 and WE570 weather instruments for accurate wind speed and direction measurements.LISTED UNDER: ANALYSIS INSTRUMENTS | Electronic Test | Meters
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The BioAnalyzer from Microfluidica provides on-line monitoring and control in fermentation broths of key chemical species including acetate, ammonium, glucose, glycerol, lactate, and phosphate.LISTED UNDER: Chemical Analyzers
Alternative Fuels Research Dynamometer Test CellJune 9, 2011 4:11 am | Product Releases | Comments
SAKOR Technologies, Inc. has delivered a single-cylinder research engine test cell to the U.S. Department of Energy's National Renewable Energy Laboratory (NREL).LISTED UNDER: ANALYSIS INSTRUMENTS | Meters
Microscope spectrophotometer with colorimetryJune 1, 2011 3:46 am | Product Releases | Comments
CRAIC Technologies has introduced the 308 PV microscope spectrophotometer with colorimetry. Designed to be added to the photoport of a microscope or probe station, the 308 PV is a spectrophotometer that can non-destructively analyze the color of many types of microscopic samples.LISTED UNDER: ANALYSIS INSTRUMENTS | Image Analysis | Microscope Supplies and Accessories
On-line calibration standards for trace sulfur in olefinsMay 26, 2011 6:29 am | Product Releases | Comments
The KIN-TEK Span Pac 261-I, industrial gas standards generator is configured to make standards for trace concentration sulfur impurities in an olefin matrix.LISTED UNDER: Gas Analyzers
Industrial gas systemMay 23, 2011 4:06 am | Product Releases | Comments
Thermo Fisher Scientific Inc. has announced enhancements to its Antaris industrial gas system (IGS). The Antaris IGS now offers scan speeds up to 5 Hz at 0.5 cm -1 resolution and enhanced electronic and communication capabilities.LISTED UNDER: Gas Analyzers | FT-IR | Spectrometry/Spectroscopy
Gas analyzer for thermal analysis systemsMay 13, 2011 4:08 am | Product Releases | Comments
The Hiden QGA mass spectrometer is a multirole gas analysis system that can monitor and/or control a range of thermal reaction systems and processes.LISTED UNDER: Gas Analyzers | Other Mass | Spectrometers
Energy dispersive x-ray fluorescence spectrometerApril 26, 2011 3:38 am | Product Releases | Comments
The EDX-LE from Shimadzu Scientific Instruments is an energy dispersive X-ray (EDX) fluorescence spectrometer designed for screening elements regulated by RoHS/ELV directives.LISTED UNDER: X-Ray Equipment, Diffractometers | Fluorescence | Spectrometers
Agilent Technologies launches industry's fastest logic analyzerApril 15, 2011 7:30 am | Agilent Technologies Inc. | Product Releases | Comments
The new analyzer offers reliable data capture rates up to 4 Gb/s on the industry's smallest eye openings: 100 ps to 100 mV. The U4154A AXIe-based logic analyzer module is engineered for working with double data rate memory systems, application-specific ICs, A/D converters, and FPGAs.LISTED UNDER: ANALYSIS INSTRUMENTS | Electronic Test
Moisture analyzerApril 14, 2011 6:40 am | Product Releases | Comments
Shimadzu Scientific Instruments announced the availability of the MOC63u moisture analyzer with UniBloc sensor technology for laboratory testing.LISTED UNDER: Moisture Analyzers
Moisture balance provides high-accuracy analysisApril 13, 2011 8:31 am | Product Releases | Comments
Shimadzu's new MOC63u Moisture Balance features UniBloc sensor technology to help ensure reliable laboratory testing, including fast response time and stable corner-load performance during analyses.LISTED UNDER: Moisture Analyzers | Testing Systems, Equipment/Supplies
Natural gas analyzerMarch 28, 2011 4:11 am | Product Releases | Comments
Thermo Fisher Scientific Inc. has announced the Thermo Scientific C2V-200 micro GC gas analyzer, designed for analysis of natural gas composition. The analyzer is utilized both inside laboratories and on-line.LISTED UNDER: Gas Analyzers | Micro GC Systems


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CIA plane crash lands with four tons of coke
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I think Americans are smart enough to realize that one of the biggest drug dealers in the world is the United States government (and its military counterpart). This has been going on for a very long time. There is a reason its called the Drug "Enforcement" Agency.
What's funny are the campaigns that make emphatically benign suggestions like "If you by a quarter oz. of marijuana from your buddy you are contributing to global terrorism". They then flash pictures of Middle East munition stashes and Afghani poppy farmers.
The truth is if you are an American and you pay taxes to the United States government, you are supporting global terrorism. It may not be pretty, but it is a fact.
What so many of these government officials have failed to realize is that we are watching from a place they are unaware of. A place that allows us to record their every move. Until that moment they will remain blissfully unaware. Until that moment they will think they have succeeded in avoiding detection and capture. Until that moment they will continue to exercise their free will.
That moment soon approaches.
Anonymous Coward 27901460
If you ever worked for USA gov, u would know that 99% of the people would tell on whoever was breaking the law. More than likly mex mofia here. If you don't know, they have the money to do anything.
Anonymous Coward 17865664
Shillin like a villain! Hope you don't think anyone here is buying your bs.
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Man finds dollar wife signed years after her death
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MTV's '120 Minutes' to Return
VJ Matt Pinfield is hosting both an on-air show, to air later this year, as well as a new weekly online program debuting Friday.
MTV's legendary alternative rock music franchise 120 Minutes is returning to the network.
Veteran VJ Matt Pinfield will host a monthly show, to air later this year on MTV2, as well as a new weekly online show, 120 Seconds, which debuts March 18 on the network's new curated site, on www.mtvhive.com/120.
"I've always loved working with MTV and its passionate staff," Pinfield said in a statement Thursday. "I am elated and proud to be part of bringing back one of the most influential and longest running music shows in the network's history. Everywhere I go, people from all over the world-talk about how much 120 Minutes shaped their musical tastes and how much they missed it. The show helped expose, and ultimately, break new artists. MTV's historical role in breaking artists of all genres can never be underestimated. I'm looking forward to the exciting present and future of 120 Minutes and 120 Seconds!"
Said Amy Doyle, EVP, Music and Talent, MTV: "The signature of MTV's 120 Minutes was the unparalleled passion for and perspective on the latest music and artists that were off the mainstream media's radar. Being able to bring back that music ethos and Matt Pinfield back as host was essential but we also needed to re-invent the 120 Minutes franchise through a multi-screen experience that a whole new generation of music fans would appreciate – and we believe we've accomplished that with MTV Hive's 120 Seconds and MTV2's 120 Minutes."
Never miss a story. Stay up-to-date with THR's Daily Headlines.
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text: Arts & Entertainment Beetles Peggy Notebaert Nature Museum Beetles on display at "Food: The Nature of Eating" exhibit at the Peggy Notebaert Nature Museum. Farmers often purchase beetles to eliminate crop-destroying pests. Heather Charles, Chicago Tribune This photo is featured in these articles: Arts & Entertainment Notebaert's natural look at food, plow to plate


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- Several Aboriginal groups are raising the alarm about a small community near Alice Springs that has been without a water supply for a month now. The Northern Territory Government has been resisting calls to reinstate water because the community isn't zoned as a town camp and isn't entitled to the ...Friday 12 September 2014
- Alice Springs Councillor Steve Brown says a government advisory committee was 'hijacked' by environmentalists...Thursday 20 March 2014
- Surveyors in the Northern Territory are using a remote control boat to measure the depth of a dam in a remote Indigenous community. ...Thursday 11 April 2013
- Scientists have dressed up about 20 trees along a river bed on a Northern Territory cattle station in large silver jackets, all in the name of groundwater science....Wednesday 10 April 2013
- The Northern Territory Government has released a draft management plan for the Great Artesian Basin....Monday 8 April 2013
Explore by Topic
Latest Water Management stories on ABC Alice Springs
Latest Water Management stories on ABC Online
- Friday 26 June 2015
- The management of the Great Barrier Reef is a constant topic of conversation among the Australian public. Whether it's agricultural runoff, mining and port development or tourism, there are a number of issues that people point to as the 'greatest threat' to our national treasure. ABC North ...Tuesday 23 June 2015
- Passionate young female surfers are using International Surfing Day to push to have the Gold Coast's beaches preserved....Friday 19 June 2015
- Most of the students at St Francis School in Hughenden in north-west Queensland live on drought-stricken grazing properties. While their parents spend their days hand-feeding the few cattle they have left, the grade four, five and six students are learning how to grow fruits and vegetables. ...Friday 19 June 2015
- Water tanks are being installed in a Tasmanian town where the water isn't safe to drink because of lead contamination. But a researcher who studies the source of the contamination says the tanks don't address the potential contamination source of the pipes within people's houses. He's ...Thursday 18 June 2015
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- Thirty years ago Tom Vandeler was a South Australian grain and sheep farmer. These days he trains pigs to fly.
- Barkly Tablelands cattleman Chris Towne has expressed safety concerns about the shutdown of the Tennant Creek weather radar in the Northern Territory.
- The Bureau of Meteorology's (BOM) acting regional director Ben Suter said he understood frustration about the short notice but said the BOM had been c
- Northern Territory Government tests water for release of Crown Land
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To be honest, I don't even have to look at the performance of these drivers to recommend them. If you saw our article regarding upcoming features the other day called Future ATI Catalyst Drivers - Why you should be excited!, you'll know why you should upgrade if there's even no performance upgrades this month.
Fortunately, outside the fancy new features that the ATI driver team has given us, there are some performance improvements. So let's have a quick look at them before checking out our testbed and getting stuck into the performance numbers.
- Performance Improvements
DiRT 2 - Overall performance improves up to 8% on ATI Radeon HD 5970, ATI Radeon HD 5800 series, and ATI Radeon HD 5700 series products
Battleforge - CrossFire ATI Radeon HD 5870 performance improves up to 6%
Unigine Heaven - DirectX 9 CrossFire performance has improved significantly on ATI Radeon HD 5700 and ATI Radeon HD 5800 series products
The Chronicles of Riddick - Assault on Dark Athena - Overall performance on ATI Radeon HD 5970 improves up to 4%
PRICING: You can find products similar to this one for sale below.
United States: Find other tech and computer products like this over at Amazon's website.
Australia: Find other tech and computer products like this over at PLE Computer's website.
Canada: Find other tech and computer products like this over at Amazon Canada's website.


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By now, most of us know that Ed McMahon, esteemed "Tonight Show" sidekick of Johnny Carson's for three decades, passed away on Monday night at age 86. In a fitting tribute, host Conan O'Brien opened his Tuesday night show with a tribute.
"It is impossible I think, for anyone to imagine the 'Tonight Show With Johnny Carson' without Ed McMahon. Ed's laugh was really the soundtrack to that show. ...
For 30 years Ed played his part perfectly, he played it with effortless joy and sitting alongside Johnny, Ed was an indelible part of what I think is the most iconic two-shot in broadcasting history. There will never be anything like that again. Now everybody here at the 'Tonight Show' mourns the lose of this warm and really truly funny man. Our thoughts go out to his family and to his fans everywhere... Ed, you will be missed."
We all will miss him.
And now, "Heeeeeeeeeeeeere's Johnny!"


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Very nice example. Number 151 of only 395 Carrera Coupes built for the US market in 1975. The motor is very strong and the... More
San Francisco Sports Cars offers a mighty cool 1973 Porsche 911E for sale. This is a fun little hot rodded long hood E coupe... More
1974 PORSCHE 911 CARRERA 2.7 TARGA SPECTACULAR CONDITION! ORIGINAL CALIFORNIA CAR! #108 OF 246 BUILT! MOST DESIRED COLOR COMBINATION! 3-OWNER'S FROM NEW! FULL DOCUMENTATION, INCLUDING: OWNERSHIP HISTORY BOOKS MANUALS SERVICE RECORDS PORSCHE CERTIFICATE OF AUTHENTICITY ORIGINAL... More
Porsche 911 E Oellklaeppe Targa one of 800 built 1972 For sale a special Porsche 911 E Oellklaeppe in the rare Targa version. Built in... More
We are excited to offer on behalf of one of our clients this outstanding 1972 Porsche 911 S Coupe. The '72 911S is the most... More
Porsche 911 S 2.7 ltr 1975 small body restored in Holland 1975 Porsche 911 with the original small body. Recently restored in Holland. New paint... More
Chequered Flag International is pleased to offer this 1973 1/2 Porsche 911T/E CIS Coupe in Red with Brown interior. Initially olive (39). Engine #... More
1975 Porsche 911 Carrera 2.7L Sunroof Coupe - US Version Chassis No. 9115400113 Engine No. 6550731 Complete Matching-Numbers as per Porsche Certificate of Authenticity Long Time California Car - Highly Original... More
1975 Porsche 911 Carrera for saleWe are proud to own and offer this 1975 Porsche 911 US Carrera with 44,281 miles finished in metallic... More
Ridged US emission standards left many car manufacturers trying to find their way during the Mid 1970's. The US automakers who has such performance... More
Porsche 911 S 2.7 Targa model 74 Smallbody matching numbers 175 pk This 1974 Porsche 911 S Targa with original Small body is one of... More
Starting with a very clean solid 911 T, this beautiful RS tribute car has the right look and is also a very fun car... More
1979 Porshce 911 SC Targa for saleExotic Classics is please to present this 1979 Porsche 911 SC Targa finished in Meteor Gray on Black... More
1971 Porsche 911T coupe, 5 speed transmission, Kardex Matching Number , Car 911 110 0515 Engine # 6115052, Silver Metallic with Black Leatherette, options... More
1976 Porsche 911 S Targa ***NEW ARRIVAL * RARE COLLECTIBLE * RESTORED*** Domani Motor Cars is excited to announce the arrival of this EXTREMELY... More


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14RE: [21stCenturyPoetsUnite] HAPPY NEW YEAR!
Expand Messages
- Jan 3, 2003Happy New Year to you, too Kat! I hope this one turns out better than
the last one. It's looking ok so far. Recent promotion, possibility of
moving to another state... We'll see. Hope all is well with you!
-----Original Message-----
From: Katyana Wylie <katyana00@...> [mailto:katyana00@...]
Sent: Friday, January 03, 2003 12:39 PM
To: email@example.com
Subject: [21stCenturyPoetsUnite] HAPPY NEW YEAR!
It's a new year and time for rejuvenation! Let's begin by welcoming
the new members and encouraging them to introduce themselves, with a
few words about their favorite poets and/or a personal poem for
We need to build this list up and this is the year to do it. Tell
your friends and family. Include a link in your signature for e- mails.
Swap links with me to include on each others pages. If you're
a member of another poetry group, tell your online buddies about this
Once I'm finished school, I hope to have more time to devote to this
group (and my own poetry).
Happy 2003 Everyone!
- << Previous post in topic


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Overall score
would recommend to a friend.
Reviewer score
Would recommend
Nice comfortable location!
A great value for a short getaway. If it was good enough for the Beatles and Cary Grant it's good enough for me.
Don't eat at Oceanus.
Ideally placed hotel
Ideally situated, minutes to Central Park or Tiimes Square. Room was very smart, the mattress and pillows made the bed one of the most comfortable hotel beds we have slept in. Staff were very helpfull.
Had breakfast in their resturant, also good.
Would definitely recommend this hotel and hope to stay there again.
Brooklyn Diner
Fantastic for a romatc date with your wife
Very friendly Staf, always willing to there best for you. But the air condition in the room was very noisy.
Dad and his girls
Went for 4 days with my 2 young daughters. The room was clean and nice. The room and bathroom were immaculate every day on return. Service was cordial and responsive . Open and easy with kids. The real value of this hotel is location, location,
location. Shopping, theatre, and great restaurants all a short walk. Close subway terminals and a very short ride to Central Park and museums and easy ride to East village and Chinatown/ little Italy. Great value for a 4 star midtown hotel. I will definitely stay again!
Another Great Trip
Just returned from another great trip to NYC. Love sharing the city and sites with family and friends. The Warwick Hotel is wonderful. It has the charm and feel of old NYC and location couldn't be better! A couple of blocks to Times Square, a
couple of blocks to Rockefeller Center/5th Avenue, MOMA, Radio City, etc. Staff friendly and helpful. Love this hotel!
Great family gathering
Excellent location, beautiful corner suit with a nice view. Wonderful cozy bar with friendly staff ,good drinks and yummi goodies.
The Plaza food hall
great stay!
The Warwick is a beautiful hotel steeped with history and grace. Built in the twenties, it still maintains the elegance of the era, but with all the modern conveniences. Our room was spacious, incredibly clean, and most importantly for me, had a
very comfortable bed. Since my husband and I were traveling together, we needed a bed that doesn't move at all (with nighttime tossing and turning) with two people, and this one was very plush and didn't move at all.
The location (mid-town-54th and 6th) is ideal. Close to 5th Ave. shopping, Broadway, Central Park, etc.
I highly recommend The Warwick to anyone who wants an amazing NYC experience!
great, great.!!
What can I say everything was perfect. From beginning till end. As soon as I checked in I asked if I could upgrade my room n of course they hooked me up right away no problem and I didn't have to wait till 3 went to my room right away. The room
was very clean . Housekeeping always on top of thing room was always clean. Actually they would come twice a day. I would go downstairs for breakfast I already have my cappuccino serve to me without asking great customer service. I govto the bar again great service both time. N I always get greeted by the staff no matter what there job desciption is. Yes I would make The Warwick Hotel my next stay. Keep up the excellent service. Thank You ♡
Everythings close by trains, shops, resturants.
An amazing night.
I needed a night to catch up with my lady who's been on tour for weeks. The place was super clean and beautiful. The staff was lovely and attentive. The minibar and in room breakfast were a little pricey but that was expected.
Location, Location, Location
Love Rudolph's looking out on the Ave of america's watching people pass. I have stayed at the 5 star hotels in the past. This is a fantastic location. The price was outstanding for the quality. I shall book here again.
Del Frisco's - pricey, bread fantastic & steak outstanding. Worth it.
Great Hotel
The Warwick is first class. Great location to Moma, Broadway, and shopping. Near subway station.
42nd Street and Broadway.
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text:
The Writing Center offers supplemental writing instruction to the entire Mount Saint Mary College Community, supporting students, staff, and faculty.
How We Do It:
For students, the primary way to use the Writing Center is by making an appointment for a writing consultation with one of our specially trained Writing Center tutors. Using our online scheduling system, you can book a 50-minute appointment to discuss your writing and your writing assignments. Through these one-on-one consultations, tutors assist writers through any and all phases of the writing process: brainstorming and organizing ideas; structuring sentences, paragraphs, and essays; strengthening argumentation; incorporating research and appropriate systems of citation; improving grammar and style; and more!
As a member of the larger Mount community, the Writing Center also sponsors various writing-related events and programs and works closely with faculty in order to support the teaching and assessment of writing in all the disciplines, thereby working to engender a culture of writing on campus.
Why We Do It:
The Writing Center is committed to the enrichment of Mount students; we are here to equip the members of our community with the writing skills they will need to effectively communicate and succeed in all their future endeavors.
Want More?
If you have any questions about the Writing Center, feel free to get in touch with us using the contact information listed to the left.


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Police are not linking the incidents
David Eggboro, Reporter - Epping Forest / / Epping ForestFollow @E_F_Guardian
A teenager was attacked and had his shoes stolen in the third reported violent incident in Epping in less than two weeks.
Police have today revealed an 18-year-old man was assaulted and robbed in Hartland Road, Epping, at around 3.50am on Saturday, when streetlights in the road were off.
The teenager, who works at the George and Dragon, was attacked by two men, who took his iphone, cash, watch, bank cards and Nike trainers as he was on his way home from a night out.
He was hospitalised after suffering facial injuries in the attack.
Attacks on Nathan Innes Harrero on Jan 15 in Albany Court and a 27-year-old male in Tidys Lane on Monday, at around 11pm, are not being linked to Saturday's incident.
Police have arrested two 15-year-old boys on suspicion of causing grievous bodily harm to Nathan Innes Harrero.
Anyone with information on any events can contact police.
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Police not linking Epping attacks
Epping High Street after midnight is like the wild west. The trouble is centred on the usual suspect bars and one nightclub in particular. They are careful that there is no trouble in the club itself, but the trouble is in surrounding streets. Drug dealing goes on a few roads away from the club, while the hobby bobbies stand around chatting to the bouncers and eyeing up the totty coming and going form the club. Who is getting the brown envelope to let this go on?
There is at least one local Tory bigwig who likes a free sherbert or two in there.
There is at least one local Tory bigwig who likes a free sherbert or two in there.


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Holiday InnRead MoreHoliday Inn has the best amenities around. Enjoy Holiday Inn when you stay in Bradenton. The business center located within this hotel is a great place to finish up some last-minute work. Selecting a room choice has never been easier with the affordable and spacious suite options at this hotel. As an added bonus, this establishment offers complimentary wifi for guests to easily connect to. Keep your workout regime on point at the hotel's complimentary fitness center. Looking to take a dip? Holiday Inn also offers a swimming pool for all guests. Guests at Holiday Inn enjoy a complimentary breakfast each morning during their stay. Affordable accommodations or nice ones? Holiday Inn doesn't make you choose. Skip the hassle of hauling your luggage around and make use of the ample parking nearby.4450 47th St WBradenton, FL US
Frank's Restaurant and CateringRead MoreDressing up the traditional sandwich, Frank's Restaurant and Catering is a go-to lunch spot. The menu at Frank's Restaurant and Catering does not include any low-fat options, so come ready to indulge. Frank's Restaurant and Catering is a prime location to dine with a group. Leave the fancy duds at home — patrons at the restaurant dress informally. The restaurant has catering services as well. Free parking is always available just seconds away from Frank's Restaurant and Catering. Keeping dinner under $20 is no small feat, but it is entirely possible at Frank's Restaurant and Catering. Stop by for three square meals a day — Frank's Restaurant and Catering serves breakfast, lunch, and dinner.2044 43rd Ave WBradenton, FL US
Boston MarketRead MoreHankering for a side of fries? Try the grub at Boston Market, a tasty restaurant serving American-style fare. Searching for gluten-free goodness? Come to Boston Market and taste it for yourself. Boston Market is a local restaurant that accommodates both large and small groups. Catering from Boston Market will take your party to the next level. Carry-out is also available for those who prefer to enjoy Boston Market's cooking from the comfort of their own home. Free parking is available in the adjacent lot. For a night out with great food that won't break the budget, head to Boston Market.5002 Cortez Rd WBradenton, FL US
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Scuba Bill's Aquatic AdventuresRead MoreThe certified instructors at Scuba Bill's Aquatic Adventures guide students through a slew of advanced diving classes as well as specialty courses in spear fishing and rescue diving. They even organize trips to exotic locales, where students can put their skills to use while diving through some of the world's most beautiful underwater scenery.4948 58th Terrace EBradenton, FL US
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Real Life Korean Celebrity Couple 2013
Real life "Producer" couple (Music Bank & 1N2D PD"s) revealed to have gotten married
The June 13 episode of KBS 2TV"s "Entertainment Weekly" featured a real life "Producer" couple! The program revealed the couple got married after spending hours and hours working together, just like the on-air producers in "Producer".. ... Read more
"Surplus Princess" Ohn Ju Wan and Jo Bo Ah confirmed as real life couple
Ohn Ju Wan and Jo Bo Ah have confirmed that they are dating each other in real life.
Ohn Ju Wan"s agency, Will Entertainment released their official statement on March 26th,"We"ve checked with him and it"s confirmed that the two are indeed dating each other. They met each other and became friends through tvN"s "Surplus Princess". They naturally developed into lovers and started dating about a month ago".. ... Read more
Actors are now a couple in real life
Siwan wishes to see a real-life Iron Man in classy pictorial with "The Celebrity"
Siwan sat down as the cover model for the March issue of "The Celebrity" despite being busy with CF shoots and fan meetings since the success of his drama, "Misaeng."
Although this was his very first time posing for the cover of a fashion magazine alone, he never lost focus throughout the long shoot and remained professional, checking every concept thoroughly and touching the staff members with his diligence. . ... Read more
Kim So Eun and Seo Kang Jun look like a sexy real-life couple for 'InStyle'
Kim So Eun and Seo Kang Jun graced the pages of "InStyle" magazine"s June issue, turning heads with their impeccable good looks.
The two could pass off for a real-life couple with their chemistry, further brought to life by their mature and sexy charms added with the help of makeup and outfits. Kim So Eun owns her dark makeup and colorful clothes, whereas Seo Kang Jun shows why he"s one of the trendiest eye candy at the moment with his suave, good looks. . ... Read more
Korean Celebrity Couple: Won Bin and Lee Na Young
This week celebrity couple Won Bin and Lee Na Young were seen at Incheon Airport boarding a flight to New York. Eden 9, the agency that represents them both would not say whether it was work related or a vacation.. ... Read more
Jeon Jihyun from "You Who Came From the Stars" living with the real life Kim Soohyun: Story of the perfect couple with her husband
Jeon Jihyun from "You Who Came From the Stars" living with the real life Kim Soohyun: Story of the perfect couple with her husband
Along with the recent behind-the-scenes story about how Jeon Jihyun initially turned down on starring in current hit K-Drama "You Who Came From the Stars", the story of how she and her husband, Choi Joonhyuk, met have also been receiving much media attention, much as it did back in 2012 when their engagement was first announced. . ... Read more
Seo In Guk Picks Girls' Generation's YoonA as Prettiest Celebrity in Real Life
Seo In Guk recently picked Girls' Generation's YoonA as the female celebrity who is prettiest in real life.
On December 24, Seo In Guk was a guest on the SBS Power FM "Two o'Clock Escape Cultwo Show" and shared many stories. . ... Read more
Choi Won Young and Shim Yi Young Become Real-Life Couple
Love is in the air this Christmas because yet another couple has been born! Actors Choi Won Young and Shim Yi Young, who played a married couple in the drama, "Hundred Year's Inheritance," have announced that they have become a real-life couple. . ... Read more


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Went with three friends for restaurant week, all were impressed with the drinks and local wine/beer offerings. The food was delicious and it was great to see into the kitchen as it was being made. The place was fancy but still approachable, a nice upbeat switch from Cafe Continental that had previously been in the location. Looking forward to eating here again.
If you own or manage 43 North, register now for free tools to enhance your listing, attract new reviews, and respond to reviewers.


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Michael's Motor Cars is pleased to offer this 1966 Lincoln Continental Convertible in charcoal frost with black leather interior and black convertible top. This... More
Professionally Built High Quality Resto-Mod That's Been Driven Just 16361 Miles Since Completion. Originally Custom Built By Rich's Street Rods In Snohomish Washington And Maintained By... More
For sale in our Detroit showroom is this clean green 1951 Lincoln Cosmopolitan. This classic Lincoln is powered its original 337 Cubic Inch flathead... More
1957 Lincoln Premiere 2D Hardtop CoupeThe 1957 Lincoln Premiere is a very elegant classic car from the 50s and is very beloved for its... More
1953 LINCOLN CAPRI "SPECIAL CUSTOM" HARDTOP COUPE. Red with Black and Red interior. Complete and accurate ground-up restoration. 1,847 miles since. $38,500. 1953 LINCOLN CAPRI "SPECIAL CUSTOM"... More
1979 LINCOLN MARK V COLLECTOR SERIES ONLY 18,840 CAREFULLY DRIVEN MILES! RARE LIMITED EDITION COLLECTOR SERIES! 1 OF ONLY 3,900 BUILT! LAST YEAR FOR THIS FULL-SIZE MODEL! FULL DOCUMENTATION,... More
Under 11,000 original miles on this 1 owner well documented Lincoln Continental 2 door hardtop Built February 24th 1977 Sold new... More
Motoexotica is pleased to introduce our newest 1971 Lincoln Mark III. 1971 saw the Golden Anniversary for the Lincoln Mark, and the third and final year... More
1951 Lincoln Lido If you are interested in this vehicle or have any questions, please call Cliff at 707-768-1735. 337 cid flathead, Hydromatic trans. Only 44500 miles. Currently lic and insured. Trade... More
1975 Lincoln Continental Mark IV Lipstick Edition. Only 6,425 Miles! 460ci/210hp/V8, Auto Trans. This gorgeous Mark IV is one of the rare Lipstick Edition... More
1971 LINCOLN CONTINENTAL MARK III COUPE JUST 1-OWNER FROM NEW! ONLY 14,713 ACTUAL MILES! SPECTACULAR CONDITION THROUGHOUT! FULLY DOCUMENTED WITH ITS ORIGINAL OWNER'S MANUALS, SERVICE BOOKS, ORIGINAL BROCHURES... More
1960 Lincoln MK 5 Convertible Ultra Clean Body (car was originally from and is presently located in California) Clear CA Title Most chrome included Most suspension in trunk One... More
1979 Lincoln Continental Mark V Sehr Guter Original zustand / SammlerstuckThis is a elegant luxury coupe of the top classe with a extraordinary powerfull... More
This 1958 - 1960 Lincoln body style is one of my favorites and most eclectic of the tail fin era. I love them and think... More
Call 440-914-0000 or email [contact seller] 1979 Lincoln Continental Description Some cars are made to stand out. Some do it with stripes, or... More


text:
NEW YORK - Detroit Tigers left-hander David Price set a record for the highest one-year contract for a player in salary arbitration, agreeing to a $19.75 million deal Friday as 95 players reached agreements on the busiest day of baseball's offseason.
NEW YORK — Randy Johnson, Pedro Martinez and John Smoltz, a trio of star pitchers who dominated in an era of offense, were elected to baseball's Hall of Fame on Tuesday along with Craig Biggio, the first time since 1955 writers selected four players in one year.
The Big Unit, Martinez and Smoltz...
SAN DIEGO - Less than five months after acquiring Yoenis Cespedes as part of a big deadline deal, the Boston Red Sox traded the slugging outfielder to help bolster their rotation.
The Detroit Tigers were happy to take him.
SAN DIEGO - Baseball's winter meetings ended with an old-style spurt of swaps, with All-Stars switching teams at a rapid pace and executives scrambling to fill roster voids.
SAN DIEGO - Dan Jennings traded Dan Jennings.
On the final day of the winter meetings, the Miami Marlins sent Jennings, a 27-year-old left-handed reliever, to the Chicago White Sox on Thursday for 26-year-old right-hander Andre Rienzo.
SAN DIEGO - Clayton Kershaw is considered the top pitcher in baseball, with three Cy Young Awards in four years for the Los Angeles Dodgers, an NL Most Valuable Player award and a $215 million, seven-year contract.
NEW YORK - Former Savannah Sand Gnats pitcher Jacob deGrom of the New York Mets won the National League Rookie of the Year Award and Chicago White Sox first baseman Jose Abreu was a unanimous winner of the AL award on Monday.
S.F. makes offer to Series star Sandoval
NEW YORK - San Francisco Giants World Series star Pablo Sandoval was among 12 free agents given $15.3 million qualifying offers Monday by their former teams.
KANSAS CITY, Mo. - A 2-foot-tall image of deer in multicolored neon with a bulls-eye on its tail is affixed to a wall in the Kansas City Royals locker room. It hangs between the stalls of Aaron Crow and Tim Collins, and has a "W" underneath a crown.
SAN FRANCISCO — Jeremy Guthrie pitched shutout ball into the sixth inning, Lorenzo Cain drove in an early run off Tim Hudson and made a pair of nifty catches, and the Kansas City Royals beat the San Francisco Giants 3-2 Friday night to take a 2-1 World Series lead.
Cain's RBI groundout three bat...
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San Antonio's historic Missions gain World Heritage recognition
Top Stories in Local
Greece still cash-starved after decisive 'no' bailout vote
Top Stories in US & World
Real Estate
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BILLY CALZADA/San Antonio Express-News
The Buzzard's Roost, seen in October 2006, was a modest, yet popular hotel in Boquillas del Carmen, Mexico, whose clientele consisted of tourists visiting from Big Bend National Park across the Rio Grande in Texas. The hotel has closed, since tourists can no longer come because of the clamping down on unofficial border crossings after the terrorist attacks of Sept. 11, 2001.
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