text:
Search for "golf" Sweepstakes
Found 31 total
Enter for a chance to win a Scotty Cameron Limited Edition Rory McIlroy Putter from GolfHQ.com!
You may not ever own the World Number One ranking, but you now can hold history in your hands with the 2012 Scotty Cameron Inspired by Rory McIlroy Newport SSS. Dream Big! 1 of 989 putters. ~Compliments of Golf Headquarters - GolfHQ.com
Enter to win a $100 Rock Bottom Golf Gift Card!*Join The Rock Bottom Golf Mailing List.
Enter to win The opportunity for you and a guest to meet Rickie Fowler at a 2015 PGA TOUR event. Grand Prize includes two (2) tickets to a 2015 PGA TOUR event (event and days to be determined by Cobra golf and Carl�s Golfland); two economy class round trip airline tickets from the winner�s nearest major airport to the event airport and back; $500 travel stipend.
2nd: Cobra Golf Staff Bag autographed by Rickie Fowler
3rd: Cobra Driver autographed by Rickie Fowler
Win a golf package for two including one night stay in a King Suite at Best Western Inn on the Bay! Travel not provided.
Enter to win SunRidge: One round of golf for 2 people. Fairmont Scottsdale Princess: Two-night stay including room and tax. TPC Scottsdale Champion Course: Twosome of golf.
One (1) Grand Prize Winner will receive a four (4) night trip for two (2) people (the Grand Prize Winner and a travel companion) to Gaylord Golf Mecca in Gaylord, Michigan.The �Grand Prize� consists of: (a) roundtrip coach class airfare for two (2) to Michigan from a major airport near Grand Prize Winner�s address (inclusive of taxes, tariffs and related fees); (b) four (4) nights� hotel accommodations (based on double occupancy, inclusive of taxes); and (c) unlimited golf for two people for five days, including date of arrival and date of departure, subject to available tee times (ARV of Grand Prize: $3,500).
Enter to Win 4 Days of Golf On Your Choice
of Myrtle Beach Area Courses
�4 Nights' Accommodations
�Breakfast and Dinner Each Day
�$100 Golfsmith Gift Card
�Roundtrip Airfare to Myrtle Beach.
Enter to Win A trip for two to Orlando, Florida for the winner and a guest. Trip package includes roundtrip, coach-class air transportation for two from a major airport near the winner�s home in the United States to the Orlando International Airport; three days and two nights hotel accommodations. Winner will receive three hours of complimentary instruction from David Leadbetter at The Leadbetter Golf Academy at the ChampionsGate Golf Resort in Orlando, Florida during their stay. The Grand Prize Winner and a guest will receive one complementary lunch with David Leadbetter. Both the Grand Prize winner and their guest will receive one complimentary round of golf at ChampionsGate Golf Resort in Orlando, Florida during their trip.
There will be one (1) grand prize winner, one (1) first prize winner and ten (10) second prize winners. The grand prize is one (1) set of Callaway Apex irons chosen by Sponsor. The approximate retail value of the grand prize is $1,100. The first prize is one (1) round of golf with a certified teaching professional (subject to availability) at a course in or near the winner�s hometown to be chosen by Sponsor. The approximate retail value of the first prize is $700. Transportation and other expenses not included. First prize must be redeemed by July 22, 2016. The second prize is five (5) pairs of Gold Toe Socks. The approximate retail value of the second prize is $50 each.
5) Five winners will be awarded 3 days, 3 nights, and 3 rounds of golf for winner and 3 guests:
�A Day with Dustin Johnson� which includes the following:
�3 Rounds of Golf for Winner and 3 Guests (a)
�3-Night�s Accommodations (double occupancy) (4 days, 3 nights)
Additional Grand Prize gifts and prizes include:
�$100 TaylorMade gift card for winner and guests
Grand Prize will consist of a trip for Grand Prize Winner and one (1) guest ("Guest") to Ireland.Estimated Retail Value ("ERV") of Grand Prize is twenty-five thousand dollars ($25,000).
There will be fifty (50) first prizes ("First Prizes", each a "First Prize") given in the Instant Win Games. Each First Prize consists of a fifty US dollar ($50) Srixon/Cleveland Golf credit in a promotional code ("Promotional Code"). Actual retail value ("ARV") of each First Prize is $50 USD. There will be fifty (50) second prizes ("Second Prizes", each a "Second Prize"). Each Second Prize consists of a forty US dollar ($40) Srixon/Cleveland Golf Promotional Code. ARV of each Second Prize is: $40 USD.
Enter to win A 3-day/2-night trip for winner and 3 guests to TPC Sawgrass in Ponte Vedra Beach, Florida. Trip includes a 2-night hotel accommodation at the Sawgrass Marriott Golf Resort and Spa (2 rooms, based on double occupancy) (room rate and related taxes only), round trip domestic coach air transportation for four (4) from major airport nearest winner�s home, one (1) round of golf for the winner and his/her guests on Dye�s Valley Golf Course at TPC Sawgrass, a MasterCard PGA TOUR Player experience at TPC Sawgrass Stadium Course for the winner and his/her guests, a 90-minute group golf lesson for the winner and his/her guests at TOURAcademy TPC Sawgrass and a $1,000 MasterCard gift card for the winner (gift card restrictions may apply). The ARV of the Grand Prize is $10,200. Entry Period Prizes (6 total, 1 per Entry Period): A Bushnell Pro X7 JOLT Range Finder and signed pin (ARV: $549.99)
Enter for a chance to win a Nike Vapor Speed Driver!
Enter to win a Solus 420 CS 3-Wedge Set.
The Winners will receive one of the following prizes: one (1) Pawleys Island Hammocks (with an
approximate retail value of two hundred dollars ($200)); one (1) Visit Myrtle Beach Beach Kit (which
includes a bag, beach towel, sunglasses, hat and various promotional items from Ripley�s Aquarium,
Myrtle Beach) (with a total approximate retail value of two hundred dollars ($200)); one (1) art sculpture
and one (1) book from Brookgreen Gardens (with a total approximate retail value of two hundred dollars
($200)); one (1) locally sourced, handmade sweet grass basket and one (1) Gullah Geechee cookbook
(with a total approximate retail value of two hundred ($200)); and one (1) Grand Prize consisting of
airfare for two (2) to Myrtle Beach, five (5) nights� accommodation at a top Myrtle Beach resort location,
one (1) five hundred dollar ($500) Visa or American Express gift card, two (2) tickets to Myrtle Beach
attractions, shopping gift cards from local retailers, one (1) free round of golf and equipment rental for
two (2), and one (1) merchandise package (which includes a Myrtle Beach cooler and beach towel) (with
a total approximate retail value of four thousand dollars ($4,000))
Enter to win a trip for winner and one (1) guest to Fredericksburg, TX. The Grand Prize trip includes:
�Roundtrip coach airfare for winner and guest from a major airport nearest winner�s residence as determined by the Sponsor to the Austin�Bergstrom International Airport or San Antonio International Airport;
�Three (3) nights hotel accommodations at the Sunday Haus Cottages at the Fredericksburg Herb Farm (one (1) standard room, double occupancy room, tax and gratuities included);
�Two (2) tickets for a Cellar Tour at Grape Creek Vineyards;
�Two (2) passes to Rockbox Theater;
�Two (2) passes to the National Museum of the Pacific War;
�Two (2) passes to the Enchanted Rock State Natural Area;
�One (1) $50 gift certificate to Otto�s German Bistro;
�One (1) round of golf for two (2) people at the Lady Bird Johnson Golf Course;
�One (1) $40 gift certificate to the Peach Tree Tea Room;
�One (1) $200 gift certificate to the Nature�s Spa
Trip must be booked at least three (3) weeks in advance and taken within one (1) year from prize award date.
Total ARV of Grand Prize: $5,000.00.
Grand Prize {1} ; a trip for (2) to Toronto, Canada consisting of the following (the �Grand Prize�): (i) round-trip coach class airfare for Grand Prize Winner and one (1) guest to Toronto, Canada from the major U.S. airport nearest Grand Prize Winner�s residence within the 48 contiguous U.S., and a return flight from Toronto, Canada; (ii) (7) days/(6) nights first class hotel accommodations (one double occupancy room); (iii) choice of either a bird�s eye view of Niagara Falls via helicopter or Hornblower Niagara Falls cruise; (iv) choice of either a 6-hour private tour of the wineries situated on Lake Ontario or one (1) round of golf at a nearby course; (v) choice of either (2) tickets to Marineland or a walking history and food tour; (vi) choice of either (2) Clifton Hill Fun Passes to enjoy the Skywheel or (2) tickets to Bird Kingdom; (vii) choice of either a four-hour fully guided tour of the Canadian side of the Niagara Falls or horseback riding along Lake Erie; (viii) choice of either dinner for (2) at Skylon Tower or the Domed Jet Boat ride; (ix) choice of either (2) tickets to Fallsview Indoor Water Park or Niagara Falls Illumination Cruise; (xii) $1,500 spending money; (x) round-trip airport transfers to/from hotel; and (xi) all taxes related to accommodations and airfare. ARV: $10,000. 1st Prizes (31) : Set of (4) pre-matted photos of Niagara Falls. ARV: $60. *ENDS 5pm EST
Enter to win A total of twenty five (25) prizes, with five (5) prizes being awarded per week. Each prize shall consist of one (1) ProDry Performance Golf Shirt (selected by the winner upon entry, subject to availability). The Approximate Retail Value (�ARV�) of the ProDry Performance Golf Shirt is seventy-five dollars ($75.00). B: Total ARV: Total ARV of all prizes is one thousand, eight hundred and seventy five dollars ($1,875.00)
Enter to win Two passes to the National Museum of the Pacific War; Two passes to the Pioneer Museum; Two passes for a wine and cellar tour at Grape Creek Vineyard; Round of golf for two, with cart fees, at the Lady Bird Johnson Golf Course; $75 gift certificate to the Cabernet Grill Texas Wine Country Restaurant; Two nights deluxe-guesthouse accommodations for two in the Cork & Barrel Cottage at the Wine Country Cottages on Main.
Enter to win either: Nampa Package: Three-night stay in a two-bedroom unit for 4 people from Wyndham Vacation Rentals Sun Valley; Two-night stay at the Fairfield Inn & Suites in Nampa, Idaho; Family pass to the Warhawk Air Museum; Wine tasting for four at Huston Vineyards; Tickets for four to the Snake River Stampede 100th Anniversary Rodeo; Full-day North Fork Cabarton whitewater rafting trip including lunch OR full-day South Fork Canyon whitewater rafting trip including lunch. OR Bear Lake West Package: Two-night stay at the Clover Creek Inn; Four golf passes w/cart to the Montpelier Golf Course; Four golf passes w/cart to the Bear Lake West Golf Course; Four tour passes to the National Oregon/California Trail Center.

subset: commoncrawl


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- Eyewash Replacement Dust Caps, PREyewash Replacement Dust Caps,PR
- Item # 9HW89
- Mfr. Model # GREEN CAPS/DUST CVR
Replacement Cap/Dust Cover, For Use With Faucet-Mount Eye and Eye/Face Wash Stations, 1 Pair
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- Cap/Dust Cover, For Eye/Fcwah, PRCap/Dust Cover,For Eye/Fcwah,PR
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- Diverter Vlv and O-Ring, Eye/FacewashDiverter Vlv and O-Ring,Eye/Facewash
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text:
but it seems to me that toward the end of Osborne's career he started to "Switzer it up" a little. That Fiesta Bowl team bathed in steriods and I think we all remember Frosty the Snow Job. All that said, I couldn't agree more about the board's opinion about how Neb's fans and team conducted themselves.
in town for free camps


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Go, Dog. Go! An I Can Read It All By Myself Beginner Book
- Occasion▼▲
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Product Description
Beginner Books blends words and pictures to encourage children to read all by themselves. Hailed by elementary educators and remedial reading specialists, these enormously popular books are now used in schools and libraries throughout the English-speaking world.
Product Information
|Format: Hardcover
Vendor: Random House
Publication Date: 1961
Dimensions: 6 3/4 X 9 1/4 (inches)
Availability: In Stock
Ages: 5-8
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Publisher's Description
Reading goes to the dogs in this timeless Beginner Book edited by Dr. Seuss. From big dogs and little dogs to red, green, and blue dogs, dogs going up and dogs going fast . . . who knew dogs were so busy? And laughter will ensue at the repeated question "Do you like my hat?" Like P. D. Eastmans classic Are You My Mother? Go, Dog. Go! has been a go-to favorite for over fifty years, leaving audiences of all breeds wagging their tails with delight.
Originally created by Dr. Seuss, Beginner Books encourage children to read all by themselves, with simple words and illustrations that give clues to their meaning.
"The canine cartoons make an elementary text funny and coherent and still one of the best around."--School Library Journal.
Author Bio
A protege of Dr. Seuss, P. D. EASTMAN wrote and/or illustrated many books for children, among them the Beginner Books Go, Dog. Go!, The Best Nest, Sam and the Firefly, A Fish Out of Water, Robert the Rose Horse, Big Dog...Little Dog, and Are You My Mother?
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Campaign Updates
Councilor Jackson seeks to increase safety and opportunityJune 4, 2015News Clip
Boston, MA - In the wake of multiple tragedies that have recently afflicted many of Boston's neighborhoods, Councilor Tito Jackson today filed legislation aimed at reducing gun violence, and promoting safety and opportunities throughout the city.
"Our community is at a crossroad. We have a choice to make meaningful change, and uplift our community, or face staying on the current course," said Councilor Jackson.Read more
Campaign Kick-Off!May 15, 2015Blog Post
Boston City Councilor Tito Jackson will formally kick off his re-election campaign for District 7 Boston City Councilor on Monday, May 18th at 6:00pm. Joined by friends, family, and supporters, Tito will share his vision for the District 7 community he represents in City Hall.
We hope you join us for a night of music, dance, food, and fun, and most importantly a milestone in Councilor Jackson's career that marks his continued commitment to serving his district.
Click here to RSVP for the event.
Read more
Tito Jackson fights to keep Stop and Shop door openMay 15, 2015News Clip
On May 4, 2015 City Councilor Tito Jackson hand-delivered a letter to the manager of the Grove Hall Stop & Shop, asking him to "immediately" open one of two pairs of doors to the Roxbury store. For more on this story, check out the recent report by Fox 25 news.Read more


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You can now invite anyone to meet at your favorite Starbucks.
Limited-time feature
34 year old man | Miami Lakes, FL, USA | Seeking women 24-37 within 50 miles of Miami, FL
Active within 3 days
There is a light at the end of the tunnel. Let's go see it together.
I am really enjoying my life, but I know there's still more I could be doing if someone else was in the picture. I've always been big on companionship, and I consider myself to be a family man and bit of a social butterfly. Some of the best moments of my life were the ones I was sharing with amazing people, so social events, and opportunities to meet new people are always at the top of my to-do list. I love to relax of course; I'd just be more inclined to embrace that with someone to come home to. I'm really big on sharing with my partner, from our interests to our families. Because I care so much for others, I make a point to bring good vibes with me wherever I go, and no other baggage! I'm a pretty respectful guy, but I still believe in being honest even when it's not easy. I live with passion and I'm serious about it, but my sense of humor shows through more often than not. If life has taught me anything, it's that being a good person and staying true to your word is worth it to everyone! My match is a strong woman and she's proven it by creating an amazing life that she can feel comfortable in financially and otherwise. She's incredibly witty, with a little bit of a nerdy side and plenty of great quirks. Those close to her find her both hilarious and inspiring because she is so unique (sarcasm included!). I want to meet someone who respects herself, though she still puts family first and focuses on being a good person on their behalf. As a partner, there couldn't be a more loving and affectionate woman to have at my side.
Alumni connections , Coffee and conversation , Business networking , Cooking , Dining out , Hobbies and crafts , Movies/Videos , Museums and art , Music and concerts , Exploring new areas , Nightclubs/Dancing , Playing cards , Shopping/Antiques , Travel/Sightseeing , Video games , Watching sports , Wine tasting
Auto racing / Motorcross, Billiards / Pool, Bowling, Hockey, Martial arts, Other types of exercise, Running, Swimming, Walking / Hiking, Weights / Machines
I exercise 1-2 times per week.
I like Birds, Dogs, Exotic Pets, Fish, Reptiles
My favorite animal would be to have a dog, like a lab or golden retriever. My second option would have to be a love bird, cause I had one when I was a child.
I have been to the Caribbean, Rome and Spain. When I dine out I like to eat pizza, sushi and burgers. I like Burger and Beer, and Rok Burger.
Florida Career College, Miami, FL
I love food, family, friends, my phone, internet, water, Linkin Park, Maroon 5, Action, Drama, Comedy, Wedding Crashers, dragons, swords, technology, beach boardwalks, balcony breezes, animals and coffee.
I enjoy seeing friends, movies, pub-crawls, travel, wine/beer tasting, video games, dining out, family time, running, cruises, cooking, museums, concerts, dance, card games, shopping, auto racing, Billiards, bowling, martial arts and more.
Z{{Cta}} {{#if HasMoreInfo}} ?{{CtaSecondary}} {{/if}}
|What he is looking for
|6'0" (182cms)
|4'11" (149cms) to 6'0" (182cms)
|Body type:
|Slender, About average, Curvy, Athletic and toned
|Black, Blue, Brown, Grey, Green, Hazel
|Auburn / Red, Black, Light brown, Dark brown, Blonde, Salt and pepper, Silver, Dark blonde, Grey, Platinum
|No Way
|No Way
|Social Drinker
|Never, Social Drinker, Regularly, Moderately
|Technical / Science / Computers / Engineering
|Administrative / Secretarial, Artistic / Creative / Performance, Executive / Management, Financial / Accounting / Real Estate, Labor / Construction, Legal, Medical / Dental / Veterinary / Fitness, Political / Govt / Civil Service / Military, Retail / Food services, Retired, Sales / Marketing, Self-Employed / Entrepreneur, Student, Education / Teacher / Professor, Technical / Science / Computers / Engineering, Travel / Hospitality / Transportation, Other profession, Nonprofit / Volunteer / Activist, Law enforcement / Security / Military, Fashion / Model / Beauty, Architecture / Interior design
|Less Than $25,000, $25,001 to $35,000, $35,001 to $50,000, $50,001 to $75,000, $75,001 to $100,000, $100,001 to $150,000, $150,001+
|Never Married, Widow / Widower, Currently Separated, Divorced
|Have kids:
|Yes, and they sometimes live at home, No, Yes, and they live at home
|Wants kids:
|Definitely, Someday
|Latino / Hispanic, White / Caucasian
|Asian, East Indian, Latino / Hispanic, Middle Eastern, Native American, White / Caucasian
Both of my parents were born in Cuba. I come from a Latin background with an American lifestyle.. That's one way of putting it.
|Christian / Catholic
|Agnostic, Atheist, Buddhist / Taoist, Christian / Catholic, Christian / LDS, Christian / Protestant, Spiritual but not religious, Other, Christian / Other
I went to catholic school and I grew up with this religion. I do believe in a higher power, but I do not practice this faith at the moment.
|English, Spanish
|English, Spanish
|Associates degree
|High school, Some college, Associates degree, Bachelors degree, Graduate degree, PhD / Post Doctoral
I have two Associate's degree in Computer Science from ITT Tech and Florida Career College.


text:
Scott came in for a massage and encountered the beautiful and busty, Sharron Lee. She began by giving him an awesome massage. Then, she asked if it was ok to massage his cock for an extra tip or possibly even more. Scott chose to get the full package. She undressed and revealed her juicy tits. She began stroking and sucking his cock. She hopped on top and rode that cock as her jugs bounced around. She finished him off with a sweet hand job as his man juice went everywhere.
"Rubs N Tugs"
"Naughty Nikko"
Nikko Jordan
"Rub And Tug"
London Keys
"Release And Repeat"
Lily Lust
"Cha Cha Chase"
Vicki Chase
"Secret Rub Down"
Mey Li
"So Magically"
Alina Li
"Massage This"
"All Hands"
Kim Kong
"Tug Team"
Asia Zo


text:
The tangle of groups, funders, and leaders in the black anti-immigration effort—as in the broader movement—can be hard to follow.
Dressed in shades of green from lime to olive, she had a tangle of glittery chains around her neck.
The tangle of enormous fake diamonds resting on top of her cleavage sparkles at every flashbulb.
mid-14c., nasalized variant of tagilen "to involve in a difficult situation, entangle," from a Scandinavian source (cf. dialectal Swedish taggla "to disorder," Old Norse þongull "seaweed"). In reference to material things, from c.1500. Meaning "to fight with" is American English, first recorded 1928. Related: Tangled; tangling. Tanglefoot (1859) was Western American English slang for "strong whiskey."
1610s, "a tangled condition," from tangle (v.).
Related Terms


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IEEE membership options for an individual and IEEE Xplore subscriptions for an organization offer the most affordable access to essential journal articles, conference papers, standards,
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SAR interferograms are affected by a strong noise component which often prevents correct phase unwrapping and always impairs the phase reconstruction accuracy. To obtain satisfactory performance, most filtering techniques exploit prior information by means of ad hoc, empirical strategies. In this paper, we recast phase filtering as a Bayesian estimation problem in which the image prior is modeled as a suitable Markov random field, and the filtered phase field is the configuration with maximum a posteriori probability. Assuming the image to be residue free and generally smooth, a two-component MRF model is adopted, where the first component penalizes residues, while the second one penalizes discontinuities. Constrained simulated annealing is then used to find the optimal solution. The experimental analysis shows that, by gradually adjusting the MRF parameters, the algorithm filters out most of the high-frequency noise and, in the limit, eliminates all residues, allowing for a trivial phase unwrapping. Given a limited processing time, the algorithm is still able to eliminate most residues, paving the way for the successful use of any subsequent phase unwrapping technique.
A not-for-profit organization, IEEE is the world's largest professional association for the advancement of technology.© Copyright 2015 IEEE - All rights reserved. Use of this web site signifies your agreement to the terms and conditions.


text:
iSeeBoard OneServer
iSeeBoard is a sophisticated yet easy to use SaaS/Cloud based digital signage platform, perfect to build small or large digital signage...
iSeeBoard is a sophisticated yet easy to use SaaS/Cloud based digital signage platform, perfect to build small or large digital signage...
New study predicts cloud-based development will be a team effort involving both business and IT. 'Developer visionaries' will lead the way, though.
This week, startup Snowflake Computing GA'd its cloud data warehouse and Microsoft took its Azure SQL Data Warehouse service to public preview. Amazon Redshift isn't the only player anymore.
Most IT pros are unprepared for a compliance audit, survey shows. Is cloud to blame, at least partially?
The companies plan to work together to advance cloud computing across the enterprise, security industry and mobile.
The cloud computing firm wants to play a key role in the strategy of cash-strapped customers and increase its influence locally.
Set up your printer to print from your iPad. PrintDirect will print to ALL printers. Print directly to most WiFi/Wireless printers...
Software, platforms, infrastructure, and storage are all being relegated to cloud services as hybrid takes over. Here's how networking is becoming a service commodity along with them.
IBM is to offer Apache Spark as a service through its Bluemix cloud platform and will deploy thousands of developers to work on the distributed computing framework for big data analytics.
Set up your printer to print from your iPad. PrintDirect will print to ALL printers. Print directly to most WiFi/Wireless printers...
Jane Aboyoun, CTO of the New York Public Library, talks about how she approaches cloud computing, digitizing and storing content and the future of the institution.
The alliance aims to help Alibaba expand into financial information services by taking advantage of the Chinese e-commerce giant's rich resources in customer data and cloud computing technology.
Piston gives Cisco more muscle around distributed systems and automated deployment, in addition to adding another level of infrastructure to the Cisco OpenStack private cloud.
The chip maker says Big Data is driving demand for high-power processors.
Long known for an expansive set of straightforward yet highly capable Web services backed by a long-term strategic vision, Amazon had a head start from the beginning. But it dominates today for other more subtle reasons that IT leaders must consider.
Cloud computing likes fast hardware so Intel has partnered with eASIC to provided specialized silicon for cloud-sized jobs.
NASA outlined its technical roadmaps designed to support missions over the next two decades. There are many cloud, supercomputing, autonomous computing, robotics, and big data points to ponder.
ZTE has attributed its focus on delivering cloud computing, big data, and smart city solutions as drivers of its net profit increase to 883 million yuan for the first quarter.
At Box's second annual developer day, the cloud wunderkind kicks off the event with one of tech's stalwart executives.
Industry cloud is an up-and-coming element within cloud computing. A Tech Pro Research survey shows that only 20 percent have ruled out using industry cloud within their organization.
Cloud computing has come of age, and we're entering a new period of activity; one that isn't necessarily public. Drew Turney deconstructs the movement's new groove.
Britain's GCHQ has built its own Pi cloud consisting of 66 Raspberry Pi Model Bs to teach its engineers about 'scale out' computing.
Alibaba is expanding its cloud computing services in the US, and the firm's first expansion overseas will be to Silicon Valley.
Enterprise Software
Perfectly legal ways you can still get Windows 7 cheap (or even free)
How much does an iPhone 6 really cost? (Hint: It's way more than $199)
Windows 10
How to survive an iPhone liquid submersion (hint: it's not rice)


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Hooked On A Feeling
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Hooked On A FeelingHooked On A Feeling (1984) - Snorks Cartoon Episode Guide by Dave Koch
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- Snorks Cartoon Episode Guide
- Hanna-Barbera Studios
- Cartoon Characters: Allstar, Casey, Tooter, Occy, Daffney, Dimmy, Mrs. Kelp, Junior, Governor Wetworth, Mrs. Wetworth, Mr. Seaworthy, Auntie Marina, Mrs. Seaworthy, Baby Smallstar, Mr. Kelp, Willie.
- Originally Released in 1984.
- Season: 1
- Color
- Running Time: 12 minutes.
Cartoon Summary:
Deep down below in the sea is a mystical underwater world of Snorkland. There lives a whole community of tiny sea dwellers called the Snorks. They are a very small & adorable snorkel headed creatures whose get involved in many adventures. The show center around a high school student named Allstar & his girlfriend Casey.
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Three brothers shot near Memphis restaurant
Three brothers told police they were shot en route to a restaurant in Whitehaven early Sunday morning.
When Police spoke to the men at Methodist South Hospital about 4:40 a.m., each said they were on their way to the IHOP near Elvis Presley and E. Shelby Drive when they were shot at by a man they couldn't identify.
Shortly before officers responded to the aggravated assault call at Methodist South, a report of shots fired drew law enforcement to the restaurant at 1277 E. Shelby.
There were no victims at the scene, according to a Memphis police spokeswoman, but officers did find a Ford F150 riddled with bullet holes and surrounded by shell casings.
The truck had been reported stolen, according to MPD, but investigators were still trying to determine what happened.
All three men were in noncritical condition Sunday.
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March 17, 2013
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The invention features porous substrates or supports fabricated from titania powder(s) having mean particle size of at least 7 μm. The titania substrates are useful for supporting porous membranes for separation and filtration processes. The titania powders provide supports with mean pore sizes in the approximate range of 3 to 15 μm, a sharp or narrow pore size distribution, total Hg porosities of at least about 30%, and MOR strengths of 50 up to 280 or more Kg/cm2. A combination of several different titania powders produced the best results. Titania membranes can be formed on the titania supports.
1. A porous titania substrate for use as a support for a membrane in separations and filtrations, formed of sintered titanium dioxide particles having a mean titanium dioxide particle size of at least 7 micrometers, and said substrate having a mean pore size of approximately between 3 to 15 micrometers, a sharp pore size distribution no greater than 10 micrometers and a total greater than approximately 30% by volume, all as determined by Hg porosimetry.
2. The titania substrate of claim 1, wherein the substrate has a Modulus of Rupture (MOR) of at least 50 Kg/cm2.
3. The titania substrate of claim 2, wherein the total porosity is at least approximately 40%.
4. The titania substrate of claim 2, wherein the MOR is at least approximately 140 Kg/cm2.
5. The titania substrate of claim 2, wherein the MOR is at least approximately 210 Kg/cm2.
6. The titania substrate of claim 1, wherein the substrate mean pore size is approximately between 5 and 10 micrometers.
7. The titania substrate of claim 1, having a honeycomb configuration.
8. The titania substrate of claim 7, wherein a transverse cross-section of said honeycomb configuration has at least 7.75 cells per square centimeter.
9. The titania substrate of claim 7 wherein the wall thickness of the honeycomb support is at least 0.254 mm.
10. The titania substrate of claim 9 wherein the wall thickness of the honeycomb support is in the range between 0.38 and 1.02 mm.
11. The titania substrate of claim 1, wherein said substrate comprises more than one titania powder in admixture.
12. The titania substrate of claim 11, wherein said admixture comprises at least two titanium dioxide powders of different mean particle size, and a mean particle size of said admixed powders of at least 7 micrometers.
13. The titania substrate of claim 1, wherein sintering is accomplished at temperatures in the approximate range of from 1,100� to 1,460� C., for a time sufficient to develop said mean pore size and total porosity.
14. The titania substrate of claim 13, wherein the total porosity is at least approximately 40%.
15. The titania substrate of claim 13, wherein the Modulus of Rupture is at least approximately 210 Kg/cm2.
16. The titania substrate of claim 13, wherein the Modulus of Rupture is at least approximately 280 Kg/cm2.
17. The titania substrate of claim 13, wherein the mean pore size of the substrate is approximately between 5 and 10 micrometers.
18. The titania substrate of claim 13, having a honey-comb configuration.
19. The titania substrate of claim 18, wherein a transverse cross-section of said honeycomb configuration has at least approximately 7.75 cells per square centimeter.
20. The titania substrate of claim 1, wherein said substrate is sintered at temperature in the approximate range of from 1,100� to 1,460� C., for a time sufficient to develop said mean pore size and porosity.
21. The titania substrate of claim 1, having a mean pore size of approximately between 5 and 10 micrometers, a total porosity of greater than approximately 40%, and a Modulus of Rupture,(MOR) of at least 140 Kg/cm2.
22. The titania substrate of claim 1, having a mean pore size of approximately between 5 and 10 micrometers, a total Hg porosity of greater than approximately 40%, and a Modulus of Rupture (MOR) of at least 210 Kg/cm2.
23. The titania substrate of claim 1, said substrate having a finely porous titania separations membrane formed thereon.
24. The titania substrate of claim 23, wherein said membrane has pore sizes that reject solute or suspended particles or molecules, which are to be separated or filtered, of at least 100 micrometers.
25. The titania substrate of claim 23, wherein said membrane is formed of multiple layers of fine titania powders of successively smaller particle sizes.
26. The titania substrate of claim 25, wherein the total thickness of the multiple layers of fine titania powders is in the range between 3 and 50 micrometers.
27. The titania substrate of claim 26, wherein the total thickness of the multiple layers of fine titania powders is in the range between 3 and 20 micrometers.
28. The titania substrate of claim 23, wherein said membrane is formed of a single layer of fine titania powders, the membrane having a thickness of about 1 to 10 micrometers.
29. The titania substrate of claim 1, wherein the sharp pore size distribution is in the approximate range of between 1 and 4 micrometers.
The invention pertains to porous titania substrates or supports for use in separating and filtering, and more particularly to membrane supports fabricated from sintered titania particles whose mean particle size is at least 7 micrometers.
The use of alumina for substrates used in separation and filtration is well known, and is one of the most commonly used inorganic materials for this purpose.
While it has often been suggested that titanium dioxide can also be used for fabricating substrates and membranes for separating and filtering purposes, it has not been generally possible or desirable to do so until the present invention.
One of the major problems with titania materials is their small particle sizes. Most commercial titania powders are used in the paint industry as pigments. These powders rarely have mean particle sizes greater than 3 micrometers.
Such small particle sizes are not suitable for making membrane supports for use in gas separations and microfiltration or ultrafiltration. Powders having small particle sizes generally produce substrates with small mean pore sizes, thus substantially reducing the flux through the porous body of the support.
Titania materials are more expensive than alumina materials, and would not provide a cost effective substitute were it not for the fact that membranes of titanium dioxide have a greater throughput during aqueous separations. (See A. Larbot, J-P. Fabre, C. Guizard, L. Cot and J. Gillot, "New Inorganic Ultrafiltration Membranes: Titania and Zirconia Membranes" J. of Am. Ceramic Soc., 72[2], 257-61, 1989.) Also, titania membranes and membrane. supports that can be properly fabricated are generally more durable for use with acidic and basic solutions, and particularly for basic solutions.
More recently, attention has been focused on the dangers of utilizing alumina substrates for processing water, foodstuffs and other comestibles, although it has not been conclusively determined that aluminum or alumina leaching into such ingestible commodities is harmful.
This fact, in addition to the other aforementioned advantages, has spurred increased interest in fabricating substrates and membranes from titanium dioxide materials.
The invention has been able to obtain titania powders of desirable particle size and distribution, and process them into efficacious substrates.
The invention also reflects the discovery that certain unacceptable powders when combined in admixture with other acceptable titania powders provide a synergistic extrudate having properties greater than either powder standing alone.
The invention also addresses a method of how to mix, shape or form, and sinter these powders to provide substrates useful for supports for microfilter, ultrafilter or gas separation membranes.
In U.S. Pat. No. 4,060,488, issued to Hoover et al, for "Particulate Membrane Ultrafiltration Device", it is suggested that membrane supports and membranes can be fabricated from a wide variety of substances, including titania.
However, the aforesaid patent never teaches by way of example how such a membrane support and membrane could be constructed, nor does this patent teach how a membrane support can be fabricated with a particle size that provides pore sizing in the substrate that yields high fluid throughput as described herein.
In fact, the patent is devoid of any teaching of how the materials are formed and/or sintered to form a membrane or membrane support. Without this teaching, therefore, it is only conjecture whether an acceptable membrane or membrane support could be fabricated from materials other than alumina.
In U.S. Pat. No. 4,781,831 issued to Goldsmith for "Cross-Flow Filtration Device With Filtrate Flow Conduits And Method Of Forming Same", porous material including titania, defining a number of passageways, is used to form a substrate that is to pass retentate from the filtration device.
In the printed Japanese patent application no. 172764-1979, publication no. 95342-1981, for "Manufacturing Method of Honeycomb Shape Body for Catalyst Applications", issued to Matsushita et al, a process for fabricating catalyst substrates made from titania of uncertain particle size is disclosed.
This Japanese application differs from the present invention in several respects, including a different intended use for the fabricated substrates, and a teaching that such substrates should not be sintered or otherwise subjected to high temperature curing in excess of 800� C. This different processing is necessary to provide Matsushita et al with the preferred pore sizes and characteristics for their particular intended use, which is opposite in character to that of this invention.
In the International Application No. PCT/US88/02537, filed Jul. 26, 1988, International Publication No. WO 89/00983, published Feb. 9, 1989, entitled "Preparation of Titanium Ceramic Membranes", a procedure is disclosed for making a sol-gel containing continuous chains of titanium dioxide having polymeric oxygen bridging. This gel is used to form membranes which can be coated upon ceramic or glass supports or can be made to be self-supporting. The process for fabricating the gel requires the use of precursors of alkoxides for causing the formation of titanium hydroxide which precipitates rapidly from the solution. The sol-gels so formed can be fired at temperatures up to 500� C., without causing the gel to crack.
The present invention is distinguished from the aforementioned patent application, in that titania powder is used to form substrates to support membranes according to the present invention, which substrates are not disclosed or suggested by the reference, and in that the mean particle size of the titanium dioxide for the substrate of the current invention is at least 7 micrometers, which is way beyond the colloidal range of titania for membranes as contemplated by the reference. In addition, the present invention contemplates firing the titanium particles at temperatures exceeding 1,200� C.
The present invention features porous substrates or supports comprising essentially titania (titanium dioxide), that are useful in gas separations, microfiltration and ultrafiltration processes, and which provide greater flux or throughput of fluid passing through the porous mass of the substrates due, in significant part, to the mean pore size of the substrates being larger than has been possible with most commercially available titania powders for fabricating substrates.
The fabricated membrane support is formed of sintered titania particles having a mean particle size of at least 7 micrometers so as to yield, in the substrate, a mean pore size of approximately between 3 to 15 micrometers, preferably between about 5 and 10 micrometers, and a sharp or narrow pore size distribution.
The term "sharp or narrow pore size distribution" shall mean for the purposes of definition herein, the pore size difference between 10% and 90% of total Hg intrusion volume being no greater than 10 micrometers, and is preferably (and more commonly) between approximately 1 to 4 micrometers.
The total Hg porosity must be at least 30%, and more preferably equal to or greater than 40%.
The aforesaid pore sizing and Hg porosity contribute to the greater flux or throughput capability of the supports according to this invention.
In an advantageous embodiment of the invention, the Modulus of Rupture (MOR) strength of the support at room temperature should be least 50 or 140 Kg/cm2, and should preferably be greater than 210 or 280 Kg/cm2.
When the above definition was applied to 51 samples considered in accordance with this invention (including those made with single and mixed titania powders), the average difference was determined to be about 2.2 micrometers. For samples made with only mixed titania powders, the average difference was 3.0 micrometers.
"A titania substrate is shaped or formed and sintered at temperatures in the approximate range of from 1,100� to 1,460� Centigrade for a time (e.g. 1 to 8 hours--desirably 2 to 6 hours, but preferably 3 to 5 hours) sufficient to produce the aforesaid properties of mean pore size and porosity, and also MOR."
It is an object of this invention to provide an improved substrate to support a membrane for performing gas separations, microfiltrations and ultrafiltrations.
It is another object of the invention to fabricate titania substrates having physical and chemical characteristics of exceptional quality.
It is another object of this invention to provide new and useful titania substrates or supports having a honeycomb or multi-channel configuration with relatively thin porous walls.
The range of particularly useful transverse cross sectional cell densities of honeycomb supports is believed to be as low as 7.75 cells/cm2 and as high as about 250 cells/cm2. Probably the more practical range of cell densities is from 15.5 cells/cm2 to about 125 cells/cm2. Although useful substrates with membranes on them have been made having 15.5-31 cells/cm2, membranes can be easily formed on higher cell density (e.g. 93 cells/cm2) substrates by use of low viscosity slips and sols.
"Thickness of walls of honeycomb supports should be sufficient for adequate strength and for flow/flux, e.g. at least about 0.254 mm and preferably about 0.38-1.02 mm."
It is yet another object of the invention to blend different titania powders into an extrudate having synergistically better qualities than does any titania powder standing alone, so that a blended powder substrate with a mean pore size between that of powders taken alone can be obtained without substantially increasing the pore size distribution.
It is yet another object of this invention to provide the new titania substrate combined with a finely porous titania membrane supported thereupon, for gas separation, microfiltration, and ultrafiltration processes.
Such membrane generally has pore sizes that reject solute or suspended particles or molecules (to be separated from fluids passing therethrough) of at least about 100 micrometers. The membrane is advantageously formed of multiple layers of fine titania powders and it generally has a thickness of about 3-50 micrometers.
These and other objects of the invention will be better understood and will become more apparent with reference to the subsequent detailed description considered in conjunction with the accompanying drawings, in which:
FIG. 1 is a perspective view of a typical membrane support of this invention; and
FIG. 2 is a cross-sectional view of a portion of the membrane support shown in FIG. 1, taken along lines A--A.
Generally speaking, the invention features substrates comprising titania powder(s), utilized in gas separation, microfiltration and ultrafiltration processes.
Titania membranes on alpha alumina supports have been found to provide greater throughput or flux than occurs with gamma alumina membranes on alpha alumina supports (see A. Larbot et al, hereinabove cited). It is advantageous to create a titania membrane support in order to form membrane filters or separation devices that are entirely constructed from titania. These support and membrane systems would also have a significantly increased durability in acidic and basic media than corresponding alumina systems, and may therefore have a longer operative life.
The invention reflects the discovery that, although it is often difficult to fabricate a membrane substrate with all the preferred or necessary parameters for commercial application utilizing titania powders, the properties can be synergistically enhanced by admixing several powders together. The resulting combination of powders can provide a substrate of higher parameters than that achieved by use of a single powder alone.
For the purposes of clarity, all similar elements will have the same designation throughout the figures.
Now referring to FIG. 1, a typical membrane support 10 of this invention in honeycomb configuration or shape is illustrated in perspective view.
Both surfaces of interior walls 20 and the interior surface of outer wall or skin 20a of the membrane support 10 are coated with titanium dioxide layers or membranes 22 of pore sizes that reject (do not pass) solute or suspended particles or molecules of about at least 100 micrometers as is conventional. Pore size range for microfiltration is generally from 100 micrometers to 200 angstroms. Pore size range for ultrafiltration is generally from 200 angstroms to 10 angstroms. Pore size range for gas separations is generally from 10 angstroms to one angstrom. Common mean pore sizes for particle filtration range from about one micrometer maximum for microfiltration to about 30 angstroms minimum for ultrafiltration. These titania membranes 22 are therefore designed to separate or filter out certain fraction(s) or solute(s) from the feedstock fluid(s) which can be gas(es), liquid(s) or solution(s), not shown. The membrane support 10 at face 16 is fed a fluid under pressure (arrow 12) that flows along its longitudinal axis through cells 18, and the filtrate exits in the perpendicular direction from exterior wall 20a, as shown by arrows 14, while the residual unfiltered feedstock exits from opposite face 17 as shown by arrow 13. The filtrate is forced, by the applied pressure, to pass through the small sized pores of the membranes 22 and into the connected pores in walls 20 and 20a of the substrate. The filtrate exits the support (arrows 14) by traveling through the open porosity of the substrate walls, exiting through the uncoated exterior surface of the outer wall or skin 20a of the honeycomb structure.
In addition, the ends or faces 16 and 17 of the membrane supports can be coated with a non-porous material, not shown, such as a glass glaze, that is applied to a short length on the outer skin and to the outer surface of the cell walls on the faces of the membrane supports. This allows seals to be made on the filtration devices to carry out filtration and separation processes.
The membrane support is honeycombed with cells 18 at a cell density of at least 15.5 cells per square centimeter and as much as 31, 62, 93 or greater cells/cm2. Each cell 18 extends the length of the membrane support 10, as better illustrated in FIG. 2.
The membrane support 10 must withstand the pressures of the introduced feedstocks. Therefore, sufficient structural strength must be achieved in the support during the fabrication process to withstand such pressures in an approximate range from 0.7 to 105 Kg/cm2. The relative strength of extruded substrates can be compared using four point Modulus of Rupture (MOR) strength measurements.
Preferably, the membrane support 10 is constructed by mixing titania powder(s) with binder and plasticizer, such as methyl cellulose and water. Other aids may be added, such as lubricants (e.g. sodium stearate), dispersants, wetting agents, and/or surfactants, to provide an even dispersion of the titania particles and to improve the uniformity of the formed substrate.
In a preferred procedure the mixture is fed through an extrusion die, e.g. as shown in U.S. Pat. No. 3,790,654, in order to obtain the honeycomb cross-section illustrated in the figures.
The substrate is then conventionally dried, e.g., at room temperature or up to about 100� C. for a time sufficient to evaporate the water (usually about 4 hours) and is then sintered by firing at temperatures ranging from 1,100� to 1,460� Centigrade for a time sufficient to develop the appropriate properties of the substrate (usually about 4 hours).
Most titanium dioxide powders that are commercially available have mean particle sizes of only 1 or 2 micrometers, and are often sub-micron in size. These particles are too small for the fabrication of the inventive membrane supports, which require a mean pore size of about 3 to 15 micrometers and desirably 3 to 10 micrometers. Titania powders for the invention must have a mean particle size of at least 7 micrometers. Particle size measurements generally have a covariance of �3.5%. In our preferred practice of the invention, powders are obtained from SCM Chemicals, Inc. of Baltimore, Md. and Kemira, Inc. of Savannah, Ga., having respective formula designations of VC Titanium Dioxide and UNIT-930 Titanium Dioxide, respectively. Substrates made from these powders are given designations of VC and UNITi-930 hereinafter for the purposes of brevity, respectively.
The VC powder had the following particle size range: 90 volume % at 21.33 micrometers, 50 volume % at 12.54 micrometers, and 10 volume % at 7.12 micrometers.
A particle size range was determined for the UNITi-930 powder, as follows: 90 volume % at 38.05 micrometers, 50 volume % at 23.55 micrometers, and 10 volume % at 14.81 micrometers.
Suitably porous membranes, and particularly porous titania membranes, can be formed on the surfaces of the porous titania substrates as a single layer or desirably multiple layers, in which a porosity gradient is produced by use of fine particle size powders with successively smaller particle sizes. In general, the membranes are formed by dipping the substrates into a slip or sol for a specified amount of time, draining the slip or sol out, drying, and firing the coated substrates. The slips or sols can also be introduced by flowing them through the substrates, for example with a peristaltic or other pump. It may also be possible to spray the slips or sols through the membrane channels of the substrates.
A first membrane layer can be formed from a slip made by dispersing a commercial titania powder in water, by controlling the pH, utilizing organic dispersants, or combinations thereof.
Various binders and plasticizers may also be added to the slip to control its viscosity, as well as the drying and firing behavior of the slip coating. This may also reduce or prevent cracking.
Aqueous dispersions are most common, but it is also possible to use organic solvents, such as alcohol, to form the dispersions.
The initial slip layer can be formed with between 10 to 25 wt. % solids of Ferro 203-1A titania powder obtained from the Transelco Division of the Ferro Corporation. This powder has a typical particle size distribution of 90% at 4.38 micrometers, 50% at 1.9 micrometers and 10% at 0.45 micrometers, and it has a nitrogen BET surface area of 8.4 m2 /g. Slips made from this material are usually adjusted to a pH of about 8, roller milled and ultrasonicated before use.
A second slip can be prepared from about 10 to 25 wt. % solids of Titanox-1000 titania powder, obtained from NL Chemicals, Inc. This powder has a particle size distribution of 90% at 1.24 micrometers, 50% at 0.55 micrometers and 10% at 0.22 micrometers, and it has a BET surface area of 9.81 m2 /g. A slip of this titania powder is usually adjusted to a pH of about 5, roller milled and ultrasonicated.
A third layer may be added using a titania powder of finer particle size, with a surface area of about 50 m2 /g, having the trade designation of Degussa P25. Slips formed from this powder have a dilution of about 1 to 3 volume %. A typical organic dispersant that can be used for the slips is Darvan C obtained from R.T. Vanderbilt Co., Inc.
Membranes formed from these slips have individual layer thicknesses of about 1 to 10 micrometers and total multi-layered thickness of about 3 to 50 (preferably 3-20) micrometers. Each slip layer is dried, e.g. under ambient conditions, and a next slip layer may be applied. Several slip layers may be formed before performing a single firing step.
After the substrates have been coated with the slips, they are dried and fired at about 700�-1500� C., e.g. 1,000� C.
For membranes with pore sizes in the ultrafiltration or gas separation ranges, it is necessary to form additional layers to those noted above. Sols utilized for these additional layers are typically colloidal aqueous sols prepared from the hydrolysis and precipitation of metal alkoxides, such as aluminum sec-butoxide, titanium tetraisopropoxide, silicon ethoxide, or silicon methoxide. However, nonaqueous sols can also be used.
The aqueous sols are stabilized by pH control, usually with acids.
About 12 hours of heating under reflux conditions is also required. The preparation of these types of sols is well documented in the literature.
For typical titania sols, the membrane can be fired at approximately 300� C., resulting in pore sizes of about 30 to 50 Angstroms in diameter.
Utilizing the above VC and UNITi-930 powders, the following substrates were fabricated:
Various shaped samples of porous substrates were extruded of each powder separately. The powder was mixed with methyl cellulose, stearate aid and water similar to Example 2. Solid rods had 0.32 inch (0.81 cm) outer diameter. Open tubes had 0.5 inch (1.2 cm) outer diameter and 0.38 inch (0.97 cm) inside diameter. One inch (2.54 cm) outer diameter honeycombs had 100 cells per square inch (15.5 cells/cm2) and wall thicknesses of 0.025 inch (0.63 mm). A variety of sintering temperatures were used for the samples. Hg porosity measurements (with �5% covariance) were made on each substrate sample. The results shown in Table 1 below indicate that both powders provided substrates with very narrow pore size distributions, with the mean pore size being about 3 micrometers for VC substrates and 6-7 micrometers for UNITi-930 substrates.
Both powders also provided substrates with very high total porosities: at least about 42% for the VC substrates and at least about 52% for the UNITi-930 substrates, respectively, when sintered at 1,320� Centigrade or less for a period of four hours. It has been determined that a porosity of 40% is more than adequate for separation substrates.
Measurements of MOR at room temperature (with �15% covariance) and of linear firing shrinkage were made on several substrate samples. The results are shown in Table 2 below. MOR of at least 140 kg/cm2 was attained in VC substrates with sintering temperatures of about 1300� C. and greater. However, suitable strength results are attained with sintering temperatures of at least about 1200� C. or even as low as 1100� C.
While useful mean pore sizes obtained were generally similar throughout the sintering temperature range of 1150�-1460� C., more modest firing shrinkages were obtained by sintering temperatures not exceeding about 1350� C., whereas MOR strengths of at least about 140 to 210 kg/cm2 were obtained in VC substrates by sintering temperatures of at least about 1200� or 1300� C.
TABLE 1______________________________________Porosity Data for TiO2 Extruded Substrates VC UNITi-930Sample Hg Porosity Hg PorositySinter Total TotalTemp Por- Pore Size Por- Pore Size(�C.) osity Distribution osity DistributionTime (Vo 10% 50% 90% (Vol 10% 50 90%(Hrs) %) (μm) %) (μm)______________________________________1150/4 46.1 4.2 3.2 2.6 54.4 8.4 6.4 3.61175/4 47.5 8.0 3.4 2.4 -- -- -- --1200/4 44.8 4.0 3.1 2.5 51.4 7.5 6.0 3.51250/4 45.6 4.0 3.2 2.5 52.4 8.7 6.9 4.41320/4 41.5 4.2 3.2 2.6 51.9 8.4 6.8 4.91390/4 31.8 6.0 2.7 2.5 49.8 8.5 7.0 5.31460/4 36.4 4.2 3.3 2.6 -- -- -- --______________________________________
TABLE 2______________________________________Physical Properties of TIO2 Extruded SubstratesVC UNIT1-930 Linear LinearSample Firing Mean FiringSintering Mean MOR Shrinkage MOR ShrinkageTemp (�C.) (Kg/cm2) (%) (Kg/cm2) (%)______________________________________1150 -- 2.6 (est.) 62.9 � 6.7 8.21175 57.8 � 11.2 2.3 -- --1250 -- 3.2 -- 9.21320 240.9 � 45.1 5.1, 4.6 97.7 � 14.9 9.51390 513.9 � 159.6 11.1 -- 10.61460 411.0 � 73.0 -- -- --______________________________________
Because the Kemira powder had a larger mean particle size and provided very high porosity values, it was decided to mix the Kemira and SCM powders in admixture in an attempt to obtain an improved extruded substrate.
It was surprising that a substrate was obtained with a mean pore size between that obtained from substrates made from either of the two powders alone, without substantially increasing the pore size distribution.
Since the flux or throughput of the substrate depends upon the square of the pore size, the increase in the mean pore size was calculated to have a significant effect upon the flux for this mixture.
Extruded substrates were formed of mixtures of both powders with water, Methocel methyl cellulose and sodium stearate (an extrusion aid), in the following respective parts by weight as set forth below in Table 3. Rods had a 0.32 inch (0.81 cm) diameter. Honeycombs had a cell denisty of 100 cells/inch2 (15.5 cells/cm2) and a one inch (2.54 cm) outer diameter.
TABLE 3______________________________________Extrusion Compositions of MixedVC TiO2 /UNITi-930 TiO2 SubstratesVC UNITi-930 Linear LinearSample Firing Mean FiringSintering Mean MOR Shrinkage MOR ShrinkageTime (�C.) (Kg/cm2) (%) (Kg/cm2) (%)______________________________________1150 -- 2.6 (est.) 62.9 � 6.7 8.21175 57.8 � 11.2 2.3 -- --1250 -- 3.2 -- 9.21320 240.9 � 45.1 5.1, 4.6 97.7 � 14.9 9.51390 513.9 � 159.6 11.1 -- 10.61460 411.0 � 73.0 -- -- --______________________________________
Tests were performed on the above-mentioned substrates. The test results are presented in Table 4.
TABLE 4______________________________________Physical Properties of Mixed VC/UNITi-930Substrates Sintered at 1320� C.Hg Porosity Water DensityTotal Pore Size Dist. Total MeanPorosity 10% 50% 90% Porosity MORSample (Vol. %) (μm) (Vol %) (Kg/cm2)______________________________________1 36.5 7.7 5.5 3.8 41.0% 220.12 39.3 7.2 5.4 4.0 40.6% 250.63 42.2 9.0 4.5 3.2 41.0% 268.64 37.2 5.3 4.6 3.6 39.1% 305.85 41.9 4.0 3.6 3.0 -- 432.0______________________________________
A range of substrate compositions from less than 5% VC powder to more than 90% VC powder mixed with UNITi-930 powder produced acceptable substrates. Sample 1, having 5% VC/95% UNITi 930, had the largest mean pore size of about 5.5 micrometers, but was slightly weaker than the other compositions with a MOR of 220.1 Kg/cm2. Sample 4, with 15% VC/85% UNITi-930, was stronger at 305.8 Kg/cm2, but had a smaller mean pore size of 4.6 micrometers. Sample 5, at 90% VC/10% UNITi-930, had the highest MOR strength of 432 Kg/cm2, and a mean pore size of 3.6 micrometers.
It appeared that a composition somewhere in between Samples 1 and 4 would provide the best result when the mean pore size is the parameter of interest. Sample 2 and Sample 3, comprising 10% VC and 12% VC powder, respectively, were found to have mean pore sizes of 5.5 micrometers and 4.5 micrometers and MOR strengths of 251 Kg/cm2 and 269 Kg/cm2. On the other hand, when the MOR strength is the parameter of most interest, Sample 5 provides the highest strength of 432 Kg/cm2, but has a mean pore size of 3.6 micrometers which is well within our desired range.
All of the above compositions were found to have a porosity approaching 40% in volume by both Hg porosimetry and water density analysis.
Thus, by mixing the VC powder and UNITi-930 powder, it is possible to obtain either substrates with larger mean pore sizes than can be obtained for substrates made from the preferred VC powder considered alone, or to obtain substrates that are stronger than substrates made from the VC powder alone, and yet still have desirable mean pore sizes.
Each of the sintered substrates provided a narrow pore size distribution in an approximate range of between 1 to 4 micrometers, as required for separation applications.
Substrates can be formed or shaped by any suitable or known fabricating technique utilizing conventional ceramic processes, and substrates can be formed having the honeycomb configuration or a multi-channel configuration obtainable by processes other than direct extrusion (e.g., see U.S. Pat. Nos. 3,112,184 and 3,444,925).
Useful substrates according to the invention described herein have been made in accordance with U.S. Pat. No. 4,877,766 so as to have cell passages of equal hydraulic diameter.
Since other modifications and changes varied to fit particular operating requirements and environments will be apparent to those skilled in the art, the invention is not considered limited to the example chosen for purposes of disclosure, and covers all changes and modifications which do not constitute departures from the true spirit and scope of this invention.
Having thus described the invention, what is desired to be protected by Letters Patent is presented in the subsequent appended claims.
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Library Branch
Book Clubs & Writers' Groups
If you are looking for a safe and creative place to meet with other like-minded individuals, please join us. Everyone welcome. For more information, please call the library at 416-396-3835.
Sat Jul 11
Sat Jul 25
Sat Aug 08
Sat Aug 22
Sat Sep 05
Meets on alternate Saturdays: Starting at 10:30 a.m....
Sat Jul 25
Sat Aug 08
Sat Aug 22
Sat Sep 05
Sat Sep 19
Mimico Centennial
The book club offers an informal book discussion, with lively and stimulating conversation.
Tue Jul 28
Tue Aug 25
Tue Sep 29
Tue Oct 27
Join us for an entertaining and relaxing afternoon with tea, snacks, and a librarian who will introduce you to compelling and exciting library material! For more information, please phone Agincourt library staff at 416-396-89...
Fri Sep 25
Eglinton Square
Members discuss a book by a woman author or about women read by the group. Call 416-396-8920 to register.
Mon Jul 13
Mon Aug 10
Mon Sep 14
Mon Oct 19
Goldhawk Park
Join us to discuss great Chinese books once a month. Registration required. To register please call 416-396-8964.
Fri Jul 03
Fri Aug 07
Fri Sep 04
Fri Oct 02
Mimico Centennial
If you like mysteries, consider joining a group of mystery lovers for informal discussions. Tell us about your favourite books and learn about new authors.
Wed Jul 08
This workshop, by writer Carolyn Grisold, will help you open up to the creative energy in your everday life. Everyone welcome.
All are welcome who are interested in learning about, sharing and discussing diverse collections of poetry. Drop-in....
Wed Aug 05
Wed Sep 02
Wed Oct 07
Share your views with us on selected books....
Thu Sep 24


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DDR3 validation results of modules tested on desktop platforms based on the Intel® 7 Series Chipset using 3rd generation Intel® Core™ i7 processors.
Video: Intel® Atom™ processor fuels everything from smart TVs and tablets to Intel's AppUp Center.
Configurable Intel® Atom™ Processor Benefit
Experience tablets powered by Intel for amazing performance to keep you entertained on the go.
The ASUS Fonepad* with Intel Inside®
Your digital life is complicated. Your operating system doesn't have to be.
Cisco Cius*: enterprise class, mobile device for business connectivity, security, and manageability.


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Kaiser Permanente Promotes Health with 2014 Rose Parade Float Entry 'First Steps to Total Health'
"First Steps to Total Health," the title of Kaiser Permanente's 2014 Rose Parade float entry, helps promote what we can all do to ensure our overall health at every stage of our life. Kaiser Permanente believes that babies who have a healthy first year will grow up to be healthy children, teens, adults and eventually become thriving seniors.
Featuring Mr. Stork and a bundle of babies, the float reminds us that, when we instill and promote healthy habits from the beginning, we are more likely to maintain them into adulthood.
And one of the most important first steps a mother can make to promote the health of her family is to choose to breastfeed. That is why twelve Kaiser Permanente Southern California hospitals are recognized as Baby-Friendly Hospitals by Baby-Friendly USA, the authority for the Baby-Friendly Hospital Initiative in the United States. The Baby-Friendly Hospital Initiative is a global effort to ensure hospital maternity services support breastfeeding. Kaiser Permanente hospitals have some of the highest rates of exclusive breastfeeding at time of discharge in the state.
"At Kaiser Permanente, we are committed to giving every baby the healthiest start possible," said Edward Ellison, MD, executive medical director, Southern California Permanente Medical Group. "Kaiser Permanente Southern California delivers an average of 35,000 babies per year. We believe in making the healthy choice the easy choice for mothers and families, so we support breastfeeding in our hospitals and in our pediatric care. We also promote and support breastfeeding as a key component of our comprehensive strategy to prevent childhood obesity."
Riding on the float this year will be two Kaiser Permanente members with remarkable stories of how they took their First Steps to Total Health and how they are thriving today. Nadia Ruiz Gonzales, a Kaiser Permanente baby born at the Bellflower Medical Center, is among the youngest and fastest Latina runners in the world to complete 100 marathons. Joining Nadia is Precious Malumfashi, a miracle baby who weighed just 1 pound, 4 ounces, when she was born 15 weeks early at the Kaiser Permanente Woodland Hills Medical Center. She is now a healthy and thriving young woman who volunteers at the very same NICU where she was born.
Also riding the float will be three Kaiser Permanente physicians who are dedicated to helping their patients thrive, one step at a time. Myra Bastidas, MD is a "Kaiser Permanente Baby" now taking care of a new generation of Kaiser Permanente babies in her role as a pediatrician at the North Hollywood Medical Offices; Sean Hashmi, MD is an internal medicine specialist who has become a health and fitness champion and an advocate for that 'First Step'; and Michael Tabak, MD is a neonatologist who has delivered over 9,000 babies and spent close to 12,000 hours in night shifts caring for babies in the NICU.
"Dreams Come True," the title of the 125th Rose Parade, marks Kaiser Permanente's ninth float entry. Designed and built once again by Raul Rodriguez and Fiesta Parade Floats, the Kaiser Permanente entry has received an award every year, including: Theme Trophy for excellence in presenting the parade theme (2013); Lathrop K. Leishman Trophy for the most beautiful float entry from a non-commercial sponsor (2012); Director's Trophy for most artistic merit in design and floral presentation (2011, 2008, 2006); Extraordinaire Trophy for the "most spectacular" float longer than 55 feet (2010); Tournament Special Trophy for exceptional merit in multiple classifications (2009); and President's Trophy for most effective floral use and presentation (2007).
For additional information about the 2014 Rose Parade, please visit the Tournament of Roses website. For more information about the Kaiser Permanente Rose Parade Float, "First Steps to Total Health," please follow us on Facebook and Twitter.
About Kaiser Permanente Southern California
Kaiser Permanente is committed to helping shape the future of health care. We are recognized as one of America's leading health care providers and not-for-profit health plans. Founded in 1945, our mission is to provide high quality, affordable health care services to improve the health of our members and the communities we serve. We currently serve more than 3.6 million members in Southern California. Care for members and patients is focused on their total health and guided by their personal physicians, specialists and team of caregivers. Our expert and caring medical teams are empowered and supported by industry-leading technology advances and tools for health promotion, disease prevention, state-of-the-art care delivery and world-class chronic disease management. Kaiser Permanente is dedicated to care innovations, clinical research, health education and the support of community health. For more information, go to: www.kp.org/share.
SOURCE: BUSINESS WIRE ©2015 Business Wire
About Author
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30 year old man | Washington, DC, USA | Seeking women 22-28 within 15 miles of Arlington, VA
I have many leather-bound books and my apartment smells of rich mahogany.
I am a confident, capable, and genuine guy. I am reserved until I get to know someone. I enjoy traveling, reading, music, and being outside. Any day at the beach is a perfect day. Corny jokes come out out whether I like it or not. I love following Pro Basketball, and College Football, going to Baseball and Hockey games, and being at the beach and in the pool. I grew up in Huntington Beach, CA. I played Water Polo at the Naval Academy for 4 years. I have been pretty busy since graduating. I lived in Florida for 4 years but went to Europe, the Middle East, and South America during my two deployments. I recently just got back from Afghanistan working with the Army. Great experience but glad I am back in 'Merica. During my time here I want be able to meet new people, discover the city, and enjoy life. Submitted from mobile
Camping , Coffee and conversation , Cooking , Dining out , Movies/Videos , Museums and art , Music and concerts , Exploring new areas , Playing sports , Shopping/Antiques , Travel/Sightseeing , Watching sports , Wine tasting
Baseball, Basketball, Football, Golf, Running, Swimming, Tennis / Racquet sports, VolleyBall, Walking / Hiking, Weights / Machines, Yoga
I exercise 5 or more times per week.
I like Dogs
I just moved here so still trying to figure out the best places. I do love to travel so I would recommend these to anyone. Cadiz, Spain; Dubrovnik, Croatia; Santiago, Chile; Montevideo, Uruguay; Nashville; NOLA; Seattle; Coronado, CA; ATL; Annapolis.
United States Naval Academy, Annapolis, MD
Movies: 25th Hour, Layer Cake, The Outlaw Josey Wales, Sound of Music Music: Usher, Kings of Leon, Too many to count Sports: Lakers, Angels, Seahawks, Ducks Exercise: Swimming, Running, Watching Biggest Loser
I would probably go to any type of sporting event. I will enjoy most everywhere and everything with my friends. Most nights I'll keep it pretty chill, make dinner, read, watch a movie, etc.
The Presidents' Club, The Tipping Point, The Rum Diary, Dixieland Delight
Z{{Cta}} {{#if HasMoreInfo}} ?{{CtaSecondary}} {{/if}}
|What he is looking for
|3'3" (99cms)
|5'4" (162cms) to 5'10" (177cms)
|Body type:
|I'll tell you later
|Slender, Athletic and toned
|Blue, Brown, Green, Hazel
|Light brown
|Light brown, Dark brown, Blonde, Dark blonde
|I'll tell you later
|No Way
|I'll tell you later
|Social Drinker, Moderately
|Political / Govt / Civil Service / Military
|No preference
|I'll tell you later
|$50,001 to $75,000, $75,001 to $100,000, $100,001 to $150,000, $150,001+
|Never Married
|Never Married
|Have kids:
|Wants kids:
|Definitely, Someday
|I'll tell you later
|White / Caucasian
German, English, Irish, Scottish, Welsh.
|Christian / Protestant
|Christian / Catholic, Christian / Protestant, Spiritual but not religious, Christian / Other
|Bachelors degree
|Bachelors degree, Graduate degree, PhD / Post Doctoral
United Sates Naval Academy; 2008.


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We spent one night here as we were attending a show at the Academy of Music (very close walk). The hotel itself is old, but in an elegant and classic way. It seemed to be very well maintained and was very clean. Our room was huge, with high ceilings and interesting details. Much of it was "wasted" space, but that was OK with us, since we were only there for the night.
The location was excellent for all that we wanted to do. It was within very easy walking distance to restaurants and the theater. I wish that we could have stayed an extra night!
- Official Description (provided by the hotel):
- A magnificently restored historic National Landmark, the hotel is conveniently located in the heart of Philadelphia's business, restaurant, shopping and theatre districts. Featuring 172 spacious guest rooms, this historic luxury property appeal to all. ... more less
- Reservation Options:
- TripAdvisor is proud to partner with Expedia, Travelocity, Hyatt Hotels Corporation, Booking.com, Priceline, Hotels.com, Odigeo and Jetsetter so you can book your Hyatt at The Bellevue reservations with confidence. We help millions of travelers each month to find the perfect hotel for both vacation and business trips, always with the best discounts and special offers.
- Also Known As:
- Hyatt At The Bellevue Hotel Philadelphia
- Hyatt Philadelphia
- Park Hyatt Philadelphia
- Philadelphia Hyatt


text:
Flippish Shows
- #Anyare?
- 30 Seconds of Pain
- According to Teacher K.
- Behind The Scenes
- Bet You Cant Do It!
- Boy Bawal
- Boy Dugyot
- Brain Freeze
- Casting Couch
- Corny
- Dashboard Confessions
- Direk
- Double B: The Super Bonngg and BA show
- Fact Sheet
- Flippish Dance Battle
- Flippish News
- Flippish Specials
- Flipptube
- Gawad Kalinga
- Girl Next Door
- Going Mental
- Honey B.
- Hot Spots
- Idedemo
- InstaCrush
- Jack en Poy
- Komiks
- Live
- LSS: Last Song Syndrome
- Momol Sessions
- Musiklab
- My Most Embarassing Moment
- Night Life
- Now Streaming
- Out of Office: The Musicale
- Para Kay Ninoy
- Passport
- Philippine Blog Awards Video Page
- Project Halo
- Ryder eXperience
- Ryder Xperiment
- School Wars
- Shorties
- Skechers Street Dance Battle
- Social Experiments
- Sun Cellular
- Test Tube
- The Blank Song
- The Event Show
- The Score
- To Be Continued…
- U Confessions
- Viral
- Weekend Warriors
- Who Dares Kring
- Who's That Girl
- Yolo
First Medal for Team Philippines!
Filipina Fencer Justine Tinio bags the first medal for Team Philippines in the 28th Southeast Asian (SEA) Games! *crowd cheers* *fireworks* *cue in marching band* *clap clap!* Tinio, who was also the Most Valuable Player in the last UAAP fencing championship, astound everyone, including herself, in giving the country its ...
Accustomed MUAY THAI fighter pretends to be a nerd girl at the gym, what she did next is hilarious.
Germaine Yeap is a pro MUAY THAI fighter who pretended to be a nerd girl who doesn't know anything about kick boxing in a prank for MUAY THAI trainers. She looks simple, demure and sweet girl for her outer appearance but she is wild, rough, and beast in the inside. ...
Want to watch the fight of the century? You can visit these places.
Are you ready for Pacquiao and Mayweather fight? Do you want to enjoy watching while resting in a high-end place? How about watching while enjoying cold beer and some good appetizers? Or are you out of budget and prefers to enjoy the comfort of your own home? Anyway, here's a ...
NES – Rachel Anne Daquis, Alyssa Valdez and Jamenea Ferrer
Watch as the Ateneo Women's Volleyball Team amazes us with their witty remarks and humor! Get to know them more as host Rizza Diaz unravels cute facts about our volleyball superstars Alyssa Valdez, Jamenea Ferrer and Rachel Anne Daquis. With talent, wit and charm, these girls surely captivate our hearts!
February 24, 2010 – PBA, UFC 101, NBA
In this episode of The Score, Jinno and Noel talk about PBA Finals, UFC 110, a recap on UEFA, NBA Trade and deadline results, Tiger Woods who finally faced the media and their picks for the week. Brought to you by Mega Sports World. Pusta Na!
February 17, 2010 – Donaire, NBA, UEFA
In this episode of The Score, Jinno and Noel talk about Nonito Donaire winning against Manuel Vargas, NBA Eastern and Western Conference results, UEFA Championship League's game schedules, and their picks for the week. Brought to you by MSW, Pusta Na!
February 3, 2010 – Aussie Open, NBA, Chris Paul, F1
In this episode of The Score, Jinno Rufino and Noel Zarate talk about Aussie Open, NBA All-Star Line-ups, Jinno and Noel's Snubs, Chris Paul who is undergoing surgery, F1 pre-season testings and their picks for the week. Brought to you by MegaSportsWorld.
Jan 20, 2010 – NFL, Arenas, Stackhouse
In this episode of The Score, Jinno and Noel talk about NFL Divisional Playoffs Results, Gilbert Arenas who pleads guilty, Jerry Stackhouse who signed with Milwaukee Bucks and of course, their picks for the week. Brought to you by MegaSportsWorld. Pusta Na!
Basketball Episode 2
Super Bonngg and BA finds out the real identity of their opponent! What are they going to do? Find it out!
Jan 13, 2010 – Pacquiao, NFL, NBA, EFL
In this new episode of The Score, Jinno and Noel talk about Pacquiao and Mayweather's cancelled fight, NFL Wildcard Playof results, 2010 NBA All-Star Balloting results, featured matchups of NY Knicks V Detroit Pistons, Washington Wizards V Chicago Bulls, Chelsea V Sunderland and Tottenham V Hull City. They also introduce ...


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Articles tagged raster noton
21 Jun 2011 // 11:30 AM
Kangding Ray have always made intricate lapidary electronic slices. Their latest album OR is no exception, as evidenced by this video of their title track.READ more
//Mixed media
Colette Carr "Static" (video) (Premiere) // Music
House of Blondes "First of July" (audio) (premiere) // Music
Digisaurus 'No More Room For Love' (EP stream) // Music
Eszter Balint 'Airless Midnight' (album stream) (premiere) // Music
//Pm Picks
PopMatters is on a short summer publishing break. We resume Monday, July 6th.
// Announcements
"PopMatters is on a short summer publishing break. We resume Monday, July 6th.READ the article


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