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The present invention relates to a process for isomerizing reactant allyl alcohols of the formula (I) to product allyl alcohols of the general formula (II)
where R1 to R5 are each hydrogen or a mono- or polyunsaturated or saturated C1–C12-alkyl radical, which can be substituted or unsubstituted,
in both directions of the equilibrium, which comprises isomerizing in the presence of a dioxotungsten(VI) complex of the general formula (III),
1. A process for isomerizing reactant allyl alcohols of the formula (I) to product allyl alcohols of the general formula (II)
where R1 to R5 are each hydrogen or a mono or polyunsaturated or saturated C1–C12-alkyl radical, which can be substituted or unsubstituted,
in both directions of the equilibrium, which comprises isomerizing in the presence of a dioxotungsten(VI) complex of the general formula (III),
2. The process as claimed in
3. The process as claimed in
4. The process as claimed in
5. The process as claimed in
6. The process as claimed in
7. The process as claimed in
8. The process as claimed in
9. A process for isomerizing reactant allyl alcohols which comprises isomerizing the allyl alcohols in the presence of a dioxotungsten(VI) complex of the general formula (III)
The present invention relates to a process for isomerizing reactant allyl alcohols to product allyl alcohols in both directions of the equilibrium, which comprises isomerizing in the presence of a dioxotungsten(VI) complex, and also to novel dioxotungsten(VI) complexes and their use.
Allyl alcohols are important intermediates in industrial organic product synthesis. Tertiary allyl alcohols in particular are used for example as intermediates in the preparation of scents in their own right or else as additives in soaps and detergents.
Allyl alcohols isomerize under acid catalysis. This isomerization corresponds to a 1,3-migration of the hydroxyl group and an internal shift of the double bond, as is shown in the following equation with the general formulae I and II:
The process is particularly suitable for the preparation of tertiary product allyl alcohols, such as 2-linalool, by isomerization of primary or secondary allyl alcohols, such as geraniol or nerol.
Geraniol (2-trans-3,7-dimethyl-2,6-octadien-8-ol), nerol (2-cis-3,7-dimethyl-2,6-octadien-8-ol) and 2-linalool (3,7-dimethyl-1,6-octadien-3-ol) are important compounds in the scent industry. They are used either directly as scents or converted to scents of higher molecular weights by reaction with other compounds. These terpene alcohols are also important as C10 building blocks in the synthesis of vitamins, such as vitamin E and vitamin A.
In the past, the literature preferentially described processes for the isomerization of linalool to geraniol. Since isomerizations are equilibrium reactions, the processes developed are in principle also usable for the reverse reaction of isomerization of geraniol or nerol to give linalool.
Initially, isomerization reactions of allyl alcohols were carried out using acids as catalysts. However, these processes were only of limited importance, since they were dominated by side reactions, such as dehydration or cyclization.
Later, molybdenum, vanadium and tungsten compounds were identified as catalysts for the rearrangement of substituted allyl alcohols and investigated as such (cf. P. Chabardes et al. in Tetrahedron 33 (1977), 1775–1783).
While the molybdenum compound described as an isomerization catalyst in GB 125 6184 gave unsatisfactory reaction results, relatively high selectivities coupled with simultaneously higher activities were possible using the tungstenoxo(VI) alkoxide catalysts of the formula WO(OR)4 in the presence of a nitrogen base as an additional ligand than were possible using the analogous vanadiumoxo(V) alkoxide catalysts of the formula VO(OR)3. Further advantages of the tungsten catalysts are that they can firstly be easily separated from the reaction mixture (cf. T. Hosogai et al. in Chemistry Letters 1982, pages 357–360) and, secondly, that they only have a low toxicity compared to the vanadium catalyst.
Furthermore, DE 25 16 698 discloses the preparation of novel catalysts based on tungsten, and also their use for the catalytic rearrangement of tertiary allyl alcohols to give primary allyl alcohols. Suitable catalysts described for this process include tungstenoxo(VI) complexes containing alkoxy radicals and/or trialkylsilyl radicals attached through oxygen, which lead to an improvement in the selectivity for ligands additionally coordinated to the tungsten, which contain an element selected from the group consisting of N, P, As and Bi, in particular ligands selected from the group consisting of the primary, secondary and tertiary monoamines, the polyamines, the Schiff bases, the imines, nitriles and isonitriles. Particularly suitable ligands mentioned therein include primary monoamines, such as methylamine, ethylamine, propylamine, β-ethoxyethylamine, butylamine, cyclohexylamine, aniline and naphthylamine; secondary monoamines, such as dimethylamine, diethylamine, dibutylamine, dicyclohexylamine, methylaniline, methylcyclohexylamine, piperidine, morpholine and pyrrolidine; tertiary monoamines, such as trimethylamine, triethylamine, ethyldibutylamine, tricyclohexylamine, dimethylaniline, pyridine, picoline, quinoline, isoquinoline, N-methylpyrrolidine and N-methylmorpholine; ethylenediamine, pyrazine, piperazine, pyrimidine, triethylenediamine, 1,8-diazabicyclo[5.4.0]undec-7-ene, polyethyleneimines, and also ion exchange resins having a multiplicity of amino groups within the molecule, in particular pyridine, triethylamine, cyclohexylamine, diethylamine and tricyclohexylphosphine. Aminoalcohols are not mentioned therein.
Our investigations into the isomerization of geraniol using a 0.05 mol % solution of tungstenoxo(VI) tetrakisgeranylate by a process similar to that described in DE 25 16 698 showed that the rearrangement of linalool in the presence of a nitrogen base at 200� C. (reaction time about 1 hour) is much more selective than when a nitrogen base is not used. Suitable nitrogen bases here include diethylamine, pyridine, imidazole and poly-(4-vinylpyridine). Improvements were achieved by the addition of aminoalcohols to the catalyst solution (see comparative experiments, examples 2 to 6). The selectivities for linalool obtained using this process are very good, but the conversions obtained leave a lot to be desired.
So the comparatively low conversions coupled with simultaneously high temperatures of over 150� C., which accelerated the formation of byproducts, had a disadvantageous effect in these experiments.
DE 25 16 698 also describes the synthesis of tungsten alkoxides, by alcoholysis of tungstenoxo tetrachloride using alcohols or alcoholic solutions of alkoxides. Although the removal of the chloride in the form of ammonium chloride using ammonia or as sodium chloride using sodium methoxide is possible, it is always incomplete. Chlorine is also almost always present in the distilled allyl alcohol product, which strongly compromises its quality and acceptability for use in scents and vitamins. Additionally, even ppm quantities of chloride in tungsten alkoxides can have adverse corrosive effects in metal columns and reactors. Subsequent removal of chloride traces using activated carbon filters or silver(I) oxide is possible but inconvenient and makes the complete process complex and more expensive.
Further, tungstenoxo tetrachloride has to be prepared by known methods using tungstic acid and thionyl chloride in a preceding reaction, so that the synthesis of tungsten alkoxides has to be carried out at high expense in a multistep process.
The process for the preparation of tungstenoxo(VI) alkoxide complexes that is similarly described in DE 25 16 698, starting from tungsten trioxide and hydroxy compounds, is not usable in industrial scale applications because of the poor yields.
Tungsten alkoxides are known to be sensitive to hydrolysis and react with water to give alcohols and tungsten oxide. Since dehydration always occurs as a side reaction of allyl alcohol isomerization, sparingly soluble tungsten oxides precipitate increasingly out of the reaction mixture under the conditions of allyl alcohol isomerization. These increase the catalyst costs and further support the formation of byproducts, and also water from allyl alcohols, and lead to further deterioration in selectivity.
It is an object of the present invention to provide further improvements in the process of isomerization of allyl alcohols such that the tungstenoxo catalyst can be prepared halogen-free and using simple, inexpensive steps, in order to avoid contamination of allyl alcohol with halogen, and further to avoid corrosion problems in the plant. Furthermore, the catalyst losses resulting from hydrolysis should be reduced or totally avoided and the product selectivity should be improved. The need also exists to speed equilibration and to increase the space-time yields without having to further increase the isomerization temperature.
Furthermore, the improved catalysts should achieve higher conversions of the reactant allyl alcohol from the isomerization of primary or secondary allyl alcohols, such as geraniol or nerol, to give tertiary allyl alcohols, such as linalool, i.e. speed equilibration. Also, the new catalysts should be easier to prepare than their predecessors.
We have found that this object is achieved by novel homogeneously dissolved dioxotungsten(VI) complexes of the general formula (III), with simultaneously improved selectivity and higher activity for the isomerization of geraniol and nerol to give linalool.
According to the invention, homogeneous solutions of dioxotungsten(VI) in water, alcohol or a different solvent can be used.
The invention provides a process for isomerizing reactant allyl alcohols of the formula (I) to product allyl alcohols of the general formula (II)
The following allyl alcohols of the general formula (I) or (II) can be advantageously isomerized by means of the process of the invention: 2-methyl-3-buten-2-ol, prenol (3-methyl-2-buten-1-ol), linalool, nerol and geraniol, and also farnesol (3,7,11-trimethyldodeca-2,6,10-trien-1-ol) and nerolidol (3,7,11-trimethyldodeca-1,6,10-trien-3-ol), in particular linalool, nerol and geraniol.
The ligands L1 and/or L2 can be either ligands such as aminoalcohols, aminophenols or mixtures thereof.
Examples of suitable aminoalcohols include: triethanolamine, diethanolamine, monoethanolamine, tripropanolamine, dipropanolamine, 3-amino-1-propanol, 1-amino-2-propanol, 2-amino-1-propanol, butyldiethanolamine, methyldiisopropanolamine, N-(2-hydroxybenzyl) amine or N,N′-bis-(2-hydroxy-benzyl)-1,2-diaminoethane, α,α-diphenyl-L-prolinol, L-tryptophanol, L-alaninol, L-isoleucinol, L-leucinol, L-methioninol, L-phenylalaninile, L-valinol and 2-(2-pyridyl)propan-2-ol.
Examples of suitable aminophenols include: o-aminophenol, m-aminophenol, p-aminophenol, or 8-hydroxyquinoline unsubstituted or substituted by halogen, alkyl, amino, hydroxy, alkoxy, thio, sulfonyl or nitro, 3-amino-2-naphthol, N-methyl-2-aminophenol, N,N-dimethyl-2-aminophenol, 2-piperidinophenol, 2-hydroxypyridine, N-methyl-2,2′-imino-bis(8-hydroxyquinoline), particularly preferably 8-hydroxyquinoline.
The phenols can be unsubstituted or substituted by halogen, alkyl, amino, hydroxyl, alkoxy, thio, sulfonyl or nitro.
The addition of ammonia or else amines to the reactant allyl alcohol, or else to the catalyst solution is advantageous.
Suitable amines include, for example, mono-, di- or trimethylamine, ethylamine, mono-, di- or triethylamine, mono-, di- or tributylamine, preferably diethylamine.
Suitable alcohols include, unless otherwise stated, any alcohol ROH, where R is a mono- or polyunsaturated or saturated C1–C15-alkyl radical, which is substituted by one or more of the substituents selected from the group consisting of halogen, C1–C6-alkyl, amino and hydroxyl, for example methanol, ethanol, propanol, isopropanol, butanol, tert-butanol, pentanol, geraniol, nerol, nerolidol, prenol, linalool or farnesol.
The invention further provides novel dioxotungsten(VI) complexes of the general formula (III),
Particularly preferred complexes are those in which the ligands L1 and/or L2 are each 8-hydroxyquinoline.
The molar ratio of tungsten to 8-hydroxyquinoline is in the range from 1:1 to 1:5, preferably from 1:1 to 1:2, and is particularly preferably 1:2.
The molar ratio of tungsten to 8-hydroxyquinoline in the solution of the complex is at least 1:1. Molar ratios of greater than 1:7 are also possible but do not yield any further benefit.
The dioxotungsten(VI) complexes can be obtained using the corresponding oxoperoxotungsten(VI) complex as an intermediate.
According to the process described in DE 195 33 331, the oxoperoxotungsten(VI) complex is initially prepared from tungstic acid and an aqueous hydrogen peroxide solution with optional subsequent addition of the ligand or ligands. This is then reduced to give the tungstenoxo compound.
Suitable reducing agents include the reactant allyl alcohol itself or, for example, sodium thiosulfate or iron(II) salts, but in particular geraniol and/or nerol.
However, the dioxotungsten(VI) complex can also be prepared from tungsten(VI) dioxo dichloride without the addition of a reducing compound.
The dioxotungsten(VI) complex can either be prepared separately before the actual reaction or in situ in the reactant allyl alcohol.
In general, the dioxotungsten(VI) complex is dissolved in the reactant allyl alcohol in a concentration in the range from 0.001 to about 5% by weight.
It is particularly advantageous first to combine the ligand L1 or L2 with or without an additional organic solvent with the aqueous or organic solution of the dioxotungsten(VI) complex and only then to add the thus prepared solution or suspension of the finished catalyst to the reactant allyl alcohol. The additional ligands are generally used in a quantity in the range from 1 mol % to 1000 mol %, preferably from 100 mol % to 700 mol %, relative to the tungsten quantity. Larger ligand quantities are also possible, but result in no further advantage.
The absolute concentrations of ligand and tungsten complex in the reaction mixture are not critical in the process of the invention and can, for example, be increased such that the speed at which equilibrium is achieved can be increased as desired.
An increase in the speed at which equilibrium is achieved can also be achieved in the process of the invention by removing water formed by side reactions from the mixture, for example by passing an inert gas stream over, the addition of known water-removing agents or stripping with the product allyl alcohol gas stream during distillation.
The process of the invention is generally carried out at from 50 to 300� C., preferably from 150 to 250� C.
It can be carried out either with or without the use of a solvent, batchwise, but also continuously. Suitable solvents include organic solvents such as toluene, tetrahydrofuran, benzene, cyclohexane, xylene, methylene chloride or mesitylene, but preferably the reactant allyl alcohol itself is used as the solvent.
The process of the invention is advantageous when the reactant allyl alcohol is present in the reaction mixture in a concentration in the range from about 10 to 100% by weight.
The process of the invention is particularly advantageous when the reactant allyl alcohols used are geraniol and nerol and the produkt allyl alcohol is 2-linalool.
To work up, 2-linalool is removed from the product mixture by distillation, as a lower-boiling component. In general, reactant allyl alcohols and secondary compounds will be present in the product allyl alcohol. Distillation to obtain the pure product allyl alcohol can be carried out by known methods.
Isomerization is an equilibrium reaction and the location of the equilibrium depends on the thermodynamic properties of the reactant and product allyl alcohols, and also on the reaction conditions. Continuous or batchwise separation of linalool, the lowest-boiling allyl alcohol, from the reaction mixture using the base of the distillation column as the reaction chamber, allows a favorable space-time yield to be achieved because of the shifting of the equilibrium even in the case of unfavorable equilibration.
The following examples illustrate the invention:
Preparation of a cis-dioxotungsten(VI) Complex Using the Example of cis-dioxotungsten(VI) bis(oxinate)
Tungstic acid is suspended, for example, at 40� C. in a 3.5:1 excess of aqueous hydrogen peroxide. After stirring for 6 hours, the solution is filtered. 8-Hydroxyquinoline is added to this prepared oxoperoxotungsten(VI) solution. The 8-hydroxyquinoline is added in solid form or as a melt, or added dropwise dissolved in an organic solvent, e.g. an alcohol. 8-Hydroxyquinoline is preferably added in a quantity of from 1 to 3.5 mol equivalents relative to tungsten. The solution or suspension obtained is used directly for the isomerization of a reactant allyl alcohol, by adding it to geraniol and/or nerol. The oxoperoxotungsten(VI) complex reacts with the reactant allyl alcohol to give cis-dioxotungsten(VI) complex and geraniol and/or nerol epoxide. The mixture obtained can be used directly for further isomerization, but the cis-dioxotungsten(VI) complex with 8-hydroxyquinoline as the ligand can also be precipitated by cooling or concentration of the mixture. The precipitated catalyst powder is filtered off, washed and dried. Any water present in the catalyst solution can be removed by distillation or by addition of drying agents. The novel tungsten complex prepared by the process described above contains two oxo groups and 8-hydroxyquinoline as a further ligand and is characterized by hydroxyquinoline being deprotonated at the phenolic OH group and the ratio of tungsten to 8-hydroxyquinoline being 1:2.
This catalyst can be added to the reactant allyl alcohol at from 20 to 300� C., either dissolved in any solvent or as a solid.
cis-Dioxotungsten(VI) bis(oxinate) can also be prepared without the addition of a reducing compound.
For this purpose, 2.0 g of tungsten(VI) dioxo dichloride are mixed with 10 g of methanol and 2.1 g of 8-hydroxyquinoline in a 50 ml autoclave under 2 bar of ammonia gas and heated to 90� C. for 24 hours. After cooling, the solid is filtered off and washed with methanol. The filter cake is boiled twice, in each case with 50 g of 50% by weight aqueous methanol, and after cooling is filtered off again and washed with methanol. The remaining cis-dioxotungsten(VI) bis(oxinate) powder is dried in the airstream of a water suction pump.
The yield is 89%.
The catalyst powder prepared in example 1 is used directly for the isomerization of geraniol. 50 g of geraniol are heated to 180� C. under argon in a 100 ml three-necked flask fitted with a distillation bridge. 0.14 g of the dried catalyst powder is then added and the mixture is stirred at 180� C. for 1 hour. During the isomerization, no product is distilled off. After cooling, GC analysis of the liquid phase is carried out.
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PlayStation Now Streaming Service Coming To PS3 On May 12thBy Ishaan . May 5, 2015 . 9:57am
More platforms planned for the future.
More platforms planned for the future.
PlayStation Now will come with two subscription plans: one month for $19.99, or a three-month package for $44.99.
Sony Computer Entertainment and Samsung are working together to bring PlayStation Now to Samsung's line of Smart TVs. The cloud streaming service will be available in the United States and Canada in the first half of 2015.
PlayStation 4 owners will be able to play over 100 PS3 games including God of War: Ascension, Dead Space 3, and Metal Gear Solid V: Ground Zeroes which were confirmed during SCEA's press conference.
PlayStation 3 games will be available for streaming on PlayStation 4 via the PlayStation Now service starting July 31st.
This morning, at the Consumer Electronics Show in Las Vegas, Sony announced "PlayStation Now," a streaming service for games on PlayStation platforms.


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Press Kit
Zip folder containing hi-resolution copies of the following screenshot images and app icons:
Pocket Anatomy and Pocket Brain Video Demonstrations:
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Fantastic app for medical students.
I'm a medical student in London and this app is such a great tool for learning, understanding and testing anatomy! I'd thoroughly recommend it. Amazing images that can be manipulated in 3D to view in new ways. Definitely worth the money and more.


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Pre-Election Statement by the Resident Coordinator, United NationsApr 26, 2015Pre-Election Statement by the Resident Coordinator, United Nations.
a2i and JUST to Build Technology Platform for the JudiciaryApr 20, 2015Two UNDP projects - Access to Information (a2i) and Judicial Strengthening Project (JUST) - partnered together aiming to establish a technology platform to ensure service delivery at doorsteps of the citizens through signing the Memorandum of Understanding (MoU) on 19th April 2015 at the Prime Minister's Office.
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UNDP and Dhaka University organise innovative research training for students on Pro-Poor TradeJan 13, 2015The Pro-Poor Trade project of the United Nations Development Programme (UNDP) in partnership with the University of Dhaka, is holding a two-day training session starting from today (Tuesday, 13 January) and ending tomorrow (Wednesday 14 January) at the Social Science Faculty Building, University of Dhaka. The project is an innovative research initiative, combining the strengths of UNDP with the knowledge of one of the leading institutions of higher education in Bangladesh.
UN-Bangladesh Mission to Sundarbans Oil Spill Shares its FindingsDec 31, 2014On its return to Dhaka after a six-day visit to the Sundabans, the UN-Bangladesh Mission shared its findings with the Ministry of Environment and Forests (MoEF), and the media, on Thursday 31 December 2014.
UN TEAM LEAVES FOR SUNDARBANSDec 22, 2014The United Nations Sundarbans Oil Spill Response mission, which is comprised of multi-disciplinary experts from seven different countries including Bangladesh, left for Sundarbans early this morning. The team will support Government of Bangladesh in containing the spillage and cleaning up; and assessing the situation and develop an action plan for a phased response and recovery.
UN SUPPORT TO SUNDARBANS OIL SPILL RESPONSEDec 18, 2014In response to a request from the Government of Bangladesh, the UN system in Bangladesh has mobilized an international team of experts to support the Government's cleanup efforts of the oil spill in the Sundarbans.
ইউএনডিপি বাংলাদেশের কান্ট্রি ডিরেক্টর পলিন ট্যামেসিসের বক্তব্য Dec 11, 2014গত ৯ ডিসেম্বরে দুর্ঘটনাকবলিত একটি জাহাজ থেকে সুন্দরবনের ভেতরে তেল নিঃসরণের সাম্প্রতিক ঘটনায় বাংলাদেশ সরকার এবং সংশ্লিষ্ট সংস্থাগুলোর সাথে সাথে ইউএনডিপি বাংলাদেশও উদ্বিগ্ন বোধ করছে।
UNDP Bangladesh Observers International Anti-Corruption DayDec 9, 2014The United Nations Development Programme (UNDP) in Bangladesh observed the International Anti-Corruption Day 2014 with an interactive event with young volunteers representing different youth activist orgnisations at the Russian Cultural Centre on Tuesday, 09 December from 4.00pm to 7.30pm.
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The Professional Choice for CNC PROGRAM EDITING As a CNC programmer or machinist on the shop floor responsible for creating or editing CNC programs you need a professional tool that is fast and flexible. CIMCO Edit 5 is the latest version of the most popular CNC program editor on the market. With over 80,000 licenses distributed in the past few years, CIMCO Edit is the editor- of-choice for professional CNC programmers who demand a full-featured and reliable, cost-effective professional editing and communication tool. The Professional CNC Program Editor CIMCO Edit 5 provides a comprehensive set of essential editing tools necessary for meeting the demands of modern CNC program editing. CIMCO Edit 5 has no program size limitations and includes CNC code specific options such as line numbering / renumbering, character handling and XYZ range finder. It also features math functions including basic math, rotate, mirror, tool compensation, and translate. CIMCO Edit 5 offers all the functions expected from an editor including drag-and-drop text editing. Best of all CIMCO Edit 5 is completely configurable and is easily adapted to any existing CNC program editing environment. Every aspect of CIMCO Edit 5 is new, from the multi-pane tabbed layout to the dynamic toolbars and menus. CIMCO Edit 5 also includes new and powerful tools such as an enhanced file compare utility, a reengineered graphical back- plotter, and the new NC-Assistant programming tool. Using Edit 5 is easy and intuitive - designed for usability and productivity New features include NC-Assistant and Cycles/Macros For more information visit us at www.cimco-software.com Product HIGHLIGHTS NC-Assistant The NC-Assistant makes editing NC code faster and easier than ever. Point at any M or G code and the NC-Assistant will identify the code allowing you to modify values using an inter- active interface linked to the CNC code. Input the desired values for any register and the NC-Assistant updates the CNC code automatically. File Compare lets you compare two programs to pinpoint their differences The NC-Assistant tool allows you to quickly insert and edit complex cycles and operations. CIMCO Edit 5 includes built- Intelligent File Compare in cycles and macros for the most common operations such as program start, program stop and tool change. You can also CIMCO Edit 5 features a fast and fully configurable side-by-side record or create custom cycles and macros for the operations file compare, allowing the user to quickly identify CNC program most common to your own specific setups and applications. changes. The file compare identifies changed and deleted / inser- ted lines, but ignores trivial format changes like block re- numbering and spacing. Differences are displayed one line at a time, all at once or printed side-by-side for offline review DNC-Link transfer status window provides comprehensive information Save time on trivial tasks with the new NC-Assistant feature CNC Communications and DNC Graphical Backplotter CIMCO Edit 5 includes DNC capabilities for reliable RS-232 The 3D Mill / 2D Lathe backplotter handles your 3-axis Mill communications with a variety of CNC controls. With the DNC and 2-axis lathe CNC programs with step and continuous option you can send and receive CNC programs to multiple forward and reverse plotting. Edit the CNC program and the machines simultaneously from inside CIMCO Edit 5. update is automatically reflected in the plot. Analyze the plot with dynamic zoom, pan, rotate and measuring functions. CIMCO Edit 5 supports solid visualization of NC code with toolholder collision check and gouge detection. Solve complex geometry problems with the CNC-Calc Add-on for CIMCO Edit 5 CNC-Calc Option CNC-Calc is a fully featured 2D CAD solution that works inside CIMCO Edit 5. This add-on is a fast and effective solution for solving problems with complex 2D geometry. Users can draw or import (DXF) 2D geometry, specify cut depths, lead-in, lead-out, and other tool Backplot your CNC programs path variables and quickly generate CNC code in ISO and other conver- using solid or wireframe views sational formats for contours and drilling. Reseller Europe North America CIMCO Integration CIMCO Integration Lyngby, Copenhagen Oakboro, North Carolina Denmark USA Tel: +45 45 85 60 50 Tel: +1 704 644 3587 Fax: +45 45 85 60 53 Fax: +1 704 645 7162 Website www.cimco-software.com E-mail firstname.lastname@example.com When Reliability Matters
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Movement of Blood cells (view at the cellular level)
The circulatory system of humans is closed, meaning that blood is enclosed by blood vessels. This image is that of an open system, meaning the blood moves freely throughout the body. In both systems, blood is pumped to the tissues of the body and then nutrients diffuse into the cells of those tissues.
SAMPEX - A Synoptic View of Earths Electron Radiation Belts: South Pole Energetic Fluxes from PET
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TOPEX-Poseidon Altimeter sea level anomaly and NCEP sea surface temperature anomaly in the Pacific from August 1996 to August 1997
#whyUToledo - Rocket Pride
Two University of Toledo students tell us #whyUToledo Follow the reasons why on Twitter: http://twitter.com/#!/search/%23whyUToledo On Monday May 2, help us spread the word about all of the great reasons to choose The University of Toledo for higher education. Students, Staff, and Faculty are asked to tell us and their friends #whyUToledo was their choice.
"I Am My Life" interview
Chaz Barracks, '11, talks about his independent study in theater and dance that has culminated in a performance piece, "I Am My Life." Video by Sam Abrahams, '14.
AU from a Longboard!
Alfred University senior Cory Lewandowski, a biology major from Spencerport, NY, provides a look at what the AU campus looks like from a longboarder's point of view. Hop aboard to see Cory's unique perspective! Video recording and editing by: Cory Lewandowski Music by: Motorama "There's No Hunters Here" Licensed under Creative Commons "Attribution 3.0" http://freemusicarchive.org/music/Motorama/Alps/09_Theres_No_Hunters_Here
WBAA: The Jewish Jesus: Revelation, Reflection, Reclamation
WBAA Public Radio interview with Zev Garber, Emeritus Professor and Chair of Jewish Studies and Philosophy at Los Angeles Valley College. He is editor of The Jewish Jesus: Revelation, Reflection, Reclamation. More information about the book is available at the Purdue University Press website: http://www.thepress.purdue.edu/titles/format/9781557535795
Ramiro Garces
Interview with Ramiro Garces, VP, Human Resource with Kimberly-Clark. Mr. Garces speaks passionately about the ties between Krannert School of Management and Purdue University, and private sector companies like Kimberly-Clark.
Herrick Labs Groundbreaking Ceremony
Herrick Labs Groundbreaking Ceremony recorded April 1, 2011
Boiler Bytes: Women in Engineering Program
Purdue University's Women in Engineering Program (WIEP) helps women and girls discover their inner engineer. From mentoring to career development, WIEP continually encourages current and future women engineering students by providing interesting and engaging programming relevant to their lives. https://engineering.purdue.edu/WIEP/AboutUs
Boiler Bytes: 2011 Bridge Bust Competition
Teams from 13 Indiana and Illinois high schools constructed bridges only to see them destroyed during the 32nd annual Bridge Bust contest March 4 at Purdue University. The competition is administered by the Purdue chapter of the American Society of Civil Engineers. http://www.purdue.edu/newsroom/events/2011/110223SchenkBridgebust.html
EAS April 25, 2011
Description not set
Boiler Bytes: Purdue Cycling Club
The Purdue Cycling Club is composed of both undergrad and graduate students who desire to become better cyclists. http://www.purdue.edu/cycling
Boiler Bytes: Students reach out to the community through Pete's Pals
Helping children is what Purdue students strive to do with every session of Pete's Pals, a physical activity program for children with disabilities sponsored by Purdue's Department of Health and Kinesiology. http://www.purdue.edu/newsroom/purduetoday/general/2010/101203_PetesPals.html
Purdue Engineering - Dreams Need Doing
Student recruitment video from Purdue's College of Engineering
5 Students: A Sustaining Force
David Perkis can sum up his inspiration in a word: sustainability. After earning a degree in chemical engineering, he worked in corporate America for five years. During those years, his understanding of economics grew and he discovered his passion for sustainability. http://www.purdue.edu/fivestudents/policy/perkis.html
2011 Purdue evGrandPrix
The evGrandPrix is an outgrowth of the Indiana Advanced Electric Vehicle Training and Education Consortium (I-AEVtec), which is developing degree and training programs for the electric-vehicle industry. Some of the karts are built as part of class work developed through I-AEVtec.
Take a class in Toy Design
Toy Product Design is a new class that is a fun introduction to product design. At the start of the course, students are grouped into four teams. Each team brainstorms lots of ideas and then narrows those to a handful to present in the form of poster sketches. These prototypes are presented at Creative Kid Stuff headquarters to designers, marketers, and engineers. With their feedback, the four teams each pick one concept and has a month to make a polished prototype for the final "Playsentations"
Grant - 60 Second Impressions, Sutton Trust Summer Schools
The Sutton Trust Summer Schools are subject-specific residential courses for Year 12 students from UK state-maintained schools, which aim to provide an insight into life as a first-year undergraduate studying at the University of Cambridge. Archaeology & Anthropology, Medicine, Modern & Medieval Languages and Physics... these are just a few of the subjects which prospective students can sample at the Sutton Trust Summer Schools in Cambridge. In this 1 minute film, Grant, a student on the Law Su
Royal items in McMaster's archives
Carl Spadoni, director of the William Ready Division of Archives and Research Collections , talks about royal items found at McMaster, including an address given at the marriage of Prince Charles and Princess Diana.


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Headrest Printer Mounts - LEM Solutions
LEM Solutions has solved the "where do you put it" question with its patented...
Havis-Shields interior window bars have a welded one-piece frame consisting of 10 vertical bars. The frame is custom designed to fit most popular police cruiser window partitions. The bars allow for quick installation and window accessibility for cleaning.
For more information, click here
Request information about this product
Tags: Havis-Shields, Vehicle Accessories, Partitions


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Texas' Coastal Bend
Make your way around the Gulf of Mexico -- from the large port cities of Corpus Cristi and Gavelston to South Padre Island on the southernmost tip of Texas.
South Padre Island
South Padre IslandDon't let this scenic view fool you, South Padre Island is spring break central and a popular year-round vacation spot due to its sub-tropical climate. It's by far the most bustling spot along the gulf with countless resort hotels, condo towers, retails shops and restaurants. 960 1280
You Might Also Like
Pier 19 Restaurant and Bar, South Padre Island
Pier 19 Restaurant and Bar, South Padre IslandOn South Padre Island, Pier 19 Restaurant and Bar is a restaurant specializing in fresh, wild-caught seafood. Go here to enjoy delicious meals, drinks and the beautiful ocean views. 960 1280
South Padre Island, TX
South Padre Island, TXSouth Padre Island, located off the coast of Texas, is one of America's hottest spring break destinations. 960 1280
Schlitterbahn Beach Waterpark, South Padre Island
Schlitterbahn Beach Waterpark, South Padre IslandSchlitterbahn Beach Waterpark, a 15-acre waterpark located on South Padre Island, hosts Ultimate Music Experience (UME) Spring Break. This 3-day music festival is popular amongst spring breakers who enjoy electronic dance music. 960 1280
Holiday Inn Resort, Panama City Beach
Holiday Inn Resort, Panama City BeachThe Holiday Inn Resort is the No. 1 hotel for spring break in Panama City Beach. More than 250,000 people enjoy beachfront access and a variety of daylong activities and entertainment. 960 1280
Club La Vela, Panama City Beach
Club La Vela, Panama City BeachLocated on Panama City Beach, Club La Vela is the largest nightclub in the US and it has it all. Experience the ultimate party in the Club's multi-level theme rooms, the rock arena for live entertainment or party on the deck of the beachfront pool. 960 1280
Panama City Beach, FL
Panama City Beach, FLLocated on the Gulf Coast of Mexico, Panama City Beach is known as the "Spring Break Capital of the World." The city's white-sand beaches and variety of entertainment attracts more than a half a million spring breakers each year. 960 1280
Spring Breaking Point Pictures 10 Photos


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Teen bride Courtney Stodden covers up with some strategically placed Christmas presents during a December 2012 photo shoot in Los Angeles.
Kendall and Kylie Jenner both just stepped out in crop tops. Who wore it better? Check out the pics below!
It's no secret that Ryan Reynolds is ridiculously good-looking.
Taylor Swift might not approve…


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Stock Photo:
Stack of wooden 2X4s on white background with copy space.
- Image ID: 52520335
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High quality images curated from over 150 countries.
Over 50 million photos, vectors, illustrations, and more.
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Telephone & Addresses
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Tamara McCoy (Age: 31)
89117 Las Vegas NV
Tamara McCoy
63026 Fenton MO
Tamara McCoy (Age: 36)
60652 …go IL
Tamara Mccoy, Atlanta, US, Sims St SW
View Tamara's social profiles and photos on Facebook, MySpace, and +40 Networks.
Yellow Page contacts
Network Profiles
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Joshua & Tara - wedding website by mywedding.com
Austin is the son of Toby and Tamara McCoy. He is a very intelligent young man with a bright future. I love him so much and am proud that he is going to be ...
Valerie Hartzell, guitarist, and Tamara McCoy, pianist, in ...
Valerie Hartzell, guitarist, and Tamara McCoy, pianist, in Recital - Your source for local - Classical events in Anchorage, AK.
Tamara Mccoy's Online Resume - ResumeBucket
Tamara Mccoy. Ga 30241. H-. M- Education : High School. Previos Employer: 11/22/1999 - 5/13/2010. Walmart Distribution. 355 Callaway Ch Rd. Ga 30240.
HELLO. - tamara mccoy. - Cargo
Tamara McCoy / Minnesota-based designer and creative.
Management & Stakeholders
Tamara Mccoy | Nordstrom Inc. | Email @nordstrom.com
Tamara Mccoy is the IT Manager of Nordstrom Inc.. Lead411's profile includes an email address, @nordstrom.com, linkedin, biography, etc.
Business Profiles
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patentbuddy: Tamara J McCoy
Clark Fork, ID, US
Private Homepages
Recent work / Tamara McCoy-Carroll | SITUATIONS
Recent work / Tamara McCoy-Carroll
Tamara McCoy Twitter Stats & Rankings (tttam) | Twitaholic.com
Stats & Rankings for Tamara McCoy. Tamara McCoy @tttam. hi, i'm tam. i ... See even more detailed Tamara McCoy Twitter stats at Twitter Counter. Want to be ...
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ratemyteachers: Tamara McCoy
Elkridge, MD, Bellows Spring Elementary School
classmates: Tamara Mccoy
East Orange High School, East Orange, NJ, 1994-1998
classmates: Tamara Mccoy
Montezuma Cortez High School, Cortez, CO, 1993-1997
classmates: Tamara Mccoy
Fox High School, Arnold, MO, 1991-1995
Celebrities & Politicians
IMDB Filmography: Tamara McCoy
Actress, Cleveland in My Dreams
Bad news
Tamara Mccoy - JustMugshots.com
Tamara Mccoy was arrested about 1 year ago on August 16, 2013 in Lynchburg, Virginia. Share on facebook Share on twitter Share on email ...
Ralph McCoy - Legacy.com
Ralph is survived by his wife, Tamara McCoy. No services will be held at this time. Remembrances and condolences may be shared with the ...
Maurice Cook Obituary - Johnson Funeral Home | Jacksonville NC
Obituary for Maurice Cook, Maurice Junior Cook, 83 of Jacksonville, passed away early Thursday morning at his residence. He was preceded in death by his...
Maurice Cook Obituary: View Maurice Cook's Obituary by Jacksonville...
Maurice Junior Cook, 83 of Jacksonville, passed away early Thursday morning Feb. 13, 2014, at his residence. He was preceded in death by his brother, Bevan...
Books & Literature
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Little Faith, Medium Faith, Mega Faith by Tamara McCoy ...
Available in: Paperback. FREE SHIPPING on orders of $25 or more. Little Faith, Medium Faith, Mega Faith by Tamara McCoy.
adlibris.com: tamara mccoy - böcker | Adlibris Bokhandel – Alltid billigt
Köp billiga böcker som matchar tamara mccoy i Adlibris Bokhandel. Little Faith, Medium Faith, Mega Faith av Tamara Mccoy,
Tamara McCoy - Goodreads
Tamara McCoy is the author of Little Faith, Medium Faith, Mega Faith (0.0 avg rating, 0 ratings, 0 reviews, published 2012)
Angus & Robertson
Search results for null on Angus & Robertson
Related Documents
ACC Stakeholder Meeting Notes RCCO 2 April 23, 2014.pdf
Brown, Sunrise Coumm, Tamara McCoy, Tammy Herbert, Tanya, Terri, Todd Lessley, Todd Solar, Veronica Martinez. ITEM #. ISSUE.
April 23, 2014 - Virtual Community for Collaborative Care
Tamara McCoy. North Range Behavioral Health. Michael McCormick. North Range Behavioral Health. Crystal Day. Rehabilitation and Visiting ...
September 19, 2012
Sunrise Community Health. Larry Pottorff. North Range Behavioral Health. Kendall Alexander. North Range Behavioral Health. Tamara McCoy.
RITA | ITS | Evaluation Summaries Regional Coordination Workshops...
Tamara McCoy - good overview; Rex Knowlton knowledgeable, thorough and amusing; Intro presentation OK. Wheels presentation "case study" very interesting and is
Woolly Owl Hat Pattern - Slugs on the Refrigerator
Posted by: Tamara McCoy | November 17, 2011 at 10:54 PM. Tiffany Milorey. Hi! Having trouble with the download. firstname.lastname@example.com ...
Video & Audio
ms tamara mccoy - YouTube
ms tamara mccoy. by MSTAMARAMCCOY; 52 videos; 4 views; 3 hours, 14 minutes. Play all. Share. Loading... Save. Sign in to YouTube. Sign in · Play next; Play ...
Tamara McCoy on Vimeo
Tamara McCoy is a member of Vimeo, the home for high quality videos and the people who love them.
Tamara Mccoy - YouTube
Tamara Mccoy. Videos · Playlists · Discussion · About. What to Watch. Best of YouTube ... Tamara Mccoy. SubscribeSubscribedUnsubscribe 0. Subscription ...
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Lions tight end Brandon Pettigrew on tornado victims: Could ...
Pettigrew said his fiance, Tamara McCoy, grew up on the south side of Oklahoma City, near Moore, the city hit hardest by the first tornado.
Tamara McCoy, of 1 Roy Kent Circle, Asheville, N.C.. Docket. Korff Holdings LLC dba Quaker City Castings v. Clear Energy Systems Inc., ...
Honor Rolls - Page 6 - Daily Press
... Tamara McCoy, Kerry McLean, Tiffany McPadden, Tina Montange, Sarah Moore, Yvonne Moorer, Gregory Morgan, Kelly Morgan, Michelle Moseley, Stephanie Nelson,
Valerie Hartzell, guitarist, and Tamara McCoy, pianist, in ...
Upcoming Anchorage Events: get information about Valerie Hartzell, guitarist, and Tamara McCoy, pianist, in Recital, including maps and ...
Reports & Statements
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je parle franglais.
October 24, 2011. 4 notes · Quote of the weekend. by jemappelletam on Flickr. Tags: typography design Kanye West Tamara McCoy quote · Photo. October 24 ...
Tamara McCoy (mare_bear315) on Instagram | iPhoneogram
Good game tonight guys. We are all so proud of what you have accomplished this year. You had an amacing season boys. We love you. View in Instagram web ...
tamara mccoy - Topix
tamara mccoy. Posted in the Burkesville Forum. Leave a Comment Track Replies. Comments. 1 - 17 of 17 Comments Last updated Oct 10, ...
tamara mccoy | ^^^ THINGS I FOUND (at the thrift store ...
Posts about tamara mccoy written by thingsifoundatthethriftstore.
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A Place For Artists: Tamara McCoy | Indie College
Indie College is happy and lucky to feature Tamara McCoy, a Minnesota-based artist and designer. She is truly a creative soul and all-around ...
Tamara McCoy-Carroll's stream on SoundCloud - Hear the ...
Tamara McCoy-Carroll hasn't shared any public sounds. Follow Tamara McCoy-Carroll for updates of their new sounds.
Tamara Mccoy - Baby Registry
Tamara Mccoy from Anchorage, AK has registered at Kohl's Little Ones and Target Baby for their baby expected on April 29, 2014. View all of ...
tamara mccoy - Mugshots-Directory: all records in one place
TAMARA MCCOY from GA was allegedly arrested on 2009-04-28 0:00 am in GA at the Fulton County Sheriff's Office. Released.
Tamara McCoy - Fundly
Tamara McCoy is fundraising for a cause on Fundly. Support or follow Tamara McCoy's personal fundraising campaigns today.
Tamara McCoy | #23 | F | Lorain County Community College ...
... Championship | Games Wanted/Needed | Championship Bid Information | Stat Archives. Tamara McCoy | #23 | F | Lorain County Community College. gp, pts/ ...
28 - Class of 1992 (Miami Killian Senior High School)
View profile »Edit profile »Tamara McCoy (Hudson). newnan, GA. Comments. Hey there!! Let the parties begin!!! Send an email to this cougar · View profile »Edit ...
Citizens of the Month
... Breyana Lilly, Tamara McCoy, Jonah Parsons, Nick Pinero, Kristina Rivera, Karina Rosso, Josh Senquiz, Clinton Simmons, Sean Sullivan, Megan Thurman, ...
Franklin Elementary School: School Site Council
Jean-Louis Robadey Julia Tang Orsi Teodorovic. Staff. Lisa Booth, Principal Jen Cibula Lori Guidi Tamara McCoy. Mary Ann Waterman ...
High School Students Monitor Water Quality with MDE
Senior Tamara McCoy lowers a secchi disk to test for water clarity. Taneara Engam, a junior at Digital Harbor High, charts the results of water quality.
LADWP Town Hall in the West Valley - Councilmember Bob ...
Tamara McCoy. David Uebersax. David Johnson. Brian St. Germain. Julia Wells. Maurice Pinto. Merrick Davidson. Cr Cochrane. Ghislaine Brassine. Royle Birk.
MCAD Emerging Talent Showcase
nicholasdahl.tumblr.com. Alexander Grimm email@example.com. Tamara McCoy email@example.com cargocollective.com/tamaramccoy.
Ralph McCoy - Sellergren-Lindell-DeMarce Funeral Home
He was preceded in death by his parents, Robert and Ellen McCoy. Ralph is survived by his wife, Tamara McCoy. No services will be held at this time.
Richmond to host amateur boxing event Saturday ...
For more information, contact Tamara McCoy-Walker at 510-621-1226. | "Richmond's Finest," an amateur boxing exhibition. The allures of gang ...
School Staff | Bryant Woods Elementary School
Kourtney Proctor | Math Interventionists | firstname.lastname@example.com | Website. Tamara McCoy | Math Interventionists | firstname.lastname@example.com | Website ...
Singer Profiles - Bel Canto Alaska
Tamara McCoy. TAMARA MCCOY – Dr. Tamara McCoy began her piano studies at the age of five in her hometown of Anchorage, Alaska. She is a prize winner ...
Staff and Board - Anchorage Unitarian Universalist Fellowship
Rosene Beachy, Director of Lifespan Religious Exploration, email Rosene. Tamara McCoy, Music Director, email Tamara. Vacant, Choir ...
Sylvia Sue Smith - Wclu
... Rickey (Pete) , David and Tamara McCoy and 28 great grandchildren. Two sisters Dina Smith of Edmonton and Earlene Smith of Eunice, Ky.
Valerie Hartzell - Photos
Sunday, March 9th at Anchorage Lutheran Church with long time friend, Tamara McCoy. NOW I can relax. After concert get together. Apparently Armin was ...
Virginia Obituary and Death Notice Archive - Page 1216
... a special caregiver, Greta Reynolds; grandchildren Kathy Cox and Mrs. Thaddeus (Vickie) McCoy; and a great-grandchild, Tamara McCoy.
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More New and Used
from Private Sellers
Happy Birthday, Baby!by DR SEUSSGERARDI, JAN
Nonspecific Binding
Random House Books for Young Readers
The Great Birthday Bird says, "Hop to it! Get dressed! Today is your day. It's the Best of the Best!" Based on Dr. Seuss'sHappy Birthday to You!, this fun-filled interactive book has elements to touch, move, and smell. Presented in the original book's spiffy color palette of yellow and red,Happy Birthday, Baby!helps babies and toddlers celebrate their day of all days with the Great Birthday Bird and everybody else! Dr. Seuss is quite simply the most beloved children's book author in the world.


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Can Data Infrastructure Vendors Stop Hackers?
A group of prominent technology vendors are teaming to offer a highly secure data infrastructure built on Security-Enhanced Linux.
A group of technology vendors at last week's GEOINT 2015 conference demonstrated a data infrastructure they claim could stop hackers in their tracks. The Multilevel Secure System (MLS) combines technology … more »


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CHRIST Church's Wonderful Ministries - Ministry Videos
Embed hmong4life 1329 views 2010-10-02T02:04:27 Christian Hmong Regeneration In Spiritual Transformation: CHRIST Church has been blessed with many wonderful programs and ministries. Under the pastoral guidance of Rev. Denice Dluabci Leslie and Rev. Paul Joseph T. Khamdy Yang, lives are changed and the Good News of Jesus Christ is proclaimed.
More Ministry Videos
- Young Girl Leaves The Judges In AWE With Broadway ClassicInspirational Videos
- Veritas - An American Anthology (Official Lyric Video)Music Videos
- Christianity.com: Does the Bible teach that a Christian can be a practicing homose...Education Videos
- When They Saw This Old Woman Sit At The Piano No One Expected THIS. Hang On Tight!Inspirational Videos
- Bluegrass Version Of 'How Great Thou Art' Will Take You BackMusic Videos
- 16-Year-Old's Version Of 'Believe' Moves Judges To TEARSMusic Videos
- Christianity.com: Why do Christians advocate obeying the laws of Leviticus regardi...Education Videos
- Powerful Performance of 'Hallelujah' by Bon JoviMusic Videos
- Clap Along With This 'HAPPY' Christian Remix – You Can't Help But Smile!Music Videos
- Hilarious Comedian Jeanne Robertson Tells Us Why Older People Shouldn't Bungee Jum...Comedy Videos
- Country Girl Gives Goosebumps With 'How Great Thou Art'Music Videos
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Words formed when one letter is changed in clove
Letter 1 (C) changed: 1 word found:
No words found when changing letter 2 (L).
Letter 3 (O) changed: 1 word found:
Letter 4 (V) changed: 3 words found:
No words found when changing letter 5 (E).
A total of 5 words can be formed from clove by changing one letter.
Some random words: ajiva eager gift kea up gude oar
This is not a dictionary, it's a word game wordfinder.
- Help and FAQ - Examples - Home
Privacy Policy - Share - © Copyright 2004-2015 Morewords.com - 85.445mS


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Ready to hear the dumbest thing ever said about social media?
The central point here is whether Twitter and Facebook, as publishers of content, should be as accountable as traditional media. The problem is one of scale. Traditional media controls its content by employing finite numbers of staff, freelance journalists and news agencies. In contrast, Facebook have an army of "citizen journalists" numbering 500 million and Twitter 175 million and don't employ any of them.
Clearly, they are going to have to introduce a delay mechanism so that content can be checked before it goes up. There will have to be a completely different structure, which will be difficult when the whole thing about Twitter is its spontaneity.
[...]Twitter and Facebook are not blank sheets of paper. They are media publishers like any other. Social networking at the moment is like a pioneering goldrush; a real land grab. We have to get some sort of international arbitration set up, which the Americans would need to be involved in, and quickly.
Those are the words of words of the UK's self-proclaimed leading business and public relations consultant, Richard Hardgrove.
We suspect his hat may be "In this style 10/6." He is seriously calling for social media sites like Twitter and Facebook to put up a filter between the users and the Tweet button.
While he is correct that these sorts of sites are becoming important ways for people to spread news and other information traditionally left up to mainstream media, such as newspapers and television, his proposal is simply insane. Not only would it be virtually impossible to implement any sort of review process, it would undo the good these media have provided.
"Citizen journalism" has taken off specifically because there is no such filter. There is no editor in chief saying "this isn't news worthy" or "this might offend our readers and sponsors." The lack of any filters does result in a lot of idiocy, and plainly false stories being spread (Camping always said the world would end in October, this isn't changing his story; May 21st was judgment, not sentencing, so stop posting that damn story all over my Facebook wall).
But, these sites have also exposed holes in the mainstream media. Stories that would otherwise go untold show up on blogs. Ideas that can't fit into a 30 second clip are fleshed out, even if they do compete with space about news of what your puppy had for lunch. The last thing we need is for social media to become more like mainstream media. Even the mainstream media has noticed this, increasingly turning to blogs and ordinary folks for reporting.
Thankfully though, the Americans have already spoken on this issue. Section 230 of the Communications Decency Act protects service providers from liability for things their users say. This goes from your ISP all the way up to the person who owns an unmoderated forum. We also have those pesky things called Freedom of Speech, Freedom of the Press, and possible even the Freedom of Assembly applies.
Individual speakers can still be held accountable, but trying to make Twitter responsible for every single Tweet is like making a bar tender responsible for every dumb thing said by a drunk patron.
On the other hand, Hardgrove does have a pretty fetching wife. If that's what having idiotic ideas gets you, then might we suggest that Facebook be required to purchase a business license for every city and county in which there is at least one Facebook user.


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Currently browsing "National Institutes of Health (NIH)"
Funding Opportunity: NIH "Strengthening the Biomedical Research Workforce" Program
The NIH Common Fund's Strengthening the Biomedical Research Workforce program announces a new Funding Opportunity to solicit applications for the Broadening Experiences in Scientific Training (BEST) awards. ... More>
OppNet Announces its First FY2014 RFA
The NIH's Basic Behavioral and Social Science Opportunity Network, announces its first FY2014 RFA: Short-term mentored career enhancement awards in the basic behavioral and social sciences: Cross-training at the intersection of animal models and human investigation (K18: RFA-DA-14-002). ... More>
Presidential Column
Small Investment, Big Returns
By most measures, we are living in the golden age of the social and behavioral sciences. Despite the modest amount and portion of funding it receives and its relevance and impact on human problems and potential, the behavioral and social sciences have many powerful critics, especially some members of Congress. ... More>
APS Fellow Nakamura to Direct the NIH's Center for Scientific Review
National Institutes of Health Director announced that APS Fellow and Charter Member Richard Nakamura will be the new director for the NIH's Center for Scientific Review (CSR). Nakamura has been serving as the acting director since September 2011. ... More>
Changing Our Environment Can Change Our Diets
Brian Wansink of Cornell University explains how what is happening around us influences the way we eat. ... More>


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MCLEAN, Va.—Hilton Worldwide has announced the signing of a management agreement with CAB, S.A. to operate the new build Hilton Garden Inn Port-au-Prince Louverture Airport. Scheduled to open in 2016, this new Hilton Garden Inn hotel in Haiti will introduce ...Read More »
Tag Archives: Hilton Garden InnFeed Subscription
Hilton Garden Inn Portland Airport Completes Expansion
PORTLAND, Maine—Hilton Garden Inn Portland Airport has announced the completion of its lobby renovation. As part of the renovation, a 36-room expansion, including two large junior suites, was added to the existing 88-room hotel. Additional improvements will continue with upgrades ...Read More »
RLJ Lodging Trust Sells Additional Hotel for $15.7 Million
BETHESDA, Md.—RLJ Lodging Trust has sold the 150-room Hilton Garden Inn St. George in St. George, Utah, for approximately $15.7 million or $104,300 per key. The sale price represents approximately an 8.7 percent capitalization rate on the hotel's 2013 net ...Read More »
Hilton Garden Inn Brand Heading to Brazil
MCLEAN, Va.—Hilton Worldwide announced plans to open the first Hilton Garden Inn in Brazil. The company signed a management license agreement with HDauff Empreendimentos Imobiliarios Ltda to operate the new Hilton Garden Inn hotel in São Jose do Rio Preto, ...Read More »
Chesapeake Hospitality Assumes Management of Two Sarasota Hotels
GREENBELT, Md.—Chesapeake Hospitality announced that it has taken over management of the Hilton Garden Inn Sarasota-Bradenton Airport and the Hampton Inn Sarasota I-75 Bee Ridge, both located in Sarasota, Fla. Kim Sims, president of Chesapeake Hospitality, made the announcement. "Chesapeake ...Read More »


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MS ME, Mechanical Engineering
Master of Science (MS) in Mechanical Engineering
The Mechanical Engineering program is designed for students who desire advanced training in areas of mechanical engineering such as acoustics, automatic control systems, biomechanics, fluid mechanics, noise control, nonlinear dynamics, MEMS and nanotechnology, robotics, structural mechanics, theoretical fluid dynamics, thermal processes, turbulence, vibrations, and wave propagation. Graduates may work in an industrial or governmental laboratory, or continue their training toward a doctoral degree in mechanical engineering, applied mechanics, or a related field.
Structured Course Requirements for MS in Mechanical Engineering
The 32 credits must be selected as follows:
- 3 courses (12 credits) must be Mechanical Engineering Core Courses
- 2 courses (8 credits) must be Engineering/Science electives (any 500/700 level engineering or physical science course, with no more than one course from the approved list of Engineering Management Courses)
- Mathematics requirement (4 credits) selected from an approved list (500 & 700 level only)
- Thesis credit requirement (8 credits)
Mechanical Engineering Core Courses
ME 501* Dynamic System Theory
ME 503 * Kinetic Processes in Materials
ME 504 * Polymers and Soft Materials
ME 505 * Thermodynamics and Statistical Mechanics
ME 508 * Computational Methods in Materials Science
ME 507 * Process Modeling and Control DL
ME 508 * Computational Methods in Materials Science
ME 510 * Production Systems Analysis DL
ME 514 * Simulation
ME 515 * Vibration of Complex Mechanical Systems DL
ME 516 * Statistical Mechanical Concepts in Engineering
ME 519 Theory of Heat Transfer
ME 520 * Acoustics I DL
ME 521 * Continuum Mechanics
ME 522 Underwater Acoustics
ME 523 * Mechanics of Biomaterials
ME 524 * Skeletal Tissue Mechanics
ME 526 Simulation of Physical Processes DL
ME 529 Thermodynamics and Kinetics of Materials and Processes
ME 531 Phase Transformations
ME 532 Atomic Structure and Dislocations in Materials
ME 534 Materials Technology for Microelectronics DL
ME 541 Classical Thermodynamics
ME 542 * Advanced Fluid Mechanics
ME 544 Networking the Physical World
ME 545 * Electrochemistry of Fuel Cells and Batteries
ME 555 * MEMS: Fabrication and Materials DL
ME 560 * Precision Machine Design and Instrumentation DL
ME 570 Robot Motion Planning
ME 579 * Microelectronic Device Manufacturing DL
ME 580 Theory of Elasticity
ME 581 Experimental Techniques in Solid Mechanics
ME 582 * Mechanical Behavior of Materials
ME 702 Computational Fluid Dynamics
ME 704 Adaptive Control of Dynamic Systems
ME 706 Acoustics and Aerodynamic Sound DL
ME 707 * Finite Element Analysis
ME 709 * Turbulent Flows
ME 710 * Dynamic Programming and Stochastic Control
ME 713 Viscous Flows
ME 714 * Advanced Stochastic Modeling and Simulation
ME 715 * Waves in Fluids
ME 718 Advanced Topics in Nanotechnology
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|Reviews for Lucky Star Truth or Dare!
| Guest chapter 20 . 2/19
Okay, I know I'm going to regret asking this but what the hell is "kitchen film"?
| konohinamoto chapter 15 . 7/11/2013
| Gnarled Bone chapter 22 . 5/13/2013
I am dense. Oblivious. Whateves. I need to pay more attention to the color of people's hair. :P
Awesome fic (just going to say that instead fo getting into all the details; I'm tired). I am now going to click "Next ".
| Sqweebs chapter 10 . 1/10/2013
That was just... Awkward... And hot... But awkward.
| Sqweebs chapter 9 . 1/10/2013
I don't know what's more disturbing, the fact that Sojiro is staying at a love hotel, or the fact that he's staying at the same one as his daughter.
| Sqweebs chapter 8 . 1/8/2013
:O someone DID beat me to the idea of using one of the character songs in a fanfic! Dang you!
| Sqweebs chapter 5 . 1/8/2013
A shaken not stirred glass of milk . Konata stop referencing James Bond, you're too small to be an action hero, especially one who orders milk.
| Sqweebs chapter 3 . 1/8/2013
I'll send you a love letter Tsukasa... :3 don't worry, you wouldn't have to lick chocolate off my face... :3
| Gigarot chapter 24 . 6/2/2012
Later I will do a full review of this, but for now I want to say:
The things I like most:
-Kagami singing 100% nai nai nai
-The references to 100% D Drive Kagamin, KonaKaga by Eunos, Niwakaame, etc.
-The tribute to Level Up! Love!
And 2 important errors:
-The trip is impossible to be in November, the anime ended in the last days of November, and they've been playing Truth or Dare for weeks, it has to be in December.
-Kagami and Tsukasa are eighteen, their birthday was in July 7th
| bfl321 chapter 12 . 2/11/2012
aw man, do you have the dare list by any chance?
| Lky str fanatic chapter 1 . 9/8/2011
Very entertaining but I've just noticed 1 slight flaw: what would be so bad to them about seeing Kagami's skirt fall up? Anyone remember episode 6 of the anime? In the baths together completely on the buff so I can't imagine an upskirt being all that bad. But then again it took me ages to notice this and it was a realy good fanfic, great job :3
| Mao chapter 4 . 9/2/2011
Damn. I was hoping for non yuri
| Aerowind Kinomoto chapter 5 . 9/1/2011
Sorry to say, but you're translating a foreign word. It's cornet, and they're from Italy.
| Tiana Koopa chapter 25 . 7/17/2011
This was a really good story!
| Shawn45 chapter 25 . 5/23/2011
Never thought I'd read a Truth of Dare story and actually like it, but here we are. I just finished watching the Lucky Star anime, and this is the first fanfic I have read of it, and I really liked it. Is it true that Konata/Kogami isn't canon? Seriously? I got a big vibe that they were at least interested in one another, that kind of makes me sad to learn that it's only one-sided. Oh well, in my fanon, they will be interested in one another!
As for the story itself I was surprised that you managed to make a nice length story involving Truth or Dare. Usually people make one or two crack chapters of the idea, and then abandon the story. I liked the pairs as well, and how they was developed throughout the story. Though I really got annoyed by Konata forgetting about the incidents she had with Kagami, it felt like a cheap story device to make their subplot last longer. Also, I was positive that you were going to make Miyuki and Tsukasa be together, given how they always paired up to do things together. As for the other pairings, Yutaka and Minami is practically a given, with the Patricia and Hiyori being unexpected, but interesting.
The truths and dares themselves though were a lot of fun, especially in the beginning. I agree with Kagami though, it was starting to get old by the end, but I loved how Konata used it to admit her feelings to Kagami, and vice versa.
Overall, this was a very satisfying story, it'll definitely go onto my favorites. Thanks for the good read, and I just noticed that there's a sequel - thank god, I wanted more Konata/Kagami of when they are an actual couple, because that was adorable, hehe.
Keep up the great work!


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Every month students will be notified electronically via Springfield College email that the bill is ready to be viewed. This is the only address the email notification will be sent to.
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Live with Courage, Love with Faith, Laugh with Hope™ Necklace
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The encouragement that winds along our intriguing mobius strip continues along a single unending plane, just as your courage, faith, and hope never run out during your most difficult times. A lovely talisman of hope and celebration of life.
- Silver-tone & cotton cord
- Hand-painted
- Reads: "Live with Courage, Love with Faith, Laugh with Hope™"
- Pendant: 1.5" H x 1.25" W (3.8 x 3.2 cm)
Black cotton cord: 15" L (38.1 cm) with a 4" L extender (10.2 cm)
- Imported
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September 30, 2014 - I love this neckless BUT I had to go online to read what it said. I found it nice when I ordered it - and uplifting BUT when I got them (Ordered 5) I could not read the print well. MAY SEND A CARD ALONG THAT TELLS OWNER WHAT IT SAYS.
April 28, 2014 - I love this necklace! I redid the cord so that it wasn't doubled up and to make it longer so it easily slips over my head and hangs down lower than in the picture. It is perfect!
February 15, 2014 - Love the size and for the price, the quality of the silver. I don't like the black cord, however, and have replaced it with a silver one. I added my deceased husband's wedding ring to hang beautifully in the center.
March 12, 2013 - I think this is very beautiful. Writing is small of course and the rope has been folded a little too long and will take some time wearing to iron out but it is very gorgeous and very reasonably priced.
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Environmental Toxicology
Discrepancy between acute and chronic toxicity induced by imidacloprid and its metabolites in Apis mellifera
Article first published online: 3 NOV 2009
DOI: 10.1002/etc.5620201113
Copyright © 2001 SETAC
Environmental Toxicology and Chemistry
Volume 20, Issue 11, pages 2482–2486, November 2001
Additional Information
How to Cite
Suchail, S., Guez, D. and Belzunces, L. P. (2001), Discrepancy between acute and chronic toxicity induced by imidacloprid and its metabolites in Apis mellifera. Environmental Toxicology and Chemistry, 20: 2482–2486. doi: 10.1002/etc.5620201113
Publication History
- Issue published online: 3 NOV 2009
- Article first published online: 3 NOV 2009
- Manuscript Accepted: 19 MAR 2001
- Manuscript Received: 3 AUG 2000
- Abstract
- Article
- References
- Cited By
- Imidacloprid;
- Metabolite;
- Honeybee;
- Chronic toxicity;
- Acute toxicity
Imidaclopridi a systemic nitroguanidine insecticide that belongs to theneonicotinoid family. As an agonist of the acetylcholine receptor, it attacks the insect nervous system and is extremely effective against various sucking and mining pests. Oral acute and chronic toxicity of imidacloprid and its main metabolites (5-hydroxyimidacloprid, 4,5-dihydroxyimidacloprid, desnitroimidacloprid, 6-chloronicotinic acid, olefin, and urea derivative) were investigated in Apis mellifera. Acute intoxication by imidacloprid or its metabolites resulted in the rapid appearance of neurotoxicity symptoms, such as hyperresponsiveness, hyperactivity, and trembling and led to hyporesponsiveness and hypoactivity. For acute toxicity tests, bees were treated with doses of toxic compounds ranging from 1 to 1,000 ng/bee (10–10,000 μg/kg). Acute toxicity (LD50) values of imidacloprid were about 60 ng/bee (600 μg/kg) at 48 h and about 40 ng/bee (400 μg/kg) at 72 and 96 h. Out of the six imidacloprid metabolites tested, only two (5-hydroxyimidacloprid and olefin) exhibited a toxicity close to that of imidacloprid. Olefin LD50 values were lower than those of imidacloprid. The 5-hydroxyimidacloprid showed a lower toxicity than imidacloprid with a LD50 four to six times higher than that of imidacloprid. Urea also appeared as a compound of nonnegligible toxicity by eliciting close to 40% mortality at 1,000 ng/bee (10,000 μg/kg). However, no significant toxicity was observed with 4,5-dihydroxyimidacloprid, 6-chloronicotinic acid, and desnitroimidacloprid in the range of doses tested. To test chronic toxicity, worker bees were fed sucrose solutions containing 0.1, 1, and 10 μg/L of imidacloprid and its metabolites for 10 d. Fifty percent mortality was reached at approximately 8 d. Hence, considering that sucrose syrup was consumed at the mean rate of 12 μl/d and per bee, after an 8-d period the cumulated doses were approximately 0.01, 0.1, and 1 ng/bee (0.1, 1, and 10 μg/kg). Thus, all tested compounds were toxic at doses 30 to 3,000 (olefin), 60 to 6,000 (imidacloprid), 200 to 20,000 (5-OH-imidacloprid), and >1,000 to 100,000 (remaining metabolites) times lower than those required to produce the same effect in acute intoxication studies. For all products tested, bee mortality was induced only 72 h after the onset of intoxication.


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Cardiff Hotels - It may be a capital city, but Cardiff is as renowned for its sweeping green spaces as it is for its cosmopolitan buzz – the emerald acres of Bute Park in the heart of the city are wonderful to wander on a sunny day. Cardiff is also a shopping mecca, thanks to the immense St David's complex which is full of high street and high-end stores, not to mention the atmospheric Edwardian and Victorian arcades with their quaint boutiques and craft shops. The nightlife here is also famous – party animals should head for Cardiff Bay, a glittering hive of bars and restaurants overlooking rippling waters. Things to see Almost surreally situated amid the shops and cafes of the city center, Cardiff Castle encompasses almost 2,000 years of history. Venture within and you'll see old Roman walls, the Norman shell keep, the proud medieval towers, and jaw-dropping décor such as the honeycomb-like ceiling of the Arab Room. A more contemporary attraction is the Wales Millennium Centre – its huge coppery façade, inscribed with Welsh poetry in huge letters, is now a symbol of the city, and it's where you can catch blockbuster shows, stand-up comedy and opera. Sports fans will want to visit the Millennium Stadium, that cathedral of rugby and football, which has hosted everything from the FA Cup Final to Rugby World Cup. Famed as one of the main filming locations for Doctor Who, Cardiff also boasts the Doctor Who Experience, a fully interactive adventure where fans can enter the Tardis and come face to face with Daleks and Cybermen. Meanwhile, the world's biggest pop and rock stars regularly perform at the Motorpoint Arena – formerly known as Cardiff International Arena. Hotels in Cardiff Looking to push the boat out while visiting the Welsh capital? Then you're in luck, because there are a number of high-end hotels in Cardiff featuring luxury spa facilities, panoramic views of the bay and the city center, and Champagne bars. That said, there are also plenty of mid-level Cardiff hotels which offer stylish, air-conditioned rooms with free WiFi. The outskirts of the city and the bay area also feature quaint boutique hotels with antique furnishings and unique décor, while cost-effective bed and breakfasts can also be readily found near the city center. Where to stay With a few exceptions such as Roath Park lake (ideal if you fancy showing off your rowing skills), Cardiff is all about the city center. It's here that visitors spend much of their time, thanks to the endless array of shops and restaurants ready to be explored. Whether you're a business traveler, a family or a couple, you probably won't stray far from one of the prettiest urban centers in the country. That said, if you do feel like seeing more of South Wales during your stay, Bridgend is well worth checking out for its nightlife and beaches. How to get to For overseas visitors and those in more distant British cities like Edinburgh and Newquay, Cardiff International Airport is a very convenient way of getting to South Wales. If you're coming in by train, chances are you'll be arriving at Cardiff Central Station, which has direct connections with London, Bristol and other major cities, while Cardiff Queen Street Station has services to the Welsh Valleys and Bridgend Station. Getting around Cardiff itself is simplicity itself, as the city center can be easily explored on foot while there are regular buses to Cardiff Bay and the suburbs.
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Radisson Blu Hotel Cardiff
Excellent 4.4 / 5 ( 828 reviews )
461 people looked at this hotel in the last hour
Most recent review
"A room with a view indeed! We stayed on 20th floor with stunning views of the city. The room was spotless, the beds were the most comfortable we ever experienced in a hotel and the business class breakfast was amazing. On the down side, the coffee table in the room was broken, the carpet was rais..."
A Traveller, Jun 2015, GB
Mercure Cardiff Holland House Hotel & Spa
Excellent 4.4 / 5 ( 306 reviews )
379 people looked at this hotel in the last hour
Most recent review
"Ive been before on my daughter 2 evenings away it was 10 women it was great.thats why when our friends said about going to Cardiff we knew straight away where to go.it was walking distance to the town and motorpoint where we we're going one evening.looking to come back again in October or Nov..."
A Traveller, Jun 2015, GB
Novotel Cardiff Centre
Excellent 4.2 / 5 ( 675 reviews )
361 people looked at this hotel in the last hour
Most recent review
"We were so Happy about the stay. The room for 4 people could have been a little bigger."
A Traveller, Jul 2015, GB
Future Inns Cardiff Bay
Excellent 4.2 / 5 ( 921 reviews )
348 people looked at this hotel in the last hour
Most recent review
"a very nice hotel evening meal was excellent rooms quite an comfortable staff were t great only downside was trying to find it even with a satnav could do with a sign at the main and hemmingway rd junction thanks"
A Traveller, Jul 2015, GB
Park Plaza Cardiff
Excellent 4.4 / 5 ( 303 reviews )
322 people looked at this hotel in the last hour
Most recent review
"Close to town which was perfect as we were in town for a stag do. The place was nice and clean. Friendly and welcoming staff even if someone did check into my room that wasn't me. It was all sorted out within minutes. Amazing shower in the room too."
A Traveller, Jun 2015, GB
Park Inn by Radisson Cardiff City Centre
Good 3.8 / 5 ( 463 reviews )
284 people looked at this hotel in the last hour
Most recent review
"The hotel was very well situated but noisy, from inside and out. It would put me off staying again unfortunately. Breakfast was nothing to write home about."
A Traveller, Jun 2015, GB
Park Inn by Radisson Cardiff North
Excellent 4.0 / 5 ( 183 reviews )
186 people looked at this hotel in the last hour
Most recent review
"Me and two of my friends stayed for a weekend, we were all amazed at the welcoming and helpful staff. The room was lovely and excellent for the price we paid! We have said we will be returning to the park inn on our next trip to Cardiff."
A Traveller, Jul 2015, GB
Copthorne Hotel Cardiff-Caerdydd
Excellent 4.0 / 5 ( 385 reviews )
183 people looked at this hotel in the last hour
Most recent review
"We went for a long weekend. Hotel is ideal for Cardiff, Barry and Brecon Beacons. It's close to the M4, so it's easy to get to. We had a lovely stay but did have a bit of an issue with room service as they kept getting a fairly simple order wrong and then charged us incorrectly. However t..."
A Traveller, Jun 2015, GB
ibis Cardiff Gate
Good 3.9 / 5 ( 305 reviews )
131 people looked at this hotel in the last hour
Most recent review
"What a great hotel, it was inexpensive, very clean and modern, the room was comfy and it had free wifi (albeit a bit slow). It ticked all of my boxes and I have nothing negative to say about this hotel. Highly recommended."
A Traveller, Jun 2015, GB
Village Urban Resort Cardiff
Good 3.8 / 5 ( 224 reviews )
72 people looked at this hotel in the last hour
Most recent review
"Good hotel, shame no air conditioning in upper deck rooms"
A Traveller, Jul 2015, GB


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Our hotel is conveniently located just off the 680 in Pleasant Hill on Contra Costa Blvd and only 1 mile from Concord Downtown -Walnut Creek Downtown and Waterworld - Oakland is located just 16 miles away and San Francisco is located just 23 miles away - San Francisco is accesible by Bart Train Station which is conveniently located by the hotel
Located in the heart of the East bay of San Francisco in the quint city of Pleasant Hill. Conveniently located just off of Hwy 680. Great location for Business Travelers as well as leisure families who need a hotel to stay at while in the east bay area. Formerly a Best Western property.
999 Contra Costa Blvd Pleasant Hill CA 94523 Ph 925 687 8096Five Guys Burgers and Fries
100 Crescent Dr Ste 7a Pleasant Hill Ca 94523 Ph. 924 806 8400Thai Osha Restaurant
1968 Contra Costa Blvd Pleasant Hill Ca 94523 Ph 925 825 2148Bangkok Restaurant
1910 Oak Park Blvd Pleasant Hill Ca 94523 Ph 925 937 4368Chipotle Mexican Grill
60 Crescent Drive Pleasant Hill Ca 94523 Ph 925 825 2148Elephant Bar Restaurant
1225 Willow Pass Road Concord Ca 94522 Ph 925 671 0119La Tapatia Mexican Cuisine
1802 Willow Pass Road Concord Ca 94520 Ph 925 685 1985Chevys Fresh Mex
650 Ellinwood Way Pleasant Hill CA 94523 Ph 925 685 6651Matsu Sushi Japanese Restaurant
1914 Contra Costa Blvd Pleasant Hill Ca 94523 Ph 925 671 9972Back Forty Texas BBQ
100 Coggins Drive Pleasant Hill CA 94523-4419 Ph 925 935 1440Benihana Japanese Steakhouse
1989 Diamond Blvd Pleasant Hill Ca 94520 Ph 925 827 4220


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New Hyundai Santa Fe India launch on 5th Feb at 2014 Delhi Auto Expo
A full sized, seven seater Hyundai Santa Fe is slated for launch at the upcoming 2014 Auto expo in February. The launch date is confirmed for February 5, 2014, the first media day at the Delhi Auto Expo.
First introduced in late 2012, the 2014 Santa Fe is finally coming to India. Expected to undercut the much in demand Toyota Fortuner where pricing is concerned, the new Hyundai Santa Fe will be assembled at the company plant in Chennai. Hyundai Motor India Limited has already commenced CKD assembly at the Chennai plant with sales in India to be initiated by end February 2014.
Hyundai Santa Fe will be fitted with the same 2.2 liter diesel engine as seen on the current model though new Piezo injectors have been added for better efficiency and lower emissions. The motor is equipped with Variable Geometry Turbo offering peak power of 194 bhp and peak torque of 44.45 kgm while being mated to a six speed automatic transmission.
In a mail to Rush Lane, Hyundai stated, The launch of Santa Fe will take place at the 12th Auto Expo 2014, on 5th February 2014 at 8:40AM onwards at Hall No. 3, Stall E4, India Exposition Mart Ltd., Greater Noida.
Pearl Daniels
Email - [email protected]


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After a bit of a hiatus, News Shotgun is back to give you a rundown of the week's cool/interesting/exciting movie news. This week we learned that Universal Studios is closing another iconic ride, Manos is coming to Blu Ray and Starship Troopers is being remade.Full Story »
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LifeLong Learning Institute
LifeLong Learning Institute
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Originally written on NESN.com | Last updated 2/23/13
Mike Napoli may be slated to get the majority of the at-bats at first base, but there are a couple reasons it may make sense to have a dedicated backup. For one, though he's never suffered any symptoms from it, there's no telling when the degenerative condition in Napoli's hip may act up. Secondly, Napoli is probably best deployed in a platoon, taking most of his at-bats against lefties. But that's why the Red Sox brought Lyle Overbay and Mike Carp in to camp to compete for a job. Check out the video above to hear Carp's thoughts on being in Fort Myers with Boston.
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Favorite TV Dads of All Time
List Criteria: Favorite TV characters who were fathers. (Not necessarily guys who were the BEST fathers.)
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