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Okay, well. Thread number three on the same subject in a day. Oh well, here we go!
Princess Fantasy Faire? What are you, CRAZY!?!
I despise PFF (Sorry Princess lovers, nothing against you!). It takes up WAY too much space for such a limited attraction, which, in my mind, shouldn't even be an attraction. What happened to roaming characters, huh? Anyways, this plan would relocate the PFF to a smaller, more thematically-correct area: the old Fantasyland Skyway Chalet. Please remember, this is not my lain fantasy idea. I have made it as realistic as possible, and with Disney these days, that means including merch.
The Queue
The queue would follow up the old path (right-hand side). Once on top, the queue would go through switchbacks outside and inside the old building.
The Princesses
Of course, there would still be three princesses. However, the layout would change from the current one so that each princess has an "corner" so that kids don't just run to their favorite princess. Each "corner" would be decorated in the fashion of an old chalet/ castle.
The Exit
To exit, you would leave the chalet and go down the path on the left-hand side. This would lead you directly to the area at the bottom.
The Merch
One of my favorite things about this location is that you do not need the seperate failities that are in use over where PFF currently is. This means no extra bathrooms need to be installed because they are directly accross the way already. Fodd service is also just accross the way at Village Haus. Makeovers will be available at Bibbody Bobbidy Boutique.
So, the merch area would use the current carts and change merchandise to Princess themed merch. That's about it; a few carts. However, signs would direct you to the Boutique for makeovers, Village Haus for food, and of course the bathrooms.
I will post a diagram and more information soon!
- More thematically correct facility
- More discreet
- More space efficient
- No extra facilities required


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Rock Candy Online
Rock Candy Online is a dynamic new music blog that doesn't pigeon hole itself into a corner. Yes the head blogger has an affinity for Hip Hop that won't quit but we also show love to alternative artists. The basic premise of Rock Candy is to bring you everything you wanna know and hear in the realm of Music, Urban Culture, Pop Culture Ramblings and the NYC scene. Features include: Music Reviews, Op-Eds, Polls, Event & Venue Reviews, a Throwback Music Video Channel and soon there will also be a Mixtape feature. For music lovers looking for something new Rock Candy definitely delivers.
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We all know that sea levels across the world are steadily rising due to climate change, but just how these changes will affect us remains to be seen. The UN's Intergovernmental Panel on Climate Change (IPCC) just released a report that states melting ice could cause water levels to rise nearly 27 inches around the world by 2100.
Photo via Shutterstock
Natural disasters and storms have been the cause of noticeable sea level rise over the past few years, proving just how vulnerable coastal areas (especially cities) are to encroaching flood waters. But the Intergovernmental Panel on Climate Change's report delves further into the future of our sea levels, going beyond passing storms and instead dealing with real and consistent issues like climate change, gas emissions and subsequent glacier melting.
From worst case to best scenario, the findings do not look good for us. The report says that melting ice and glaciers around the world could add an additional 14 inches to our oceans- coupled with other environmental factors that could add even more. The influx of this water over the next 83 or so years will affect different areas around the world in varying ways, meaning lower-lying regions could experience a sea level rise of 27 inches.
Although the report are purely estimates, the 24 institutions funded by the European Union feel the worst case scenarios are accurate, and add that temperatures could increase 3.5 C by 2100.
Via Treehugger
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Raleigh's Phononic Devices raises $10M
- Jeff Drew
Phononic Devices Inc., a Raleigh company that makes coolers and power generators with thermoelectric technology, has raised $10 million in a second round of venture-capital financing led by existing investors Venrock and Oak Investment Partners.
The funding, announced Wednesday, brings Phononic's total venture haul to $12 million.
Phononic's technology, a thin semiconductor film, is designed to dramatically increase the efficiency of two types of products:
• Thermoelectric coolers, which use electricity to remove heat for cooling and refrigeration. Such technology can be used to cool products ranging from laptops to refrigerators.
• Thermoelectric generators, which convert heat from industrial processes into usable electric power.
"This latest financing enables Phononic Devices to assemble a world-class team and bring our high efficiency thermoelectric modules to the multi-billion dollar electronics cooling, refrigeration, and power generation markets," said Dr. Anthony Atti, President and CEO of Phononic Devices.
• Click here to download a PDF of the Phononic Devices news release.
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White House Release Super Duper Dire We're Doomed List Of State By State Sequestration Results
Leading by fear-mongering
(The Blaze) On Sunday, the White House continued its effort to prevent the $85 billion in automatic spending cuts known as "sequestration" from starting this Friday, releasing a dramatic state-by-state list of how they claim each state will be impacted if Congress fails to act.
It's worth remembering that the "cut" is only to the projected increase in spending, not to what we are currently spending.
That last part surely can't be correct: Obama's not saying that. Most of the Legacy Media isn't saying that. Democrats aren't saying that. Of course, in Washington a tiny reduction in the rate of future spending is considered a draconian cut that will mean the elimination of school meals for every kid and riots in the streets (but not the kids, because they'll be hungry to riot).
White House political director Dan Pfeiffer said on a call Sunday, according to the Hill, that the sequester is only going to happen if Republicans refuse to compromise.
He added: "Republicans are making a policy choice that these cuts are better for the economy than eliminating tax loopholes that benefit the wealthy."
If someone is constantly insulting you, do you work with them? But, this is part of the Obama management and leadership style. We've seen it time and time again. However, Americans voted for fear-mongering, blamestorming, and train-loads of mule fritters over competent leadership and a way out of this economic malaise.
House Speaker John Boehner's spokesman Michael Steel said in a statement: "Republicans in the House have voted — twice — to replace President Obama's sequester with smarter spending cuts. The White House needs to spend less time explaining to the press how bad the sequester will be and more time actually working to stop it."
It's a nice statement, but perhaps it's time for Republicans like Boehner to stop being pleasant and go for the jugular.
The article has a list (that comes from the Wall Street Journal) of all the world ending tiny reductions in spending growth that are completely over the top. Shock face.
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we know Kendrick works on quality over quantity, do you think TPAB can hold you for two years or are you…
If so for what device
I was formerly know as ChemicaLLord, now I am 2604.
Pre GKMC Kendrick vs Joey now
Whose the better rapper?
J Cole, please stop biting …
These days, underground rappers put out non profit mixtapes from which they don't get anything except pu…
We all know Nas' classic verse on Verbal Intercourse.
He raps at one point:
"When I'm deceased, by the…
I've known about the site for a while and I asked @Halfadelic about it and I made an account. Now I'm ju…
think about it
Fuck Wit Me Now — CoCo Island
On every Friday of each month you post your 3x3 last 7 days collage.
On the last day of each month you p…
what verse do you think was his best ever?
Forever by Drake, he ethers Em, Wayne, and the Jew.
Jew? her name is Aubrey.
2nd Verse on New Slaves is one of the Greatest Rap verses of all time
@Scoobers . After hearing Eminems verse, Kanye went back and spent 2 weeks re-writing his verse.
Too many classics to decide
His verse on Knock Me Down.
Idk why but i love his first verse on The Joy
Crack Music first verse too
any verse from DFSL
Second verse from Flashing Lights
Second verse on Blame Game
New God Flow verse
@DrizzyBigsean i heard that too
It's hard to pick "best", he's had so many different styles. As far as intricacy and power goes, I'd have to go with his verse on NEW GOD FLOW. His most soulful for me as been Blood on the Leaves, especially the first half. Something about the auto-tune really resonates with me, while still feeling genuine.
Last verse on Gone
his verse on
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Holdays.net Home
• Quick connector set from Driver Recovery Products. Provides simple and convenient method for disconnecting power to a winch or other electrical device such as remote battery chargers, trailers, or for any purpose requiring a high-current, quick-disconnect connector.
Connectors are made from extremely-tough polycarbonate and each end features a fitted rubber boot to protect against dust, moisture, corrosion and the elements. Connector ends are identical, so either end is suitable for connection to the power or load side, however they are mated (they connect in only one polarity or direction), to prevent anyone from connecting them cross-polarity.
Although all the components of these connectors can withstand high voltages, these connectors are designed for low-voltage (12-36 volts DC), direct-current use (high-voltage connectors usually have a socket and plug arrangement, so the socket, or power end, can be fully enclosed). Universal; this set may be used to connect any brand of winch, however the connector ends may not be an exact match to connectors included with other winch brands.
• Easy to use - Simply insert wires into terminal pins, then crimp or solder. Pins are then inserted into the connector housing, where they lock in place (pins can be removed from housing if necessary).
• High-current - All components are suitable for very high-current use, such as for winches rated 8,000 pounds or greater (true rated capacity is 350 amps, however we have seen other dealers quote much higher numbers for similar or inferior connectors). The terminal pins (0.35" inner diameter) can accept wire from 2-4 gauge.
• Dimensions - Each connector measures 3-1/8" long x 2-1/8" wide x 1" thick (connected set measures 5-1/4" x 2-1/8" x 1").
• Complete set - Kit includes one pair of connectors (2 connector ends, 4 terminal pins and 2 rubber boot caps).
Terms of saleDISCLAIMERS, WAIVERS AND INDEMNITY: By placing a offer / purchasing this or any other product ("Item") from Seller or Seller's affiliates (collectively known as "Seller"), no matter in which venue or location the sale is consummated, you ("Purchaser") represent that you are of legal age (18 years or older) to use this Item, enter into this agreement, and become bound by its terms. There are inherent risks involved in using any product, even while using protective equipment (which Purchaser is responsible to investigate and obtain), including but not limited to: serious physical injury, and possibly death. Purchaser acknowledges that Seller is neither the manufacturer of this Item nor an agent of the manufacturer. Purchaser waives all liability of Seller and claims against Seller for damages, losses, costs, injuries, penalties, expenses, attorney's fees and liabilities of whatever nature whether in tort, contract, warranty or strict liability, including without limitation those resulting from injuries or deaths of persons and damages to property resulting from, or arising out of or in connection with the use of this Item, loss or liability resulting from negligence, operational deficiencies or failures, acts of God, or other cause (whether such causes are avoidable or not) caused in whole or in part, directly or indirectly by Purchaser, Seller's employees, representatives, agents or third parties (collectively, "specified claims"). Under no circumstances is Seller responsible for special, indirect, incidental or consequential damages, even if Purchaser has been advised of their possible existence. Purchaser agrees to indemnify, defend and hold Seller harmless from and against any and all specified claims. Seller hereby disclaims all claims, express and implied, with respect to this Item, including without limitation, any implied warranties of merchantability, fitness for a particular purpose, or that the Item is free from latent defects. Purchaser has had the opportunity to contact Seller to ask any questions regarding this Item prior to purchase. Item is sold in its current as/is condition as described subject only to warranty for repairs if offered. Purchaser knowingly and freely assumes all risks of ownership and use, known and unknown. If Purchaser loans, re-sells, gifts, or transfers the Item, Purchaser will obtain transferee's agreement of all the terms contained herein. Should any legal cause of action arise, the Buyer agrees to defend Seller, and hold harmless, and forever release the seller, from any and all legal liability. PURCHASER WARRANTS THAT THEY HAVE READ, UNDERSTOOD, AND ACKNOWLEDGE THAT THEY HAVE GIVEN UP SUBSTANTIAL RIGHTS BY THIS AGREEMENT, AND AGREE TO THESE TERMS FREELY AND VOLUNTARILY WITHOUT ANY INDUCEMENT.
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Billet Aluminum Front Towing Hook Kit Jdm Anodized Black Racing Bumper Tow Set
Rear Bumper High Strength Towing Hook Anodized Red Racing Tow Cnc Aluminum
Tow Hook Set Front Bumper Towing Anodized Gold Billet Cnc Aluminum Universal
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Light up your garden with the delightful glow of our magical mushroom, featuring an uplifting butterfly or dragonfly. The colorful stake absorbs sunlight during the day, to emit a gentle illumination at night.
- Glass & metal
- Waterproof
- Hand painted
- Includes rechargeable & replaceable ni-Mh AAA battery
- Mushroom measures 7" diameter (17.8 cm)
- 20" H (50.8 cm)
- Imported
For bulk pricing on these and other items, please contact our Customer Service department at email@example.com.
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December 25, 2014 - I just received these as Christmas gifts. They are absolutely gorgeous! I hope the solar lights will work long into the night, but it is winter here right now & they won't be going into the yard until spring. Love the colors. Very vibrant!
August 27, 2013 - A beautiful addition to my newly landscaped yard. I love it and would highly recommend it to any customer.
June 5, 2013 - I have the butterfly solar garden stake. It is really lovely, however, the solar light only worked for a short while. After reading the previous comment about the rain (we have had quite a lot of rain lately), I am thinking that may be the issue. I have not checked that out yet. If that is the case, this item is only decorative as the solar light is not well made.
June 2, 2013 - My butterfly light is beautiful but only worked for a few nights. After it rained a little, this solar light didn't light up anymore and when I opened it up to check on the rechargeable battery, there was water inside and no longer works. I am hoping that the customer service dept. will either refund me my money or send me one that doesn't take on water. It advertises that it is waterproof. Not sure how the water got inside mine and stopped working even after wiping out the battery dept and recharging the battery.
May 31, 2013 - I purchase one of each for myself. I love them so much, I purchased 3 more to give as presents. Every person that received one loves them too. They are pretty during the day and even better at night.
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Aricent Supports a Tier 1 UK Operator Utilizing Keynote's DeviceAnywhere Platform for Automated Mobile Testing
JoshGalde Tags: ios anywhere iphone device blackberry deviceanywhere test 5 testing automation keynote android mobile hp ibm 1,694 Visits
Aricent Group, a global innovation and technology services company, working closely with Keynote, has developed a flexible, best-of-breed testing environment for a Tier 1 mobile network operator in the UK. This operator and other companies can now have...
Upcoming webcast: Scott Barber answers "Is Early Performance Testing Valuable AND Viable?" Community Blog
LBuckley Tags: starwest quality-management agile testing rational test-automation performance-testing alm 1,997 Visits
Many organizations are neglecting to include a comprehensive performance testing process in their quality arsenal as it is too expensive or time consuming to measure the stability and scalability of business critical functionality prior to releasing to...
from Blog: Application Lifecycle Management
Rational Quality Manager in 3 minutes
from Blog: Random Rational tidbits
Know your IBM Champions!
VijaySankar Tags: quality management alm innovate automation testing requirements ibm champions 2,111 Visits
Couple of months back, IBM took recognizing technical thought leadership by announcing IBM Champion program . An IBM Champion is an IT professional, business leader, developer, or educator who influences and mentors others to help them make best use of IBM...
from Blog: The Rational Tester
Testing en la nube
JoseAntonioMuñoz Tags: testing desarrollo pruebas greenhat cloud 1,873 Visits
IBM ha anunciado un acuerdo definitivo para adquirir Green Hat, proveedor líder de soluciones de software que ayudan a probar en entornos cloud la calidad de las aplicaciones antes de su lanzamiento. Una vez que se cierre la adquisición, las soluciones...
Improve security by integrating development and static and dynamic testing Community Blog
allenkane Tags: ibm-security open_source application-security testing dynamic_testing security static_testing application_development 1,066 Visits
Independent expert M. Tim Jones takes you on a tour of testing your applications for security capabilities during the development and verification phase , focusing on code that you can touch, test, and inspect manually, as well as code that is perfect for...
from Blog: Security on developerWorksModified by CalvinPowers
The Right Tool for the Job - Building an Automation Testing Matrix Community Blog
JoshGalde Tags: level device automation mobile systems rational deviceanywhere testing keynote object test ibm 1,611 Visits
For Desktop-based testing it's a no-brainer: Use object-based scripting to maximize reuse across platforms/browsers. In today's mobile world it really isn't that simple. There are many different platforms, OS versions, form factors and carrier/manufacturer...
from Blog: IBM Rational community
Generating Test Reports using JsTestDriver
Hazem Saleh (IBM) Tags: reports jstestdriver testing javascript unit html 2,409 Visits
JsTestDriver is one of the most powerful JavaScript unit testing tools. I wrote an article in developerWorks about efficient JavaScript unit testing using JsTestDriver, please read first it before reading this post. In this post, I will show you how to...
Test your software, not your patience
ErikaHorrocks Tags: ibm-rational service-virtualization quality-manager research info-tech workbench testing report software quality 2,833 Visits
As our need to deliver software faster and meet market demands has increased, something usually has to give. The old adage says that you can only deliver against 2 of the 3 mandates (cost, timeframe, quality), so choose which one won't happen. However, that is...
from Blog: The Invisible Thread
[DeveloperWorks] Efficient JavaScript unit testing
Hazem Saleh (IBM) Tags: developerworks testing java javascript unit 1,549 Visits
I published this article in developerWork: http://www.ibm.com/developerworks/library/os-jstesting/ . I wish it can be useful for you.
The Keys to a Successful Mobile App Strategy
JoshGalde Tags: ios development strategy automation anywhere mobile ipad deviceanywhere app keynote android test iphone testing blackberry 5 device mini 2,938 Visits
There are many phases in the testing of any mobile app or website, specifically when it comes to QA and development. Within development (or pre-launch) there is Functional Testing, Usability Testing, and Performance Testing, amongst others. And in...
Mobile App Testing More Complex than Desktop – Shocker! Community Blog
JoshGalde Tags: enterprise object-level android keynote qa systems blackberry deviceanywhere smartphones ctia applications store apps testing test developers os object google automation native mozilla mobility windows level web fragmentation scripting iphone app developer smartphone firefox ios html5 device application mobile 2,680 Visits
It should come as no surprise to find out how much more complicated testing an app on a mobile device is than on a desktop. Desktop apps can be complicated sometimes, but typically they are fairly straight forward. This is due to several factors. First,...
from Blog: IBM Rational community
Netflix Talks HTML5-based Mobile Testing on Android
JoshGalde Tags: mobile keynote iphone netflix automation test anywhere testing deviceanywhere device ios blackberry 5 android 2,005 Visits
In a recent article posted by Amol Ker of Netflix, he shared his struggles with performing device testing of their mobile apps and websites. Since they operated on a hybrid approach using HTML5 based coding. In the article Amol shared the following...
"Efficient JavaScript unit testing" video session in CONFESS 2012
Hazem Saleh (IBM) Tags: unit austria confess javascript hazem saleh presentation testing jstestdriver leogang confess_2012 video session 2,556 Visits
This video provides a presentation about how to make efficient JavaScript unit testing. I presented it in the CON-FESS 2012 international conference which was held in Leogang, Austria. I wish it can be useful.
IBM Rational for Software Development Community Blog
John_Schilt Tags: software testing lyfesycle architect engineering development 1,153 Visits
Software development is a popular subject in Australia and New Zealand universities - especially given that jobs in the IT sector are available and the software development career can be flexible and lead to other roles such as Project Management, Architect...
from Blog: Academic Initiative - Australia


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Popular this month
Duran Group Scilabware Wins Fisher Scientific Supplier of the Year Award
Agar Scientific installs new scanning electron microscope, setting a new standard for quality control
How to Minimize HPLC Pump System Problems
Advances in Bio-Separations - ChromSoc release Preliminary Programme
Novel Organoid Matrix Enables Long-Term Culture of Human Hepatocytes
Free Guide to Solvent Evaporation
'Stem Cell' Test Could Identify most Aggressive Breast Cancers
Call for Posters: PREP 2015 July 26-29, 2015 in Philadelphia, PA, USA
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Call for Posters: PREP 2015 July 26-29, 2015 in Philadelphia, PA, USA
Ensuring Reliable Sample Containment with Autosampler Vials
Expanded Family of Hydrophobic Interaction Columns Offers New Selectivity Options for Characterizing Monoclonal Antibodies
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HORIBA Scientific presents the 'nano partica' SZ-100, Particle Size, Zeta Potential and Molecular Weight Analyzer
publication date: Oct 24, 2011
author/source: HORIBA Scientific
The new SZ-100 series instruments analyze key particle physical properties including size, zeta potential, molecular weight, and second virial coefficient (A2). Particle size analysis is performed by dynamic light scattering (DLS). Zeta potential is measured by electrophoretic light scattering. Molecular weight and A2 are analyzed by static light scattering using a Debye plot.
The SZ-100 is the only instrument available capable of performing size measurements at both 90° and backscatter (173°). This unique feature provides maximum sensitivity and allows the user to optimize measurement conditions for all possible sample types. Particle size measurements are performed in a variety of cells at volumes down to 12 µL. Zeta potential measurements are made in either disposable cells for aqueous samples or dip cells for organic and biological samples. The unique disposable cells using carbon electrodes can typically measure hundreds of samples before requiring replacement.
An automatic titrator is available for iso-electric point determinations of zeta potential vs. pH, or studies investigating optimum surfactant concentration for formulation or processing.
Particle size measurements can be made from 0.3 nm - 8 µm at concentrations from 0.1 mg/mL (lysozyme) to 40 wt percent depending on sample properties. Zeta potentials from -200 to +200 mV can be analyzed manually or with the auto titrator. Molecular weight of small particles (<100 nm) is measured from 1x103 to 2x107 g/mol. Typical applications include nanoparticles, colloids, proteins, biomolecules, and emulsions.
For more information or for demonstration click here firstname.lastname@example.com or click here to visit our website.
Exhibitions & Events
Latest O'Neill Report on Superbug Resistance Highlights Antibiotic Research UK's Antibiotic Resistance Breaker Concept
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Novel Organoid Matrix Enables Long-Term Culture of Human Hepatocytes
Researchers Study Cultural Heritage Painting Cross-Sections Using Breakthrough AFM Based Nanoscale Mass Spectrometry Technique


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GLAAD Elects Herndon Graddick President
LGBT advocate and former television producer Herndon Graddick has been elected the next president of GLAAD.
Officials at the Gay & Lesbian Alliance Against Defamation praised Graddick as a committed advocate for equality and as an inspirational figure.
PHOTOS: GLAAD Media Awards Red Carpet Arrivals
"Herndon Graddick is already a well-respected leader within the LGBT movement, and we believe will be a visionary and strategic leader for GLAAD's culture-changing work," Sheri Fults, National Co-Chair of the Board of Directors, said in a statement.
Since 2010, Graddick has served as vice president of programs and communications at GLAAD, where he helped organize the Stand up for Ellen campaign, launched in response to the group One Million Moms calling for Ellen DeGeneres to be fired as a spokesperson for J.C. Penney because of her sexual orientation.
Graddick said he looked forward to working toward change as GLAAD president.
PHOTOS: 22nd Annual GLAAD Awards
"Right now GLAAD and our partners in the LGBT movement are making a significant difference at a time when a difference needs to be made, Graddick said in a statement. "I look forward to working with our dedicated staff to create a culture where there is a welcoming and respected space for LGBT Americans. GLAAD's work with the media to inspire Americans to speak out against anti-LGBT actions and support equality is needed today more than ever."
Graddick previously worked as a supervising producer at E! Networks and as the day-of-air news division director at CURRENT TV. He will speak at the 23rd Annual GLAAD Media Awards in Los Angeles on April 21, where he will be officially introduced as president.
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2006 Chevrolet Corvette in Roanoke, VA
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My 2006 Corvette is a pretty decent car. It was purchased at CarMax in Wichita, Ks. with 20,000 miles on it and I have had only 1 issue with it. It has great power and gets nearly 30 mpg highway. The 1 issue is the clutch....I once went to leave a stoplight by revving it up and dropping the clutch and the clutch pedal stayed on the floor and the...
2006 Chevrolet Corvette Coupe Used Cars in Kernersville, NC 27284
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Blake Shelton – Sangria (Official Music Video)
The official "Sangria" music video!
Fans of A&E's "Duck Dynasty" will be delighted to learn that "The Duck Commander Musical" — the stage play centered around the famed Robertson family — is slated to premiere next month in Las Vegas, with tickets for the show already on the market.
In terms of "giving in" to kids, I think there's a difference between preemptively planning things so that a young child can stay engaged or not get too bored while you shop (like letting them bring a book, or finding an age-appropriate way for them to help with the shopping) and giving in to their […]
The 2015 COUNTRY MEGATICKET AT WALNUT CREEK AMPHITHEATRE – a multi-show package featuring the summer's hottest country shows in Raleigh. Available only online HERE, the 2015 COUNTRY MEGATICKET gives you the opportunity to buy your tickets first for the 2015 stellar lineup of country shows! Several different packages are available for a limited time only.
WKML Salutes our hometown heroes, the men and women from Fort Bragg, North Carolina that are serving our country or have served our country away from home! Friends and family can post messages of support and even photos of their loved ones on the dedicated "Wall of Honor"


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Home > All Cities > Athens, GA Real Estate Listings > Villas At Snapfinger Subdivision
Properties for sale in the Villas At Snapfinger Subdivision, Athens, GA
Properties 1 to 1 of 1
184 Wakefield Trce, Athens, GAList Price: $117,000 | Bed:2 | Bath:2.00
Excellent condition one level living. Ready to move into. Two owner home. Sloping, Wooded Ceilings - Vaulted, Pulldown Attic Stairs, Wall-to-wall Carpet Street Lights Deck/Patio
Listing Office: RE/MAX TOP PERFORMERS | MLS ID#: 07394594


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Read the full story here Web Link posted Tuesday, November 13, 2007, 11:09 AM
Town Square
Fishing is now banned in San Francisco Bay
Original post made on Nov 13, 2007
Read the full story here Web Link posted Tuesday, November 13, 2007, 11:09 AM
Comments (4)
a resident of East Palo Alto
on Nov 13, 2007 at 11:42 am
this sucks!
a resident of Another Palo Alto neighborhood
on Nov 13, 2007 at 12:52 pm
Six days after the spill, fishing is now banned. The amazing slowness of the cleanup is quite disturbing. Bunker fuel must be more toxic than coal tar because almost no volunteers have been able to help, especially in the early days before the globs of oil broke up.
a resident of College Terrace
on Nov 13, 2007 at 4:46 pm
you should not eat fish any time from the bay because of the very high levels of mercury
a resident of Midtown
on Nov 13, 2007 at 5:30 pm
There are fish in the south Bay? Who knew?
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Freebirds Palo Alto shutters, Pieology to move in
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By Douglas Moran | 12 comments | 2,266 views
Deny the 429 Univ Ave Project Appeal
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Now Playing - Your Dinner!
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Ill have the Kraft Mac n Cheese w/Ketchup, Please
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41 of 46 people found the following review helpful
Could not put down...,
Verified Purchase(What is this?)
This review is from: The Magpies: A Psychological Thriller (Kindle Edition)
This is a great book.. I really hated it when my train journey into work came to an end and I had to wait all day before I could continue on the way home..!!
I agree, it's like a modern day Rosemary's Baby but I preferred this because it was so much more believable.. This could happen..! I was freaked out by the spiders and convinced I would find one in my bath later that night.. (I didn't I'm glad to say)
I tried to guess the outcome and got it completely wrong. I was sad and suprised at the ending. The only thing that I was a bit confused about was why did Paul change so much? I thought it was going to come out that Chris had been turning him against Jamie, Kirsty and Heather.
I have never felt compelled to write a book review before, and I have read thousands over the years.. (but then I have never got so involved in the plot and the characters)
Think I have driven all my family and friends mad telling them how good this book is...!
I am now on a mission to find a book just as gripping.. I have this void to fill !
Obviously, I would recommend this book to everyone !
Tracked by 1 customer
Sort: Oldest first | Newest first
Showing 1-3 of 3 posts in this discussion
Initial post: 29 Apr 2013 13:46:03 BDT
mredwards says:
Thanks so much for this review but could you please remove the lines that give away the end? I don't want it to be spoiled for people who haven't read it yet.
Thank you! Mark
In reply to an earlier post on 29 Apr 2013 15:35:08 BDT
Kath J says:
So sorry. It's my first review and I didn't think..!! Have edited it out.. Sorry again. K
In reply to an earlier post on 29 Apr 2013 15:42:14 BDT
mredwards says:
Don't worry! Thanks for editing it and I'm really happy you liked the book so much.
Best wishes
‹ Previous 1 Next ›
Review Details
(3,068 customer reviews)
Out of stock
Top Reviewer Ranking: 270,088


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Jacki Weaver on Bradley Cooper and the "Brilliant" Jennifer Lawrence
Jacki Weaver on Bradley Cooper and the "Brilliant" Jennifer Lawrence
Watch a Sneak Peek of Community Episode 4
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Jacki Weaver's Silver Linings Playbook role is earning her lots of award season attention, and this weekend was no different. On Saturday, she was honored at the Australian Academy of Cinema and Television Arts Awards in LA, where we chatted with her on the red carpet. Jacki talked about playing mom to Sexiest Man Alive Bradley Cooper and her admiration for the "brilliant" Jennifer Lawrence, who picked up the best actress SAG Award at last night's ceremony.
Community Season Six: The Dean gets a promotion and Annie and Chang audition for a play in this trailer for the fourth episode of season six.
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City of Hope's 2012 Spirit of Life Award was presented to OPI's George Schaeffer, who raised $5.2 million for City of Hope for diabetes research. (He raised $2.7 million and pledged to match $2.5 million on his own.) This video was played at the gala on Saturday, July 28, 2012 at Cosmoprof in Las Vegas. Five for Fighting's John Ondrasik sang the hit song "100 Years" live during the tribute.
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A method for forming an ordered array of nanocrystals where a hydrophobic precursor solution with a hydrophobic core material in an organic solvent is added to a solution of a surfactant in water, followed by removal of a least a portion of the organic solvent to form a micellar solution of nanocrystals. A precursor co-assembling material, generally water-soluble, that can co-assemble with individual micelles formed in the micellar solution of nanocrystals can be added to this micellar solution under specified reaction conditions (for example, pH conditions) to form an ordered-array mesophase material. For example, basic conditions are used to precipitate an ordered nanocrystal/silica array material in bulk form and acidic conditions are used to form an ordered nanocrystal/silica array material as a thin film.
1. A method for making a nanocrystalline micellar solution, consisting essentially of:
forming a first solution comprising a surfactant in water;
forming a second solution comprising a hydrophobic material, the hydrophobic material comprising a nanocrystal core surrounded by a hydrophobic stabilizing ligand, in an organic solvent;
mixing the first and second solutions to form a third solution; and
removing at least a portion of said organic solvent from the third solution to form a solution of nanocrystal micelles, each micelle comprising the nanocrystal core and a hybrid bilayer shell comprising a surfactant secondary layer interdigitated with a hydrophobic stabilizing ligand primary layer.
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This application is a continuation-in-part application of U.S. patent application Ser. No. 10/683,810, entitled �Self-Assembly of Water-Soluble Nanocrystals,� filed on Oct. 10, 2003 now abandoned, and claims priority to and the benefit of the filing of said U.S. patent application.
This invention was made with Government support under Contract No. DE-AC04-94AL85000 awarded by the Department of Energy and Contract No. CTS-9624841 through the National Science Foundation. The Government has certain rights in the invention.
The invention relates to a method for making water-soluble nanocrystals, and, more particularly, to a method for making ordered nanocrystal arrays and subsequent nanocrystal mesophases through self-assembly of water-soluble nanocrystal-micelles.
Nanometer-sized crystallites of metals, semiconductors, and oxides exhibit optical, electronic and chemical properties often different from those of the corresponding isolated molecules or macroscopic solids. The ability to adjust properties through control of size, shape, composition, crystallinity, and structure has led to a wide range of potential applications for nanocrystals (NCs) in areas like optics, electronics, catalysis, magnetic storage, and biological labeling. Furthermore NC assembly into two- and three dimensional arrays is of interest for development of synthetic solids with collective optical and electronic properties that can be further tuned by the nanocrystal spacing and arrangement. For example, using uniformly-sized CdSe nanocrystals passivated with a close-packed monolayer of organic coordinating ligands (trioctylphosphine oxide or alkane-amines or mixtures thereof), monodisperse lyophobic colloids self-assembled to create periodic, three-dimensional quantum dot superlattices. In another instance, ordered CdSe quantum dot films were prepared, demonstrating optical gain and stimulated emission. In two-dimensional (2-D) quantum dot monolayers formed in a Langmuir trough, quantum mechanical tunneling was reported to occur between adjacent silver nanocrystals at an interparticle spacing below 1.2-nm and a reversible insulator-to-metal transition below 0.5-nm. Even richer transport and collective phenomena are expected for three-dimensional (3-D) NC arrays.
Despite recent advances in the synthesis and characterization of nanocrystals and nanocrystalline arrays, there remain numerous challenges that limit their practical utilization. For example, synthesis procedures generally used for metallic and semiconducting nanocrystals employ organic passivating ligands, making the nanocrystals water insoluble. This is problematic for biological imaging and for incorporation of nanocrystals in hydrophilic sol-gel matrices like silica or titania needed for the fabrication of robust, functional lasers. Furthermore, while steric stabilization of nanocrystals with organic passivating layers suppresses strong, attractive particle-particle interactions, thereby facilitating self-assembly of nanocrystal arrays, it necessarily causes the arrays to be mechanically weak and often thermally and chemically unstable. This ultimately limits routine integration of NCs into devices.
Three different approaches have been used to prepare water-soluble semiconductor NCs using currently-available hydrophobic NCs: 1) ligand-exchange, 2) encapsulation into a water-soluble shell (for example, silica or phospholipids) and 3) arrested precipitation in water. The ligand exchange method involves the use of carboxylic acid or amine terminated thiols (for example, amino-ethanethiol and mercaptopropionic acid) to replace trioctylphosphine or alkaneamine ligands. This often results in aggregation of resulting water-soluble NCs and a lower photoluminescence (PL) quantum efficiency (QE) (QE, 10-30%) than original NCs. In the case of CdSe NCs, the emission has been observed to be completely quenched after transfer into water, if no shell of a wider band gap material is used. The encapsulation of the NCs into a water-soluble shell typically yields PL QEs of 20-30%. The method of forming hydrophilic silica shell for transferring NCs into water involves several steps and thus has the additional disadvantage of being rather complicated and time-consuming. Arrested precipitation in water in the presence of stabilizers (for example, thiols) is a faster and simpler method to synthesize water-soluble quantum dots (QDs) and has been applied to several semiconductors potentially relevant to biolabeling (for example, CdS, CdSe, CdTe).
Useful would be a direct synthesis method of water-soluble nanocrystalline micelles (NC-micelles) utilizing hydrophobic compounds and their further formation into robust, ordered three-dimensional nanocrystalline mesophases in bulk or thin film forms.
In the method of the present invention, a hydrophobic precursor solution comprising a hydrophobic core material in an organic solvent is added to a solution of a surfactant in water, followed by removal of a least a portion of the organic solvent to form a micellar solution of nanocrystals (see
The hydrophobic precursor solution can comprise any hydrophobic material in an organic solvent, wherein the hydrophobic material is the core material for the micellar solution formed and is a compound or material selected from, but not limited to, a metal, a semiconductor, a magnetic nanocrystal, a porphyrin, dye molecules, carbon nanotubes, fullerenes, including carbon 60 (C-60) compounds (that is a compound containing 60 carbon atoms), carbon 70 (C-70) compounds, carbon 80 (C-80) compounds, carbon 90 (C-90) compounds, and hydrophobic polymers. These hydrophobic materials include, gold, silver, II-VI and III-V nanocrystals, such as CdSe, CdTe, HgTe, CdHeTe, CdS, PdS, ZnS, ZnSe, CdSe/ZnS, InAs, InP, GaP, GaN, and ZnO among others, Ge, Co, Ni, Fe, Cu, Si, Pt, Pd, PtPd, FePt, and BaTiO3, as well as oligomers, dendrimers, and polymers. It is required that these core materials be hydrophobic. The core material can be a single molecule, an oligomer, a polymer, a cluster, or a nanoparticle. They can exist as either a liquid or a solid. They can geometrically be a spherical particle, a rod or a tube. The organic solvent can be selected from any standard organic solvent, including both alkyl and aromatic compounds, that can adequately solubilize the hydrophobic material (for example, chloroform, hexane, and benzene). It is important to note that no hydrophilic compounds are added during the synthesis process, as addition of hydrophilic compound significantly changes both the composition and structure of the resulting materials. Additionally, this embodiment contemplates a method wherein only insignificant amounts of other components or the presence of other steps which do not materially affect the characteristics of the invention.
Surfactants such as a cationic surfactant, an anionic surfactant, a nonionic surfactant, a block polymer, or a lipid can be utilized as the surfactant in water. In particular, useful surfactants include compounds selected from the group consisting of sulfates, sulfonates, phosphates, carboxylic acids, alkylammonium salts, gemini surfactants, cetylethylpiperidinium salts, dialkyldimethylammonium, primary amines, poly(oxyethylene) oxides, octaethylene glycol monodecyl ether, octaethylene glycol monohexadecyl ether and block copolymers.
To form ordered nanocrystal mesophases, a precursor co-assembling material, such as a metal oxide, water-soluble oligomers and water-soluble polymers are mixed with the nanocrystal micellar solution in the presence of an acid or base. In one embodiment, the precursor co-assembling material, such as a metal oxide, as an alkoxysilane, such as tetraethylorthosilicate or tetramethylorthosilicate, or other metal oxides such as titanium butoxide, titanium iso-propoxide, zirconium n-butoxide, and aluminum iso-propoxide can be added to this micellar solution under basic conditions to precipitate an ordered, three-dimensional, mesophase nanocrystalline array in bulk form. To form a three-dimensional mesophase array as a thin film, the micellar solution of nanocrystals can be mixed with the precursor co-assembling material under acidic conditions to make a solution that can be formed as a thin film by deposition of the solution on a substrate by standard methods such as spin-coating or casting.
In the present invention, monosized, organically-passivated nanocrystals are considered as large hydrophobic molecules that, if incorporated individually into the hydrophobic interiors of surfactant micelles, result in the formation of monosized nanocrystal (NC) micelles composed of a metallic (or other) NC core and a hybrid bilayer shell with precisely defined primary and secondary layer thicknesses (see
The general preparation involves forming a first solution of a surfactant in water or alcohol or a mixture thereof. The surfactant is completely dissolved, such as by sonication or like method. A second solution is formed by dissolving the hydrophobic core material in an organic solvent. The first and second solutions can be formed in any order. Although heating of the solutions can be performed, the solutions can easily be formed at room temperature, These first and second solutions are mixed and the organic solvent is removed, such as by heat treatment or by vacuum, to form a third solution, where, upon evaporation of the solvent, yields a nanocrystal-micellar ordered array. In the nanocrystal-micellar ordered array, there are no empty micelles (that is, each micelle contains at least one hydrophobic core material compound). Under proper preparation conditions, each micelle can be prepared to contain one hydrophobic compound molecule. The third solution can also be deposited on a substrate, such as TEM grid, silicon, glass, mica, graphite and other standard substrates, wherein after evaporation of the solvent, yields ordered nanocrystal arrays.
To form thin film mesophases, an acid is added to the third solution with the addition of a precursor co-assembling material, such as a metal oxide, water-soluble oligomers and water-soluble polymers. In particular, metal oxides such as an alkoxysilane, such as tetraethylorthosilicate or tetramethylorthosilicate, or other metal oxides such as titanium butoxide, titanium iso-propoxide, zirconium n-butoxide, and aluminum iso-propoxide can be used. Water-soluble oligomers, including, but not limited to, water-soluble aniline and thiophene oligomers, and water-soluble polymers including, but not limited to, water-soluble polyaniline and polythiophene can also be used. The resulting solution can be deposited on a substrate by a standard method such as spin-coating, dip-coating or casting to form a thin film mesophase on the substrate. The acid used can be any standard acid in solution such as an aqueous HCl solution.
To form bulk mesophase material, the third solution is mixed with the precursor co-assembling material, such as a metal oxide, water-soluble oligomers and water-soluble polymers, in the presence of a base. In particular, metal oxides such as an alkoxysilane, such as tetraethylorthosilicate or tetramethylorthosilicate, or other metal oxides such as titanium butoxide, titanium iso-propoxide, zirconium n-butoxide, and aluminum iso-propoxide can be used. Water-soluble oligomers and water-soluble polymers can also be used. The resulting precipitated bulk mesophase material can be recovered by standard techniques, such as filtration, washing, and drying. The base can be any standard base in solution such as an aqueous NaOH or NH3 solution.
To individually incorporate NCs in surfactant micelles, a micro-emulsion procedure was developed. A concentrated nanocrystal solution, prepared in organic solvent (such as chloroform or hexane), is added to an aqueous solution of surfactant with a volume ratio in one embodiment of 1:10 under vigorous stirring to create an oil-in-water micro-emulsion (higher and lower volume ratios can also achieve the micro-emulsion with the ratios dependent upon the particular reaction system considered). Organic solvent evaporation (aided optionally by vacuum or heat treatments) transfers the NCs into the aqueous phase by an interfacial process driven by the hydrophobic van der Waals interactions between the primary layer of the stabilizing ligand and the surfactant, resulting in thermodynamically defined interdigitated bilayer structures. In one embodiment, for single-tailed surfactants, an alkane chain of eight or more carbons is required to form micelles with gold nanocrystals stabilized by C12 alkanethiols (dodecanethiol). Cationic, anionic, non-ionic surfactants, block polymers, or lipids can all form NC-micelles, allowing facile control of micelle surface charge and functionality.
In one embodiment, fluorescent semiconducting CdSe NCs (stabilized by trioctylphosphine oxide) were formed into NC-micelles with maintenance of optical properties, further supporting the general nature and flexibility of this approach. NC-micelle solutions are generally colored and indefinitely stable (prepared solutions have been stable for greater than two years). In another embodiment, the formation of individual gold NC-micelles (as opposed to aggregated dimers, trimers and the like) was confirmed by ultraviolet (UV)/visible spectroscopy (
In addition, evaporation of the NC-micelles resulted in self-assembly of hexagonally ordered NC arrays as expected for individual, monosized nanocrystals. In aqueous media, NC-micelles organize hydrophilic components/precursors at the surfactant/water interface through electrostatic and hydrogen-bonding interactions in a mechanism analogous to that of surfactant-directed self-assembly of silica/surfactant mesophases (used as precursors to so-called mesoporous silicas). For example, addition of tetraethyl orthosilicate under basic conditions results in the formation of hydrophilic oligo-silicic acid species that organize with NC-micelles to form a new type of ordered gold NC/silica mesophase with face-centered-cubic (FCC) symmetry (space group Fm3m).
It can be noted that reducing the concentration of the gold NCs, while maintaining a constant surfactant/silica molar ratio, caused the progressive transformation of the cubic, gold NC/silica mesophase to a 2-D hexagonal silica/surfactant mesophase (
As shown by additional XRD results, changing the primary NC particle size, dp, the primary layer thickness, d1, or the secondary layer thickness, d2, allows adjustment of the NC mesophase lattice constant. For example, results have shown that the (111) d-spacing changes linearly from approximately 5.0 to 7.2-nm through variation of dp from 1.0 to 3.3-nm. Changing the secondary layer thickness d2 by 4 carbon units (CH3(CH2)n(NCH3)3 +Br+Br−, nL=11 to nK=15, where nL and nK are the carbon numbers in each surfactant) results in a 1.11-nm change in (111) d-spacing (1.38-Å/C-C bond) consistent with model predictions and structural studies.
Using acidic conditions designed to minimize the siloxane condensation rate (pH value of approximately 2), pathway i-ii-iv (
The ordered arrays of metallic nanocrystals (NCs) described herein are potential implementations of several types of model systems. Electrostatically, such an ordered array of metallic particles is identical to the composite model systems used in textbooks to describe the properties of polarizable media. They also may be a means of implementing nanocrystal memory devices wherein the nanocrystals are present in a single plane and serve to store charge and modify the channel conductance. However, the three-dimensional array of nanocrystals presented here offers a variety of opportunities to study the physics of transport. Thus the structures produced according to the method of the present invention could permit experiments and encourage modeling of new systems.
One advantage of the method of the present invention is its capability to utilize a wide variety of hydrophilic core materials and surfactants in the formation of the reactant solutions to subsequently form NC micelles. Through using surfactants/lipids with different functionally-terminated groups, these NC-micelles can be easily conjugated with a variety of biospecies such as Streptavidin, biotin, DNA, IgE, and antibodies, among others. The method can be finished in a single, rapid step of solvent evaporation without using special equipment. The results indicated that, in a laboratory environment, grams of water-soluble NCs can be prepared in less than 10 minutes. In other methods, such as the ligand exchanging method, chemical replacement reaction at nanocrystal interface occurs. This often results in the changes of nanocrystal physical properties such as band gap, aggregation, photoluminescence intensity and life time. In the method of the present invention method, the stabilization of hydrophobic nanocrystals in water relies on the thermodynamically favorable interdigitation of surfactants and nanocrystal stabilizing ligands formed after solvent evaporation. Without chemical replacement reaction involved, this does not affect the physical properties of original source hydrophobic nanocrystals. Additionally, the method can effectively prevent NC-micelles from aggregation and non-specific binding. Also, dense-packed surfactant/lipid layers help to prevent NCs from oxidation and preserve their luminescence properties.
As an initial investigation of charge transport in our ordered three-dimensional nanocrystal arrays, planar metal-oxide-semiconductor (MOS) devices (see schematic in
With improvement, these NC arrays could be the ideal media for the study of the Hubbard Hamiltonian and the variety of transport and collective phenomena predicted to occur for such systems. Key to such studies is the ability to control the array lattice constant and hence the spacings between individual NCs as we demonstrate. Briefly summarizing the implications for transport studies, wider spacing between the NCs leads to weaker coupling and creates the situation for observing the collective coulombic blockade behavior described for a one-dimensional array. Stronger coupling arising in more closely spaced dots permits efficient tunneling between the dots and observation of such phenomena as quantum Hall behavior and intricate energy gap dependence on magnetic field for a two dimensional array of quantum dots. The ability to modulate this behavior with an external electric field can allow a controllable Mott transition. Beyond transport, the robust, highly ordered NC arrays described could be useful in photonic devices such as lasers and the water-soluble NC micelle intermediates that are promising for biological labeling. Finally, due to their uniform gold spacings, NC arrays can serve as an optimal platform for sensors and molecular electronic nanocell logic gates formed by �wiring� the NCs with conjugated dithiol oligomers as was demonstrated in a preliminary experiment.
0.4 g surfactant (CH3(CH2)15N+(CH2)3Br−) was added to 14 g DI-water (or alternatively, one can use pure water, alcohols, or water and alcohol mixtures) to form solution A. Solution A was sonicated to completely dissolve the surfactant. 0.4 g 1-dodecanethiol (1-DT) derivatized gold nanocrystals were dissolved in 1-2 ml chloroform (can be hexane, benzene, toluene, or other solvents) to form solution B. Solutions A and B were mixed together with vigorous stirring, and the chloroform was removed by vacuum or heat treatment to finish the encapsulation. A dark-red water solution (C) was obtained containing gold nanocrystals. Solution C can be further diluted for UV-vis spectroscopy or TEM characterization. To form ordered nanocrystal arrays, solution C can be deposited on substrates like TEM grids, glass, silicon, mica, and graphite, wherein, after evaporation or drying, ordered nanocrystals arrays will be formed. To synthesize bulk, ordered gold NC/silica mesophases, 1.3 g tetraethyl orthosilicate (TEOS) was added to solution C. The mixture was stirred at room temperature followed by addition of 1N sodium hydroxide (NaOH) aqueous solution (1-3 ml). After 3 hours, the resulting precipitate was recovered by filtration, washing, and drying. To form thin film mesophases, 0.07N hydrogen chloride (HCl) aqueous solution (0.2 ml) was first added to C (2 ml) followed by addition of TEOS (0.2 g) under stirring at room temperature. The solution was stirred for 1-3 hours. Thin films were deposited on silicon substrates by spin-coating at 500-5000 rpm, casting, or dip-coating.
0.2 g surfactant (CH3(CH2)15N+(CH2)3Br−) was added to 6 g DI-water (again, this can be pure water, alcohols, and water and alcohol mixtures) to form solution A. Solution A was sonicated to completely dissolve the surfactant. 0.2 g trioctylphosphine/hexadecylamine derivatized CdSe nanocrystals were dissolved in 1-2 ml chloroform (alternatively, hexane, benzene, toluene, or other organic solvents) to form solution B. Solutions A and B were mixed together with vigorous stirring, and the chloroform was removed by vacuum or heat treatment to finish the encapsulation. A solution (C) was finally obtained containing CdSe nanocrystals. Solution C can be further diluted for UV-vis spectroscopy or TEM characterization. Mesophase materials were prepared using methods similar to those in the previous example.
The invention being thus described, it will be apparent that the same may be varied in many ways. Such variations are not to be regarded as a departure from the spirit and scope of the invention, and all such modifications as would be obvious to one skilled in the art are intended to be included within the scope of the following claims.
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(L-R) Bill Coons, director of Optocore North America, and Antony David, managing director of Solid State Logic, announced the direct connection of SSL C10 HD and C100 HDS consoles to Optocore Optical Digital Network System at NAB 2010.
New Integration Enables Direct Connection of SSL C10 HD and C100 HDS Consoles to Optocore Optical Digital Network System
LAS VEGAS, NV â Solid State Logic, the manufacturer of industry leading digital consoles for the broadcast industry, announced the integration of their digital broadcast console range with the Optocore Optical Digital Network System at NAB 2010.
âThis collaboration enables SSL C10 HD and C100 HDS consoles to connect directly to the Optocore Optical Digital Network System via MADI optical fibre,â? says Niall Feldman, director of new products at SSL. âOptocore produces a high quality system that has enjoyed considerable success in the stadium and theater installation sectors so this integration extends the range of facilities for which the benchmark audio quality and rich feature set of SSL digital consoles will be a plug and go option.â?
With the SSL MADI I/O control protocol now integrated into Optocoreâs topology, Solid State Logic C10 HD and C100 HDS consoles can now transmit/receive up to 128 audio I/O channels over an Optocore Optical Digital Network System. In addition users will have the ability to remotely control the microphone preamplifiers in the 48 input Optocore LX4AP stagebox. Under the new implementation, SSL C10 HD and C100 HDS consoles will automatically identify, label and control any connected Optocore LX4AP Stageboxes. Combining SSLs MORSE Stageboxes with Optocore LX4AP Stageboxes allows users to connect multiple consoles and stageboxes with full redundancy. The ability to remotely control stagebox gains over the Optocore fibre network is a major advantage for users, giving that extra degree of flexibility and control over the relevant parts of an installed system, particularly in theatres and stadiums.
Solid State Logic is the worldâs leading manufacturer of analogue and digital audio consoles and provider of creative tools for music, broadcast and post production professionals. For more information about our award-winning products, please visit: www.solid-state-logic.com.
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Westwood, NJUSA 07675
March 9, 2013
There isn't one particular genre that I don't like, although I gravitate towards fiction much more often than non-fiction.
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Hi I'm Donna! I moved to Westwood,NJ just before my baby girl was born. She is now 8 months old and I am ready to get out and have some adult time again... a book club sounds like fun!
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Game Questions & Answers (Q&A) service lets you ask questions about video games for game consoles or PC games. So ask your Resident Evil: Operation Raccoon City question for Xbox 360 and get answers from real gamers or answer questions and share your insights and experience with the rest of the gaming community.
- Developer: Slant Six
- Publisher: Capcom
- Genre: Action Adventure
- Release Date: Mar 20, 2012
- ESRB: Mature
- Other Platforms
- Expansions List
Question & Answers
Answer from: amir
I think it's better to use a grenade lancher or try to shoot him in head with a powerfull weapon.
Answer from: megafreakintron
The tall men are called trents. if your referaing to the 2 at the barber shop you have to do head shots. for a long time. only way to kill trents. if your referaring to the one in the warehouse that is nemisus stand. by teh ammo crate at start and just corner shoot him till empt and reload untill he falls
Answer from: Pat H
Yeah just shoot the tyrants in the head, it took me and my brother a while but it can be done :)
Answer from: stubo
Btw they trents arnt called trents lol haha there called tirants lol just setting u straight
Answer from: jack
Actually its tyrant ans nemesis
Answer from: The Toddinator
They are called Tyants and they are very sensitive to fire. So if you are in a area with a flamethrower take it. Then keep firing it at the tyants head. In no time they will die.
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From: SilverWolf
Posted on: 04-07-2012
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In the Media
3 cool higher-ed changes you may not know about
USA Today identifies Humans vs. Zombies, which originated at Goucher, as part of a trend toward new extracurricular activities in college.
UPDATE: Dean moves on to provost position at Goucher College
The Ithacan covers Leslie Lewis' career move, from dean of the School of Humanities and Sciences at Ithaca College, to provost and vice president of academic affairs at Goucher.
What's in a name affects attitudes: 'rain tax' vs. 'stormwater fee'
This Baltimore Sun article includes the Goucher Poll as it analyzes residents' perceptions of the controversial measure.
Take 10 with Jose Antonio Bowen, Goucher College president
The Baltimore Sun chats with President José Antonio Bowen about some of his most prized possessions, some of which might surprise you.
Editorial: Video applications show clearer picture of students
The University of Pittsburgh features an editorial with thoughts on the Goucher Video Application.
Path to College May Soon Be on Your Smartphone
The radio station KSOO covers the Goucher Video Application's innovative way of opening college admissions.
Linthicum Elementary among 10 2014 National Blue Ribbon Schools in MD
Chesapeake Family magazine recognizes the achievements of one of Goucher's professional development schools, where education majors student teach.
It's not too late: Colleges still accepting applications for fall 2015
The Examiner points out it's not too late to apply to college, including Goucher.
Colleges With the Best Study Abroad Programs
Goucher is ranked No. 1 in this Chacha listing of best places for students who want to study abroad.
Videos replace essays and test scores for some kids' college applications
In this article The Washington Post takes an in-depth look at the Goucher Video Application results so far.


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Love both the grand and petit Trianon, without checking out those two, you won't get a complete look into Louis XIV, XV, XVI and Marie Antoinette's dramatic lives.
Yes they are worth visiting but if you are short of time not a priority. The Great is better; the Petit is interesting but not quite so attractive
Away from the palace grounds this area is much more serene and with fewer people allowing a more tranquil experience. There is an opportunity to spend a reasonable amount of time inside the residence(s) as the unique experience is meandering outside along the trails. This area is less extravagant than the main palace; however, beautiful in its own way.
We visited here in October 2013. We decided to do a day trip as a previous half day trip was disappointing. So glad we took a whole day to visit Versailles as we had time to see the chateau and then hop on the transport taking us to the Trianons and Hamlet. These are quite amazing in their own right...
The two Trianons were much less opulent and also less crowded. They were more the less public time of the royalty. The Hamlet was built for Marie Antoinette as a way to escape as well as reconnect with her native Austria. It's a working farm with lots of goats, sheep, chickens and pigs. Lots of fun for the little ones...
We had seen the Trianons the previous year so we visited the hamlet this time. It was a nice sunny afternoon and the whole experience was relaxing, almost a step back to when it was in its pomp. Make sure you also take in the farm, butting goats were comical. You could see why the queen spent long hours here,...
If the Chateau de Versailles was meant to represent the masculine, public image of French royalty, then the Trianons would represent its feminine, more private side. Not that it was intended to even exist but Marie Antoinette's distaste for court life at the Chateau resulted in the Grand Trianon and the hamlet being built to serve as her retreat. Despite...
After going through the Palace of Versailles, we waked down and rented bicycles to get through the gardens Trianons and Hamlet. I did enjoy the bike ride and the buildings. The grounds were not as beautiful as others have commented, but I think it was because it was November and the fountains weren't on and the statues were covered. You...
We took a tour called "Marie Antoinette's Estate Tour" with paristoversailles.com , she told me she learn a lot about MA and enjoyed a tour in a very peaceful park full of lovely animals!
Trianons et le hameau seems to be a must to see in Versailles!
You have to go to the Hamlet and the Trianons. I recommend it more than taking time in the Palace. Bring bread to feed the fish - it is terrifying and hilarious!
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Country View Rv Park
27202 State Highway 69 S Wagoner, Oklahoma 74467(918) 485-8470
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AboutCountry View Rv Park is located at the address 27202 State Highway 69 S in Wagoner, Oklahoma 74467. They can be contacted via phone at (918) 485-8470 for pricing, hours and directions.
Country View Rv Park provides Event Hosting, On-Site Management, Lunch to it's customers. For maps and directions to Country View Rv Park view the map to the right. For reviews of Country View Rv Park see below.
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"One weekend, my girlfriend Cindy's parents were visiting us in New York City, and I thought it would be great to catch this play that everyone was raving about, so I bought tickets and told everyone they'd love it. But when we got there and the lights went out, we were shocked to see a dude walk onstage naked. I had no clue the play involved a lot of male nudity. By intermission, her parents insisted we leave, and on our way out, I heard her dad whisper to her mom, 'I hope Cindy doesn't marry this weirdo.'" -Frank, 33
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Monthly menu planning - please inspire me with quick, easy, nutritious meals(17 Posts)
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App Information
iTunes Download - £9.99
Developer: Touch Press
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Pyramids 3D Review
Bring the wonders of Egypt to life on your iPad
Giving you the opportunity to explore the stunning sights of Giza, Pyramids 3D brings this historic area to life. Once you open the app, you'll see the Giza plateau displayed in all its glory. You're free to zoom in on any location you wish, or simply drag and swipe across the screen to navigate around the landmarks, including the Great Pyramid, the Sphinx, and more.
Once you tap on a landmark, you can view it in greater detail and read up on its history through the information tab. With most of the pyramids and tombs you're able to enter the buildings and see the internal structures and wall paintings, complete with audio narration.
To complement the exploration side of the app, there is a range of other impressive features on offer. You can learn about objects discovered in the area through archeological digs, read about the history of the Old Kingdom – featuring interactive animations – and even view Then and Now images of the main sights.
Along with all the positives there are a couple negatives. Firstly, the app is a whopping 1GB in size, meaning it'll take up a serious chunk of your iPad's internal storage. Navigation can also be disorientating at times, and it's also quite expensive. However, for anyone fascinated by Egyptian history, or wanting to learn about some of the world's most incredible landmarks, this app is an excellent educational tool.
The visuals and information on offer is remarkable, but the app's size and cost will limit its appeal.
The Icky Mr Fox Review
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Play your iTunes music library via a gallery of album covers with Wall of Sound for iPhone and iPadRead more...
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Add vintage effects to your videos in just two taps with Cine Lumiè for iPhoneRead more...
Lightt – Video life Review
Record and share snippets of your life with the world, thanks to Lightt for iPhoneRead more...


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Description Flute, Harp. Rorem, N more
Lastminute.com are a number one European e-commerce lifestyle player that delight their customers with great-value inspiration and solutions. They have won the following awards: Investor Relations Awa...
Description Speel-studieboek voor de beginnende fluitist. more
Description Speel-studieboek voor de gevorderde saxofonist. more
Description SATB. Brunner, D more
Description Study Score - Hawkes Pocket Score 1263. Torke, M more
Description Flute, Clarinet, Violin, Cello, Piano. Torke, M more
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published 24/02/2008
No charge until you have stayed.
published 23/08/2007
extensive database of hotels, many quite inexpensive
if a hotel cheats you, they will apologize, but do nothing.
published 08/04/2012
Fast, easy to navigate, secure booking, large search database