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Martinmas Lantern Walk
The Early Childhood classes — Miss Kathy, Miss Olga, and Miss Julie — will celebrate Martinmas with a lantern walk during the school day on Friday, November 8. The three classes will walk down to the creek together during their outdoor playtime, to sing songs and leave seeds and crumbs for the forest animals.
Martinmas celebrates the life of St. Martin and reminding us that we each have a light inside of us that we can share with the world. This is a simple celebration, intended to both observe the changing of the seasons and inspire generosity of spirit.
St. Martin was a soldier in Rome in the 4th century. Legend says that one wintry night, he met a poor beggar, half dressed and freezing. Martin removed the heavy cloak from his shoulders and, drawing his sword, cut it in two, and gave half to the beggar. That night, Christ appeared to Martin in a dream, wrapped in the same piece of cloak Martin had given the beggar, and said, "Martin has covered me with this garment." Martin became the patron saint of beggars, drunks, and outcasts, dedicating his life to helping others.
Early Childhood Graham Crackers
Our Early Childhood Extended Care teacher, Kathy Miller, shares one of her favorite recipes from the Morning Glory Playgroup at Prairie Hill Waldorf School.
Home Made Graham Crackers
- 2 ½ Cups Whole Wheat Flour
- ½ Tsp Salt
- ½ Tsp Baking Powder
- ¼ Tsp Cinnamon
- 1 stick of Butter
- 3/4 Cup Honey
Preheat oven to 375. Sift together the flour, salt, baking powder and cinnamon into a bowl. Melt together the honey and butter. Pour this into the dry ingredients. Mix with a fork then push the dough together with your hands. Do not knead or over mix. Place the dough on a well-floured rolling pin to 1/8" thick. Cut rectangles (1 ¼" X3") with a knife and prick them with a fork. Place on a lightly greased baking tray and bake for just 10 minutes. Cool on a rack.
Where Do You Buy Rain Pants?
Welcome to the world of outdoor play, EVERY day! Kids don't care about rain and snow and at Spring Garden they get outside to move three times a day rain or shine, wet or dry, mud or mud. This is why Waldorf schools require proper outerwear for active kids.
Unfortunately, the big box stores don't have these items on the list of back-to-school essentials, so finding a pair of rain pants locally, in August, can be tricky. Besides, if Target had four pairs of rain pants, one of the other 100+ Waldorf families in your area might have snagged them first. And so . . . here are some places where you can buy rain gear for the kiddos before August 27th (6 weeks from today!).
Need it all? Here are three retailers who sell jackets, pants and boots, all in one place:
If you only need Pieces Parts you can shop above or also try:
Oftentimes, each of these retailers will have all these items or run out of stock in one or more items. So, it helps to shop early. And, of course, there's always thrift shopping and swapping with other families!
Openings Now Available in Full Day Preschool
Due to planned expansion, our wait list has cleared and we now have several new openings in our full day preschool program.
Spring Garden Waldorf preschool is a nurturing day focused on fostering the small child's imagination through storytelling, music, outdoor play and artistic activities. It is also an extension of the family experience — full of comfort and routine — a step between home and formal schooling for children age 3-5.
Program Schedule:
For children 3 years old by June 1, we offer:
Three Half or Full Days ~ Wednesday thru Friday ~ 8:30 am to 12:00 pm or 3:20 pm
For children 4 years and older by June 1, we offer:
Five Half or Full Days ~ Monday thru Friday ~ 8:30 am to 12:00 pm or 3:20 pm.
If you have a child you are considering enrolling in 2013, please call or email our Admissions Director, Amy Hecky, at 330-666-0574 and email@example.com.
More Information:
The day's activities unfold in an unhurried way with each day following the same rhythm, giving the child a sense of security and consistency.
The program is based on the understanding that young children learn primarily through imitation. The sharing of practical activities such as snack preparation and clean up starts the child on the path toward personal responsibility and respect for others.
Early academic foundations are formed. Work with beeswax modeling cultivates small motor skills, puppetry helps children develop memory and language acuity, and nature walks increase large motor abilities and attention span.
Call and email to learn more: 330-666-0574 and email@example.com.
The Case for a Summer Slowdown
If you Google, "Summer break with children," you get two types of search results — a variety of activity lists or articles about the evils of summer's off. Turns out they call it "summer fade," which is a one month backslide in learning coupled with an increase in Body Mass Index (BMI) for kids.
Many parents counter these issues with a rigorous schedule of summer camps, sport practice and tutoring. While watching television all day with a box of pop tarts is obviously not good, there are some other options beyond a highly structured and scheduled summer.
When planning, or not planning your child's summer, consider the scientifically proven benefits of boredom, free play and time in nature. These research studies about children and learning support the idea of a summer slowdown.
In a recent BBC news article, Children should be allowed to get bored, Dr Teresa Belton said, "Cultural expectations that children should be constantly active could hamper the development of their imagination."
Now couple that reality with studies connecting time in nature with increased learning and emotional capabilities. The positive results of being outdoors for children are vast as seen in this PDF of a decade of Scientific Studies on this topic. Some highlights include:
- "When children engage in authentic play in nature-based outdoor spaces, they develop skills in a variety of domains simultaneously." – Miller, D.L., Tichota, K,.White, J. (2009).
- "Sullivan has revealed that the symptoms of children with Attention Deficit Disorder (ADD) are relieved after contact with nature. The greener the setting, the more the relief." – Taylor, A., Kuo, F. & Sullivan, W. (2001).
- "Children who regularly have positive personal experiences with the natural world show more advanced motor fitness, including coordination, balance and agility." – Fjortoft, Ingunn (2001).
In addition to the learning benefits to boredom and time in nature, there is also the issue of free play. This article from Parenting Science explores over a decade of studies about the benefits of unstructured play time. The author is careful to note that free play does not mean physcial education classes or sports. Free play is just that. Unstructured play time, which is proven to help math skills, language development, and creative problem solving.
- "Play and exploration trigger the secretion of BDNF, a substance essential for the growth of brain cells."
- "Psychologist Edward Fisher analyzed 46 published studies of the cognitive benefits of play (Fisher 1999). He found that "sociodramatic play"—what happens when kids pretend together—'results in improved performances in both cognitive-linguistic and social affective domains.'"
And finally, before you schedule a summer of busy stimulation, consider this article and advice from Simplicity Parenting writer Kim John Payne. He says:
"[When Google is hiring they say] 'we're less concerned about grades and transcripts and more interested in how you think.'"
If we rewind to a childhood that makes an adult like that, what do we see? Is it racing around from one prep course to another? From soccer to piano to Mandarin? A childhood on the clock and filling up the gaps with zoning on the iPad and obsessing about making more friends on Facebook?
I don't think so.
When we really look at what happens for a kid when they slow down, tune in to themselves, take space and get busy in serious play, we can see that what they are learning is how to be create a kind of inner structure that will serve them (and us) well in the world ahead. … Play provides a deep and wide-reaching domain for kids to experiment with the real work of the real world."
Teacher Communication – Early Childhood
Here at Spring Garden, parents receive regular communication from class teachers about what the children are learning and what the teacher's are observing. We wanted to give an example here on our blog of our thorough, and some might say, inspired, teacher communication.
This letter is from our Extended Care, Early Childhood teacher, Kathy Miller:
Dear Extended Care Families,
The children came back from holiday break relaxed, calm and happy to see one another. The afternoon life rhythm here at Spring Garden has become such a strong part of the children's daily life that with only a few gentle reminders we were able to get back into the swing of things. It was like we had never been away from one another.
As a mother and teacher I always like to stress the importance of a daily life rhythm. Having a consistent routine (rhythm) is also a preventative to illness, builds an inner knowing of time, makes transitions easier, eliminates discipline problems, builds trust in children's surrounding environment and overall decreases stress in children because they always knows what is going to happen next. Wow, all these benefits when we simply provide a rhythmical daily.
There have been a few questions/requests from parents regarding lunch meal requirements. The following table provides the elements of a recommended healthy lunch and some ideas for meals.
Bread/Bread alternative (1 serving) Sandwiches Crackers Rolls/muffins/cornbread Cereal-hot/cold Grains –oats, barley, millet, couscous Rice dish Pasta Mashed potatoes Soup |
Fruit & Veggies (2 servings) All types of fruits and Veggies. Recommended amount( ½ cup of each) 1) 2 servings of veggies 2) 2 servings of fruit 3) 1 serving of each (fruit cereal bars, fruit snacks, fruit roll ups, juices etc… do not count as one serving of fruit) |
Protein (1 serving) Milk (1 cup) Meat/Meat alternative (2 oz) Yogurt (¾ cup) Cheese (1 ½ oz) Peanut butter/or other nut or seed butter (3 TBS) Peanuts/soy nuts/tree nuts/seeds (3/4 oz) Cooked or dry beans or peas (1/2 cup) |
I have recently introduced the Old Mother West Wind Series for the nap time story. The chapter book tells about the adventures of animals that live in the "Green Forest". Throughout this series the children have been introduced to many different animal characters such as; Bobby Raccoon, Johnny Chuck, Jimmy Skunk, Jerry Muskrat, Grandfather Frog and Danny Meadow Mouse just to name a few. I read one to two chapters every day. Many children have captured these characters into their hearts as I've heard children question, to each other, whether the animals live in our woods next door.
Before winter break I mentioned that we were going down to the woods to play in the afternoon. I strive to go there every afternoon. However, it does depend how sleepy our children are and how the nature of the afternoon is unfolding that will predict whether we get there or not. With this being said, dismissal area has become different on a daily basis. If we are not in the meadow playing, it means we have made it to the woods and therefore dismissal will be in the hallway at 3:20 pm. If we are in the woods and you need to pick up earlier then 3:20 pm, please see Hazel at the front desk and she will verbally guide you down to where we play. You could also check the extended care room. Your child may still be in the room with Ms. Lori as she is helping the last group of children get ready to go outdoors.
The play area in the woods is quite, still and very magical this time of year. Together many of the kindergartners have created a home out of large sticks (tee pee like). I've observed children sweeping the ground with large sticks preparing the home. Some children have gone fishing (large wet soggy leaves have become large tasty fish) for dinner in the large puddle of standing water not too far from where the home was built. Sometimes the roof of the home falls in and the children call the 'roofers' to come and fix it. It really is magical to see all the children working together. The preschoolers continue to explore the open area. They are busier with moving their bodies. They climb and swing from fallen logs and branches. Some love to dig in the large dirt mounds. Some love running up and down the hill that guides them to the play area. The paths in our play space have slowly come to life again with work from teachers and children. These paths provide a large running area for all the children.
With a very chilly week a head of us, please remember to dress your child in layers. To dress in layers please consider the following; three layers on top for example: t-shirt, long-sleeve cotton shirt or sweater and two layers on the bottom for example: cotton PJ or long underwear & Pants. Going outside in cold weather provides opportunity for physical movement and sensory experiences. When the children dress for the outdoors we guide them in the following way; snow pants, boots, jacket, hat, scarf, and mittens/gloves. All children are encouraged to dress themselves. It is important to provide children with outdoor gear (including boots) to be successful in dressing themselves. This is the time of year we begin to get older kindergartners prepared for 1st grade, which includes dressing self.
Based upon the different areas I have touched on in this newsletter, there are follow up articles located in the Early Childhood Hallway, (by Extended Care Classroom on round table by double doors). Feel free to take and read.
As always if there are any questions or concerns do not hesitate to email or call me.
Stay warm on this chilly day!
Ms. Kathy
Mitten Strings for God; Reflections for Mothers in a Hurry by: Katrina Kenison (Rhythm)
Illness By: Gudrun Davy (Trust, Blessing of a fever, Illnesses of Civilization)
More Nutrition Ideas By: Susan R. Johnson, MD. (Guidelines about the foods we eat & health)
Do Kids Catch Cold Outside? By: Robert Needleman, M.D & Gloria Needleman

subset: commoncrawl


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The Intercontinental Kansa City at the Plaza is literally a block and a half from the Plaza, and at night, has a spectacular view of the Plaza. The staff are helpful and friendly. Like it has been noted in other reviews, I was surprised about the internet and the difficulty I had with the internet in this facility. I had to call for help 3 times in 48 hours. I will not discuss the cost as several other high end hotels have also charged. I think this is one of the perks that should be offered. The buffets I had while dining here were very good and this is surprising for a hotel buffet. Overall, a nice place to stay.
- Official Description (provided by the hotel):
- Welcome to the InterContinental Kansas City at the Plaza, where you will find impeccable service and all the luxuries you have come to expect from an InterContinental Hotel. Our luxuriously appointed guest rooms and superb meeting facilities are all just steps away from the Country Club Plaza entertainment district. ... more less
- Reservation Options:
- TripAdvisor is proud to partner with IHG, Booking.com, Expedia, Priceline, Travelocity, Hotels.com, Despegar.com, Agoda, Odigeo and Tingo so you can book your InterContinental Kansas City at the Plaza reservations with confidence. We help millions of travelers each month to find the perfect hotel for both vacation and business trips, always with the best discounts and special offers.
- Also Known As:
- Intercontinental Kansas City At The Plaza Hotel Kansas City
- Kansas City Intercontinental
- Fairmont Hotel Kansas City


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US 5227407 A Abstract The addition of water into a Fischer-Tropsch hydrocarbon synthesis reaction zone employing passing a CO and H2 feed mixture over a catalyst comprising cobalt, ruthenium and mixtures thereof preferably on a titania support and which may include a promoter metal, that results in 90% CO conversion to hydrocarbons and increased C5 + hydrocarbon selectivity, along with a decrease in methane production.
Claims(10) 1. A once-through, fixed or slurry bed Fischer Tropsch process with enhanced CO conversion activity and C5 + liquid hydrocarbon selectivity comprising contacting a feed mixture of carbon monoxide and hydrogen in a reaction zone with about 1 Vol % to about 70 Vol % water based on the total volume of feed mixture, at a pressure above one atmosphere and a temperature ranging from about 150� C. to about 300� C., with a catalyst selected from the group consisting of cobalt, ruthenium, and mixtures thereof on a titania support, wherein said titania support is less than 40 m2 /g, converting at least 90 Vol % of the carbon monoxide to liquid hydrocarbons, and in the substantial absence of CO2 formation.
2. The process of claim 1 wherein the said catalyst is promoted with one or more promoter metals when said catalyst is a cobalt catalyst.
3. The process of claim 2 wherein said promoter metal is selected from the group consisting of Re, Hf and mixtures thereof.
4. The process of claim 3 wherein said catalyst contains rhenium promoter metal.
5. The process of claim 1 wherein the mole ratio of H2 to CO in the feed ranges from about 0.5 to 6.
6. The process of claim 2 wherein the amount of cobalt catalyst ranges from about 2 wt % to about 25 wt % based on the total catalyst weight.
7. The process of claim 1 wherein the amount of ruthenium ranges from about 0.1 to 20 wt % ruthenium metal based on the total catalyst weight.
8. The process of claim 4 wherein the rhenium to cobalt ratio in said catalyst composition is greater than about 0.01 to 1.
9. The process of claim 2 wherein the CH4 selectivity is less than about 10%.
10. The process of claim 1 wherein the CO2 produced in the process is less than about 2% based on feed.
Description This is a continuation-in-part of copending U.S. Ser. No. 676,640 filed March 28, 1991 (abandoned Mar. 24, 1992), which is a continuation-in-part of U.S. Ser. No. 417,384, filed Oct. 5, 1989 (abandoned Mar. 28, 1991), which is a continuation-in-part of U.S. Ser. No. 237,355, filed Aug. 29, 1988 (abandoned Oct. 5, 1989), which is a continuation-in-part of U.S. Ser. No. 084,629, filed Aug. 11, 1987 (abandoned Aug. 29, 1988), which is a continuation-in-part of U.S. Ser. No. 814,679 filed Dec. 30, 1985 (abandoned Aug. 17, 1987), based on U.S. Ser. No. 313,565, filed Feb. 21, 1989 (abandoned Oct. 5, 1989), which is a Rule 60 continuation of U.S. Ser. No. 115,971, filed Nov. 2, 1987 (abandoned Feb. 21, 1989), based on U.S. Ser. No. 541,659, filed June 21, 1990 (abandoned Apr. 15, 1991), which is a Rule 60 continuation of U.S. Ser. No. 185,953, filed Apr. 25, 1988 (abandoned Jan. 31, 1991). This invention relates to a water addition process for increasing the activity of a Fischer-Tropsch, fixed bed or slurry bed, hydrocarbon synthesis reaction over a catalyst comprising metals selected from ruthenium, cobalt and mixtures thereof. The catalyst preferably will be supported on a support containing titania. However, where cobalt metal is used, the catalyst may be in bulk form. More particularly, this invention relates to increasing catalyst activity by decreasing the methane make, increasing the CO conversion and increasing C5 + hydrocarbon selectivity of a Fischer-Tropsch hydrocarbon synthesis process which comprises feeding a mixture of H2, CO and H2 O into a reaction zone containing a catalyst comprising metals selected from ruthenium, cobalt and mixtures thereof in the reduced, metallic form wherein said mixture contacts said catalyst at elevated temperature for a time sufficient to convert at least a portion of said feed to C5 + hydrocarbons. The production of hydrocarbons from mixtures of H2 and CO via the Fischer-Tropsch process is well known to those skilled in the art. As opposed to the well-known "methanization" process which produces methane as synthetic natural gas from mixtures of H2 and CO, the Fischer-Tropsch process is more generally aimed at producing higher value products such as chemical feedstocks and liquid fuels. Thus, high methane make is undesirable in Fischer-Tropsch synthesis processes because it is a relatively low value product which is formed at the expense of more desirable products. It is also uneconomical to try to convert the so-formed methane back into a CO and H2 mixture and recycle it back into the reactor. Methane make in Fischer-Tropsch reactions is often expressed by a term known as methane selectivity. Methane selectivity can be defined by either of two methods. They are: (a) mole % CH4 produced based on the amount of CO consumed or (b) weight % of CH4 produced based on total hydrocarbon products formed. Many different catalysts and processes have been disclosed for Fischer-Tropsch synthesis, some of which have extremely high methane make. Thus, U.S. Pat. No. 4,077,995 discloses synthesis of C1 -C4 aliphatic hydrocarbons over a catalyst comprising a sulfided mixture of CoO, Al2 O3 and ZnO while U.S. Pat. No. 4,039,302 discloses C1 -C3 hydrocarbon production using a mixture of the oxides of Co, Al, Zn and Mo. U.S. Pat. No. 4,151,190 discloses producing C2 -C4 hydrocarbons from mixtures of CO and H2 using a supported catalyst comprising a metal oxide or sulfide of Mo, W. Re, Ru, Ni or Pt plus an alkali or alkaline earth metal, with Mo-K on carbon being preferred. U.S. Pat. Nos. 4,243,553 and 4,243,554 disclose MoS2 as a Fischer-Tropsch catalyst. Many other catalysts are known to be useful for Fischer-Tropsch synthesis employing metals such as iron, copper, titania, etc. These are known to those skilled in the art. The type of catalyst used and process conditions employed have an important bearing on CH4 selectivity. For example, nickel gives a high CH4 selectivity and is used mainly as a methanization catalyst. Methane selectivity usually increases with increasing temperature, decreasing pressure and increasing the H2 /CO ratio of the feed. Accordingly, process conditions are selected so as to minimize CH4 selectivity while maintaining a relatively high reaction rate as is well known to those skilled in the art. It is known that CH4 selectivity is influenced by the choice of promoter and support, such as alkali metal promoters reducing CH4 selectivities of iron catalysts. It is also known in the art that noble metals such as ruthenium supported on inorganic refractory oxide supports exhibit superior hydrocarbon synthesis characteristics with relatively low methane production. Thus, U.S. Pat. No. 4,088,671 suggests minimizing methane production by using a small amount of Ru on a cobalt catalyst. Examples of supported ruthenium catalysts suitable for hydrocarbon synthesis via Fischer-Tropsch reactions are disclosed in U.S. Pat. Nos. 4,042,614 and 4,171,320. It is also known that the type of support used also influences methane production. In the case of supported ruthenium catalysts, the use of a titania or titania containing support will result in lower methane production than, for example a silica, alumina or manganese oxide support. European patent application 83201557.2 relates to a Fischer-Tropsch hydrocarbon synthesis process employing, as a catalyst, cobalt supported on silica promoted with zirconium, titanium or chromium wherein the cobalt is deposited on the silica carrier by a kneading process. In this process, 10 to 40 volume percent steam is added to the feed, based on the H2 /CO/H2 O mixture. The amount of cobalt present in the catalyst is 10-40 pbw based on 100 pbw of silica. In the examples, very little enhancement in either CO conversion of C3 + selectivity is shown as a result of the water addition to the feed. U.K. patent application 2,146,350A relates to a Fischer-Tropsch hydrocarbon synthesis process employing a similar catalyst, followed by a hydrocracking process wherein the Fischer-Tropsch products are hydrocracked over a noble metal catalyst. The same type of catalyst is also used in the Fischer-Tropsch processes described in U.K. patent application nos. 2,149,812A and 2,149,813A. U.S. Pat. No. 4,628,133 discloses the use of steam with a cobalt/silica catalyst and reports that activity decreased with the addition of water while selectivity to C9 + products increased. Thus, the overall yield of valuable products decreased but the selectivity to certain products was enhanced. In Satterfield et al., AIChE Journal, #3338, p.E7, July 1985, water addition over iron based catalysts again showed decreased activity although the effect was reversible upon removal of the water. U.S. Pat. No. 3,927,999 relates to a process for producing a methane rich fuel gas containing 70 to 98 mole % methane by contacting a mixture of H2, CO and H2 O with a suitable catalyst at elevated temperature. This invention is based on the discovery that the methane content of the product gas from the methanator is maximized by adjusting the mole % H2 O in the synthesis gas feed to a critical value in the range of 1 to 3, while maintaining the H2 /CO mole ratio of the synthesis gas feed to a critical value in the range of about 1 to 1.15. The feed gas may also contain methane. Group VIII transition metals such as iron, nickel and cobalt are suggested as suitable catalysts, but only nickel on alumina is actually used. Example 1 shows the production of a fuel gas containing 96.4 mole CH4 from a feed gas containing 48.1 mole % CH4 over a catalyst containing nickel, thoria, magnesia and kieselguhr. U.S. Pat. No. 2,479,439 relates to a process for alternately increasing the activity of an alkali metal promoted, powdered iron catalyst or decreasing the coke buildup thereon, or accomplishing both simultaneously by passing an aqueous solution of alkali metal salt, such as KF, into the hydrocarbon synthesis reaction zone to contact the iron catalyst. The presence of the water is said to remove carbon from the iron catalyst. U.S. Pat. No. 2,539,847 relates to a Fischer-Tropsch hydrocarbon synthesis process employing a catalyst consisting of thoria promoted cobalt supported on bentonite. U.S. Pat. No. 4,568,663 relates to a Fischer-Tropsch hydrocarbon synthesis process employing a rhenium cobalt on titania catalyst. The Fischer-Tropsch (FT) process, the process to which this invention relates, must also be distinguished from the well known Kolbel-Engelhardt (KE) process (described, for example, in Canadian Patent No. 530,932). The FT process may be described by equation (1), the KE process by equation (2). 2nH2 +nCO→-(CH2)n -+nH2 O (1) nH2 O+3nCO→--(CH2)n -+2nCO2 ( 2) The two processes may appear similar in that they yield similar products and can employ Group VIII metals as catalysts. The reactions are not similar because their reaction paths differ. In FT synthesis, in the absence of substantial water gas shift, at least about 90% of the CO is converted to hydrocarbon products. However, in KE, up to only about 33% of the CO is converted to hydrocarbon products. FT yields H2 O as a product while KE consumes H2 O as a reactant and generates CO2 as a by-product. The reactions can be distinguished in that in FT there is no net consumption of H2 O, whereas in KE there is net consumption of H2 O. Even if hydrogen is added to the reaction mixture for KE, water will be consumed. Equation two indicates that for every three moles of carbon monoxide consumed, two moles of carbon dioxide are necessarily produced. If carbon monoxide were to be 100% converted, two-thirds would be converted to carbon dioxide. This ratio holds throughout the KE synthesis. Therefore: Moles of CO converted�2/3=Mole of CO converted to CO2 Moles of CO converted�1/3=Moles of CO converted to hydrocarbon The present invention teaches the nonwater gas shift Fischer-Tropsch hydrocarbon synthesis using a noniron catalyst. Under ideal conditions, for every 100 moles of carbon monoxide converted, 0 moles of carbon dioxide are produced. Clearly the present invention is different from the KE synthesis. A further differentiation of the KE process is shown in Chaffee, et al., Applied Catalysis, 19, p. 419-422 (1985) where the KE reaction produces relatively high levels of aromatic products. The process of this invention by contrast produces substantially all paraffins. Ruthenium catalysts for use in Fischer-Tropsch synthesis were first discovered by Pichler (see H. Pichler, Brennstoff-Chem. 19, 226 (1938) and H. Pichler, and H. Bufflet, Brennstoff-Chem. 21, 247, 273, 285 (1940) that Ru catalyst can produce H2 /CO mixtures at low temperature and high pressures, very high molecular weight waxes of about MW 1000 and above, i.e., polymethylenes, having melting points of 100� C. and above. Karn, et al., I&EC Product Res. & Devel. 4, 265 (1965) describe the reactivity of ruthenium on alumina catalysts in producing hydrocarbons ranging from C1 -C30 + including runs made at 21.4 atmospheres pressure, 300/hr. space velocity, temperature of 220�-240� C. and H2 /CO molar ratios of 1 to 4 resulting in % CO conversions of 46-82%. U.K. Patent Application 2,024,246A describes a hydrocarbon synthesis process for hydrocarbons in the C5 -C12 range, in which mixtures of H2 CO are contacted with a supported ruthenium catalyst, preferably on alumina at elevated temperature. A criticality of the process is described wherein the outlet CO partial pressure must be not less than 0.8 atmospheres at a process temperature of about 500�-525� K. and not less than 3.0 atmospheres in the temperature range of 525�-550� K. R. J. Madon in J. of Catalysis 57, 183-186 (1979) describes the C5 -C20 production of hydrocarbons in Fischer-Tropsch processes utilizing ruthenium on alumina catalyst. U.S. Pat. Nos. 4,042,614, 4,042,615 and 4,116,994 to Vannice and Garten disclose ruthenium, nickel and rhodium, respectively, supported on titania and titania-containing supports as Fischer-Tropsch catalysts for producing hydrocarbons from mixtures of CO and H2. Ko and Garten in Ethane Hydrogenolysis Studies of TiO2 -Supported Group VIII Metal Catalysts, J. Catalysis, v. 68, pp. 233-236 (1981) disclose each and every one of the Group VIII metals on both silica and titania supports as ethane hydrogenolysis catalysts. Vannice, in a 1982 article titled Titania-Supported Metals as CO Hydrogenation Catalysts, J. Catalysis v. 74, pp. 199-202 (1982), discloses each one of the Group VIII metals, except osmium, supported on a titania support for Fischer-Tropsch synthesis of hydrocarbons. In this article, Vannice states that rhodium and ruthenium on titania did not have as high a CO conversion activity as nickel on titania, but produced more useful hydrocarbons and less methane make than nickel on titania. Wells, et al., in a 1982 article titled "Supports Effects in the Ruthenium Catalyzed Hydrogenation of Carbon Monoxide," appearing on pages 247-254 of Metal-Supported and Metal-Addition Effects in Catalysis, Imelik, et al. (Ed.), Elsevier 1982, also disclose ruthenium supported on titania as a Fischer-Tropsch catalyst. This article compares both the CO conversion activity and the CH4 production activity of ruthenium on both anatase and rutile containing titania. Wells et al. found that the CO conversion activity was substantially greater for ruthenium on anatase titania than for ruthenium on rutile titania. The methane activities were fairly similar. Another article on pages 337-348 of the same book by Reymond, et al., titled Influence of the Support or of an Additive on the Catalytic Activity in the Hydrocondensation of Carbon Monoxide by Iron Catalysts compares iron on various support materials as Fischer-Tropsch catalysts. FIG. 2 of this article compares the activities, in terms of methane production, or iron on both anatase is shown to be substantially greater than rutile. U.S. Pat. No. 4,477,595 to R. J. Madon discloses a Fischer-Tropsch process for selectively producing paraffinic hydrocarbons employing a catalyst comprising ruthenium supported on an inorganic refractory metal oxide support, preferably wherein the support material includes titania or various titanates and wherein the ruthenium metal loading on the catalyst may range from 0.01 to 15 wt. %. S. R. Morris, et al., in "Metal-Support and Metal-Additive Effects in Catalysis," Ed. B. Imelik et al., Elsevier, 1982 disclose a ruthenium supported on titania catalyst used in Fischer-Tropsch catalysis wherein the amount of the supported ruthenium range from 2 to 17 wt. %. This article discloses no trend in CH4 selectivity or paraffin olefin ratios as a function of the Ru loading level on the catalyst. C. H. Yang, et al., in "Physical Effects on Fischer-Tropsch Synthesis Over Composite Ru Catalysts," Canadian J. Chem. Eng., 61, 213-217 (1983) employed a mixture of catalysts for Fischer-Tropsch synthesis. The catalysts both employed 6.5 wt. % ruthenium. In one case the support was titania and in the other catalyst the support was a mixture of titania and silica in a 1:4 volume ratio. The minimum methane make was reported as being about 20%. Dautzenberg, et al., "Pulse-Technique Analysis of the Kinetics of the Fischer-Tropsch Reaction," J. of Catalysis, 50, 8-14 (1977) employed ruthenium supported on alumina as a catalyst. After hydrogen reduction at 350� C., the catalyst was then contacted with a mixture of CO/H2 at 210� C. from 4-12 minutes followed by 14 minutes on pure H2, followed by 4 minutes with CO/H2. The object was to observe product formation under such short exposure to CO/H2 reagents. Toshiaki-Mori, et al., in "Promoting Effect of V, Mo, W, and Re on the Rate of C-O Bond Dissociation of Adsorbed CO in Methanation on Ru/A1203," J. Chem. Society Commun. 678-679 (1984) disclose promoting Ru/A1203 catalysts with various metals at a Ru loading of 0.5 wt. %. This was also a pulse technique and not a steady-state reaction and the product was almost all methane. Stowe, et al., in "Optimize Syngas to Naphtha Over Ruthenium Catalysts," Hydrocarbon Processing, 95-100 (June, 1984) disclose Ru on various aluminas at a Ru loading level of 0.5, 1.0 and 2.0 wt. %. E. Kikuchi, et al., in "Fischer-Tropsch Synthesis Over Titania-Supported Ruthenium Catalysts," Applied Catalysis, 10, pp. 251-260 (Elsevier, 1984) employed ruthenium on both titania and alumina supports at a ruthenium loading range from 0.5 to 2.0 wt. %. In all cases, their data shows a minimum methane make of 16 wt. % with a titania support and 25 wt. % with an alumina support. There exists a need in the art for Fischer-Tropsch processes useful for the conversion of mixtures of CO and hydrogen to C5 + hydrocarbons at high CO conversion levels, and high hydrocarbon yields, with relatively low methane make. It has now been discovered that in a fixed or slurry bed, nonrecirculating Fischer-Tropsch hydrocarbon synthesis reaction for producing C5 + hydrocarbons from a gaseous feed mixture of H2 and CO in the presence of a catalyst comprising bulk cobalt or metals selected from cobalt, ruthenium and mixtures thereof, mounted on a titania support, one can increase both the CO conversion activity and the C5 + hydrocarbon selectivity and, at the same time, decrease the methane make by adding H2 O to the reaction zone. The present invention relates to a nonrecirculating Fischer-Tropsch process for synthesizing C5 + hydrocarbons by introducing into a catalytic reaction zone a feed mixture of CO and H2 and added H2 O wherein said CO and H2 feed mixture react with a catalyst comprising metals selected from ruthenium, cobalt and mixtures thereof, where the catalyst has a titania containing support. Where cobalt metal is used, the catalyst may be in bulk form. The reaction is conducted at elevated temperatures for a time sufficient to convert at least a portion of said feed to C5 + hydrocarbons. By cofeeding H2 O into the reaction zone, along with the H2 and CO feed mixture, it has been found that C5 + hydrocarbon production is increased, CO conversion is increased such that at least about 90% of the CO is converted to hydrocarbon products and CH4 production is decreased. The increase in activity and selectivity is effected in the substantial absence of CO2 formation (less than about 2% based on feed). In one aspect of the invention, the catalyst may be cobalt alone as in the reduced, metallic form, preferably a high surface area cobalt such as cobalt black or a more conventional preparation such as cobalt on titania. The H2 O that is added to the reaction zone may be in the form of steam or moisture or a suitable H2 O precursor, such as C1 -C6 alcohols, for forming H2 O in-situ in the reaction zone. It is essential to the understanding of the process of this invention that the H2 O introduced into the reaction zone is external H2 O that H2 O which is formed in-situ in the reaction zone as a consequence of the Fischer-Tropsch hydrocarbon synthesis reaction from the H2 and CO. It has also been found that the process of this invention improves with increasing pressure in the reaction zone and with decreasing CO conversion. The addition of water to the reaction process does not aid all catalysts. In fact, water addition is catalyst specific. For example, water addition has no advantageous effect on iron based catalysts and shows a selectivity advantage but an activity debit with cobalt/silica catalysts. By contrast, for example, catalysts such as cobalt black and cobalt on titania show advantageous results for water addition for both activity and selectivity, particularly with regard to C10 + paraffins. In a preferred embodiment of the invention, the synthesis gas feed, carbon monoxide and hydrogen is substantially free of ,and preferably completely (except for trace amounts) free of methane or other light hydrocarbons. The hydrocarbon free synthesis gas feed is easily accomplished in a once-through system where there is no recycle of unconverted hydrogen and carbon monoxide (along with undesirable light hydrocarbons) directly to the hydrocarbon synthesis reaction zone. Preferably, the synthesis gas feed contains only H2, CO and water and is substantially free of light hydrocarbons, e.g., methane. Allowable limits on light hydrocarbons in the synthesis gas feed are no more than about 1 vol. % and preferably less than about 0.5 vol. The process of the present invention resides in adding, to the Fischer-Tropsch reaction zone, H2 O or a suitable H2 O precursor such as an alcohol. The amount of H2 O added to the reaction zone will range from about 1-70 volume % of the total feed mixture of H2 O, CO and H2 and, preferably, from about 5-30 volume As the extent of CO conversion increases, the amount of water produced in-situ in the reaction zone increases and, concomitantly the beneficial effect of introducing additional water into the reaction zone to increase CO conversion, reduce CH4 selectivity and increase C5 + hydrocarbons selectivity decreases. Thus, in some cases, it may be advantageous to practice the process of this invention at CO conversion levels below about 60 percent. That is, below about 60% per pass, reaction zone, or stage. As the pressure in the reaction zone increases, the beneficial effect of the process of this invention of adding water to the reaction zone increases with respect to increasing CO conversion activity, decreased CH4 selectivity and increased C5 + hydrocarbon selectivity. At relatively low pressures in the reaction zone (i.e., less than about 1 atmosphere), little effect will be seen in increased conversion activity, etc. by adding H2 O to the reaction zone. Thus, the process of this invention will be operated at a pressure above about one atmosphere. In general the pressure will range from about 1-50 atmospheres, and more preferably 5-30 atmospheres. In the process of this invention, the addition of H2 O enhances the formation of C5 + hydrocarbons, particularly C10 + hydrocarbons and reduces CH4 make in a uni-directional or linear fashion. It has also been found that the rate of the Fischer-Tropsch reaction employing the process of this invention increases with increasing partial pressure of H2 O at any fixed total pressure in the reaction zone, up to a point, after which point the rate slowly goes down with continually increasing H2 O partial pressure. In general, the Fischer-Tropsch hydrocarbon synthesis reaction process of this invention is carried out at a H2 :CO mole ratio of greater than about 0.5, and preferably the H2 :CO mole ratio ranges from about 0.5 to about 6, more preferably from about 0.5 to about 3, and still more preferably from about 1.50 to about 2.1 at gas hourly space velocities ranging from about 100 V/Hr/V to about 5000 V/Hr/V, preferably from about 300 V/Hr/V to about 1500 V/Hr/V, at temperatures ranging from about 150 C to about 300� C., preferably from about 180� C. to about 240� C., and pressures above about 1 atm, preferably ranging from about 1 atm to about 50 atm, more preferably from about 5 atm to about 40 atm and still more preferably from about 5-30 atmospheres. As previously stated, the hydrocarbon synthesis process of this invention employs a catalyst comprising cobalt in its reduced, metallic-form, preferably a high surface area cobalt such as cobalt black. The cobalt may be in the form of a finely divided powder, or granules which may be mixed with a suitable diluent to aid in heat transfer and removal from the reaction zone. The cobalt may be supported on a suitable support material, such as cobalt plated on carrier metal. The cobalt in bulk form, or plated, explosion-coated, etc. may also be in the form of various high surface area shapes such as spirals, metal wool, honeycomb configurations, etc., the choice being left to the practitioner. The hydrocarbon synthesis process of this invention may also employ a catalyst comprising ruthenium supported on TiO2. This catalyst will also be a particulate catalyst composition containing a catalytically active amount of ruthenium. In general, the ruthenium metal loading on the titania support will generally range from about 0.1 to 20 wt. % ruthenium metal and preferably from about 0.1 to 10 wt. % based on the total catalyst weight. These percentages refer to the ruthenium metal in the reduced metal form. When supported catalysts are employed, for example, cobalt on a support such as titania, the improvement in the process from the addition of water is apparent only with supports of a relatively low surface area. Thus, supported cobalt catalyst preferably have a surface area of less than about 40 square meters per gram of catalyst (BET). The preferred support, therefore, is titania which has a surface area of less than about 40 m2 /gm. As previously mentioned, other supports do not show the combined result of increased activity and increased selectivity with the addition of H2 O. A preferred titania support is one that is primarily TiO2, preferably greater than about 50% titania, more preferably at least about 75% titania, and still more preferably substantially completely TiO2, and has a rutile content of at least 40 wt. %. The rutile anatase weight ratio is preferably about 3:2 and is determined by ASTM D3720-78: Standard Test Method for Ratio of Anatase to Rutile in Titanium Dioxide Pigments by Use of X ray Diffraction. The titania supported catalyst can be prepared by a variety of known techniques, e.g., by gelation, or cogelation. Suitably, however, the cobalt can be deposited on a previously pilled, pelleted, beaded, extruded, or sieved support material by the impregnation method. In preparing a cobalt based catalyst, the cobalt is deposited from solution on the support in preselected amounts to provide the desired absolute amounts. When promoter metals are employed, such as rhenium and hafnium and mixtures thereof, the metal amounts deposited should also reflect the weight ratios of each metal. Preferably the promoter will comprise rhenium alone. The promoter, if used, will be added to the catalyst in an amount to form a catalyst having a promoter:cobalt weight ratio greater than about 0.010:1, preferably from about 0.025:1 to about 0.10:1. In terms of absolute concentrations, from about 0.05 percent to about 3 percent of rhenium, preferably from about 0.15 percent to about 1 percent of promoter, based on the total weight of the catalyst composition (dry basis), is dispersed with the catalytically active amount of cobalt on a titania support. In terms of absolute concentrations, cobalt is present in the composition in amounts ranging from about 2 percent to about 25 percent, preferably from about 5 percent to about 15 percent, based on the total weight of the catalyst composition (dry basis), and sufficient promoter, such as rhenium, is added to form a catalyst having a weight ratio of rhenium:cobalt greater than about 0.010:1, preferably from about 0.025:1 to about 0.10:1, based on the total weight of the cobalt and rhenium contained in the catalyst composition (dry basis). The absolute concentration of each metal will, of course, be preselected to provide the desired ratio of rhenium:cobalt as heretofore expressed. The catalysts useful in this invention are prepared by depositing the metal or metal precursor component onto the support material from a precursor solution using any of the well-known techniques such as incipient wetness, multiple impregnation, pore-filing, etc. the choice being left to the convenience of the practitioner. Suitably, one metal can be first composited with the support, and then the other; or both may be added simultaneously. The amount of impregnation solution used should be sufficient to completely immerse the titania, usually within the range from about 1 to 20 times the carrier by volume, depending on the metal, or metals, concentration in the impregnation solution. The impregnation treatment can be carried out under a wide range of conditions including ambient or elevated temperatures. The catalyst, after impregnation, is dried to remove solvent and/or water by heating. In the case of cobalt metal, the drying temperature is above about 25� C., preferably between about 65� C. and 150� C., in the presence of nitrogen or oxygen, or both, in an air stream or under vacuum. In the case of ruthenium metal, drying is performed at a relatively low temperature of less than about 100� C. and slowly raising the temperature to between 200� and 500� C. Drying is conducted for a time sufficient to reduce the metal precursor on the support material. The metal or metals contained on the catalyst can then be reduced. Reduction is performed by contact of the catalyst with hydrogen or a hydrogen containing gas stream at temperatures ranging from about 150� C. to about 565� C. for periods ranging from about 0.5 to about 24 hours at from about 100 kPa to about 4000 kPa, depending on the nature of the metal precursor and impregnation or deposition technique employed and the extent of catalytic metal loading desired for the final catalyst. A gas containing hydrogen and inert components, or a gas containing hydrogen and carbon monoxide in admixture are satisfactory for use in carrying out the reduction. Suitably, the cobalt on a titania support is present in a catalytically active amount, e.g., 2 to about 25 wt. %, preferably 5 to 20 Wt. % (dry basis). Promoter metals may be present in amounts to form a weight ratio of promoter:cobalt greater than about 0.01 to 1; preferably 0.025 to about 0.1 to 1 based on total weight of cobalt and promoter. The following examples will serve to illustrate the invention. A bulk cobalt catalyst, designated as a cobalt black catalyst, was prepared by a conventional method known in the art, i.e., adding a stoichiometric amount of ammonium carbonate (as an aqueous solution) to an aqueous solution of cobalt nitrate, filtering the precipitate, washing the filtered solid with deionized water, drying at 120� C., and calcining at 500� C. in air for 5 hours. The resulting material showed an X ray diffraction patter of Co3 O4 which, when reduced at 450� C. in a H2 stream, produced a cobalt black catalyst having a surface area of 7.7 m2 /gr. The performance test of this catalyst was carried out by charging an intimate mixture of the Co3 O4 powder (6.8 grams) and a diluent (quartz powder, 80-140 mesh, 18 grams) into a down-flow fixed bed reactor made of 3/8" OD stainless steel tube with a concentric 1/8" OD thermocouple well. When reduced, 6.8 grams of Co3 O4 will yield 5.0 grams of cobalt black. The use of diluent and an aluminum block jacket fitted tightly around the reactor minimized uneven temperature profile along the bed. The Co3 O4 was then reduced in-situ in the reactor in a flowing H2 stream (200 cc/m, 1 atm) overnight at 450� C., cooled to 175� C. and then pressurized to 20 atm using a pre-mixed gas composed of 63.1% H2, 33.0% CO and 3.9% N2. At pressure and at a preset flow rate, the temperature was raised to 200� C. over a period of one hour and then data acquisition was initiated. The rate of CO conversion and the rates of various hydrocarbon products formation were monitored using two on-line GC's. The data taken after 70 hour on-stream-time are shown in Table 1. TABLE 1______________________________________EFFECTS OF EXTERNAL H2 O ADDITIONON ACTIVITY SELECTIVITIES OF Co BLACKTemperature = 200� C.Feed Gas Composition = 63.1% H2 /33.0% CO/3.9% N2SV = 3600 Scm3 /g hour (calculated for H2 and CO)*1 Run 1 Run 2 Run 3 Run 4______________________________________% H2 O Added*2 0 12.5 27.7 50.0Total Pressure, atm 20.7 21.6 24.9 28.6PH2 + Pco, atm 20.0 18.7 18.9 18.6PH2 O, atm 0 2.3 5.2 9.3% CO Conv. 12.1 27.3 28.7 18.8CH4 Select*3 10.5 7.1 5.8 4.0CO2 Select*3 0.27 0.21 0.34Hydrocarbon Product Distribution, wt. %CH4 11.5 8.1 6.7 4.6C2 -C4 15.6 8.7 7.8 8.6C5 -C9 17.4 9.5 9.0 9.7C10 + 55.5 73.7 76.5 77.1C10 -C20 21.7 17.0C21 -C30 21.7 13.8C31 -C40 6.9 11.1C41 -C.sub. 50 4.7 8.1C51 + 11.8 23.7______________________________________ *1 cc of H2 and CO measured at 1 atm, 22� C. per gram of catalyst per hour *2 Moles of H2 O added per 100 moles of CO and H2 *3 Moles of CH4 or CO2 per 100 moles of CO converted Comparison of the data with and without the external H2 O addition clearly establishes the advantages of H2 O addition; (1) the CO conversion increases markedly (up to 2.5 fold increase), (2) the methane make is greatly reduced and, (3) the desired heavy hydrocarbon product yields, which may be gauged by the C10 + selectivity, increase dramatically. Thus, this example clearly demonstrates the benefits of conducting a Fischer-Tropsch hydrocarbon synthesis reaction with external H2 O addition in the presence of a catalyst comprising metal cobalt. Another batch of a bulk cobalt catalyst was prepared using highly purified Co(NO3)2.6H2 O (99.99% pure Puratronic grade) according to a procedure similar to that described in Example 1. The evaluation procedure was also identical to that used in Example 1. After an extended reduction in a flowing H2 /He mixture at 500� C., the material was passivated and found to have about 1.5 m2 surface area per gram. This catalyst (5 grams) and 10 grams of quartz powder were mixed and charged into the reactor and pretreated as described in Example 1. At 201.5� C. and 20.7 atm, a gas mixture composed of 63.1% H2, 33.0% Co and 3.9% N2 was passed at a rate of 105 Scm3 /m. After one day on stream the data in Table 2 were obtained. TABLE 2______________________________________EFFECTS OF ADDED H2 O ON THE ACTIVITYAND SELECTIVITIES OF CO HYDROGENATIONOVER A HIGH-PURITY BULK Co CATALYSTTemperature = 202� C.Feed Gas Composition = 63.1% H2 /33% CO/3.9% N2Pressure = 20 atmSV = 1200 Scm3 /g hour Run 5 Run 6______________________________________% H2 O Added 0 21% CO Conversion 7.2 15.6CH4 Selectivity 8.2 4.21-Olefin/Paraffin RatioC2 0.13 0.36C3 2.47 3.68C4 1.87 2.52Hydrocarbon Product Distribution, wt. %CH4 9.4 4.8C2 -C4 21.1 20.4C5 -C9 11.0 11.6C10 + 58.5 63.2______________________________________ Using a test rig similar to that used above, a 12% cobalt on titania (rutile) catalyst was tested with and without water addition. The titania was Digussa p. 25, 50-150 mesh and the catalyst was prepared by depositing cobalt nitrate into the titania, drying in air, calcining, and reducing in flowing hydrogen. The results are shown in Table 3. TABLE 3______________________________________EFFECTS OF ADDED H2 O ON THEACTIVITY AND SELECTIVITY OF COHYDROGENATION OVER 12% Co/TiO2 CATALYST Temperature = 200� C. � 2� C. Pressure = 20.7 atm (catalyst diluted with rutile powder, 5 pt catalyst/6 pt powder)______________________________________GHSV, cm3 /gm-hour 3540 3540 1180 1180% H2 O added based on 0 12 0 35H2 + COFeed Gas Composition, Mol %H2 63.9 57.4 63.9 47.8CO 32.1 28.9 32.1 24.0N2 4.0 3.6 4.0 3.0H2 O 0 10.1 0 25.2% CO Conversion 8.5 21.9 40.2 50.7% SelectivityCH4 9.6 4.1 6.5 2.7CO2 0.22 0.21 0.15 0.68Olefin/ParaffinC2 0.20 0.78 0.11 0.47C3 2.22 3.92 1.61 3.29C4 1.24 2.38 0.84 2.00______________________________________ The results of the test show clearly that water addition to a cobalt/titania catalyst increases catalyst activity by virtue of the CO conversion and methane make is significantly reduced. Also, CO2 formation is virtually nonexistent, thereby showing that the KE reaction is also virtually nonexistent in these circumstances. Table 4 shows the improved C5 + selectivity obtained from the experiment of Example 3. Some of the data is repeated. TABLE 4______________________________________EFFECT OF ADDED H2 O ONACTIVITY/SELECTIVITY OF 12% Co/TiO2 CATALYST Temperature = 200� C. Pressure = 20 atm______________________________________GHSV, 3540 3540 1180 1180SCM3 /gm-hour.sup.(1)% H2 O Added.sup.(2) 0 12 0 35% CO Conversion 8.5 21.9 40.2 50.7% CH4 Selectivity.sup.(3) 9.6 4.1 6.5 2.7% CO2 Selectivity.sup.(3) 0.22 0.21 0.15 0.68CH4, Wt. % 10.9 4.6 7.5 3.1C2 -C4 9.8 5.0 8.1 4.7C5 -C9 15.9 9.3 13.2 10.5C10 + 63.4 81.1 71.2 81.6C10 -C20 21.0 24.9C21 -C30 16.9 15.1C31 -C40 13.1 9.5C41 -C50 9.4 6.8C50 + 20.7 15.0______________________________________ .sup.(1) cm3 of H2 = CO (1 atm, 22� C.) per gram of catalyst per hour .sup.(2) moles H.sub. 2 O added per 100 moles of H2 + CO .sup.(3) moles CH4 or CO2 produced per 100 moles of CO converte The results conclusively show that water addition increases both activity and selectivity of the cobalt/titania catalyst, and that CO2 remains quite low. A 1.1% Ru/TiO2 catalyst was prepared by impregnating Degussa P-25 TiO2 (sieved at 80-140 mesh; BET area=28 M2 /g; 70% rutile--30% anatase) with an acetone solution of Ru(NO3)3, drying at 120� C. and reducing at 450� C. in a H2 flow (1 atm) for 5 hours. The catalyst thus prepared was passivated at room temperature and characterized to contain 1.1 wt. % Ru, and 70% of Tu was exposed to surface. 5.0 grams of Ru/TiO2 and 10.0 grams of quartz powder (diluent; 80-140 mesh) were mixed thoroughly and charged in a down-flow fixed-bed reactor made of 3/8" OD stainless steel tube with a concentric 1/8" OD Thermocouple well. The use of a diluent and an aluminum block jacket fitted tightly around the reactor minimized uneven temperature profile along the bed. The catalyst was then re-reduced in a flowing H2 stream (200 cc/m, 1 atm) overnight at 450� C., cooled to 175� C. and then pressurized to 20.7 atm using a pre-mixed gas composed of 64% H2, 32% CO and 4% N2. At pressure and at a pre-set flow rate, the temperature was raised to 200� C. over a period of 2 hours and then data acquisition was initiated. The rate of CO conversion and the rates of formation of various products were monitored by use of two on-line GC's equipped with both TCD and FID. The data taken after 125 hours on-stream-time are shown in Table 5. Comparison of the data in Runs 1, 2, and 3 shows clear benefits of performing external H2 O addition; (1) the productivity increases nearly 3 fold when 22.4% H2 O was added and (2) the hydrocarbon products become heavier (less undesirable CH4 and more desirable C5 + or C10 + products). A similar trend was observed when the external H2 O addition was carried out at a lower space velocity (Runs 4 and 5). TABLE 5______________________________________EFFECTS OF EXTERNAL H2 OADDITION ON ACTIVITY SELECTIVITIESOF 1.1% Ru/TiO2 IN CO HYDROGENATIONTemperature = 200� C.Pressure = 20.7 atmFeed Gas Composition = 64% H2 /32% CO/4% N2 Run 1 Run 2 Run 3 Run 4 Run 5______________________________________SV*1, Scm3 /g hr 2460 2460 2460 1230 1230% H2 O added*2 0 5.8 22.4 0 20.3% CO Converted 6.3 10.4 17.2 17.9 35.2CH4 Selectivity*3 5.8 3.1 1.6 3.9 1.5CO2 Selectivity*3 0.34 0.45 0.42 0.50 0.60Hydrocarbon Product Distribution, wt. %CH4 6.5 3.6 1.8 4.5 2.1C2 -C4 12.6 7.4 4.1 9.6 4.8C5 -C9 29.3 20.2 11.9 18.0 12.0C10 + 51.6 68.8 82.2 67.9 81.1C5 + 80.9 89.0 94.1 85.9 93.1______________________________________ *1 cc of H2 and CO measured at 1 atm., 22� C. per gram o catalyst per hour *2 Moles of H2 O added per 100 moles of CO and H2 *3 Moles of CH4 or CO2 produced per 100 moles of CO converted This example demonstrates the benefits of external H2 O addition when Fischer-Tropsch hydrocarbon synthesis reactions are carried out using promoted Co/TiO2 catalysts. This example specifically shows that the benefits of external H2 O addition for Fischer-Tropsch synthesis over a Co/TiO2 catalyst are not diminished by addition of a promoter, or promoters, to the base catalyst, Co/TiO2 as exemplified by the beneficial effects of external water addition to a rhenium promoted Co/TiO2 catalyst. 109 grams of Co(NO3)2.6H2 O and 16 cc of aqueous perrhenic acid containing 0.83 g of rhenium (as metal) were dissolved in 300 cc acetone, to which 160 g of TiO2 (rutile, BET=13.6 m2 /g, 80-140 mesh) was added. The acetone was then removed in a rotary evaporator, followed by further drying a 140� C. in a vacuum. The resulting material was calcined in air at 250� C. for 3 hours. 3 g of this catalyst was intimately mixed with 12 g of diluent (low-surface-area rutile, 80-140 mesh) and charged to the reactor. The catalyst was then reduced in-situ in flowing H2 (1 atm, 200 cc/m) by gradually raising the temperature from room temperature to 450� C. over a period of 4 hours and then keeping at 450� C. for 16 hours. The performance data, listed in Table 6, were taken after 200 hours on-stream-time. TABLE 6______________________________________EFFECTS OF ADDED H2 O ON ACTIVITY ANDSELECTIVITIES OF CO HYDROGENATION OVERRHENIUM PROMOTED Co/TiO2 (12% Co-0.5% Re/TiO2)Total Pressure = 20.7 atmFeed Gas Composition = 64% H2 /32% CO/4% N2Temperature = 200� C. Run 5 Run 6 Run 7 Run 8 Run 9______________________________________SV, SCM3 /g. hr 3510 3510 3510 2340 2340% H2 O added 0 12 26 0 18% CO Conversion 9.9 24.2 26.4 21.0 36.3CH4 Selectivity 9.4 4.3 3.4 8.1 3.6CO2 Selectivity 0.39 0.38 0.27 0.381-Olefin/Paraffin RatiosC2 0.34 0.48 0.63 0.22 0.56C3 2.42 3.16 3.34 2.22 3.26C4 1.71 1.97 2.39 1.24 1.97Hydrocarbon Product Distribution, wt. %CH4 10.7 4.9 3.9 8.8 4.3C2 -C4 8.4 4.2 3.6 5.9 4.0C5 -C9 15.0 8.9 7.5 10.3 7.9C.sub. 10 + 65.9 82.0 85.0 75.0 83.8C5 + 80.9 90.9 92.5 85.3 91.7______________________________________ The results in Table 6 clearly establish that the benefits of external H2 O additions on the activity/selectivities of a rhenium-promoted Co/TiO2 catalyst. This example thus establishes that promoted Co/TiO2 catalysts show higher productivity and better product selectivities when external H2 O addition is performed during the Fischer-Tropsch hydrocarbon synthesis reaction. A series of runs to examine the influences of process variables, including the levels of externally added H2 O, were conducted using the catalyst and procedure described in Example 5, except that the catalyst used in this example was about 25% less active than that described in Example 5 due to different histories. The results in Table 7 nevertheless demonstrate that the beneficial effects of external H2 O addition can be realized both at a relatively low addition level of 6.7% and at a very high level of 104 %. Thus, this example demonstrates that for a wide range of external H2 O addition levels, 2-100% based on the combined H2 and CO feeds, beneficial effects of increased productivity and desirable selectivities can be realized. The results in Table 7 also demonstrate that the beneficial effects of added H2 O do not vary significantly over the temperature ranges of 180�-220� C., which suggests that the effects of external H2 O addition do not vary significantly with process conditions. TABLE 7______________________________________EFFECTS OF ADDED H2 O ON ACTIVITYAND SELECTIVITIES OF CO HYDROGENATIONOVER RHENIUM PROMOTED Co/TiO2Sum of Partial Pressures of CO and H2 = 20.0 atmFeed Gas Composition = 64.2% H2 /31.8% CO/4.0% N2 Temper-Run SV ature % H2 O % CO CH4# SCM3 /g. hr �C. Added Conversion Selectivity______________________________________10 3650 200 0 5.2 13.011 3650 200 6.7 13.7 5.812 3650 200 28.0 18.8 4.113 3650 200 34.0 15.8 3.314 3650 200 104.0 7.7 2.915 10950 221 0 5.7 16.216 10950 221 25.5 13.9 7.417 1210 181 0 8.2 9.018 1210 181 23.5 25.4 2.2______________________________________ Patent Citations
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TMS Savannah Side Chair
TMS Savannah Side Chair
Weights & Dimensions
Product Type: Side chair | Finish: Cherry |
Distressed: No | Frame Material: Wood |
Seat Frame Material: Wood | Number of Items Included: 1 |
Arms Included: No | Upholstered Seat: No |
Style: Traditional | Back Style: Slat back |
Swivel: No | Foldable: No |
Dining Type: Casual/Kitchen | Stackable: No |
Number of Legs: 4 | Leg Material: Wood |
Commercial Use: No | Product Care: Wipe with mild furniture cleanser |
Country of Manufacture: Malaysia |
Assembly Required: Yes |
About the Manufacturer
TMS is a supplier of affordable and quality ready-to-assemble and assembled home furniture ranging from dining sets, bar stools, occasional furniture, home office, and accent furniture. TMS has been established in the furniture industry for more than 20 years, and focuses on offering functional and stylish designs at great prices.STYLE
TMS Savannah Side Chair
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2 star | 0 | |
1 star | 0 |
Savannah side chairs Mary from Joliet,, IL– Verified Buyer Spent four months trying to "match" current kitchen set which came with only four chairs. The delivery time was great got them 3 days early! Set up was easy to do. They seem to be holding up well and match my set quite nicely. The photos online did justice to the product. |
Adorable Chair used for a desk! Natalie from Terre Haute, IN– Verified Buyer Nice chair! The white is not SUPER white but a little more like creamy white. We get lots of compliments on how cute it is. |
Ship Fast! Good Price! Xiaodong from Cullowhee, NC– Verified Buyer I bought this product marked as 'open box item' at almost half price. When I received the item, it looked as 'Brand New'. Excellent product! Thanks! |
Just what I needed Patty from Jacksonville, NC– Verified Buyer Needed a white chair to go with a new white computer desk. Didn't want one with wheels. This looks great with the desk. |
perfect size HA from CA– Verified Buyer This is perfect for my desk. The finish is smooth and polished and easy to slide on and off of the chair. It is the perfect size; not too bit and bulky. It is comfortable to sit in and a love it. |
Sturdy and of great quality KATHRYN from CRAWFORDVILLE, FL– Verified Buyer These chairs are a great price for the quality. I purchased six chairs for a eat in kitchen area and they are perfect. I highly recommend them. |
First time buyer Lora from Maple Grove, MN– Verified Buyer Easy, easy assembly and good looking desk chair. Very happy with my purchase. |
Small and sturdy Sherry from Venice, FL– Verified Buyer This chair went together easily and it is very sturdy. Perfect for our need for a desk chair to fit in a small kneehole. |
Cherry chair Joseph from Philadelphia, PA– Verified Buyer This Cherry chair was a steal as I bought it at a sale price. High quality and easy to assemble. |
Valued Customer from United States– Verified Buyer |
Savannah Side Chair is also sometimes listed under the following manufacturer numbers: 33418CHY, 33418WHT


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GE Energy Financial Services Inc., a unit of General Electric Co. (GE), will invest in a 32-megawatt solar power project in southwest Japan's Okayama prefecture.
You are here
SEIA is the solar energy industry's go-to source for the latest coverage on solar power, including U.S. and international policy, research and polls, business and financing trends, and more. Our staff strives to support the media covering solar energy issues and guide our members on effective media outreach with clear statements, background materials, news and multimedia resources.
SEIA is committed to informing policymakers, the media, and the American public about the benefits of solar energy for today's communities, our economy, and our country.
Learn more from our statements and industry news below.
Inside Connor Barwin's Exciting Offseason
It was quite the eventful offseason for Eagles outside linebacker Connor Barwin.
SEIA Elects New Board Chairman, Vice Chairman
Following a vote at its board meeting in San Francisco yesterday, the Solar Energy Industries Association (SEIA) announced that Nat Kreamer, President and CEO of Clean Power Finance, has become Chairman of the SEIA Board, effective immediately. Tom Starrs, Vice President of Market Strategy and Policy for SunPower Corp, will serve as Vice Chairman.
Commerce Solar Trade Decision Adds Urgency to Industry Discussions
Today's decision by the U.S. Department of Commerce to impose new tariffs on solar modules from China threatens to derail the rapid growth of the U.S. solar industry, according to the Solar Energy Industries Association (SEIA). Commerce will immediately impose countervailing duty tariffs ranging from 18.56 to 35.21 percent.
SEIA Vice President Designated Chairman of Dept. of Commerce Advisory Committee
WASHINGTON, DC -- John Smirnow, vice president of trade and competitiveness at the Solar Energy Industries Association® (SEIA®), has been designated chairman of the U.S. Department of Commerce's Renewable Energy & Energy Efficiency Advisory Committee (RE&EEAC). The re-charted committee was launched in recent days by U.S. Commerce Deputy Secretary Rebecca Blank.
SEIA Vice President Designated Chairman of Department of Commerce Advisory Committee
WASHINGTON, DC -- John Smirnow, vice president of trade and competitiveness at the Solar Energy Industries Association® (SEIA®), has been designated chairman of the U.S. Department of Commerce's Renewable Energy & Energy Efficiency Advisory Committee (RE&EEAC). The re-charted committee was launched in recent days by acting U.S. Commerce Secretary Rebecca Blank.
Gov. Cuomo's NY-Sun Competitive Solar Program Off to a Bright Start
March 28, 2013 – Albany, NY – Governor Cuomo's NY-Sun Competitive PV Program is drawing strong participation from New York energy customers and solar developers. In a successful first round, the New York State Energy Research and Development Authority (NYSERDA) awarded $46 million for 76 large-scale projects totaling 52 megawatts (MW) of new solar capacity, enough to power nearly 9,000 New York homes. Solar advocates and industry applauded the early results of the program and the state's continued commitment to bringing reliable clean power and local solar jobs to New York.
New Jersey Solar Market Hits 1 Gigawatt Milestone
TRENTON, NJ— The New Jersey solar market hit a new milestone this week when it eclipsed the 1 gigawatt (GW) mark for total installed solar electric capacity. This is enough solar electricity to power 139,000 homes.
U.S. Solar Market Grows 76% in 2012; Now an Increasingly-Competitive Energy Source for Millions of Americans Today
Added Record 3.3 Gigawatts of Capacity, Enough New Capacity to Power More Than 500,000 Homes
Apple's Second Catawba Solar Farm To Open This Fall
Apple Inc.'s second solar farm for its server operation in Maiden is expected to start operating in October, according to a filing the Cupertino, Calif., company (NASDAQ:AAPL) has made with the N.C. Utilities Commission.
Germany Broke World Solar Power Generation Record In July With 5.1 TWh
Germany's not a very sunny place, yet yet it leads the world in solar power, showing that you don't have to be in the middle of the Sahara desert to generate lots of clean power from the sun.
Virtual Net Metering Increases Solar Market Potential
Many of you have already heard that it's not practical/possible for most people to install solar systems on their rooftops. This is misleading, and the reason for it is that many people don't own their homes outright — they can't install solar panels on other people's property, unless they receive permission to do so.
FERC Chair Jon Wellinghoff: Solar 'Is Going to Overtake Everything'
If anybody doubts that federal energy regulators are aware of rapidly changing electricity landscape, they should talk to Jon Wellinghoff, chairman of the Federal Energy Regulatory Commission (FERC).
Will panels atop White House boost solar industry?
I haven't seen any photos yet, but supposedly workers are atop the building this week, installing the panels.


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"There's a scramble because banks have until the end of the year [to comply with the FFIEC guidance], so they're exploring all their options."
Christine Barry
"It's the third time they've wrestled in a year and (Jerod) got caught in a scramble and then came up on the wrong leg. (Jerod) will work on what he needs to do."
Dan Svirbly
"Now, you scramble because it's November, less than a year from the opener."
Steve Holton
"If you're a meth addict you either throw in the towel and go into treatment, or you scramble to find some other way to get it."
Curt Smith
"That kid is a good quarterback. He scrambles well and has got a lot of poise, but we let him off the hook too many times."
Joe Paterno
"It's the way he plays. It doesn't matter in corners. If he gets ran or it's a scramble or whatever, he's so calm. That's his personality, and it's part of the team's personality now. He brought that to our team, and now we're all like that."
Henrik Tallinder
"Marcus isn't a guy who wants to scramble to run the ball, he wants to pass the ball. This guy is all about running the ball. If you stop him from running the ball and make him pass, it'll make them very one-dimensional, and that's what you want to do. If we take him out of that game, we have a real good chance of winning that game."
Buster Davis


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Brookline, MA
Extremely Loud And Incredibly Close
Juergen Roth
Photograph - Flower Fine Art Photography
Flower macro fine art photography of pink blooming Orchids. The graceful and elegant Orchid flower epitomizes love, luxury, strength, and beauty.
March 13th, 2012
Viewed 3,599 Times - Last Visitor from Beverly Hills, CA on 02/28/2015 at 10:59 PM
Sales Sheet
More from Juergen Roth
Corpus Christi, TX - United States
Featured in Fabulous Art Boutique! Congratulations! What a fabulous work of art! Nicely done, bravo! Be sure to view how your image is displayed, looks Fabulous!
Sequim, WA - United States
Stunning macro, J�rgen! It almost looks other-worldly! Voting for your entry in Pink contest! Hervorragend!
Greensboro, NC - United States
Juergen, this is so incredible! What a beautiful macro with gorgeous light, f/v.
Brookline, MA - United States
Thanks a ton for your wonderful comment on my Orchid flower photography artwork and vote at http://fineartamerica.com/contests/national-tv-photo-contest.html?tab=vote&artworkid=534365 .... very much appreciated Stav!
Playa El Tunco, La - El Salvador
Stunning macro!! You got my vote in the FAA Featured Photography contest :)
Brookline, MA - United States
Thanks so much for commenting on my pink Orchid flower photography macro ... glad you like it Steven!
Brookline, MA - United States
Thanks a trillion for dropping in and commenting on my latest Orchid flower photography Kathy ... glad you like Extremely Loud and Incredible Close!
Cupertino, CA - United States
What an aptly put title for such a beautiful image. I love seeing every detail of this orchid up close and personal!! Great shot! :)
Brookline, MA - United States
Thanks a trillion everybody for commenting on my latest orchid macro photography ... very much appreciate the positive feedback!
Brookline, MA - United States
Thanks a million all for stopping by and commenting on my latest orchid flower photography fine art Extremely Loud & Incredible Close ... appreciate the great response and glad you like it! I liked the movie a lot and thought it suites the image well :-)
Bothell, WA - United States
Feel like I'm Alice Through the Looking Glass .... where's the caterpillar and my hit of acid? Love it!! Instant Fav!!
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Latest Titles With Ellen Page
- Job Types
- Movies or TV
- Genres
- Keywords
- IMDb Rating
- Instant Watch Options
- In Theaters
- On TV
- Release Year
1. Untitled John Belushi Project
Biography, Drama | Announced
The story of comic superstar John Belushi who rose to fame in the 1970s died of a drug overdose in 1982 at the age of 33.
Writer: Steve Conrad | Director: Steve Conrad | Stars: Miles Teller, Ellen Page, Emile Hirsch
2. Window Horses
Animation | Filming
A young Canadian poet with Chinese and Persian parents travels to Iran to perform at a poetry festival.
Director: Ann Marie Fleming | Stars: Ellen Page, Sandra Oh, Shohreh Aghdashloo, Omid Abtahi
3. Miss Stevens
Comedy | Announced
A comedy focused on a teacher who chaperones a group of high schoolers to a state drama competition.
Writer: Julia Hart | Director: Ellen Page | Star: Anna Faris
4. Queen & Country
Action | Announced
Special Ops agent is on the run after assassinating a powerful figure in Eastern Europe.
Writers: Olivia Milch, Greg Rucka | Director: Craig Viveiros | Star: Ellen Page
5. Freeheld (2015)
Biography, Drama, Romance | Post-production
New Jersey car mechanic Stacie Andree and her police detective girlfriend Laurel Hester both battle to secure Hester's pension benefits after she was diagnosed with a terminal illness.
Writer: Ron Nyswaner | Director: Peter Sollett | Stars: Julianne Moore, Luke Grimes, Steve Carell, Ellen Page
6. Into the Forest (2015)
Drama, Sci-Fi | Post-production
In the not too distant future, two young women who live in a remote ancient forest discover the world around them is on the brink of an apocalypse. Informed only by rumor, they fight intruders, disease, loneliness & starvation.
Writers: Jean Hegland, Patricia Rozema | Director: Patricia Rozema | Stars: Evan Rachel Wood, Ellen Page, Callum Keith Rennie, Max Minghella
7. Robodog (2015)
Animation, Adventure, Comedy
Follows a dog that is a robot with a machine-like brain.
Writers: Alex Ankeles, Morgan Jurgenson, Robert Reece, William Schneider | Director: Donovan Cook | Stars: Ellen Page, Ron Perlman, Rainn Wilson, Steve Zahn
8. Women Who Act (2015)
Writer: Barry Avrich | Director: Barry Avrich | Stars: Andrea Martin, Tatiana Maslany, Sandra Oh, Ellen Page
9. X-Men: Days of Future Past (2014)
PG-13 | 131 min | Action, Adventure, Sci-Fi
The X-Men send Wolverine to the past in a desperate effort to change history and prevent an event that results in doom for both humans and mutants.
Writers: Simon Kinberg, Jane Goldman, Matthew Vaughn | Director: Bryan Singer | Stars: Patrick Stewart, Ian McKellen, Hugh Jackman, James McAvoy
10. Late Night with Seth Meyers (2014– )
Comedy, Talk-Show
Seth Meyers hosts a late-night talk show.
Stars: Seth Meyers, Fred Armisen, Conner O'Malley, Michelle Wolf
11. 2014 MTV Movie Awards (2014 TV Special)
Comedy, Music, Reality-TV
A film-awards show presented annually on MTV.
Writer: Lauren Greenberg | Director: Evan Silver | Stars: Conan O'Brien, Andy Samberg, Seth Rogen, Sarah Silverman
12. Tiny Detectives (2014)
Short, Comedy
Writers: Andrew Bush, Jake Fogelnest | Director: Andrew Bush | Stars: DeMorge Brown, Kate Mara, David Marciano, Ellen Page
Ellen: The Ellen DeGeneres Show (2003– )
Ellen Page/Katie Lowes/Jhere Aiko/Guest DJ tWitch
TV-G | Comedy, Talk-Show
Ellen Page; Katie Lowes. Also: performances from Jhene Aiko and guest DJ tWitch.
Stars: Ellen DeGeneres, Jhene Aiko, Stephen Boss, Katie Lowes
Late Night with Seth Meyers (2014– )
Ellen Page/Lewis Black/Black Label Society
Comedy, Talk-Show
Ellen Page; Lewis Black. Also: Black Label Society perform.
Writer: Ben Warheit | Stars: Seth Meyers, Fred Armisen, Black Label Society, Lewis Black
The Colbert Report (2005– )
Episode #10.140
TV-14 | Comedy, News, Talk-Show
Watch with Prime starting 5/16. Actress Ellen Page sits down with Stephen to chat about her role in the movie "X-Men: Days of Future Past."
Writer: Max Werner | Stars: Stephen Colbert, Ellen Page
Conan (2010– )
Episode #4.92
TV-14 | Comedy, Music, Talk-Show
Writers: Josh Comers, Jessie Gaskell, Andres du Bouchet | Stars: Conan O'Brien, Andy Richter, Ellen Page, Bob Saget
Made in Hollywood (2005– )
Episode #9.30
Director: Cleveland O'Neal III | Stars: Drew Barrymore, Peter Dinklage, Michael Fassbender, Julie L. Harkness
Fox and Friends (1998– )
Episode dated 10 May 2014
News, Talk-Show
Stars: Anna Kooiman, Clayton Benjamin Morris, Tucker Carlson, Rick Reichmuth
Good Morning America (1975– )
Episode dated 20 May 2014
News, Talk-Show
Toni Braxton; Ellen Page; Wendi McLendon-Covey. Also: Phillip Phillips performs; dance champion Louis van Amstel discusses the freestyle dances on the previous night's "Dancing with the Stars".
Stars: Toni Braxton, Ron Claiborne, Bianna Golodryga, Wendi McLendon-Covey
Good Morning America (1975– )
Episode dated 27 May 2014
News, Talk-Show
Elle Fanning; Ellen Page; Larry Birkhead & Helio Castroneves; Dave Zinczenko.
Stars: Larry Birkhead, Helio Castroneves, Ron Claiborne, Elle Fanning
Good Morning America (1975– )
Episode dated 9 May 2014
News, Talk-Show
Ellen Page. Also: a performance by Hunter Hayes; deals and steals; "Shark Tank".
Stars: Howard Bragman, Ron Claiborne, Bianna Golodryga, Hunter Hayes
22. The East (2013)
PG-13 | 116 min | Drama, Thriller
An operative for an elite private intelligence firm finds her priorities changing dramatically after she is tasked with infiltrating an anarchist group known for executing covert attacks upon major corporations.
Writers: Zal Batmanglij, Brit Marling | Director: Zal Batmanglij | Stars: Brit Marling, Alexander Skarsgård, Ellen Page, Toby Kebbell
23. Beyond: Two Souls (2013 Video Game)
M | Adventure, Crime, Drama
Live the life of Jodie Holmes, a young woman who possesses supernatural powers through her psychic link to a mysterious invisible entity.
Writer: David Cage | Director: David Cage | Stars: Ellen Page, Willem Dafoe, Eric Winter, Kadeem Hardison
24. Touchy Feely (2013)
R | 89 min | Drama
A massage therapist is unable to do her job when stricken with a mysterious and sudden aversion to bodily contact. Meanwhile, her uptight brother's floundering dental practice receives new life when clients seek out his healing touch.
Writer: Lynn Shelton | Director: Lynn Shelton | Stars: Rosemarie DeWitt, Ellen Page, Josh Pais, Scoot McNairy
25. Out There (2013– )
Animation, Comedy, Drama
Out There chronicles the coming-of-age misadventures of socially awkward Chad, his little brother Jay, and his best friend Chris. Living in the small town of Holford, the boys wander its ... See full summary »
Creator: Ryan Quincy | Stars: Ryan Quincy, Justin Roiland, Fred Armisen, Megan Mullally
26. The 2013 Film Independent Spirit Awards (2013 TV Movie)
Writers: Erik Weiner, Wayne Federman, Andy Samberg, Michael Patrick O'Brien, John Solomon | Director: Chris Donovan | Stars: Andy Samberg, Kerry Washington, Rama Burshtein, Derek Connolly
27. Stroumboulopoulos (2013– )
60 min | Talk-Show
Explores the worlds of art, pop culture, politics, tech news, and sports through the eyes and the words of their most interesting figures.
Stars: George Stroumboulopoulos, Jay Baruchel, Valerie Bertinelli, Jon Cioffi
Out There (2013– )
Ace's Wild
Animation, Comedy, Drama
Cool yearbook staffers catch sight of Chad's classroom doodles and ask him to join their clique.
Creator: Ryan Quincy | Director: Ryan Quincy | Stars: Ryan Quincy, Justin Roiland, Megan Mullally, Fred Armisen
Conan (2010– )
Butt-Dial M for Murder
TV-14 | Comedy, Music, Talk-Show
Writers: Scott Chernoff, Josh Comers, Andres du Bouchet | Stars: Conan O'Brien, Andy Richter, Ellen Page, Craig Robinson
The Daily Show with Jon Stewart (1996– )
Ellen Page
TV-14 | Comedy, News, Talk-Show
Actress Ellen Page sits down with Jon to talk about her new movie "The East."
Writers: Rory Albanese, Steve Bodow, Tim Carvell, Travon Free, Hallie Haglund, J.R. Havlan, Elliott Kalan, Dan McCoy, Jo Miller, John Oliver, Zhubin Parang, Daniel Radosh, Jason Ross, Lauren Sarver, Jon Stewart | Director: Chuck O'Neil | Stars: Jon Stewart, Ellen Page
Stroumboulopoulos (2013– )
Episode #1.3
Director: Russell Norman | Stars: George Stroumboulopoulos, Jay Baruchel, Bill Maher, Ellen Page
Made in Hollywood (2005– )
Episode #8.30
Director: Cleveland O'Neal III | Stars: Zal Batmanglij, Julie Delpy, Jesse Eisenberg, Isla Fisher
The Late Late Show with Craig Ferguson (2005– )
Episode dated 28 May 2013
TV-14 | Comedy, Music, Talk-Show
Writer: Bob Oschack | Director: Tim Mancinelli | Stars: Craig Ferguson, Ellen Page, Shadoe Stevens, George Stroumboulopoulos
Up Close with Carrie Keagan (2007– )
Episode dated 30 May 2013
Creator: Kourosh Taj | Director: Kourosh Taj | Stars: Carrie Keagan, Alexander Skarsgård, Brit Marling, Ellen Page
Reel Junkie (2007– )
The East
Creator: Kourosh Taj | Director: Kourosh Taj | Stars: Kourosh Taj, Ellen Page, Alexander Skarsgård, Brit Marling
36. To Rome with Love (2012)
R | 112 min | Comedy, Romance
The lives of some visitors and residents of Rome and the romances, adventures and predicaments they get into.
Writer: Woody Allen | Director: Woody Allen | Stars: Woody Allen, Penélope Cruz, Jesse Eisenberg, Ellen Page
Chelsea Lately (2007– )
Episode #6.91
TV-14 | Comedy, Talk-Show
In her opening monologue, host Chelsea Handler talks about how she has now assembled the perfect family, with one more she would like to add. Chelsea and her round table panelists Michael Yo... See full summary »
Writer: Fortune Feimster | Stars: Alec Baldwin, Chuy Bravo, Jesse Eisenberg, Fortune Feimster
The Late Late Show with Craig Ferguson (2005– )
Episode #8.244
TV-14 | Comedy, Music, Talk-Show
Writer: Bob Oschack | Stars: Lee Brice, Craig Ferguson, Ellen Page, Shadoe Stevens
Charlie Rose (1991– )
Episode dated 19 June 2012
News, Talk-Show
Stars: Charlie Rose, Letty Aronson, Alec Baldwin, Penélope Cruz
The View (1997– )
Episode dated 22 June 2012
TV-14 | Talk-Show
Stars: Whoopi Goldberg, Joy Behar, Elisabeth Hasselbeck, Sherri Shepherd
Episode dated 29 June 2012
Stars: Byron Allen, Ellen Page, Andy Samberg
Family Guy (1999– )
Tom Tucker: The Man and His Dream
TV-14 | 22 min | Animation, Comedy
Tom Tucker goes to Hollywood to revive his acting career, with Peter as his agent. Back in Quahog, Chris starts dating a girl who looks exactly like Lois.
Creators: Seth MacFarlane, David Zuckerman | Directors: Greg Colton, Peter Shin | Stars: Seth MacFarlane, Alex Borstein, Seth Green, Mila Kunis
43. Tilda (2011 TV Movie)
A powerful Hollywood journalist and an upstart creative assistant.
Writers: Bill Condon, Cynthia Mort | Director: Bill Condon | Stars: Diane Keaton, Ellen Page, Sanaa Lathan, Jason Patric
44. Na Nai'a: Legend of the Dolphins (2011)
75 min | Fantasy
Director: Jonathon Kay | Stars: Gerard Butler, Megan Fox, James Franco, Whoopi Goldberg
45. A Look Behind the Scenes: Super (2011)
Director: Miranda Bailey | Stars: Kevin Bacon, Miranda Bailey, James Gunn, Ted Hope
Glenn Martin DDS (2009– )
Date with Destiny
TV-14 | Animation, Comedy
Writer: Sivert Glarum | Director: Ken Cunningham | Stars: Kevin Nealon, Catherine O'Hara, Judy Greer, Jackie Clarke
Late Show with David Letterman (1993– )
Episode #18.112
Comedy, Music, Talk-Show
Stars: David Letterman, Chris Rock, Ellen Page, Funeral Party
The Late Late Show with Craig Ferguson (2005– )
Episode #7.137
TV-14 | Comedy, Music, Talk-Show
Stars: Craig Ferguson, Marc Maron, Ellen Page, Shadoe Stevens
Real Time with Bill Maher (2003– )
Episode #9.10
TV-MA | 60 min | Comedy, News, Talk-Show
Writers: Scott Carter, Brian Jacobsmeyer, Jay Jaroch, Chris Kelly, Bill Maher, Billy Martin | Stars: Bill Maher, David Brooks, Tina Brown, Ellen Page
50. Inception (2010)
PG-13 | 148 min | Action, Mystery, Sci-Fi
A thief who steals corporate secrets through use of dream-sharing technology is given the inverse task of planting an idea into the mind of a CEO.
Writer: Christopher Nolan | Director: Christopher Nolan | Stars: Leonardo DiCaprio, Joseph Gordon-Levitt, Ellen Page, Ken Watanabe


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We launched leggings! Step into a world of individuality.
o4 . o3 . 2o1o
acrylic on canvas
minimal digital
24"x 30"
warning: my art does not always depict my state of being or mind… xoxo
Amazing art !
right through the left tit ….. great work
I am glad you finally put up a disclaimer. This is passionate and edgy! Love it. Since you do it with X Japan, I only love it more. You rock Mimi!!!!
good to know, dearheart.
but it is always beautiful. x
Dramatic and painful Mimi! Your talent shines through!!!
Each arrow death to my bleeding heart! Beauty as-always friend with a message to be heard! Bravo, Bravo!!!…)o(
That is wicked good piece of art.. the end and the beginning.
Absolutely outstanding Art.
Amazing Amazon!
Oh Butterfly ……………………..


text:
USA Technologies Reports GAAP And Non-GAAP Profitability For The Second Quarter Of Fiscal 2013
USA Technologies, Inc. (NASDAQ: USAT), ("USAT"), a leader of wireless, cashless payment and M2M telemetry solutions for self-serve, small-ticket retail industries, today reported results for the second quarter of fiscal 2013 ended December 31, 2012. Second quarter highlights, compared to the corresponding quarter of the prior fiscal year, included:
- 29% increase in total revenues to $8.9 million and 33% increase in license and transaction fee revenues ("recurring revenues") to $7.4 million, representing 83% of total revenues for the quarter;
- 86% increase in gross profit to $3.6 million;
- Adjusted EBITDA of $1,752,721, up from an Adjusted EBITDA loss of ($938,400);
- GAAP net income of $153,758, up from a GAAP net loss of ($1,821,061); and,
- Non-GAAP net income of $557,393, up from a non-GAAP net loss of ($997,820) in the same quarter a year ago.
In addition, customers and connections to USAT's cashless payment and M2M telemetry service, ePort Connect®, continued to demonstrate solid growth in the second quarter. Highlights, compared to the second quarter of the prior fiscal year, included:
- 12,000 net new connections, a 71% increase;
- 186,000 total connections, a 37% increase; and,
- 375 new customers, a 50% increase, for 4,100 total customers, a 62% increase.
"We are extremely pleased to achieve non-GAAP net income for the first time in USAT's history," stated Stephen P. Herbert, chairman and CEO of USA Technologies, "and to deliver that target with such strength that we achieved GAAP net income as well, even after absorbing a sizable warrant adjustment for the quarter. The aggressive actions taken as part of our turnaround plan communicated to shareholders last year are clearly visible in our results, with exceptional improvements in both gross profit margin and operating margin this quarter. In addition, the inherent value of the recurring revenue base that we are building with every new connection is evident in the steady improvement in revenues over the last quarters and the $1.8 million base of Adjusted EBITDA reported for the second quarter—a great improvement from just one year ago.
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Read what other Viator.com travelers think about the Singapore Shared Departure Transfer: Hotel to Airport. What they loved, what they liked and what they think could be improved, it's all here to help you make the most of your next trip.
Click here for tour details, schedule and pricing
Good company.
We were picked up with plenty of time to get to the airport.
Friendly driver.
Excellent Services, Timely departure, Friendly and Efficient Driver.
The transfer from airport to hotel and return was great. Drivers were polite and on time. I will certainly use this facility again for future travels.
The day before pick-up, I called the Singapore tel. no. listed on the voucher abt. 10:30 a.m. twice but no one answered. Later in the day I called and after 2 rings, the call was answered and I was given pick-up time. The driver was in the hotel lobby right on time on a very busy evening and we were at the airport in no time. For reliability, which was the most important issue for us, I give them 5 stars. On the off side, we were anxious when no one answered the phone and we couldn't get the seat belts to operate in the van.
The driver was early but since I was the only pick up the was no rush. Kind curteous service.
Denise S
On time, polite, clean mini bus, could not ask for more.
Turned up spot on time, helpful driver, happy days
United Kingdom
Excellent - arrived on time and very helpful
Excellent service.
the best...will use again...
Stress free travel from our hotel to the airport. Would recommend especially if you're carrying a decent amount of luggage.
United Kingdom
excellent, no problems
excellent, no problems
on time and very polite


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As Director of Government Relations, Daron Korte serves as the primary liaison between the state legislature and the Minnesota Department of Education. Mr. Korte is responsible for monitoring all state and federal legislative activity relating to early childhood and K-12 education in Minnesota. This includes assisting the Commissioner in developing the department's legislative agenda and advocating that agenda at the state legislature. In addition, he is responsible for analyzing pending education legislation, collaborating with education stakeholder groups, and tracking legislative activity. Mr. Korte serves as the department's legal counsel, identifying and analyzing legal issues as they arise and providing advice to the Commissioner and Executive Team.
Mr. Korte's previous role at the department was Deputy Director of Government Relations. Prior to his work at the department, he served as Committee Administrator and Senate Counsel for the Minnesota Senate Education Policy and Finance Committee.
Mr. Korte holds a J.D. from the DePaul University College of Law in Chicago, Illinois and a B.A. in Sociology of Law, Criminology, and Deviance from the University of Minnesota.
Meet the 2015 Science Mathematics Principal
John Garcia, principal of Cedar Park Science, Technology, Engineering and Mathematics (STEM) School in Apple Valley, has been named the 2015 Science and Mathematics Elementary and Middle Level Principal of the Year. Created through a partnership between the Science Museum of Minnesota and the Minnesota Elementary School Principals' Association (MESPA), the award recognizes the importance of fostering lifelong science literacy and the key role principals play in developing a culture that encourages student interest in math and science.
Copyright 2015
Minnesota Department of Education


text: With 7 core ingredients and only 15 minutes of active prep time, this hearty autumn meal will leave you feeling full of the good stuff! October 27, 2011 | By Laura Schwecherl The Greatist Recipe: Stuffed Squash 1.7K Pin it Share It's officially autumn, which means it's time to get out the gourds. And while they fare well as Halloween-décor, they are also quite delicious— and nutritious! This recipe has us using acorn squash, which serves as an edible bowl filled with protein-packed quinoa, spinach, and low-fat creamy ricotta! Quinoa and Spinach Stuffed Acorn Squash What You Need: 2 medium-sized acorn squash, halved 1 10oz box frozen spinach 1 cup quinoa 1 cup part-skim ricotta cheese ½ yellow onion, chopped 2 cloves garlic, minced 2 tbsp extra-virgin olive oil Salt and pepper to taste Optional: Sprinkle of Parmesan cheese What To Do: 1. Preheat oven to 375 degrees. 2. Cut acorn squash in half and spoon out seeds. Brush with 1 tbsp olive oil, sprinkle with salt and pepper, and bake for 50 minutes, or until soft. 3. Bring two cups of water to a boil and add quinoa. Bring quinoa to a simmer and then lower the heat. Cook until all the water is absorbed—about 15 minutes. 4. While the quinoa is cooking, heat a skillet on medium with 1 tbsp olive oil. Add onions and let cook for five minutes, or until they start to brown. 5. Add spinach and minced garlic, stirring constantly until the spinach defrosts and warms. Add salt and pepper to taste. 6. Combine cooked quinoa into the skillet with spinach, garlic, and onions, and add ricotta. Stir on low heat for two minutes. 7. Remove the squash from the oven and add the quinoa mixture. Place back in the oven for 8-10 minutes, or until the "stuffing" is hot. 8. Let cool for five minutes, add a sprinkling of Parmesan cheese, and enjoy! Send Me the Ingredients! Powered by Popcart Pin it Share Like Us On Facebook Quinoa Healthy Recipes Fall Foods


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M Ashwell
Woodturning & Machining London
M Ashwell can be found at Arch 190 Morning Lane . The following is offered: Woodturning & Machining. The entry is present with us since Sep 11, 2008 and was last updated on Aug 6, 2014. In London there are 12 other Woodturning & Machining. An overview can be found here.
Published by: OpendiWoodturning & Machining


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Genuine Frigidaire part. Frigidaire brands include Electrolux, Frigidaire, Gibson, Kelvinator, Westinghouse, and others. See all items in Refrigerator Hinge. Electrolux also makes various appliance models for Sears / Kenmore
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Part Number 5303289320 (AP2144026) replaces 628190, AH461282, EA461282, PS461282.
Michael for Model Number 25350682002
Answer Hello Michael, You need to make sure the unit is properly leveled so the door liner will not drag inside the cabinet when the door is closing. The leveling of the unit affects the "twist" in the cabinet which directly affects the door strike. Also lubricate the lower hinges with white lithium grease WC32X5003. You may need to replace or add washers 215744100 under the door on the door hinge. You may also need to clean the door seals and they can be lubricated with a small amount of anti-bacterial soap on the hinge side of the door.
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