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A more detailed discussion of the comparative risk between a robotic servicing mission and a shuttle mission to HST is presented in Chapter 7.
FINDING: Many of the concerns raised by the committee regarding the risk of attempting to robotically service the Hubble Space Telescope could be mitigated for future programs through planning for robotic servicing in the initial spacecraft design.
The National Academies | 500 Fifth St. N.W. | Washington, D.C. 20001
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5 HST Robotic Servicing Assessment ."
Assessment of Options for Extending the Life of the Hubble Space Telescope: Final Report . Washington, DC: The National Academies Press,
2005 .
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As of 2013, the National Science Education Standards have been replaced by the Next Generation Science Standards (NGSS), available as a print book, free PDF download, and online with our OpenBook platform.
The NGSS offer a detailed description of the key scientific ideas and practices that all students should learn by the time they graduate from high school. The standards are based largely on the 2011 National Research Council report A Framework for K-12 Science Education: Practices, Crosscutting Concepts, and Core Ideas.

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Top Definition
The act of masturbating during every episode of Glee that appears on television.
I was watching Glee last night and I had to drop trou and "gleesterbate" all over my favorite jeggins.
by Joey Dee3
December 17, 2010
1 more definition
masturbating to any and all episodes of Glee
I just watched Glee and I had to get naked and "gleesterbate" all over my jeggins!
by Joey Delu
December 17, 2010


text: http://techcrunch.com – Last Wednesday, eBay unveiled "The New eBay", a completely redesigned website that is slowly being rolled out to all users, and released same day delivery service eBay Now in San Francisco. We got the chance to talk about product vision with President Devin Wenig and CTO Mark Carges. With today's earnings, eBay proved once again that marketplace is still driving the revenue for the company. That's why eBay still seems very committed to its core marketplace experience, even though it creates new shopping experiences to stay relevant at the same time. Understanding mobile (IT news)


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Don't miss a moment from the world's biggest mobile show
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At IFA 2013, Samsung has shown off loads of great-looking UHD TVs that use cutting-edge OLED technology. Plus some crazy printers that play music and are made of paper.


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Mirror Reporter
Local News
CL Police Chief announces retirement plans
Wednesday, 08 January 2014 12:47
Clear Lake Police Chief Greg Peterson says he will retire from the CLPD effective April 30, 2014.
Peterson, who came to Clear Lake in November 2006 to lead the CLPD, said he intends to remain in the community and will likely stay involved with the department a few hours each week as it transitions through City Hall
Polar blast!
Wednesday, 08 January 2014 12:42
Area sees coldest temperatures since '95
It was the kind of day you may tell your grandkids about some day. Heck, it might be the kind of winter you tell them about! The coldest, most dangerous blast of polar air in decades gripped Clear Lake, along with the entire Midwest Sunday and Monday, closing schools and day care centers, closing businesses and forcing people to pull their hoods and scarves tight to protect exposed skin from nearly instant frostbite.
VPA and township trustees still at odds over cost of fire protection
Wednesday, 08 January 2014 12:41
Each side has proposal for 'fair and equitable' service
Nearly one month after a contract deadline issued by the Ventura Fire Protection Association was missed, and almost three weeks after Clear Lake Township Trustees responded with their own proposal, there is still no agreement to provide fire service to the township after July 1, 2014.
The two parties have been at odds since the VPA announced its plan to dissolve and transfer ownership of the department to the City of Ventura at the start of the fiscal year, July 1, 2014. In preparation for the change, late last summer the VPA
Going cold turkey!
Wednesday, 08 January 2014 12:40
Gobbler hunt provides chilling experience
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Page 67 of 225


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Krimson 35 (Thread 184113)
UpdatedComments Submitted Says:
does krimson 35 retain weight
Reply to this threadShowing Replies 1 - 6 of 6
simran vilkhu Says:
information including uses, side effects,
naaz Says:
I forgot to take my pills yesterday and day before ( 2 pills ).I have already taken 9 pills in this month's course.today i got my periods..should i contiune taking my pills or wait for the periods to get over?
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side effects of krimpson35
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iam 23 years old married i having pain sometimes severe at the right lower side of the abdomen. doctor asked me to scan and said as pcod and gave krimson 35 for six months course the main problem is does it has side effects iam having a severe headache and many other problems and having it
Nidhi9 Says:via mobile
28 years age married planning a baby . Pcod problem prescribed krimson 35 and metaformin for 6 months I want to knoe how krimson 35 ,would help in conceiving. about met I know. does it reduce androgen level or just plain birth control.pill to regularize period?
kanchan Says:via mobile
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text:
Here's Why Twitter Is Surging In One Chart
NEW YORK (TheStreet) -- Twitter (TWTR - Get Report) shares are surging because of one number, and one number only: 271 million monthly active users, widely known as MAUs.
Consensus for Twitter's MAUs was so negative, especially after the company finished last quarter with 255 million MAUs, that any print over 267 million was enough to send shares soaring, especially when you factor in that Twitter is a profitable business, albeit on a non-GAAP basis (love those tech companies!).
"The key metric for the quarter-user growth-was stronger than published sell-side estimates and we believe much stronger than subdued buy-side expectations," wrote Sterne Agee analyst Arvind Bhatia in a research note.
Read More: Twitter Q2 Live Blog Recap Bhatia, who rates Twitter "neutral," believed that the sell-side was expecting 12 million MAUs and the buy side was even lower, at 10 million. The 16 million MAU add was the highest in five quarters. Twitter has made recent product changes, including making signing up easier, reducing steps, making it more visually appealing by embedding photos and others, and it's clear these changes are working, at least for the for time being. The company clearly benefited from the World Cup (an event that only happens once every four years), though CEO Dick Costolo attributed the user growth more towards the product changes than the actual event. The question surrounding Twitter has never been about profitability (it earned an adjusted 2 cents per share on $312 million in the second quarter), it's always been about whether it's a mainstream product. "Twitter is everywhere," Costolo said on the earnings call. "It's all over TV. When the NBA commissioner gets on TV and talks about sanctions about Donald Sterling, there are tweets all over the screen. This is all happening on twitter." Costolo noted that Twitter's reach (MAUs plus unique logged out visitors) is two to three times what its monthly MAU number is, but the company is really only monetizing its MAUs, those Costolo hinted that would be coming down the line. For now, investors are happy to see that although Twitter may never be as big as Facebook (FB) users base is, it's not as small as they feared either. Read More: Why Twitter Has More Upside Than Facebook -- Written by Chris Ciaccia in New York >Contact by Email. Follow @Chris_CiacciaCheck Out Our Best Services for Investors
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text:
Open AccessThis article is
MDPI and ACS Style
- freely available
- re-usable
Remote Sens. 2009, 1(3), 243-265; doi:10.3390/rs1030243
An Automated Artificial Neural Network System for Land Use/Land Cover Classification from Landsat TM Imagery
Received: 10 June 2009 / Revised: 23 June 2009 / Accepted: 24 June 2009 / Published: 9 July 2009
Download PDF [461 KB, uploaded 19 June 2014]
Abstract: This paper focuses on an automated ANN classification system consisting of two modules: an unsupervised Kohonen's Self-Organizing Mapping (SOM) neural network module, and a supervised Multilayer Perceptron (MLP) neural network module using the Backpropagation (BP) training algorithm. Two training algorithms were provided for the SOM network module: the standard SOM, and a refined SOM learning algorithm which incorporated Simulated Annealing (SA). The ability of our automated ANN system to perform Land-Use/Land-Cover (LU/LC) classifications of a Landsat Thematic Mapper (TM) image was tested using a supervised MLP network, an unsupervised SOM network, and a combination of SOM with SA network. Our case study demonstrated that the ANN classification system fulfilled the tasks of network training pattern creation, network training, and network generalization. The results from the three networks were assessed via a comparison with reference data derived from the high spatial resolution Digital Colour Infrared (CIR) Digital Orthophoto Quarter Quad (DOQQ) data. The supervised MLP network obtained the most accurate classification accuracy as compared to the two unsupervised SOM networks. Additionally, the classification performance of the refined SOM network was found to be significantly better than that of the standard SOM network essentially due to the incorporation of SA. This is mainly due to the SA-assisted classification utilizing the scheduling cooling scheme. It is concluded that our automated ANN classification system can be utilized for LU/LC applications and will be particularly useful when traditional statistical classification methods are not suitable due to a statistically abnormal distribution of the input data.
automated artificial neural network; simulated annealing; Kohonen's self-organizing mapping; Landsat TM; land use land cover; image classifiers; image processing; accuracy assessment
This is an open access article distributed under the
Creative Commons Attribution License which permits unrestricted use, distribution,
and reproduction in any medium, provided the original work is properly cited.
Export to BibTeX | EndNote
MDPI and ACS Style
Yuan, H.; Van Der Wiele, C.F.; Khorram, S. An Automated Artificial Neural Network System for Land Use/Land Cover Classification from Landsat TM Imagery. Remote Sens. 2009, 1, 243-265.
AMA StyleYuan H, Van Der Wiele CF, Khorram S. An Automated Artificial Neural Network System for Land Use/Land Cover Classification from Landsat TM Imagery. Remote Sensing. 2009; 1(3):243-265.
Chicago/Turabian StyleYuan, Hui; Van Der Wiele, Cynthia F.; Khorram, Siamak. 2009. "An Automated Artificial Neural Network System for Land Use/Land Cover Classification from Landsat TM Imagery." Remote Sens. 1, no. 3: 243-265.
Remote Sens.
Published by MDPI AG, Basel, Switzerland
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Last Activity: 18th January 2015 01:57 AM
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1 | Hi, I decided to switch from CM10 to JellyBam, just to change flavours a bit. Luckily, I decided to make a nandroid first. I then rebooted to recovery, wiped data/cache, and proceeded to install the ROM, choosing CM10 kernel in Aroma, along with... | View... |


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In Stock
Ships Within 24 Hours Sellout Risk: Extremely High
Helmet compatible with fantastic comfort in the mountains, the Zeal Fargo Goggles for men are built to perform in the snow. With a clean no frills design, the injection molded frame looks amazing and being impact resistant, holds up to seasons of hard use. The Optimum lens features 100% UV protection and provides a wide field of view that helps you see more of the upcoming terrain in this mountain eyewear.


text:
Therapeutic Drug Monitoring in IBD
Anti-MAdCAM antibody induces remission in ulcerative colitis
Assessing Real-world Outcomes with New HCV Regimens in 2014: HCV-TARGET Registry Findings
Pediatric Metabolic Liver Disorders: Diagnostic Challenges via Case Choice
Patients with Crohn's disease were at increased overall risk for cancer compared with the general population, while those with ulcerative colitis were not in a recent study.
Researchers evaluated 1,437 patients with ulcerative colitis (UC) and 774 with Crohn's disease (CD) between 1978 and 2002 in Denmark. Follow-up was conducted until Dec. 31, 2010 or cancer incidence, death or emigration during a median of 15 years and 14 years for the UC and CD groups, respectively.
Cancer developed in 207 patients in the UC group, with no significant increase in overall risk (standardized IR=1.12; 95% CI, 0.97-1.28) regardless of sex, age, tobacco use, disease localization or use of 5-aminosalicylic acid (5-ASA) or thiopurines. These patients, however, were at significantly elevated risk for prostate cancer (SIR=1.82; 95% CI, 1.17-2.71), particularly among patients who had ever used 5-ASA (SIR=1.84; 95% CI, 1.16-2.76) and had never used thiopurines (SIR=1.84; 95% CI, 1.17-2.76).
Patients with CD were at significantly increased overall cancer risk, with 129 cases developing during follow-up (SIR=1.55; 95% CI, 1.29-1.84). Specifically, these patients were at elevated risk for small bowel (SIR=15.18; 95% CI, 1.84-54.78) and lung cancers (SIR=2.13; 95% CI, 1.19-3.52), and cervical dysplasia (SIR=1.65; 95% CI, 1.1-2.37) and non-Hodgkin's lymphoma (SIR=3.43; 95% CI, 1.38-7.07). Men with CD also were significantly more likely to develop colorectal cancer (SIR=2.43; 95% CI, 1.05-4.78).
The increased lung cancer risk in CD patients was associated with smoking and more prominent among women; cervical dysplasia was linked to smoking, 5-ASA use, thiopurine exposure and younger age at diagnosis. Lymphoma diagnosis in CD patients was associated with nonuse of 5-ASA, younger age and small bowel and colonic disease.
"This population-based cohort study … showed that the overall risk of cancer was increased in CD patients, but not in UC patients," the researchers wrote. "However, the risk of certain subtypes of cancer was significantly higher than in the general population. … Our study's findings add to the ongoing discussion of ways of differentiating between baseline and treatment-induced cancer risk in IBD patients."
Disclosure: The researchers report no relevant financial disclosures.
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The McDougal Family page of West VirginiaUpdated July 12, 2003 |
Jim McDougal email@example.com |
Edit Your Page |
This page contains my ancestors back to William McDougal who came to the US in about 1760. If you have comments please feel free to email me. I'd love to hear from you. Jim |
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Results 1 to 15 of 57
Thread: Collusion!
March 11th, 2012, 12:02 PM #1
- Join Date
- Sep 2001
- Posts
- 921
Have you heard the latest? The Justice Department is considering bringing a lawsuit against Apple and several other retailers for colluding with publishers to keep ebook prices high.
It all stems from the new pricing model. Publishers used to sell books to retailers and then the retailers set competitive prices. No more - publishers set the prices for ebooks, and retailers take a 30% cut. The deal was first struck with Apple, and then quickly signed by Amazon, B&N, etc. It results in the same price everywhere, no competition, and no ability of the retailer to lower prices. And that's not America. That's not even Canada.
It's almost certain that the DoJ interest will result in a freer market - and lower prices on ebooks. Soon, retailers will probably have the ability to set their prices on ebooks. Amazon already takes losses on many paper books to drive people to its site. If it had the ability to make its Kindle pass the iPad in popularity, how low do you think they will set ebook prices? I for one, can't wait!
March 11th, 2012, 12:22 PM #2
for all I care they can charge an arm and a leg for e-books, I wouldnt mind a price reduction on actual books though.
March 11th, 2012, 01:21 PM #3
as I understand it from the indictment, the main issue here is the clause that say the publisher is forbidden to offer the book at a lower price anywhere else, eliminating competition and artificially inflating the value of th ebook.
March 11th, 2012, 01:28 PM #4
I get the idea that publishers want to get as much as possible for their product. Even applaud it. Thats what free enterprise is about. But to legally keep prices high, I sure don't agree with. Competition is the backbone of free enterprise and I think that if the publishers cut the prices of some of their ebooks they might find in the long run they will make more. I would probably buy even more books for my Nook if they were cheaper, and I know there are quite a few people out there that feel the same way. Greed has gotten to be the way of this country and it is a sad thing to see.
March 26th, 2012, 10:36 AM #5
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They updated with a new article. The issue of forbidding the publisher from offering a lower price elsewhere is one facet, but another is that the JD claims the publishers and multiple competitors (namely Apple and Amazon) colluded to set book prices. When competitors work together to set high prices for books so they can make more money, it is illegal.
It was always obvious that a couple of years ago, ebook prices went through the roof and were artificially high. I assumed the publishers were asking for a lot of money for the ebooks from the retailers. Looks like the retailers were in on it. The JD thinks they have a very strong case, and I'm looking forward to much lower ebook prices.
Publishers claim 90% of their cost is from things other than printing and distributing the books. They claim they couldn't lower ebook prices if they wanted to. Why argue with the - the easiest way is to eliminate the publisher. More and more writers are becoming successful without a publisher by direct selling ebooks. This kind of reminds me of Louis CKs latest show, which he offered for $5 from his website. He made well over $1M, which he said is far more than he would have made selling the show to HBO and having them make a video of it. He simply hired a producer and the camermen himself. Better for everyone (except the middleman).
March 26th, 2012, 11:48 AM #6
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I understood that the "price fixing" was in response to Amazon selling ebooks below cost so they could sell more kindles. If that is the case (which it may not be), I think both are wrong.
Obviously publishers are struggling with the the new technology. They can resist but new tech will happen whether they want it to or not. Ask Kodak.
I have not tried an e-reader yet. I like books but will at least give a reader a shot sometime.
Two things that may make them work for me:
1. Read without reading glasses.
2. Easier to read in bed than a hard cover book.
March 26th, 2012, 12:05 PM #7
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April 12th, 2012, 09:39 PM #8
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The U.S. accused Apple and five of the nation's largest publishers Wednesday of conspiring to raise e-book prices, in a case that could radically reorder the fast-growing business.
In a civil antitrust lawsuit, the justice department alleged that CEOs of the publishing companies met regularly in private dining rooms of upscale manhattan restaurants to discuss how to respond to steep discounting of their e-books by amazon.com inc., a practice they disliked. The executives also called and emailed each other to craft a solution to what one of them called "the wretched $9.99 price point," the suit said.
The five publishers and apple hatched an arrangement that lifted the price of many best-selling e-books to $12.99 or $14.99, according to the suit. The publishers then banded together to impose that model on Amazon, the government alleged.
"As a result of this alleged conspiracy, we believe that consumers paid millions of dollars more for some of the most popular titles," said attorney general Eric Holder.
The publishers and apple denied any wrongdoing. Some publishers said the government's action could harm consumers by giving Amazon excessive control of the industry.
The lawsuit upends an industry already undergoing wrenching change as printed books give way to electronic books that can be transmitted anywhere in seconds. Publishers want to keep their role as gatekeeper and ensure that e-books are profitable.
Three of the publishers settled with the justice department, agreeing to let Amazon and other retailers resume discounting of e-books. settlement of a separate suit filed by 16 states and U.S. Territories could lead to tens of millions of dollars in restitution to consumers who bought e-books at the higher prices.Last edited by phil_geo; April 12th, 2012 at 09:41 PM.
April 12th, 2012, 10:15 PM #9
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April 12th, 2012, 10:42 PM #10
April 13th, 2012, 02:15 AM #11
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April 13th, 2012, 05:08 AM #12
We all realise that the agency model usually meant the publisher making less and the third party resellers making more. And that Amazon forcing prices down so far was part of why they changed (so that third party, Amazon or no, got a set amount). Making people NOT Amazon (who were selling ebooks at less than cost to drive sales for the kindle) more competitive, thus reducing the monopolization by Amazon?
If anyone was going to collude to price fix, surely they'd do so to, I don't know, make more money per book, not less?
April 13th, 2012, 06:07 AM #13
Yes, but that is in a perfect world where there are no backroom deals and people always know what these guys are doing. They were caught this time, but given time and the likely small slap on the wrist they will get, they will try something else. This is the way our free market actually works, Enron, Tyco, etc.
April 13th, 2012, 06:40 AM #14
E-books are The Devil, and I will have nothing to do with them. Books are paper - real wrinkly, rustly, mildewy, smelly, yellowing, broken spines, falling open at your favourite parts paper. When you start a book you have a big chunk of pages in your right hand and just a few in your left; you can judge where you are in a story by how that balance changes. You can re-read a book and remember the feel of it in your hand, the weight of THAT book, the curl of its page corners, that weird splodge on page 296. When you read and love a book, you can have the excitement/disappointment of going into a bookshop a few years later and seeing it has got a new cover. E-books, however, are sterile joyless ugly lifeless horrible horrible horrible things. I'll never never switch to using one.
Aaaaaand relax *breathes*.
April 13th, 2012, 06:44 AM #15


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3131 S. Bristol Street Costa Mesa, CA 92626 United States
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The Crash will present a stellar billboard at Auditorio Municipal
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The Mexican boxer reviewed the virtues and weaknesses of his Filipino mate
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CONADE will loose around 15,000,000 dollars
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Get ready for a killer day of riding with your new K2 Supersweet Skis. Catch free rocker makes learning the sport super easy and its soft flex going in and out of each turn will have you saying things like "tubular" and "sweet" and maybe "super". Get ready to start tackling the blues and black diamonds because your Supersweet skis allow you to excel to levels you thought weren't in the cards. The K2 Supersweet, everything its name wants it to be!


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Family Dollar assistant manager accused of embezzlement
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The woman allegedly stole around $7,000 from the store in Suffolk, police said.
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Young Chefs Academy is a unique cooking experience which offers cooking classes to children in a safe environment that encourages discovery and creativity. Each visit is a new experience with monthly themes and exciting new programs. Students sharpen their skills every week! At Young Chefs Academy we take the fear, mystery, and the unknown out of cooking. In addition, each class and event incorporates supplemental subject matter which ties into each theme. Our Class Instructors carry out our mission to provide and interactive learning experience that gives children the opportunity to develop a life-long love for a life-long skill!!
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Cap off your Thunder game day wardrobe with this Tactical structured Flex hat from adidas! It features an embroidered Oklahoma City team logo on the crown, an official adidas logo on the left side along with an NBA logo at the back. Small fits 6 3/4 - 7. Medium fits 7 - 7 1/4. Large fits 7 1/4 - 7 1/2. XL fits 7 1/2 - 7 5/8. Sizes are approximate.
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Meet Hot Guy Panelist, Jason Video
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US 4832877 A Abstract Broadly stated, the present invention encompasses tetranuclear sulfide-bridged complexes of Cr(III) having bridging organo-carboxylate ligands. Indeed, in one embodiment, the present invention is directed toward a novel composition of matter having a complex cation of the general formula Cr4 S(RCO2)8 (L)4 2+, wherein R represents alkyl groups having from 1 to 12 carbon atoms, L represents a ligand or ligands containing a donor atom selected from oxygen, nitrogen, carbon, and sulfur. In the complex of the present invention, the four Cr(III) atoms are bound to a central tetrahedral sulfur atom. The chromium atoms also are octahedrally coordinated with bridging carboxylates and the ligand molecule. Also, the bridging carboxylates, RCO2 of the above formula, are the same or different carboxylates.
Claims(17) 1. A compound containing a complex cation having a central four coordinate sulfur atom bound to four chromium atoms which are substantially in a tetrahedral array and which have bridging organo-carboxylate ligands, and said compound containing an anion capable of rendering the compound stable.
2. The compound of claim 1 wherein the chromium atoms are octahedrally coordinated with the brigding carboxylate ligands.
3. The compound of claim 1 wherein the anions of selected from BF4 -, NO3 -, B(C6 H5)4 -, SO4 2-, MoO4 2-, Cl- and Br-.
4. A compound containing a cation having the formula:
Cr4 S(RCO2)8 (L)4 2+ wherein R is an alkyl group having from 1 to 12 carbon atoms; L is a ligand or ligands containing a donor atom selected from oxygen, nitrogen, carbon, and sulfur; and an anion capable of rendering the cation stable. 5. The compound of claim 4 wherein RCO2 groups represent the same organo-carboxylate.
6. The compound of claim 4 wherein the RCO2 groups represent a mixture of organo-carboxylates.
7. The compound of claim 5 wherein R is methyl.
8. The compound of claim 4 wherein L is selected from H2 O, CH3 OH, and CH3 CN.
9. The compound of claim 7 wherein L is H2 O.
10. The compound of claim 7 or 9 including an anion selected from the group consisting of BF4 -, NO3 -, B(C6 H5)4 -, SO4 2-, MoO4 2-, Cl- and Br-.
11. The compound of claim 10 wherein the anion is selected from the group consisting of BF4 -.
12. A method of forming a compound containing a tetranuclear sulfur-bridged complex of Cr(III) having bridging organo-carboxylate comprising: reacting zero valent chromium and sulfur with a source of the organo-carboxylate at temperatures and for a time sufficient to form said compound containing said complex.
13. The method of claim 12 wherein said chromium is present as chromium hexacarbonyl.
14. The method of claim 13 wherein said source of carboxylate is selected from the group consisting of organo-carboxylic acids, acid anhydrides and mixtures thereof.
15. The method of claim 14 wherein said source of carboxylate is a mixture of carboxylic acid and its corresponding acid anhydride.
16. The method of claim 15 wherein said carboxylic acid is acetic acid and said acid anhydride is acetic anhydride.
17. The method of claim 15 wherein said temperature is the reflux temperature of said mixture of acetic acid and acetic anhydride.
Description This invention relates to novel compositions containing chromium and sulfur. More specifically, this invention relates to novel tetranuclear sulfido-bridged complexes of Cr (III) having strongly magnetic ground states and methods of making the same. Various complexes containing two, three and four chromium atoms are known. With respect to bi- and trinuclear chromium complexes, see, for example, Magneto-Structural Correlation in Exchange Coupled Systems, Willett et al., Ridel, Dordrecht, pp. 497-522 (1985). See also Dubicki et al., Inorganic Chemistry, 11, 1869 (1972) and Figgis et al., Nature (London), 205, 694 (1964) who report a trinuclear chromium (III) acetate in which the three chromium atoms are linked to a central oxygen atom. Two complexes of chromium that have four chromium atoms bound to a central sulfur atom have been reported in journal articles. For instance, Darensburg et al., Organometallics, 3, 1598-1600 (1984) report the synthesis of a sulfur-capped trinuclear chromium carbonyl cluster, S[Cr(CO)4 ]3 2- ; and Hoefler et al., J. Am. Chem. Soc., 105, 6338-6339 (1983) report the synthesis of [PPN]2 (μ2 -CO)3 (CO)9 Cr3 (μ4- S)Cr(CO)5 ], in which the anion consists of chromium triangle capped with an SCr(CO)5 group. Chromium complexes with bridging ligands formed from benzoic acid and containing three chromium atoms connected to a central sulfur atom have been reported by Eremenko et al., Inorg. Chim. Acta, 73, 225-229 (1983). None of these references disclose a tetranuclear sulfide bridged complex of Cr (III). Accordingly, the invention embodied herein is believed by the applicants to be novel in all its aspects. Broadly stated, the present invention encompasses tetranuclear sulfide-bridged complexes of Cr(III) having bridging organo-carboxylate ligands. Indeed, in one embodiment, the present invention is directed toward a novel composition of matter having a complex cation of the general formula Cr4 S(RCO2)8 (L)4 2+, wherein R represents alkyl groups having from 1 to 12 carbon atoms, L represents a ligand or ligands containing a donor atom selected from oxyen, nitrogen, carbon, and sulfur. In the complex of the present invention, the four Cr(III) atoms are bound to a central tetrahedral sulfur atom. The chromium atoms also are octahedrally coordinated with bridging carboxylates and the ligand molecule. Also, the bridging carboxylates, RCO2 of the above formula, are the same or different carboxylates. The compositions of the present invention are especially unique in that they have ferromagnetic properties. As as a result thereof, these compositions are particularly useful as contrasting agents for nuclear magnetic resonance (NMR) imaging, shiftless relaxation reagents to aid the accumulation of 13 C NMR data, orienting agents for attached polymers in a magnetic field, selective microwave absorbers for localized heating of a particular organelle, organ, organism or inanimate substructure, or as part of a thermometer for use above 0.2 degrees Kelvin. The novel compositions disclosed are made by reacting a source of chromium, such as chromium metal or chromium carbonyl with sulfur and the appropriate source of coordinating bridging carboxylate, such as the corresponding carboxylic acid, acid anhydride or mixtures thereof at temperatures and for time sufficient to form the composition. The invention will now be illustrated in non-limiting fashion by the following example and discussion. The DRAWING is a depiction of the structure of a complex cation of the present invention. The invention encompasses tetranuclear sulfide-bridged complexes of Cr(III) including bridging ligands from carboxylates. Indeed, the complex cations of the present invention are represented by the general formula Cr4 S(RCO2)8 (L)4 2+, wherein R is an alkyl group having from 1 to 12 carbon atoms and L is a ligand containing a donor atom selected from oxygen, nitrogen, carbon, and sulfur. Preferably R is methyl and L is selected from H2 O, CH3 CN and CH3 OH. It should be noted that the bridging carboxylates in the above formula are preferably all of the same type; however, such is not necessary and a mixture of different bridging carboxylates may be employed, if so desired. Compounds containing the novel complex cation will contain an anion. Any anion which will render the compound stable is suitable. Examples of such anions are BF4 - NO3 -, B(C6 H5)4 -, SO4 2-, MoO4 2-, Cl-, Br-, and the like. These complexes are made by reacting Cr(CO)6 or chromium metal with sulfur and an appropriate source of bridging organo-carboxylates such as organo-carboxylic acid and organo-carboxylic anhydrides at a temperature and for a time sufficient to form the complex cation. The reaction may be conducted in an inert solvent; however, when the source of the bridging carboxylate is a liquid a solvent is not necessary. Indeed, it is particularly preferred to react the Cr(CO)6 or chromium metal with sulfur and with a mixture of an acid and an anhydride. For example, especially preferred is a one-to-one mixture of acetic acid and acetic anhydride. The reaction also is preferably conducted at elevated temperatures such as the refluxing temperature of that of the source of coordinating bridging carboxylate. The reaction does yield a mixture of cationic species which can be separated by generally known techniques. For example, these species are separable by ion-exchange chromatography. Moreover, elution with an appropriate source of anion will yield the complex cation in a form which can be crystallized as a salt by slow evaporation of the solvent, by recrystallization from a suitable solvent, and the like. The following is an example of one species of the present invention and its method of preparation. Cr4 S(O2 CCH3)8 (H2 O)4 [(BF4)2.H2 O] was prepared by adding Cr(CO)6 (2 grams, 9.1 millimoles) and elemental sulfur (0.3 grams, 9.4 millimoles) to 50 ml of a one-to-one mixture of acetic acid/acetic anhydride and refluxing the mixture for 2.5 hours. The reaction mixture then was diluted with 100 ml H2 O and adsorbed on an ion-exchange column containing Dowex 50W-X2, a cation exchange resin containing sulfonated polystyrene sold by Dow Chemical Company, Midland, Michigan. Elution with 0.1 M HBF4 solution removed a green band of [Cr3 O(O2 CCH3)6 (H2 O)3 ]+. The blue band of [Cr4 S(O2 CCH3)8 (H2 O) 4 ]2+ was removed with 0.5 M HBF4 solution and the blue solution was placed in a dessicator for evaporation of the water. Upon evaporation of the water, dark blue crystals were obtained. These were recrystallized from methanol by slowly evaporating that solvent. Elemental analysis was as follows: Calculated for [Cr4 S(O2 CCH3)8 (H2 O)4 (BF4)2.H2 O; C, 19.67; H, 3.48; S, 3.28; Cr, 21.31; F, 15.57. Found: C, 18.93; H, 3.46; S, 3.50; Cr, 20.48; F, 15.39. The compound also was analyzed by single crystal X-ray diffraction analysis techniques. The key parameters for determining the structure of the complex obtained in accordance with the present invention is shown in Table I. TABLE I______________________________________Parameters from Structure Determination of[Cr4 S(O2 CCH3)8 (H2 O)4 ](BF4)2.H2 O______________________________________a, Å 21.066(4)b, Å 19.086(3)c, Å 9.323α, deg 90.0β, deg 90.0α, deg 90.0V, Å3 3,748(1)z 4.0Calculated Density, g/cm3 1.73Reflections with F > 3σ 2,939.0μ, cm-1 1.27 mn-1sinθ/λ (max) 0.650R 0.048Rw 0.049GOF 2.03______________________________________ Atomic coordinates for non-hydrogen atoms are given in Table II. TABLE II______________________________________Atomic Coordinates for Non-Hydrogen Atoms inCrystalline [Cr4 S(O2 CCH3)8 (OH2)4](BF4)2.H2 Oa Equivalent Isotropic ThermalAtom Fractional Coordinates ParameterTypeb 104 x 104 y 104 z B, Å2 � 10c______________________________________CationCr1 5,971(1) 3,473(1) 4,120(1) 25(1)Cr2 4,414(1) 2,500d 5,078(1) 21(1)Cr3 4,936(1) 2,500d 1,266(1) 24(1)S 5,326(1) 2,500d 3,628(2) 19(1)O1 6,539(2) 4,300(2) 4,614(4) 44(1)O2 3,609(3) 2,500d 6,279(7) 40(2)O3 4,518(4) 2,500d -692(6) 42(2)O4 5,300(2) 3,983(1) 5,142(4) 35(1)O5 4,737(2) 3,208(2) 6,412(3) 32(1)O6 5,540(1) 3,208(2) 570(3) 32(1)O7 5,732(2) 3,962(1) 2,361(3) 31(1)O8 4,018(1) 1,751(2) 3,979(3) 33(1)O9 4,341(1) 1,739(2) 1,969(3) 34(1)O10 6,681(1) 3,087(2) 3,036(4) 37(1)O11 6,253(2) 3,087(2) 5,944(3) 36(1)C1 4,939(2) 3,826(2) 6,144(5) 31(1)C2 4,712(3) 4,395(3) 7,114(7) 60(2)C3 5,743(2) 3,786(2) 1,063(5) 31(1)C4 6,015(4) 4,288(3) 1(6) 61(2)C5 4,032(2) 1,504(2) 2,727(5) 29(1)C6 3,627(3) 871(3) 2,473(7) 29(1)C7 6,896(3) 2,500d 2,649(7) 33(2)C8 7,463(4) 2,500d 1,688(13) 54(3)C9 6,345(3) 2,500d 6,530(7) 26(2)C10 6,572(4) 2,500d 8,038(9) 41(2)AnionB 7,752(4) 4,190(4) 7,532(10) 64(3)F1 7,145(2) 4,297(3) 7,305(6) 103(2)F2 8,068(3) 4,779(3) 7,627(6) 127(2)F3 7,880(3) 3,714(3) 8,436(7) 146(2)F4 7,926(4) 3,922(4) 6,203(7) 195(4)Water of CrystallizationOw 3,212(4) 2,500d -314(8) 92(3)______________________________________ a The numbers in parentheses are the estimated standard deviations i the last significant digit. b Atoms are labeled in agreement with the drawing. c This is onethird of the trace of the orthogonalized Bij tensor. d This is a symmetryrequired value and is therefore listed without a estimated standard deviation. As is shown in the drawing, the complex cation of this invention consists of a central four coordinate sulfur atom bound to four chromium atoms which are in an approximate tetrahedral array. The chromium-chromium distances average 3.83 Å (range 3.72-3.91 Å). Each chromium atom is six-coordinated with a near-octahedral arrangement of five oxygen donors in the central sulfur atom. The one water ligand on each chromium lies trans to the sulfur atom. The remaining oxygen ligands of each chromium come from bridging acetate ligands. These are of two types: four acetate ligands are involved as two pairs of double bridges. These acetates are equivalent and related by an approximate S4 axis. The overall symmetry of the cation is close to a D2d while that of inner Cr4 S core is very close to Td. The structure shown is related to that of beryllium basic acetate, Be4 O(CH3 CO2)6 (see Charalombous et al., Inorg. Chim. Acta, 14, [1975]), although in this structure, the Be atoms are tetrahedrally four-coordinated rather than octahedrally six-coordinated, as are the Cr atoms in the chromium complex. Clearly, the complex of the present invention represents a new structural type containing a central four-coordinated sulfur atom, and four octahedral metal ions on the tetrahedral periphery. In addition to the unique structure of the complex of the present invention, it displays unusual magnetic behavior. The magnetic susceptibility χ versus temperature T was measured on polycrystalline samples from 13� mK to 300� K. in magnetic fields, H, of 75 Gauss to 6.3 k Gauss using SQUID, Faraday and vibrating sample magnetometers (VSM). In addition, magnetization versus H isotherms were measured at 1.3� K. and 4.2� K. using the VSM. These data prove that the ground state of the Cr4 cluster has a spin S=6, with a Landeg factor g=2.00�0.02. Electron spin resonance data at 15� K. for the Cr complex frozen in solution yielded a very similar g value. The chromium compound of the present invention is useful, for example, as a thermometer at temperatures above 0.2� K. By measuring the magnetic susceptibility, χ, of the compound, the temperature can be determined from the following relationship: ##EQU1## where χo =-4.66�10-4 cm3 /mole Cr4, E=-JS(S+1) with J/kB =14.5� K., Gs =4, 9, 11, 10, 6, 3 and 1 for S=0, 1, . . . , 6, respectively, N is Avogadro's number, g=2.00 is the Landeg-factor, μB is the Bohr magnetron, kB is Boltzmann's constant, and Z is the partition function: ##EQU2## It should be understood that the foregoing disclosure, description and example are only illustrative of the invention. Various changes to the details of the invention will be apparent to the skilled worker, and may be made within the scope of the appended claims without departing from the spirit of the invention. Non-Patent Citations
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Gourment Sweet Treats Tower Gift Set - 26.4 oz.
24.4 oz. of Delectable Tasting Treats. Beautifully decorated gift tower with the perfect mix of sweet treats. Everyone is sure to Enjoy this Delicious Gift Tower
For click 'n pull orders, please specify the color or style in the comments section. Colors and styles may vary due to inventory for each club.
This Holiday Tower is 5 Boxes containing the best treats. Luxurious Chocolate Gift. 26.4 ounces of goodness! Great holiday gift for all, corporate, holiday or business. For the chocoholic in all of us.
Available to purchase in 3 Styles: Red, Gold and Silver. For Click 'n' Pull orders, during checkout please specify in Comments Box which color/style you prefer. Selection limited to availability at local Clubs. All colors and styles may not be available at all Clubs.
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Water Fight Recorded: Friday, March 7, 2014
Senior Fellow Randy T. Simmons, co-editor of Aquanomics, looks at the battles over water in the western United States. Thirsty citizens of growing cities, farmers, factories and environmentalists are in a fight for a natural resource that is priced arbitrarily. Its value is determined not by the free market, but by bureaucrats. Outdated government reclamation projects and water policies have put residents of the Golden State at the mercy of the weather, and of government's mandatory regulations.
Experts: Randy T. SimmonsType: Independent Institute TVIssues: Business, Economic Policy, Environment, Land Use, Political Ideology and Philosophy
The Roots of Government Failure: An Interview Recorded: Wednesday, November 30, 2011
William Shughart interviews Economist Randy T. Simmons, author of Beyond Politics: The Roots of Government Failure.
Experts: William F. Shughart II, Randy T. SimmonsType: Independent Institute TVIssues: Democracy, Economic History and Development (U.S.), Public Choice Theory
Understanding Today's Economy: A Summer-Seminar Preview for Teens and Their Parents Recorded: Thursday, May 20, 2010 – Monday, January 1, 1900
Part 1 | Part 2 | Part 3 | Part 4 | Part 5 | Part 6
Part 1: Introductory Remarks by David Theroux Part 2: Why Economics Matters more than Ever with Gregory Rehmke Part 3: Healthcare Reform: a Principled Critique by Michael Winther
Experts: Anthony Gregory, Gregory Rehmke, Emily C. Skarbek, David J. Theroux, Michael Winther, José Maria J. YuloType: Independent Institute EventIssues: Free Market Economics, Political Ideology and Philosophy


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open an account and enjoy 25% off* your purchasewhen you apply for a Brooks Brothers Platinum MasterCard® or the Brooks Card®
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Columbus Day Sale - 20% Off All Sweaters* Shop Now
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Wool, smoke mother-of-pearl buttons, half-lined. Dry-clean only.
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United Technologies
1 person found this helpful
"Great place to work and get advanced education "
- Comp & Benefits
- Work/Life Balance
- Senior Management
- Career Opportunities
I worked at United Technologies
employee scholar program (was) best in the industry
solid benifits
ability to move up and remain in similar geographic location (northeast)
too much beaurocracy
lower level employees not empowerd enough
continue to develop and promote new talent and leadership
"+/- "
- Comp & Benefits
- Work/Life Balance
- Senior Management
- Career Opportunities
I have been working at United Technologies
ProsThere are lots of opportunities for movement - many locations within a 30 minute driving area as well as many locations around the world if a move is preferred. You also do not get trapped in job situations for years on end, as movement is encouraged.
Networking and being recognized is very easy due to the large but centralized company. Most employees have worked for and keep in touch with employees in other divisions, so there is no excuse to not have a reputation to work with.ConsPay and benefits are very low compared to similar jobs in the surrounding area. The employee scholar program is the only unique benefit, but if you do not intend to take advantage, UTC can be frustrating to work for.
Low compensation is even harder to grasp due to the poor work life balance offered. Hours and face time expectations are high and there is always a shortage of heads to complete necessary tasks (even in the good economic times).Advice to ManagementAdviceMany employees work at UTC understanding their pay may be lower than similar jobs. The hard part is the lack of comp time, extremely stingy PTO policies, etc.
Also - you pay in the (less than) 50th percentile, you retain employees that perform less than that mark. You lose the employees that are worth their salt to competitors who will compensate for performance.Doesn't RecommendApproves of CEO -
1 person found this helpful
"Intern "
- Comp & Benefits
- Work/Life Balance
- Senior Management
- Career Opportunities
I worked at United Technologies
ProsThey allow you to learn new things and technologies for advancing your career. When you work within the company, you have many chances to move around and find something else in a different location or in the same location if you would like. Very diverse.
ConsUpper level management really needs to pay more attention to what is going on with the employees and the problems encountered. Their valuable input is sometimes ignored because someone is worried about upper level management.
Advice to ManagementAdviceListen to employees, even the guys at the bottom. If you want to bring people back to the company and earn trust, that is what you need to do.
No opinion of CEO -


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Commenting on Entertainment Pages
Closed - This job posting has been filled.
Job Description
This job is for online gamers with at least average english writing skills and passion to online games.
(need several people for this project)
I need some comments / communication / posts on free games pages.
Your tasks will be commenting / chatting / discussing games / gameplays on site.
Please note: its NOT a backlink building on other sites, but simple communication (content creation) on my sites.
5 - 10 cents per comment (first we start at 5 cents per comment and if you stay constantly active and writing good comments price will be raised to 10 cents per comment)
Comment must be between 50 - 100+ words length, not silly, but fun or informative comment.
I would need up to 5-10 comments per day from each commenter (not nessesary every day).
Comments discussion can not be copy/pasted from other internet places (copyscape passed), must be written by yourself, and must be not out of context.
This is ongoing job and i expect long working relationships with creative mind writers who have strong sense of responsibility.


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Seed swap update and directions
So as not to confuse anyone I am manure queen. Gathering will be January 3, 12ish. We confab, swap then we dine.
I do nto fret about what anyone brings, we eat whatever is brought.
I do not do disposables if any one wants to bring napkins that would be fine , other wise, we use paper towels.
I am at 5707 Old Temple Hill road
temple hills 20748. There are 3 unconnected pieces of old TH , I am on the section at the top of the hill off Temple hills road at St stevens baptist church. If by chance the road is parked on both sides just drive thru the lot and come out the next exit on the left. It is safer.
If coming from the North on the beltway, exit branch Ave S(route 5). take the 2nd exit and turn right onto Allentown, Trn right at the 3rd light onto Brinkley . Go abt 1mi to Temple Hills (light) and turn right. take 2nd left at top of hill. I am 2nd house on rt in 2nd block.
From the South on the beltway get off exit 4A(east to miss as exit sign is at the turn for the ramp) turn left at 2nd light at end of ramp. onto Brinkley road at gnhouse
Proceed to temple hills road and turn left at light. proceed as above to Old TH rd on the left.


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VIEWS: 6 PAGES: 3 CATEGORY: Other POSTED ON: 12/15/2010
Fertility-Boosting Foods, Boosting Female Fertility, Effective Ways to Increase Female Fertility, How to Become Pregnant Naturally
Boosting Female Fertility - Some Dos and Don'ts Many women wish to get pregnant and have a child, but not all find getting pregnant to be an easy task. Often, women older than 35 years have a hard time trying to conceive, but fertility issues may also be experienced by younger women. The good news is, regardless of age, there are helpful tips that really work by boosting female fertility. There are definite dos and don'ts to follow to increase one's chances of becoming pregnant. Boosting female fertility, these are some dos to observe: 1. Do exercise regularly to maintain a good body weight. Being underweight or being overweight prevents a woman from getting pregnant. Exercising regularly has many benefits; it makes one healthy and is a good way to de-stress. 2. Do eat a balanced diet. Make sure to get enough of these fertility-enhancing nutrients: vitamins D, C, B and E, antioxidants, folic acid, zinc, selenium and omega-3 fatty acids. Consult a nutritionist to get professional advice on what specific food items and supplements to take to help increase fertility levels. 3. Do drink plenty of water. 4. Do seek prompt treatment for diseases related to the reproductive system, such as chlamydia. 5. Do use ovulation kits or basal body temperature charts to determine when to have sex that will lead to conception. On the other hand, these are don'ts that should be avoided at all costs: 1. Don't smoke. The harmful substances in cigarettes impair reproductive functioning and decrease estrogen levels in the body. 2. Don't take caffeine and alcohol. Coffee is especially harmful, according to studies. It is estimated that having even one cup of coffee a day can decrease a woman's chances of getting pregnant by 55%. 3. Don't stress. Excessive stress lowers fertility levels significantly, which is why women who desperately want to get pregnant cannot do so when they try too hard. 4. Don't stay in places where there are pesticides, radiation, lead, heavy metals and other environmental hazards. Do you want to naturally and safely get pregnant within four weeks from now? If yes, then I I advise that you use the techniques recommended in this infertility cure guide: Pregnancy Miracle Program, to significantly boost your odds of quickly conceiving and giving birth to a healthy baby. Click here ==> Lisa Olson's pregnancy miracle guide, to read more about this Natural Infertility Treatment System, and see how it has helped tens of thousands of women allover the world with infertility related problems.


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Callaway Golf Appoints Harry Arnett Senior Vice President Of Marketing
CARLSBAD, Calif., June 18, 2012 /PRNewswire/ -- Callaway Golf Company (NYSE: ELY) today announced the appointment of Harry Arnett as Senior Vice President, Marketing. In this role, Arnett assumes leadership of the Company's global marketing, communications and go-to-market functions. The announcement was made by Chip Brewer, President and CEO, Callaway Golf.
"Harry has demonstrated an impressive ability to develop and execute compelling strategies on a global scale that clearly connect with golfers," said Brewer. "We're looking forward to his contributions and leadership of our Marketing as we further strengthen our organization and move ahead with our turnaround plan."
"It's awesome to be a part of such an iconic brand and join a company so completely dedicated to making the best products in the world," said Arnett.
Arnett joins Callaway Golf with extensive golf industry experience. He most recently held the position of VP of Global Marketing, TaylorMade, adidas, and Ashworth Golf. In addition, he has held senior marketing leadership roles at Russell Corporation and Tinwood Media Ventures. Arnett earned an MBA from Duke University after completing his undergraduate studies at Emory University in Atlanta.
For more on Callaway Golf Company, please visit www.CallawayGolf.com About Callaway Golf Through an unwavering commitment to innovation, Callaway Golf Company (NYSE:ELY) creates products and services designed to make every golfer a better golfer. Callaway Golf Company manufactures and sells golf clubs and golf balls, and sells golf apparel, footwear and accessories, under the Callaway Golf® and Odyssey® brands in more than 110 countries worldwide. For more information please visit www.callawaygolf.com or shop.callawaygolf.com. CONTACT: Tim Buckman Callaway Golf Company firstname.lastname@example.com 760-804-4133 (Logo: http://photos.prnewswire.com/prnh/20091203/CGLOGO) SOURCE Callaway GolfCheck Out Our Best Services for Investors
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Latest News
Catch up on the latest news and information on SASA and let us know your thoughts
Read our latest...Club Directors
Our Director of Coaching and Board of Directors is here to serve you
Club Directors...Latest Posts
SASA Hosts British Summer Soccer Camp
July 20th -24th at Sandra Richardson Park — Full and Half Day Options for Players ages 3 to 18 Register
Have you touched a ball lately?
Check out wonderkid U8 player Denim Nnamudi from Chelsea FC's development program in England:
View our SASA Player Development Philosophy
At SASA, we seek to develop our players across the club with a common vision. To help illustrate our thoughts on how best to build a legacy one player at a time, we have created a Player Development Philosophy. This document outlines how we as a club view development at each broad stage of development, […]
SASA welcomes another amazing new coach to our travel program — Peri Marosevic!
Peri played for the US National U15-U20 teams, U of M, FC Dallas and Toronto FC (both of which are MLS teams). He represented the US on the U20 team at the 2009 World Cup in Egypt and captained the U17 and U18 US teams. He's also a leader off the field, with multiple academic […]
Field Status
The fields are CLOSED for the winter. Check back here during the season to see the status of our SASA fields for practices and games.


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Instructions on how to take advantage of the Groups feature in our community. Tags: how, to Melissa Lee Feb 5, 2009 435 views
Follow these links to learn more about the different groups that help us coordinate volunteer work… Tags: DHF, groups Manny Hernandez Jan 14, 2009 552 views
Exercise can be something done in a group setting outdoors! Type 2 diabetics need exercise....here… Tags: exercise, diabetes Richard Aguinaldo Mar 13, 2008 237 views
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Emily Coles (Head of Communities, has type 1) Mila Ferrer Mike Lawson Corinna Cornejo Desiree Johnson (Administrative and Programs Assistant, has type 1) |
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Even though Dexter's iPhone -- and eventual PC release -- game debut has been put on hold until the summer his game trailer debut is happening right now. The trailer (found after the break) showcases ... well, nothing really. It's a few shots of Dex swinging a knife around wildly -- and quite out of character, might we add -- with a final shot of Showtime's lovable serial killer decked out in full Dark Passenger garb, requesting our silence and attention.
Wait. Is he talking to us? Oh crap, he is. Listen, we didn't do that thing you think we did. Seriously, you can let us go now. Ow! That knife is sharp. Is that blood? We're not too good with the sight of ... uh oh ... passing out now.
Featured Stories
Off the Grid: The Witcher Adventure Game and Star Wars Imperial Assault
Posted on Feb 3rd 2015 2:15PM


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Burn Calories in Style
Now that your new gym routine is in motion, it's time to complement your workout with a few new pieces. Burn calories in style with Nordstrom Zella's activewear line, featuring high-performance clothing that is simultaneously comfy and cute. Add a dose of color to your morning run in bold colorblock and space-dyed separates, or make the ultimate fashion statement in a pair of power-striped printed leggings. No doubt, these pieces will make you want to move.
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Nowadays it seems like everybody and their grandmothers own iPhones, and it's starting to get – dare I say it? – boring. Where's the fun? Where's the individuality? Do you really want to live in a world where every smartphone looks the same? No, I didn't think so. That's where Grove Skatebacks come in. Made from waste material created during skateboard manufacturing, the Grove Skatebacks are protective back covers with peel-and-stick 3M adhesive that add a whole lot of personality your iPhone 4 or 4S. (Price: $49.00 BUY)
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Grove Skatebacks
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Will Ferrell & More Among Winners of AMERICAN COMEDY AWARDS; Full List Announced
The "American Comedy Awards" aired last night, Thursday, May 8 (9-11 p.m. ET/PT) on NBC. The awards honor those who have achieved new heights during the past year in both film and television and pay tribute to some of comedy's most enduring personalities.
Chris Rock presented the Johnny Carson Award for Comedic Excellence to Bill Cosby. Other presenters include Scott Aukerman, Lake Bell, Mike Birbiglia, Hannibal Buress, Andy Daly, Billy Eichner, Bill Hader, John Hodgman, Johnny Knoxville, Leslie Mann, Stephen Merchant, Adam Pally, Aubrey Plaza, Timothy Simons, JB Smoove, Patrick Stewart and Matt Walsh. Stand-up comedian and actor Craig Robinson and The Nasty Delicious performed as the House Band.
The full winners list is as follows
Bruce Dern - Nebraska
Will Ferrell - Anchorman 2: The Legend Continues
Johnny Knoxville - Jackass Presents: Bad Grandpa
Simon Pegg - The World's End
Seth Rogen - This Is the End
Comedy Actress - Film
Lake Bell - In A World...
Sandra Bullock - The Heat
Julia Louis-Dreyfus - Enough Said
Melissa McCarthy - The Heat
Kristen Wiig - The Secret Life Of Walter Mitty
Comedy Supporting Actor - Film
Louis C.K. - American Hustle
Steve Carell - Anchorman 2: The Legend Continues
Will Forte - Nebraska
Jonah Hill - This Is the End
Danny McBride - This Is the End
Comedy Supporting Actress - Film
Scarlett Johansson - Her
Jennifer Lawrence - American Hustle
June Squibb - Nebraska
Emma Watson - This Is the End
Kristen Wiig - Anchorman 2: The Legend Continues
Funniest Motion Picture
Anchorman 2: The Legend Continues
The Heat
Jackass Presents: Bad Grandpa
This Is the End
Comedy Director - Film
Paul Feig, The HeatSPIKE Jonze, Her
Alexander Payne, Nebraska
Seth Rogen & Evan Goldberg, This Is the End
Edgar Wright, The World's End
Comedy Screenplay
The Heat, written by Katie DippoldHer, written by SPIKE Jonze
Nebraska, written by Bob Nelson
This Is the End, written by Seth Rogen & Evan Goldberg
The World's End, written by Simon Pegg & Edgar Wright
Comedy Series
Brooklyn Nine-Nine
Modern Family
Parks and Recreation
Saturday Night Live
Alternative Comedy Series
Drunk History
Key & Peele
Kroll Show
Late Night Talk Show (tie)
The Colbert Report
The Daily Show with Jon Stewart
Jimmy Kimmel Live!
Late Night with Jimmy Fallon
Comedy Actor - TV
Fred Armisen - Portlandia
Jason Bateman - Arrested Development
Keegan-Michael Key - Key & Peele
Jordan Peele - Key & Peele
Andy Samberg - Brooklyn Nine-Nine
Comedy Actress - TV
Zooey Deschanel - New Girl
Lena Dunham - Girls
Julia Louis-Dreyfus - Veep
Amy Poehler - Parks and Recreation
Amy Schumer - Inside Amy Schumer
Comedy Supporting Actor - TV
Aziz Ansari - Parks and Recreation
Will Arnett - Arrested Development
Ty Burrell - Modern Family
Bill Hader - Saturday Night Live
Tony Hale - Veep
Comedy Supporting Actress - TV
Vanessa Bayer - Saturday Night Live
Julie Bowen - Modern Family
Kate McKinnon - Saturday Night Live
Chelsea Peretti - Brooklyn Nine-Nine
Aubrey Plaza - Parks and Recreation
Comedy Writing - TV
Arrested Development
The Colbert Report
Key & Peele
Modern Family
Parks and Recreation
Comedy Directing - TV
Arrested Development
Eastbound & Down
Key & Peele
Modern Family
Parks and Recreation
Comedy Special of the Year
Aziz Ansari - Buried Alive
Kristen Schaal - Live at the Fillmore
Louis C.K. - Oh My God
Mike Birbiglia - My Girlfriend's Boyfriend
Patton Oswalt - Tragedy Plus Comedy Equals Time
Sarah Silverman - We Are Miracles
Club Comic
Maria BamfordBill Burr
Jerrod Carmichael
Ron Funches
Kyle Kinane
Sebastian Maniscalco
Sean Patton
Brian Regan
Rory Scovel
Doug Stanhope
Concert Comic
Bill Burr
Hannibal Burress
Louis C.K.
Jim Gaffigan
Kevin Hart
Kathleen Madigan
Patton Oswalt
Russell Peters
Brian Regan
Amy Schumer
Viral Video
"Bad Lip Reading: The NFL" http://www.youtube.com/watch?v=Zce-QT7MGSE"Bound 3" (James Franco & Seth Rogen) http://www.youtube.com/watch?v=nRckgn36lzY
"Dead Giveaway" (Charles Ramsey Cleveland Hero Remix) http://www.youtube.com/watch?v=nZcRU0Op5P4
"How Animals Eat Their Food" http://www.youtube.com/watch?v=qnydFmqHuVo
"Miley Cyrus: Wrecking Ball" (Chat Roulette Version) http://www.youtube.com/watch?v=W6DmHGYy_xk
"Sad Cat Diary" http://www.youtube.com/watch?v=PKffm2uI4dk
"Sexy Pool Party" http://www.youtube.com/watch?v=9R6Ibz31DtE
"Taylor Swift: I Knew You Were Trouble" (Goat Edition) http://www.youtube.com/watch?v=BCv-HxktZFc
"What Does the FOX Say?" http://www.youtube.com/watch?v=jofNR_WkoCE
"Worst Twerk Fail EVER - Girl Catches Fire" http://www.youtube.com/watch?v=HSJMoH7tnvw
Photo courtesy of NBC
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Sleep Paralysis Center - Cape Coral, FLWebMD Physician DirectoryCape Coral, FloridaSleep ParalysisSleep paralysis introductionHave you ever felt like you were awake but unable to move? You might have even felt afraid but could not call for help? This condition is called sleep paralysis. Sleep paralysis may leave you feeling frighten... Other Related Sleep Paralysis ArticlesEmergency Contact for Cape Coral
Nearby Cape Coral Hospitals *Cape Coral Hospital Lee Memorial Health Systems Gulf Coast Medical Center Health Park Medical Center Lehigh Regional Medical Center Riverside Behavioral Center Charlotte Regional Medical Ctr Faucet Memorial Hospital Peace River Regional Med Ctr NCH North Naples Hospital Physicians Regional Medical Cen Englewood Community Hospital NCH Downtown Naples Hospital *Provider Directory Terms of Use: The WebMD 'Provider Directory' is provided by WebMD for use by the general public as a quick reference of information about Providers. The Provider Directory is not intended as a tool for verifying the credentials, qualifications, or abilities of any Provider contained therein. Inclusion in the Provider Directory does not imply recommendation or endorsement nor does omission in the Provider Directory imply WebMD disapproval. |