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Capital, The (Newspaper) - June 17, 1986, Annapolis, Maryland f x Bullets to acquire 76ers' Malone. SEEPAGE 19 Tomorrow's Pleasant For see page i. JUNE GOOD PONT FORGET THE IRISH group Celtic Thunder will present a free concert from 7 to 9 tonight at City Dock. AREA NAACP LEADERS have asked the county to get its pension funds out of South Africa. Page 28. CRAFTS COLONIAL ARTISANS for Annapolis will hold their 8th Annual Summer Arts and Crafts Fair. Page 24. ENTERTAINMENT YOUNGSTERS WILL travel of this when they enter the Discovery Tent at the Annapolis Arts Festival. Page 23. DR. QOTT LOUD MUSIC causes ing damage. Page 29. STATE ATTORNEY GENERAL Ste- pnen Sachs and Baltimore Mayor WlQlam Donald Setae- fer take stands for stronger gun control SOUTH AFRICAN govern- meat reports 11 blacks kUltd during Ptgt i. THE WIDOW of the Chil- Itatir pilot says NASA used 'terrible' judgment. Page SPORTS ROOKIE PITCHER helps Tl- gers get by Pagt 18. PEOPLE His father's face is known the world but being the president's son apparently does not give Ron Reagan Ic a r t e blanche or ready recog- Inition. Young in soon could be mil- of _____ you know in a commercial for the American Express credit card. a typical 'Do you know me' commercial. You know the name but can't place the said Jerry C. executive vice-president for American Express. The which was complet- ed last must be ap- proved by American Express executives before it said Welsh we see the film ind judge its we don't know if it'll make on the be said Welsh would oot say bow much Reagan was paid for his appearance Tor a look at other people in the news today see ptge 3 LOTTERY Numbers drawn yesterday Three-digit 712 Pick 4 INDEX 4 lections. M pages Business Calendar Classified Ads Conies columns iBterutanttot 11-16 28 31 -M 27 tt I 24-ZS 25 at last AAGH to branch out from care Last la a aeries. By SCOTT LAUTENSCHLAGER Staff Writer In its first major venture outside health Anne Arundel General Hospital is taking the initial step toward developing 30 acres of prime real estate in Parole. Hospital officials hope that income derived from the property will elimi- nate the future need for major fund such as the W million cam- paign currently under The hospital has received propos- als from about 10 developers for the which could involve con- struction of retail and office said Robert a member of the AAGH building com- mittee. While it is too early to put a pricetig on the going be a lot of DeStefano The project may involve the of up to 20 buildings in oark-like he said. very Important of said who his living is a going to hive decided mpsct on how people think of Anne Hospital officials hope to pick a Developer by this said spokes- woman Lisa But construction will not begin until 1090 or later because the hospi- tal is committed to waiting until a major new highway interchange is completed in she The on the south side of Jennifer Road near the Annapolis is part of a 100-acre parcel bought by the hospital in AAGH is raising the 16 million for health care facilities to be built on the other on Page Hospitals compete for Park By SCOTT LAUTEN8CHLAGER Staff Writer North Arundel Hospital will build a S3 million medical com- plex in Several expanding medical care options for resi- dents. The facility will house a walk- in clinic ind physicians' said James North Aruo- del associate director. expected to start in eight or nine wlU take about a he North Arundel joins Anne Arun- del General Hospital in compet- ing the blossoming market created by popoUtioa growth In Several AAGH is search- ing toe community for i location for iu own wilk-iu clinic. The known 11 ire intended to treat non Ufa-threatening injuries and Illnesses that require immediate Urgi centers generally are not designed to provide the continu- ing care ordinarily provided by a family The new which will be to squire will be built on a S-acre site on the west side of Ritchie just north of Robinson Road. The project is a joint venture on Pafe Col. Black on board sought by NAACP By PETER WEST Staff Writer Demanding a minority voice on the county school a civil rights group today petitioned Gov. Harry R. Hughes to appoint a black nominee to the eight-member body. Jean president of the coun- ty chapter of the presented a petition this morning asking Hughes to appoint Joseph S. Belt III to the seat now held by Patricia Huecker. a U-year-old Gambrills resi- is a property rehabilitation specialist under contract to the coun- ty the board is composed of white members with the exception of Michael the student rep- resentative whose term expires this summer folks cannot represent Mrs Creek said. white person cannot relate to the black community as a black person can An all-white board breaks a 30- year tradition of minority represen- tation in the Mrs. Creek said. She said Wiggins' appointment doesn't balance an otherwise board because Wiggins rep- M Page CoL Patrons protest closing By DEBRA VIADERO Writer When the first picket U0e went up this morning to protest the closing of the Eastport Safeway store. 75-year-old He leo Motfett vowed to be oo it old enough to get out said the snow-haired Mrs. Moffett is among seven Eastport most them senior wfao signed up to picket Safeway stores to the Eastport Shopping Center and in nearby from t to 10 a m More protesters plan to keep up the moniatg vigil through the week The picketing is part of s campaign organised over the weekeod by Aider mat Brad to keep Safeway Stores lac eleetaf the Etstport store or MW grocer from refitting ft. to to brtag the harsh glare of ptfhtte alasajUuii oo Imspiaelbli sctaosC' Mid D- Eastport elderly picket Safeivay a candidate for County called meeting night of nearly 100 unhappy a and two city at the Eastport United Metbedist Church near the Safeway The half-hour meeting was punctuated by sharp attacks on Safewaj the na tioe's largest grecer Eartport store is the oldest of six ran by the company te i Arundel County yonr store has had higher asd Boom setecttofi than Magnder's and Grsvl's stores nearby successor will fted thoiutods aal themadi of costoeers watttec to shop st a quisty David- a tkat read. Puts Profits First and People He read from a letter to from Mayor Dennis Callahan fellow Alder man Alfred A Hopkins D w ard 6 and himself Safeway officials an nounced that the Eastport store will closf- on July It becauae it is losing nooey. The store Is popular with neighbors who wilk there to shop If another grocer does not replace tt those custom some of whom have DO have DO where to shop within easy walking disUDce Most of the shoppers who cane last ftiffht were elderly womea from Water- gate Village apartments behind the store. Aboot M percent of the approxi- matt i.m resideots ere sea- ler ctilsssM. the sflsttstfer said Thert were reports this week of Bteg to the naoager with tears M. Cei t Hi UNI KOTFfTT
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In the 1960s a box of marriage certificates created between 1822 and 1876 was found at the Milwaukee County Courthouse. The certificates and accompanying documents were filmed in 1966. The…
December 8, 1980 is a tragic day in rock music history. 34 years after John Lennon's death, his influence is as strong as ever.
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iM TOP NOTCH PUNKiSH HOOD ROCK iCED DOWN REAL CRiSP AND NEAT ALL THE WAY TO THE T...i GETS DOWN iM C.Y.S. ((CRAZY YOUNG 'N' SCANDALIS)) i GO AND SO DOES ALL MA SOLiDZ.i DONT MESS WiT FAKE BUSTAS WHO R STAiGHT SUCKAS NOR MESSY FEMALES.DA BOYS THAT B ON MY LiNE BUT NOT ON MA GAMEPLAN i TELL'EM BOY STO
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Hi I am a single woman, born and raised in SF. Looking for someone with an equally busy lifestyle, but wants room for love as well. When I'm not working, I love to hang out at home with friends, have some wine and make everyone dinner. Let me know if you're in the Bay Area, and maybe we can meet up.
i can't work a cash register for the life of me... i'm kind of cynical. i'm bright... VERY bright, obsessed with coldplay, go to uc berkeley. love to party. my favorite show is chip & dale rescue rangers. i have an insane metabolism. my friend put me up to this. let's see if you're cuter than my cat
I am currently attending an art school studing interior design, work as a waitress,have my own apt.So I get pretty busy sometimes.I like billiards,darts, sports,camping, dining, going out for drinks w/ friends. I have a broad range of interests, you will have to ask if you are interested in knowing.
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Starting at the U of Pittsburgh this fall. I love theater, playing the trumpet, playing/watching soccer, Tae Kwon Do, and generally having a good time with friends. I am an intellectual, but also appreciate the physical, sensual sides of life. This pic is of me at my Senior Banquet, having fun!
I am cute...optimistic..luv to have fun with my friends..luv to go to movies, cruising, shopping, and on road trips. Life is like an ice-cream...enjoy it before it melts :-) I treasure true love and I treasure the best memories that I experience...it could be with you ;-) Well Lets find out then.
I'm a mexican american, daughter, sister, and a best friend... I'm an all round fun and friendly girl...I enjoy out door sports and camping... I love to try out different things and i'm always willing to try. biggest turn on is confindance Got game? use it! I hang around postive people. Drama Free!
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This film came out of the processing tank showing signs of low level fogging, which I can't explain. Three rolls were processed at the same time, same conditions, and only one had fogging. However, it did result in some interesting effects.
This photo was shot on film. Taken by troch with a Holga 120 N loaded with Lomography Lady Grey B&W 400 (120) film (available in our Online Shop) in Sunshine Coast, BC, Canada. These tags describe this photo: b&w, black and white, fogged, square, 120, medium format, diy,, rodinal, stand, process", scenic, nature, canada, and holga. Date: 2012-04-04. This photo can also be found in the album Lady Grey II.Please login to get more out of this site
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Tonight's host quest will be available by accessing the "Q" button on the toolbar after you enter a player area. It will be listed as the last quest and is available only from 5:30-8:30 PST. The Prizes are green score board and green penny press.
As with all VMK quests, it is recommended that you try the quest on your own first, and come to the spoilers only if you need assistance, as a last resort.
Below is the new quest spoiler format for MiceChat. Changes may occur, but please be considerate and enjoy your quest.
* This Host Quest has been played before. *
1.SpoilerNautilus Grotto
2.SpoilerFind Mickey; Space Moutain Quest Deck
3.SpoilerPirates Treasure Room
5.SpoilerBear Rug
6.SpoilerFind jewel; Fantasyland in the sky
7.SpoilerBuy a Goofy hat (unless it is in your inventory)
8.SpoilerMain Street Music Game Lobby
9.SpoilerFind atom; VMK Central
10.SpoilerGo to dungeon
11.SpoilerSay inner space shop
12.Spoilerfind horseshoe in Ned's
14.Spoilerfind golden Mickey in Haunted Mansion Ballroom
15.SpoilerGive thumbs up
16.SpoilerGo to Castle Forecourt
18.SpoilerGo to Tomorrowland Hub


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Charles, I'm so sorry to hear of the death of Joyce. She was a wonderful researcher and I can't tell you how many times I've used her and Linnie's book. We corresponded for quite a long time and there wasn't much she missed regarding the Alspaugh/Alspach family. I'm sorry now I didn't write and tell her how remarkable their research is. I tried to find her email but it was nowhere to be found and I should have dropped her a note. I don't know of any reprint either, but there certainly should be. It's kind of you to offer to do look ups in the book. The book is scarcer than hen's teeth so your offer is doubly useful. Arlene Notify Administrator about this message?
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Today's News
Mega Buzz: Get the Scoop on Criminal Minds' Young Gideon
And how is Young Rossi different? Joe Mantegna dishes on Wednesday's big flashback
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Nick Jonas Joins Ryan Murphy's Upcoming Scream Queens
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See the alleged errors they made
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4.5 Feel Good Film KurtisMovieLover | 30/06/2010 | See all KurtisMovieLover's reviews (125) I like this better than the original which is hard for me too say, but i do
4.5 A Feel Good Christmas Movie for the Family. Rambo456 | 25/12/2009 | See all Rambo456's reviews (1259) A Feel Good Christmas Movie for the Family.Fantastic movie for all the family to enjoy anytime of the year.The story is very sweet and acted with class.Richard Attenborogh is perfect in his role and so is the little girl.
4.5 Excellent Christmas Film olismummy | 21/10/2009 | See all olismummy's reviews (18) Brings back all the memories of christmas as a child, Love it!!!
4.5 fantastic awesomecity | 06/11/2008 | See all awesomecity's reviews (987) A superb christams movie and a tear jerker, i love this film and watch it every christmas eve.
4.5 LOVE CHRISTMAS, LOVE THIS FILM!! AshleySmith29 | 03/11/2008 | See all AshleySmith29's reviews (134) Who doesnt love christmas?Who doesnt love this film?I never saw the original and never plan on it as this is perhaps the perfect christmas film, you simply cannot help but be filled with christmas cheer after watching this.Just thinking about it and re-watching it in my mind fills me with memories of xmas joy!!
4.5 Profoundly Moving MondeoST | 09/12/2007 | See all MondeoST's reviews (8) This film offers outstanding performances from Richard Attenborough and Dylan McDermott, alongside Elizabeth Perkins and Mara Wilson. The film based on Santa Clause is magical and poignant, creating a true loving family film. The film captures so many fantastic qualities that people love to see in a film, that it was a pleasure and privilege to watch. The movie is enduring and eye catching making it a superb Christmas movie. I would recommend anyone to purchase this film, as it contains and features what Christmas is all about.
4.5 Lovely fankyskag | 29/11/2007 | See all fankyskag's reviews (19) A very heart-warming film to get you into the spirit of Christmas. Richard Attenborough portrays Mr. Claus very well and a young Mara Wilson makes the film as sweet as it can be.
4.5 Brilliant Christmas Film Nicola8776 | 13/11/2007 | See all Nicola8776's reviews (4) This is such a lovely film that gets you right into the spirit of christmas, Kids loved it!
4.5 Christmas has arrived! katmomo | 06/11/2007 | See all katmomo's reviews (2) This is one of my all time favourites. Christmas hasn't arrived until i have watched this usually on christmas eve. It brings back the childlike wonder of christmas and once again makes you believe in the hope and spirit of christmas not to mention santa claus. This is a must for anyone who loves christmas!


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Women's Boots On Clearance @ kmart.com boots as low as $4.99 many for $8.99 - FS w/order of $25+
Last edited by immad; 10-08-2012 at 08:02 PM..
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I believe though a couple of these might work out for certain "costumes" - like this one for $8.99? A slightly different take on Dorothy, perhaps?
http://www.kmart.com/yoki-women-s...ockType=G1 Klaatu: I'm impatient with stupidity. My people have learned to live without it.
Mr. Harley: I'm afraid my people haven't. I'm very sorry. I wish it were otherwise. Facts burns! Facts burns us! Numbers freezes! Nasty liberals twisted it. Take it off us! - deliberate misquote while arguing factoids about healthcare cost inflation. You may be born stupid, but ignorance is a choice - personal observation. Who need drugs when you can have fatigue toxins and caffeine. - Keith D., law enforcement |
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Results 1 to 2 of 2
- Join Date
- Oct 2004
- Posts
- 641
- Location
- New Brunswick, Canada
- Tractor
- Kubota B7800, Case 450
A Different Firewood Processor
Here is a modern (1890's) woodcutter located at King's Landing Historical Settlement, NB, Canada. The log sets on a carriage that is advanced by a ratchet mechanism on the spiked drum. The pulley ratio from the horse power to the saw crank is about 4:1, so the saw can move quite fast. However, it seemed like forever to cut the log, due in part to an unco-operative horse and also possibly due to a dull saw. I think two good men on a crosscut saw could easily beat it (but maybe not for long). I remember my father bucking firewood by hand with a buck saw (also known around here as a pulp saw). I'm glad I have my power toys to do all that.
Kubota B7800, LA402 FEL, Homemade cab, 60" bushcutter, 74" rear snowblower.
Kubota RTV500.
Case 450 c/w 6-way dozer.
- Join Date
- Feb 2011
- Posts
- 7,683
- Location
- Frederick County, VA
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- Kubota BX2360 & L4240 HSTC
Re: A Different Firewood Processor
That's cool, I did not know that firewood processors had been around that long.
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At Elberton, Franchot Brown had a team-high 22 points and nine rebounds to lead Washington-Wilkes (2-0).
Tyrekus Bowman added 12 points and 15 rebounds, and Jamal Binns had 11 points, six assists and six steals.
Lajarvis Goss led Elbert County with 17 points.
Washington-Wilkes host Taliaferro County on Friday at 7:30 p.m.
Published in the Athens Banner-Herald on Thursday, December 12, 2002.
Athens, GA • Athens Banner-Herald ©2015. All Rights Reserved.


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Book your room at Samasati Nature Retreat
Max Occupancy: 3 guests (up to 2 children, 1 infant)Classic Room, 1 Double or 2 Single Beds
Max Occupancy: 2 guests (up to 1 child, 1 infant)Romantic hotel with full-service spa and restaurant
Situated in a national park, this spa hotel is 3.8 mi (6.1 km) from Black Sand Beach and within 12 mi (20 km) of Cahuita National Park and Grand Beach. Refugio Nacional de Vida Silvestre Gandoca-Manzanillo is 12.5 mi (20.2 km) away.
Hotel Features
Along with a full-service spa, this smoke-free hotel has a restaurant and a bar/lounge. Free breakfast, free self parking, and a free beach shuttle are also provided. Other amenities include a spa tub, a conference center, and coffee/tea in the lobby.
Room Amenities
All rooms are individually decorated and offer balconies and ceiling fans.
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English author Beatrix Potter created several animal protagonists for her stories, but none is more famous than Peter Rabbit. Peter was the archetype for many fictional bunnies; like the later Bunnicula and Were-Rabbit, his predilection for devouring others' vegetables frequently got him into trouble.
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Published 03/13/2014 12:00 AM
Updated June 23. 2014 1:10PM
State program helping Pawcatuck-based cabinetmaker build up his business
State gives grant to lawyers suing New London
State program assists its 1,000th business
Malloy's program creates 1,000 jobs, but critics say that's not enough
Small business aid program needs scrutiny
Burrito shop owner who got $150,000 in state aid had $728,000 in debt
Mystic burrito shop that got $150,000 in state aid closes
Winter storm warning for most of Connecticut; 5 to 10 inches of snow predicted along shore
Downtown New London comes alive with Hygienic Art XXXVI show
In Westerly, family means business
More than 250 firefighters battle seven-alarm warehouse blaze in Brooklyn
UPDATED: Whitney Houston's daughter found unresponsive in tub Saturday
Police save beaten puppy buried alive in snowbank; owner arrested
Norwich looks for real estate help
Dazzling Big Bang 'discovery' goes poof
VIDEO: Brooklyn warehouse fire raised to 7 alarms as more than 250 firefighters battle flames, smoke
First-time mothers celebrate with their babies after completing Nurse-Family Partnership program
Blizzard time lapse: drifting snow in Waterford
Blizzard time lapse: downtown New London
Highlights: New London 72, Ledyard 70
UConn scholarship a dream come true for Cespedes
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text: Enterprise Directory 3/29/11 4:14 PM Tuesday, March 29, 2011 Enterprise Directory: Policies Table of Contents Purpose of this Policy Scope Enterprise Directory Schema & Data Visibility Data Update Communication Root Backup & Disaster Recovery Solution Authentication Enterprise Directory Administrator Responsibilities AuthDN Owner Responsibilities Joining/Leaving/Change of Role(s) within Enterprise Directory Compliance Access Request Process Purpose of this policy The purpose of this policy is to provide requirements and specific recommendations for the successful operation of the UMD Enterprise Directory. Top Scope This policy applies to all computer support personnel making use of UMD's Enterprise Directory. It covers information regarding the design of the Enterprise Directory, responsibilities for computer support personnel and compliance guidelines. Top Document Information Tree (DIT) The Enterprise Directory contains a single DIT which is subdivided into six branches: people (active users) application (application specific sub-branches) entity (non-person objects such as listservs) extended-service (former students) guest (wireless access) ldap (internal service objects) People objects are created for all employees, students and affiliates (as defined in PHR) of UMCP as well as employees of UMBI, UMCES, UMES, and USMO. The servers and services (hardware/software) which run and support the Enterprise Directory are monitored by OIT http://www.oit.umd.edu/middleware/directory/docs/policy.html Page 1 of 4 Enterprise Directory 3/29/11 4:14 PM administrators on a 24x7 basis. Top Schema & Data Visibility The schema is a definition of all object classes and their attributes contained within the directory. An annotated attribute schema can be found at www.oit.umd.edu/middleware/directory/internals/schema.html. The schema may be dynamically extended through the approval of OIT and the Directory administrators. Schema testing in a staged environment will occur before and during the request for modifications. Changes will only be implemented after two weeks of successful testing with no major issues identified. Data visibility is controlled by issuing applications binding credentials (dn & password) referred to as an "authDN". This authDN will be associated with various Access Control Lists (ACLs) which control the objects and the attributes of those objects that can be accessed. All authenticated binds must be done over a secure connection (SSL/TLS). Top Data Update The Enterprise Directory is updated daily with data drawn from PHR and SIS representing people who have active relationships with UMCP, UMBI, UMCES, UMES, or USMO. Students are added to the Enterprise Directory when they are "admitted with letter sent" and remain active until the next occurrence of the last semester for which they were registered. Employees, in general, will remain active for thirty days past the separation date of their last appointment. Persons needing accounts who are neither students nor employees must be entered into PHR as an affiliate by their sponsoring department. Top Communication Communication will occur via the appropriate mailing lists. Top Root Backup & Disaster Recovery Solution The Enterprise Directory is currently on a nightly full backup schedule with hourly incremental database snapshots. Top Authentication Application needing to merely authenticate users should consider using the UM Single-Signon Service (CAS). EIS also provides the UMCP Shibboleth Identity Provider (IdP) and is a member of the InCommon federation. Top Enterprise Directory Administrator Responsibilities: The Enterprise Directory Infrastructure is composed of many different computing, administrative and consulting services. This section provides a brief description of these services and specific contact information for each. OIT installs and maintains the servers and support machines which run Enterprise Directory. Staff within the Enterprise Internet Services (EIS) group configure and maintain the Enterprise Directory servers for the campus Enterprise Directory. Urgent problems related to directory servers or LDAP services should be reported by calling the OIT Helpdesk Desk at 301.405.1500. For general discussion, this group can be contacted via e-mail at directory- http://www.oit.umd.edu/middleware/directory/docs/policy.html Page 2 of 4 Enterprise Directory 3/29/11 4:14 PM email@example.com. The responsibilities of the Enterprise Directory Administrators are: Configure and maintain the Enterprise Directory servers. Manage the flow of information to and from the Enterprise Directory. EIS also manages the replication of directory information within the Enterprise Directory, and makes any enterprise level changes to the directory, such as schema modifications. Diagnose all reported directory problems. Provide backups for disaster recovery purposes Responsible for maintaining security of the directory. Maintain test and development environments for internal and campus testing. OIT-TSS provides a test environment that mimics the production environment so that services can be tested and questions answered before introducing them into the production environment. Any department can participate in the test environment in a manner appropriate to the way that they will participate in the production environment. Testing may also be required before new services or applications are introduced into the production forest. Communicate all enterprise-wide changes to the directory via listserv (email@example.com) and other technical team reflectors. Support staff required to have working knowledge of the Enterprise Directory. Maintain a well documented infrastructure diagram of their respective environments, including descriptions of all services provided by directory servers. Maintain the appropriate level of security and patch revisions on the directory servers as specified by OIT-TSS. All changes to the directory will be approved by OIT's Change Management Committee Directory servers will be monitor 24x7 to ensure high availability. Must have directory servers strategically located in multiple locations to provide redundancy in case of a disaster. Servers must be physically secured. Servers should have a current hardware agreement with vendor. On-call staff will monitor and resolve all issues pertaining to the servers Must have onsite support to resolve issues during business hours Must have disaster recovery & backup/recovery solution for the Enterprise Directory. Communicate and coordinate all scheduled and unscheduled outages or major upgrades to authDN owners/administrators. Must coordinate any maintenance that may affect the directory (i.e. replication, adding services, etc.) Follow all OU administrator responsibilities below. Top AuthDN Owner Responsibilities Agree to the policies and guidelines for authDN owners. Work closely with the EIS directory support team. Ensure security and privacy of all data accessed. Apply for a new authDN for every application server which will utilize Enterprise Directory for authentication. Top Leaving\Change of Role (s) within Enterprise Directory If at any time a department decides that it no long requires an authDN, the department head or authDN owner will need to provide a written statement (email or memo) to the director administrators indicating this. If an authDN owner changes (resignation, new job responsibilities, etc.), then department head must notify the directory administrators immediately of the new owner. Top Compliance All Colleges/Departments/Units heads and designated administrators will have to sign a Memorandum of Understanding and the Enterprise Directory Policy in order to make use of the campus Enterprise Directory. It is the responsibility of each authDN owner/administrator to comply with the above specifications and guidelines. Department heads will be notified upon repeated violations by an authDN owner/administrator and explained the impact it has on the entire http://www.oit.umd.edu/middleware/directory/docs/policy.html Page 3 of 4 Enterprise Directory 3/29/11 4:14 PM directory infrastructure. In cases of gross negligence or refusal to adhere to the agreed policy, OIT will immediately suspend the authDN credentials. Top Access Request Process Applications wishing greater access than anonymous binds to the Directory can request a Directory authDN. To initiate the process, requestors must complete the Directory Data Request Questionnaire and e-mail the completed questionnaire to: email@example.com When the Directory administration staff receives the completed questionnaire they will review and work with the requestor for clarification if necessary. Then an authDN data access request will be sent via email to the Unit Head and campus data stewards for approvals of the specific user populations and data attributes for the application. Once all approvals are received, OIT will send the requestor an e-mail with a customized Memorandum of Understanding (MOU) for their application containing approved population and data attributes. The requestor is then responsible for printing and signing the MOU, obtaining the Unit Head's signature and returning the MOU back to OIT for review. After OIT receives the signed MOU, the authDN is created and the requestor notified via email with their new authDN information. Top View the Memorandum of Understanding (MOU) (html/pdf) View the Enterprise Directory Best Practices (html/pdf) Return to index http://www.oit.umd.edu/middleware/directory/docs/policy.html Page 4 of 4


text:
US 6413638 B1 Abstract Finely divided particles can be provided in a simple manner and with good adhesion with a coating which is a polyfunctional organosilane and/or a hydrolysis product thereof, and/or a reaction product thereof with an organosilane which contains a hetero atom and/or with an alkoxide.
Claims(13) 1. Coated particles comprising particles (A) coated with a material (B), wherein material (B) is a monomeric, polyfunctional organosilane containing at least two silicon atoms, each with one to three hydrolysable and/or condensation cross-linking groups, and the silicon atoms are each bonded by an Si�C bond to a structural unit which links the silicon atoms, and/or a hydrolysis product of said monomeric, polyfunctional organosilane and/or a reaction product of said monomeric, polyfunctional organosilane, with an organosilane containing a hetero atom and/or an alkoxide.
2. The coated particles according to
3. The coated particles according to
4. The coated particles according to
5. The coated particles according to
6. The coated particles according to
m represents 1 to 10,
n represents 0 to 2,
o represents 0 to 2,
R2 represents H, alkyl or aryl, and
R3 and R4 are identical or different and represent alkyl or aryl.
7. The coated particles according to
8. The coated particles according to
M represents Li, Mg, Sr, Ba, Mn, Fe(II), Co, Ni, Cu, Zn or Cd, and the molar ratio of x to z is between 0 and 1.
9. The coated particles according to
M1 represents Si, Sn, Ti, Zr, B or Al,
R1 represents alkyl or aryl, and
y represents 4 in the case where M1is Si, Sn, Ti and Zr, and represents 3 in the case where M1 is B or Al.
10. The coated particles according to
11. The coated inorganic particles according to
i represents 2 to 4,
p represents 1 to 4,
R5 represents alkyl or aryl,
R6 represents hydrogen, alkyl or aryl when a is 1 and alkyl or aryl when a is 2 or 3,
R7 represents alkyl or aryl,
a represents 1 to 3;
m represents 3 to 6,
q represents 2 to 10,
R8 represents a C1-C6 alkyl or a C6-C14 aryl,
R9 represents hydrogen, alkyl or aryl when b is 1, or alkyl or aryl when b is 2 or 3,
R10 represents alkyl or aryl,
r represents 1 to 10,
c represents 1 to 3,
k represents 2 to 4,
R11 represents alkyl or aryl,
R12 represents H, alkyl or aryl when c is 1, and alkyl or aryl when c is 2 or 3,
R13 represents alkyl or aryl, and
R14 represents alkyl or aryl.
12. The coated particles according to
i is 4,
p is 2to 4,
R7 is methyl,
m is 3,
q is 2,
R8 is methyl or ethyl,
R10 is methyl,
r is 2 to 4,
k is 4,
R11 is methyl,
R12 is H, CH3, C2H5 or C3H7, when c is 1; and CH3, C2H5 or C3H7, when c is 2 or 3, and
R13 is methyl.
13. The coated inorganic particles according to
Description This invention relates to coated particles, particularly particles with an inorganic content, preferably purely inorganic particles and most preferably coated magnetic particles, which are used as carrier particles in electrostatographic developers for the electrostatographic production of images. There is a series of electrostatographic printing methods which are known, e.g. direct electrostatic printing, in which toner is deposited by means of an electronically addressable print head on to a receiver material which does not comprise a latent electrostatic image. In another form of electrostatic printing, toner formers are produced on an image-producing element in the form of a rotating drum which contains an electrostatic layer which consists of a multiplicity of controllable electrodes in and under a dielectric layer. An electrical voltage is generated in the controllable electrodes, according to the image, and attracts toner particles from a toner source. In addition, it is known that in electrographic printing and in electrophotographic copying a latent electrostatic image can be produced, either of an original to be copied or for digitised data which describe an image which is accessible electronically. In electrophotography, a latent electrostatic image is produced by the steps of a) charging a photoconductive element congruently, and b) discharging according to the image by an exposure which is modulated image by image. In electrographics, a latent electrostatic image is produced by the deposition of electrically charged particles corresponding to the image, e.g. on a dielectric substrate by an electron beam or by ionised gas. The latent image formers obtained are developed, namely they are converted to visible images by depositing substances on them which selectively absorb light; these substances are called toners and usually carry a triboelectric charge. Two techniques are used for the toner development of latent electrostatic images: dry powder and liquid dispersion development, with dry powder development being the more commonly used. Dry powder development can be carried out in various ways. One method is the single component method, in which the toner itself is charged by friction, transported by a roller and deposited on the latent image. The quality is limited, particularly if coloured prints are to be produced. Another method utilises liquid development, in which colloidally charged toner particles are applied to the photoconductor in a liquid insulating medium, e.g. a hydrocarbon. One disadvantage of this method is the emission of volatilised organic substances, particularly when high printing speeds are employed. A third method utilises a two-component developer. In this case, large-grained carrier particles which can be attracted magnetically form a magnetic brush on the surface of the developer roll, by forming the magnetic hairs of the brush. Triboelectrically charged toner particles are present on the surface of the carrier particles. These are stripped from the carrier particles according to the electrical charge of the latent electrostatic image, whereby the toner image is produced. In this method, the carrier particles are reused repeatedly; their mechanical stability is therefore particularly important. Non-magnetic electrophotographic developers comprising two components can also be used as an alternative to what is termed the magnetic brush. In one particular embodiment, the developer consists of small glass spheres, which arc optionally coated, and of toner particles. The developer is caused to deposit on the element carrying the latent image and in this manner causes development, as is described in BE 828 210. The carrier particles are also reused in this case. In the case of surface-coated carrier particles, the stability of the surface coating is particularly important. Insufficient mechanical stability results in losses of quality of the printed image, and the developer has to be replaced, which causes unnecessary stoppages and cost. A material with anti-adhesion properties is preferred for coating the carrier particles, in order to prevent the toner from sticking to the carrier surface. In most cases, however, this leads to a decrease in the adhesion of the coating on the carrier, which results in a shortening of the service life, e.g. when silicone resins are used as carrier coating media. Carriers are known from U.S. Pat. No. 4,977,054 which consist of a magnetic powder and a silicone resin coating. The silicone resin used consists of D and T structural units (in D units the silicon atom is linked to further silicon atoms via 2 oxygen atoms, in T units it is linked via 3 oxygen atoms), wherein other functional organosilanes, such as di- and trialkoxy-functional organosilanes and/or di- and trialkoxy-functional organosilanes which contain nitrogen, can also be added in addition. Deposition is effected, as can be inferred from the examples, in a fluidised bed reactor; thereafter, the coatings are also cured at 190� C. to 296� C. However, the aforementioned coatings comprising (polymeric) silicone resins have the disadvantage that high temperatures (190 to 296� C.) are necessary for complete curing. Furthermore, many silicone resin coatings in fact exhibit anti-adhesion properties, and inevitably exhibit poor bonding to the substrate. According to U.S. Pat. No. 4,4977,054, di- and trialkoxy-functional organosilanes, for example, therefore have to be added to these silicone resins in order to improve their adhesion. The object of the present invention was therefore to provide coated particles, particularly particles having a content of inorganic materials, and particularly carrier particles for electrostatographic processes, wherein the particles have a magnetic core and a coating on the core which a) is non-sticky, so that free-flowing particles which are predominantly free from agglomerates are obtained, b) does not soften, even at elevated temperature, c) prevents permanent adhesion and adhesive bonding of colour-imparting toners, d) has a high resistance to abrasion, e) adheres well to the particles, and f) in the case of carrier particles for electrophotography has a good charging capacity, so that sufficient toner is taken up and can be released again. The object of the present invention was also to provide a process for coating particles, particularly particles having a content of inorganic material, and particularly magnetic particles, which does not have the aforementioned disadvantages and which is characterised, for example, in that the deposition of the coating is effected in apparatuses which are as simple as possible by a simple process, and curing of the coating is effected at low temperatures. Surprisingly, it has now been found that coated particles which do not have the aforementioned disadvantages are obtained, particularly coated particles containing inorganic material, if the coating is produced from monomeric polyfunctional organo-silanes and/or hydrolysis products thereof and/or reaction products thereof with organo-silanes containing hetero atoms and/or alkoxides. The present invention therefore relates to particles (A) which are coated with a material (B), wherein particles (A) preferably contain inorganic material and are most preferably magnetic carrier particles for electrostatographic processes, and wherein material (B) is a monomeric, polyfunctional organosilane and/or a hydrolysis product thereof and/or a reaction product thereof with an organosilane containing a hetero atom and/or an alkoxide. Organosilanes which contain hetero atoms in the sense of this invention consist of at least one silicon atom with hydrolysable and/or condensation crosslinking groups such as �SiOR, wherein R represents alkyl, cycloalkyl or aryl in particular, preferably alkyl, or consist of SiOH and at least one organic radical which contains a hetero atom and which is bonded via a carbon atom, which may be an alkyl, cycloalkyl or aryl radical. The hetero atoms of the organosilanes which contain hetero atoms are preferably N, P, S, F, Cl, Br, O, Band Al. The preferred hetero atoms are N and F, wherein nitrogen atoms are particularly preferred. The preferred organosilanes which contain nitrogen correspond to formula (I)
wherein m represents 1 to 10, preferably 2 or 3, n represents 0 to 2, preferably 2, o represents 0 to 2, preferably 0, R2 represents H, alkyl or aryl, preferably H, and R3, R4 represent alkyl or aryl, preferably CH3 or C2H5. The preferred alkoxides correspond to formula (II)
wherein M1 represents Si, Sn, Ti, Zr, B or Al, R1 represents alkyl or aryl, preferably a C1-C4 alkyl, and y represents 4 in the case of Si, Sn, Ti and Zr, and represents 3 in the case of B or Al. Polyfunctional organosilanes in the sense of the invention are characterised in that they contain at least 2, preferably at least 3 silicon atoms, each with 1 to 3 hydrolysable and/or condensation crosslinking groups, particularly alkoxy, acyloxy or hydroxy groups, and the silicon atoms are each bonded by a Si�C bond to a structural unit linked to the silicon atoms. In the simplest case, examples of linked structural units which are suitable in the sense of the invention include linear or branched C1 to C10 alkylene chains, C5 to C10 cycloalkylene radicals, aromatic radicals, such as phenyl, naphthyl or biphenyl for example, and combinations of aromatic and aliphatic radicals also. The aliphatic and aromatic radicals may also contain hetero atoms, such as Si, N, O, S or F for example. In addition, siloxanes in chain, ring or cage form, such as silsesquioxanes, are also suitable as linked structural units. Examples of linking structural units are listed below, wherein X denotes Si atoms which have 1 to 3 hydrolysable and/or condensation crosslinking groups, and Y denotes corresponding Si atoms which are bonded via an alkylene chain to the linking structural unit; n represents a number from 1 to 10, and m represents a number from 1 to 6:
wherein R is an organic radical, e.g. alkyl, cycloalkyl, aryl or alkenyl. Examples of polyfunctional organosilanes include compounds of general formulae (IV), (V) and (VI): (R5)4−iSi[(CH2)pSi(OR6)a(R7)3−a]i (IV) wherein i represents 2 to 4, preferably 4, p represents 1 to 4, preferably 2 to 4, R5 represents alkyl or aryl, R6 represents hydrogen, alkyl or aryl when a is 1 and alkyl or aryl when a is 2 or 3, R7 represents alkyl or aryl, preferably methyl, and a represents 1 to 3; wherein m represents 3 to 6, preferably 3, q represents 2 to 10, preferably 2, b represents 1 to 3, R8 represents a C1-C6 alkyl or a C6-C14 aryl, preferably methyl or ethyl, R9 represents hydrogen, alkyl or aryl when b is 1, or alkyl or aryl when b is 2 or 3, and R10 represents alkyl or aryl, preferably methyl;
wherein r represents 1 to 10, preferably 2 to 4, c represents 1 to 3, k represents 2 to 4, preferably 4, R11 represents alkyl or aryl, preferably methyl, R12 represents H, alkyl or aryl, preferably H, CH3, C2H5 or C3H7, when c is 1; and alkyl or aryl, preferably CH3, C2H5 or C3H7, when c is 2 or 3, R13 represents alkyl or aryl, preferably methyl, and R14 represents alkyl or aryl. Examples of polyfunctional organosilanes include: (a-1) Si[(CH2)2Si(OH)(CH3)2]4, (a-2) H3C�Si[(CH2)2Si(OH)(CH3)2]3, (a-3) C6H5�Si[(CH2)2Si(OH)(CH3)2]3, (a-4) Si[(CH2)3Si(OH)(CH3)2]4, (a-5) cyclo-{OSiCH3[(CH2)2Si(OH3)(CH3)2]}4, (a-6) cyclo-{OSiCH3[(CH2)2Si(OCH3)(CH3)2]}4, (a-7) cyclo-{OSiCH3[(CH2)2Si(OCH3)2CH3]}4, (a-8) cyclo-{OSiCH3[(CH2)2Si(0C2H5)2CH3]}4, (a-9) cyclo-{OSiCH3[(CH2)2Si(OC2H5)3]}4. Examples of alkoxysilanes which contain nitrogen include: (b-1) H2N�(CH2)3Si(OCH3)3 (b-2) H2N�(CH2)3Si(OC2H5)3 (b-3) H2N�(CH2)2�HN�(CH2)3Si(OCH3)3 (b-4) H2N�(CH2)2�HN�(CH2)3Si(OCH3)2(CH3) (b-5) C6H5�HN�(CH2)3Si(OCH3)3 (b-6) C6H5�HN�(CH2)3Si(C2H5)3 (b-7) H2N�(CH2)2�HN�(CH2)2�HN�(CH2)3Si(OCH3)3 (b-8) H2N�(CH2)2�HN�(CH2)2�HN�(CH2)3Si(OC2H5)3. Examples of alkoxysilanes which contain fluorine include: (d-1) F3C�(CH2)2�SiR′3−x(OR)x (d-2) F3C�(CF2)7�(CH2)2�SiR′3−x(OR)x (d-3) (F3C)2CF�O�(CH2)3�SiR′3−x(OR)x (d-4) (3-F3C�C6H4)�SiR′3−x(OR)x (d-5) (3-F3C�C6H4)2Si(OR)2. wherein x is 1 to 3 and R and R′ are alkyl, cycloalkyl or aryl, preferably ethyl or methyl. Examples of alkoxides which can be used for the production of the reaction products according to the invention, e.g. in order to obtain an improvement in abrasion-resistance or in the tribological properties, include: (c-1) Si(OC2H5)4 (c-2) B(OC2H5)3 (c-3) Al(O�i�C3H7)3 (c-4) Zr(O�i�C31H7)4. In addition, the reaction products according to the invention can also contain finely divided metal oxides or metal oxide-hydroxides of the elements Si, Sn, In, Tl, Zr, B or Al, e.g. silica sols, which contain organic solvents in particular. The preferred primary particle size thereof falls within the range from 1 to 50 nm; they are hereinafter termed �nanoparticles�. Agents which induce conductivity, e.g. carbon and charge-regulating agents e.g. nigrosine, can also be added to the coating. Material B preferably contains 0.1 to 100% by weight of polyfunctional organosilane, 0 to 20% by weight of organosilane (I) which contains a hetero atom, 0 to 70% by weight of nanoparticles and 0 to 99.9% by weight of alkoxide (II). Material B most preferably contains 20 to 80% by weight of polyfunctional organosilane, 20 to 80% by weight of alkoxide (II), 0 to 10% by weight of organosilane (I) which contains a hetero atom, and 0 to 50% by weight of nanoparticles. Magnetic inorganic particles are preferred as the particles. The magnetic particles are preferably iron oxide pigments of formula (III)
wherein M is Li, Mg, Sr, Ba, Mn, Fe(II), Co, Ni, Cu, Zn or Cd, and the molar ratio of x to z is between 0 and 1, preferably between 0.3 and 1. It is also possible to use composite particles which consist of 20 to 85% by weight of magnetic microparticles and an organic or inorganic binder, e.g. an organic polymer or a ceramic material. Moreover, it is possible to use non-magnetic cores such as glass beads. Reaction products B) according to the invention are generally deposited on particles A) as a coating. The polyfunctional organosilanes can be deposited on particles A in solvent-free form or dissolved in a solvent, optionally in the presence of a catalyst. Coating B) is obtained after volatilisation of the solvent and curing at a suitable temperature. In one preferred embodiment, the polyfunctional organosilanes are first mixed, optionally in a solvent, with alkoxides and with organosilanes containing hetero atoms, for example, and are deposited on particles A, optionally in the presence of a catalyst, and cured. In order to increase the reactivity and to reduce the drag-out of low-boiling, readily volatile starting materials such as tetraethyl orthosilicate, it is particularly advantageous firstly to react the starting materials with water, optionally in the presence of a catalyst. Reactive, less volatile, oligomers and/or polymers are formed in the course of this procedure. After a defined reaction time, this coating solution is deposited by a suitable method, e.g. in a fluidised bed, on the materials which contain iron oxide, the volatile constituents are volatilised and the coating which is thus obtained is optionally subsequently cured thermally. Suitable catalysts include organic and inorganic acids or bases, e.g. HCO2H, CH3COOH, HCl, NH4OH and alkali metal hydroxides, as well as salts containing F such as NaF or NH4F. The added metal oxides themselves, such as Ti(OC2H5)4 and Ti(Oi�C3H7)4, may also have a catalytic effect. Metal soaps such as zinc octoate or dibutyltin laurate may also be used. Information on the hydrolysis and condensation of polyfunctional organosilanes, optionally in the presence of alkoxides, is to be found, for example, in DE-OS 196 03 242 and in WO 94/06897. For example, the polyfunctional organosilanes are mixed with the alkoxides, a solvent, water and a catalyst with stirring and are allowed to react for a defined period before films or, after complete reaction (gelling), even shaped bodies can be obtained from these solutions. The film-forming properties of reaction product (B) constitute a useable indication that the solutions are suitable for coating the particles. If a glass plate is coated, for example, a transparent, substantially fissure-free film which wets the entire area should be obtained after volatilisation of the volatile constituents. The tendency to form fissures increases with the layer thickness of the film, however. In one preferred embodiment of the process according to the invention, the alkoxysilanes which contain nitrogen are not added until the polyfunctional organosilanes and optionally the alkoxides have been reacted as described above and this preliminary condensate has been diluted with further solvent. As is known from the literature, silanes which contain nitrogen, such as H2N�(CH2)3Si(OMe)3, catalyse the hydrolysis and condensation of alkoxysilanes. This can result in the most reactive component, e.g. H2N�(CH2)3Si(OCH3)3, being rapidly hydrolysed and being condensed to form an insoluble solid. This can be prevented by adding the alkoxysilanes which contain nitrogen to the diluted coating solution. In order to obtain a homogeneous distribution of the coating solution on all the particles which contain iron oxide, it is advantageous to dilute the preliminary condensate further with additional solvent. Moreover, the further reaction of the polyfunctional organosilanes and alkoxides which are used proceeds considerably more slowly in dilute solutions, which results in improved stability of the coating solutions on storage. Examples of suitable solvents which can be used for the dilution of the preliminary condensate include alcohols such as methanol, ethanol, n-propanol, n-butanol, iso-propanol, sec-butanol or ethylene glycol, ketones such as acetone or methyl ethyl ketone, amides such as N-methylpyrrolidone, or even water. Alcohols, particularly iso-propanol, are preferred, due to their good miscibility with the preliminary condensate. Mixtures of different solvents may also be used. After the deposition of the coating solution, the solvents can be recovered, e.g. by condensation, and can be re-used in the process, optionally after purification. Curing of the coating is preferably effected at temperatures from 25 to 220� C., more preferably from 80 to 180� C., most preferably from 100 to 140� C. The amount of coating deposited with respect to the core is between 0.1 and 10% by weight, preferably between 0.5 and 5% by weight, and most preferably between 0.5 and 2% by weight. In particular, the coated inorganic particles, particularly carrier particles for electro-photography which contain a magnetic core, are spherical and have an average particle diameter of 20 to 200 μm, preferably 40 to 120 μm. It is also possible to deposit two or more layers on the particles (A), e.g. firstly an electrically insulating layer and above this a layer which improves the stability of the coated particles under mechanical stress. Cu�Zn ferrite particles supplied by Powdertech Co. Ltd., 217 Toyofuta, Kashiwa-Shi, Chiba (Japan) were used as particles containing iron oxide for coating tests. These were characterised as follows: d50: 50 μm density: 2.68 g/cm3 saturation magnetisation: 60-70 emu/g resistance: 2�107 ohm .cm Their flowability was determined using a run-out cup and 500 g of the coated particles. The specific resistance (Ωspec) of the carrier was determined in a cylindrical measuring cell with an inside diameter of 22.5 mm. This was filled to a height of 4 mm with carrier, on which a die was placed which was loaded with 1 kg. The current strength at a voltage of 200 V was read from the measuring device and Ωspecwas calculated as follows:
where U=the applied voltage (200 V) I=the measured current strength S=the internal surface of the measuring cell (4 cm2) d=the height of the carrier introduced (0.4 cm). The charge acceptance (−Q/m) was determined by development. For this purpose, 100 parts by weight of carrier and 5 parts by weight of toner were mixed in the developer unit. The developer mixture was activated for 10 minutes in a commercial copier device. After development, both the amount of toner generated (m) and the charge thereof (Q) were measured. The charge acceptance was therefore given by: The amount of coating given in the examples is represented by the sum of the amounts of polyfunctional organosilane and of tetraethyl orthosilicate used, in % by weight, in relation to the amount of carrier. The proportion of nitrogen-containing aminosilane (b-1) or (b-8) is given in % by weight in relation to the coating material. To determine the abrasion-resistance of the coating, 80 g of the coated carrier was mixed with 50 g of ceramic beads with a diameter of 10 mm in a 120 ml bottle, so that the degree of filling of the bottle was about 50%. The bottle was rotated for 16 hours on a roller table at a speed of 25 m/minute. The coating was partially abraded by this process and the amount of coating material removed by abrasion was determined as follows: The amount removed by abrasion was so small that it could not be determined gravimetrically. However, it could be distributed very homogeneously on a sheet of paper with a known optical density (determined using a Macbeth densitometer). The optical density was then re-measured. The values given in the Tables are density differences which could be reproduced very well. The smaller the value, the less the abrasion. The particles could be coated by different methods, e.g. in an industrial fluid bed reactor or in a 2 litre three-necked flask fitted with a stirrer, with an injection system for solution containing the coating material and with a condenser for recovering volatilised solvent. A coating temperature of 80 to 100� C. under a slightly reduced pressure of 950 to 100 mbar absolute, using a coating period of 15 to 60 minutes, proved to be advantageous. Curing was effected in the same vessel at 120 to 190� C. for 20 minutes to 4 hours. �X� in Tables 1 to 3 means that the substance was not used.
Bontron N�O 2 is a nigrosine compound which is employed for charge control. Spilon black TRH is a Cr-azo complex which is employed for charge control. Carbon black is a conductive lamp black. 75 kg of the ferrite particles were coated with solutions 1 and 2 at 85� C. and 98� mbar, dried, and cured by heating for 3 hours at 140� C. The results are given in Table 4.
A solution of 3.6 g of a silicone resin containing 95% by weight T units and 5% by weight M units (linkage of the Si atom via an oxygen atom with a further Si atom), 2.1 g of a silicone resin containing 100% by weight T units, 300 ml methyl ethyl ketone and 0.84 g (b-1) were mixed in this sequence, with stirring. A ready-for-processing coating solution was obtained, which gave a 0.5% by weight coating on 1 kg ferrite particles. Coating was effected at 70� C. and 50 mbar. The product was dried for 30 minutes at 90� C. and was cured for 16 hours at 140� C. The results are presented in Table 5.
The particles were sticky and therefore formed an amount of agglomerates or bonded firmly to the vessel. A larger amount of dust was formed on drying. 7.5 kg of the ferrite particles were coated with solutions 3 to 13 at 95� C. and 980 mbar, dried for 30 minutes at 90� C. and cured for 4 hours at 140� C. The results are listed in Table 6.
1 kg of the ferrite particles were coated with solutions 14 to 21 at 70� C. and 200 mbar, dried for 30 minutes at 90� C. and 50 mbar, and cured for 4 hours at 140� C. The results are listed in Table 7.
Coatings were deposited on 2 kg of the ferrite particles with solutions 22 to 27 in a fluidised bed reactor, under the following conditions: Bed temperature: 100� C. Gas temperature: 135� C. Spraying rate: 90 kg/hour Spraying direction: from below Duration of spraying: 40 minutes. Thereafter, the product was subsequently cured for about 90 minutes at a bed temperature of 150� C. and was finally cooled to room temperature. The results are listed in Table 8.
7.5 kg of the ferrite particles were coated with solution 5 as in coating example 1 and were cured under different conditions. The results are given in Table 9.
1 kg of magnetic carrier CM 40-75 SH supplied by Hoganas AB, S 26383 Hoganas (Sweden), with an average particle diameter of 65 μm and a saturation magnetisation of 90 emu/g, was coated with solution 28, with an amount of coating of 1.0% by weight and a content of b-1 of 4.0% by weight. Ωspec was 4�105Ωcm; −Q/m was 9.3 μC/g. 3.5 kg of glass beads with an average diameter of 360 μm were coated with solution 29. The amount of coating was 0.4% by weight. A coating which adhered well was obtained. After the admixture of toner, the coated glass beads were suitable as electrophotographic cascade developers. 7.5 kg of ferrite carrier was coated with solution 30 at 85� C. and 980 mbar, as in example 6, dried, and cured for 2 hours at 160� C. The amount of coating was 2.1% by weight; the content of b-7 was 1.0% by weight. Ωspec was 2.2�109 Ωcm; −Q/m was 16.1 μC/g; abrasion: 0.12; coarse fraction >125μm 0.9% by weight. 7.5 kg of ferrite carrier was coated with solution 31 at 85� C. and 980 mbar, as in example 6, dried, and cured for 4 hours at 160� C. The amount of coating was 1.6% by weight; the content of b-7 was 0.9% by weight. Ωspec was 1.5�108; −Q/m was 18.7 μC/g; abrasion: 0.14; coarse fraction >125μm 0.1% by weight. 7.5 kg of ferrite carrier was coated with solution 32 at 85� C. and 980 mbar, as in example 6, dried, and cured for 2 hours at 140� C. The amount of coating was 1.0% by weight; the content of b-7 was 2.0% by weight. Ωspec was 1.5�108; −Q/m was 18 μC/g; abrasion: 0.12; coarse fraction >125μm 0.1% by weight. 7.5 kg of ferrite carrier was coated with solution 33 to 35 at 85� C. and 980 mbar, as in example 6, dried, and cured for 2 hours at 140� C. The results are presented in Table 10:
Developers were prepared with the carriers produced as in coating examples 2, samples 2.3 and 9, and were tested, by the admixture of toner, in a continuous 10 printing test on a digital colour printer (Chromapress� manufactured by Agfa-Gevaert AG). More than 400,000 copies in DIN A4 format were produced, and were of a constant, good quality. Patent Citations
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Comfort Inn hotels in Williamsport
Popular with travellers from Ireland
Comfort Inn Selinsgrove
Good 3.9 / 5 ( 52 reviews )
37 people looked at this hotel in the last hour
Most recent review
"We have stayed here several times. The rooms are clean and comfortable. Some of the furniture shows a little wear but is not torn or dirty.Access is a little tricky as it is on a divided highway with only one direction in and out. That said once that is figured out there is no problem. There are ..."
A Traveller, Nov 2014, US
Comfort Inn Lamar
Good 3.6 / 5 ( 110 reviews )
30 people looked at this hotel in the last hour
Most recent review
"It was very nice. Breakfast was great. The only issue was that the water wasnt very hot for showering. Otherwise it was clean and staff were nice."
A Traveller, Oct 2014, US


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Have You Considered a Vertical Monitor Setup? Vertical monitor setups are not a new idea. We see them all over the world. At the airport. At restaurants. At the train station. And yet, it's not something we encounter that often in our offices at home and at work. However, there are definitely a few reasons more of us should consider it.
Snugg Tablet Travel Case Tech Test Lab Review Product: The Snugg iPad and Tablet Cases Price: $35.99 - $49.99 Rating: Recommend* When taking trips, it's not uncommon for me to leave the laptop at home and opt for my iPad or tablet instead. Most road warriors I know are pretty committed to a bluetooth keyboard and tablet, which is why finding the perfect case is so critical.
What Are Your Tech Pet Peeves? My very first computer was a desktop my family and I shared. It was a Dell from the era of the Dell Dude, complete with a 25 pound monitor and a loud and hot tower which held the keys to Minesweeper and the world wide web. It was also my first and my last shared computer, because as a tech lover, I picked up a few tech pet peeves.
Weekend Project: Organize Your Digital Planner Apartment Therapy Videos: Justin Klosky In today's video, Justin brings us a weekend project that can help you better manage your time both at home and away from home. In today's video, Justin brings us a weekend project that can help you better manage your time both at home and away from home.
Bye Bye Sticky Keyboard! Keep This Cleaning Kit in Your Desk Drawer Are you reading this at your desk? Take a peek between the keys and see if your computer keyboard might need a little attention. Gross, right? If you kept this keyboard-cleaning toolbox in your desk drawer, you could take care of that crumby mess right now.
DIY Gift Idea: 10 Tablet Case Projects for Every Skill Level Whether you need to whip up a tablet case for either a 7" or 10" tablet for yourself or to gift a friend, we've got you covered this week with a several do it yourself projects, ranging from beginner to DIY pro. There's surely at least one in here that will rock your recipient's socks off...
25 Free & Festive Holiday Wallpapers for Your Desktop It's probably a little too early to put up the Christmas tree according to the "It's-not-Thanksgiving-yet" neighborhood brigade. Thankfully, your desktop offers a safe space where anyone can wallow in holiday cheer—even in the middle of November. Here are our favorite picks for desktop wallpaper that celebrate all things snowy, wintry, lit-up, and festive. Grinches, back off!
10 Cases for the Colorful iPhone 5c My wife and I have recently became proud owners of a pair of "his & hers" iPhone 5c's. We're enjoying the newfound color in our lives, however, we're worried about dropping our new phones because the polycarbonate shells are on the slippery side. Unfortunately, not many cases are yet available in stores except ones from Apple, but there are a few stylish options online to match our equally stylish phones.
Should I Get the MacBook Air or the New iPad Air? Good Tech Questions Q: I have been going back and forth on a tech purchase and was hoping other Apartment Therapy readers could help me make a decision. The question: MacBook Air (11.6") or iPad Air?
20 iPhone 5s Cases In Nearly Every Material Finish Not content to settle for just your typical run-of-the-mill case for your brand new iPhone 5s? We've collected 20 of the latest cases, ranging from the soft to the heavy and hard, all designed to protect and accessorize the latest iPhone in unique material finishes...


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Kitchen Units + worktop + sink + cooker QUICK SALE!!! USED BUT GOOD CONDITION
Kitchen for sale Used but in good condition asking £650 ONO and must go first week of Feb (or earlier) as new kitchen coming in. What's for sale: All the units as on pictures + Worktop + sink + battery + cooker + extractor Dishwasher not included!


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Photos from IRS protests around the country today
Tweet |
Tea Party Patriots, 9/12 groups, liberty groups, and their grass-roots supporters quickly mobilized through social media and gathered today at IRS offices nationwide to protest the chilling political witch hunts conducted by the Obama administration.
They will not be silenced. And they will not stand down.
Here's a photo collection from across the country:
#IRSProtest attendees in Town & Country MO wearing targets on their backs ==> twitter.com/Hauckers/statu…
— Michelle Malkin (@michellemalkin) May 21, 2013
RT @cindylamar IRS protest in Evansville, IN twitter.com/CindyLaMar/sta…
— Michelle Malkin (@michellemalkin) May 21, 2013
#IRSProtest sign in Nashville: "I'm from the IRS and I'm here to enforce Obamacare. Isn't that special?" twitter.com/WSMVCarley/sta…
— Michelle Malkin (@michellemalkin) May 21, 2013
#IRSProtest MT @bundgaard2 Protest outside Nashville Fed Ct House vs IRS for targeting Tea Party groups twitter.com/bundgaard2/sta…
— Michelle Malkin (@michellemalkin) May 21, 2013
Crowd swells & horns honk at IRS protest at Nashville's Fed Ct. House. Crowd incl Rep. Joe Carr, Sen Mike Bell @wkrn twitter.com/bundgaard2/sta…
— Chris Bundgaard (@bundgaard2) May 21, 2013
Over 500 here now.more coming #IRSprotest #IRSProtestCincy twitter.com/annbecker1999/…
— Ann Becker (@annbecker1999) May 21, 2013
The corner of 10th & PA Ave is packed with #IRS protestors: twitter.com/matthewhurtt/s…
— Matthew Hurtt (@matthewhurtt) May 21, 2013
Mobile Al IRS rally twitter.com/ZanP/status/33…
— Zan (@ZanP) May 21, 2013
More from Twitchy Team here.
Barred from entering the US? Try making some generous campaign contributions
December 17, 2014 09:03 AM by Doug Powers
Obama's scandal-tainted BCBG (best Chicago golfing buddy)
December 5, 2014 08:28 AM by Michelle Malkin
Obama's executive amnesty helps draw thousands of Lois Lerner's emails out of the shadows
November 21, 2014 07:22 PM by Doug Powers
Jonathan Gruber cashed in even more than previously thought; Update: And Obama JUST found out about all this
November 16, 2014 09:23 AM by Doug Powers
Nancy Pelosi was for Jonathan Gruber before she never heard of him
November 13, 2014 08:56 PM by Doug Powers
Categories: Corruption, Democrats, Health care, Nancy Pelosi


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byScott Campbell on
PC Settings
The PC Settings within Windows 8.1 lets users more easily access settings without having to go to (or find, in the case of novice users) the desktop's Control Panel. Specifically, Windows 8.1 users will be able to change their display resolution, set power options, do a Windows Update, change the product key, view available storage or manage SkyDrive from PC Settings, according to Microsoft.
CRN's Channel And Technology Predictions For 2015
CRN offers up some predictions for the channel and technology industry as a whole in 2015.
Here are 10 recent searches by CRN visitors.


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Taris and Gamma Orionis
Does the "Taris" mission in Iconia unlock the missions to Gamma Orionis? I was unable to beat the psionic warriors until today and I finished the mission several weeks after trying it for the first time. Admiral T'nae then disappeared from the "Hail Starfleet" area but there were new missions in "Hail Starfleet", to Gamma Orionis.
I almost never got to Gamma Orionis because of those purple outline enemies. I used all Vulcans in my away team to Taris, used focus fire, and used a blast type weapon against the Reman Captain with the psionic powers and then against Taris herself. That is how I finally finished it. |
You must have reached RA3, that is when you get a mission to go to Gamma O.
All times are GMT -7. The time now is 10:45 PM. |


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(1 review)
cakie on 12/3/2004 3:20:00 PM More reviews by cakie
Age: 19-24 Skin: Oily, Fair-Medium, Warm Hair: Brown, Wavy, Medium Eyes: Brown
I'm using this in Mauve. It is a pink color powder. I can only use it during winter as it made me look soooo pale during summer. The powder is pretty nice, and it does hide some pimple marks on my face :] Though I think this has been D/Ced. I would buy it again, in other color, if I could find it.
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