text:
My Profile
Chef #386740
Crescent City, California
Member since Nov 2006
Flag This ProfileFlag as Inappropriate
Reviewed Pork-Bellied Poppers
Dec 12, 2012 in Food Network Community Toolbox on FoodNetwork.com
"I loved it, finally a recipe where the cheese filling didn't spill out in the cooking process, The reason only 4 stars is because the peppers were very crisp and I prefer them soft for poppers. Maybe next time I will par-boil them before doing any of the other steps. Also, my peppers were so spicy hot that we actually ended up eating the filling o""
Saved Recipe Mixed Green Salad With Fresh Peaches, Basil and Chevre by CaliforniaJan
Mar 22, 2011 on Food.com
Saved Recipe Mixed Greens with Dried Cranberries and Toasted Pecans by Sharon123
Mar 22, 2011 on Food.com
Saved Recipe Mixed Green Salad With Oranges, Dried Cranberries and Pecans by Bev
Mar 22, 2011 on Food.com
Saved Recipe Kittencal's Famous Barbecue Sauce for Chicken and Ribs by Kittencalskitchen
Dec 23, 2010 on Food.com
Saved Recipe Sweet Vanilla Bourbon Sauce for Filet Mignon or Salmon by GoldsmithLissa
Dec 23, 2010 on Food.com


text:
(The following press release from Swiss International Air Lines was received by e-mail. The sender verified the statement.) Media release Zurich Airport, 8 February 2013 CFO Marcel Klaus to leave the company Chief Financial Officer Marcel Klaus has decided to leave Swiss International Air Lines after 12 years with the company. Klaus, who is 51, intends to take a sabbatical before pursuing new professional goals. He will leave SWISS in July. Marcel Klaus has extensive experience in both the airline and the financial sector. He began his career 20 years ago with the then Crossair in Basel, and has served SWISS in key executive financial capacities (including Head of Group Controlling) since its beginnings in 2001. He played a vital role in its challenging corporate turnaround, and was appointed CFO in 2006 following the company?s acquisition by the Lufthansa Group. ?I will miss the SWISS culture, the team spirit and our dynamic industry environment,? Klaus says. ?But after spending such a good part of my working life with the company, including seven years as CFO, I feel it?s time to take a new path and seek new perspectives. And I?m greatly looking forward to whatever challenges the future may hold.? As CFO, Marcel Klaus is also responsible for SWISS?s cargo and IT units. He additionally serves on the boards of directors of the company?s Swiss European Air Lines and Swiss AviationSoftware subsidiaries, and as chairman of the board of further subsidiary Swiss AviationTraining. Within the broader Lufthansa Group he is currently project leader at SWISS for the groupwide SCORE results enhancement programme. Marcel Klaus has been instrumental in establishing and refining the efficient structures, clear responsibilities, keen cost-awareness and short decision-making channels that SWISS can rely on in its Finance Division today. He has also been responsible for consolidating Swiss WorldCargo?s strategy as an autonomous business unit and further developing its role and success as a provider of quality niche cargo transport products. ?In Marcel Klaus we are losing a talented, experienced and highly-valued member of our top-management team,? adds CEO Harry Hohmeister. ?Our company has a lot to thank Marcel for. We are very sorry to see him go; and we wish him every continued success and satisfaction, both professionally and personally, in the years ahead.? Marcel Klaus will remain SWISS CFO until July. The Board of Directors will appoint his successor in the next few months. 20130208_Media Release_CFO Marcel Klaus to leave the company.pdf For further information visit www.swiss.com/media Contact Swiss International Air Lines Ltd. Media Relations P.O. Box, 8058 Zurich Airport Switzerland Phone: +41 848 773 773 Fax: +41 44 564 2127 firstname.lastname@example.com swiss.com
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subset: commoncrawl


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With the sixth pick in the NFL draft, the Browns definitely will select ...
Blog Entry:
April 25, 2013 10:03 AM | Author: KEVIN KLEPS
Would the Browns, a year after selecting a 28-year-old quarterback in the first round, take another QB near the top of the draft tonight?
Would they use the No. 6 overall pick on a cornerback, Alabama's Dee Milliner, who has had a combined five surgeries for shoulder, knee and leg injuries (Milliner's tally includes a sports hernia)?
Your guess is as good as mine.
Speaking of guessing, we rounded up some educated ones — the mock drafts of five local beat writers and six national experts.
The consensus from the 11 mock drafts: The Browns will select Milliner if they can't trade down. Two mocks have the Browns trading with San Diego, which owns the 11th overall selection, to recoup the second-round pick they surrendered when they took wide receiver Josh Gordon in the supplemental draft last summer.
Milliner was the Browns' choice on four of the 11 mocks, and West Virginia QB Geno Smith was the pick on three. Oregon linebacker Dion Jordan had a pair of "votes," and linebackers Jarvis Jones (Georgia) and Barkevious Mingo (LSU) were each pegged as the Browns' choice on one of the 11 mock drafts.
The 11 mocks resulted in five players heading to the Browns, which tells you all you need to know about the craziness that is predicting where the top players are headed in tonight's first round.
But it's fun, and we can all pretend we've broken down the scouting videos when we argue the Browns' selection of a linebacker or cornerback we might have watched two or three times in all of 2012.
The 11 writers' and draft experts' (ladies and gentlemen, Mel Kiper!) picks for the Browns are as follows:
Mary Kay Cabot,
The Plain Dealer:
Dion Jordan, LB, Oregon.
Cabot writes:
I believe the Browns would be thrilled if Jordan falls to them here. … The Browns will try to trade down if one of their coveted players isn't there.
Doug Farrar, Yahoo! Sports:
Dee Milliner, CB, Alabama.
Farrar writes:
New Browns defensive coordinator Ray Horton loves physical defensive backs, and Milliner fits the bill.
Tony Grossi, ESPNCleveland.com:
Barkevious Mingo, LB, LSU.
Grossi writes:
If my top five are correct, Browns will be able to trade down.
Peter King, Sports Illustrated:
Geno Smith, QB, West Virginia. (King has the Browns trading down to No. 11, and San Diego moving up to No. 6, netting the Browns a second-round pick.)
King writes:
Don't let the smokescreen acquisition of Jason Campbell, a backup, fool you: the Browns want a QB in this draft, and they get one.
Mel Kiper, ESPN:
Kiper writes:
The Browns are really desperate for another corner to play opposite Joe Haden. If they get Milliner, that's a solid No. 2 option, also allowing them to move Buster Skrine inside to cover the slot, a position where he's far better.
Jason La Canfora, CBS Sports:
La Canfora writes:
The Browns are comfortable with corner Dee Milliner's medical situation, but already have a stud corner in Joe Haden, so if they have the choice of these two players, I say they go Jordan.
Mike Mayock, NFL Network:
Mayock writes:
When I look at Geno, I see a kid who's got everything you want to see in a franchise quarterback, but there's just too much bad tape. I would not take him this early; I would go for an edge or a corner.
Todd McShay, ESPN:
McShay writes:
McShay didn't write anything. It was just a list. (Maybe that's for the best.)
Scott Petrak,
The Elyria Chronicle-Telegram
The Medina Gazette:
Jarvis Jones, LB, Georgia. (Petrak also has the Browns trading down to No. 11.)
Petrak writes:
28 sacks in last two years fits profile of what the Browns want.
Jeff Schudel,
The News-Herald
and the
Lorain Morning Journal:
Schudel writes:
I still expect the Browns to trade down if they can.
Nate Ulrich, the
Akron Beacon Journal:
Ulrich writes:
If Milliner is available at No. 6 and the Browns don't trade down, this pick would be a no-brainer because it would fill the team's dire need for a cornerback who can immediately start opposite Joe Haden.
My take: If the Browns can trade down, add a second-round pick and end up with one of the top pass rushers on the board, it will be a good night.
Step aside, McShay. We're all experts tonight.
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text:
Welcome, guest
The opening of Myanmar to the outside world
Despite political football, the bank is still in the game
September 2011
by Eric Ellis
Australia has struck it rich, and lucky, as it has used its natural resources to benefit from the China spending boom. But the careful stewardship of its treasurer, Wayne Swan, has played a key role in making it the best-performing economy among the world's richer, developed nations. Not that he is likely to get much credit at home, as Eric Ellis reports.
Finance minister of the year 2011 Wayne Swan Press release How Euromoneys finance minister award became an Aussie political football Finance minister of the year Wayne Swan Media coverage Also see More on China More Asia coverage
New to Euromoney.com? Subscribe now or Take a free trial
The less charitable might even recall the words of Donald Horne, in his 1964 book The Lucky Country, which read: "Australia is a lucky country, run by second-rate people who share its luck."
Swan would probably be among the first to admit that he has indeed had some luck. But his work as treasurer is acknowledged by Euromoney as much for what didnt happen to Australia on his careful four-year watch economic Armageddon in the trail of the 2007-08 subprime meltdown, which he confronted in his first year in office as for what he positively did, positioning Australia to power through the new crisis looming from abroad.
"The fiscal rules that we put in place to deal with the global recession when we moved to stimulate the economy were ahead of the rest of the world," says Swan, in an interview from the kookaburra-chorused back verandah at his home in Brisbane.
"These were the sorts of rules that were ultimately adopted by the G20 in its summits through 2009, this whole notion that you needed an exit strategy. At the time we moved to stimulate, we put one in place and weve been applying it vigorously. Its not happening anywhere else in the world."
As a result, Australia is one of only three OECD economies not to fall into recession since 2008, alongside Poland and South Korea. And it seems well placed to repeat the feat as the worsening euro crisis and US funk spread their infection. After two decades of growth, Australias sustained expansion has been the most impressive performance of any member of the developed rich countries club.
Thats all very well, but is Swan a worthy recipient of the award, in this era of booming Brics and roaring Tigers emerging to trump the sputtering west?
Former ANZ chief economist Saul Eslake of the University of Melbourne think-tank The Grattan Institute knows the 57-year-old Swan well, and offers a qualified yes.
"Swan is certainly after glory," says Eslake, "but for his party, not for himself. Hell be thinking how this gong will improve Labors chances of winning the next election, seeing it in intensely political terms as will, of course, his political opponents."
That political capital might be useful, given that theres every possibility that by the next time Euromoney considers the global field of finance ministers, Swan wont be among them. The longevity of the minority Labor-led government of prime minister Julia Gillard Swan is deputy prime minister depends on the whim of three independent MPs who face a voter backlash in their own constituencies, because they backed Labor into power last year.
And none have been impressed by Hookergate, allegations that Labor backbencher Craig Thomson, who chaired a key parliamentary economics committee, paid for prostitutes with his unions credit card, as Labor bailed him out of bankruptcy with party funds. With a two-seat majority and a 15-point deficit in opinion polls, Labor cant waste a single seat, lest it trigger an early election it will certainly lose.
What does Swan think?
"Oh, I think Australians recognize that we did really well during the global financial crisis and the global recession," he says.
"Australians do understand that we were almost alone among the developed economies to not go into recession. Thats the thing Im most proud of.
"When we moved to stimulate the economy (in 2007-08), given the nature of the debate in Australia, it was controversial and vehemently opposed by our political opponents. As time has proven, the fact is we did keep Australia out of recession, we had one quarter of negative growth and avoided it in the subsequent three. We took a well-thought-out, well-executed set of plans to stimulate the economy.
"And it worked, so we didnt go into recession and we didnt suffer the capital destruction and the skill destruction that we saw in many other countries, and its given us a really great foundation to approach the Asian century and the resources boom that comes with it, because we are going into that from a position of strength."
If only Australians saw it that way. Through their gloomy prism, things are grim, and theyre pointing fingers at the government. Indeed, during this 20th anniversary of the collapse of the Soviet Union, theres something of Gorbachev about Swan and Labor hailed abroad by everyone from the IMF to the OECD but loathed at home. Or perhaps its a little like what sport-obsessed Australians are world renowned for. They hate it when the referee intervenes in an epic battle. Sport is best contested when the umpire is invisible, which usually means hes doing a good job. But Australian umpires, like their politicians, arent to be praised, no matter how well run the contest. Elections elsewhere are fought on the economy, and Australians are the thankless lot who bounced the conservative Howard-Costello team from office after 11 years, while the booming economy was at the peak of its powers.
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Full details of the award, including an in-depth interview with Videgaray and coverage of the reception at the IMF in Washington will be live October 10.
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Padma Yoga - Yoga Related Event |
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Dr. Robert F. Denyer, DO
Cardiovascular Disease, Austin Heart PA
- 1900 Scenic Dr Ste 3308
Georgetown, TX 78626 - 1 Office Location
- (512) 869-2566
Dr. Robert F. Denyer graduated from the University of North Texas College of Osteopathic Medicine in 1997. He works in Georgetown, TX and specializes in Cardiovascular Disease and Vascular Surgery. Dr. Denyer is affiliated with St Davids Georgetown Hospital and Saint Davids Medical Center. He speaks English and Spanish.
Gender: Male
Years in Practice: 18 Years
Languages Spoken: English, Spanish
Medical School: University of North Texas College of Osteopathic Medicine
Graduation Date: 1997
Hospital Affiliations: St Davids Georgetown Hospital, Saint Davids Medical Center
Specialties: Cardiovascular Disease, Vascular Surgery


text:
- Musician's Friend Best Selection, Price & Service. Guaranteed.
Call our Gear Heads
at: 800-449-9128
Call our Gear Heads
at: 800-449-9128
An analog, solid-state, two channel amp based on the prestigious Rockerverb range.
The Orange Crush CR60C is a 60W solid-state combo made from 18mm ply and loaded with a single 12â³ 60W, 16 Ohm Voice of the World speaker. The Voice of the Worlds combined with the analogue solid-state circuitry gives the CR60C the tonal clarity and definition players adore in an Orange amplifier.
The Crush CR60C combo amp is part of the Crush range, marking Orange's first foray into the world of high power, solid-state amplifiers. Orange have spent years creating a solid-state amp they could be proud of. The Orange team wanted to keep these amp simple. The dirty channel uses a circuit based on four stages of gain and a three band EQ which provides the player with a wide pallet of over-driven and distorted sounds. The clean channel is based on a two stage, two band EQ design, that gives the player a clean but warm sound which when cranked begins to break up.
These amps have a transparent effects loop, allowing you to plug in your favorite pedals. It also contains a digital reverb that provides a natural sounding spring, hall or plate reverb. The Crush CR60C features Orange basket-weave Tolex, woven speaker grille, beading, hieroglyphs, and of course the Orange signature picture frame edging.
Call or click to get this combo.
Review Snapshot®
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Best Uses
Reviewed by 4 customers
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Best Uses
Comments about Orange Amplifiers Crush Pro CR60C 60W Guitar Combo Amp:
the clean is very clean an the dirty chanle is a great platform for my pedels . the 3 reverbs are fine....this is great for smaller gigs. where my stack would be way to much..over all im very pleased so far. an its light..42LBs I can def. deal with that...I will let you know how it works when I use it live ..........stay tuned
Best Uses
Comments about Orange Amplifiers Crush Pro CR60C 60W Guitar Combo Amp:
I tried one of these out at my local shop and was amazed by the sounds. Clean channel is clear and articulate. I had no trouble geting beautiful sounds on the clean channel.
The Drive channel took a bit of getting used to as the Orange sound seems to have a breathy, kind of airy mid frequency. Though I found scooping the mids yielded a more pleasant tone to my ears. There is plenty of gain on tap for metal, and in fact I'd highly reccomend this amp if you're in a metal band. Either the Combo or the Head verson.
Once I got the EQ dialed, I had no problem dialing the right amount of gain for some hard rock and blues tones. Even with the mids scooped a bit, it yielded some nice round notes with plenty of soul, and the treble control added just enough bite to the top end to get that Hard Rock growl that I like.
You can select from 3 different types of reverb, but I like the spring setting the best. Even though it's a digital reverb, it faithfully recreates that dripping, springy sound, especially on the clean channel.
The combo is definitely a great amp for gigging at your local pub, or doing a few festival shows, or even just to have on hand for your studio.
I look forward to getting one of these in the near future.
Best Uses
Comments about Orange Amplifiers Crush Pro CR60C 60W Guitar Combo Amp:
I checked out one of these amps a local Blues musician was trying to sell. Now I know why he wanted to sell it. Won't go into details. I will say it wasn't that amp was bad or anything. The clean was about average for a SS amp, I could get a good basic vintage Rock and Blues sound, for Jazz and other clean guitar it just didn't excite me much. Reverb was okay. Get a Roland if you want good clean for Jazz or better yet a Fender SS amp in same price range, but they don't have the Orange "coolness" to them. Other wise, if your into Hard Rock, Metal or you don't ever play clean guitar the OD channel is your puppy, You'll dig it. The speaker didn't impress me much, which may be part of the problem. I would have liked to hook-up the Jensen in my Deluxe Reverb and gave a listen, but it's a 16 ohm speaker and my amp is 8 ohms, not sure it would sound like it should. For some this will be a great amp. I think it's well built and should last along time.
Best Uses
Comments about Orange Amplifiers Crush Pro CR60C 60W Guitar Combo Amp:
The Orange CR60 Combo Amp -Solid State
I've tried many other solid state amplifier through the years , from Fender , Peavy, Marshall ect,ect. This CR 60C is without a doubt one of two of the best sounding out there, the other being made by tech 21. The orange will give you the mid focused clean , and since the clean side has 2stages it give you that mimicked focus overdrive , nice real nice and it 4stage gain control takes you from smoky blues to all out ACDC, and more , 60s, 70s, 80s, Rock!!! The controls are simple easy to use just like the Rockverb , plus you get a three level reverb , Hall, Plate and my own favorite spring . The amp is well designed for gigging as it is built like a tank, very road worthy. Price, you get what you pay for, simply if you want profession electronic just like anything else you pay for it. Great playing, a lot of Musical combination and no warm up time like tubes, but let there be No Mistake , so far no matter how great the electronics are the is no replacement for the characteristics of a tube amp , but Orange has sure come clear in there duplication of sounding just like there tube version of the Rockverb in this Solid State of the Art amp , The CR60C , for me is a perfect ,and first edition of a solid state amp to my collection of over 15 tube amps ranging from VOX to Marshall ,and all down the Alphabet.
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John Parmelee, immigrant ancestor, was one of the first settlers of Guilford. Connecticut, and one of the twenty-five signers of the Plantation Covenant, June 1, 1639. He died in New Haven, November 8, 1659, leaving property inventoried at seventy-eight pounds, thirteen shillings. His will was probated January 3, 1659-60. His home lot in Guilford was on the site of the present Congregational church and contained two and a half acres. He married (first) Hannah (second) Widow Elizabeth Bradley, who died in New Haven, January, 1683. After his death she married, May 27, 1663. John Evarts. of Guilford. Children : John, born about 1620, mentioned elsewhere; Hannah, about 1625; Mary, married, September 16. 1660, Dennis Crampton, of Guilford.
Biographical Sketch of John Parmelee
MLA Source Citation:
Milliken, Charles F. The History of Ontario County, New York, and Its People Lewis Historical Publishing Co., New York. 1911. AccessGenealogy.com. Web. 31 January 2015. http://www.accessgenealogy.com/new-york/biographical-sketch-of-john-parmelee-2.htm - Last updated on May 17th, 2011Contribute to the Conversation!
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5 Stocks Set to Soar on Bulish Earnings
My first earnings short-squeeze play is durable goods rent-to-own operator Rent-A-Center (RCII - Get Report), which is set to release numbers on Monday after the market close. Wall Street analysts, on average, expect Rent-A-Center to report revenue of $787.95 million on earnings of 75 cents per share.
The current short interest as a percentage of the float for Rent-A-Center is very high at 16.1%. That means that out of the 51.73 million shares in the tradable float, 8.34 million shares are sold short by the bears. The bears have also been increasing their bets from the last reporting period by 7.2%, or by about 562,000 shares. If the bears get caught pressing their bets into a bullish quarter, then shares of RCII could easily rip significantly higher post-earnings as the shorts rush to cover some of their positions.
>>4 Stocks Spiking on Big Volume
From a technical perspective, RCII is currently trending below both its 50-day and 200-day moving averages, which is bearish. This stock has been downtrending over the last six months, with shares dropping sharply from over $39 to its recent low of $30.74 a share. During that downtrend, shares of RCII have been consistently making lower highs and lower lows, which is bearish technical price action. If you're bullish on RCII, then I would wait until after its report and look for long-biased trades if this stock manages to break out above some near-term overhead resistance levels at $32.01 to its 50-day moving average of $33.08 a share with high volume. Look for volume on that move that hits near or above its three-month average action of 524,976 shares. If that breakout hits, then RCII will set up to re-test or possibly take out its next major overhead resistance levels at its 200-day moving average of $35.70 to $37.23 a share. Any high-volume move above those levels will then give RCII a chance to tag $40 I would simply avoid RCII or look for short-biased trades if after earnings it fails to trigger that breakout and then drops back below its 52-week low of $30.74 a share to some more past support at $30.30 a share with high volume. If we get that move, then RCII will set up to enter new 52-week-low territory, which is bearish technical price action. Some possible downside targets off that move are $25 to $22 a share.Check Out Our Best Services for Investors
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Australian Al-Jazeera reporter Greste deported, Fahmy and Mohamed still...
Djokovic makes it 5 from 5 in Australian Open finals, delivers another...
Michael Jackson's former home could become a sex-assault rehabilitation...
Cartoonist Steve Nease goes all the way back to 1912 to find a suitable and...
CLARINGTON -- Clarington is changing and so is its local library....
DURHAM -- If you've ever struggled with a one-size-fits-all fitness routine, then you will want to stay tuned this week as we go through a series of videos on inclusive exercises.
As an International Centre of Excellence, and state-of-the-art fitness facility, the Abilities Centre in Whitby is making waves as a leader in accessibility. Since opening in June 2012, the centre has developed classes and workshops that reflect the needs of a growing community. With the number of Ontarians with a disability reaching 1.85 million, more Durham Region residents will benefit from inclusive health and wellness activities.
If you don't have a disability, there are loads of benefits from inclusive exercise. Recover from old injuries or achieve long-standing fitness goals with the help of an integrated community and trained fitness professionals.
The following segments for this series will focus on inclusive health and wellness activities that can lessen stress, increase quality of life and improve your overall health. Learn how traditional fitness exercises are being adapted for different abilities, and discover exciting new sports that are taking the fitness world by storm.
What to expect:
- Yoga is an excellent example of how fitness can be made adaptable and accessible. With a variety of forms and speeds, the modifications available extend to levels of fitness and flexibility. Participants can expect improved muscle tone, increased range of motion, decrease in spasticity and improved breathing capacity.
- One fitness class that can easily be adapted to all fitness levels is spin. Find a comfortable seating position, adjust the tension to your capability, and go at your own rate. A note for beginners: the beauty of spin is even if you are the slowest one in the class, you can never fall behind. At the Abilities Centre, we've gone one step further to make spin class accessible by offering hand cycle spin bikes.
- New and trendy TRX (Total body resistance crosstraining) uses bands and your own body weight as resistance. Sculpt and strengthen using only your body weight, or a fraction of it, in this military-inspired fitness routine.
- ParaSport: Let's face it, not everybody finds weight-lifting and cardio machines fun and entertaining, but that's OK, there are other ways to get in shape. Sports are a fantastic alternative for improving your fitness. Parasports such as wheelchair basketball, wheelchair lacrosse, and sitting volleyball challenge your muscles, your stamina, and your hand-eye coordination. Or perhaps, you prefer something less intense? Try boccia or chair curling.
- Running is one of the easiest exercises to incorporate into your lifestyle. Whether you jog or run, why not challenge yourself to go the distance this year and try your first marathon... or 5k? Learn to finish the race safely by participating in a running clinic. At the Abilities Centre, we have clinics starting mid-March for 5K, 10K, half and full marathons.
- Contrary to popular belief, resistance training can be safe and beneficial for youth -- it improves coordination, increases metabolism, and can build self-confidence. To ensure a safe, positive experience, the Abilities Centre has developed a short course (a mix of anatomy, physiology, and practical) for our youth who wish to participate in strength training.
- For anyone who struggles with lung health, respiratory recovery programs can make a world of difference in the rehabilitation process. Low-impact and monitored cardiovascular exercises re-build lung capacity and can combat symptoms of lung disease such as COPD and emphysema.
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Reviewed Cuban Slow-Cooker Pork Chops
Sep 3, 2013 in on Food.com
"This was a great recipe. Used 4 thick bone-in chops. I seared the chops first before cooking. They came out so tender and flavorful. Served with yellow rice and green beans. I will be making this one again.""
Saved Recipe Auberge Cheddar Cheese and Ham Breakfast Buns - Muffins by French Tart
Jul 16, 2013 on Food.com


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A'ja Wilson's decision to go to South Carolina is great for the Gamecocks. But for the general women's basketball fan, perhaps the best part of her announcement Wednesday was more about where Wilson isn't going.
Apr 16 | By Mechelle Voepel
Many Eastern Conference teams got a makeover Monday as both veterans and draftees found new homes in the WNBA draft or via trades.
Apr 14 | By Mechelle Voepel
Over the past decade, the No. 1 picks in the WNBA draft have all paid off. On Monday, either Stanford's Chiney Ogwumike or Baylor's Odyssey Sims will get a chance to continue that legacy.
Apr 13 | By Mechelle Voepel
Stanford's Chiney Ogwumike and Baylor's Odyssey Sims have emerged as the most likely candidates for the No. 1 overall pick in Monday's WNBA draft.
Apr 11 | By Mechelle Voepel
What was a star-crossed season for UConn junior forward Kaleena Mosqueda-Lewis turned into a starring role in the NCAA tournament.
Apr 8 | By Mechelle Voepel
No matter the opponent, no matter the stage, no matter the names of his players, Geno Auriemma keeps yielding the same result: NCAA titles. And UConn's road to a record ninth championship was no different.
Apr 8 | By Mechelle Voepel
WBCA names 10-member All-America team.
Apr 5 4:43 PM ET | By Mechelle Voepel
Tyler Summitt and Jimmy Dykes may be headline-making hires, but they deserve a shot to validate themselves -- and to create their own headlines for the masses to judge only after they take over.
Apr 2 | By Mechelle Voepel
Natalie Achonwa, diagnosed with a season-ending torn ACL on Tuesday, is a player and leader Notre Dame will struggle to replace as it prepares for its fourth straight Final Four and possible matchup with UConn.
Apr 1 | By Mechelle Voepel
After weeks of anticipation, UConn and Notre Dame each won Monday to advance to the Final Four, putting two perfect teams in Nashville.
Mar 31 | By Mechelle Voepel
The madness we've all been waiting for tips Saturday morning. We look at what underdogs might come out on top, which teams might make the most noise, and the tourney's reigning top dog, UConn sophomore Breanna Stewart.
Mar 21 | By Mechelle Voepel
Tennessee has won seven consecutive games and 13 of its past 14. Yes, the Lady Vols seem to have really clicked at just the right time.
Mar 20 | By Mechelle Voepel
It's a long way to a potential NCAA championship-game matchup between undefeated titans Connecticut and Notre Dame, but one thing's for sure: They won't overlook any opponents along the way.
Mar 17 | By Mechelle Voepel
South Carolina received its first No. 1 seed and has no complaints about traveling three time zones away to Seattle for its NCAA tournament opener.
Mar 17 | By Mechelle Voepel
Undefeated UConn and Notre Dame are locks for No. 1 seeds. Will Stanford and Tennessee also be on the top line? Will the Huskies be placed in Lincoln? Will the Fighting Irish face a road game in the second round?
Mar 17 | By Mechelle Voepel
The women's tournament could give fans the first title matchup between two undefeated teams, but plenty can happen between now and Nashville. Mechelle Voepel looks at potential obstacles for Connecticut and Notre Dame.
Mar 17 | By Mechelle Voepel
It's official. UConn's win Monday means two undefeated teams -- Notre Dame and the Huskies -- will head to the NCAA tournament. Now, let's talk about which regional UConn should end up in when the bracket is unveiled.
Mar 10 | By Mechelle Voepel
Jewell Loyd's 26 points, including one of her patented alley-oops, ignited Notre Dame past Duke as the Irish improved to 32-0 and won the ACC tournament championship.
Mar 9 | By Mechelle Voepel
Who says Duke is down and out? The Blue Devils beat longtime rival North Carolina in a thriller Saturday to advance to the ACC tournament final, where they'll meet unbeaten Notre Dame, the new standard in the ACC this season.
Mar 8 | By Mechelle Voepel
Four months ago, Duke, North Carolina and NC State set out on their seasons with high expectations. How did it turn out for the Blue Devils, Tar Heels and Wolfpack?
Mar 5 | By Mechelle Voepel
In the 2011, '12 and '13 LPGA seasons, Paula Creamer had a combined 23 top-10 finishes, placing as high as runner-up each year. But she hadn't won since 2010, although that victory was a huge one: The U.S. Women's Open.
Mar 3 1:12 AM ET | By Mechelle Voepel
In its second season in the Big 12, West Virginia has won its way into second place in the league.
Feb 28 | By Mechelle Voepel
The Cornhuskers hit 16 3-pointers to put on a clinic -- and likely lock up their spot in the NCAA tournament field -- to knock off No. 8 Penn State.
Feb 24 | By Mechelle Voepel
After a combined 77 points, 23 rebounds and six assists in three Notre Dame victories, sophomore Jewell Loyd nabbed our weekly honor.
Feb 24 2:14 AM ET | By Mechelle Voepel
Dawn Staley didn't win an NCAA title as a player. But with a handful of talented players at South Carolina, she is constructing a program to give her that chance as a coach.
Feb 20 | By Mechelle Voepel


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Product Description
- Pattern: Rainbow
- Material: Cotton Blend
- Size: 200 x 25cm/78.7 x 9.8in(L x W)
- This is a color matching rainbow pattern warm cotton blend winter scarf
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- This women scarf can be a good partner for any season
- This women scarf is cozy. Besides, it has many functions of embellishment
How to Wash:
Cotton blends clothing is made from fibers of both cotton and synthetic polyester. The fabric is lightweight and typically does not need to be ironed, which makes it great for traveling. The cotton polyester blend doesn't shrink as much as cotton.
•l Machine washes on the warm cycle with a detergent of your choice
•l Separate whites from colored clothes. Wash whites and colors, separately to ensure color preservation
•l Wash a load of either whites or colors in the washing machine on the delicate cycle using cold water. Use regular laundry detergent without bleach to wash the clothes
•l Add a fabric softener if you so desire
Tumble dry the clothes on the delicate setting, unless the tags specifically direct you to line dry or lay the item flat to dry. If you are concerned about shrinkage, then tumble dry the items for a couple of minutes to get the wrinkles out, then hang them to finish drying
Package Included:- 1 x Scarf
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• Please contact Live Chat or click here to learn more return policy.


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Overview - Titus 3 | |
1 | Titus is yet further directed by Paul, both concerning the things that he should teach and not teach. |
10 | He is to reject obstinate heretics. |
12 | He appoints him time and place wherein he should come unto him. |
Titus 3:11 (King James Version)
Knowing that he that is such is subverted, and sinneth, being condemned of himself.


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Bring you own kayak or canoe…we have secured indoor storage for your personal craft, or simply rent from one of our Trailhead partners. Whether you're looking for a day trip or a longer excursion, our Trailhead Adventure Hosts can advise you. The Lake Superior coast is a paddler's mecca, giving you access to rugged rock headlands as well as sheltered sand and cobble beaches. There are many launch points, most often from beaches. Closer to the Inn, you can paddle the St. Mary's River that links Lake Superior to Lake Huron. You can even paddle through the Canadian Canal lift, which is open only to pleasure craft. Or try a leisurely float trip down the Goulais River. Day-trip canoe routes within the park include the Fenton-Treeby Lake route, Mijinemungshing Lake, Gamitagama Lake, and the Crescent Lake system. Canoe route maps are available through the Provincial Park's headquarters, the campground gate offices or through the Friends of Lake Superior Provincial Park interpretive centre. Rentals are also available in the park. One of our Trailhead Adventure hosts can get you started.
The Inn is a perfect family hang-out. The kids love Club Cabana's hot tubs and pools (we go swimming at least once a day), and there's always something tasty on Casey's Kid's menu. For me, I love that there's a fridge in every room, and that I can request a microwave...it makes small family meals a cinch.
- Captain Dave Conrad


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Thessaloniki Travel Guide: 538 reviews and 1,536 photos
2013, March. Traditional carnival of Sochos (Prefecture of Thessaloniki).
A collection of excellent motorcycles by collector Panagis Maratos on display at NOESIS Museum of Thechnolgy in Thessaloniki from November 2012 till January 2013
Late at night, music on the streets of Thessaloniki. Further down the road, ghosts in the shape of umbrellas. The old prison on the shore to the left, white in the artificial light. Talk of old gods while looking in the *luft-ed* dark distance.
Have you been to Thessaloniki?


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This is the picture for Series 1 till series 5:
And last is the picture for RM1 series 6th:
Hopefully next time I can stumble upon an Ali Abul RM1 CR note while getting my change at a Giant Supermarket. Wishful thinking. LoL.
Blog mostly about Malaysian banknotes, coin collection, numismatic, rare coins and more.
Hie Danny, Gary hr, i m interested into selling my 3 Series of RM1 H22 (No.444444).....my email is email@example.com if u r interested.....THX


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Benjamin® Trail BBP77 Nitro Piston® Air Pistol
Item # WX2-226400
- Google+
This item cannot ship via any of our Next Day or Second Day Express delivery methods.
You must be 18 years of age to purchase this item.
Shipping restrictions apply to this product under some jurisdictions. Known age, state and local shipping requirements are applied at checkout and may result in changes to an order.
This item cannot ship to Canada.
This item cannot ship internationally.
- Details & Specs
Benjamin® Trail Nitro Piston® Air Pistol, 600 F.P.S. fast, quieter and smoother!
Benjamin® puts its Nitro Piston® technology into the BBP77 .177 Pellet Pistol, making it exceptionally powerful and more quiet, too!
- The Nitro Piston gas piston operates with up to 70% less noise than a spring piston, smoother, and with less recoil. Velocity: Lead Pellets travel up to 525 F.P.S. and Alloy Pellets travel up to 625 F.P.S.
- Rifled steel barrel
- Fiber optic front sight and adjustable rear sight
- Tough tactical synthetic frame
- Removable cocking aid that sharpens the look and eases loading. 11mm dovetail can accept a scope. Weighs a solid 2 lbs., 8 ozs.
For new, better plinking power, get this prime Air Gun ONLINE today!
- Reviews
Benjamin Trail BBP77 Nitro Piston Air Pistol is rated out of 5 by 11.Rated 5 out of 5 by JAMES from This air pistol is quiet and powerful. It is an excellent gun. The front sight is too tall, so I had to add a longer screw in the back sight to make the gun hit the bullseye.Date published: 2014-02-22Rated 5 out of 5 by MEL/KAREN from Gun was as advertised. Hopefully with differant sight it will shoot better. Front sight was or is too high and adjustments on rear sight not enough. The trigger pull was really heavy.and the adjustment screw didn't cure the problem, However its worth fooling with being a new system.Date published: 2013-12-31Rated 5 out of 5 by DONALD from Accurate and reasonably quiet, a well made gun.Date published: 2013-12-05Rated 5 out of 5 by JEFFREY S from Fun to shoot and quite. Squirrels beware!Date published: 2013-11-11Rated 5 out of 5 by RON from The nitro piston isn't much quieter than a regular pistol. I think any break barrel gun pretty much sounds the same. I have a Gamo w/ a noise supressor and it sounds about the same as all my other guns.Date published: 2013-11-04Rated 3 out of 5 by PHILIP H from No complaints so far. I will not have the chance to rate this item better until after Christmas.Date published: 2013-10-09Rated 2 out of 5 by KYLE from Nice pellet pistol. Kinda irked to find it at Wal-Mart $10 less. Price match ?Date published: 2013-09-28Rated 5 out of 5 by ROBERT from This air pistol is a lot of fun. If there was one thing I would change, it would be a .22 caliber instead of .177. Overall it's a terrific gun and I found the sights to be easily adjustable and on target. I like that I can mount a scope on it if I choose to do so.Date published: 2013-09-11
<!--BVSEO|dz:Main_Site-en_US|sdk:v18.104.22.168-n|msg:Error: Request errored out - The remote server returned an error: (403) Forbidden. -->
- Articles & Tips
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Ruger® Safety / Shooting Glasses with Interchangeable Lenses
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Story: Jan 09, 2015
Time-lapse video shows completion of major construction on n...
CIA Exhibition: Jan 15, 2015
35th Annual Scholastic Art & Writing Exhibition
Story: Jan 08, 2015
Recognition, milestones were highlights of 2014 for CIA
Events: Jan 19, 2015 @ Museum of Contemporary Art Cleveland in Cleveland, OH
CIA Freshman Mail Art at MOCA
Social: 2 days ago via Facebook
This weekend, enjoy a winter wonderland and some very cool student work from Associate Professor Kevin Kautenburgers fall semester course, Community Works: Env...
Story: Dec 23, 2014
Printmaking project links students with seniors and their st...
CIA Exhibition: Feb 13, 2015
69th Annual Student Independent Exhibition
Story: Nov 03, 2014
CIA video shows off new Uptown Residence Hall
Events: Feb 16, 2015
CIA Campus Connection: Presidents' Day
Story: Aug 18, 2014
CIA again named to "Best in the Midwest" list
Academics . Painting . Faculty . Daniel Cuffaro
Daniel Cuffaro
Title Associate Professor/Chair of Industrial Design
Department Painting
Phone 216.421.7929
Courses Industrial Design 1.1 | Industrial Design 2.1 | Industrial Design 2.2 | Industrial Design 3.2 | Professional Practices
Dan is a designer, educator and entrepreneur. He consults in the area of industrial design, design strategy and user experience, and is an expertwitness in IP litigation. He is the Founder and Principal Designer for Abeo Design LLC, a sustainable furniture manufacturing company. He is the former Director of Design at Altitude, Inc, an award-winning product development firm in Boston, MA, and he worked as a consultant for Arthur D. Little, an international management and product development consulting firm. He has won several IDSA/IDEA awards and holds multiple patents. He has written for Innovation Magazine, The Design Management Institute Journal, and is co-author of the book 'Process, Materials and Measurements.' He has lectured in Mexico, The United Kingdom, and around the US. Dan is a co-founder of the District of Design economic development initiative aimed at positioning Northeast Ohio as a recognized center of design and innovation excellence. Dan is pursuing a Ph.D. in Management from the Weatherhead School of Management.
Degree BFA, Cleveland Institute of Art
While at CIA, you'll learn from the masters through our rigorous, world-class curriculum and connect with working professionals to begin your career.


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"These cards came out exactly how I wanted. The card stock is thicker then most cards you'd buy at a store and therefore are of higher quality in my opinion. Perfect size to fit a short Thank you note. No complaints!"
"I love this Thank You card! A simple thank you, a name and small photo....all done so perfectly! Another great product from Tiny Prints!! My favorite place to shop for all my special occasions!!!"
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"Love that I was able to get matching thank you notes at the same quality as my invites. I also liked that her name could be on it."
"I was able to was able to easily personalize this card at the bottom with all our names. The quality of the paper and envelopes was sturdy and the colors turned out exactly how I saw it online. I used these as thank you cards for our baby shower- I used a very similar Invite from Tiny Prints as well. I will be ordering our birth announcements from Tiny Prints because of the great service and quality and their variety of the cutest designs that were affordable online."


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Filesharing Now an Official Religion In Sweden
Re:Religious Prosecution of File Sharers (358 comments)
You might be right, I have no idea what other countries do to not separate religion from the state.
Announcing: Slashdot Deals - Explore geek apps, games, gadgets and more. (what is this?)
We are sorry to see you leave - Beta is different and we value the time you took to try it out. Before you decide to go, please take a look at some value-adds for Beta and learn more about it. Thank you for reading Slashdot, and for making the site better!
Re:Religious Prosecution of File Sharers (358 comments)
You might be right, I have no idea what other countries do to not separate religion from the state.
Re:Religious Prosecution of File Sharers (358 comments)
Fun fact: In Finland, the only person you should confess a murder to is a priest. Even the court can't force a priest to break the secrecy.
Re:Surprise? (368 comments)
No, lucky/successful mutations can route around certain obstacles. Also, making gene manipulations isn't evil in of itself. I don't see why you needed to make your comment so sensationalistic
Re:Less than a "PC" (349 comments)
So, when i unplug my peripherals from my computer case, it ceases to be a PC? Whoa. Radical, dude.
Ford Nucleon? (937 comments)
So, how does this differ from the old idea of http://en.wikipedia.org/wiki/Ford_Nucleon ?
Re:Old news for Finland, too (420 comments)
Seems like your Finnish ISP has the censor list in use - that's the page you land on.
For all I know, you might be some guy who tries to enforce Lex Karpela or something, so I won't give you any advice to circumvent the restriction. Sorry for that. Google around and you're bound to find it out yourself.
Old news for Finland, too (420 comments)
We've had this in Finland for a while now, too. See http://lapsiporno.info/english-2008-02-15.html for internet activist Matti Nikki's fight against the debated censorship. OpenDNS is the de facto way to circumvent this censor list. Ironically, his site is blocked by the child porn list by our Keskusrikospoliisi (federal police).
Re:Interesting spin (117 comments)
Well, you could always put ten programmers on the job and see how they all help to deliver the baby in less than 9 mythical months...
Whoops! (263 comments)
I think I accidentally the post.
Re:PostgreSQL (335 comments)
No, not when you are working on commercial, closed-source projects.
Re:PostgreSQL (335 comments)
Why do you like [PostgreSQL] so much?
The reason we use PostgreSQL instead of MySQL at work is mainly because the JDBC drivers for MySQL are GPL licensed, while Postgres' isn't.
What? No Ion cannon? (550 comments)
Next you're trying tell me that Kane will cancel his plans for the Temple of NOD?
Wasn't NIH after all (108 comments)
Whew... By reading the topic alone, I thought someone "great! someone just reinvented IRC..."
Huh, confirming theories... that's a new one (167 comments)
And I who thought that theories cannot be confirmed by real-world observations, only supported.
Re:All this sounds nice, but there's another side. (1224 comments)
I'm talking about capping the speeds at around 160-odd km/h, not choking horsepower/torque just for the fun of it.


text:
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Know how to use "fewer" and "less"? Find out.
radioactive element, long one of the "missing elements," 1948, so called by discoverers Jacob Marinsky and Lawrence Glendenin, who detected it in 1945 in the fusion products of uranium while working on the Manhattan Project. From Prometheus, who stole fire from the gods and was punished for it, + element name ending -ium. "The name not only symbolizes the dramatic way in which the element may be produced in quantity as a result of man's harnessing of the energy of nuclear fission, but also warns man of the impending danger of punishment by the vulture of war." [Marinsky and Glendenin]
promethium pro·me·thi·um (prə-mē'thē-əm)n. Symbol Pm A radioactive rare-earth element prepared by fission of uranium. Pm 145 is the longest-lived isotope with a half-life of 17.7 years. Atomic number 61; melting point 1,042°C; boiling point 3,000°C; valence 3.
(Pm), chemical element, only rare-earth metal of transition Group IIIb of the periodic table not detected in nature. Conclusive chemical proof of the existence of promethium, the last of the rare-earth elements to be discovered, was obtained (1947) by J.A. Marinsky, L.E. Glendenin, and C.D. Coryell, who isolated the radioactive isotope promethium-147 (2.7-year half-life) from uranium fission products at the research site at Oak Ridge, Tenn. Identification was firmly established by spectroscopy. Earlier investigators thought that they had found the element with atomic number 61 in naturally occurring rare earths and had prematurely called it illinium and florentium. Promethium-147 is effectively separated from the other rare-earth fission products by an ion-exchange method. Its soft beta radiation is converted to electricity in miniature batteries formed by sandwiching promethium between wafers of a semiconductor such as silicon; these batteries operate in extreme temperatures for five years. Promethium has also been prepared by slow neutron bombardment of the isotope neodymium-146; the resultant isotope, neodymium-147, decays by electron emission to promethium-147. The metal itself was first prepared (1963) by reduction of the fluoride, PmF3, with lithium


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The inherently dysfunctional "codependency dance" requires two opposite but distinctly balanced partners: the pleaser/fixer (codependent) and the take...
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Women who grew up as targets of abuse -- physical, sexual, or psychological -- or abandonment, or who witnessed sexual betrayal in their parents' marriages, tend to be drawn to partners who will re-enact the betrayal of their childhood.
The discovery of a partner's sexual compulsivity is a wake-up call. If both partners are committed to recovery, the marriage could actually be transformed into a real union marked by genuine intimacy and integrity.
In her new "Codependent No More Workbook," Beattie says that codependence recovery means being kinder to yourself, learning how to trust your instincts and speaking up for your needs.
Quick question. Are you happy? That's right, I am talking to you. You know, the one half of any relationship you create and the only part you can control: You.
When you stay neutral, you turn the decision over to the addict; you are empowering them with their own choice, and at the same time empowering yourself with a commitment to neutrality.
When the attachment with a parent is fraught with fear, the child can become overly preoccupied with getting it right for the parent rather than for themselves.
If there's anything I hate about recovery it's all the aphorisms that are bound up with it. I didn't want to hear another pithy saying. All I wanted was some iota of hope for the future.
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Hi all, Need to find descendants of Henry Derouin/Drouin and Anne Sirois. Henry Drouin/Derouin (father Thomas and Marguerite (n�e Desmarais) born about 1882, Hull, Quebec. Spouse of Anne Sirois (nothing known about dates for her) married 7 JUL 1901, Hull, Quebec (her parents were Valence Sirois and Arthemise Bourgoin. Any leads would be appreciated Yours CD Notify Administrator about this message?
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Publications (96)385.42 Total impact
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ABSTRACT: Head-to-tail backbone cyclization of proteins is a widely used approach for the improvement of protein stability. One way to obtain cyclic proteins via recombinant expression makes use of engineered Intein tags, which are self-cleaving protein domains. In this approach, pH-induced self-cleavage of the N-terminal Intein tag generates an N-terminal cysteine residue at the target protein, which then attacks in an intramolecular reaction the C-terminal thioester formed by the second C-terminal Intein tag resulting in the release of the cyclic target protein. In the current work we aimed to produce a cyclic analog of the small γ-Ec-1 domain of the wheat metallothionein, which contains six cysteine residues. During the purification process we faced several challenges, among them premature cleavage of one or the other Intein tag resulting in decreasing yields and contamination with linear species. To improve efficiency of the system we applied a number of optimizations such as the introduction of a Tobacco etch virus cleavage site and an additional poly-histidine tag. Our efforts resulted in the production of a cyclic protein in moderate yields without any contamination with linear protein species.Protein Engineering Design and Selection 10/2014; · 2.32 Impact Factor -
Article: Preface.
Journal of biological inorganic chemistry : JBIC : a publication of the Society of Biological Inorganic Chemistry. 08/2014; 19(Supplement 2):699. - [Show abstract] [Hide abstract]
ABSTRACT: The first cyclic analog of a metallothionein (MT) was prepared and analyzed by UV and (magnetic) circular dichroism spectroscopy, ESI-MS as well as NMR spectroscopy. Results reveal that the evaluated cyclic g-Ec-1 domain of the wheat MT Ec-1 retains its ability to coordinate two Zn(II) or Cd(II) ions and adopts a three-dimensional structure that is highly similar to the one of the linear wild-type form. However, the reduced flexibility of the protein backbone facilitates structure solution significantly and results in a certain stabilization of metal binding to the protein.Molecules 11/2013; 18(11):14414-14429. · 2.10 Impact Factor - [Show abstract] [Hide abstract]
ABSTRACT: Recognition and stabilization of an RNA three‐way junction by a supramolecular di‐iron(II) cylindrical complex is described by R. K. O. Sigel, B. Spingler, M. J. Hannon, E. Freisinger et al. in their Communication on page 11513 ff. This potential anti‐cancer metal‐based drug fits perfectly into the central RNA core and stabilizes this architecture in the solid state as well as under native gel conditions. (Cover picture: Joachim Schnabl.)Angewandte Chemie International Edition 10/2013; 52(44). · 11.34 Impact Factor - [Show abstract] [Hide abstract]
ABSTRACT: Erkennung und Stabilisierung einer Y‐verzweigten RNA durch einen zylinderförmigen supramolekularen Dieisen(II)‐Komplex werden von R. K. O. Sigel, B. Spingler, M. J. Hannon, E. Freisinger et al. in der Zuschrift auf S. 11727 ff. beschrieben. Der potenzielle Antikrebswirkstoff passt genau in den zentralen RNA‐Hohlraum und stabilisiert die Architektur im Festkörper ebenso wie unter nativen Gelbedingungen. (Bild: Joachim Schnabl)Angewandte Chemie 10/2013; 125(44). - [Show abstract] [Hide abstract]
ABSTRACT: Getting to the heart of it: Co-crystallization of an RNA three-way junction with a cylindrical di-iron(II)-based anti-cancer drug (green) results in π-stacking interactions between the cylinder and the central base pairs of the RNA structure. The shape, size, and cationic nature of the cylinder were found to be responsible for this perfect fit. Native gel electrophoresis studies confirmed stabilization of the RNA three-way junction by the iron(II) cylinder.Angewandte Chemie International Edition 08/2013; · 11.34 Impact Factor - [Show abstract] [Hide abstract]
ABSTRACT: Metallothioneins (MTs) are among others involved in the cellular regulation of essential Zn(II) and Cu(I) ions. However, the high binding affinity of these proteins requires additional factors to promote metal ion release under physiological conditions. The mechanisms and efficiencies of these processes leave many open questions. We report here a comprehensive analysis of the Zn(II)-release properties of various MTs with special focus on members of the four main subfamilies of plant MTs. Zn(II) competition experiments with the metal ion chelator 4-(2-pyridylazo)resorcinol (PAR) in the presence of the cellular redox pair glutathione (GSH)/glutathione disulfide (GSSG) show that plant MTs from the subfamilies MT1, MT2, and MT3 are remarkably more affected by oxidative stress than those from the Ec subfamily and the well-characterized human MT2 form. In addition, we evaluated proteolytic digestion with trypsin and proteinase K as an alternative mechanism for selective promotion of metal ion release from MTs. Also here the observed percentage of liberated metal ions depends strongly on the MT form evaluated. Closer evaluation of the data additionally allowed deducing the thermodynamic and kinetic properties of the Zn(II) release processes. The Cu(I)-form of chickpea MT2 was used to exemplify that both oxidation and proteolysis are also effective ways to increase the transfer of copper ions to other molecules. Zn(II) release experiments with the individual metal-binding domains of Ec-1 from wheat grain reveal distinct differences from the full-length protein. This triggers the question about the roles of the long cysteine-free peptide stretches typical for plant MTs.Metallomics 07/2013; · 4.10 Impact Factor - [Show abstract] [Hide abstract]
ABSTRACT: A new family of hydrazone-based nucleosides for use in metal-mediated base pairs was devised. The artificial nucleobases are derivatives of the papy ligand (papy = pyridinecarboxaldehyde-2′-pyridylhydrazone). By replacing the pendant pyridine moiety in papy by furan and thiophene, respectively, tridentate nucleosides with N, N, N-, N, N, O- and N, N, S-donor sites were obtained. As only a few transition metal complexes with pendant furan ligands have been reported, a model nucleobase for the N, N, O-donor nucleoside was synthesized. The molecular structures of its Cu2+, Ni2+, and Co2+ complexes are reported. In all complexes, only weak M–O(furan) bonding is observed. The Co2+ complex displays a pentagonal bipyramidal coordination arrangement. In general, the structures of the metal complexes suggest that the respective nucleosides can be applied in metal-mediated base pairs.Zeitschrift für anorganische Chemie 07/2013; · 1.25 Impact Factor - [Show abstract] [Hide abstract]
ABSTRACT: The plant metallothioneins (MTs) show high sequence diversity. Proposed to function mainly in metal ion homeostasis and detoxification these small cysteine-rich proteins exhibit pronounced affinities to metal ions with the electron configuration d10. Having previously studied the coordination abilities of two MTs from Cicerarietinum (chickpea) for divalent metal ions we now aim to expand the knowledge to the binding characteristics for CuI. Performing titration studies followed by UV and circular dichroism spectroscopy distinct differences between the two proteins are revealed.Zeitschrift für anorganische Chemie 07/2013; 639(8‐9). · 1.25 Impact Factor - [Show abstract] [Hide abstract]
ABSTRACT: A spring from a former copper shale mine in the area of Mansfelder Land, Germany, shows extremely high transition metal ion concentrations, i.e. 40mM Zn(II), 208μM Cu(II), 61μM As(V), and 25μM Cd(II). This makes it a challenging habitat for living organisms as they have to cope with metal ion concentrations that by far exceed the values usually observed in spring water. One of the surviving species found is the aquatic fungus Heliscus lugdunensis (teleomorph: Nectria lugdunensis). Investigation of its redox related heavy metal tolerance revealed the presence of small thiol containing compounds as well as a small metallothionein, Neclu_MT1 (MT1_NECLU: P84865). While Cd(II)-induction of metallothioneins is observed in many species, the fact that exclusively Cd(II), but not Zn(II), Cu(I), As(III) or oxidative stress can induce Neclu_MT1 protein synthesis is unparalleled. To complement the physiological studies performed in the fungus H. lugdunensis, the Cd(II) and Zn(II) binding characteristics of the recombinantly expressed protein were spectroscopically analysed in vitro aiming to demonstrate the observed Cd(II) specificity also on the protein level. Stoichiometric analyses of the recombinant protein in combination with photospectrometric metal ion titrations and (113)Cd-NMR experiments reveal that metal ion binding capacities and consequently the structures formed at physiological Neclu_MT1 concentrations differ from each other. Concluding, we describe the first solely Cd(II)-inducible metallothionein, Neclu_MT1, from H. lugdunensis, featuring a difference in the structure of the Cd(II)versus the Zn(II) metalated protein in a physiologically relevant concentration range.Journal of inorganic biochemistry 06/2013; · 3.25 Impact Factor - [Show abstract] [Hide abstract]
ABSTRACT: Metallothioneins are small cysteine-rich proteins coordinating various transition metal ions preferably with the electron configuration d(10). They are ubiquitously present in all phyla, and next to phytochelatins they represent a successful molecular concept for high-capacity metal ion binding. Recent studies showed the incorporation of sulfide ions into the metal-thiolate cluster of metallothionein 2 from the plant Cicer arietinum (cicMT2) increasing the cadmium binding capacity and stability of the cluster. In the present work, the sulfide-induced structural changes accompanying the cluster formation and the sulfide-modulated increase in cluster size are analyzed in detail with a variety of analytical and spectroscopic techniques. Evaluation of the mechanism of sulfide containing Cd(II)-thiolate cluster formation in cicMT2 reveals a strong dependence on the sequence of metal and sulfide additions for successful sulfide incorporation. To probe the general ability of metallothioneins to form sulfide containing larger metal-thiolate clusters, analogous experiments were performed with a mammalian metallothionein. The observation that the cadmium binding ability of rabbit liver MT2A was only slightly increased led to the development of a hypothesis in which the long cysteine-free linker regions present in certain plant metallothioneins may contribute to the accommodation of the respective larger cluster assemblies.Dalton Transactions 05/2013; · 4.10 Impact Factor -
Article: Cadmium in metallothioneins.
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ABSTRACT: Metallothioneins (MTs) are low-molecular-mass cysteine-rich proteins with the ability to bind mono- and divalent metal ions with the electron configuration d ( 10 ) in form of metal-thiolate clusters. MTs are thought, among others, to play a role in the homeostasis of essential Zn(II) and Cu(I) ions. Besides these metal ions also Cd(II) can be bound to certain MTs in vivo, giving rise to the perception that another physiological role of MTs is in the detoxification of heavy metal ions. Substitution of the spectroscopically silent Zn(II) ions in metalloproteins by Cd(II) proved to be an indispensable tool to probe the Zn(II) sites in vitro. In this review, methods applied in the studies of structural and chemical properties of Cd-MTs are presented. The first section focuses on the physical basis of spectroscopic techniques such as electronic absorption, circular dichroism (CD), magnetic CD, X-ray absorption, and perturbed angular correlation of γ-rays spectroscopy, as well as mass spectrometry, and their applications to Cd-MTs from different organisms. The following is devoted to the discussion of metal binding affinities of Cd-MTs, cluster dynamics, the reactivity of bound Cd(II) ions with metal ion chelators and of thiolate ligands with alkylating and oxidizing agents. Finally, a brief summary of the known three-dimensional structures of Cd-MTs, determined almost exclusively by multinuclear NMR techniques, is presented. Besides Cd-MTs, the described methods can also be applied to the study of metal binding sites in other metalloproteins.Metal ions in life sciences. 01/2013; 11:339-71. - [Show abstract] [Hide abstract]
ABSTRACT: The plant metallothionein2 from Cicer arietinum (chickpea), cic-MT2, is known to coordinate five divalent metal ions such as Zn(II) or Cd(II), which are arranged in a single metal thiolate cluster. When the Zn(II) form of the protein is titrated with Cd(II) ions in the presence of sulfide ions, an increased Cd(II) binding capacity and concomitant incorporation of sulfide ions into the cluster are observed. The exact stoichiometry of this novel cluster, its spectroscopic properties, and the significantly increased pH stability are analyzed with different techniques, including UV and circular dichroism spectroscopy and colorimetric assays. Limited proteolytic digestion provides information about the spacial arrangement of the cluster within the protein. Increasing the Cd(II) scavenging properties of a metallothionein by additionally recruiting sulfide ions might be an economic and very efficient detoxification strategy for plants.Inorganic Chemistry 12/2012; · 4.79 Impact Factor - [Show abstract] [Hide abstract]
ABSTRACT: Multinuclear and multidimensional nuclear magnetic resonance (NMR) spectroscopy is applied in our groups to gain insights into the role of metal ions for the function and structure of large biomolecules. Specifically, NMR is used i) to investigate how metal ions bind to nucleic acids and thereby control the folding and structure of RNAs, ii) to characterize how metal ions are able to stabilize modified nucleic acids to be used as potential nanowires, and iii) to characterize the formation, structure, and role of the diverse metal clusters within plant metallothioneins. In this review we summarize the various NMR experiments applied and the information obtained, demonstrating the important and fascinating part NMR spectroscopy plays in the field of bioinorganic chemistry.CHIMIA International Journal for Chemistry 10/2012; 66(10):791-7. · 1.09 Impact Factor -
Article: N-Methyl-2, 2'-Dipicolylamine Complexes as Potential Models for Metal-Mediated Base Pairs †‡
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ABSTRACT: Metal-mediated base pairs can be used to insert metal ions into nucleic acids at precisely defined positions. As structural data on the resulting metal-modified DNA are scarce, appropriate model complexes need to be synthesized and structurally characterized. Accordingly, the molecular structures of nine transition metal complexes of N-methyl-2, 2'-dipicolylamine (dipic) are reported. In combination with an azole-containing artificial nucleoside, this tridentate ligand had recently been used to generate metal-mediated base pairs (Chem. Commun. 2011, 47, 11041–11043). The PdII and PtII complexes reported here confirm that the formation of planar complexes (as required for a metal-mediated base pair) comprising N-methyl-2, 2'-dipicolylamine is possible. Two HgII complexes with differing stoichiometry indicate that a planar structure might also be formed with this metal ion, even though it is not favored. In the complex [Ag2(dipic)2](ClO4)2, the two AgI ions are located close to one another with an Ag···Ag distance of 2.9152(3) Å, suggesting the presence of a strong argentophilic interaction.Zeitschrift für anorganische Chemie 09/2012; 638(11). · 1.25 Impact Factor - [Show abstract] [Hide abstract]
ABSTRACT: 2,2'-Bipyrazine (2,2'-bpz) reacts with cis-(NH(3))(2)Pt(II) in water to give a variety of products, several of which were isolated and characterized by X-ray analysis: cis-[Pt(NH(3))(2)(2,2'-bpz-N4)(2)](NO(3))(2)·3H(2)O (1), [{cis-Pt(NH(3))(2)(2,2'-bpz-N4,N4')}(3)]-(PF(6))(5)NO(3)·7H(2)O (2a), [{cis-Pt(NH(3))(2)(2,2'-bpz-N4,N4')}(3)](BF(4))(2)-(SiF(6))(2)·15H(2)O (2b), and [{cis-Pt(NH(3))(2)(2,2'-bpz-N4,N4')}(4)]-(SO(4))(4)·22H(2)O (3). In 1, 2b, and 3 the 2,2'-bpz ligands adopt approximately C(2h) symmetries, hence the two pyrazine halves are in trans orientation, whereas in 2a all three 2,2'-bpz bridges are approximately C(2v) symmetric, with the pyrazine halves cis to each other. The topologies of the two triangular complexes 2a and 2b are consequently distinctly different, but nevertheless both cations act as hosts for anions. In 2a a PF(6)(-) and a NO(3)(-) anion are associated simultaneously with the +6 cation, whereas in 2b it is a BF(4)(-) anion and a water molecule, which are trapped in its cavity. There is no anion inclusion in case of the metallasquare 3. In principle, 3 can exist in a large number of stereoisomers, depending on the rotational states of the bridging 2,2'-bpz ligands. Isolation of a single rotamer form of 3 with C(2h) symmetric 2,2'-bpz ligands and an overall meso form is proposed to be a consequence of a highly efficient self-assembly process that starts from the precursor 1 and reaction with two cis-(NH(3))(2)Pt(II) units. This process leads to the isolated rotamer of 3 regardless of whether two cations 1 in head-head form react with two cis-(NH(3))(2)Pt(II), or whether the Δ enantiomer of the chiral head-tail form of 1 combines with its Λ enantiomer through two cis-(NH(3))(2)Pt(II) entities.Chemistry - A European Journal 08/2011; 17(38):10771-80. · 5.93 Impact Factor - [Show abstract] [Hide abstract]
ABSTRACT: The novel C2h-symmetrical tetranuclear metallacycles (III) and (IV) crystallize isotypically in the triclinic space group P with Z = 1 (single crystal XRD).ChemInform 06/2011; 42(25). - [Show abstract] [Hide abstract]
ABSTRACT: The metallothionein (MT) superfamily combines a large variety of small cysteine-rich proteins from nearly all phyla of life that have the ability to coordinate various transition metal ions, including Zn(II), Cd(II), and Cu(I). The members of the plant MT family are characterized by great sequence diversity, requiring further subdivision into four subfamilies. Very peculiar and not well understood is the presence of rather long cysteine-free amino acid linkers between the cysteine-rich regions. In light of the distinct differences in sequence to MTs from other families, it seems obvious to assume that these differences will also be manifested on the structural level. This was already impressively demonstrated with the elucidation of the three-dimensional structure of the wheat E(c)-1 MT, which revealed two metal cluster arrangements previously unprecedented for any MT. However, as this structure is so far the only one available for the plant MT family, other sources of information are in high demand. In this review the focus is thus set on any structural features known, deduced, or assumed for the plant MT proteins. This includes the determination of secondary structural elements by circular dichroism, IR, and Raman spectroscopy, the analysis of the influence of the long linker regions, and the evaluation of the spatial arrangement of the sequence separated cysteine-rich regions with the aid of, e.g., limited proteolytic digestion. In addition, special attention is paid to the contents of divalent metal ions as the metal ion to cysteine ratios are important for predicting and understanding possible metal-thiolate cluster structures.European Journal of Biochemistry 06/2011; 16(7):1035-45. · 3.16 Impact Factor - [Show abstract] [Hide abstract]
ABSTRACT: C2h-symmetrical tetranuclear metallacycles {[M(en)(CN)]4}(NO3)4 with M = PdII (4) and PtII (5) have been prepared upon reacting M(en)(CN)2 [M = PdII (1), PtII (2)] with [M(en)(H2O)2](NO3)2. Replacement of the nitrate anions of 5 by terephthalate anions yields the corresponding salt 5a. The X-ray crystal structures of 1, 4, 5, and 5a have been determined. In the metallacycles 4, 5, and 5a the four metals form almost ideal squares with average M···M distances of ca. 5.05 Å (5, 5a) and 5.08 Å (4) along the sides. As shown by 1H NMR spectroscopy, the Pt square 5 is stable in aqueous solution, whereas the Pd square 4 undergoes rearrangement reactions upon aging or the presence of other Pd species such as (bpy)PdII. Preliminary studies on the possibility of non-covalent interactions of 4 and 5 with model nucleobases in water reveal that only 5 is useful in this respect. According to the concentration-dependence 1H NMR study, there is an interaction with the purine base 9-ethyladenine, molecular details of which are unclear at this stage, however. Compound 4 is substitutionally labile and is transformed into the coordination compound 8 with 1-methylcytosine. Two more side products, produced during the various reactions carried out, were characterized by X-ray crystallography: [Pt(en)2][Pt(CN)4] (3) and [Pd(bpy)(en)](SO4)·3H2O (7).Berichte der deutschen chemischen Gesellschaft 04/2011; 2011(10). · 2.97 Impact Factor - [Show abstract] [Hide abstract]
ABSTRACT: Metallothioneins (MTs) are small cysteine-rich proteins coordinating various transition metal ions, including Zn(II), Cd(II), and Cu(I). MTs are ubiquitously present in all phyla, indicating a successful molecular concept for metal ion binding in all organisms. The plant MT E(c)-1 from Triticum aestivum, common bread wheat, is a Zn(II)-binding protein that comprises two domains and binds up to six metal ions. The structure of the C-terminal four metal ion binding β(E) domain was recently described. Here we present the structure of the N-terminal second domain, γ-E(c)-1, determined by NMR spectroscopy. The γ-E(c)-1 domain enfolds an M (2) (II) Cys(6) cluster and was characterized as part of the full-length Zn(6)E(c)-1 protein as well as in the form of the separately expressed domain, both in the Zn(II)-containing isoform and the Cd(II)-containing isoform. Extended X-ray absorption fine structure analysis of Zn(2)γ-E(c)-1 clearly shows the presence of a ZnS(4) coordination sphere with average Zn-S distances of 2.33 Å. (113)Cd NMR experiments were used to identify the M(II)-Cys connectivity pattern, and revealed two putative metal cluster conformations. In addition, the general metal ion coordination abilities of γ-E(c)-1 were probed with Cd(II) binding experiments as well as by pH titrations of the Zn(II) and Cd(II) forms, the latter suggesting an interaction of the γ domain and the β(E) domain within the full-length protein.European Journal of Biochemistry 03/2011; 16(5):683-94. · 3.16 Impact Factor
Publication Stats
918 | Citations | |
385.42 | Total Impact Points | |
Top Journals
University of Zurich
- Institut für Anorganische Chemie
Zürich, ZH, Switzerland
Technische Universität Dortmund
- Faculty of Chemistry
Dortmund, North Rhine-Westphalia, Germany
Stony Brook University
- Center for Structural Biology
Stony Brook, NY, United States
University of California, Berkeley
Berkeley, California, United States
University of Virginia
- Department of Chemistry
Charlottesville, Virginia, United States -
University of Queensland
Brisbane, Queensland, Australia


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Need to introduce no-parking for four-wheelers on more roads
Despite converting the East Veli Street into an one-way, vehicle movement is always either at snail's pace or gets choked due to haphazard parking and loading and unloading of lorries, unmindful of problems created by them to other motorists.
Taking into account the rise in number of vehicles, the police had long ago converted the two-way traffic into one-way system on East Veli Street. A major portion of the broad road had been encroached by some people who are using the public space as their private garage space by permanently parking their vehicles. Some have even covered their vehicles with tarpaulin sheets, a banker who uses the road frequently says.
Coming out with a different tale, lorry drivers say, "We are forced to park vehicles almost on the middle of the road as cars are parked close to the pavements."
"What irritates the motorists is the lorry crew who go on with their work unmindful of the traffic jam for which they are solely responsible. The other day, an emergency service vehicle took a long time to come out of the traffic snarl as the ambulance driver did not have a clue that the lorry in front was involved in loading goods. The ambulance had to reverse the vehicle and proceed to the Mission Hospital, a shopkeeper, Subburaj, in the area said.
Though a traffic police officer in the vicinity justified that the goods vehicles entered only on specific timings they were permitted to come inside the city, the problem lay in haphazard parking. "The police let drivers to park on whichever side they want thus causing bottlenecks. Parking on both sides of the road gives very little space to negotiate for other vehicles. Strict enforcement alone would put an end to this problem," a medical representative, Ravindran, said and suggested that the police should allow one-side parking only.
The double-side parking menace persists on Tamil Sangam Road also where traffic snarl is caused due to police apathy. Heavy vehicles taking a 'U' turn from North Veli Street to enter Tamil Sangam Road find it hard as goods vehicles would be usually parked at the entrance of the road during peak hours opposite the petrol bunk, a few metres away from a city bus stop as well. A traffic constable posted on the stretch uses a mobile public address system, but the drivers have scant regard to his instructions.
Like the no-parking rule for four-wheelers introduced on North Veli Street, the police should also declare East Veli Street and Tamil Sangam Road the same way and reduce the timing of entry for goods vehicles.
Meanwhile, parking space for shoppers' vehicles on East Veli Street could be allotted on Kamarajar Salai and for those coming to Tamil Sangam Road, the nearby Krishna Rao Tank Street may be an alternative spot.
Again, when the police identify a space for parking in these locations, taxis encroach, thus giving very little space for shoppers.
With Deepavali fast approaching, the police should find ways that would keep the vehicle flow as shoppers would start visiting from forenoon itself.
Keywords: East Veli Street, parking issues


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