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Updated: 08/12/2014 7:43 AM
Created: 08/12/2014 7:38 AM KSTP.com
By: Jennie Olson
A side-by-side twin home had extensive damage after a deck fire early Tuesday morning.
Crews were called to the 6600 block of Kara Drive in Eden Prairie around 2:30 a.m. on a report of a deck fire. When firefighters arrived, they found two decks fully engulfed in flames. The fire then spread to both homes, causing extensive damage.
Everyone escaped uninjured.
Crews from Edina, Chanhassen, Excelsior and Minnetonka assisted Eden Prairie. The cause has not yet been determined, and the fire is still under investigation.
String of Group Attacks Has St. Paul Police on High Alert; Businesses on Edge |
4 Wis. Teens Facing Charges After 'Sex Party' |
Delta Flight from Mpls. Lands in Vegas with Pilot Locked Out of Cockpit |
Fifth-Grader in Custody after Threat Found at Rush City School |
Report: Obscure Minnesota Speeding Law Allows Habitual Offenders to Remain on Road |

subset: commoncrawl


text:
ARMONK, N.Y., Nov. 20, 2014 /PRNewswire/ -- IBM (NYSE: IBM) today announced that it is bringing a greater level of control, security and flexibility to cloud-based application development and delivery with a single-tenant version of Bluemix, IBM's platform-as-a-service. The new platform enables developers to build ap...
By Marketwired . | Article Rating: |
November 13, 2012 08:00 AM EST | Reads: |
927 |
TORONTO, ONTARIO -- (Marketwire) -- 11/13/12 -- CornDog Apps today launched Left Lane Looey(TM), a hilarious road racing game that puts a whole new spin on road rage. Players become Left Lane Looey, a racing delivery truck driver forever frustrated by morons who coast in the left lane. Players attempt to race past, around and even through all the cars and trucks that make Looey crazy angry when he is delivering his cargo of frozen chickens. Players earn or buy coins to purchase ammo to blow up, push away or fry cars and trucks in Looey's path so that he gets to his destination before his precious cargo melts or before his head literally explodes from losing his cool.
Left Lane Looey is available today for the iPhone® and iPad® for an introductory price of $0.99 (regularly $1.99). There is also an ad-supported, free version of Left Lane Looey with all the same features as the paid version. For a limited time, players who buy the app will receive 10,000 free coins that they can use to buy ammo, speed bursts and SereniTea(TM) drinks for Looey.
"Left Lane Looey uses quirky characters and scenarios to turn the frustration of driving in traffic into something fun and funny," says Harris Korn, President of CornDog Apps. "There are a lot of great racing games, but they are all very intense and serious. Left Lane Looey is totally different in that it is as much about having a good laugh as it is about getting to the next level."
Looey crosses paths with a unique cast of characters, including Road Rage Rhoda(TM), Cell Phone Guy, Slowpoke Sally(TM), Zombie Dudes, the Hillbillies and others who are all determined to get in his way and make him lose his cool - and the game.
With Left Lane Looey, every level is a new adventure with new challenges, new characters and a great soundtrack. In Bathroom Bedlam Looey has been drinking too much soda and needs to find a bathroom - fast! For Church on Time, Looey has to make a timely delivery to a wedding or deal with a bride-to-be that quickly morphs into Bridezilla. On the Dead Man Driving level, Looey has a delivery in Zombie City. He'd better get there quick or he'll be on the menu!
"The idea for the game came to me while driving on a busy stretch of highway in Toronto surrounded by slow and careless drivers. I thought: How can I turn this into something fun?" says Korn. "Left Lane Looey is for people of all ages. Adults love it because it's witty and they can identify with Looey's frustration. Kids are attracted to the game, as they love fun racing games and think Looey and the other characters are hilarious."
Players earn coins during the game by driving over them on the road, and by getting to their destination fast. Coins can be used to buy ammo for weapons such as the ChickenZooka(TM) and Chicken Wedge(TM) to blast irritating drivers out of Looey's way. Players can also buy Speed Boosts to race through traffic, and SereniTea(TM) drinks to calm Looey's nerves and lower his Rage-o-Meter(TM) level so his head doesn't explode. Players can also buy coins in the game to get ammo and speed bursts faster.
Left Lane Looey is available today for iOS devices. The game will also be available for Android devices on Google Play and the Amazon Appstore later this month. CornDog Apps also plans to launch the game on Microsoft Surface tablets and Windows Phone 8 devices, as well as on BlackBerry PlayBook and BB10 devices.
Left Lane Looey Resources
App Store (Paid): https://itunes.apple.com/us/app/left-lane-looey-racing/id567271315?ls=1&mt=8
App Store (Free): https://itunes.apple.com/us/app/left-lane-looey-racing-free/id567309402?ls=1&mt=8
Trailer: http://www.youtube.com/watch?v=pWda7zei9rg
Facebook: http://www.facebook.com/leftlanelooey
Twitter: http://www.twitter.com/leftlanelooey
YouTube: www.youtube.com/leftlanelooey
Newsroom: http://leftlanelooey.com/newsroom
About CornDog Apps Inc.
CornDog Apps is dedicated to developing exceptional, creative, fun and challenging apps that excite and enthral players of all ages. CornDog Apps was founded by Harris Korn and is based in Richmond Hill, Ontario, Canada. Harris is also the founder of Xpressions Inc, which markets innovative productivity apps including the very successful BlackBerry Mileage Tracking App VQ Mileage Tracker (www.4tracker.com) and BB Car Locating App VQ CarFinder (www.4carfinder.com) apps. For more info, visit http://www.leftlanelooey.com.
The Left Lane Looey family of related marks, images and symbols are the exclusive properties and trademarks of CornDog Apps Inc. All other brands, product names, company names, trademarks and service marks are the properties of their respective owners.
Media Contact
Echo Communications
Michelle Magee
+1 416-471-2336
[email protected]
Published November 13, 2012 Reads 927
Copyright © 2012 SYS-CON Media, Inc. — All Rights Reserved.
Syndicated stories and blog feeds, all rights reserved by the author.
More Stories By Marketwired .
Copyright © 2009 Marketwired. All rights reserved. All the news releases provided by Marketwired are copyrighted. Any forms of copying other than an individual user's personal reference without express written permission is prohibited. Further distribution of these materials is strictly forbidden, including but not limited to, posting, emailing, faxing, archiving in a public database, redistributing via a computer network or in a printed form.
Jan. 28, 2015 11:15 AM EST Reads: 4,634 |
By Elizabeth White "The age of the Internet of Things is upon us," stated Thomas Svensson, senior vice-president and general manager EMEA, ThingWorx, "and working with forward-thinking companies, such as Elisa, enables us to deploy our leading technology so that customers can profit from complete, end-to-end solutions."
ThingWorx, a PTC® (Nasdaq: PTC) business and Internet of Things (IoT) platform provider, announced on Monday that Elisa, Finnish provider of mobile and fixed broadband subscriptions, will deploy ThingWorx® platform technology to enable a new Elisa IoT service in Finland and Estonia. Jan. 28, 2015 11:00 AM EST Reads: 2,429 |
By Elizabeth White Advanced Persistent Threats (APTs) are increasing at an unprecedented rate. The threat landscape of today is drastically different than just a few years ago. Attacks are much more organized and sophisticated. They are harder to detect and even harder to anticipate. In the foreseeable future it's going to get a whole lot harder. Everything you know today will change. Keeping up with this changing landscape is already a daunting task. Your organization needs to use the latest tools, methods and expertise to guard against those threats. But will that be enough? In the foreseeable future attacks w... Jan. 28, 2015 11:00 AM EST Reads: 4,641 |
By Elizabeth White Building low-cost wearable devices can enhance the quality of our lives. In his session at Internet of @ThingsExpo, Sai Yamanoor, Embedded Software Engineer at Altschool, provided an example of putting together a small keychain within a $50 budget that educates the user about the air quality in their surroundings.
He also provided examples such as building a wearable device that provides transit or recreational information.
He then reviewed the resources available to build wearable devices at home including open source hardware, the raw materials required and the options available to power s... Jan. 28, 2015 11:00 AM EST Reads: 3,603 |
By Elizabeth White The Internet of Things is not new. Historically, smart businesses have used its basic concept of leveraging data to drive better decision making and have capitalized on those insights to realize additional revenue opportunities. So, what has changed to make the Internet of Things one of the hottest topics in tech?
In his session at @ThingsExpo, Chris Gray, Director, Embedded and Internet of Things, discussed the underlying factors that are driving the economics of intelligent systems. Discover how hardware commoditization, the ubiquitous nature of connectivity, and the emergence of Big Data a... Jan. 28, 2015 10:45 AM EST Reads: 4,062 |
By Elizabeth White "There is a natural synchronization between the business models, the IoT is there to support ," explained Brendan O'Brien, Co-founder and Chief Architect of Aria Systems, in this SYS-CON.tv interview at the 15th International Cloud Expo®, held Nov 4–6, 2014, at the Santa Clara Convention Center in Santa Clara, CA. Jan. 28, 2015 10:45 AM EST Reads: 4,711 |
By Liz McMillan From telemedicine to smart cars, digital homes and industrial monitoring, the explosive growth of IoT has created exciting new business opportunities for real time calls and messaging.
In his session at @ThingsExpo, Ivelin Ivanov, CEO and Co-Founder of Telestax, shared some of the new revenue sources that IoT created for Restcomm – the open source telephony platform from Telestax.
Ivelin Ivanov is a technology entrepreneur who founded Mobicents, an Open Source VoIP Platform, to help create, deploy, and manage applications integrating voice, video and data. He is the co-founder of TeleStax, a... Jan. 28, 2015 10:45 AM EST Reads: 4,927 |
By Liz McMillan The Internet of Things will greatly expand the opportunities for data collection and new business models driven off of that data. In her session at @ThingsExpo, Esmeralda Swartz, CMO of MetraTech, discussed how for this to be effective you not only need to have infrastructure and operational models capable of utilizing this new phenomenon, but increasingly service providers will need to convince a skeptical public to participate.
Get ready to show them the money! Jan. 28, 2015 10:30 AM EST Reads: 4,587 |
By Elizabeth White We certainly live in interesting technological times. And no more interesting than the current competing IoT standards for connectivity. Various standards bodies, approaches, and ecosystems are vying for mindshare and positioning for a competitive edge. It is clear that when the dust settles, we will have new protocols, evolved protocols, that will change the way we interact with devices and infrastructure. We will also have evolved web protocols, like HTTP/2, that will be changing the very core of our infrastructures. At the same time, we have old approaches made new again like micro-services... Jan. 28, 2015 10:30 AM EST Reads: 3,900 |
By Elizabeth White Disruptive macro trends in technology are impacting and dramatically changing the "art of the possible" relative to supply chain management practices through the innovative use of IoT, cloud, machine learning and Big Data to enable connected ecosystems of engagement. Enterprise informatics can now move beyond point solutions that merely monitor the past and implement integrated enterprise fabrics that enable end-to-end supply chain visibility to improve customer service delivery and optimize supplier management. Learn about enterprise architecture strategies for designing connected systems tha... Jan. 28, 2015 10:00 AM EST Reads: 4,795 |
By Elizabeth White The Internet of Things is a misnomer. That implies that everything is on the Internet, and that simply should not be - especially for things that are blurring the line between medical devices that stimulate like a pacemaker and quantified self-sensors like a pedometer or pulse tracker. The mesh of things that we manage must be segmented into zones of trust for sensing data, transmitting data, receiving command and control administrative changes, and peer-to-peer mesh messaging.
In his session at @ThingsExpo, Ryan Bagnulo, Solution Architect / Software Engineer at SOA Software, focused on desi... Jan. 28, 2015 10:00 AM EST Reads: 3,749 |
By Liz McMillan Today's enterprise is being driven by disruptive competitive and human capital requirements to provide enterprise application access through not only desktops, but also mobile devices. To retrofit existing programs across all these devices using traditional programming methods is very costly and time consuming – often prohibitively so.
In his session at @ThingsExpo, Jesse Shiah, CEO, President, and Co-Founder of AgilePoint Inc., discussed how you can create applications that run on all mobile devices as well as laptops and desktops using a visual drag-and-drop application – and eForms-buildi... Jan. 28, 2015 10:00 AM EST Reads: 4,230 |
By Pat Romanski "For over 25 years we have been working with a lot of enterprise customers and we have seen how companies create applications. And now that we have moved to cloud computing, mobile, social and the Internet of Things, we see that the market needs a new way of creating applications," stated Jesse Shiah, CEO, President and Co-Founder of AgilePoint Inc., in this SYS-CON.tv interview at 15th Cloud Expo, held Nov 4–6, 2014, at the Santa Clara Convention Center in Santa Clara, CA. Jan. 28, 2015 09:30 AM EST Reads: 3,508 |
By Liz McMillan Things are being built upon cloud foundations to transform organizations. This CEO Power Panel at 15th Cloud Expo, moderated by Roger Strukhoff, Cloud Expo and @ThingsExpo conference chair, addressed the big issues involving these technologies and, more important, the results they will achieve. Rodney Rogers, chairman and CEO of Virtustream; Brendan O'Brien, co-founder of Aria Systems, Bart Copeland, president and CEO of ActiveState Software; Jim Cowie, chief scientist at Dyn; Dave Wagstaff, VP and chief architect at BSQUARE Corporation; Seth Proctor, CTO of NuoDB, Inc.; and Andris Gailitis, C... Jan. 28, 2015 09:00 AM EST Reads: 4,128 |
By Liz McMillan Recurring revenue models are great for driving new business in every market sector, but they are complex and need to be effectively managed to maximize profits. How you handle the range of options for pricing, co-terming and proration will ultimately determine the fate of your bottom line.
In his session at 15th Cloud Expo, Brendan O'Brien, Co-founder at Aria Systems, session examined:
How time impacts recurring revenue
How to effectively handle customer plan changes
The range of pricing and packaging options to consider Jan. 28, 2015 09:00 AM EST Reads: 4,167 |
By Elizabeth White The Industrial Internet revolution is now underway, enabled by connected machines and billions of devices that communicate and collaborate.
The massive amounts of Big Data requiring real-time analysis is flooding legacy IT systems and giving way to cloud environments that can handle the unpredictable workloads.
Yet many barriers remain until we can fully realize the opportunities and benefits from the convergence of machines and devices with Big Data and the cloud, including interoperability, data security and privacy. Jan. 28, 2015 09:00 AM EST Reads: 4,135 |
By Liz McMillan The 3rd International Internet of @ThingsExpo, co-located with the 16th International Cloud Expo - to be held June 9-11, 2015, at the Javits Center in New York City, NY - announces that its Call for Papers is now open.
The Internet of Things (IoT) is the biggest idea since the creation of the Worldwide Web more than 20 years ago. Jan. 28, 2015 07:00 AM EST Reads: 10,257 |
By Pat Romanski The Internet of Things is tied together with a thin strand that is known as time. Coincidentally, at the core of nearly all data analytics is a timestamp.
When working with time series data there are a few core principles that everyone should consider, especially across datasets where time is the common boundary.
In his session at Internet of @ThingsExpo, Jim Scott, Director of Enterprise Strategy & Architecture at MapR Technologies, discussed single-value, geo-spatial, and log time series data.
By focusing on enterprise applications and the data center, he will use OpenTSDB as an example t... Jan. 28, 2015 02:45 AM EST Reads: 4,746 |
By Liz McMillan Scott Jenson leads a project called The Physical Web within the Chrome team at Google. Project members are working to take the scalability and openness of the web and use it to talk to the exponentially exploding range of smart devices. Nearly every company today working on the IoT comes up with the same basic solution: use my server and you'll be fine. But if we really believe there will be trillions of these devices, that just can't scale. We need a system that is open a scalable and by using the URL as a basic building block, we open this up and get the same resilience that the web enjoys. Jan. 28, 2015 02:00 AM EST Reads: 4,689 |
By Liz McMillan Code Halos - aka "digital fingerprints" - are the key organizing principle to understand a) how dumb things become smart and b) how to monetize this dynamic.
In his session at @ThingsExpo, Robert Brown, AVP, Center for the Future of Work at Cognizant Technology Solutions, outlined research, analysis and recommendations from his recently published book on this phenomena on the way leading edge organizations like GE and Disney are unlocking the Internet of Things opportunity and what steps your organization should be taking to position itself for the next platform of digital competition. Jan. 28, 2015 02:00 AM EST Reads: 4,660 |


text:
Show-Concept.ch Invests in JBLâs VTX Line Arrays and Crown I-Tech HD Amplifiers
After running JBLâs VERTEC® in its inventory, the company has now stepped into the future, placing an order for 16 JBL VTX V20âs and eight each of the new VTX S25 subs and have also added four Crown I-Tech 12000HD and 12 Crown I-Tech 4x3500HD amplifiers to its existing Crown I-Tech HD inventory.
âThe main reason for purchasing a new system was to take a step forward in tour soundâand of course to be up to date,â stated Cyril Schmuki, audio engineer for show-concept.ch âadding that its new front line PA system will be backed-up by other systems, including three complete VERTEC rigs.
VTX V20 features the advanced technology of VTX V25 in a smaller format and the high power density of this 3-way system is complemented by a new ASM suspension system that provides efficient transport, fast setup and precise configuration. Utilizing Differential Drive⢠technology and a small format version of the revolutionary D2 dual compression driver, the integrated V5 presets fully realize the processing capability of the Crown I-Tech HD amplifiers.
âThe handling and the rigging system were what we especially liked,â added Schmuki. âThis and the new JBL HiQnet Performance Manager⢠software were the main advantages.â
The sale was supported by Dr. W.A. Guentherâs Director of Sales Felix Alpstaeg, and Application & Project Engineer, Jaromir Ott. Already familiar with JBL VERTEC and Performance Manager for system configuration, monitoring and control, the production company is nevertheless planning advanced training in conjunction with Dr. W.A. Guenther for next yearâs festival season.
Overall Schumuki couldnât be more pleased with his new JBL and Crown powered rig, âWe are delighted with the VTX V20, itâs a pleasure to work with. Iâve never heard a system which is so precise over the whole frequency range; and what is absolutely astonishing is to stand behind the array, because itâs just so quiet.â
HARMAN (www.harman.com) designs, manufactures and markets premier audio, visual, infotainment and integrated control solutions for the automotive, consumer and professional markets. With leading brands including AKG®, Harman Kardon®, Infinity®, JBL®, Lexicon® and Mark Levinson ®, the Company is admired by audiophiles, musicians and the entertainment venues where they perform. More than 25 million automobiles on the road today are equipped with HARMAN audio and infotainment systems. HARMAN has a workforce of approximately 16,000 people across the Americas, Europe, and Asia and reported sales of $5.3 billion for the twelve months ended June 30, 2014.
Related Topics: Audio, Loudspeakers, New Products, News, Video
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Brittany is a director of the Toxic Free Foundation and created the first ever Toxic Free Certification Program. Weekly, Brittany publishes the Toxic Free Blog and provides coaching to over 10,000 families in the United States alone. She is the author of a Toxic Free educational series and co-author of several Toxic Free learning programs. Brittany is also an award winning author.
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Latest TV News, Reviews & Listings for Central New York
Tom Kenny, the voice of 'SpongeBob,' recalls growing up (sort of) in East Syracuse
By Geoff Herbert | email@example.com
January 08, 2015, 11:17AM
"Since I spend my days acting like a hyperactive child, you can't really say I grew up," Kenny says. Full story »
Astrophycisist Neil deGrasse Tyson to host new late-night talk show
By The Associated Press
January 08, 2015, 5:27AM
Tyson is known for mixing pop culture with science on his podcast and Twitter. Full story »
Netflix announces premiere dates for 'Daredevil' and three more new series
By The Associated Press
January 07, 2015, 3:56PM
The first Netflix original series, "House of Cards," debuted two years ago. Full story »
Finger Lakes town (and a winery) featured on next episode of HGTV's 'House Hunters'
By Don Cazentre | firstname.lastname@example.com
January 07, 2015, 3:14PM
Couple visits Fox Run Vineyards while considering which house to buy on reality show. Full story »
Verizon FiOS customers in Syracuse get Fox back on TV after dispute is resolved
By Geoff Herbert | firstname.lastname@example.com
January 07, 2015, 12:54PM
Fox 68 and My43 were removed from Verizon FiOS for more than four days. Full story »
Phylicia Rashad defends Bill Cosby: 'Forget these women' accusing him of rape
By Geoff Herbert | email@example.com
January 07, 2015, 9:18AM
It's "The Cosby Show" wife's first public statement since new allegations came to light. Full story »
A slimmed-down 'American Idol' returns for season 14 on Wednesday
By The Associated Press
January 06, 2015, 7:00PM
Starting in March, "Idol" will be a two-hour show just once a week. Full story »
'The Bachelor' recap: Crazy contestants, SU alumna draws Kim K comparisons, more
By Geoff Herbert | firstname.lastname@example.com
January 06, 2015, 8:30AM
Ashley Iaconetti is a Newhouse grad who previously interned at NewsChannel 9. Full story »
Mike Huckabee leaving Fox News, considering running for president in 2016
By The Associated Press
January 05, 2015, 4:25AM
The former Arkansas governor said he expects to make a decision in the spring. Full story »
Verizon FiOS says Syracuse TV station owner demands 'shockingly higher fees'
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January 04, 2015, 6:53AM
Verizon FiOS customers lost two TV stations on Saturday after a contract deadline passed. Full story »
Verizon FiOS customers lose two Syracuse TV stations due to contract dispute
By Geoff Herbert | firstname.lastname@example.com
January 03, 2015, 7:00AM
A video says Bristlecone Broadcasting is "demanding millions more in extra fees." Full story »
Watch Billy Joel receive the Library of Congress Gershwin Prize tonight on WCNY
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January 02, 2015, 12:54PM
Joel was awarded the prize at a ceremony in Washington, D.C. in November. Full story »
Alec Baldwin's wife pregnant with another grandkid for CNY's Carol M. Baldwin
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January 01, 2015, 1:35PM
There's also speculation Stephen Baldwin's daughter is dating Justin Bieber. Full story »
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Police raid Nanakuli cockfighting ring
Police raided a cockfighting ring in Nanakuli shortly before noon yesterday, citing four men for alleged cruelty to animals charges.
Full StoryComments
1 - 4 of 4 Comments
Last updated Apr 12, 2012
May 18, 2010
Just legalize it already, damn think about this all you people who are against cockfighting and says it is animal cruelty here is a question for you!!! when you bust a chicken fight what do you guys do with the roosters after you confiscate them? A---you let them loose in the wild
B---you chope em up and make chicken long rice C---you kill them because you say that you can not do nothing with them. THE ANSWER is..... TAH DUH...C----so who is more cruel now at least by fighting in the ring the rooster has a chance to live but when you guys take em and just kill em they have no chance at all GOOD JOB ANIMAL ACTIVIST you all need to get a life and realize what you are doing is even more cruel. |
May 20, 2010
I am against cockfighting because I live near dumbasses that have them. The roosters crow all night, and their daily activities draw all sorts of punks that have no jobs, don't go to school, deal and do drugs all day, and blast rap music from thier POS Hondas. They let roosters run around and when the guys are caught in your yard they say they were just chasing their rooster. More likely looking for stuff to steal, I've caught them red-handed, stealing chicken feed. They have absolutely zero respect, parking on peoples' lawns and blocking driveways, it's like they dare people to say anything to them. It's the criminal element that has no respect for their neighbors, so I will and have immediately reported any chicken fights that I see or know about. What's nice is that now it's a federal offense and you brought in on yourselves. I keep chickens myself but I don't allow it to bother anyone. You won't police yourselves so suffer the consequences.
Apr 12, 2012
stealing chix feed from somebody's yard. that's sad. they shouldn't have birds in the first place! |
Apr 12, 2012
Let the damn braddahs fight their roosters. Jesus what's the big deal? Guess the police can't find any REAL crimes to solve.
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Spain's Present is Obama America's Future
Although Spain is not as bad off as Greece, a look at Spain's current economic reality reveals the future of America under four more years of Barrack Obama.
Despite European commitments to inject up to 100 billion euros into Spain's faltering banking system, bank withdrawals have accelerated.: During July, doubts about Spain's financial system caused Spaniards to withdraw a record $94 billion from their banks. : : That amounts to 7 percent of Spain's total domestic economic output.
Capital flight is beginning to include educated entrepreneurs who are fed up with scant job opportunities in a country with a 25 percent unemployment rate.: Statistics show that in a twelve month span 30,000 Spaniards have registered to work in Britain, an increase of 25 percent over 2011 levels.
Since taking office in 2009, Obama has aggressively promoted a "green energy" agenda modeled after the one pursued by Spain.: The assumption that pursuing the same agenda will bring about different results is based on no known empirical data.
If American voters are willing to accept 25 percent unemployment as the new normal and can live with a combination of major investment capital flight and disappearing employment opportunities, then Obama's re-election is a foregone conclusion.
However, if Americans prefer to see a resurgence of American economic might through development of its domestic energy resources, and the millions of jobs that activity will create, then Obama's days in the White House are numbered.
Also see...
Welcome to the 6th annual 20 hottest conservative new media list Men of 2014 edition. I gave the judges one rule: Set personality aside and pick the men who you...
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Thousands Of Climastrologers Freeze Their Buns Off Protesting Keystone Pipeline
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US 5173209 A Abstract A composition of at least one lithium cycloalkyl imide of the formula: ##STR1## wherein R and R' each represent a hydrogen or alkyl of 1 to 4 carbon atoms, and x and y are integers of 1 to 3.
Claims(4) 1. An ether-free reagent composition which comprises a lithium cycloalkylimide of the formula: ##STR9## wherein R and R1 are each selected from the group consisting hydrogen and alkyl of 1 to 4 carbon atoms, and
a hydrocarbon solvent, said reagent composition having a concentration greater than about 1.6 M. 2. The reagent composition of claim 1 wherein said solvent is selected from the group consisting of benzene, toluene, ethyl benzene, cumene, xylene and diisopropyl benzene.
3. The reagent composition of claim 1 wherein said solvent is selected from the group consisting of cyclopentane and cyclohexane.
4. The reagent composition of claim 1 wherein said lithium cycloalkylimide is lithium hexamethyleneimide.
Description This application is a continuation-in-part application of application Ser. No. 374,740 filed Jun. 30, 1990, entitled "Stable Lithium Amides and Reagent Compositions Thereof" and of application Ser. No. 521,743, filed May 10, 1990, entitled "Stabilized Lithium Acetylide and Reactions Therewith" of Smith et al., now U.S. Pat. No. 5,068,368. The present invention relates to stable lithium cycloalkylimides and reagent compositions which comprise these compounds. More particularly, the invention concerns the preparation of stable solutions of lithium cycloalkylimides and to reagent compositions thereof containing increased concentrations of the lithium cycloalkylimides in solution. The reagent compositions are capable of producing increased yields in subsequent reactions such as the formation of lithium acetylide which may be used in simultaneous or subsequent reactions with aldehydes and ketones, and the direct metalation of ketones followed by subsequent reactions. Lithium amides, for example, lithium diisopropylamide, are widely used as reagents for reactions with aldehydes and ketones in the preparation of pharmaceuticals and specialty chemicals. Lithium amides are particularly useful for the preparation of lithium acetylide compounds which are used to form acetylenic substituted organic compounds such as steroid and fragrance intermediates. In order to form the lithium acetylide, acetylene is reacted with a lithium amide, such as lithium diisopropylamide just prior to reacting the newly formed lithium acetylide with the ketone or other reagent in the same reactor. All of the steps in the prior art are performed below 0�C. Usually, it is necessary to add an ether cosolvent such as tetrahydrofuran (THF) at this point to increase the limited solubility of the reagents and the subsequently formed lithium salt of the product from the reaction with the ketone. The lithium amide may be added as a preformed solution or it may be formed in the same reactor by reacting an alkyllithium such as n-butyllithium with an amine such as diisopropyl amine. In either case, the lithium amide usually exhibits lower solubility than desired for maximum reactivity and yet there is a need to minimize the amount of solvents employed. In order to increase the concentration of the lithium amide in the preformed solutions, ethers such as tetrahydrofuran and/or complexing agents such as organomagnesium compounds, which are also stabilizing agents, have been added to increase the solubility of the lithium amide in solution. The presence of the ethers makes these solutions unstable and they decompose on standing in storage. The presence of magnesium compounds in the reaction and subsequent workup is undesirable because the possibility of lower reactivity and yields of desired products plus the more difficult workup due to the presence of the formed magnesium oxide and hydroxide which are highly insoluble and formed during washing. Additionally, when tetrahydrofuran is used as the solvent it has been found necessary to limit the amount of tetrahydrofuran to no more than one mole for each mole of lithium amide in order to minimize degradation of the system. This also produces problems in recovering mixed solvents. Aromatic solvents were not utilized as the solvent for preparing preformed lithium amide solutions in the past because the increased solubility was not appreciated and the belief that there would result a degradation of the organo lithium in an aromatic solution. It has been found that mixed amines provide higher solubilities in alyshatis solvents. Monolithium acetylide is a valuable reagent for the preparation of ethynyl carbinols and terminal acetylenes. Monolithium acetylide has been used to ethynylate 17-keto steroids unsubstituted in the C16 position. However, it was previously necessary to utilize only tetrahydrofuran (THF) or other ethereal solvents to prepare the reagent. Such solvents cause problems in commercial scale processes. It is well known to prepare 17-keto, 3-keto or 3, 17-diketo steroids with substituents on the A, B or C rings, see for example U.S. Pat. Nos. 3,166,551; 3,065,146; 3,516,991; 3,629,298 and 4,216,159. M. M. Midland in J. Org. Chem. 40, 2250 (1975) reported reacting n-butyllithium with acetylene in THF at low temperatures (<-70� C.) and in dilute solutions to produce monolithium acetylide. (See Fieser and Fieser, Reagents for Organic Synthesis, Vol. 1, Wiley, New York, 1967, p. 573). Midland found that warming or attempting to generate a more concentrated solution resulted in disproportionation to the insoluble dilithium acetylide and acetylene. This disproportionation is an important disadvantage and occurs in the absence of a complexing agent. (See Corbellini et al, Chem. Ind. (Milan) 42, 251 (1960) and Chem. Abstr. 54, 19250 (1960)). To reduce or prevent the disproportionation, the monolithium acetylide is usually prepared in liquid ammonia, which presumably services as an appropriate complexing agent. An amine such as ethylenediamine can also be used to stabilize monolithium acetylide. Ethylenediamine, while stabilizing monolithium acetylide to the point it can be sold commercially, actually reduces the reactivity of the reagent to the point that it is not useful for many ethynylation procedures. U.S. Pat. No. 4,005,562 discloses the use of monolithium acetylide to ethynylate 17-keto steroids unsubstituted in the C16 position. The monolithium acetylide was prepared by bubbling acetylene into THF held at -70� C. under anhydrous conditions followed by addition of butyllithium. The 17-keto steroid was added to the unstabilized monolithium acetylide and the mixture stirred for 3 hours at -70� C. to produce the 17α-ethynyl-17β-hydroxy steroid product. U.S. Pat. No. 4,320,236 discloses the use of a monolithium acetylide-ammonium complex (which is well known to those skilled in the art) to ethynylate ketones at below about -30� C. The examples in U.S. Pat. No. 4,320,236 disclose ethynylation reaction temperatures of -50� to 10� C. The unsaturated acyclic ketones ethynylated in U.S. Pat. No. 4,320,236 are very reactive whereas the monolithium acetylide reagent produced by the process of the present invention is reactive with steroidal 17-ketones such as cyclopentanones, that are ordinarily much less reactive. U.S. Pat. No. 4,526,720 to Van Rheenen et al discloses a one pot and a two pot process for preparing monolithium acetylide. Each reaction involves contacting an organolithium compound with a solution containing acetylene in the presence of a stabilizing amine. The amine reacts with the organolithium compound to form a lithium complex and/or a corresponding lithium amide which is subsequently reacted with acetylene. U.S. Pat. No. 4,595,779 to Morrison et al relates to a composition and method for preparing lithium diisopropylamide by the reaction of lithium metal and diisopropylamine in tetrahydrofuran and an inert liquid hydrocarbon cosolvent including styrene as an electron carrier. However, the use of tetrahydrofuran is considered essential in the preparation when utilizing lithium metal. The article of Keith Smith entitled "Lithiation and Organic Synthesis", Chemistry In Britain. Jan. 1982, pages 29-32, discloses the preparation of lithium dialkyl amides for use as lithiating agents by the reaction of organolithium reagents in aliphatic hydrocarbon solvents. U.S. Pat. No. 3,542,512 to Honeycutt relates to the preparation of lithium amide by contacting lithium metal with liquid ammonia and then heating the mixture at a temperature about 150� degrees C. in an inert liquid medium. The inert liquid medium includes aromatic compounds having a boiling point above 200 degrees C. It is an object of the present invention to provide novel lithium cycloalkylimides reagent compositions having greater amounts of the lithium cycloalkylimides in solution. It is a further object of the invention to provide a process for preparing lithium cycloalkylimides in higher concentrations in solution and in a solvent which is stable. It is a yet still further object of the invention to prepare lithium cycloalkylimides in situ to utilize the resulting mixture to prepare lithium acetylide and optionally carry on further reactions with aldehydes or ketones. It is still another object of the invention to prepare novel lithium cyclohexamethylenimine and reagent compositions thereof. It is yet another object of the invention to provide a novel mixture of lithium compounds for use in a reagent composition for the preparation of lithium acetylide in high yields. In accordance with one embodiment of the invention it has been found that soluble lithium cycloalkylimides could be prepared in high concentrations by the reaction of in a suitable an alkyl lithium compound with a cycloalkylimine in a suitable organic solvent. More particularly, the invention is concerned with the preparation of lithium cycloalkylimides by the step of reacting an alkyl lithium compound of 1 to 8 carbon atoms with an imine of the formula: ##STR2## wherein R and R1 are each selected from the group consisting of hydrogen and alkyl of 1 to 4 carbon atoms, and x and y are each an integer of 1 to 3. In accordance with another embodiment of the invention there is prepared lithium acetylide by the use of at least one lithium cycloalkylimine in a solvent, preferably comprising an aromatic hydrocarbon, in a reaction with acetylene. In a still further embodiment of the invention, the lithium acetylide is reacted simultaneously or subsequently with a carbonyl-containing compound, such as an aldehyde or ketone to form the corresponding hydroxyl carbonyl compound. The reactions can all take place in the same reaction vessel with a suitable solvent for subsequent reactions without the need of any ethers, extra amines or stabilizers other than those formed from the lithium cycloalkylimine. Surprisingly, the reaction to form the carbonyl compounds may be at higher temperatures, for example, at ambient temperatures, preferably between 0� and 20� C. when prepared in an aromatic solvent. The reactions involved in the processes of the invention are as follows: ##STR3## wherein R2 is an alkyl group of 1 to 8 carbon atoms, and R, R1, x and y are as hereinbefore, defined. ##STR4## wherein R, R1 x and y are as hereinbefore defined, ##STR5## wherein R" can be hydrogen or lower alkyl (C1 -C4), R'" can be hydrogen, or any aliphatic, alicyclic or aromatic hydrocarbon group which can be unsubstituted or substituted, or R" and R"' together with the carbon to which they are attached is a steroid. The hydrolysis of the ethynyl compound can be effected in a known manner, e.g., with dilute sulfuric acid, acetic acid, water, ammonium chloride, and the like to form the corresponding ethynyl carbinol. The present invention is concerned with novel lithium cycloalkylimides, lithium dimethylaminopropylamide, reagent compositions containing these compounds, and similar compounds, their use in the preparation ethynyl carbinol compounds, and for direct metalation reactions. More particularly, the invention relates to a lithium cycloalkylimine of the formula: ##STR6## wherein R1 and R2 are each hydrogen or alkyl of 1 to 4 carbon atoms, and x and y are each an integer of 1 to 3. The most preferred compound is lithium hexamethyleneimide. These compounds possess high solubility in most organic solvents. However, they are most advantageously utilized in an aromatic solvent. The compounds can be used alone or in combination with a lithium dialkylamide such as lithium dimethylaminopropylamide to prepare lithium acetylide without isolation. The same reaction mixture can be used for subsequent reactions with aldehydes and ketones which after hydrolysis yields a compound of the formula: ##STR7## wherein R" is hydrogen or lower alkyl (C1 -C4). R'" is hydrogen, or any aliphatic, alicyclic or aromatic hydrocarbon group which is unsubstituted or substituted, or R" and R"' together with the carbon to which they are attached is a steroid. Among the preferred groups are alkyl, alkenyl, alkynyl, cycloalkyl, cycloalkenyl, aryl, aryl-lower alkyl, aryl-lower alkenyl, cycloalkyl-lower alkyl and cycloalkenyl-lower alkenyl. In accordance with another embodiment of the invention, the aforementioned aryl, cycloalkyl or cycloalkenyl groups can be unsubstituted or substituted in at least one position with one or more substituents selected from the group consisting of lower alkyl, lower alkoxy, halo, trifluoromethyl, amino, hydroxyl and carboxyl. The term "aliphatic hydrocarbon" includes open chain aliphatic and cycloaliphatic hydrocarbons as well as hydrocarbons containing both aliphatic and cycloaliphatic moieties. The term alkenyl designates alkenyl groups having at least one olefinic double bond and containing from 2 to 20 carbon atoms such as vinyl, allyl, 5-octenyl, 2,3-dimethyl-4-octenyl, 8-hexadecenyl, 5,6-dimethyl-7-hexadecenyl, 5,6-dimethyl-7-hexadecenyl, etc. The term alkynyl includes alkynyl groups having at least one triple bond and containing from 3 to 20 carbon atoms such as propynyl, 3,7-dimethyl-5-octynyl, 6-heptadecynyl, etc. Cycloalkyl groups which are designated by R" and R"' generally contain from 3 to 8 carbon atoms, such as cyclopropyl, cyclohexyl and the like. The cycloalkenyl groups contain from 3 to 8 carbon atoms, such as cyclopropenyl, cyclohexenyl, etc. The term "aryl" includes aromatic, monocyclic or bicyclic residues which can, if desired, contain a hetero atom in the ring. Among the preferred hetero atoms are sulfur, oxygen and nitrogen. The preferred aromatic residues are phenyl, naphthyl, pyridinyl, and the like. The term "lower alkyl" includes saturated aliphatic hydrocarbon radicals containing from 1 to 7 carbon atoms such as methyl, ethyl, n-propyl, isopropyl, etc. The term "lower alkenyl" designates lower alkenyl radicals containing from 2 to 7 carbon atoms such as vinyl, allyl, etc. The term "lower alkoxy" includes lower alkoxy radicals containing from 1 to 7 carbon atoms such as methoxy, isopropoxy, ethoxy, etc. The aromatic solvents which may be used in the present invention include benzene, toluene, ethyl benzene, cumene, xylene diisopropyl benzene, and the like. Other solvent hydrocarbons such as cycloalkanes, more particularly, cyclopentane, cyclohexane, or the like, or aliphatic hydrocarbons such as hexane, heptane, or the like. It is also understood that tetrahydrofuran and other ethers may be used or added to the solvent, although, this is not preferred. The solvents may be used alone or in admixture with each other. A preferred mixture is toluene and cyclohexane. Advantageously, the reactions to prepare the lithium acetylide and the subsequent reactions can be performed in the same reaction vessel without separation and in the same solvent. It is well known that allowing the monolithium acetylide to stand even at -78� C. for 6 hours with an atmosphere of acetylene may lower the yield 10%. In the past, a stabilizing amine was utilized to form a complex with the monolithium acetylide but the additional amine is not necessary in the present invention. Also, the presence of mixed solvents as proposed in the prior art is not essential since it makes recovery of the solvent and the product after each reaction more difficult. Examples of suitable compounds which may be used in the invention to prepare the corresponding ethynylcarbinol include: ______________________________________Cyclopentanone AcetaldehydeCyclohexanone 4-Androstene-3,17-dioneCycloheptanone 4-Androstene-17-oneAcetone Isophorone2-Butanone Mesityl oxide3-Pentanone Benzal acetoneFenchone Dibenzal acetone2- or 3-Octanone AcetophenoneDiisopropyl ketone Propiophenone2-Cyclohexylcyclohexanone Benzophenone3-Cyclohexylcyclohexanone 9-FluorenoneBenzaldehyde 1-Indanone Tetralone______________________________________ In accordance with another embodiment of the invention, there is provided novel catalysts and reagent compositions comprising at least one lithium cycloalkylimide of the formula: ##STR8## wherein R and R1 are each selected from the group consisting of hydrogen and alkyl of 1 to 4 carbon atoms, and x and y are each an integer of 1 to 3. The reagent compositions which comprise the lithium cycloalkyl imides of the invention in a solvent can include lithium amides such as disclosed in application Ser. No. 374,740, namely, the lithium amides derived from alkyl amines such as methyl amine, isopropyl amine, isoamylamine and the like, dialkyl amines such as dimethyl amine, diethylamine, diisopropyl amine, diisobutyl amine, diisoamyl amine, dialkyl heptylamine, dialkylhexyl amine, for example, dimethylhexylamine and diethyl hexyl amine, N, N'-dialkyl alkylene diamine, for example, N, N'-di(tert-butyl)ethylene diamine, N, N-dimethylaminoethyl amine, N, N-dimethyl aminopropyl amine, N, N, N'-trimethylethylene diamine, N, N-dipropylaminopropylene amine, N, N'-diethyl -1, 3-propanediamine, N, N, N'-trimethylethylene diamine, N, N, N'-triethylethylene diamine, N, N-dimethyl-N'-ethylethylene diamine and the like. The preferred amines which may be utilized in admixture with the imides of the invention include dimethylaminopropyl amine (DMAPA), diethylaminoethyl amine, diisoamyl amine, diisobutyl amine, di-sec-butylamine, diisopropyl amine and diethylhexylamine. It has been surprisingly discovered that the preparation of a reagent composition of lithium cycloalkylimides which includes lithium amides increases the solubility of the amides especially in an aromatic solvent. Also, the preparation of an ordinarily insoluble lithium amide together with a soluble lithium cycloalkyl imide results in the solubility of said otherwise less soluble lithium amide. The principal advantage of the lithium cycloalkyl imides of the invention is their high solubility in most solvents. This feature permits the selection of a solvent which can be used in a continuous process. Furthermore, when used or prepared in combination with a lithium amide in an aromatic solvent particularly, lithium dimethylaminopropyl amide, the reagent composition provides high yields even at ambient temperatures when used for ethynylation reactions. Both lithium cycloalkyl imides and lithium dimethylaminopropyl amide have high solubility in most organic solvents. The following examples are illustrative of the practice of the method of the present invention. It will be understood, however, that it is not to be construed as in any way limitative of the full scope of the invention since various changes can be made, without departing from the spirit of the teachings contained herein, in the light of the guiding principles which have been set forth above. All percentages herein stated are based on weight except wherein noted. Preparation of Mixed Lithium Catalysts To 20 ml. of n-butyl lithium (0.05M) in toluene is added 0.025 mole of dimethylaminopropylamine and 0.025 mole of hextamethylene imine in toluene. The mixture is stirred for 10 minutes. A 25% by weight reagent composition is formed containing a 50--50 mole ratio of mixed lithium reagents. 20.4 g (0.2 mole) of dimethylaminopropyl amine (DMAPA) were added to 100 ml (0.2 mole) of a 2.0M toluene solution of n-butyllithium under nitrogen with stirring at 20� C. The clear solution was cooled at 10� C. and saturated with acetylene (which was passed over alumina to remove acetone). The clear solution (the complex was totally soluble) was warmed up to 20� C. with stirring and bottled. After two weeks storage at room temperature, 0.18 moles of diisopropyl ketone in 50 ml toluene were added to this solution over a 30 minute period under nitrogen at 10� C. The solution was hydrolyzed with 20 ml water and then an anhydrous sodium sulfate was added. The solution was analyzed for ethynyl carbinol using gas chromatography with 1-octanol as the internal standard. The yield was 83%. 12.6 g (0.2 mole) of hexamethyleneimine were added to 100 ml (0.2 mole) of a 1.6 M solution of n-butyllithium in toluene at 20� C. under nitrogen with stirring. The clear solution of the lithium hexamethyleneimide was then saturated with acetylene at 20� C. and stored. The lithium acetylide complex was soluble and stable. The acetylene atmosphere was maintained while 17.1 g (0.15 moles) of diisopropyl ketone dissolved in 50 ml toluene were added at 30� C. over a one hour period. When the addition was completed, the solution was permitted to warm up over 30 minutes and then 20 ml of water were added. About 10-15 g of anhydrous sodium sulfate was added and the saturated salt layer allowed to settle. To this solution was then added 10.0 g 1-octanol and a sample of the solution injected into a gas chromatograph. The ratio of the peaks for product and the 1-octanol standard was corrected for response difference (1.1 times the 1-octanol peak). The yield of the ethynyl alcohol was 93%. 9.9 g (0.1 mole) of hexamethylenimine were added to 500 ml of a 2.1M (0.1 mole) solution of n-butyllithium in toluene at 20� under nitrogen. To this clear solution were added 0.1 mole of cyclohexanone and stirred for 0.5 hrs. Then 0.2 m of allyl bromide was added. The solution was hydrolyzed with 50 ml of water then anhydrous sodium sulfate. The clear organic layer was analyzed by gas chromatography for 2-propenyecyclohexanone. The yield was 95%. The acetylene atmosphere was maintained while 17.1 g (0.15 moles) of diisopropyl ketone dissolved in 50 ml toluene were added at 30� C. over a one hour period. When the addition was completed, the solution was permitted to warm up over 30 minutes and then 20 ml of water were added. About 25 g of anhydrous sodium sulfate was added and the saturated salt layer allowed to settle. To this solution was then added 10.0 g 1-octanol and a sample of the solution injected into a gas chromatograph. The ratio of the peaks for product and the 1-octanol standard was corrected for response difference (1.1 times the 1-octanol peak). The yield of the ethynyl alcohol was 93%. To demonstrate the increased solubility of the amides or imides of the invention the following experiments were performed. Molar equivalents of the corresponding imides and diamine were added to 2 ml of 15% n-butyllithium in the solvent under nitrogen. The addition was carefully performed with syringes and the glass bottle was then capped after the reaction subsided, about 2 minutes. The solutions were permitted to stand two weeks at 20 degrees C. with intermittent shaking to be certain crystals had equilibrated with the solution. 2 ml samples were taken and filtered and then injected into 25 ml water and titrated with 0.1 N HCI with adequate stirring. A pH meter was used to determine the end point of 7.0. There was no apparent break for the LiOH and the amine or diamine present. Therefore the total titration was divided by the equivalents of base present. For each mole of the amide formed, the titration would be divided by two for monoamines and three for diamines. Table 1 lists the results: TABLE 1______________________________________Alkyl amine Solvent Solubility______________________________________A. hexamethyleneimine cyclohexane >1.6M toluene >2.2M heptane 0.7MB. 90% dimethylaminopropyl toluene >2.2Mamine10% 2-diethylaminoethylamineC. hexamethyleneimine 20% cyclohexane >1.6Mdiisopropyl amine 80%D. 3-methylpiperidine toluene 0.83ME. dimethylaminopropyl heptane 1.1MamineF. 20% hexamethyleneimine heptane >1.4M80% diisobutylamineG. diethylaminoethylamine toluene >2.2M heptane >1.4MH. 90% hexamethyleneimine toluene >2.2M10% diisobutylamine heptane 1.4M______________________________________ Patent Citations
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Is it time for cheap tricks? |
| Print | |
Steve Strauss |
Friday, May 15, 2009 |
So, what's working for your business? It's not an insignificant question, that's for sure. With Oregon unemployment the second highest in the nation, finding and keeping customers is harder than ever. Go to any retail area around Portland, or a main street in any rural community in Eastern Oregon and all of the "for rent" signs are potent reminders of those small businesses that never did figure out the answer to the question posed above. For many businesses the answer is discounting. I know that's true for mine. I am in the business of selling content, and whether it is an article, a webinar, a speech or whatever, we are not commanding, nor are we asking for the sorts of prices we got even a year ago. And it's working. Of course, discounting your prices is a strategy that must be undertaken carefully. Cut too much and it could kill your brand or cannibalize your other offerings. But that said, it is equally true that right now it's a buyer's market out there. Another thing that often works for small businesses in an economy like this is increased marketing, as counter-intuitive as that may sound. Because customers are in fact looking for a bargain these days, especially here in Oregon, loyalty is rare. So you need to keep getting new customers to replace those that are going to leave, and you also need to nab some of those who are looking for greener pastures. Increased marketing allows you to do both of those things. And it need not cost a fortune. Whether it is increased Internet marketing or a discount coupon, shoestring marketing works. So what's working for you? Steve Strauss is the small business columnist for Oregon Business. |
Real Time - Oregon Business
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Will Medford Ever Be Cool? |
The Carbon Calculus |
The Human Factor |
Convention Wisdom |
Raising the Stakes |
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Is your business ready to join us in the call for action? This opening panel includes Oregon businesses who will discuss why they signed the Oregon Climate Declaration, the investments they are making to reduce carbon emissions, and how their actions are affecting their companies.
Get ready for two days of special events produced with the EPA, Portland Timbers and ISOS before and after the GoGreen Conference on October 16.
hubbub health uses behavior change science to rethink wellness programs.
In Ashland, a public-private partnership results in online resources to help diversify the local economy.
How sports tourism is driving economic growth and making cities across Oregon a better place to live.
Sussman Shank LLP is pleased to announce that Matt Mertens has joined the firm. Matt will practice in the firm's Business, Litigation, and Business & Restructuring practice groups.
If you have given a former employee access to your company's electronic information by virtue of assigning a desktop or laptop computer and you suspect he or she of having taken electronically stored data, there are several steps to follow to preserve electronic forensic evidence from spoliation.
The official launch will be Jan. 14.


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Falling Water, Incredible Green House Design Natural Environment
Falling Water is incredible green house design with natural environment by Frank Lloyd Wright, a popular architects in the world. Frank Lloyd Wright made incredible house design which is build above falling water. Outdoor water features becomes a fantastic landscape for this green house. When you go to this incredible house design, you will welcomed by big trees and wide front yard. Outdoor water features is natural landscape which is created from natural environment. Falling water below this green house design offers extremely and beauty natural environment. Frank Lloyd Wright was built this incredible house design with strong construction to avoid eruption for falling water. Exterior of this green house design was dominated by natural environment especially with outdoor water features.
Natural environment at this green house design offers beautiful place as vacation home for all visitors. Falling water now is popular museum of Frank Lloyd Wright. Incredible house this green house design visited by many people. They want to see how awesome outdoor water features of falling water at this green house design. Incredible house of falling water has unique staircase. Frank Lloyd Wright gives a stair that straight to natural environment of cool rivers. Outdoor water features of this incredible house design are the place for relax and get awesome photograph. Natural environment of this green house design offers comfortable and cool atmosphere. Outdoor water features of falling water provide natural views foe all people who see this house design. Frank Lloyd Wright created this green house with detail of art and landscape. See all images below! Get coolest feeling of falling water, an incredible house!
Falling Water, Incredible Green House Design Natural Environment Pictures Gallery
Reference Architecture Design Ideas
New Product of Creative Furniture Collection
London Design Festival will be held starts on September, 14 until 23, 2012. There so many new product of creative furniture collection and other product will be on display. At this moment, we will show you new product from Dare Studio. All products are handmade to the finest quality with highly skilled craftsmen. All pieces can be modified to accommodate your specific requirements. Customers can alter dimensions, timbers, colors and finishes of each furniture that they need. The latest collection includes two occasional tables named Maya Desk, a contemporary bed named Zephyr Bed, two modern sofa and chair. Beside of […]
Environmentally Friendly Euclid Avenue Green House Design
Levitt Goodman, with cold hands makes Euclid Avenue as beautiful house to become a unique alternative of Toronto's environmentally friendly home. Euclid Avenue green house design comes from innovative ideas of beautiful house and determined by the flexibility, integrity and sustainability in every part of the beautiful house design. This green house design becomes environmentally friendly home which consists of two floors. Half of the basement in this Toronto's environmentally friendly home is designed to ensure maximum daylight into the beautiful house design. Garages built to integrate with the yard and serves as a yard between two buildings of this […]
Small Indoor Garden Modern Japanese House Interior Design
Modern Japanese house in Nagoya by Suppose Design Office has awesome Japanese house interior design with small garden design as indoor garden of glass garden and glass roof. Modern Japanese house has awesome Japanese house interior design with glass garden for small indoor garden design and glass roof. Small garden design as indoor garden in this modern Japanese house provides natural atmosphere. Japanese house interior design was created in white interior for wall, stairs and Japanese furniture design. Japanese furniture design is made of wood to give warm atmosphere. Glass garden of indoor garden offers freshness and cozy feeling. Glass […]


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Looking for the best services for your Napa or Sonoma Wine Country wedding? We've got them right here. How do we know? We ask. And ask. And ask. The wedding photographers, caterers, wedding planners and so on that you find here have all been Certified By The Guide. That means we've asked dozens of people (other professionals who've worked with them and brides and grooms and mothers of the bride, etc.) for feedback on each one of them…and they passed with flying colors.
Company | Special Offer | Real Weddings | Main Office Location | Category |
Goodtime DJs and Karaoke
Mark and his staff provide full disc jockey and master of ceremony services, as well as assistance with reception planning. Karaoke and a singer are available, and if they don't already have the… |
SF Bay Area | DJs and Entertainment | ||
Karenscape Photography
Interesting angles, creative composition, and a unique perspective are the hallmarks of Karenscape Photography's wedding imagery. Karen Gordon specializes in high-quality, artistic wedding photo… |
Sebastopol | Photographer | ||
Tosca Productions
Tosca and her team design and produce upscale weddings and events, incorporating each couple's personal style and cultural traditions from around the globe, including Catholic, Jewish, Chinese,… |
Daly City | Coordinator / Wedding Planner | ||
Sasha Photography
Always trying to push his camera to new limits, Sasha's bold and vibrant images make it clear: this is wedding photography for rockstar couples. Sasha's images are modern, bright, artistic… |
San Francisco | Photographer | ||
WedSafe Wedding Insurance
WedSafe® offers two wedding insurance products that can be purchased individually or as a package to help provide security and protect your wedding:Wedding Event Cancellation / Postponement Plus I… |
Jericho | Wedding Insurance | ||
Deborah Coleman Photography
With Deborah Coleman you receive a true photojournalist who documents your wedding day. Deborah conveys the best of your event, expertly using light, camera angles, and subsequent post-production work… |
San Francisco Bay Area | Photographer | ||
Photo-matica Photo Booth Co.
The Photo-matica Photo Booth provides the best of both worlds: a sleek, vintage-inspired outside with the best available digital technology on the inside. And the Photo-matica team follows suit—… |
San Francisco | Photo Booth | ||
Kevin Chin Photography + Cinema
Kevin Chin Photography + Cinema is a full service portrait and wedding studio located in the SOMA district of San Francisco. With over 20 years of professional experience, Kevin wins the confide… |
San Francisco | Photographer | ||
Mandy Scott Events
With a rich background as an award-winning floral designer, and a personal interest in art, interior design, and world travel, Mandy Scott brings an incredibly creative eye and artistic perspective to… |
San Francisco | Coordinator / Wedding Planner | ||
Susan Adler Photography
Susan Adler photographs weddings, engagements, portraits, and other special event photography in medium format and 35 mm film and in digital. She offers fine art albums, online proofing, images on di… |
San Rafael | Photographer | ||
Park Avenue Catering
As the first Green Certified Caterer in Napa and Sonoma Counties, Park Avenue Catering is committed to providing fresh, local, farm-to-table cuisine for your wedding or special event. As a full-servic… |
Cotati | Caterer | ||
Fleurs de France
Fleurs de France has a very lush European romantic style. Designer Jessica Switala's creations are abundant, natural and uncontrived combinations ranging from delicate and very subtle to extrem… |
Sonoma/Napa | Flowers | ||
Sutherland Entertainment - Music And More For Private Events
With Spencer Sutherland, you no longer have to choose between the romantic ambience of a live guitarist and the party atmosphere of a rockin' DJ/MC. Described by his brides as the "whole p… |
Vallejo | DJs and Entertainment | ||
La Tavola Fine Linen Rental
La Tavola Fine Linen Rental offers a diverse array of exquisite linens and table toppers for your wedding. Whether your style is elegant, traditional, contemporary, or even a little eccentric, La Tavo… |
Napa | Party Rentals and Linens | ||
Freedom Bakery and Confections
Freedom Bakery and Confections is all that you would wish for in a neighborhood bakeshop: Family owned and operated since 1975, they produce all of their gourmet wedding cakes, cupcakes, cookies, and … |
Watsonville / Monterey Bay | Favors | ||
Waterlily Pond Floral and Event Design
Voted "Best of the Bay Wedding Flowers" by San Francisco Chronicle readers, Waterlily Pond Floral and Event Design speaks to brides looking to make a truly unique aesthetic statement. Wate… |
San Francisco | Flowers | ||
Verducci Event Productions
Verducci Event Productions is home to Snapture! Photobooths. Custom-built exclusively for weddings, they fit anywhere from 3-12 guests and take 4 photos per strip with the simple push of a button. An … |
Berkeley | Photo Booth | ||
Perfect Circle Photography with Curtis Myers
There is only one chance to document your wedding day and Curtis Myers embraces this responsibility as a huge honor. He will work closely with you to ensure your photos are relaxed, natural and a clea… |
San Francisco | Photographer | ||
Paper and More!
Paper and More! is the perfect online resource for brides designing their own wedding invitations or stationery. They offer high-quality card stock, envelopes, metallic card stock, vellum paper, linen… |
Fremont | Invitations | ||
Rikki Ward Photography
Rikki's brides tell us that of all their wedding photos, none of the images felt "posed" or "contrived." Rikki Ward knows how to capture the essence of the moment and the… |
San Francisco | Photographer | ||


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FBR Capital Upgrades AMD (AMD) to Outperform Ahead of Results
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Rating Summary:
8 Buy, 11 Hold, 11 Sell
Rating Trend: Down
Today's Overall Ratings:
Up: 25 | Down: 40 | New: 35
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Intra-day, FBR Capital upgraded Advanced Micro Devices Inc. (NYSE: AMD) from Market Perform to Outperform with a $5.25 price target. The upgrade follows positive comments and raised estimates from the broker earier. FBR said they are "putting our money where our mouth is" with the upgrade.
On the upgrade the firm said, "We do think the company will report strong 2Q results and 3Q guidance on Tuesday after the market close, so this is a somewhat shorter-term call in nature. Our new distributor checks suggest Asian distributors had a stronger-than-expected June quarter and are more positive about 3Q shipment prospects. In addition, recent checks for AMD and the PC supply chain have strengthened."
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User Review
we have been living here for the past 3 year's quite, clean,reasonable plus the girl's that work in the office are awesome and friendly and the maintenance guy's rock always on time
Lugano | $680 - $920 | 1 Bathroom | 650 Sq. Ft. |
Como Grande | $710 - $950 | 1 Bathroom | 735 Sq. Ft. |
Ascona | $800 - $1090 | 2 Bathrooms | 1056 Sq. Ft. |
Campione | $900 - $1225 | 2 Bathrooms | 1176 Sq. Ft. |
Welcome to Promontory Point. Here you will find spacious apartment style homes away from congested city streets. Located in prestigious Green Valley, our serene location provides privacy and a true country feel. Promontory Point is just minutes from freeway access, shopping, Sunset Station and the Galleria Mall. Nearby are restaurants, McCarran international Airport, the beautiful Wild Horse Golf Course and the Green Valley Athletic Club. We offer four unique floor plans especially created for contemporary, carefree lifestyles. Every aspect of your comfort has been meticulously considered. It is all waiting for you at Promontory Point.
Year Built: 1991
Apartments in Community: 180
We believe school data to be accurate, but do not guarantee that. Please be sure to verify where your children will attend school before making your housing decision.
Please call for fees & restrictions.
we have been living here for the past 3 year's quite, clean,reasonable plus the girl's that work in the office are awesome and friendly and the maintenance guy's rock always on time
I've been living here for the last two years and it's been wonderful. It's quiet, safe, and the ladies at the leasing office are super helpful and friendly. The apartments are lovely and are very generously priced. Definitely recommend.
Promontory Point is located in the Green Valley/Henderson area of Las Vegas, NV. We offer 1, 2 & 3 bedroom apartments for rent. Amenities include 2 pools & spa, roommate style spacious floor plans, wood burning fireplace, cathedral ceilings, huge walk-in closets, boat & RV parking, washer & dryer, playground, 24 hour emergency service and we are close to Galleria Mall, Sunset Station Casino and Lake Mead Recreational Area.
Take US-95 to Sunset Road and exit West. Make a Right on Arroyo Grande. We are on the Left past Warm Springs.
As you search for your perfect apartment, please keep in mind that rental rates (including specials and discounts) and availability are very fluid in the apartment industry. Based on many factors, the rental rates (including specials and discounts) and availability can actually change not just daily, but hourly, if not even more quickly. While our advertisers do take steps to keep their information current, the rental rates or availability you may find here now at ForRent.com may not be the same as when you contact the communities.


text: Home Animal Dog Wolf Love_53415 Wallpaper Wolf Love_53415 Wallpaper knowing Wallpaper HDR Revised by gaeljet2 Wallpaper Normal Resolution: 800x600 | 1024x768 Wallpaper:Wolf Love Updated:2011-06-28 Rating: (0 votes) Category:Animal Wallpapers Size:0.12 MB View:1569 Subcategory:Dog Wallpapers Uploader: admin Download:681 TAG: AnimalsdogdogsforestnatureWOLFwolves Add to Favorite Wallpapers Share | Comment Relevant Wallpapers ROMANTIC DOG in Dog Dog with Beautiful B... in Dog Adorable Puppy in Dog So Sleepy in Dog Puppy Gift in Dog baby waiting in Dog Comments for Wolf Love Wallpaper No Comment for this wallpaper. Why not leave it the first one? Post Your Comment Comment:500 characters at most Code: Sumbit


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Gard On Tomb Raider, Galleon, Delays 24
from the for-he's-a-jolie-good-fellow dept.
Slashdot stories can be listened to in audio form via an RSS feed, as read by our own robotic overlord.
The Stone Roses' "Second Coming"? He's saying his own game is gonna suck after all this time?!
We don't share your stereotypes about our nation. We don't even find them funny.
I'm sure you Brits have stereotypes about Americans that aren't remotely true. We all find reasons to laugh at each other. Life would be so boring if we didn't.
--from a gal who never really got the joke with Austin Powers' teeth until now...
*shudders* There's something wrong with this guy"Lara was based on elements of Indiana Jones, Tank Girl and, people always say, my sister," says Gard. "Maybe subconsciously she was my sister."
In other words : "she was this boobalishous gal, was perfectly postured and formed, and armed with dual pistols with supernatural aim and strength with unlimited ammo."
Prince of Persia Sands of Time is pretty much the Galleon was going to be, which leaves Galleon itself rather out in the cold..
Nothing succeeds like the appearance of success. -- Christopher Lascl


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xxGreat Saiyaman
I have been waiting for a Singed skin for quite a while and U have probably seen other people complain about the same exact thing that I am going to complain about but Teemo's little gay ass has 4 skins...I don't know wat went into the minds of riot to give Teemo four skins when some people are still missing a secondary one. Yes, I know i'm complaining but if u liked Singed too u would probably complain to. When this update came out i couldnt believe that they were giving people skins who already have 1. Jax got two skins on the same month. also Corki got two skins on the same week! nobody plays Corki but also nobody plays Singed either but they atleast play Singed more when he is free. It was just disappointing to all fans of a person doesnt have a skin yet and when they looked at the update last week they were probably frustrated like I was. I kno it is not a big deal becuz its a game. I wouldnt care if they made Singed armor black with white outlining it, with some green eyes and when he does his poison trail skin make the gas black. That's it Riot please give me a Singed skin .
Senior Member
Singed is my main and I agree. Actually, I they should make a skin for every character that doesn't have one instead of making multiple teemo skins and skins for other characters who have them.
Need some love for Janna and maplhite too. Some others I can't remember. Q_Q
I can agree that i would like to see a skin for Singed (especially considering the possibilities with him), but i cannot stand the way you made this topic. There is absolutely NO reason to bold your entire post. You have poor grammar, poor spelling, and your post is filled with annoying complaints. You're only making it very tedious for other members to read your topic.
Shameless plug: http://www.leagueoflegends.com/board...ht=singed+skin Making my own skin soothed the sting of being left out of official skinning.
http://www.heroesmod.com/skins/viewtopic.php?f=36&t=158 riot remake that skin as a singed skin plox ! O.O
Hi, i was thinking of making singed a custom skin, but I'm kind of stumped for ideas. If anyone's got a cool theme for him, I'd be happy to make it and release it for use.
What's the deal with custom skins if you're the only one seeing them?
Well in livestream... and such but its like owning any virtual/pixels thing just there to have.
Lol dude chill out usually people on the internet do not write with good grammar but obviously u do also sry for bolding my letter didnt know it would hurt u lol. didnt mean to make u made


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Vestas considers Mitsubishi cooperation |
| Print | |
Must Reads | |||
Tuesday, August 28, 2012 | |||
Vestas Wind Systems said it is in discussions with Mitsubishi Heavy Industries to consider a "potential strategic cooperation." Read more at Sustainable Business Oregon. {biztweet}vestas mitsubishi{/biztweet}
Top stories in 2014The LatestThursday, December 18, 2014 2014 was a year of wild contradictions, fast-paced growth and unexpected revelations. Read more... |
Powerbook PerspectiveJanuary-Powerbook 2015Friday, December 12, 2014 BY LINDA BAKERA conversation with Oregon state economist Josh Lehner. Read more... |
Crowdfunding 2.0NewsTuesday, December 02, 2014 BY LINDA BAKERA conversation with attorney Erich Merrill about the latest way to raise money from large groups of people. Read more... |
Closing the Gap: The two Oregons and the way forwardFebruary 2015Monday, January 26, 2015 BY JOE CORTRIGHT"Nostalgia is not an economic strategy." Read more... |
Tackling the CEO-worker pay gapJanuary-Powerbook 2015Thursday, December 11, 2014 BY OREGON BUSINESS STAFFAn SEC rule targets the disparity between executive and employee compensation, reigniting a long-standing debate about corporate social responsibility. Read more... |
Corner Office: Timothy MitchellJanuary-Powerbook 2015Saturday, December 13, 2014 A look-in on the life of Norris & Stevens' president, plus an abridged Powerlist for the best commercial real estate firms. Read more... |
A legislative preview — and celebrationNewsFriday, January 23, 2015 BY LINDA BAKER | OB EDITORThe Northwest Environmental Business Council previews the 2015 legislative agenda as Hatch Oregon celebrates Oregon's new community crowdfunding rules. Read more... |
Real Time - Oregon Business
TWITTER FEED Tweets by @OregonBusiness |
Will Medford Ever Be Cool? |
The Carbon Calculus |
Convention Wisdom |
The Human Factor |
Raising the Stakes |
Light Moves |
Which Way to Chinatown? |
Is your business ready to join us in the call for action? This opening panel includes Oregon businesses who will discuss why they signed the Oregon Climate Declaration, the investments they are making to reduce carbon emissions, and how their actions are affecting their companies.
Get ready for two days of special events produced with the EPA, Portland Timbers and ISOS before and after the GoGreen Conference on October 16.
hubbub health uses behavior change science to rethink wellness programs.
In Ashland, a public-private partnership results in online resources to help diversify the local economy.
How sports tourism is driving economic growth and making cities across Oregon a better place to live.
Sussman Shank LLP is pleased to announce that Matt Mertens has joined the firm. Matt will practice in the firm's Business, Litigation, and Business & Restructuring practice groups.
If you have given a former employee access to your company's electronic information by virtue of assigning a desktop or laptop computer and you suspect he or she of having taken electronically stored data, there are several steps to follow to preserve electronic forensic evidence from spoliation.
The official launch will be Jan. 14.


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, ,
Our Price: | $31,900 |
Sale Price: | $23,900 |
Total Savings: | $8,000 |
Contact: | Email Us |
Stock Number: | 4332 |
Model: | 31BHDS |
Class: | Fifth Wheel |
Condition: | Used |
Status: | Available |
Length: | 33' 0' |
Exterior: | White |
Slides: | 1 |
2014 Palomino Basecamp W-10DFG (New) Stock #: 3734 Class: Folding Camper |
2013 Palomino Maverick 2910 (New) Stock #: 3272 Class: Truck Camper |
2014 Palomino Backpack WSS1225 (New) Stock #: 3586 Class: Truck Camper |
2014 Palomino Basecamp W-8B (New) Stock #: 3730 Class: Folding Camper |
2014 Palomino Basecamp W-10DD (New) Stock #: 3733 Class: Folding Camper |
Meridian RV Mfg., Ltd. Port Coquitlam
1690 Coast Meridian Road
Port Coquitlam, V3C 3T8
Contact Information:
While we attempt to ensure display of current and accurate data, this listing may not reflect the most recent transactions or may reflect occasional data entry errors. All inventory listed is subject to availability and prior sale. Please consult dealership personnel for details. Prices are quoted in CDN only and may not include dealer preparation, transportation, taxes, or other applicable charges. Photographs may be representative only and may vary somewhat from the actual items offered for sale. Meridian RV is not responsible for any misprints, typos, or errors found in our website pages. Any price listed excludes sales tax, registration tags, and delivery fees. Manufacturer pictures, specifications, and features may be used in place of actual units on our lot. This information is general and is subject to change. We are not responsible for any errors as data changes frequently. Please contact us to confirm this information is accurate.


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CHEFS Catalog |
180 Reviews
$79.95 | See It | |
$79.95 | See It |
Product Details
Santoku Knives - The most popular knife shape, with a hollow-ground edge for smooth, stick-free slicing.About Wusthof Gourmet: A precision-stamped blade of high-carbon stainless-steel that sharpens easily and holds its edge. Compression rivets securely attach the high-impact handles to the full tang for superior balance and maneuverability. Dishwasher safe, but hand washing is recommended. Made in Solingen, Germany. -
Quick Glance
cutlery type: knife sets
Product Title: Wusthof 7-inch Hollow Edge Santoku Knife - Wusthof Gourmet
Manufacturer: Wusthof
Lowest Price: $79.95 from Crate & Barrel
Power Score: 4.3 | 10 Reviews


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Posted on What the heck is this thing?
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3898 posts in 796 days
#1 posted 04-03-2013 09:08 PM
"just a solid chunk of mystery."
Ok, seriously this time… Maybe it's some sort of splitter? Looks like it has a hex end for screwing it in?
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Friday, October 25, 2013
My Favourite Scents in Soap: Part 1, Essential Oils
All essential oils are amazing, however when it comes to cold process soap, some perform better than others. My criteria for EOs in soap is that they hold their scent well, don't accelerate trace, and are reasonably inexpensive to buy. These are my "must have" essential oils for a soapmaker's arsenal!
Orange 10fold
Rose Geranium
Tea Tree
Ylang Ylang
These are some of my favourite blends:
Hippie Blend
2 parts patchouli
1 part lemongrass
1 part orange 10fold
Ocean Blend
2 parts lavender
2 parts rosemary
1 part lemongrass
1 part peppermint
Forest Blend
2 parts lavender
1 part cedar wood
1 part lime
1 part rosemary
Minty Blend 1
1 part peppermint
1 part eucalyptus
Minty Blend 2
2 parts lavender
1 part peppermint
1 part spearmint
Spiritual Blend
3 parts frankincense
3 parts mandarin
1 part lemongrass
1 part patchouli
1 part orange 10fold
Bliss Blend
3 parts rose geranium
3 parts cedarwood
2 parts patchouli
2 parts mandarin
1 part ylang ylang
Eau De Cologne Blend
2 parts petitgrain
2 parts lavender
1 part orange 10fold
Clear Complexion Blend
1 part lavender
1 part tea tree
Do you have a favourite essential oil or blend in soap? Pop it in the comments below!
8 comments:
- RosanneOctober 28, 2013 at 12:26 AM
Thank you....it is lovely when experienced soapmakers are willing to share their expertise. I am going to try some of these to see which I like!
ReplyDelete I love your blends! The only essential oil you mention that I don't have is frankincense. I will try your 2nd minty blend out soon - equal parts of peppermint and spearmint are just not doing it for me....lol.
My favourite blend is a simple one: May Chang/Litsea with Lavender (or Lavandin Grosso in soap so it comes through better).- AnonymousMarch 3, 2014 at 4:52 AM
Great blends, however have not had good luck with lime in cp soaps.
ReplyDelete - AnonymousMarch 19, 2014 at 2:20 PM
Your blog is so inspiring to a new soapmaker like me, could you please explain the 1 part of the essential oils, how much in ml or drops, thanks a lot ......
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