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used honda aviator bangalore
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Used Cars
Volkswagen Polo 1.2L Comfortline (Petrol) (2010)
Well maintained. Bangalore used only. upto date service. Used by Senior Citizen very cautiously. ... read more
|Registration no: KA 04 MH 3538
|Colour: Black
|City: Bangalore
|Asking Price: 4,25,000
Hyundai i10 Sportz 1.2 AT Kappa2 (2009)
I am selling my Hyundai i10 Sportz 1.2 AT Kappa2 2009 bought in Bangalore in 2009 , it's been driven for kilometers. ... read more
|Registration no: KA51Z 4670
|Colour: Black
|City: Bangalore
|Asking Price: 4,00,000
User Reviews
Volkswagen Vento 2010-2014 Reviews
Until just over a year ago, Honda had been ruling the market in all the segments it was present in India. All its models- City, Civic, Accord and CR-V used to top the sales charts year after year. But with the launch of new models like the Corolla Altis, Superb and the Fortuner, the long dominance oread more
Mercedes Benz C Class Reviews
check out pre owned used mercedes cars bets car in segment bmw beats some featuresread more
Honda Motorcycle & Scooter India Pvt. Ltd. (HMSI), has launched the New Aviator in India. The bike comes with a host of new features. Aviator h Read more detail
Despite the automarket downturn, used cars business is witnessing far higher growth rates and car manufacturers are planning to cash in on the demand Read more detail
Expert Reviews
Honda 2013 Aviator review
Beauty, smartness and intelligence always attract and that is how the phrase was proved so true while passing through a parking. Standing discreetly b read more
The refurbished Skoda Fabia
Indians are getting used to paying premium prices for premium products. When the Skoda Fabia was first launched, it was one of the most expens read more
New Honda Aviator Review 2013
We test ride the all new Honda Aviator which has just been launched in its 2013 avatar. The price is about Rs. 55 Thousand and it is a versus Piaggio ...view video
Mahindra First Choice "Highline Store" Inauguration
India's leading multi-brand certified used car company Mahindra first choice wheels LTD. Inaugurates first "HIGHLINE" Store in Gurgaon ...view video
Forum Discussions
which one is best gearless scooter
hi binny here, i am planning to buy new gearless two wheeler and also good milage and power. Please advise me which one is best scooter from the following: honda activa honda aviator suzuki access
Ford Ikon 1.3 Flair
I would like to know -for how much price i can sell off my Ford Ikon 1.3 Flair 2006 Dec Model - I used it for 26500 kms till now. Could some one please let me know used car dealers in Bangalore. T
Honda Aviator
Honda Aviator is powered by an engine with a displacement of 109 CC. Its maximum power is 8.1PS. The dimensions of the motorcycle are 1802 x 703 x 1162 mm (length X width X height). The bike's seat height or the ground clearance is 145. ... read more
Honda Activa
Honda Activa's engine displacement is 109.2 CC. Its engine generates a maximum power of 8.1PS. The exterior dimensions of the bike are 1761 x 710 x 1147 mm (length X width X height) while its ground clearance is 153. ... read more
New Car Dealers
Kesar Cars Pvt. Ltd. ( Honda)
101, Baner, Mumbai Bangalore Highway - 411045 , Mumbai Bangalore Highway
Phone: 020 - 66336633
Lally Motors Ltd. ( Honda)
G.T Road, Sultanwind, Sultanwind
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Used Car Dealers
Dakshin Honda(Elite automobiles Pvt. Ltd.)
97/1A, Singhasandra Village, Hosur Road, Bangalore-560068Bangalore, Hosur Road
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Programmes A to Z - K
Karajan's Magic and Myth
Profile of the controversial, enigmatic conductor Herbert von Karajan.
BBC Four
Kate and Mim-Mim
Animated series about feisty five-year-old Kate and her toy bunny Mim-Mim's adventures
Kenny Rogers: Cards on the Table
Chronicling Kenny Rogers's rise to the top and the golden era of country he ushered in.
BBC Four
Quiz show where teams answer questions and race around weird and wonderful raceworlds
The Killing Fields
A reporter attempts to find his translator, who has been captured by the Khmer Rouge.
BBC Four
The Kitchen
Documentary series which follows eight very different households in their kitchens.
BBC Two

subset: commoncrawl


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After the first two games were both taken by White, games three and four of the GM Levon Aronian versus GM Hikaru Nakamura match both ended in draws.
The match, dubbed as the "Showdown in St. Louis," is hosted by the Chess Club and Scholast... | Read More
UPDATE: Here's your chance to ask a question at the Rd. 11 press conference. Click here to submit your question and we will pick one!
On Friday GM Viswanathan Anand used up one of his two remaining turns with White at the 2014 FIDE World Champio... | Read More
GM Viswanathan Anand produced only a modicum of pressure in game eight of the 2014 FIDE World Championship on Tuesday. He could not net the full point as White against the champion GM Magnus Carlsen.
White got nothing from his pressure on t... | Read More
The fifth game of the world championship match in Sochi, Russia between Viswanathan Anand and Magnus Carlsen ended in a draw.
The score is 2.5-2.5; game six will be played tomorrow at 3 p.m. Sochi time (noon GMT, 7 a.m. EST).
Ca... | Read More
The fourth game of the world championship match in Sochi, Russia between Magnus Carlsen and Viswanathan Anand ended in a draw. The score is 2-2.
For his second black game, Anand switched from 1...e5 to a 2...e6 Sicilian and it was no surpri... | Read More
Sure, the Closed Spanish, Open Spanish and Berlin have all been popular at times in the last 30 years, but don't forget about another solid variation against the Lopez: the Steinitz Defense. Players looking for a solid structure with a minimal space disadvantage might just catch their opponents by surprise with 3...d6. Today GM Dzindzichashvili focuses on 4. d4 and both possible recaptures. If it is good enough for a preeminent theoretician, it it surely good enough for you! | Watch video
Back by popular demand, GM Ben Finegold begins a three-part series on his favorite defense to 1. d4 - the Chigorin. He promises you'll get an exciting position that you'll know better than White. Today he focuses on some pedestrian replies from the first player, but they also happen to be the most common moves. Watch and see that even though Ben knows a ton about the opening, he once had a 7-year-old student teach him something new! | Watch video
Want a unique system against the Closed Sicilian? No longer do you have to just drop knights into d4. GM Khachiyan shows that leaving the long dark-squared diagonal open can restrain all of White's queenside pieces. The king's bishop is the lion tamer, and the circus of pieces is definitely more enjoyable from Black's seat. White's thrusts go nowhere, and once the center collapses and the c-file opens, it is him wearing the clown suit. | Watch video
So you want to play the Grünfeld huh? Well GM Dzindzichashvili says, "Get read to work," because White has all the choices. Today he wraps up his in-depth four-part series by showing one of his games. He also covers all the other sidelines of the opening, giving White even more choices to face one of Black's most popular defenses to 1. d4. | Watch video
With his second video, GM Perelshtyen provides more proof that a repertoire built around positional themes and thematic ideas can work at the highest level! He reviews his own games, highlighting the critical moments where the proper "square control" approach and maneuvers are necessary (his Nf6-d7-f8-e6-d4 plan is quite instructive). | Watch video
"Opening Of The Month" for 1.d4 Nf6 Indians
by Ambassador_Spock 12 months ago
The Halasz Gambit 1.e4 e5 2.d4 exd4 3.f4
by DarthMusashi 19 months ago
Dealing with 1.d4 d5 sidelines
by Expertise87 2 years ago
Hurt/ Heal 1.d4
by amaan1 2 years ago
1. d4 d5 2. c4 -A breakdown for Black
by Twarter369 6 years ago
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Hi everyone, I'm a newbie here. My husband & I are doing some remodeling, and we're looking for some sort of non-slip floor other than carpeting. We have 4 very large dogs, so our new floors need to be easy to clean, durable, and non-slip. We currently have laminate in our dining room, and love every aspect of it except that the dogs tend to wipe out whenever they run through that room, even though I've strategically placed a few rubber-backed throw rugs.
I would love to install some kind of laminate or possibly sheet vinyl - can you tell me if any are truly non-slip, or if there's some sort of non-slip coating that can be used on them without damaging the flooring?
Thanks for any suggestions you can offer!
- Forum >
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text:
Yeah Nikon, I play the card game. Placed Fourth in a tournament of twenty.
Um yeah!!Originally Posted by KenX
I find it(anime) entertaining, but I would never waste my money on the card games.
So Zui Quan, you don't like CCS either??
Yeah Nikon, I play the card game. Placed Fourth in a tournament of twenty.
I'm a veteran of the TCG
played it for over three years
don't play in tourneys not that much lately,
but I duel now and then
the new season kinda sucks
if an episode makes a YGO addict like me go "WTF?" then you know there's something wrong
the episodes lately have been weird lately
sometimes I think I'm watching something else
there are so many cliches in this season that its's enough to make me sick
IMO, I like the third season (Battle City) better
(in case someone doesn't know...
the first season never made it to the states because it was too violent and weird for our virgin eyes
4Kids used the second season as their "first"
the second season was the "Duelist Kingdom" saga
the third season was the "Battle City" saga
Innerhell OUT!!
I love my girlfriend.
Originally Posted by mega
Placed second with my Spirit deck in tournement of 40.
Placed first with Harpie deck in tournement of 10.
Placed fifth with Brutal beatdown deck in tournement of 80. :Thumbd:
How true it is. How true it is.Originally Posted by Zui Quan


text:
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The Trick to Locating a Terrific Estate Agent
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A polyurethane adapted for making non-ionic aqueous polyurethane dispersions without an added emulsifier is prepared by reacting a conventional organic diisocyanate and an organic compound having groups reactive with isocyanato groups and having a side chain which contains repeating -O-CH2-Ch2 ) groups. Latices prepared from the polyurethane may be used to prepare films and coatings having improved physical properties.
Claims available in
Description (OCR text may contain errors)
United States Patent [1 1 Noll [4 1 Sept. 16, 1975 AQUEOUS DISPERSIONS OF POLYURETHANE HAVING SIDE CHAIN POLYOXYETHYLENE UNITS [75] Inventor: Klaus Noll, Cologne, Germany [73] Assignee: Bayer Aktiengesellschaft,
Leverkusen, Germany 22 Filed: Mar. 18, 1974 211 Appl. No.: 452,163
[30] Foreign Application Priority Data Mar. 23, 1973 Germany 1. 2314512 [52] US. Cl. 260/29.2 TN; 260/77.5 AQ;
260/75 NQ; 260/859 R; 260/859 PV [51] Int. Cl C08g 22/14; C08g 51/24 [58] Field of Search 260/292 TN [561 References Cited UNITED STATES PATENTS 2,835,653 5/1958 Haas et al 260/292 TN 3,479,310 11/1969 Dieterich et a1 260/292 TN 3,666,542 5/1972 Kigane et a1. 260/292 TN 3,730,927 5/1973 Schloss 260/292 TN 3,769,318 10/1973 Windemuth et al 260/25 AT 3,796,678 3/1974 Bartizal 260/292 TN FOREIGN PATENTS OR APPLICATIONS 2,141,805 Germany 2,141,807 Germany Primary ExaminerJohn C. Bleutge Assistant ExaminerArthur H. Koeckert Attorney, Agent, or Firm-Joseph C. Gil
[ ABSTRACT 9 Claims, N0 Drawings This invention relates generally to polyurethanes and more particularly to an improved polyurethane for making dispersions, to a method for making them and to films and coatings prepared therefrom.
It has been disclosed before that polyurethanes and polyurethane ureas can be emulsified in water with emulsifiers and under the action of high shearing forces to form latices (e.g. as described in US. Pat. No. 3,294,724). The preparation of these latices is difficult and requires close technical control of the process. Moreover, the resulting latices have the disadvantage that films produced therefrom have a poor resistance to water because of the use of an emulsifier. The latices also are often not of a sufficiently fine state of subdivision to be stable against irreversible sedimentation of the polyurethane.
Latices prepared with polyurethane ionomers which contain an internal dispersing agent in the form of ionic groups built into the molecule are very finely divided stable dispersions and do not have these disadvantages. These known latices (see e.g. US. Pat. No. 3,479,310 or British Pat. Specification No. 1,076,688) have the advantage of possessing the excellent properties of linear polyurethane elastomers, such as high elasticity, high tensile strength, high resistance to hydrolytic influences and weathering and high resistance to exposure to light, combined with the ability to be worked up from solvent-free media. The danger of a fire or explosion because of the presence of a volatile solvent is avoided and moreover, it is not necessary to destroy or recover organic solvents which may be harmful to the health and may adversely affect the environment. Such latices also have a high solids content.
Although these dispersions have already become technically important, they have two properties arising from their nature as polyelectrolytes which are somewhat disadvantageous and may jeopardize their universal acceptance. They are sensitive to electrolytes and to cold temperatures.
Other dispersions have been disclosed and described in German Offenlegungsschrift Nos. 2,141,805 and 2,141,807 in which the dispersibility is brought about not by groups of an ionic nature but by centers which make use of the hydrophilic character of polyethylene oxide ethers. These dispersions, insofar as they do not contain dispersifying groups of an ionic nature, are prepared by reacting a trifunctional isocyanate'prepolymer (obtained from a trifunctional polypropylene oxide polyether and the stoichiometrically required quantity ofa diisocyanate) with alcohol mixtures which contain monofunctional polyethylene oxide ethers in such a manner that the reaction mixture contains one mol of the mixture of monofunctional alcohols to one mol of isocyanate prepolymer. The resulting mixture which contains NCO-groups is dispersed in water by the action of shearing forces and undergoes an increase in molecular weight due to the conventional reactions between NCO-groups and difunctional reactive hydrogen containing compounds (cg. diamines). According to the examples given in German Offenlegungsschrift No. 2141.805 and in Example 4 of German Offen legungsschrift No. 2,141,807 films produced from these dispersions have e-moduli of about 5 l g.wt./cm and tensile strengths of about [10 kg.wt./cm at elongations at break of 200%. Such dispersions are unsuitable for making coatings or coverings having good physical properties because such coatings must have a minumum tensile strength of kg.wt./cm and minimum elongation at break of about 400%.
It is therefore an object of this invention to provide a completely new method of obtaining polyurethanes which can'be dispersed in water without the aid of dispersing agents and polyurethane dispersions obtained from these polyurethanes which are free from the above disadvantages. Another object of the invention is to provide a process for producing non-ionic, aqueous polyurethane dispersions which are free from emulsifiers. Another object of the invention is to provide improved polyurethane latices. Still another object of the invention is to provide polyurethane latices adapted for use in 'the preparation of coatings or coverings having improved physical properties.
The foregoing objects and others are accomplished in accordance with this invention, generally speaking, by providing a polyurethane having a micromolecular structure including a side chain containing repeating -(-OCH CH groups and attached to the micromolecular chain through specific groups described hereinafter.
The polyurethane provided by the invention is prepared by a process wherein an organic diisocyanate is reacted with an organic compound having a molecular weight of from about 500 to about 6,000 which is difunctional for the purpose of the isocyanate polyaddition reaction and contains terminal hydrogen atoms which are reactive with isocyanatogroups but does not contain side chain polyethylene oxide units and with an organic compound which is difunctional for the purpose of the isocyanate polyaddition reaction and contains terminal hydrogen atoms which are reactive with isocyanate groups as well as side chain polyethylene oxide units. The reaction mixture may contain, optionally, a conventional chain-lengthening agent having a molecular weight below 500 (hereinafter called op tional chain extender) and other suitable conventional auxiliary agents and additives used in polyurethane chemistry.
The reactions ofthe organic polyisocyanate with the organic compound having groups containing reactive hydrogen atoms determinable by the Zerewitinoff method having a molecular weight from about 500 to about 6000 and with the chain extender may be conducted under substantially anhydrous conditions and the resulting polyurethane may then be converted later into an aqueous dispersion or the polyurethane may be prepared by a prepolymer process in which an excess of organic polyisocyanate is reacted with the organic compound having reactive hydrogen atoms and a molecular weight of at least about 500 in a first step under substantially anhydrous conditions and the prepolymer is then chain extended in the presence of water while forming a dispersion. Any difunctional organic compound which contains reactive hydrogen atoms and side chain polyethylene oxide units of the following general formula (1) may be used:
in which R represents a divalent group obtained by removing the isocyanate groups from a diisocyanate with a molecular weight of from about 1 12 to about 1000.
X represents oxygen or NR" R and R are identical or different and represent a monoval ent hydrocarbon group containing from l to l2 carbon atoms,
R represents hydrogen or a monovalent hydrocarbon group containing from 1 to 8 carbon atoms, and
n represents an integer of from 4 to 89.
The invention also provides aqueous polyurethane dispersions obtainable by this process.
The invention also provides a process for producing thermoplastic, non-ionic polyurethane elastomers with a substantially linear molecular structure which are dispersible in water wherein an organic diisocyanate is reacted with a difunctional organic compound having terminal hydrogen atoms which are reactive with isocyanate groups, a molecular weight of from about 500 to about 6,000 which is free from side chain polyethylene oxide units and with a difunctional compound having both terminal hydrogen atoms which are reactive with isocyanate groups and side chain polyethylene oxide units. Conventional chainlengthening agents with a molecular Weight below 500 (optional chain-lengthening agents) as well as the usual auxiliary agents and additives customarily used in polyurethane chemistry may also be used. The difunctional organic compounds containing terminal hydrogen atoms which are reactive with isocyanate groups and contain side chain polyethylene oxide units are those of the general formula 1 given above.
The invention also comtemplates the polyurethanes obtainable by this process.
Any organic diisocyanate of the general formula R(NCO) in which R represents an organic group such as can be obtained by removing the isocyanate groups from an organic diisocyanate with a molecular weight of from about 1 12 to about 1,000, preferably abut 140 to about 400 may be used. Diisocyanates which are particularly suitable for the process provided by the invention are those of the general formula R(NCO) in which R represents a divalent aliphatic hydrocarbon group containing 4 to 18 carbon atoms, a divalent cycloaliphatic hydrocarbon group containing 5 to 15 carbon atoms, a divalent aromatic hydrocarbon group containing 6 to 15 carbon atoms or an araliphatic hydrocarbon group containing 7 to 15 carbon atoms. The following are examples of typical representatives of these organic diisocyanates which are particularly suitable for the process according to the invention: tetramethylene diisocyanate, hexamethylene diisocyanate, dodecamethylene diisocyanate, cyclohexane-l,3- diisocyanate, cyclohexane- 1,4-diisocyanat6. 1- isocyanato-3-isocyanatomethyl-3,5,5-trimethyl cyclohexane and 4,4-diisocyanatodicyclohexylmethane as well as aromatic diisocyanates such as 2,4- diisocyanatotoluene and 2,6-diiscyanatotoluene and mixtures of these isomers, 4,4- diisocyanatodiphenylmethane, l ,5-
diisocyanatonaphthalene and the like.
Any suitable difunctional organic compound having terminal groups which contains hydrogen atoms determinable by the Zerewitinoff method and has a molecular weight in the range of about 500 to about 6,000, preferably about 600 to 3000, may be used.
Any suitable dihydroxy polyesters known per se in polyurethane chemistry which is obtained by esterification of a dicarboxylic acid such as succinic acid, adipic acid, suberic acid, azelaic acid, sebacic acid, phthalic acid, isophthalic acid, terephthalic acid, tetrahydrophthalic acid, and the like, and diols such ethylene glycol, propylene-1,2-glycol, propylene-1,3-glycol, diethylene glycol, butane-1,4-diol, hexane-1,6-diol, octane-1,8-diol, neopentyl glycol, 2-methylpropane-l,3- diol or the various isomeric bis-hydroxymethyl cyclohexanes and the like may be used.
Any suitable polylactone known per se in polyurethane chemistry, e.g. polymers of e-caprolactone and one of the abovementioned dihydric alcohols may be used.
Any suitable polycarbonate known per se in polyurethane chemistry which may be obtained, for example, by reacting the above-mentioned diols with diaryl carbonates or phosgene may be used.
Any suitable polyether known per se in polyurethane chemistry, e.g. polymers or copolymers of styrene oxide, propylene oxide, tetrahydrofuran, butylene oxide or epichlorohydrin, which polymers or copolymers are prepared from divalent starter molecules such as water, the above-mentioned diols or amines which contain 2 N-H bonds may be used. A certain amount of ethylene oxide may also be used in the preparation of these compounds, provided the polyether used does not contain more than about 10 percent by weight of ethylene oxide. In general, however, polyethers which have been obtained without the addition of ethylene oxide are used.
Any suitable polythioether, polythio mixed ethers and polythioether esters known per se in polyurethane chemistry may be used.
Any suitable polyacetal known per se in polyurethane chemistry, for example those obtained from the above-mentioned diols and formaldehyde may be used.
Any suitable difunctional polyether ester containing terminal groups which are reactive with isocyanate groups may be used.
It is preferred to use dihydroxy polyesters, dihydroxy polylactones and dihydroxy polycarbonates as the organic compound having a molecular weight of at least about 500 in the process according to the invention.
Any suitable chain-lengthening agents having a molecular Weight below 500 may be used as optional chain extenders in the process according to the invention for producing the polyurethanes which can be dispersed without the aid of dispersing agents such as, for example, the low-molecular weight diols which have been described for the preparation of dihydroxy polyesters and the like, or also diamines such as diaminoethane, l ,6-diaminohexane, pipcrazine, 2,5-dimethyl piperazine, 'l -amino-3-aminoethyl-3,5 ,S-trimethylcyclohexane, 4,4-diaminodicyclohexylmethane, |,4- diaminocyclohexane or l,2-propylenediamine or also hydrazine, aminoacid hydrazides, hydrazides of semicarbazidocarboxylic acids, bis-hydrazides, bis semicarbazides, and the like.
In order to synthesize the new 'self-dispersible polyurethanes, it is an essential feature of the invention to use organic compounds which contain both hydrogen atoms capable of reacting with isocyanate groups and side chain ethylene oxide units, as represented by the above general formula 1.
These compounds having ethylene oxide derived side chains which are essential to the invention will hereinafter be referred to as hydrophilic chain-lengthening agents.
Preparation of the hydrophilic chain-lengthening agents may be carried out, for example, as follows:
Monovalent alcohols or monovalent phenols of the general formula RXH (X are first prepared in known manner or the corresponding monovalent a1- cohols containing polyethylene oxide units as represented by the formula are prepared by ethoxylation of secondary amines of the general formula R-XH (X -NR-). 1n the above formula 11, R and R" represent identical or different hydrocarbon groups, in particular C to C alkyl groups, C to C cycloalkyl groups, C to C aryl groups or C to C aralkyl groups.
Any suitable alcohol or phenol may be used such as, for example, methanol, ethanol, n-propanol, n-hexano1, ndecano1, isopropanol, tertiary butanol, phenol, pcresol, benzyl alcohol or the like. Any suitable secondary amine may be used such as, for example, dimethylamine, diethylamine, dipropylamine, N- methylhexylamine, N-ethyl-decylamine, N-methylaniline, N-ethylbenzylamine, N-methy1cyc1ohexy1amine, or the like.
The quantity of ethylene oxide grafted into the molecule may vary within wide limits. The polyethylene oxide chains generally consist of from about to about 90 and preferably about 20 to about 70 ethylene oxid units.
1n the second reaction stage, the resulting monovalent alcohols which contain polyethylene oxide units are reacted with a large excess of one of the diisocyanates of the general formula R(NCO) given above as examples, followed by removal of the diisocyanate excess to obtain, the corresponding monoisocyanate which contains polyethylene oxide units as represented by the general formula quent removal of the diisocyanate excess is preferably carried out by thin-layer vacuum distillation at about 100C to about 180C. i
6 The hydrophilic chainlengthening agent is then obtained in the third reaction step by reacting the above described monoisocyanates which contain polyethylene oxide units with dialkanolamines of the general formula in which -R has the meanings already indicated above. In this third reaction step, the reactants are preferably used in stoichiometric proportions. This step of the reaction is preferably carried out at temperatures between about 0 and about 50C, preferably at about 15 to about 30C. Suitable dialkanolamines of the general formula shown above are, for example, diethanolamine, dipropanolamine (R" CH bis-( 2-hydroxy- 2-pheny1-ethy1)-amine and the like.
The use of components which are exclusively difunctional is an essential feature of the process according to the invention for producing the self-dispersible polyurethanes and for preparing non-ionic polyurethane dispersions. As is known from the chemistry of high polymer latices, however, in some cases the addition of very small quantities of trifunctional low-molecular weight compounds, e.g. trifunctional isocyanates or trifunctional chain-lengthening agents, may improve the properties of the product. However, such trifunctional components should not be used in quantities of more than one equivalent percent, based on all the building components which take part in the polyaddition reaction.
The process provided by the invention for producing the self-dispersible polyurethanes may be carried out by the known methods of polyurethane chemistry, either by the one-stage process or by the two-stage process (prepolymer process).
The reactants for producing the self-dispersible polyurethanes may be used in an equivalent ratio of isocyanate groups to groups which are reactive with isocyanate groups of between about 0.8:] and about 2.5:1, preferably between about 0.95:1 and about 1.5: 1. If an excess of NCO is used, the compounds obtained obviously contain NCO-groups which when the compounds are converted into an aqueous dispersion continue to react with water by a chain-lengthening reaction to yield the dispersed end product. The equivalent ratios given above therefore include all the components which take part in the synthesis of the polyurethanes 20% by weight, of side chain polyethylene oxide segments.
Both theone-stage method and the two-stage method of the process may be carried out either with or without solvents. Anysuitable organic solvent may be used, especially if production of the polyurethanes is intended to be accompanied or followed by conversion of the polyurethanes into an aqueous dispersion, including, for example, those solvents which are miscible with water and inert towards isocyanate groups and have a boiling point below 100C, for example, acetone or methyl ethyl ketone.
If the one-stage process is employed, the difunctional organic compounds which have a molecular weight of from about 500 to about 6,000 and contain groups capable of reacting with isocyanate groups, are preferably mixed with the hydrophilic chain-lengthening agent and with the optional chain-lengthening agent having amolecular weight below 500. The chain-lengthening agents with a molecular weight below; 500 which are optionally used in the one-stage process may be the diols disclosed above for the preparation of .dihydroxy polyesters. The diisocyanate component is then added to the resulting mixture without solvents, and reaction of the mixture is then brought about, preferably at tem peratures of about 50 to about 150C, optionally after the addition of catalysts commonly used in polyurethane chemistry. The quantity of diisocyanate component used is. such .that the NCO/OH-ratio is between about 0.8 and about 1.05. The, viscosity of the mixture rises during the reaction, and one of the aforementioned solvents is therefore gradually added to the mixture. An organic solvent solution of the completely reacted polyurethane is thus obtained and the concentrationof this solutionis preferably adjusted to a solids content of about 1 to about 50percent by weight, preferably about to about 40 percent by weight.
Conversion of the dissolved polyurethane elastomers into an aqueous dispersion may then be carried outconveniently by adding water to the stirred solution. In many cases, the solution then passes through the phase of a water-in-oil emulsion until it passes av viscosity maximum, at which point there is a sudden changeover into an oil-in water emulsion. After removal of the sol-- vent by distillation, a purely aqueous stable dispersion is left behind. i
prepolymer may then be reacted in known manner with the optional chain-lengthening agent which has a molecular weight below SOOsuch as those given as examples above. To prepare the polyurethane dispersions according to the invention, it is advisable to use a special variation of the two-stage process in which the chain-lengthening agent, in this-case preferably one of the above-mentioned diamines or hydrazine derivatives, dissolved ina small quantity of water or a mixture of water and solvents, is added to the above-described solution of the NCO prepolymer in such quantities that the NCO/OH ratio is between about 2.5 and about l.O5. This reaction may be carried out atroom temper.
ature or preferably at about 250? to 609C. Subsequent and about additionof the remainder of the water followed by removal of the solvent yields the polyurethane dispersion. In this variation of the-process, the optional chainlengthening agent may, if desired, be dissolved in the total quantity of water subsequently present in the dispersion (50 to 200% by weight based on solid polyurethane).
in principle, the polyurethane elastomers provided by, the invention ,can. also be converted into dispersions by other methods, for example, dispersion can be carried out without using solvents, e.g. by mixing the solvent-free elastomer melt with water in an apparatus which is capable. of producing high shearing gradients, or it can be carried out with very small quantities of solvents to act as plasticizing agents, again using the same apparatus, or it can be carried out with the aid of nonmechanical dispersing agents such as sound waves of extremely high frequency. Also, in the case of polyurethane ureas,"chain-lengthening can be carried out after conversion of the propolymer into an aqueous emulsion.
Polyurethane dispersed in accordance with the. invention have an average particle size of about 0.5 mg. to about 5ma, preferably about 100 to 500 mu, the optical dispersion or Tyndall effect obviously beginning to appear at dispersions with particle sizes below 500 mg.
The rheological characteristics of the dispersions, which will not be discussed in detail here, depend on the particle size and the concentration of the dispersion. As the particles become very small, the viscosity increases and moreover with particles measuring less than about 100 my., the flow limit progressively increases with decreasing particle size (Bingham body). Regardless of this relationship, the viscosity increases with increasing concentration which may be as high as in this class of dispersions, the viscosity in some cases reaching a value of 50 cP.
The dispersions are insensitive to electrolytes and consequently the latex particles may be subjected, for example, to acid catalyzed cross-linking with formaldehyde or formaldehyde derivatives; they may also be pigmented with electrolytically active pigments or sions, e.g. with dispersions of polyvinyl acetate, polyethylene, polystyrene, polybutadiene, polyvinyl chloride, co-polymer synthetic resins .or the like.
Any suitable dispersion of filler, plasticizer, pigment, carbon black, silica sol, aluminium, clay, asbestos or the like may also be incorporated in the dispersions.
The dispersions of the polyurethane compounds are stable in water and can be stored and transported and worked up at anylater date, e.g., into shaped products. They generally dry directly to dimensionally stable synthetic coatings although the products of the process may also be shaped in the presence of known crosslinking agents. The polyurethanes obtained vary in their properties according to the elected chemical composition and the urethane group content. They may be obtained in the form of soft, sticky compounds or thermoplastic or rubbery elastic products within a wide range of hardness up to glasshard duroplasts. The hdrophilic character of the products may also vary within wide limits. The elastic products can be worked thermoplastically at elevated temperatures, for example 100 to 180C.
The products of the process are suitable for coating, covering or impregnating woven or non-woven textiles, leather, paper, wood, metal, ceramic, stone, concrete, bitumen, hard fiber, straw, glass, porcelain, synthetic resins of various kinds of glassfibers to produce antistatie and crease-resistant finishes or they may be used as binders for fleeces, adhesives, adhesifying agents, laminating agents, agents to render products hydrophobic, plasticizers or binders, e.g. for corkmeal or sawdust, glassfibers, asbestos, paper-type materials, plastics or rubber waste or ceramic materials or as auxiliary agents in clothprinting and in the paper industry, as adhesives for polymers, as sizing agents, e.g., for glass fibers, and for finishing leather.
For these purposes, the dispersions or pastes are preferably applied to a porous support which subsequently remains bonded to the finished product, e.g. woven or non-woven textiles or fiber mats, felts or fleeces or also paper fleeces, foam plastics foils or split leather, substances which cause immediate solidification of the coating by virtue of their absorbent action. The materials are then dried at elevated temperature and if necessary pressed. Drying may also be carried out on smooth, porous or non-porous materials such as metal, glass, paper, cardboard, ceramic materials, sheet steel, silicone rubber or aluminium foil, in which case the finished sheet product is then lifted off and used as such or applied to a substrate by the reversal process by glueing, flame-laminating or calendering. Application by the reversal process may be carried out at any time.
The properties of the products of the process can be modified by the addition of vinyl polymers or active or inactive fillers, for example polyethylene, polypropylene, polyvinyl acetate or ethylene/vinyl acetate copolyrriers which may be saponified or partly saponified and- /or grafted with vinyl chloride; styrene/butadiene copolymers, ethylene (graft) copolymers, carbon black, silica, asbestos, talcum, kaolin, titanium dioxide, glass in the form of powder or fibers, and cellulose. The end product may contain up to 70% of such fillers, based on the total quantity of dry substances, depending on the required properties and the purpose for which the end products are to be used.
Dyes, pigments, plasticizers or additives which influence the flow properties may, of course, also be added.
After the products have been applied by the various techniques, they may be dried at room temperature or at elevated temperature. The drying temperature to be selected in each individual case, which depends not only on the chemical composition of the material but above all on the moisture content, the drying time and the thickness of the layer, can easily be determined by a preliminary test. For any given heating time, the dry ing temperature must in any case be below the solidification temperature.
The sheet structures may be coated subsequently with a finish to increase the resistance of the surface. Aqueous dispersions or solutions are again preferably used for this purpose.
EXAMPLE 1 Three hundred and seventy parts of a linear polyester diol of adipic acid, hexanediol and 2,2-dimethylpropane-1,3-diol having an OH-number of about 66 were mixed with 53 parts of a compound (hereinafter termed dispersing agent A) of one mol of a polyethylene oxide ether with OH-numlber 48 which had been initiated on n-butanol, one mol of hexamethylene-l ,6- diisocyanate and one mol of bis-(B-hydroxyethyhamine, and to this mixture were added 1 l 1 parts of 3- isocyanatomethyl-3,5,5-trimethylcyclohexylisocyanate and the mixture was heated to a temperature of C. Heating was continued for 3 hours with stirring and the exclusion of atmospheric moisture. The isocyanate content of the mixture dropped to 4.7% during this time. The mixture was then cooled to 60C and diluted] with 1,020 parts of acetone.
A solution of' 15 parts of diaminoethane in parts of water was prepared and rapidly added to the reac- I tion solution and homogeneously mixed with stirring. 700 parts of water were rapidly added with vigorous stirring to the resulting clear solution which contained 35% solids, a milky white dispersion of the solid in water being formed. The dispersion contained acetone and it had a brownish, translucent appearance when viewed in thin layers. After removal of the acetone by distillation under a pressure of 100 mm.Hg, a pure, aqueous dispersion of the polyurethane urea solid was left behind. It had a solid content of 40%.
Tensile strength: Elongation at break:
kg,wt./cm 910 "/1 The products of Examples 2 to 19 summarized in the following table were prepared by the process described in Example 1.
Table 1 Examples 2 19 1 11 111 IV Macrodiol Dispersing Diisocyan- Equivalent Chain Equivalent Concentration Tensile Example of agent ate ratio lengthening ratio polyethylene strength/ No.
NCO/OH agent concentration oxide units elongation based on NCO/NH based (71 by weight) at break In 1, 11 and on prepolymer polyurethane 111 and chainsolid lengthening agent Polyester of hexane B D/E* 2.0 G/H** 1.25 407! 8.6 210/820 2 diol,2,2- dimethyl- B D/E* 2.2 G/H** 1.33 50% 5.1 260/730 3 propanediol Adipic acid 6O6H-number B D/E* 2.0 G 1.4 50% 5.8 190/900 4 B D/E* 2.0 l 1.25 40% 8.5 250/640 5 B .E 2.0 l 1.25 40% 8.6 170/1070 6 A D 2.0 H 1.1 40% 7.4 198/730 7 C D 2.0 G 1.0 4071 8.4 170/800 8 Polyester of hexane C D 2.0 L 1.0 357: 14.0 180/600 9 diol. B D 2.0 G/H** 1.25 4071 13.0 190/580 [0 acid OH- number 130 A D 2.0 L 1.0 4071 685 200/830 1 l Polyester of butane diol. B D/E* 2.5 H 1.7 4071 9.6 170/920 12 adipic acid OH-number 1 l7 OHnumher 50 C D/E* 2.5 L 1.25 4071 l 1.6 230/640 13 C D/E* 3.3 C 1.25 3571 11.3 240/810 14 Polyester 1 of ethylene glycol, adipic acid, phthalic acid. OH-' number 65 B D/E* 2.5 G 1.4 3071 8.6 175/630 15 Polyester 2 of diethylene glycol. adipic acid OH-number 40 Polycarbon- B D/E* 2. G 1.25 40% 7.6 350/640 16 ate of hexanediol B D/E* 2. G/H** 1.25 4071 7.8 320/510 17 OH number 56 B D/E* 2.2 l 1.25 40% 7.5 250/740 18 Polycarbonate of hexanediol B D/E* 3.0 H l. 1 4071 7.7 220/460 19 tetramethylene 'glyeol OH number 90 see example 1 3-isocyanatomethyl-3.5,5-trimethyl-cyclohexyl isocyanate hexamethylenel ,6-diisocyanate 3-aminomethyl-3 5 5-trimethy| cyclohexylamine hydrazine monohydrate 4,4'-diaminodicyclohexylmethane diaminoethane *molar ratio 1:1
"molar ratio 131 EXAMPLE 234 parts of a polyester diol of adipic acid and diethylenc glycol with OH-number approximately 40 are mixed with 49.5 parts ofdispersing agent A from Example 1 in the solventfree melt at C. 15.7 parts of butane-1.4-diol were then added and also homogeneously mixed. 25.2 parts of an 80:20 mixture of tolylene-ZA-diisoCyanate and tolylene-2,6diisocyanate were then added all at once to this mixture with stirring. The temperature was then raised to 90C. The viscosity of the mixture then rapidly rose and reached a same as dispersing agent A (example 1 OH-number of polyether 29 same as dispersing agent A (example 1 OH-number of polyether 25.5
value of about 20,000 cP in 15 minutes. 50 parts of acetone were then added. whereupon the temperature dropped to about C with vigorous boiling. The viscosity fell at this stage but then started to increase again slowly. whereupon a further 50 parts of acetone were added.
This process was repeated until 6000 parts of acetone had been added. A clear solution of a polyester polyurethane in acetone with a solids content of 35% was obtained. This solution was cooled to 30C and 525 parts of water were then added all at once with vigorous stirring. A bluish-white, medium viscosity dispersion of the solid in the acetone/water mixture was soft and slightly sticky film was left behind which had a thickness of y, and the following mechanical propabout, 6,000 and is free fro'irf'side chain polyethylene oxide units and 'withan organic compound which is di-" functional for the purpose of the isocyanate polyaddition reaction, contains terminal hydrogen atoms which are reactive with isocyanate groups and contains side chain polyethylene oxide units, said organic compound containing side chain polyethylene oxide units having the formula erties: a I r r a I HO-CHCH. ,-NCH ,CHOH Tensile strength: I70 kgwL/cm g j I Elongation at break: I090 "/1 l5 R I v +CH, cH. ,-o+,;CH,-cH, x-R' The products in the' following examples 2] and 22 were preparedby the process described in Example 20. in which Table 2 Macrodiol Dispersing Diiso; Equivalent Chain- Equivalent Concentra- Concentra- Tensile Example agent cyanate ratio lengthening ratio tion tion of strength, No,
NCO/OH agent NCO/NH based polyethylelongation based on on prepolymer ene oxide at break I and ill and chain units (/1 lengthening by weight) I ll lll agent in polyurc' thane s'olid Polyester of ethylene glycol. A F 3.0 K 0.99 4071 l l.' 205/980 2l adipic acid OH-number 56 Polyester of butane adipic acid M F 3.3 K L] 407: 8.8 185/1000 22 OH-numher 50 A: see table I M: same as dispensing agent A (example I OH-number of the polyether 32 F: 80:20 mixture of tolylene-2,4- and -2,6-diisocyanate K: butane-1,4-diol Any of the other organic compounds having a molecular weight of from about 500 to about 6,000, optional chain-lengthening agents, hydrophallic chain lengthening agents and organic polyisocyanates disclosed as suitable herein may be substituted into the foregoing examples. Other suitable components for making the polyurethanes are disclosed in US. Pat. No. 3,479,310 granted November 18, I969 and in the book by Saunders and Frisch: Polyurethanes Chemistry and Technology" published by lnterscience Publishers, Copyright 1962, the disclosures of which are incorporated herein by reference thereto.
Although the invention has been described in detail for the purpose of illustration, it is to be understood that such detail is solely for that purpose and that variations therein can be made by those skilled in the art without departing from the spriit and scope of the invention except as it may be limited by the claims.
What is claimed is:
1. A process for making non-ionic aqueous polyurethane dispersions free from emulsifier which comprises reacting an organic diisocyanate and an organic compound which is difunctional for the purpose of an isocyanate polyaddition reaction, contains terminal hydrogen atoms which are reactive with isocyanate groups, has a molecular weight range of from about 500 to R represents a divalent group obtained by removing the isocyanate groups from a diisocyanate with a molecular weight of from about l 12 to about 1000,
: X represents oxygen or NR" R and R" are identical or different and represent monovalent hydrocabon groups containing 1 to 12 carbon atoms,
R represents hydrogen or a. monovalent hydrocarbon group containing 1 to 8 carbon atoms and n represents an integer of from 4 to 89.
2. A polyurethane dispersion prepared by the process of claim 1.
3. A process for producing thermoplastic non-ionic polyurethane elastomers which are dispersible in water and have a substantially linear molecular structure which comprises reacting an organic diisocyanate with an organic compound which is difunctional for the purpose of an isocyanate polyaddition reaction, contains terminal hydrogen atoms which are reactive with isocyanate groups, has a molecular weight of from about 500 to about 6,000 and is free from side chain polyethyleilG oxide units and with an organic compound which is difunctional for the purpose of an isocyanate polyaddltion reaction and contains terminal hydrogen atom! which are reactive with isocyanato groups and side chain polyethylene oxide units, said compound @081- taining side chain polyethylene oxide units having the general formula V in which R represents a divalent group obtained by removing the isocyanate groups from a diisocyanate with a molecular weight of from about 1 12 to about 1000,
X represents oxygen or -NR,
R and R are identical or different and represent monovalent hydrocarbon groups containing 1 to 12 carbon atoms,
R represents hydrogen or a monovalent hydrocarfrom ethylene oxide arid a hydrophilic chain lengthening agent having the formula 6. The process of claim 1 wherein a difunctional organic compound having hydrogen atoms reactive with isocyanato groups, a molecular weight of below 500 and free from groups derived from ethylene oxide is included in the reaction mixture.
7. The process of claim 3 wherein a difunctional organic compound having hydrogen atoms reactive with isocyanato groups, a molecular weight of below 500 and free from groups derived from ethylene oxide is included in the reaction mixture.
8. The process of claim 5 wherein a difunctional organic compound having hydrogen atoms reactive with isocyanato groups, a molecular weight of below 500 and free from groups derived from ethylene oxide is included in the reaction mixture.
9. A process for making dispersions which comprises dispersing the product of claim 5 in water.
Patent Citations
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I usually think of him by his first and last name, or sometimes just his last name, but that would make him too traceable, or me too traceable to him, so I'll call him 'Solace' because that's the name he used when we were antagonistic correspondents (pen-enemies). It's short for 'All Solace Everywhere,' which is a very annoying name that sums him up pretty well.
I don't even know what I'm doing here; I just discovered this site today, but it looks like a lot of kids not all that different from me write a lot of stuff here that may be crap or may actually be kind of meaningful, so I'm willing to give it (whatever 'it' is) a shot without worrying too much about clogging up the Internet with my irrelevant musings.


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Congratulations to the recipients of the 2013 Team DC College Scholarship Awards!
- Terrance Curry – T.C. Williams High School (Alexandria, VA)
- Sarah Kerndt – West Springfield High School (Springfield, VA)
- Christian Tarver – Bell Multicultural High School (District of Columbia)
- Laura Ventura – Walter Johnson High School (Bethesda, MD)
The presentation of the Scholarships took place on Thursday, July 18 at the annual Champions Awards Reception.
Guest speaker was former NFL player Wade Davis.
Special thanks to the Capital Tennis Association, DC Gay Flag Football League and the DC Front Runners for making the Team DC College Scholarship program a part of their fundraising efforts.


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- Product Information
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Its a pirate theme party. Our bounty of pirate paper goods include our skull and sword Pirate Party paper goods group a great choice for pirate parties for all ages. Our Pirate Party beverage napkins are sold 16 to a pack. Please order in increments of 1 pack.
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This company has an easy site to look thru and super fast service.
(Posted on 10/25/13)
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Ideas on Decorating for Hanukkah Celebrations This Year
Invite friends and family over for a Hanukkah celebration! Decorate the party space in blue, white and silver and serve traditional foods while making memories.
Ugly Christmas Sweater Party Ideas
Host a fun and tacky Ugly Christmas Sweater Party this holiday season! Invite friends over for an ugly sweater contest, karaoke, drinks and more, with these great party ideas and tips.
How to Create the Perfect Holiday Party Look with Holiday Party Accessories
Whether it's a company holiday party or an Ugly Christmas Sweater Party, you can make your party attire look fun and festive when you add the right holiday party accessories!


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"With every passing year, we have a greater understanding of the magnitude of Dr. King's achievements and the historic place he occupies in the pantheon of American heroes."
—Tom Brokaw
On the 50th Anniversary of "Letter from Birmingham Jail"
April 16th marks the 50th anniversary of the Reverend Dr. Martin Luther King Jr.'s "Letter from Birmingham Jail," a passionate response by Dr. King to eight white clergymen who argued that racial segregation should be fought in the courts and not by protest in the streets. The letter is Dr. King's answer to claims that he was an outside agitator when he was, in reality, a peaceful protester, saying, "Injustice anywhere is a threat to justice everywhere." (More information... )
Why We Can't Wait Turns 50
Often applauded as King's most incisive and eloquent book, Why We Can't Wait recounts the Birmingham campaign in vivid detail, while underscoring why 1963 was such a crucial year for the civil rights movement. King examines the history of the civil rights struggle and the tasks that future generations must accomplish to bring about full equality.


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Google AND Yahoo! hijacked in Ireland after domain namespace grab
Google and Yahoo!'s Irish domains were briefly hijacked on Tuesday afternoon, the IE Domain Registry (IEDR) has confirmed. Fraud officers from the Garda Bureau of Fraud Investigation are said to be investigating how malefactors were able to take the websites offline for several hours after mischievously changing both Yahoo.ie …
Heads will roll for that one. Ouch!
Unlikely, the problems are from the top down.
Many in work here phoned my IT desk saying the internet wasn't working, after the 5th call we asked them "had they typed google into google" ( With apologies to the IT crowd)
Well kept us amused anyway
I'm surprised they managed to get hold of a .ie domain in the first place, it's bloody difficult to register one unless you are Irish, speak Irish, and preferably have never left Ireland your entire life.
If you happen to be a UK based company with an Irish office then be prepared for days and days of wrangling just to get one .ie address.
But if you are an American company who only pays tax in Ireland on their earnings in the UK you can expect a bit more red-carpet treatment.
Trust me, if you actually had to speak Irish to get a .ie registration then very few people even in Ireland would be able to manage it. But this does reinforce the impression of IEDR as an amateur-hour operation - with exceptionally high prices, too, natch.
[ ] human error
[x] something more sinister
[x] something more sinister
A secret sinister plot by the Irish intelligence agency to take over Google and !Yahoo! ?
Slow News Day
Someone guessed a domain registrar's password and did a bit of DNS redirection. Nothing to see here. Move along.
I'm delighted - it couldn't have happened to a more anal-retentive bunch of dicks. Good work IEDR! NOT.
What action have the IEDR taken?
"Last night IEDR took all their websites and WHOIS offline. The main IEDR site is still offline and is currently displaying a message about the incident, while the API and WHOIS are running as normal". link
Hang on....
...involving two high profile .ie domains
Well, there's an oxymoron for a start.
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Join the 'Evista' group to help and get support from people like you.
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Tel: (618)476-3510
St. James Catholic School provides a superior educational program for students from Pre-Kindergarten through Eighth grade.
We are to proclaim the love of God by word and action through teaching, prayer and community service.
We strive to meet the spiritual, intellectual, physical, social, moral, emotional and technological needs of our students and challenge them to work to the best of their ability.
School and parent cooperation is essential in the emotional and academic development of children.
It is in this spirit that St. James Catholic School has adopted the following policy St. James School expects parental cooperation and support regarding all school policies and procedures as criteria for continued enrollment in St. James Catholic School.
St. James Catholic School admits students of any race, gender, color, national and ethnic origin to all the rights, privileges, programs and activities generally accorded or made available to students at the school.
Students are not discriminated against on the basis of gender, race, color, national and ethnic origin in administration of its educational policies, scholarship and local programs, athletic and other school administered programs.
School Overview
|School Membership(s)School Assoc.
|National Catholic Educational Association (NCEA)
|Religious Affiliation
|Roman Catholic
|Grades Offered
|Grades Prekindergarten - 8
Student Body
|Total Students
|116 students
|Student Body Type
|% Students of Color
State avg.: 29%
|Students by Grade
Academics and Faculty
|Total Classroom Teachers
|11 teachers
|Student : Teacher Ratio
National avg.: 13:1
Nearby Schools:
All Schools | High Schools | Elementary Schools | Preschools | Public Schools
Show me:
- School Location Miles Students Grades
ColumbiaImmaculate Conception
321 S Metter Avenue
Columbia, IL, 62236
(618)281-5353(Roman Catholic)5.5 mi | 349 students | Gr. PK-8
BellevilleOur Lady Queen Of Peace School
5915 N Belt W
Belleville, IL, 62223
(618)234-1206(Roman Catholic)6.7 mi | 215 students | Gr. PK-8
SmithtonSt John The Baptist School
10 S Lincoln St
Smithton, IL, 62285
(618)233-05816.8 mi | 74 students | Gr. PK-8
DupoApostolic Learning Academy
400 Louisa Avenue
Dupo, IL, 62239
(618)286-4279(Pentecostal)7 mi | n/a students | Gr. K-12
BellevilleAlthoff Catholic High School
5401 W Main St
Belleville, IL, 62226
(618)235-1100(Roman Catholic)7.1 mi | 417 students | Gr. 9-12
School Reviews
Area Statistics
Recent Articles
Updated October 26, 2014
What do you do when you are dissatisfied with your local public schools? Homeschool your children? Send them to private school? Let's look at your options.
Your religion matters to you. You want your child to attend a school which will combine academics and religious education. Here is an overview of what is available together with some links to denominational web sites.
Add things up and you'll quickly find the answer- math is crucial both in academics and the real world. By following these strategies and following personal training programs, students can uncover their weaknesses and conquer math.
More ArticlesElementary Issues, Running a Private School, Pre-elementary, Opinion, Why Private School


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Welcome to revolution corner, or 'The only spot on the interlink to buy one-off die-cut stickers'. Individual slices of personality, totally unique and 400% awesome. A splendid way to collect t-shirt designs when your wardrobe is full.
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Estate of John E. Passaneau, late of Centre County, Pennsylvania. Carmine Prestia, Executrix, PO Box 332, State College, PA 16804. H. Amos Goodall, Jr., Esquire, Goodall & Yurchak, P.C., 328 South Atherton St., State College, PA 16801, Attorneys. All persons...More info Email a friend
ESTATE NOTICE DECEDENT: Ruth Virginia Sunday, Late of College Township, Centre County, Pennsylvania EXECUTOR Norman Sunday, Jr. 415 Wayne Street Johnstown, PA 15905 Linda S. Carter 70 E. Ridge Street Carlisle, PA ATTORNEY: Robert A. Mix, Esquire Lee, Green...More info Email a friend
BENNER TOWNSHIP CENTRE COUNTY, PENNSYLVANIA NOTICE OF PUBLIC HEARING THE BENNER TOWNSHIP BOARD OF SUPERVISORS WILL HOLD A PUBLIC HEARING ON DECEMBER 1, 2014 AT 7:00 P.M. AT 1224 BUFFALO RUN ROAD, BELLEFONTE, PA 16823 FOR THE PURPOSE OF CONSIDERING THE...More info Email a friend
ESTATE NOTICE MCMULLIN, RALPH G., late of 402 Catherine Street, Milesburg, Boggs Township, Centre County, Pennsylvania. Executor - Robert L. McMullin, 404 Catherine Street, P.O. Box 332, Milesburg, PA 16853 Attorney - John R. Miller, III, Esquire, Miller...More info Email a friend
NOTICE IS HEREBY GIVEN that articles of incorporation were filed with the Department of State of the Commonealth of Pennsylvania for GLOCAL RESOURCES, formed pursuant to the provisions of the Pennsylvania Nonprofit Corporation Law of 1988 for charitable...More info Email a friend
Notice of Intent to appoint CPA The Potter Township Board of Supervisors gives notice of its intent to appoint a Certified Public Accountant to perform the annual audit in place of the elected auditors for fiscal year ending 12/31/2014. The CPA will be...More info Email a friend
PATTON TOWNSHIP ORDINANCE CONSIDERATION REAR YARD SETBACKS FOR POOLS AND ACCESSORY STRUCTURES IN THE A-1 AND R-1 DISTRICTS The Patton Township Board of Supervisors will hold a public meeting beginning at 7:00 PM on December 10, 2014, at the Patton Township...More info Email a friend
MID-CENTRE COUNTY AUTHORITY WILL MEET ON THE FOLLOWING DATES IN 2015 AT 7:00 PM AT THEIR OFFICE LOCATED AT 296 MID-CENTRE LANE, HOWARD, PA JANUARY 14, FEBRUARY 11, MARCH 11, APRIL 8, MAY 13, JUNE 10, JULY 8, AUGUST 12, SEPTEMBER 9, OCTOBER 14, NOVEMBER ...More info Email a friend
NOTICE IS HEREBY GIVEN, pursuant to the provisions of the Fictitious Name Act, 1982-295 (54 Pa.C.S. § 311) that the Fictitious Name of "WPE-Consulting" was registered in the Office of the Secretary of the Commonwealth of Pennsylvania on October 31, 2014...More info Email a friend
NOTICE NOTICE IS HEREBY GIVEN that the Consolidated Return of the Centre County Tax Claim Bureau in connection with the Centre County Tax Sale of September 24, 2014, No. 2014-4366 filed with the Centre County Court of Common Pleas on November 12, 2014...More info Email a friend


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CNET breaks out the most important things to know when shopping for a new television.
What good is a digital assistant if she can't tell you to leave early because of traffic reports? That's a question asked by Microsoft at any rate.
Biotech startup Suneris has developed a plant-based polymer it says functions like "Lego building blocks for the body," drastically reducing the amount of time it takes to stop a wound from bleeding.
The JBL Cinema Base is a likable smaller sound base that offers easy hookup and packs a home-theater punch.
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Video games made by small studios have an effective tool in their arsenal when it comes to setting themselves apart.
The Internet giant faces yet another tussle with European officials, who want Google to split off its search business.
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A year after exiting BlackBerry, Thorsten Heins weighs in on his time at the smartphone maker and dishes on his current phone.
The most important things to know when shopping for a new laptop, hybrid, or Windows tablet.


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- CII Conference on "Chemistry Everywhere" Click Here
- Seminar on Operation & Maintenance of Caustic Evaporation & Flaking units and Exhibition Click Here
Alkali Manufacturers' Association of India
Promoting sustainable development and growth of Indian Alkali Industry
Mission Statement
Represent Indian Chlor-Alkali Industry nationally and globally and facilitate the industry's commitment to technological and economic growth, continuous improvement in protecting human health and environment, guided by sound science, technology and risk management principles. AMAI will achieve this by proactively promoting the industry through practices that are fair, inclusive and sustainable.
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Seminar on "Operation & Maintenance of Caustic Evaporation & Flaking units"
Seminar Topics New Developments and Advancements in Caustic Evaporation & Flaking Units by Technology Suppliers Innovations & New Developments by... Read More →


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Republican Grove is a populated place located in Halifax County at latitude 36.945 and longitude -79.044.
The elevation is 643 feet. Republican Grove appears on the Republican Grove U.S. Geological Survey Map. Halifax County is in the Eastern Time Zone (UTC -5 hours).
Halifax County: Cities & Towns | ZIP Codes | Schools | Features (airports, churches, hospitals, etc.)
BIG Map |
Driving Directions |
Data Source - USGS GNIS FID: 1477676
BOUNDARY MAPS: District 1 | Halifax County
Republican Grove, VA
(< 0.1 mile)
Volens, VA (1.9 miles ESE)
North Stanton, VA (2.7 miles NW)
Hickory Grove, VA (3.1 miles WSW)
Stovall, VA (3.6 miles N)
Acorn, VA
(3.6 miles ENE)
Leda, VA (3.6 miles SW)
Cody, VA (3.9 miles NW)
Alchie, VA (3.9 miles SSE)
Hermosa, VA (4.3 miles W)
Morefield Mill, VA
(4.3 miles E)
Loftis, VA (4.9 miles ESE)
Chaneys Store, VA (8.2 miles SSW)
Patrick Henry, VA (9.9 miles NE)
Carrington, VA (12.3 miles ESE)
Canterbury Estates, VA
(13.3 miles SSE)
Riverview Heights, VA (13.5 miles SSE)
Banister Town, VA (13.7 miles SSE)
Neals Corner, VA (14.2 miles ESE)
Pleasant Grove, VA (14.7 miles S)
The Demographic Data for the 2,126 Virginia cities, towns, counties, ZIP Codes and Census Designated Places (CDPs) profiled in this gazetteer is updated annually. Last Update: July 1, 2014.
The ZIP Code maps and the data regarding the number of residential and business addresses in each ZIP Code are updated four times per year. Last Update: November 1, 2014.
The information on the 60,784 Virginia Physical, Cultural and Historic Features is updated six times per year. Last Update: October 5, 2014.
The School Attendance Zone Maps for 1,666 Virginia public schools are updated four times per year. Last Update: October 6, 2014.


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Welcome to The Giving Tree Montessori School! Our School was established in 1977. For over thirty years, our goal has been and continues to be, to provide children with the opportunity to develop physically, mentally, and emotionally at their own pace. Our hope is to develop creative, independent children who have enthusiasm towards learning.Our school offers programs for infant through...
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I am so excited about my son starting school here this September! Me and my family went to the open house and were able to meet all the teachers and the...
I love Brooks and all of the teachers and staff TRULY care about ALL students. There are no favorites, they are all treated equally and provide an environment that is diverse, fun and extremely challenging to students.
Montessori School-The Giving Tree is located at 4351 Marseilles St, Detroit, MI. This location is in the Finney neighborhood. This business specializes in Preschools.


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Governor Culver proclaimed this November as Iowa Wine Month; an effort that the owners of local wineries say is significant for the state's wine industry.
Keywords: Bob Wersen, Grape Escape, Iowa Wine Month, Leighton, Pleasantville, Rod Haworth, Tassel Ridge Winery
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The Will to MeaningPaperback Meridian S
List price $13.55
Unavailable - AbeBooks may have this title.
- Publisher: Penguin Books Australia
- Format: Paperback | 208 pages
- Dimensions: 134mm x 203mm x 15mm | 186g
- Publication date: 28 February 1991
- Publication City/Country: Hawthorn
- Edition statement: Expanded ed.
- Sales rank: 68,584
Product description
From the author of "Man's Search for Meaning," one of the most influential works of psychiatric literature since Freud. "Perhaps the most significant thinker since Freud and Adler," said "The American Journal of Psychiatry" about Europe's leading existential psychologist, the founder of logotherapy.
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Author information
Viktor E. Frankl was the former Professor of Neurology and Psychiatry at the University of Vienna Medical School and Distinguished Professor of Logotherapy at the U.S. International University. He was the founder of what has come to be called the Third Viennese School of Psychotherapy (after Freud's psychoanalysis and Adler's individual psychology) -- the school of logotherapy. Born in 1905, Dr. Frankl received the degrees of Doctor of Medicine and Doctor of Philosophy from the University of Vienna. During World War II he spent three years at Auschwitz, Dachau and other concentration camps. Dr. Frankl first published in 1924 in the International Journal of Psychoanalysis and has since published twenty-six books, which have been translated into nineteen languages, including Japanese and Chinese. He has been a visiting professor at Harvard, Duquesne and Southern Methodist Universities. Honorary Degrees have been conferred upon him by Loyola University in Chicago, Edgecliff College, Rockford College and Mount Mary College, as well as by universities in Brazil and Venezuela. He has been a guest lecturer at universities throughout the world and has made fifty-one lecture tours throughout the United States alone. He is President of the Austrian Medical Society of Psychotherapy.He died in Vienna at the age of 92.


text:
A term used to define Getting High.
Will the pirate ate a bagel twice today.
Hmm, He is always eating a bagel...
Hmm, He is always eating a bagel...
by That One Fly Girl June 22, 2009
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Taste of Berkmar planned for Saturday
The Taste of Berkmar, to benefit the Patriots' track and field program, will feature food from local restaurants, vendor showcases, entertainment and a silent auction
Archer senior Tatiana Wayne to play basketball, run track at Columbus State
Archer senior Tatiana Wayne has made a commitment to the Columbus State University women's basketball and track and field programs
Parkview track patriarch returns to see changes
The year was 1976 and Parkview was beginning its first year as a high school. For Park Turner, it was a chance to start a tradition in track and field at the new Lilburn school.
GHSA Executive Committee tackles busy agenda at fall meeting
GHSA tackles busy agenda during its fall meeting Monday in Macon
Getting To Know Larry Satchwell
Getting to Know longtime Gwinnett Co. track and field throwing coach Larry Satchwell
Despite success, Archer's Serenity Douglas still just loves to run
Running has always been something that just came naturally for Serenity Douglas. Since elementary school she has been beating all the girls and the boys in foot races on the playground.
GIRLS FIELD PERFORMER OF THE YEAR: Collins Hill's Hambolu caps season with title
Collins Hill's Bola Hambolu won the state championship in the long jump and was second in the triple jump this season
GIRLS RUNNER OF THE YEAR: Obeng-Akrofi makes mark on young Archer program
Archer senior Akua Obeng-Akrofi is the Daily Post's runner of the year for girls track and field
2014 Gwinnett Daily Post All-County Girls Track and Field
The Daily Post's selections for the best in high school girls track and field from the 2014 season
Region 8-AAAAAA honors best in track and field
The county's coaches have released the lists of the best from region track this season
Gwinnett high school coaches honor season's best in track and field
The Gwinnett County track and field coaches honored the top athletes in their sports and inducted five new hall of famers this week
Greater Atlanta Christian to host Olympians at free Friday track meet
Lolo Jones heads up the athletes competing in American Track League series
Fans Choice Female Athlete of the Week: Wesleyan's Cairo Booker
Sophomore won two state track and field state championships in Albany
GWINNETT SPORTS HALL OF FAME: Collins Hill's Drouin relishes trip home, honor
Collins Hill grad Jackie Drouin will be inducted Friday into the Gwinnett County Sports Hall of Fame during a banquet at the Gwinnett Civic Center
FANS CHOICE FEMALE ATHLETE OF THE WEEK: Candidate Profiles
A look at the girls high school athletes from spring sports up for this week's award, which is decided by fan voting
Previous Next
Boys Track
- Mill Creek senior Menzies to sign with Georgia Tech
- Taste of Berkmar planned for Saturday
- Parkview track patriarch returns to see changes
- GHSA Executive Committee tackles busy agenda at fall meeting
- Getting To Know Larry Satchwell
- Shiloh's Blaszkiewicz named Georgia track and field coach of the year
- Brookwood's Vitatoe headed to Hurricanes
- Norcross' Strother signs with Tennessee Volunteers in track and field
- Six Gwinnett track athletes honored by Atlanta Track Club
- 2014 Gwinnett Daily Post All-County Boys Track and Field
Spring Sports
- Grayson's Stevens, Westendorf named NSCAA All-Americans
- Lanier's Burrow, Santiago commit to college baseball programs
- Parkview grad Tim Gustafson signs deal with Baltimore Orioles
- Grayson's Gorski signs with Gardner-Webb lacrosse
- Getting to Know — Lee Rider
- Archer's Terry, Fitzpatrick and Ranel headed to college baseball programs
- Wesleyan's Jones, Hall and McDonald to sign with colleges
- Greater Atlanta Christian to honor college baseball signees
- Mill Creek to salute boys lacrosse, girls basketball signees
- Buford will have 15 early college athletics signees