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12 Inspirational Quotes
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12 Inspirational Quotes
Inspirational quotes from Prayables: Looking for inspiration? Here's 12 inspirational quotes to delight and inspire you!
Dalai Lama QuotesThese Dalai Lama quotes show why the Dalai Lama is one of the most revered spiritual...
Prayers and Blessings from Around the WorldThese prayers and blessings from around the world reveal how much we all have...
Bible Verses About Healing That Will Work MiraclesThese Bibles verses about healing offer comfort and guidance to those in pain.
6 Misconceptions About the BibleYou've read the Bible, but how well do you know it? Here are six things everyone...


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Perfect Interview Answers Free Training Webinar
Did you know that employers are listening for certain words, phrases, and concepts in your interview answers? If you don't say what they want to hear, you won't get the job. In this webinar, you will learn perfect interview answers you can adapt for any job in any field. These answers are the "magic words" that will unlock job offers for you. You will learn:
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New Year Offer
Enjoy unforgettable winter holidays at Kempinski Grand Hotel Gelendzhik getting in the mood of magic atmosphere of the New Year...
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Find records of Robert Knight
Find birth, death, marriage, military, and other records of Robert L Knight at Ancestry.com.Search for records
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Robert L Knight (1939 - 2008) was born on May 10, 1939. He was born into the Knight family.
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Dr. Bashar Marji specializes in cardiovascular disease in Pittsburg, Kansas.
Dr. Bashar Marji has been compared 83 times. Details of Dr. Marji's 20 years experience as an MD, his hospital affiliation and education at University of Mosul are available on your free doctor report.
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The NLETC was incorporated in 1981 by Mr. Jim Lindell.
The Company was reorganized as a 501(c) (3) not-for-profit corporation in 2007. The NLETC is currently served by an Executive Board of Directors.
The NLETC conducts reasonable use of force training and consultation utilizing an international cadre of professional instructors; serving Law Enforcement, Corrections, Security and Military clientele.
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Lateral Vascular Neck Restraint (LVNR®)
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More pics
Here's more pics so you can get an idea of how large a tub you can make with an SOL Emergency Blanket. In the previous pics, I had adjusted the knots to make it a little smaller so that it wou...
SOL Emergency Blanket....
I screwed around for awhile trying to figure out a nice way to tape the corners to create a tub. Then I discovered that just tying a loose overhand knot in each corner was waaaaay better, takes no...
Re: Solomid floor?
Art, the bathtub floors that zpacks makes are great! They're high enough to actually do some good. A couple months ago in the Duomid, I was getting LOTS of splashes over a foot and a half int...
Solo vs Duomid (cuben)
Hi there. Stuart told me you were looking for this information, and since I have both of these shelters in cuben (with the new reinforced areas already mentioned, I'll pass on what I know. ...
Used only one night. Seam sealed using the method Henry Shires shows on his website in the video section. Guylines changed to orange Reflective Glowire from Lawson Cline. Mesh inner. In origina...
Zimmerbuilt ROCKS!!!
You might as well scratch Oookworks off of your list...at least for now. I've sent 3 emails expressing interest in his work, because his inners look fantastic. No response to ANY of them. An...
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Set up several times in the yard but never used in the field. $215 includes UPS Ground shipping anywhere in the lower 48.
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Polyvinyl alcohol fatty acid esters, notably unsaturated acid esters, comprise a new class of edible fat replacements. Polyvinyl oleate, prepared either by direct esterification of low molecular weight polyvinyl alcohol with oleic acid, oleic anhydride or oleyl chloride, by the transesterification between low molecular weight polyvinyl alcohol and methyl oleate, or by the interesterification between low molecular weight polyvinyl acetate and methyl oleate, is a preferred edible fat replacement.
1. A food composition comprising as an edible fat compound, molecular weight 1000 to 5000 polyvinyl alcohol esterified with fatty acids.
2. The composition according to claim 1 wherein the fatty acids comprise C4 to C30 fatty acids.
3. The composition according to claim 1 wherein the fatty acids are selected from the group consisting of butyric, caproic, caprylic, pelargonic, capric, lauric, myristic, palmitic, stearic, arachidic, behenic, oleic, linoleic, linolenic, eleostearic, and arachidonic acids, and mixtures thereof.
4. The compound according to claim 1 wherein the fatty acids are derived from non-hydrogenated or hydrogenated oils selected from the group consisting of soybean, safflower, sunflower, sesame, peanut, corn, olive, rice bran, canola, babassu nut, coconut, palm kernel, cottonseed, and palm oils.
5. The composition according to claim 4 wherein said oil is selected from the group consisting of cottonseed, peanut, olive palm sunflower, sesame, safflower, rice bran, soybean, and corn oil.
6. The composition according to claim 1 wherein the fatty acids comprise unsaturated fatty acids.
7. The composition according to claim 6 wherein the fatty acids comprise C14 to C22 fatty acids.
8. The composition according to claim 6 wherein the unsaturated fatty acid is oleic acid.
9. The composition of claim 1 wherein said food composition is a cookie.
10. The composition of claim 1 wherein said food composition is a cracker.
11. The composition of claim 1 wherein said food composition is a frying oil.
12. The method of preparing a reduced calorie food composition which comprises formulating said composition with molecular weight 1000 to 5000 polyvinyl alcohol esterified with fatty acids.
13. The method according to claim 12 wherein said fatty acids comprise C4 to C30 fatty acids.
14. The method according to claim 12 wherein the fatty acids are selected from the group consisting of butyric, caproic, caprylic, pelargonic, capric, lauric, myristic, palmitic, stearic, arachidic, behenic, oleic, linoleic, linolenic, eleostearic, and arachidonic acids, and mixtures thereof.
15. The method according to claim 12 wherein the fatty acids are derived from non-hydrogenated or hydrogenated oils selected from the group consisting of soybean, safflower, sunflower, sesame, peanut, corn, olive, rice bran, canola, babassu nut, coconut, palm kernel, cottonseed, and palm oils.
16. The method according to claim 12 wherein the fatty acids comprise unsaturated fatty acids.
17. The method according to claim 16 wherein the fatty acids comprise C14 to C22 fatty acids.
18. The method according to claim 12 wherein the fatty acid ester is polyvinyl oleate.
19. The method according to claim 12 wherein said food composition is a cookie.
20. The method according to claim 12 wherein said food composition is a cracker.
21. The method according to claim 12 wherein said food composition is a frying oil.
22. In a food composition the improvement wherein at least a portion of the digestible fat ingredient is replaced by an unsaturated fatty acid ester of molecular weight 1000 to 5000 polyvinyl alcohol to produce a reduced calorie product.
23. The composition of claim 22 wherein said food composition is a bakery product.
This invention relates to the use of polyvinyl alcohol fatty acid esters, notably unsaturated fatty acid esters, as fat replacements in food and pharmaceuticals. Polyvinyl oleate is a preferred compound in this new class of edible fat replacements.
Since fats provide nine calories per gram compared to four calories per gram provided by protein or carbohydrates, major research efforts toward reduction of caloric intake for medical or health reasons have focused on ways to produce food substances that provide the same functional and organoleptic properties as fats, but not the calories. Analogues of natural triglyceride fat, sugar fatty acid polyesters and similar derivatives of other polyhydric compounds, neopentyl alcohol esters, esters of di- and tri-carboxylic acids, jojoba oil, silicone oils and various polysaccharides have been suggested for use as edible fat replacements. (For recent reviews, see Hamm, D.J., 49 Food Sci. 419 (1984), and Haumann, B.F., 63 J. Amer. Oil Chem. Soc. 278 (1986).)
In the selection, modification, and/or synthesis of low calorie replacements of edible fats and oils, the polymeric fat replacements, for example, polysaccharides, have a great deal of structural flexibility because of the inherent nature of polymers. Not only may side chain fatty substituents attached to a chemical structure be varied to achieve different chemical and physical properties (as was the case, for example, with the hydrogenated, partially hydrogenated and unhydrogenated fatty acids condensed with sucrose in Eur. Pat. Ap. No. 235,836 to Bodor and Page and in Eur. Pat. Ap. No. 236,288 to Bernhardt to make different sucrose polyesters), but the entire structure may be shortened or lengthened to make macromolecules of enormously differing functionality.
A number of branched and linear polysaccharides and lower molecular weight dextrins and amyloses have been suggested as fat replacements in foods. Polydextrose, a tasteless non-sweet low calorie bulking agent formed by the random polymerization of glucose with lesser amounts of sorbitol and citric acid, has been used as a partial replacement for fat (and sugar) in a variety of common processed foods, including desserts (U.S. Pat. No. 4,626,441), dairy products (U.S. Pat. No. 4,631,196), and crackers (U.S. Pat. No. 4,678,672). Polyglucoses and polymaltoses, prepared by the polycondensation of saccharides in the presence of a polycarboxylic acid catalyst, were synthesized and used in dietetic foods in U.S. Pat. No. 3,876,794 to Rennhard and combined with dietary fiber in U.S. Pat. No. 4,304,768 to Staub et al.
Converted starches (mostly from tapioca, corn, and potato starches), prepared by the chemical, thermal, or enzymatic degradation of starch molecules to lower molecular weight fragments (including dextrins and amyloses), were disclosed as fat- or oil-replacements in foodstuffs in U.S. Pat. Nos. 3,962,465 and 3,986,890 to Richter et al., U.S. Patent No. 4,247,568 to Carrington and Haleck, and U.S. Pat. No. 4,510,166 to Lenchin et al. Modified high amylose starches have been employed as fat extenders in imitation cheeses (U.S. Pat. No. 4,504,509, U.S. Pat. No. 4,608,265, and U.S. Pat. No. 4,695,475) and in batter coatings for baked food products that resemble fried foods (U.S. Pat. No. 4,504,509). An anionic polysaccharide obtained from algae was disclosed with mono and/or disaccharides to extend fats in whippable emulsions in U.S. Pat. No. 3,944,680 to van Pelt et al.
Polyglycerol esters comprise another class of polymeric fat replacements. Widely used as emulsifiers, polyglycerol fatty esters are wax-like solids which may be used with hydrophilic colloids to form compositions oleaginous in appearance and texture, but containing substantially no fat. Linear and cyclic polyglycerols of different chain lengths have been prepared for consumption in food (U.S. Pat. No. 3,968,169), and substituted with a range of fatty acid residues (U.S. Pat. No. 3,637,774) for use in margarine, imitation butter, cheese spreads, dips, puddings, icings, salad dressings, sauces, and frozen desserts, including ice cream and sherbet (U.S. Pat. Nos. 3,637,774 and 4,046,874).
Though great variations in chain length and structure are possible with the currently available polymeric fat substitutes, most have the disadvantage of being at least partially, if not totally, digestible. (See Haumann, supra, pp. 278-280, for a discussion of polysaccharides, and Babayan, V.K., 41 J. Amer. Oil Chem. Soc. 434 (1963), for polyglycerol esters.) In addition, polymerization reactions are hard to control. The direct free radical polymerization of vinyl esters of unsaturated fatty acids, for example, do not form linear polymers, but polycondense to form cross-linked products (Seymour, R.B., and Carraher, C.E., Polymer Chemistry, Marcel Dekker, New York, 1988, chapter 9).
By the same token, degradation reactions are hard to control. Thus, close attention must be made to the conditions under which starches are degraded to form dextrins and sugars (U.S. Pat. No. 4,510,166). Homogeneous products are difficult to achieve, and vary greatly with the starting material used. Even if the starting material were a pure compound, which most natural products are not, the sugar moieties making up polysaccharide chains have myriad functional groups that can react, and geometric and optical isomerism further complicates condensation reactions. (In the esterification of a single sucrose molecule with an excess of fatty acid, for instance, the eight hydroxyl groups can react to form 255 different sucrose esters if all isomers are counted; see Weiss, T.J. et al., 48 J. Amer. Oil Chem Soc. 145 (1971).)
An objective of the present invention is to provide a simple polymeric fat replacement for food compositions which is free from the above-described disadvantages. Heterogeneity problems resulting from the polymerization or degradation of polysaccharides and polyglycerols to form complex mixtures of macromolecules are avoided by using a simple polymeric backbone to which fatty substituents can be attached. Synthetic fats with the different properties (rheology, viscosity, and so forth) needed for different culinary applications can be formulated by varying the degree of substitution and the chain length of the polymer.
It has now been found that relatively low molecular weight polyvinyl alcohol esterified with fatty acids can be used as an edible fat replacement for part or all of the fat in food compositions. More particularly, it has been found that unsaturated fatty acid esters of polyvinyl alcohol are especially useful as fat replacements in food, and that polyvinyl oleate is a preferred compound.
Polyvinyl alcohol (--CH2 --CHOH--)n is apparently the simplest possible water-soluble polymer. (See recent reviews in Dunn, A.S., 1980 Chem. & Ind. (London), 801-806 and Leeds, M., in the Kirk-Othmer Encyclopedia of Chemical Technology, 2nd ed., vol. 21, Wiley-Interscience, N.Y., 1970, pp. 353-368. Most of its uses involve extrusion of the resin or its application as a surface coating. It has been employed in films, adhesives and binders, and in the treatment of textiles and paper.
Polyvinyl alcohol undergoes chemical reactions very similar to those of low molecular weight aliphatic alcohols. For example, it reacts with acid chlorides or anhydrides to form esters. In many instances, it is possible to obtain a completely new resin by reacting all of the hydroxyl groups. Even with lesser degrees of substitution, the properties of the resin may be considerably altered, while retaining, if desired, the water solubility. Further interesting property variations can be achieved by using partially hydrolyzed polyvinyl alcohol or by varying the chain length of the polymer.
Polymeric synthetic drying "oils" for use in the surface coatings industry can be prepared by reaction of polyvinyl alcohol with long chain unsaturated fatty acids (Leeds, M., supra at 358). Polyvinyl oleate was among the polyvinyl alcohol esters synthesized for this use (U.S. Pat. No. 2,601,561 to Schertz; Rheineck, A.E., 28 J. Am. Oil Chem. Soc. 456 (1951); and Balakrishna, R.S. et al., 16 Paintindia 20 (1967)). However, among the esters made, polyvinyl oleate was a poor drying oil. When used in a varnish, it did not exhibit desirable properties, e.g., it did not develop early hardness (Rheineck, A.E., supra at 458). A film of the ester took a long time drying, and even then remained tacky after two months (Balakrishna, et al.. supra at 21)
The polyvinyl alcohols used to make these unsuccessful polyvinyl oleate synthetic drying oils were, relatively, medium chain length resins. M. Leeds gives molecular weights of parent polyvinyl acetates as ranging from 10,000 to 400,000 (Table 3, supra at 356). In the examples of U.S. Pat. No. 2,601,561, the polymeric alcohols employed were molecular weight 14,000 (Examples I-VI and VIII) or 52,000 (Example VII). R.S. Balakrishna, et al. used polyvinyl alcohol having a molecular weight 30,000 to 35,000 (supra at 20).
In the practice of the present invention, on the other hand, a considerably lower molecular weight polyvinyl alcohol is esterified with fatty acids, preferably unsaturated fatty acids such as oleic acid, to use as an edible fat replacement. The polymeric size will range between molecular weight 500 and 8000, preferably between 1000 and 5000.
The term "polyvinyl alcohol" as used herein refers to a polymer prepared from polyvinyl acetate by replacement of the acetates with hydroxyl groups, and may contain residual acetyl groups. In the practice of this invention, some residual acetyl groups are preferred. In general, polyvinyl alcohol acetylated to 25% esterification is preferred over polyvinyl alcohol substantially free of acetyl groups.
The term "fatty acids" used here means organic fatty acids containing four to thirty carbons, and may be synthetic or natural, saturated or unsaturated, with straight or branched chains. Preferred fatty acids have from 10 to 22 carbons. Examples of fatty acids that can be used in this invention are butyric, caproic, caprylic, pelargonic, capric, lauric, myristic, palmitic, stearic, arachidic, behenic, oleic, linoleic, linolenic, eleostearic, and arachidonic acids. Mixtures of fatty acids may also be used, such as those obtained from non-hydrogenated or hydrogenated soybean, safflower, sunflower, sesame, peanut, corn, olive, rice bran, canola, babassu nut, coconut, palm kernel, cottonseed, or palm oils.
In this invention, unsaturated fatty acids are preferred. The term "unsaturated fatty acid" as used here means any unsaturated fatty acid containing at least 8, and preferably from 14 to 22, carbon atoms. The unsaturated fatty acids must contain at least one alkene linkage and may contain two or more alkene groups in any position in the hydrocarbon chain, and the unsaturation may or may not be present as a conjugated system of double bonds. A suitable acid for this purpose is oleic acid. Alternatively, mixtures containing oleic and/or other unsaturated acids, such as that obtained from cottonseed, peanut, olive, palm, sunflower, sesame, safflower, rice bran, soybean, or corn oil may be used.
The term "fatty acid derivative" as used herein means a derivative other than an ester, for example, a fatty acid, a fatty acid chloride, or a fatty acid anhydride.
The term "fatty acid ester" as used herein means the methyl, ethyl, propyl, butyl, or pentyl ester of a fatty acid, and any geometric or optical isomer thereof. In the preferred embodiment, the methyl or ethyl ester of an unsaturated fatty acid is used.
A solvent may be employed. The term "solvent" used in the description and claims means any material that is liquid at the synthesis reaction temperature and pressure and will dissolve, suspend or hold the reactants in the reaction mixture in an amount effective to expedite contact for the desired esterification, interesterification or transesterification to occur.
In the practice of the present invention, polyvinyl alcohol may be condensed with a fatty acid, a fatty acid chloride, or a fatty acid anhydride; in the preferred embodiment, the fatty acid or fatty acid derivative is unsaturated. The total amount of fatty acid, acid chloride, or anhydride present in the reaction mixture can be a maximum that theoretically will react to completely esterify all the free hydroxyls of the polyvinyl alcohol. Thus, the total amount of fatty acid or acid chloride or anhydride present will be one mole for each mole of free hydroxyl moieties available on the polyvinyl alcohol reactant. However, best results are achieved by using an excess of fatty acid, acid chloride or anhydride. Typically, a thirty percent excess is employed.
In an alternate practice of the present invention, polyvinyl alcohol may be transesterified with a fatty acid ester, preferably an unsaturated fatty acid ester. Theoretically, the total amount of fatty acid ester present in the reaction mixture can be a maximum that theoretically will react to completely transesterify all the hydroxyls of the polyvinyl alcohol reactant. However, best results are achieved by using an excess of fatty acid ester over the theoretical stoichoimetric amount required. Typically, a fifteen percent excess is used.
In another alternate practice of the present invention, polyvinyl acetate may be interesterified with a fatty acid ester, preferably an unsaturated fatty acid ester. Theoretically, the total amount of fatty acid ester present in the reaction mixture can be a maximum that will react to completely interesterify all the acetate groups of the polyvinyl reactant.
The transesterification and interesterification reactions are carried out in the presence of a catalyst, such as, for example, sodium. A sodium/potassium alloy can also be used.
According to a preferred embodiment of the present invention, the polyvinyl alcohol is dissolved in the fatty acid, the acid chloride, or anhydride. Alternatively, the polyvinyl acetate is dissolved in the fatty acid ester and a catalyst is added to the mixture. The reaction mixture in either case may be warmed at reflux and stirred to speed the reaction. The length of reaction time varies with the reaction conditions and may require several hours.
The polyvinyl esters of this invention may be incorporated either alone, or in combination with another fat and/or fat mimetic, into any food composition or used in conjunction with any edible material. The term "edible material" is broad and includes anything edible. Representative of edible materials which can contain the polyvinyl esters of this invention in full or partial replacement of natural fat are: frozen desserts, e.g., sherbet, ice cream, ices, or milk shakes; puddings and pie fillings; margarine substitutes or blends; flavored bread or biscuit spreads; mayonnaise; salad dressings; filled dairy products such as filled cream or filled milk; dairy or non-dairy cheese spreads; coffee lighteners, liquid and dried; flavored dips; frying fats and oils; reformed and comminuted meats; meat substitutes or extenders; whipped toppings; compound coatings; frostings and fillings; cocoa butter replacements or blends; candy, especially fatty candies such as those containing peanut butter or chocolate; chewing gum; bakery products, e.g., cakes, breads, rolls, pastries, cookies, biscuits, and savory crackers; mixes or ingredient premixes for any of these; as well as flavor, nutrient, drug or functional additive delivery systems.
The following examples detail three methods of preparing polyvinyl fatty acid esters in accordance with the present invention, an in vitro screening test for lipase digestibility of the compounds, and some compound uses in food compositions. It is to be understood that these examples are merely illustrative and are not to be construed as being limitative. In the chemical syntheses, the biochemical screenings, and the food composition recipes, all percentages given are weight percentages, and are based on the weight at the particular stage of processing described.
Polyvinyl oleate for use in food compositions is synthesized from polyvinyl alcohol in this example.
A reaction flask is charged with 1.25 grams polyvinyl alcohol powder (0.00063 moles of 75% hydrolyzed polymer, approximately 2000 molecular weight). To the flask is added 15 grams oleic anhydride. The flask is stirred and heated to reflux at 218� C. for seven hours. After the contents of the flask cools to room temperature, the reaction product is dissolved in 200 mL toluene. A hundred mL water is added to this mixture and separated using a separatory funnel. The water layer is removed and tested with litmus. More water is added in 100 mL aliquots, and this procedure is repeated until the water layer is neutral to litmus paper. This requires between 5 to 10 washings.
The remaining toluene layer is transferred to a beaker and heated over moderate heat on a hot plate to evaporate the toluene. The beaker is then placed in a vacuum oven of 105� C. for twenty-four hours.
In this example, polyvinyl oleate for use in food compositions is synthesized from polyvinyl acetate.
A reaction flask is charged with 25 grams polyvinyl acetate resin (0.00357 moles of Rhodopas RB-1, a resin that meets the chemical identity standards listed in the Food Additive Regulation 21 C.F.R. 172.615, and has a molecular weight of approximately 7000). To the flask is added 100 grams 99% methyl oleate and 1.74 grams sodium. The flask is stirred and heated to reflux at 216� C.
This example describes an alternate polyvinyl oleate synthesis.
A reaction flask equipped with a magnetic stirrer, a thermometer, a dropping funnel, a nitrogen purge, and a reflux condenser is charged with 10 grams polyvinyl alcohol (molecular weight 2000, 75% hydrolyzed) and 115.68 grams phenol. The mixture is stirred, heated, and purged with nitrogen throughout the dissolution. At about 90� C., the polyvinyl alcohol begins to become soluble in the phenol, forming a clear yellow solution. After two hours between 100� and 130� C., practically all the polyvinyl alcohol is in solution.
The reflux condenser is then changed to a distillation apparatus, and 48.2 grams oleic acid is slowly added dropwise through the dropping funnel as phenol is distilled off over the course of about three hours. (Phenol which occasionally crystallizes in the condenser is melted with a heat gun.) During the course of the reaction, the temperature rises from 185� to 250� C. The mixture is left overnight.
The mixture is then reheated to 235� C. for two and a half hours under vacuum. The mixture changes from yellow to brown. About 115 grams of crude reaction product is recovered and further purified by step-wise separatory funnel extraction with three 120-mL aliquots of methanol. The (top) methanol layers extract color and are decanted and discarded, leaving a mustard-colored product which is vacuum dried to a clear brown viscous oil product.
This example outlines the procedure for estimating the in vitro digestibility of the polyvinyl esters of this invention.
1. Buffer: A pH 7.1 phosphate buffer is prepared by dissolving 6.8 g. KH2 PO4 in 1 L. of millipore filtered water (to yield 0.05 M phosphate). Fifty mg. Ca(NO3)2 and 5.0 g. cholic acid (Na salt, an ox bile isolate from Sigma) are added to give 300 microM Ca++ and 0.5 % cholic acid in 0.05 M phosphate. The pH is adjusted to approximately 7.1 with solid NaOH. Several drops of Baker "Resi-analyzed" toluene are added to prevent bacterial growth during storage at 3-5� C.
2. Lipase: About 15 mg./mL commercial porcine pancreatic lipase from U.S. Biochemical Corporation is dissolved in buffer.
3. Substrates and Standards: A 1.0 mL volumetric flask is charged with an amount of lipid substrate (test substance or standard) calculated to give a concentration of 200 nanomoles per microliter in Baker "Resi-analyzed" toluene. (The proper concentration may be approximated by doubling the molecular weight of the lipid in question, dividing by 10, and diluting to the mark; this yields about 200 nanomoles per microliter.) This preparation affords the substrate to be used in the hydrolysis reactions. Fatty acids and glyceride standards from Nu Chek or Sigma are prepared for elution on TLC plates (prewashed with 1:1 chloroform/methanol) by diluting the substrate solution with 10:1 toluene (1 part substrate plus 9 parts toluene) in septum vials.
In a 25 mL Erlenmeyer, emulsify 20 mL buffer (at room temperature) and 40 microliters of substrate using an ultrasonic disrupter at a microtip maximum setting for approximately 10 seconds. This results in a 0.4 micromole/milliliter emulsion. Place in a 37� C. water bath and stir vigorously. After temperature equilibration, add 40 microliters of enzyme solution and start timing. Remove 5.0 mL aliquots at convenient time intervals for analysis. To establish a standard curve for triolein, for example, aliquots are taken at 10, 20, 30 and 40 minutes. A zero time control should be run for all test compounds. Add the aliquot to a 15 mL glass centrifuge tube containing a drop of concentrated HCl. Add approximately 3 mL of a 2:1 mixture of CHCl3 : CH3 OH and shake vigorously. Centrifuge at approximately 5000 rpm for about 5 minutes and transfer the bottom layer with a Pasteur pipet to a 5 mL septum vial. Repeat the extraction step once and combine the two bottom layers. Evaporate the solvent in nitrogen gas. After about half of the solvent is removed, add an equivalent volume absolute ethanol and continue evaporation in a nitrogen stream until dryness is achieved. Samples may be warmed with a heat gun to facilitate drying.
When the samples are dry, add exactly 200 microliters of toluene containing 10% DMSO, cap tightly, and spot TLC plate with 2.0 microliters per channel. (If 100% extraction efficiency of a zero time control, this amounts to 20 nanomoles of substrate spotted on the plate.) Develop with a suitable solvent system, such as, for example, hexane: ethyl ether: acetic acid in a ratio of 60:40:1. After 15 cm elution, dry plate with a heat gun and determine amounts of starting substrate and products of hydrolysis by scanning 10 to 20 nanomoles per channel at a wavelength of 190 nm using the CAMAG TLC Scanner II densitometer equipped with a Spectra Physics 4270 integrator and comparing with controls run at the same time.
Using this procedure with polyvinyl oleate prepared in Example 3, no hydrolysis is observed after three hours contact with pancreatic lipase. Using a triglyceride control, triolein is substantially hydrolyzed in 10 minutes with this enzyme system.
Polyvinyl oleate prepared in Example 3 is used in a cookie recipe in this example.
The cookie dough is prepared by creaming together 23.11 grams fine granulated sucrose, 0.37 grams salt, 0.44 grams sodium bicarbonate, and 11.38 grams polyvinyl oleate. At this stage, no "foam" appears as with solid shortening during creaming. To this blend is added 3.74 grams distilled water and 5.87 grams 5.93% (wt/wt) dextrose solution, and then 39.10 grams flour. The dough is very tacky, and may be extruded or rolled out and cut before baking in the usual manner (e.g., at 400� Fahrenheit for 10 minutes). The tops of the cookies crack during baking.
Polyvinyl oleate prepared in Example 3 is used in a sprayed cracker recipe in this example.
A dough prepared from 100 parts flour, 5 parts sugar, 1.5 parts malt, 7.5 parts of the polyvinyl oleate prepared in Example 3, 1 part salt, 0.9 parts sodium bicarbonate, 2.5 parts non-fat dry milk, 2.5 parts high fructose corn syrup, 0.75 parts monocalcium phosphate, and 28 parts water is sheeted, stamped, sprayed with polyvinyl oleate from Example 3, and baked to produce a cracker product.
Polyvinyl oleate prepared in Example 3 is used as a frying oil in this example.
Standard packaged precut and frozen "French fried" potatoes are dropped into preheated polyvinyl oleate and fried at 325� to 375� F. for 8 to 10 minutes, or until golden.
The above descriptions are for the purpose of disclosing to a person skilled in the art how to practice the present invention. These are not intended to detail all the obvious modifications and variations of the invention which will become apparent upon reading. However, applicants do intend to include all such obvious modifications and variations within the scope of their invention which is defined by the following claims.
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Best of Burque Restaurants 2009
Welcome back to Best of Burque Restaurants! Inside, you'll discover nearly 100 lip-smacking categories of the best food in Albuquerque, selected through thousands of votes cast by Alibi readers. Why do we roll out such a smorgasbord of a poll every year? Well, for one, your Best of Burque votes reward local businesses with hard-earned recognition. And as long as you keep eating and voting, we'll be able to amass these indispensable guides to the best food our city has to offer. To see addresses, hours and other searchable information about the winning restaurants, just start on clicking names. Bon appétit!
Flickrshow will appear here!
• Around the World: Ethnic cuisines
• A.M.: Breakfast
• P.M.: Lunch and dinner
• No Bones About It: Vegetarian
• State Treasures: New Mexican cuisine
• Gluttony: The filling foods hall of fame
• The Sweet Stuff: Dessert
• Best of the Rest: The best restaurant in Albuquerque and beyond
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Batangas City, Batangas, Philippines
Barangays (105) of Batangas City, in the Batangas Province within Region IV-A in the Republic of The Philippines
Alangilan | Balagtas | Balete | Banaba Center | Banaba Kanluran | Banaba Silangan | Banaba Ibaba | Barangay 1 (Pob.) | Barangay 2 (Pob.) | Barangay 3 (Pob.) | Barangay 4 (Pob.) | Barangay 5 (Pob.) | Barangay 6 (Pob.) | Barangay 7 (Pob.) | Barangay 8 (Pob.) | Barangay 9 (Pob.) | Barangay 10 (Pob.) | Barangay 11 (Pob.) | Barangay 12 (Pob.) | Barangay 13 (Pob.) | Barangay 14 (Pob.) | Barangay 15 (Pob.) | Barangay 16 (Pob.) | Barangay 17 (Pob.) | Barangay 18 (Pob.) | Barangay 19 (Pob.) | Barangay 20 (Pob.) | Barangay 21 (Pob.) | Barangay 22 (Pob.) | Barangay 23 (Pob.) | Barangay 24 (Pob.) | Bilogo | Bolbok | Bukal | Calicanto | Catandala | Concepcion | Conde Itaas | Conde Labak | Cuta | Dalig | Dela Paz | Dela Paz Pulot Aplaya | Dela Paz Pulot Itaas | Dumuclay | Dumantay | Gulod Itaas | Gulod Labak | Haligue Kanluran | Haligue Silangan | Ilijan | Kumba | Kumintang Ibaba | Kumintang Ilaya | Libjo | Lobo | Liponpon Isla Verde | Maapas | Mabacong | Mahabang Dahilig | Mahabang Parang | Mahacot Kanluran | Mahacot Silangan | Malalim | Malibayo | Malitam | Maruclap | Pagkilatan | Paharang Kanluran | Paharang Silangan | Pallocan Silangan | Pallocan Kanluran | Pinamucan | Pinamucan Ibaba | Pinamucan Silangan | Sampaga | San Agapito Isla Verde | San Agustin Kanluran Isla Verde | San Agustin Silangan Isla Verde | San Andres Isla Verde | San Antonio Isla Verde | San Isidro | San Jose Sico | San Miguel | San Pedro | Santa Clara | Santa Rita Aplaya | Santa Rita Karsada | Santo Domingo | Santo Niño | Simlong | Sirang Lupa | Sorosoro Ibaba | Sorosoro Ilaya | Sorosoro Karsada | Tabangao Aplaya | Tabangao Ambulong | Tabangao Dao | Talahib Pandayan | Talahib Payapa | Talumpok Kanluran | Talumpok Silangan | Tinga Itaas | Tinga Labak | Tulo | Wawa
We ask the Barangay Chairman, to please Help update his/her barangay webpage with information updates or Picture Uploads to promote tourism and attract investors.
- Batangas City is the capital and largest city in Batangas province. Batangas City is an important seaport and trade center for the province, which is a sugar-growing region. Silk and cotton fabrics and coconut oil are manufactured in the city.
|Adopt this webpage. Help your community get more exposure to TOURISTS and INVESTORS. Help us improve this webpage.
List of Municipalities in the Batangas Province within Region IV-A in the Republic of The Philippines
Agoncillo | Alitagtag | Balayan | Balete | Bauan | Calaca | Calatagan | Cuenca | Ibaan | Laurel | Lemery | Lian | Lobo | Mabini | Malvar | Mataasnakahoy | Nasugbu | Padre Garcia | Rosario | San Jose | San Juan | San Luis | San Nicolas | San Pascual | Santa Teresita | Santo Tomas | Taal | Talisay | Taysan | Tingloy | Tuy
Cities in the province of Batangas: Batangas City (Capital) | Lipa City | Tanauan City
Regions | Philippine Provinces | Philippine Cities | Municipalities | Barangays | High School Reunions
Seal of Batangas City
|Interactive Google Satellite Map of Batangas City, Philippines
Location of Batangas City
Batangas Province, Philippines
City Hall of Batangas City
Visit our website: B.O.S.S.
Basilica Immaculada Conception Parish
Registry of Deeds Building in Batangas City
Batangas City,
Batangas Province, Philippines
- Batangas City has a total of 105 barangays
- Registered Voters of Batangas City as of (2010) = 157,748
- Population of Batangas City (as of Aug 1, 2007) = 295,231
- Land Area of Batangas City (as of 2007, in hectares) = 28,296
- Batangas City is a 1st class component city and Partially Urban.
- Batangas City is in the Batangas province and within Region_IV-A - Calabarzon in the island of luzon.
Batangas City is the capital and largest city in Batangas province. Batangas City is an important seaport and trade center for the province, which is a sugar-growing region. Silk and cotton fabrics and coconut oil are manufactured in the city. The batangas city is also the largest seaport in the CALABARZON region.[1]
Location of Batangas City, Batangas, Philippines
- 13.7500° N, 121.0500° E - Batangas City, Coordinates
- Batangas City is the capital city of the province of Batangas
- Batangas is within Region_IV-A and in the island of luzon
History of Batangas City, Batangas, Philippines
Spanish missionaries first set foot in Batangas City in 1572. The settlement was founded in 1581 and named "Batangan" because of the numerous big logs that abounded the Calumpang River. The logs were called "batang" by the natives who settled near the river and called the settlement "Batangan". This name was modified and became Batangas in 1601. Don Agustin Casilao was appointed as the first Gobernadorcillo. Since 1754, the city has been the capital and administrative center of the province. Batangas became a city in 1969 through Republic Act. No. 5495.
People of Batangas City, Batangas, Philippines
- Registered Voters (2010): 157,748
- Population (as of Aug 1, 2007): 295,231
Elected Government Officials of Batangas City, Batangas, Philippines
The Sangguniang Panlungsod is composed of the City (Municipality) Vice-Mayor as Presiding Officer, regular Sanggunian members (Councilors), the President of the Association of Barangay Captains and the President of the Sangguniang Kabataan.
They shall exercise and perform the legislative powers and duties as provided for under Republic Act No. 7160, otherwise known as the Local Government Code of 1991. Shall consider and conduct thorough study all matters brought to their attention and consequently pass resolutions, enact ordinances and to introduce recommendations.
Elected government officials of Batangas City for the term of 2013-2016
- Mayor of Batangas City: Eduardo B. Dimacuha
- Vice-Mayor of Batangas City: BERBERABE, DOC JUN
- Councilors:
- Hamilton Guinhawa Blanco LIBERAL PARTY 54519 7.12%
- Sergie Rex Montales Atienza NATIONALIST PEOPLES' COALITION 50984 6.66%
- Armando Chavez Lazarte NATIONALIST PEOPLES' COALITION 49045 6.41%
- Gerardo A. Dela Roca NATIONALIST PEOPLES' COALITION 47347 6.19%
- Julian B. Villena NATIONALIST PEOPLES' COALITION 44821 5.86%
Elected government officials of Batangas City for the term of 2010-2013
- Mayor: Vilma Abaya Dimacuha
- Vice-Mayor:Jose Virgilio Ylagan Tolentino
- Councilors:
|Hon. Eduardo B. Dimacuha
|Hon. Jose Virgilio Ylagan Tolentino
|• Councilors
|Hon. Luisa F. Macaraig
|Hon. Carmela H. Atienza
|Hon. Nestor E. Dimacuha
|Hon. Julian B. Villena
|Hon. Ricardo A. Ambida
|Hon. Renato C. Cruz
|Hon. Eloisa Angela De Loyola Portugal
|Hon. Manuel S. Aclan
|Hon. Gerardo A. Dela Roca
|Hon. Mario Vittorio Agregado Mariño
Barangays Elected Officials of Batangas City, Batangas
Businesses in Batangas City, Batangas, Philippines
- How to Improve Your Business and Livelihood
The Philippine Livelihood Program: The Philippine government provides several programs to enhance the livelihood of the Filipino people. The department of Science and Technology through its Technology Research Center (TRC) regurlarly conducts various types of hands-on and personalized training programs.
- DOST - Website
- UPLiFT stands for Urban Program for Livelihood Finance and Training. - Website
- DSWD Pro-poor and Livelihood Programs - Website
Take a picture of your Business (from a Sari-Sari Store to a Mega Mall). Upload that picture here in zamboanga.com and that picture can immediately be your business webpage. It is that easy. Here are two examples of how a picture becomes the webpage of the business: Twins Fried Chicken Restaurant and ABC Shopping Center
- Give your business a good description. Add your address and contact number if available.
- Possible Businesses
- Auto, Trucks, Motorcycle and Bicycle dealers
- Banks, Lending Firms, Pawnshops, and Financial Institutions
- Clinics, Veterinary Clinics and Hospitals
- Pharmacies, Drug Stores, Agri-Vets
- Convenient Stores, Hardware and Supplies, General Stores, Sari-Sari Stores, Internet-Cafes
- Department Stores and Appliance Stores
- Supermarket, wet market, Fish Markets
- Hotels, Motels, Pension Houses, Boarding houses and Resorts
- Repair Shops: Shoe repair, Cellphone, Bikes (bicycles), motorcycles etc...
- Restaurants, Carenderias, Coffee Shops, and Bakeries (Bakeshops)
- Salons, Spas, Beauty Shops and Barber Shops
- Gas Stations, Water Stations, Propane Stations
Real Estate for Sale or Lease in Batangas City, Batangas, Philippines
- If you have real estate property for sale in Batangas City, you can list that property for free.
- Click to VIEW, EDIT or ADD Realty Listings.
- You can list your House and lot or farm land for sale for free here in Z-Wiki
- If you are a real estate developer, you can list your subdivision, condominiums, high rises, apartment complexes, shopping strips or malls, open market developments FOR FREE.
Churches, Mosques, or Places of Worship in Batangas City, Batangas, Philippines
The name of your church, mosque, or place of worship can be listed here. We can even provide you with a free webpage for you. We can help you. Take a picture of the facade of your church and it can be posted here.
Schools in Batangas City, Batangas, Philippines
School year 2014-2015 starts June 2, 2014 and ends March 27, 2015, for public elementary and secondary schools. The school year will have 201 school days, of which 180 days are "nonnegotiable" student-teacher contact time.
The name of your school in Batangas City can be listed here. You can list it like this:
- Name of School. Private or Public. It can be an elementary school, high school, college.
- Address of your school
- Telephone Number
- Principal of the school
You can also create a webpage for your school. We can help you.
Economy of Batangas City, Batangas, Philippines
- If you have an article that talks about the improvement of the economy of Batangas City you can post that article here. If you come across any news items that talk about the economy of Batangas City, you may post it here. Of course you have to reference the writer of the article. Any improvement to transportation, power and service usually improves the economy of the community, so go ahead and report that too.
Jobs in Batangas City
If you have a job available and that job is within Batangas City, Philippines, you may post it here.
Remember to be as descriptive as possible and to post your Company name, Contact person, physical address, email address and Phone number.
Post expiration of Job Application. Go ahead and Click HERE to Insert your job offer in the "Jobs in Batangas City" page.
Natural Resources of Batangas City, Batangas, Philippines
- Protect the environment
It is sad but true that as of the year 2012 the rivers of the Philippines continue to be the #1 Sewer Systems of the Philippines.
Protect & Save the Rivers. Do not let your sewer drain into the river. Your community can be the first to initiate this project.
Build your riverbank protection with a built-in gutter system. Reforest within Ten Years - Guaranteed!
Let us plant more trees in every barangay in the entire Philippines. It does not make any difference if the barangay is urban, partially urban or rural; we need more trees. Trees will prevent erosion, provide oxygen, prevent green house effect, and even a place of business for the shade tree mechanic.
The Philippines is a tropical country and practically anything will grow. The DENR has the planting trees project that goes on every year. Lots of picture taking for the media. Planting trees one by one is the "human" way of doing it. This individual planting of trees is good if done to "line" the roads and highways with trees or along fences or property divisions, or if you have a plantation.
To reforest the nation of the Philippines we have to plant trees the "mother nature" way. Sow the seeds during the rainy season. Go deep into "bald" forests and plant trees by sowing seeds. If there's not enough volunteers to do this, use the military helicopters to fly over the designated areas and sow the seeds.
Guaranteed within a few years, The Philippines will be lush again. >>Read More
We are using our rivers as our sewer system. If you ask a Filipino, "Are the Filipinos a clean people?" The answer is an automatic, "Yes!". However, the Filipinos are suffering from the same disease or attitude as most people do, and that is the "NIMBY" disease or "NIMBY" attitude. (NIMBY) Not In My Back Yard. So it is OK to dump my garbage and sewer there. Not mine! Someone else will take care of it.
This attitude is killing our rivers. Your great-grandparents, grandparents or parents were once proud to tell the stories of how they enjoyed swimming in the river behind your house or nearby. However, you can't say the same or tell the same stories to your kids or grand kids. Why? Because your generation is killing the river.
- Secretary Ramon J. P. Paje
- Department of Environment and Natural Resources
- Visayas Avenue, Diliman, 1100 Quezon City, Philippines
- +63-2-929-6626
- firstname.lastname@example.com
We have so much water in the Philippines and yet very little to drink.
Instead of relying too much on Diesel fuel and Coal to generate the majority of Philippine's Electrical energy Supply, we can concentrate more on renewable and sustainable source of energy such as: Hydro Power, Solar Power, and Wind Power. We have too many black outs.
Tourists Attractions of Batangas City, Batangas, Philippines
- Help us add some of the tourist attractions of Batangas City in Z-wiki. This will help boost the local economy of Batangas City. Anything that is unique or anything that stands out in your community may be a tourist attraction.
- Landmarks are usually photographed a lot by visitors. Post the Batangas City landmarks here.
Festivals, Fiestas and Traditions of Batangas City, Batangas, Philippines
Every city has some sort of a festival or tradition that is celebrated every year. In the Philippines almost all barangays that are predominantly populated by Christians celebrate fiesta. Tell us about the festivals, fiestas and traditions of Batangas City.
Your Story about Batangas City, Batangas, Philippines
Tell your story about Batangas City. You can talk about the good things in Batangas City or simply talk about the past. You can talk about the eco-system of Batangas City. What is the local LGU doing about the preservation of your natural resources? The topic can start here and once it gets bigger it can have a page of its own in Z-Wiki. It's all up to you.
Featured News of The Philippines
- President Aquino leads launch of Philippines' biggest solar project in SM North EDSA
- Tuesday, November 25, 2014
- MANILA, Nov. 25 -- President Benigno S. Aquino III on Monday led the launch of SM City North EDSA's solar rooftop project, so far the biggest solar project in the country.
- In his speech, the President commended the country's biggest retail outlet for its initiatives on environmental protection and energy conservation ......................... Full Story»
- Moody's keeps positive outlook on Phl banks
- Monday, November 24, 2014 12:00 am
- MANILA, Philippines - Moody's Investors Service has kept a "positive" outlook on the Philippine banking system on expectations its low penetration and the strong economic growth will support further expansion in credit.
- In a report late last week, Moody's said banks are well-positioned to guard themselves against external shocks given a stable asset quality, strong capitalization and adequate reserve levels ......................... Full Story»
- Carabao Festival
- Date: May 14 - Location: Angono, Rizal
- Farmers pay tribute to their patron saints; a procession of carabao carts bearing a myriad local produce is held; prizes are awarded to the strongest and most beautifully decorated carabaos.
- Date: May 14 Location: Pulilan, Bulacan
- Hundreds of festively adorned carabaos are paraded by their farmer-owners on the street leading to the church; there the carabaos are made to kneel down as a homage to San Isidro de Labrado, the patron saint of farmers.
- Azkals conquer Indonesia, book AFF semis ticket
- Tuesday, November 25, 2014 7:51 pm
- MANILA, Philippines—And the Philippine Azkals finally did it.
- Not only did they book an early ticket to the semifinals of the Asean Football Federation (AFF) Cup, they also exorcised the demons that Indonesia inflicted upon the Philippines for 56 years as the Azkals buried the Garuda 4-0 in their group stage encounter in Vietnam Tuesday evening ............................... Full Story»
Batangas City News
PIA Press Release
Thankful Batangueños vow "strong support" for PGMA
Batangas City (28 March 2008) -- The provincial government of Batangas has vowed its strong support for President Gloria Macapagal-Arroyo as it thanked the "untiring" Chief Executive through a Provincial Board Resolution of Support for all the graces that the province has so far received from the Arroyo administration.
The President was informed about the provincial resolution strongly supporting her after she had alighted from a bus that took her on a windshield inspection tour Wednesday (March 26) of the newly-paved 20-kilometer portion of the Southern Tagalog Arterial Road (STAR) that links the Tambo interchange in Lipa City with the Balagtas interchange in Batangas City.
Sponsored by Batangas Vice Gov. Antonio "Marc" Leviste II and co-sponsored by all 12 provincial board members, the resolution dated March 24 thanked the President "for extending numerous projects and programs to Batanguenos and the province of Batangas."
"Her Excellency Gloria Macapagal-Arroyo has been constantly developing the foundation for a robust and more progressive Philippines (and) has effectively widened the various socio-economic programs to increase growth and cut poverty," stressed the Provincial Board's Resolution of Support that was approved by Gov. Vilma Santos-Recto.
Recalling that President Arroyo had unveiled in her 2006 State-of-the- Nation Address (SONA) "her programs to upgrade all ways of transportation such as roads, bridges, port services and railways, among others, which are aimed at establishing economic 'super regions' to goad the development of our nation," the Batangas leaders then provided a litany of what Batangas had so far obtained from the President's super regions vision:
"As a result thereof (super regions), the Western Roll-on, Roll-off (RORO) Nautical Highway in Batangas City that connects Southern Luzon to the Visayas and Mindanao is a big success;
"The Calatagan-Lubang Port has been completed; several bridges under the President's Bridges Programs have been constructed all over Batangas province;
"The modernization program of the International Port of Batangas was turned over and inspected by the President last January 26, 2008;
"The road-widening project of the South Luzon Expressway (SLEX) and the construction of its extension up to Sto. Tomas, Batangas is ongoing;
"The realization of the development of a 'cyber corridor' to attract investments for the call center and business process outsourcing (BPO) sectors has been achieved; and
"The continuation of the STAR from Lipa City to Batangas City is now open for public use."
The resolution further dubbed as "clear, achievable and within reach" the President's "vision and promise… for the so-called 'Metro Luzon Beltway' which includes the Province of Batangas and the rest of Region IV into a globally competitive urban economic and tourism hub through infrastructure developments."
"The Provincial Government and Provincial Board of Batangas (are) optimistic that the priority and objective of the President's economic plan is to continuously harness together the major economic provinces and regions such as Batangas and Southern Tagalog, respectively, and make it larger than the sum of its parts, giving our kababayans the much-needed opportunities for progress," added the resolution which concluded, thus:
"The President (is) worthy of the gratitude and support of our kababayans for her untiring and resolute efforts to improve the quality of life of our people through strengthened partnerships, strong leadership, and excellent economic policies.
"As duly-elected representatives, we renew our confidence in the Arroyo administration, and we encourage the Filipino people to unite for the achievement of a common vision, and uphold the rule of law in order for our government to move on and realize a peaceful, progressive and stable nation through genuine reconciliation."
The President was joined in her bus ride cum drive-through inspection by Batangas officials led by Governor Santos-Recto, Rep. Mark Llandro Mendoza, Rep. Eileen Ermita-Buhain, Transportation Secretary Leandro Mendoza, and former Sen. Ralph Recto, among others.
Batangas City, Batangas, Philippines supports Philippine Cycling
Philippine Cycling is about cycling in the Philippnes. Philippine Cycling helps promote bike races, cycling clubs, bicycle tours, and the development of bicycle trails. Activities are coordinated with bike shops and cycling clubs throughout the Philippines to promote the fun of riding bikes. Philippine Cycling will be coordinating events with tour of Luzon, Visayas and Mindanao. Road biking and mountain bikings will be promoted by Philippine Cycling.
Cycling Activity to Participate In
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That's the reason I started building this dispenser. The days of cut sheet paper are quickly passing, so we need to adapt.
I'm thinking about using this power trimmer to cut the paper when I pull it from the dispenser:
The idea is to measure the needed length and then trim it by the edge of the dispenser. Don't know yet how well it will work, but that's the idea. Can you share what you are using?


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Disney Magic sailing tips?
My husband and I are traveling with our two children (ages 10 & 8) on the April 28 Disney Magic (7-night Caribbean cruise). I have read lots of comments and complaints from past travelers on other web sites and was interested in hearing from someone here. Any helpful hints regarding embarkation; when is the Captain's Dinner; anything to avoid?; etc.
We are not first time cruise-travelers, but i always find it helpful to have a little edge or info on a new ship.
Thanks and happy sailing to all!
Re: Disney Magic sailing tips?
Check out the website www.disneyinfo.com and see the cruise line discussion. It won't give you an edge, but it will help you find every piece of information you could possibly want!
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A deadly blast of arctic air shattered decades-old temperature records as it enveloped the eastern United States on Tuesday, snarling air, road and rail travel, driving energy prices higher and overwhelming shelters for homeless people.
Icy, snow-covered roads and high winds made travel treacherous from the Dakotas to Michigan and Missouri as much of the US braced for dangerously cold temperatures that could break records.
The death toll from a powerful winter storm that pushed through the US midsection into the Northeast has risen to 12.
Day in Pics: 27th November
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Poonam Pandey: The internet sensation


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Dr. Farner graduated from the University of Illinois College of Medicine at Peoria prior to pursuing his training in Orthopaedic Surgery at the University of Louisville. He continued his training in Hand and Microsurgery at the Christine M. Kleinert Institute and the University of Louisville Hospitals in Louisville, Ky. Dr. Farner is board eligible in Orthopaedic Surgery by the American Academy of Orthopaedic Surgeons. He joined the staff in August 2014 and brings his training, experience, and knowledge in orthopaedic surgery to expand the scope of the practice to include disorders of the entire upper extremity, including the shoulder.
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text: iPad apps: A sneak peek Here's a quick look at what to expect in the coming weeks once iPad-specific apps begin rolling into the iTunes App Store Ian Paul (PC World) 0 - - - - print email prev next Loading... Zen Bound 2Game developers at Secret Exit have had a hit with Zen Bound - a cool game that tests your patience and contemplative skills as you rotate carved wooden animals and wrap them in rope trying to cover as much as you can before running out of twine. According to early reviews of the game, Secret Exit isn't just porting the game to match the iPad's larger display. Rather the game developer is enhancing Zen Bound with new levels, music, game play, and improved graphics that complement the beefier hardware capabilities of the iPad. Prev More slideshows 10/10 Comments on this image There are currently no comments for this image. Post new comment Comment Name Email (This will be kept private) Users posting comments agree to the Good Gear Guide comments policy. Login or register to link comments to your user profile, or you may also post a comment without being logged in. Close iPad apps: A sneak peek 10 images


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State's tax collections grew 5 percent last budget year
Published: July 2,2014
Tags: appropriation, budget, collection, general fund, Herb Frierson, house, House Appropriation Committee, House Transportation Committee, Mississippi Adequate Education Program, Mississippi Legislature, rainy day fund, revenue, Robert Johnson, Senate, State Department of Revenue, state government, State of Mississippi, Tate Reeves, tax
JACKSON — Mississippi tax collections continued growing strongly in the just-concluded budget year, posting another year of 5 percent growth and ensuring that money will be available to help improve local roads and bridges.
State Department of Revenue figures show general fund tax receipts grew to a record $5.25 billion in the 2014 budget year, which ended Monday.
Lawmakers raised expectations in March, but revenue kept growing and ended up at least $32 million above the revised number.
That extra money means Mississippi will be able grant $32 million in aid for local roads and bridges that House members fought for on the 2014 session's closing night. Upset about $40 million in special projects targeted to home areas of Senate leaders, the House initially balked at approving a transportation budget. In the end, the House and Senate agreed to spend more to help local roads and bridges if tax collections allowed.
"We'll do so much good with this," House Transportation Committee Chairman Robert Johnson, D-Natchez, said yesterday.
He said he hoped it would build support for further increases in transportation spending: "Maybe they'll understand how critical the need is in the state."
General fund revenue is now 20 percent higher than in fiscal 2010, when receipts touched a low of $4.37 billion after a two-year slide during the recession.
Mississippi's government spends much more than $5 billion a year, plus billions in federal aid and taxes and fees earmarked to particular agencies. In the 2015 budget year, which started yesterday, the state plans to spend $20 billion from all sources, including $8.9 billion in federal money and $5 billion in other state revenue.
Both House and Senate leaders crowed that the 2015 budget spends very little non-recurring revenue on recurring expenses.
"State government is finally doing what taxpayers do every day in their homes and businesses: spending what it takes in, prioritizing needs and saving money for a rainy day," Lt. Gov. Tate Reeves said in a statement.
The strong budget year also filled Mississippi's rainy day fund to its $409 million legal limit.
Lawmakers put an additional $72 million into the Mississippi Adequate Education Program — the state's public school funding formula — in the 2014 session, but most money went to cover a pay raise for teachers. The formula remained $257 million short of full funding.
House Appropriations Committee Herb Frierson, R-Poplarville, said some new revenue will be needed next year to cover the second year of the teacher pay increase, as well as other commitments. But if revenue again rises, lawmakers could have a substantial amount to spend or grant tax cuts during an election year.
"If we have 4 or 5 percent, we'll be able to do some things," Frierson said yesterday. "We'll find out how people really feel about MAEP."
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Israel Hernandez: One Year Later, Still No Answers
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Is door-buying the big problem taxi drivers seem to think it is? "I wouldn't say it's a big problem, but it does create an unfair playing field," Mora affirms. According to his office, county code-enforcement officers made 1750 visits to 224 hotels countywide in the last six months of 2002 with the aim of catching, or at least discouraging, door-buying, but issued just 31 $500 citations for the offense. Mora says it's difficult because the violators basically have to be caught in the act. But he says just the presence of the officers, both county code enforcement and Beach police, at the hotels inhibits the practice.
At a smoothie shop on Alton Road and Sixteenth Street, a handful of taxi drivers sit on a couch and loveseat in the corner of the store. One of them runs over to the Dunkin' Donuts for coffee, returns with it, and plops down on the loveseat. Peña recounts with an odd relish the events of an evening a few weeks prior, when he had a run-in with county inspectors. Five drivers were standing around on 23rd Street, chatting and complaining, as usual, about the state of the industry. "All of a sudden two inspectors pull up at 50 miles an hour and blocked everybody in," Peña sputters. "It was like Starsky and Hutch. One of the inspectors says to me: 'Give me your fucking [taxi driver] license.' I said, 'Fuck you, I'm not driving. I don't have to give you my license.'"
Peña explains that the inspectors thought he'd been driving a friend's taxi, even though his license had expired. "The inspector says, 'I've been looking for you for three days now.' My friend was around the corner getting coffee, so they towed his car. Then they called his boss and told her that he was letting me drive his cab and I was a troublemaker. And she threatened him if he ever let me drive his car. But I wasn't driving. It's the county coming after me. It's insane!"
"We're not after Mr. Peña," counters Joe Mora wearily. "We're not after any driver. Issues of compliance is all we're interested in."
Peña is unconvinced. "I'm going to sue them for harassment," he mutters. "This isn't the end of me."


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Yesterday, the Académie Française announced the election of its first ever British member. Michael Edwards, a poet, professor, and literary critic who writes in both French and English, will join the ranks of les immortels (the immortals) who serve to protect and defend the French language from impurities. The Académie has been issuing judgments on vocabulary, grammar, spelling, and proper usage since 1635. Recently, they banned the word "hashtag" from French, proposing mot-dièse be used in its place.
The election of a native English speaker to the Academy may be a move to enhance the credibility of the organization's main job these days: Weeding out the influence of English. As the Academy fights against the encroachment of Anglicisms like dispatcher, reminder, overbooker, débriefer, and impacter, it might be nice to have an English speaker on their side. But it probably won't make a difference. The Academy's proclamations generally go unheeded by the public, who go on talking the way they want to talk.
At least the recommendations of the Académie Française aren't enforceable by law. There was an outcry in Quebec this week, after the agency charged with enforcing language laws there told the owner of an Italian restaurant his menu (filled with words like pasta and calamari) didn't have enough French on it. The government later retracted the complaint, calling it a mistake. It was not only a mistake, but a perfect example of the ridiculousness of authoritarian language meddling.
The U.S. has never had a language academy. John Adams proposed the idea of forming one to the Continental Congress in 1780, arguing that government should have a role in shaping the language that would propagate democratic ideals in the wider world, but his proposal never got out of committee. It carried a disagreeable scent of monarchy about it, a whiff of top-down control at odds with liberty. The U.S. at that time was a multilingual nation with significant numbers of French and German speakers who had served the Revolution and went on to wield economic and political influence in their own linguistic communities without interference. It wasn't until the xenophobic panic of World War I that people began calling for official English laws, a pointed rebuke to German speakers. In the controversy over immigration in the 1980s these calls resurfaced, this time directed at Spanish, and continue today.
Let's hope they don't succeed. The language of the U.S. has done quite well for itself in the world without a language academy or even official status. Kids running around saying "hashtag," or "impactful," or whatever else gets people complaining about the decline of language, is a small price to pay for liberty.
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Discus Thrower Heart design by Eberjagd. Vector; colors and size customizable. For sporty t-shirts, bags, hoodies, baseball caps and more.
This great custom product in light oxford from our department Men and T-Shirt category can be printed just for you in the size and style you like. The design Discus throw heart coeur herz was created by Eber Hunt and uploaded to Spreadshirt for you to have printed on a T-Shirt. Next to a host of other great customized designs, you can find this Discus throw heart coeur herz design in Spreadshirt's Miscellaneous category. If you are interested in topics like Athletics or Discus throw, then you'll love Discus throw heart coeur herz designs by Eber Hunt. Spreadshirt also offers a huge selection of custom t-shirts, hoodies and accessories for the category Miscellaneous as well as top ancient clothing. Eber Hunt's designs have already impressed many of our customers, so we are sure that we've got right stuff for you! Spreadshirt is your destination for great designs of all kinds – whether it's Athletics, Discus throw or ancient. We are sure that you will find something nice in our shop, there are many amazing custom Miscellaneous t-shirts, hoodies, or accessories for you to find! Tags: Design ID: 12407523
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This relaxed fit cotton t-shirt for men has a seamless rib collar with double-needle cover-stitching, shoulder-to-shoulder taping, double-needle sleeve and bottom hem. The shirt is made from 100% pre-shrunk cotton and has a relatively light fabric weight of 5.3 oz. Light oxford is made from 99% cotton/1% polyester.
still to fill


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Eighty4 Fly - Kush High
Artist: Eighty4 Fly
Producer: A Dot (Green)
Album: COLORS
Avg Rating: 3.8 ( 14 votes )
With flesh-eating zombies roaming the streets of America first and foremost we should thank Eighty4 Fly for merely being Kush High – lord knows getting bath salts high can lead to bad things. Making its online world premiere in The DJBooth right here, right now, Kush High floats along on a smoking beat from A Dot (Green) that's potent enough to give listeners a contact high through their headphones alone. On the mic the Seattle spitter continues to show his range coming off Go Slow, dropping much more than just stoner raps by proclaiming that while he can blaze up with the best of them, he's still stone cold sober when it comes to his lofty ambition: "Bottles of that Cliquot, pour it in the chalice / been a king for years, all I need is the palace." Listeners looking to get even higher (figuratively speaking) with Fly can keep it locked for the release of his COLORS album on August 25 – or if you can't wait that long and are in the Seattle area, simply flip on KUBE93 and hear Kush High on rotation.
Written by Nathan S. on 07/16/12
Submit your Rating
Taylor Management Group
First DJ Booth Appearance:
"Go Slow" (2012)
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The Ministerial Internship Program (MIP) utilizes select courses from the Certificate In Ministerial Studies (CIMS) program to train ministers for their calling.
New Users:
- Create an online account by clicking on the "My Courses" tab above.
- Confirm your account, and your courses should show up within one-two business days.
Current Users enrolled in the new learning management system:
If you already have an account, your courses will be added to your existing account.
*Spouses need to create a separate online account as two people cannot complete their studies on the same account.
Session I Courses:
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Please contact Haylee Robinson at firstname.lastname@example.com if you have any questions about this process.


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CNET breaks out the most important things to know when shopping for a new television.
The Audiophiliac reviews the Hifiman RE300, a new low price model from a high-end headphone-maker.
What good is a digital assistant if she can't tell you to leave early because of traffic reports? That's a question asked by Microsoft at any rate.
The US Navy christens the first of three cutting-edge Zumwalt-class destroyers
The iOS 8.2 beta reveals new info about the Apple Watch, the next iPhone camera is announced by Sony, and YouGov profiles an Apple Fan versus a Samsung fan. We can't wait to see the comments.
Geordi has a giggle fit, Picard gets trampled by Bev Crusher, and Riker chases a shipmate in the most hilarious way possible in a new blooper reel.
The first teaser clip for the Chris Pratt-starring reboot harks back to a terrifying moment in the original "Jurassic Park".
The Charge tracks steps and sleep, and does it well, but you really should wait for the heart-rate-tracking version next year. Here's why.
LikeAGlove smart garments act like high-tech personal shopping assistants, checking your measurements and finding you clothes that fit.
Video games made by small studios have an effective tool in their arsenal when it comes to setting themselves apart.


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Thoughts on Paul Ryan?
Find a Conversation
|Mon, 08-13-2012 - 9:54am
I'm kind of new to iVillage, so I hope I'm posting in the right place!
I was just wondering what you think about Romney's VP choice. I don't know a lot about Paul Ryan, so I don't have much of an opinion yet.
|Tue, 08-21-2012 - 12:14pm
While it's understandable that the economy weighs heavily on the minds of many, failing to consider a candidate's or a party's stance on other issues would be a colossal and possibly catastrophic blunder.
Todd Akin is NOT a Missouri senator, though he's running for that office. His words matter because they indicate his mindset. Given the actions of other GOP congresspeople, there is reason to believe that the rights of women to reproductive choice are being attacked. Paul Ryan was one of the most active. http://www.rhrealitycheck.org/article/2012/08/20/what-does-ryan-believe-about-abortion IF the GOP dominates both houses of Congress as well as the White House (and an Akin victory was considered to be part of that strategy), then women could see their roles revert back to those of the fifties.
But that would only happen if women pay no attention to any issues but those associated with economic policy. See ladies? There's nothing threatening about that big wooden horse. No attack on your body or rights to control it until after you've cast your votes for conservatives and opened the gate....... The Cassandras among us know better. We see the actions of the past, compare them to the words of the present and come to the conclusion that there's a definite disconnect!
|Tue, 08-21-2012 - 11:57am
"Do show us the basis for your claim that "consumers are not buying". "
The claim that "consumers are not buying" was actually "claimed" by the poster to whom I was replying That was her assertion. I was simply opining about her assertion, so perhaps your question would be more correctly directed at her.
"Pffffffft. There was NO attempt to suppress military voting. That arrant nonsense was trumpeted by conservative outlets."
The democrats can try to spin it any way they want, but they certainly were trying to reduce the amount of time given to military voters to cast their votes. A study done by the nonpartisan Military Voters Protection Project found that in 2008 less than 20% of 2.5 million military voters successfully voted by absentee ballot, clearly demonstrating that they could benefit from the additional time Ohio was allotting them. It is a fact that on July 17, the Obama for America Campaign, the Democratic National Committee and the Ohio Democratic Party filed suit in Ohio, a swing state, to strike down part of the state's law governing voting by members of the military that gives them extra time to cast their ballots.
Romney's time at Bain did not have to do with "gutting" companies? Where did you get than information? According to the WSJ:
"Bain was investing in "riskier deals," said Steven N. Kaplan, a finance professor at the University of Chicago's Booth School of Business. "For every one that went bankrupt, they had one that was a screaming success. The overall effect was terrific performance" for the firm's investors.
Were all of the businesses successful? Of course not, to expect a 100% success rate would be foolish of us. However, a few of the businesses were/are very successful, like Staples and Domino's Pizza and created thousands of jobs for people. I wonder how many private sector jobs Obama has been responsible for creating during his pre political career? The answer to that question may give us an idea of whether or not he has a clue about what it takes to get it done and why we are stuck with unemployment numbers over 8%.
"As for "small businesses not hiring", that's another sweeping statement. Prove it."
That can be summed in one number: 8.3% unemployment rate......with a U6 rate of nearly 15%
|Tue, 08-21-2012 - 11:25am
|Tue, 08-21-2012 - 11:23am
|Tue, 08-21-2012 - 11:20am
|Tue, 08-21-2012 - 11:10am
|Tue, 08-21-2012 - 11:06am
|Tue, 08-21-2012 - 10:42am
Pffffffft. There was NO attempt to supress military voting. That arrant nonsense was trumpeted by conservative outlets.
At issue is the legality of an Ohio law cutting three days out of the early-voting period for everyone except members of the armed forces and Ohio citizens living overseas......
As state lawmakers debated changes to election laws, the Ohio Association of Election Officials endorsed the idea of cutting the three final early-voting days, those just before Election Day, contending they needed the extra time over the weekend to prepare for Tuesday voting.
Democrats say it smacks of political manipulation to restrict in-person voting for most people while giving service members extra time to cast a ballot, even if they are not stationed abroad. They want the three days added back for everyone. http://www.startribune.com/politics/national/166223166.html?refer=y
Too bad your awareness doesn't appear to extend to the role Congress played in jockeying and chivvying for political gain at the expense of the nation's wellbeing. That "failed record" was not just Obama's.
Again, if conservatives are really concerned about debt, they would look at all measures, including the raising of taxes to reduce the debt, not just the systematic evisceration of social safety nets and environmental safeguards.
Do show us the basis for your claim that "consumers are not buying". Looks to me like they're being a bit reluctant to buy homes but that's understandable given the volatility of the housing market, which BTW, started before Obama took office. As for "small businesses not hiring", that's another sweeping statement. Prove it. My DH is an SBO who hired three more employees this past month. Even with the additional hires, the company is extremely busy.
As for the last sentence that one of the candidates is "a man who realizes the importance small businesses have in our economy and has experience in that arena", I assume you refer to Romney. Bain Capital isn't a small business itself. Seems that the interaction Romney had with small businesses while at Bain had to do with gutting companies if it was decided that investors would be better served by so doing. Acting as hatchet men for corporate raiders, IOW. With friends like that, what small business needs enemies?!
|Tue, 08-21-2012 - 9:10am


text: In pictures: Parrot AR.Drone launch We get our hands on Parrot's latest iPhone toy: a remote control AR.Drone helicopter with a camera and Wi-Fi Campbell Simpson (Good Gear Guide) 0 - - - - print email prev next Loading... A demonstration of the Parrot AR.Drone with telemetry from the iPhone shown on the rear screens. Prev Next 13/24 Comments on this image There are currently no comments for this image. Post new comment Comment Name Email (This will be kept private) Users posting comments agree to the Good Gear Guide comments policy. Login or register to link comments to your user profile, or you may also post a comment without being logged in. Close In pictures: Parrot AR.Drone launch 1 24 images


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2003 Subaru Baja Owner Reviews
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- Performance
- Quality & Durability
03 baja
bought my baja from a dealer in florida, used of course, I could never have imagined how awesome this little truck is......I live in louisiana and I play with my toys hard.....this little truck will take a beating and continue to run excellent, drive excellent,and never misses a beat.........LOVE IT
Owner's Car DetailsReport This
- Trim:
- Base4dr Crew Cab
- Date Purchased:
- February, 2008
- Current Mileage:
- 100,000+
- My Age:
- 36-45
- Location:
- deville, Louisiana
- Type of Driving:
- Suburbs
- Driving Style:
- Spirited
- Primary Use:
- Daily Commuting
- Secondary Use:
- Fun or Weekend Car
Stohlman Subaru of Herndon770 Elden St, Herndon, VA 5.2 miles from you
Stohlman VW and Subaru8433 Leesburg Pike, Vienna, VA 13.6 miles from you
Subaru of America51 Mannakee St, Rockville, MD 17.0 miles from you
Brown's Manassas Subaru9020 Liberia Ave, Manassas, VA 17.8 miles from you
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