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Posts by John McArthur
2 posts • joined 7 Dec 2010
Dell and Compellent are exclusive
It's less about revenue than margin
Chris, regarding your statement: "...Dell's failure to generate significant revenue from its co-branded EMC CLARiiON block-access arrays..." I suspect this is more about margin than revenue. At one time Dell was a significant portion of EMC CLARiiON revenue, but they derive better margins from the Equallogic products. The acquisition of Compellent will give them the ability to capture more margin in larger enterprises.
NetApp whips out a blade
The list of VSA's doesn't stop with LeftHand (or NetApp)
In your discussion of Storage Virtual Appliances, you left off StorMagic (www.stormagic.com), which was one of the first to ship an SVA. They carry the VMware Ready designation: http://www.vmware.com/appliances/directory/323773. They also recently signed a reseller relationship with NetWorld, VMware's largest reseller in Japan.
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CBS Chicago 10/6/14: Video Honors Indiana Teenager Murdered By Ex-Boyfriend. A video has been launched in honor of a Northwest Indiana teenager who was murdered by her ex-boyfriend, and as a way to get the message of teen dating violence out. The five minute long video is part of an anti-violence message aimed at teenagers put together by the Caring Place in Valparaiso.
The Lauren Dunne Astley Memorial FundOur mission is to promote dynamic educational programs, particularly in the areas of the development of healthy teen relationships, the arts, and community service.
48 Hours: Breakup Violence Documentary "Loved to Death"
"Milk Cartons" by Kim Gallagher
Boston Globe: Parents of slain teen dedicated to ending dating violence
Preventing Breakup Violence
Beautiful Children's Book
Contact UsContact us by clicking here
The board of the Lauren Dunne Astley Memorial Fund is greatly appreciative of the pro bono legal services of Mintz, Levin, Cohn, Ferris, Glovsky and Popeo, P.C and of ML Strategies for advice and research.

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Word: Soós Imre
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Zambia Adventure Tours
Our Zambia adventure tours take you to the home of the breathtaking Victoria Falls and the wild Zambezi River. Zambia is the adrenaline capital and adventure playground of Southern Africa. Livingstone, named after the explorer David Livingstone, is just 10 kilometres south of the Victoria Falls and is the perfect place to cast aside your inhibitions with white water rafting (graded 3 to 5) on the lower Zambezi, bungee jumping, river boarding or jet boating. If you prefer a slower paced activity, why not try a game drive, canoeing or a helicopter ride to admire the raging Victoria Falls from above.
Mosi-oa-Tunya, as the Falls are known to local tribes, is a 1,700 metre-wide water sheet that crashes 110 metres into the Zambezi River below, and is one of the Seven Wonders of the World. David Livingstone described his first sight of the Falls as, "scenes so lovely (they) must have been gazed upon by angels in their flight", a sight you will enjoy on your Zambia adventure tour. Lusaka is Zambia's capital city and an ideal place to visit a market to soak up the colourful and lively atmosphere. In Chipata, ornate mosques are an unexpected surprise and an ideal last stop to stock up on local crafts to remind you of your Zambia adventure tour.
Enquire About This Tour Code RZBLS1 Victoria Falls Excursion Package
Duration: 3 Days Route: Livingstone to Livingstone Style: Add-ons Level: Standard Price: US$329.00
Known to the Mosi-oa-Tunya people as 'the smoke that thunders', Victoria Falls have been known to strike awe into the hearts of even the most intrepid of explorers, even David Livingstone himself, who gave his name to the nearby city. Twice as high as Niagara Falls and several times longer, Victoria Falls is an incredible sight, not to be missed. You'll also experience an evening sunset cruise on the Zambezi River.
Enquire About This Tour Code FKV Kruger to Vic Falls
Duration: 10 Days Route: Pretoria to Livingstone Style: Overland Tours Price: US$779.00
South Africa, Botswana, Zambia
Enjoy a taste of Africa in this tour through some of the continent's most popular highlights. Track down the Big Five at the world famous Kruger National Park and explore their natural habitat with expert guides. Explore Chobe National Park on a river cruise before we head to Victoria Falls to gaze at the majesty of 'the smoke that thunders'. We finish our adventure in Livingstone where you can enjoy adrenaline pumping optional excursions.
Enquire About This Tour Code FZV Zanzibar to Vic Falls
Duration: 14 Days Route: Dar es Salaam to Livingstone Style: Overland Tours Price: US$1,239.00
Tanzania, Malawi, Zambia
The tour begins with the enigmatic Isles of Zanzibar, exploring spice fields, stunning white-sand beaches and the labyrinthine alleyways of Stone Town. On to Malawi to visit traditional villages where the welcome is one of the friendliest in the world, ending up in Livingstone to see one of the natural wonders of Africa, the impressive Victoria Falls.
Enquire About This Tour Code FVZ Zanzibar to Vic Falls
Duration: 14 Days Route: Livingstone to Dar es Salaam Style: Overland Tours Price: US$1,329.00
Zambia, Malawi, Tanzania
Enjoy an exciting tour through some of Africa's most beautiful scenery including glistening Lake Malawi with its beaches and party atmosphere. Get an insight into Malawi's customs and lifestyle in Chitimba. Then on Zanzibar there's time to relax on the beach, go snorkelling, sip a cocktail and gaze over the waves or explore picturesque Stone Town, steeped in history.
The tour that we operate in the reverse direction is Zanzibar to Vic Falls (FZV).
Enquire About This Tour Code FVC Vic Falls to Cape
Duration: 19 Days Route: Livingstone to Cape Town Style: Overland Tours Price: US$1,629.00
Zambia, Botswana, Namibia, South Africa
Africa's animal life is extremely photogenic so make sure you bring plenty of memory cards to capture each exciting moment on safari. In the Chobe National Park you'll spot large herds of elephants while in the watery maze of the Okavango Delta there are hippos, birds and beautiful water lilies to look for. At Etosha National Park you can watch the animals gather at waterholes, and at Fish River Canyon you may see falcons riding the thermals.
Enquire About This Tour Code FNV Nairobi to Vic Falls
Duration: 19 Days Route: Nairobi to Livingstone Style: Overland Tours Price: US$2,359.00
Kenya, Tanzania, Malawi, Zambia
Explore the vast Serengeti National Park and experience the daily drama of life and death as predators track their prey across the savannah. Witness the natural beauty of diverse landscapes and hear the thunder of millions of hooves pounding across the plains during the great wildebeest migration. On Zanzibar unwind on the beach or discover the markets.
Enquire About This Tour Code FVN Nairobi to Vic Falls
Duration: 19 Days Route: Livingstone to Nairobi Style: Overland Tours Price: US$2,589.00
Zambia, Malawi, Tanzania, Kenya
This expedition into East Africa offers a unique combination of fascinating cultures and wildlife. Meet the friendly locals in the traditional Malawian village of Chitimba then enjoy a few days on the beach at Zanzibar, the spice island. During game drives at Serengeti National Park and Ngorongoro Crater there's plenty to see, including the Big Five if you're lucky!
The tour that we operate in the reverse direction is Nairobi to Vic Falls (FNV).
Enquire About This Tour Code FEA East Africa Adventure
Duration: 23 Days Route: Nairobi to Livingstone Style: Overland Tours Price: US$3,139.00
Kenya, Tanzania, Malawi, Zambia
Undisturbed wildlife, local culture, history and landscapes combine in a beautiful explosion of colours and sounds on this epic Overland Tour. It takes you from East Africa's most famous national parks to the incredible Victoria Falls, via the exotic spice island of Zanzibar and the tranquil shores of Lake Malawi.
Enquire About This Tour Code FKZ Kruger to Zanzibar
Duration: 24 Days Route: Johannesburg to Dar es Salaam Style: Overland Tours Price: US$2,299.00
South Africa, Botswana, Zambia, Malawi, Tanzania
Celebrate the diversity of Africa on this exciting overland expeditions tour. Kruger National Park in the heart of South Africa's big game country offers unspoiled scenery with opportunities to see cheetah on the hunt while giraffes graze the tree tops. In Chobe National Park see elephants bathing in the rivers and wandering the grasslands. The immense cascades of Victoria Falls and the glorious beaches of Zanzibar Island are highlights during the tour.
Enquire About This Tour Code FSA Southern Africa & Game
Duration: 29 Days Route: Pretoria to Cape Town Style: Overland Tours Price: US$2,399.00
South Africa, Zambia, Botswana, Namibia
The first stop on this thrilling adventure is a game drive through Kruger National Park, one of South Africa's most famous parks. If you don't spot the big five there then over the next month there will be plenty more opportunities in Etosha NP and Chobe NP. You'll also marvel at the incredible landscapes ranging from mountains and deserts, to one of the most dramatic coastlines in the world.


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Music veteran Nas recently discussed his perception of the rap game and how hip-hop stars like Kanye West, Drake, Rick Ross and more are forcing him to stay on his toes.
Satisfied with the variety in rap these days, Nas also co-signed hip-hop newcomers Odd Future.
"I'm happy about music, it's pushing me back into the studio. I just love what's happening [in music]: I love Odd Future, [Lil] Wayne, Drake, 'Ye [and] Rick Ross. It's something that threatens my position. Or it makes me question what I'm going to do next. What kind of impact do I want have now that I've been in the business this long. It's a challenge, it's scary even. But I'm very comfortable. I'm excited to see what comes out of me… I'm ready." (The Juice)
Earlier this month, rap veteran Rakim expressed his thoughts on the rap game lacking consciousness.
"It's hard," Rakim says. "The conscious level is definitely low and the substance of the music is so much lighter, but you have to understand the game is young in new places. It's still growing…We really need some of that consciousness, that fly on the wall that watches over us and comments. I like B.o.B. and Lupe Fiasco a lot, they're both exploring the music, but I don't see a lot of artistry out there." (The Guardian)
M.O.P.'s Billy Danze recently hit up SOHH and shared his outlook on the current state of rap.
"If you want to listen to four people, you buy one person's album and everybody's happy," Danze explained. "Fortunately, we were able to come into the game listening to Kool G Rap and Rakim, KRS-One, those guys that showed us it was cool to be different and cool to be creative and actually put you on to a record. Hip-Hop is always here. As long as M.O.P. is here, KRS-One, Rakim, all of us, we always got your back." (SOHH)
A few weeks back, fellow New York rapper Prodigy said he was optimistic toward the rap game.
"It's in a good place man," P said referring to hip-hop. "Any time you've got a whole bunch of competitors it only steps up the quality of the sh*t that's out there. How are you going to shine and stand out with all this new sh*t that's happening, and all the heavy competition in the game? What's going to make you so special? So it makes you work harder to prove that you deserve what you've got, prove that you deserve your sh*t. You've got to earn what you've got. So that's how I see it. It just makes you work that much harder." (Complex)
Check out a recent Nas interview below:


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Very good post, as well!
Submitted by SteveMartin on Fri, 06/01/2012 - 08:22. Permalink
Nevada patriots: BE SURE TO LEAN ON THE LIBERTY-LOVING CURRENT NV GOP to announce that they DO NOT support/condone TEAM NEVADA, and make sure they don't stall. Get it done now, and make sure they get it out as a press release to all major outlets in NV and to all the national networks, and large daily papers, etc.
"Truth is an absolute defense to the charge of paranoia."
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From the wardrobe malfunction seen around the world to a power outage of epic proportions, here are four Super Bowl halftime shows we couldn't forget.
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How Do We Interpret Christopher Dorner?
As he sat, surrounded, in that cabin with his foes having now encircled and closed in, was Dorner meditating on his role as an anti-hero to some, a villain to others? Did he make peace with the outcome and the consequences of his decision to shoot and kill several people? He fought "The "Man." But, in the end, did "The Man" really win? Given the bloody end of the Christopher Dorner saga the public will likely never get a clear answer.
Christopher Dorner will live a life much longer than the 30 years he spent on terrestrial earth. The 24/7 news cycle will quickly move on. But in many communities Dorner is going to be discussed—both positively and negatively—for quite some time to come.
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One of the things that happens the night before Basket Day is using up the remnants of whatever is left in the veggie drawer in the fridge. One of the easiest things to do (and currently one of our favorites) is to go Indian – with a veggie tikka masala.
Archive for the 'By Diet Style' Category
Vegetable Tikka MasalaFriday, May 9th, 2014
One of the things that happens the night before Basket Day is using up the remnants of whatever is left in the veggie drawer in the fridge. One of the easiest things to do (and currently one of our favorites) is to go Indian – with a veggie tikka masala.
Mozzarella Stick StackersThursday, January 30th, 2014
As a little kid (and a college kid, and a newly married kid) one of my favorite junk food treats was a crispy, fried mozzarella stick. There is just nothing better than biting into a crunchy layer of browned bread crumbs followed by the oooey- goooey- goodness of cheese. Well, maybe even better is giving that a dip into some spicy marinara sauce. But after my second baby I started to feel my metabolism slowing down and by baby number four it was quite apparent that an indulgent mozzarella stick would hang around (in the form of hips and tummy) for far longer than I wanted. It was clear I had to avoid one of my favorite guilty pleasures. Until now! (more…)
Lemon Blueberry MuffinsWednesday, January 29th, 2014
I should have never questioned one of my friends….she knows I love allergy friendly recipes! She brought these to a MOPS meeting (Mothers of Preschoolers). I begged and she sent me this recipe…..but told me she used regular butter…..so I subbed in dairy free Earth's Balance and created a dish both my son and another friend (gluten free) could have. (more…)
Veggie scrambleTuesday, January 21st, 2014
I really need a protein rich breakfast to get my day started. One of the easiest and healthiest protein breakfasts is for me to scramble up some eggs. This is a great recipe to use up a variety of vegetables and it is fast so it is perfect for weekday mornings. I will pretty much use whatever I have on hand but some of my favorites are tomatoes, spinach, kale, onion, broccoli, carrots, summer squash, zucchini, herbs, leeks, and potatoes. (more…)
Brussels Sprouts and Parmesan FrittataWednesday, December 25th, 2013
My chickens have an incredible ability to produce more eggs than we can eat at breakfast, so we are constantly on the lookout for dinner recipes that have the ability to use a ton of eggs! This recipe fits the bill, and could only perhaps be improved by a smidge of bacon being added at the beginning.
Tangy Cran-Orange Coconut ChickenWednesday, December 18th, 2013
When I was a small child, I would awake Christmas Eve morning to the smells of cinnamon, cloves, vanilla, oranges and cranberries that wafted around the clinking sounds of Grandma in the kitchen preparing everyone's favorite dishes for our dinner later that day. Grandpa would be in the his chair humming Christmas Carols as he put on his shoes. I could see the glow of the Christmas tree lights dancing across the ceiling from where I lay snug in my bed, cozy and warm under the heavy handmade quilt. (more…)
Pear-Lime Water InfusionMonday, October 21st, 2013
Infusing fruit flavors into water is one trick I use it make water just a little more fun. Our bodies need to replenish water that is lost due to perspiration, through regular trips to the bathroom, and even through breathing. Dehydration, even mild, can be the cause for fatigue, dry skin, headaches, The amount of water differs for each person but following the simple, 8-8 rule… Eight glasses of eight ounce fluids is a great idea.
Asparagus and Sardine PastaFriday, October 18th, 2013
Did you luck out with a case of asparagus last week? I was lucky enough to share a case with a friend. I've got Asparagus coming out my ears…Here is one way that I used some this week.
I started out following Gordon Ramsay's recipe for a rustic pasta sauce that included anchovies. Well, I didn't have any anchovies, but I did have sardines. Earlier in the day, I had canned a bunch of asparagus, and had some inch long pieces that didn't quite fit in my jars. So, I decided to take Gordon's basic recipe and modify it for what I had on hand in my kitchen.
Stuffed Pepper Soup Freezer packsTuesday, October 15th, 2013
Its officially Soup Season! Its my favorite go to lunch, a steaming bowl of soup and a sandwich really hits the spot on cold days. I really love when I can go out to the deep freeze and grab a soup pack and have lunch or dinner on the table in an hour, or in the crockpot in minutes. Several readers were curious how I make freezer packs from recipes, here is how I break it down.
Weekend BountyTuesday, October 15th, 2013
Saturday breakfast is hard. With getting up to volunteer at the BB site, bringing the bounty home, and then trying to get everything rinsed and put away, making breakfast on Saturday morning is generally the last thing I want to do. But this time, my husband woke up early to pick up our bounty and the bonus was that I was highly motivated to make something yummy for breakfast! Low and behold, beautiful grape tomatoes, onions, asparagus, and I just happened to have mushrooms and eggs in the fridge. Coupled with the most wonderful Organic honey wheat bread purchased as an add-on this week this was a Saturday morning treat I'm sure I can use to bribe my husband and children to wake up every Saturday morning for basket pickup!


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Win 1 of 5,000 awesome FIFA15 codes thanks to Coca-Cola
We take a look at Ubisoft's next iteration in the Far Cry universe to see just what is on offer
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Need for Speed: Rivals Review
(Score: 8.5/10)
Review by ko-zee-ii @ 15th November, 2013
Whether you're a looking to leave your mark as a maverick speed demon with a legion of fans or skirting the thin blue line desperate to shut entitled street trash down, each campaign is a blast to work your way through, even if the plot surrounding them isn't.
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Deadfall Adventures Review
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Review by KostaAndreadis @ 15th November, 2013
Deadfall Adventures neatly follows this path but also tries to provide a story driven adventure that transcends its genre (the first-person shooter) by tying it to the title's namesake – the traditional adventure game.
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(Score: 6.8/10)
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Call of Duty: Ghosts Review
(Score: 6.9/10)
Review by Steve Farrelly @ 12th November, 2013
With that out of the way, the first thing to really regale is that Call of Duty: Ghosts is a mess of a game. That's not to say that it's nonfunctional or bad to play, rather, it loses sight of its core principles and eschews an amazing opportunity with the advent of our transition to next-gen, as well as being the first
IW CoD sans Zampella and West, through poorly constructed (and utilised) tech, half-assed delivery of modes and a single-player campaign that sets the series back more than a few years...
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Rocksmith 2014 Edition Review
(Score: 9.5/10)
Review by Dan @ 8th November, 2013
By itself, as just a game for someone that has no interest in learning guitar, it's probably no more or less engaging than past rhythm games, but for those who dream of shredding, I can't think of a better starting point.
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Phoenix Wright: Ace Attorney - Dual Destinies Review
(Score: 8.9/10)
Review by Gameboffin @ 6th November, 2013
Dual Destinies is a comfortable sequel. Yet another episode where satisfaction comes not from some new gameplay innovation but the bordering-on-laborious logic hills that must be traversed.
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Assassin's Creed IV: Black Flag Review
(Score: 9.3/10)
Review by nachosjustice @ 29th October, 2013
The greatest compliment I can afford Black Flag, though, is that I wanted more at the end of my time with it. With such an expansive map to explore and so many alluring distractions on offer, this is the kind of game a player could easily lose scores of hours exploring...
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Battlefield 4 Review
(Score: 9.4/10)
Review by nachosjustice @ 29th October, 2013
Battlefield 4 is visually amazing, with plenty of pretty that is often simultaneously aesthetic and practical, while the DICE sound wizards continue to forge a second-to-none soundscape that complements the eye candy...
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Skylanders SWAP Force Review
(Score: 9.1/10)
Review by Hoops @ 26th October, 2013
It's very easy to dismiss the whimsical art style, collecting and platforming as a game for kids, but dig a little deeper and you'll find a lot to like about Swap Force.
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Batman: Arkham Origins Review
(Score: 7.8/10)
Review by Jickle @ 25th October, 2013
For all its faults, Arkham Origins lives up to the prestige associated with its name. It's easy to be negative about it, simply because everything it does well the previous games also pulled off splendidly, but the fact is that if the other Arkham games didn't exist this would be the best Batman game ever by a mile.
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Scribblenauts Unmasked: A DC Comics Adventure Review
(Score: 5.5/10)
Review by Gameboffin @ 15th October, 2013
It's also quite a well made side-scrolling adventure, especially if you love the DC universe. However, I can't help thinking that if more effort had gone into tweaking character aggression and interactions the resulting product might have been far more enjoyable...
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The Wolf Among Us Review
(Score: 8.0/10)
Review by Jickle @ 14th October, 2013
Right from the start it feels like the work of an assured, energised developer, one looking to top their crowning achievement. Whether or not this will actually happen is anyone's guess, but things are off to a promising start...
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Beyond: Two Souls Review
(Score: 2.5/10)
Review by Jickle @ 13th October, 2013
David Cage may have succeeded at making his most cinematic game yet, but if I'd paid $8 to see Beyond on the cinema's cheap day I would have walked out well before the credits rolled.
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FIFA 14 Review
(Score: 7.0/10)
Review by Joaby @ 30th September, 2013
FIFA 14 is a solid game, and the changes to FIFA Ultimate Team certainly improve that aspect, but I have too many issues with other elements of it...
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Diablo 3 Console Review
(Score: 9.0/10)
Review by Steve Farrelly @ 20th September, 2013
Diablo III adds just enough to the console experience to separate it from its older PC sibling without stripping away the core action RPG base.
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Fiesta Ivory Holiday Bread & Butter Plate
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Capture the spirit of the season with this festive Fiesta collection. Featuring whimsically decorated trees against a classic ivory background, these pieces are sure to mix and match perfectly with all your holiday dinnerware and decor. For gatherings or family meals, this Fiesta holiday collection is the perfect way to celebrate the most wonderful time of the year.
- Sculpted, concentric rings highlight the edges.
- Chip-resistant construction ensures years of use.
- Nonporous glaze withstands food odors.
- Details:
- 6 1/8-in. diameter
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- Model no. 4639051
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One killed, four hurt in west side crash
IMPD continues to investigate what led up to the crash.
IMPD continues to investigate what led up to the crash.
He says, especially on days like Thanksgiving when families get together, a healthy person can still get others sick.
Popovich missed the game after undergoing what the team is calling a minor medical procedure.
This year, many stores plan to open on Thanksgiving, and police issued reminders for shoppers to take precautions.
Those volunteers are working to get food prepared for Thursday, which will be served at 40 different sites in the Indianapolis area.
The man barricaded himself in a garage with a meth lab when police tried to serve him with a search warrant, ISP officials said.
Business owners said the night before the holiday is one of the biggest party nights of the year.
A detective made contact with one woman, who was later arrested on a misdemeanor charge of prostitution.
Despite all the benefits the cameras still have limits.
Lawyers for the plaintiff, who sued to try to stop the hunt, argued the city didn't follow proper procedures in allowing it to begin with.


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In the famous Greenwich Village of New York, West Fourth Street Basketball courts sit right on top of the major junction of the West Fourth Street Subway line. Starting as an underused square of concrete with two baskets & surrounded by chain link fence, it was used for seedy hanging out and not much sport. By the Seventies it was turning into hot competitive games with fewer amateurs and serious top-notch players. Huge crowds of fans, rock'n'roll blaring on fuzzy speakers, beer, hooking up, and a lot of nonsense and brawls.
It's equally famous as the subway stop where you get out for the West Village: jazz, food, great Italian neighborhood, theatres, tiny but highly-coveted apartments, NYU campus down the block in Washington Square, beatniks, Mc Dougal Street, markets, and lots of street and foot traffic.
You'd be running up the same subway steps that Bob Dylan used to race to get to the nickel and dime gigs at dark clubs when he was making history.
Great description Barbara.
Thanks, Alistair. I used to spend so much time in the Village, lots of friends there, lots of waitressing jobs over the years, lively interesting place. And West Fourth Street subway station was a vast, multi-train line stop and launch for Manhattan.
– Barbara Sparhawk
Hi Barbara! Your writeups are the BEST! I am always learning the most interesting facts from you, my Dear Friend! Wonderful addition to your collection………xxoo
Ruthie, my Buddie, many thanks. I really enjoy writing up these little histories of the city I lived in for so long. When I read about your environs, it's equally interesting, the shape of the land and it's skies. xx00 back atcha.
– Barbara Sparhawk
Beautifully created and beautifully described, Barbara. Your words always bring these scenes to life for me. Thank you!
Thanks, dear Sande. Posting some more artsy stuff soon, but I wanted to get this one out. W 4th has become a landmark.
– Barbara Sparhawk
Cool, love reading where you have been : )
Thanks, bites….same here. This place is a university for me; glad to contribute bits and pieces.
– Barbara Sparhawk
Stunning tee & wonderful description.
Thanks so much, photos40. It's a lively place.
– Barbara Sparhawk
Please call me Wayne.
Howdy, Wayne. Nice to meet you, properly.
– Barbara Sparhawk


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text:
A method and apparatus are provided for using certain hydrofluoroethers (HFEs) as low temperature heat transfer media in secondary loop refrigeration systems. These materials exhibit a low, somewhat linear Temperature Difference Factor over the temperature range of −15° C. to −65° C., making them ideal for use as low temperature heat transfer media. The HFEs of the present invention are nonflammable, nontoxic, environmentally benign, and have a high heat transfer capacity and low viscosity over the required operating temperatures. Furthermore, since these materials have high boiling points and low freezing points, they are not prone to phase changes over the required operating temperatures, and do not require pressurized systems.
1. A refrigeration system, comprising:
a display case for displaying refrigerated goods;
firstsecond heat transfer means for transferring heat from said display case to a firstsecond heat transfer medium; and
secondfirst heat transfer means for transferring heat from said firstsecond heat transfer medium to a secondfirst heat transfer medium; wherein said secondfirst heat transfer means cools said firstsecond heat transfer medium to less than about −15° C., and wherein said firstsecond heat transfer medium comprises an ether of the formula
wherein R1 and R2 are alkyl groups, and wherein at least one of R1 and R2 is at least partially fluorinated.
2. The refrigeration system of claim 1, wherein R1 is a perfluorinated alkyl group.
3. The refrigeration system of claim 1, wherein R1 and R2 are short chain alkyl groups, and wherein R1 is perfluorinated.
4. The refrigeration system of claim 1, wherein said ether is selected from the group consisting of C3F7OCH3, C4F9OCH3, and C4F9OC2H5.
5. The refrigeration system of claim 1, wherein said second first heat transfer medium comprises ammonia.
6. The refrigeration system of claim 1, further comprising:
accelerating means for accelerating the rate at which heat is transferred from said heat source to said first second heat transfer medium.
7. The refrigeration system of claim 6, wherein said accelerating means induces a turbulent flow in the atmosphere between said heat source and said first second heat transfer means.
8. The refrigeration system of claim 7, wherein said accelerating means comprises a high velocity fan.
9. The refrigeration system of claim 1, wherein said first heat transfer medium and said second heat transfer medium are disposed in separate refrigeration loops.
10. The refrigeration system of claim 1, wherein said first second heat transfer means comprises a refrigeration coil disposed in said display case.
11. A refrigeration system, comprising:
a display case for displaying refrigerated goods;
a first refrigeration loop with a first refrigerant disposed therein;
a second refrigeration loop with a first refrigerant disposed therein;
a refrigeration coil, in open communication with said second refrigeration loop, for transferring heat from said display case to said second refrigerant; and
a heat exchanger for transferring heat from said second refrigerant to said first refrigerant;
wherein said first second refrigerant comprises a fluorinated ether.
12. The refrigeration system of claim 11, wherein said refrigeration coil is disposed in said display case.
13. The refrigeration system of claim 11, further comprising:
a compressor for transferring heat from said first refrigerant to the ambient atmosphere.
14. In combination with the refrigeration system of claim 11, a building defining an interior space and an exterior space, wherein said display case is disposed in said interior space and said compressor is disposed in said exterior space.
15. The combination of claim 14, wherein said first refrigeration loop is disposed primarily in said exterior space and said second refrigeration loop is disposed primarily in said interior space.
16. The refrigeration system of claim 11, wherein said first second refrigerant is cooled to less than about −15° C.
17. The refrigeration system of claim 11, wherein said first second refrigerant is cooled to less than about −25° C.
18. The refrigeration system of claim 11, wherein said ether is selected from the group consisting of C3F7OCH3, C4F9OCH3, and C4F9OC2H5.
19. The refrigeration system of claim 11, wherein said first refrigerant comprises ammonia.
20. The combination of claim 11, wherein said first refrigerant comprises ammonia, wherein said fluorinated ether is selected from the group consisting of C3F7OCH3, C4F9OCH3, and C4F9OC2H5, and wherein said second refrigerant is cooled to less than about −15° C.
21. The combination of claim 20, wherein said second refrigerant is cooled to less than about −25° C.
This is a Continuation of U.S. patent application Ser. No. 08/731,539, filed Oct. 16, 1996, now U.S. Pat. No. 5,713,211.
The present invention relates to heat transfer media, and in particular to the use of hydrofluoroethers (HFEs) as low temperature heat transfer media.
Various materials are known to the art which can be used as heat transfer media in refrigeration systems. These materials include water, aqueous brines, alcohols, glycols, ammonia, hydrocarbons, ethers, and various halogen derivatives of these materials. While many of these materials are effective as heat transfer media under certain conditions, practical considerations eliminate many of them from use in key commercial settings, such as in refrigeration systems in grocery stores. In these applications, only a fraction of the class of known heat transfer agents are of commercial significance.
One factor that eliminates many heat transfer media from consideration is their environmental impact. Many known heat transfer media are being phased out because of their environmental persistence, or because they have been implicated in depletion of the ozone layer. An example of the former are the perfluoroalkanes, whose chemical inertness prevents them from being degraded by the natural processes that cleanse the atmosphere. As a result, perfluoroalkanes can have atmospheric half lives of several decades. An example of the latter are the chlorofluorocarbons, which are currently being banned in most countries. See, e.g., P. S. Zurer, "Looming Ban on Production of CFCs, Halons Spurs Switch to Substitutes." Chemical & Engineering News, page 12, Nov. 15, 1993.
Another factor that removes many heat transfer agents from consideration is their toxicity. This is the case, for example, with ammonia and with many of the ethylene glycols. The toxicity of these materials, by ingestion, inhalation, or transdermal absorption, makes them dangerous to handle and unsuitable for commercial food handling environments.
Still other heat transfer agents are disfavored because of their flammability. This is the case, for example, with most ethers and hydrocarbons. The risk of flammability is particularly great where the heat transfer agent is subject to large positive pressures within the refrigeration cycle.
Other heat transfer agents are disfavored because they are gases at normal operating temperatures. An example of this type of refrigerant is ammonia. Gaseous heat transfer media require special high pressure equipment, such as pressure regulators and reinforced tubing, that are not required for refrigerants that remain in a liquid state through most or all of the operating cycle. Furthermore, high pressure systems are prone to leakage. Thus, it has been estimated that annual refrigerant losses to the atmosphere from high pressure systems fall within the range of 10 to 20% of the full charge per year.
Still other heat transfer media are not preferred because of their corrosive nature. Many of the aqueous brines fall into this category. Like gaseous media, corrosive agents require special handling provisions, such as Teflon®-lined conduits and interfaces, which add significantly to the overall cost of the system. Furthermore, restrictions on the selection of materials usable with corrosive agents decreases the overall efficiency of these systems.
Recently, a new type of refrigeration system has emerged that has placed even greater demands on the already narrow class of commercially viable refrigerants. This type of system, known as a secondary loop refrigeration system, has many advantages over conventional refrigeration systems, one of the most important being a significant improvement in energy efficiency. Currently, 20% of the refrigerants sold in the United States are installed in conventional high pressure supermarket systems. These systems consume about 4% of the electrical energy output in the United States each year (see Hrnjak, EPA grant application AEERL 5-22, Mar. 25, 1995). Hence, the total energy savings offered by secondary loop refrigeration systems in the supermarket sector alone is enormous.
In addition to being more energy efficient, secondary loop systems are also more compact in design, can be factory built, and are capable of operating with an extremely small charge of refrigerant. Furthermore, in secondary loop systems, the vapor compression process of the refrigeration cycle is centralized, and can be operated from a remote location. Thus, the compressor in a secondary loop system can be placed on a roof top, in a ventilated machine room, or in any other convenient location where it will not occupy valuable floor space or contribute to background noise, and where the effects of refrigerant leakage are minimized. Also, since the primary running through the compressor is segregated from the secondary loop used to cool the goods being refrigerated, the primary loop may utilize ammonia and other high efficiency refrigerants that are unsuitable for use as direct refrigerants in many applications.
While secondary loop systems have many clear advantages over conventional refrigeration systems, for commercial use of secondary loop systems has been limited by the unavailability of suitable secondary refrigerants. For a secondary loop system to function most efficiently, the heat transfer media within the secondary loop must be cooled to a low temperature, typically at least −15° C., and more preferably lower than about −25° C. While refrigeration systems are known that cool to temperatures of −30° to −40° C., such systems typically require the use of high pressure refrigerants to achieve these temperatures. The disadvantages of high pressure systems have already been noted.
Unfortunately, absent a high positive pressure, most refrigerants that perform suitably at normal temperatures no longer perform well at the low temperatures required by secondary loop systems. See, e.g., E. Granryd, A. Melinder, "Secondary Refrigerants for Indirect Refrigeration and Heat Pump Systems", ScanRef 14-20 (April 1994), which considers a variety of secondary refrigerants, but concludes that it is difficult to nominate good candidates for low temperature applications. At low temperatures, the viscosities of many refrigerants increase to the point where a large amount of energy is required to circulate the refrigerant through the secondary cooling loop. Propylene glycol exhibits this phenomenon. Other refrigerants, such as silicone oils and hydrocarbon based fluids, have a poor heat transfer capacity at low temperatures. As a result, systems utilizing these refrigerants suffer a marked decrease in energy efficiency at lower temperatures. Often, the drop off in performance of refrigerants at lower temperatures is precipitous. Thus, the efficiency with which Tyfoxit® 1.15 transfers heat decreases by more than 15% between −10° C. and −15° C. When one considers that many conventional refrigerants undergo phase changes at temperatures above about −20° C., the choices of heat transfer media for secondary loop systems are few indeed.
There thus remains a need in the art for a heat transfer medium that is suitable for low temperature applications, and for secondary loop refrigeration systems in particular, and which is nontoxic, nonflammable, environmentally friendly, and does not require the use of a high positive pressure. These and other needs are answered by the present invention, as hereinafter disclosed.
The present invention provides a method and apparatus for using certain hydrofluoroethers (HFEs) as low temperature heat transfer media in secondary loop refrigeration systems. Surprisingly, these materials exhibit a low, somewhat linear Temperature Difference Factor over the temperature range of −15° C. to −65° C., making them ideal for use as low temperature heat transfer media. The HFEs of the present invention are nonflammable, nontoxic environmentally benign, and have a high heat transfer capacity and low viscosity over the required operating temperatures. Furthermore, since these materials have high boiling points and low freezing points, they are not prone to phase changes over the required operating temperatures, and do not require pressurized systems.
FIG. 1 is a schematic drawing of a secondary loop refrigeration system suitable for installation in a supermarket;
FIGS. 2 and 2a are graphs depicting the pressure drop factor as a function of temperature for some embodiments of the present invention as well as several prior art heat transfer fluids;
FIGS. 3 and 3a are graphs depicting the heat transfer factor as a function of temperature for some embodiments of the present invention as well as several prior art heat transfer fluids;
FIGS. 4 and 4a are graphs depicting the temperature difference factor as a function of temperature for some embodiments of the present invention as well as several prior art heat transfer fluids; and
FIGS. 5-7 are graphs depicting the theoretical specific pump power requirements of several conventional secondary cooling fluids compared with C4F9OCH3, C3F7OCH3 and C4F9OC2H5 respectively.
As used herein, the term "secondary loop refrigeration system" refers to a system in which a heat transfer medium is used to transport energy from a heat source to a primary refrigeration system.
The term "secondary loop" refers to the path over which the heat transfer medium travels while it is being cycled between the heat source and the primary refrigeration system.
The term "secondary refrigerant" refers to the heat transfer medium in the secondary loop.
The term "primary refrigeration system" refers to that portion of a secondary loop refrigeration system where heat is transferred to the external environment by way of a compressor.
The term "primary refrigerant" refers to the heat transfer medium used in the primary refrigeration system.
FIG. 1 illustrates the configuration of a typical secondary loop refrigeration system 10 suitable for installation in a grocery store. The goods to be refrigerated are arranged in a series of display cases 12 located throughout the store. Each display case is fitted with one or more refrigeration coils that are in open communication with a network of liquid feedlines 14 which convey the secondary refrigerant from the primary refrigeration system 16 to the display cases.
In operation, energy enters the display cases in the form of ambient heat, and is transferred to the secondary refrigerant by way of the refrigeration coils. The transfer of heat to the secondary refrigerant is typically facilitated by the use of fans, which circulate air around the goods in the display case and over the surfaces of the refrigeration coils. The warmed secondary refrigerant is then withdrawn from the display cases through the liquid return lines 18 by means of a circulation pump 20 and is fed into a primary-to-secondary heat exchanger 22, where the heat from the warmed secondary cooling medium is transferred to the primary refrigerant. The cooled secondary medium is then returned to the display cases by means of the liquid feed lines.
The warmed primary refrigerant is circulated through a roof top compressor 24. In the compressor, heat is extracted from the primary refrigerant and expelled to the environment. In the process, the primary refrigerant is liquefied and cooled. The primary refrigerant is then expanded and returned to the primary-to-secondary heat exchanger.
To date, several criteria have been used in the art for selecting refrigerants for particular applications. However, for the purposes of the present invention, it was desirable to find a single factor that would summarize the overall performance of a refrigerant as a function of temperature, and that could be used to compare the performance of any two refrigerants independent of system specific variables. In order to accurately reflect the performance of a heat transfer medium in a secondary loop refrigeration system, such a factor would have to take into account the energy required to pump the medium through the secondary loop as temperature decreases, and the ability of the medium to transfer heat at lower temperatures.
The factor selected for this purpose is the Temperature Difference Factor (F∂), which has been described by Granryd and Melinder, SCANREF International, pp. 15-20 (April 1994). The Temperature Difference Factor describes the performance of a fluid over a broad temperature range by characterizing the temperature difference on the fluid flow side of a heat exchanger under turbulent flow conditions, at a given heat flux, q, and at a given specific pumping power, E/Q. The Temperature Difference Factor can be determined from four system independent transport variables: density, thermal conductivity, specific heat, and kinematic viscosity. Consequently, the Temperature Difference Factor allows for direct comparison of performance for both aqueous and non-aqueous secondary cooling fluids over their entire operating ranges by showing the temperature rise of a given fluid as it passes through a heat exchanger under predetermined conditions of heat flux, load, pump power, pump efficiency and tube diameter. In evaluating heat transfer fluids, a low value of F∂indicates a low temperature rise, and therefore high heat transfer efficiency.
The Temperature Difference Factor (F∂) is calculated from the equation
where q is the heat flux, d is the diameter of the tube, ηp is the pump efficiency, Ep is the pump power, Q is the load and ∂ is the temperature difference between the fluids in the heat exchanger. The equation can be solved for pump power, Ep, and the ratio of pump powers for any two fluids can be determined. This ratio provides a comparative factor for the relative pump power requirements of two different fluids under a given set of fixed conditions of heat flux, load and tube diameter, and is given by the equation
For example, a first fluid having F1∂=0.006 and a second fluid having a F2∂=0.004 Kg2/7 m2S1/3/J would have a pump power ratio of 4.1. This demonstrates that the power required to pump the first fluid is 4.1 times greater than the second fluid.
Equation 1 may be simplified to
where Fp is the Pressure Drop Factor and Fα is the Heat Transfer Factor. The Pressure Drop Factor is an estimate of the pressure drop, or loss due to friction, as a fluid flows through a tube. As such, it is a function of both fluid properties and system properties. This factor separates fluid-dependent variables from system-dependent variables and, when plotted as a function of temperature, allows different fluids to be compared, independent of system specific variables. The Pressure Drop Factor is calculated by the equation
where ρ is density of the fluid and ν is the kinematic viscosity of the fluid at a specified temperature.
The Heat Transfer Factor is proportional to the heat transfer of a fluid under turbulent flow conditions. Heat transfer is a function of both fluid properties and the geometry of the heat transfer surface. As with the Pressure Drop Factor, the fluid-dependent variables may be separated from the system-dependent variables and the former may be plotted as a function of temperature. The Heat Transfer Factor (Fα) may be calculated by the equation
where λ is the thermal conductivity, ρ is the density, cp is the specific heat, and ν is the kinematic viscosity.
The heat transfer media useful in the present invention comprise fluorinated ethers of the formula
where R1 and R2 are the same or different and are selected from the group consisting of substituted and nonsubstituted alkyl, aryl, and alkylaryl groups and their derivatives. At least one of R1 and R2 contains at least one fluorine atom, and at least one of R1 and R2 contains at least one hydrogen atom. Optionally, one or both of R1 and R2 may contain one or more caternary or noncaternary heteroatoms, such as nitrogen, oxygen, or sulfur, and/or one or more halogen atoms, including chlorine, bromine, or iodine. R1 and R2 may also optionally contain one or more functional groups, including carbonyl, carboxyl, thio, amino, amide, ester, ether, hydroxy, and mercaptan groups. R1 and R2 may also be linear, branched, or cyclic alkyl groups, and may contain one or more unsaturated carbon-carbon bonds.
Preferably, the heat transfer media of the present invention comprise fluorinated ethers of the formula
where Rf and R are defined as above for R1 and R2, except that Rf contains at least one fluorine atom, and R contains no fluorine atoms. More preferably, R is a noncyclic branched or straight chain alkyl group, such as methyl, ethyl, n-propyl, iso-propyl, n-butyl, iso-butyl, or t-butyl, and Rf is a fluorinated derivative of such a group.
In the most preferred embodiment, R1 and R2 or Rf and R are chosen so that the compound has at least three carbon atoms, and the total number of hydrogen atoms in the compounds is at most equal to the number of fluorine atoms. Compounds of this type tend to be nonflammable. Specific examples of preferred heat transfer media for use in the present invention include C3F7OCH3, C3F7OC2H5, C4F9OCH3, and C4F9OC2H5.
The heat transfer media of the present invention may be used alone or in conjunction with one or more other heat transfer media of the invention or with one or more other heat transfer media as are known to the art. The heat transfer media of the present invention may be used as a pure compound, or as a blend, solution, or mixture (azeotropic or otherwise) with one or more other materials. Such other materials may include other heat transfer media, either of the present invention or as are known to the art, or one or more substances used to induce a freezing point depression or boiling point elevation.
Examples 1-4 illustrate the improved performance characteristics of the heat transfer media of the present invention, compared to prior art heat transfer media.
The thermal conductivities of C4F9OC2H5, C4F9OCH3, C3F7OCH3, and C6F14 were determined using a transient, hot-wire thermal conductivity cell over the temperature range of −50° C. to +50° C., according to ASTM D 2717-86. A platinum wire was used in the measurements. The wire was 20 cm in length, 0.17 mm in diameter, and had a resistance of 120Ω at 20° C. The thermal conductivities are set forth in Tables 1-4.
The densities of the fluids of Example 1 were determined from 0° C. to +50° C. using a using a Mettler-Parr Model DMA45 densitometer. For temperatures below 0° C., densities were determined by extrapolation of the measured densities with a linear curve fit. The densities are set forth in Tables 1-4.
The kinematic viscosity of the fluids of Example 1 were measured according to ASTM D 4486-85 over the temperature range of −60° C. to 25° C. The results were curve fit to five data points. The resulting kinematic viscosities are set forth in Tables 1-4.
The specific heats of the fluids of Example 1 were measured by differential scanning calorimetry according to ASTM E 1269-90 over a temperature range of −30° to 58° C. For temperatures below −30° C., specific heats were determined by extrapolation of the measured specific heats with a linear curve fit. The specific heats are shown in Tables 1-4.
The values of the Pressure Drop Factor, the Heat Transfer Factor and the Temperature Difference Factor were calculated using Equations 1, 3, 4 and 5 for the temperature range 20° C. to −60° C. for each of the compounds of Example 1, based on the data in Table 1-4. For the purposes of these calculations, the specific heats and thermal conductivities for the compound C3F7OCH3 were assumed to be the same as for C4F9OCH3. For comparison, corresponding data was collected for C6F14, and the Pressure Drop Factor, Heat Transfer Factor, and Temperature Difference Factor were determined for this compound as well. These results are plotted in FIGS. 2-4. For further comparison, the Pressure Drop Factor, Heat Transfer Factor, and Temperature Difference Factor for several conventional refrigerants, as obtained from Granryd and Melinder, supra, is also shown. The units for the Heat Transfer Factor are J/(s1/3m8/3°C.). The units for the Pressure Drop Factor are Kg/(m13/5S1/5). The units for the Temperature Difference Factor are (Kg2/7m2 s1/3)/J
The above Examples, as summarized in FIGS. 2-4, illustrate the unexpected advantages of the heat transfer media of the present invention over other refrigerants in low temperature applications.
FIGS. 2 and 2a depict the Pressure Drop Factor as a function of temperature for several heat transfer media. The viscosity of a fluid has the greatest influence on the Pressure Drop Factor. A low viscosity indicates that the fluid enters turbulent flow sooner given the same fluid velocity. The frictional forces from the tube walls are translated into the fluid, forcing it to churn and mix. As the viscosity increases with reduced temperature, the frictional forces also increases, as does the Pressure Drop Factor.
The relative energy transfer losses that occur due to friction are readily apparent from FIGS. 2 and 2a. All of the aqueous solutions follows a nonlinear plot as the temperature drops. The fluids with the least pressure drop are the Dowtherm® (a mixture of alkylated aromatic isomers, available from Dow Corning Corp., Midland, Mich.) and Syltherm® (a silicone polymer available from Dow Corning Corp., Midland, Mich.) heat transfer fluids, primary due to their combined low viscosity and low density. Below −15° C., C4F9OCH3 is surpassed only by these two fluids.
With reference to FIGS. 3 and 3a, the Heat Transfer Factor curves are essentially linear for all of the fluids of interest, although the slopes of these curves vary significantly. The aqueous solutions generally follow the same slope, but are shifted along the ordinate by the different freezing point depressants added to the water. Relative to the non-aqueous fluids, the slopes of the curves for the aqueous solutions are quite steep, and indicates that their ability to transfer heat drops off rapidly as the operating temperatures of secondary systems is approached. Below −20° C., C4F9OCH3 holds the highest value of the Heat Transfer Factor.
The value of the Pressure Drop Factor is generally less significant than the value of the Temperature Difference Factor. As noted in Equation 3, the Pressure Drop Factor is required to calculate the Temperature Difference Factor, but its value is reduced by raising it to the power of {fraction (2/7)} during this calculation. The Temperature Difference Factor is very important for these calculations because it relates the ability of the fluid to transfer heat to the cost of pumping the fluid through the loop. Since the pump power requirements are determined by the temperature difference factor raised to the {fraction (7/2)} power (see Equation 2), a small difference in the Temperature Difference Factor between two fluids can mean a large difference in pump power requirements.
To illustrate the magnitude of the shift in power requirements brought about by small differences in the Temperature Difference Factor, the Pump Power Ratio (Ep1/Ep2) was determined as a function of temperature in accordance with Equation 2 for Tyfoxit® 1.15, Tyfoxit® 1.21 (inhibited alkali ethanate solutions commercially available from Tyforop Chemie GmbH, Hamburg, Germany), an aqueous solution of 25% by weight ethyl alcohol, and an aqueous solution of 33% by weight of propylene glycol. The reference medium used was C4F9OCH3 as shown in FIG. 5. C3F7OCH3 as shown in FIG. 6, and C4F9OC2H5 as shown in FIG. 7.
As indicated in FIGS. 5-7, the Pump Power Ratio of all but one of the known heat transfer media surpasses unity at temperatures below about −10° C. Below about −20° C., the freezing point of Tyfoxit® 1.15, C4F9OCH3 stands alone. When evaluating the Pump Power Ratio, the compound C3F7OCH3 is especially effective as a secondary heat transfer medium.
Water mixed with a freezing point depressant tends to follow the same slope and curve function. Whether the depressant is alcohol, glycol, or salt, the slope and form of the curves tend to very similar. The ability of these fluids to transfer heat drops off rapidly as temperatures approach −20° C. The power required to circulate these water mixtures also climbs at a rapid pace, reducing the feasibility of the secondary heat transfer loop as an economic alternative to direct expansion systems. By contrast, C4F9OCH3 has excellent low temperature heat transfer abilities that result in a much reduced pump power requirement for circulation in a secondary system.
The fluorinated ethers C4F9OCH3, C4F9OC2H5, and c-C6F11OCH3 were tested for flash point by the standard method defined by ASTM D3278-89. Each compound was determined to have no flash point.
The environmental impact of several of the fluorinated ethers of the present invention was assessed by determination of the atmospheric lifetime (tsample) and the global warming potential (GWP) of certain compounds, as described in Examples 10-11 below.
The atmospheric lifetime (tsample) of various sample compounds was calculated by the technique described in Y. Tang, Atmospheric Fate of Various Fluorocarbons, M.S. Thesis, Massachusetts Institute of Technology (1993). According to this technique, an ultraviolet (UV) gas cell was charged with a sample compound, a reference compound (either CH4 or CH3Cl), ozone, and water vapor. Hydroxyl radicals were then generated by photolytic decomposition of the ozone in the presence of the water vapor and an inert buffer gas, i.e., helium. As the sample compounds and reference compounds reacted with the hydroxyl radicals in the gas phase, their concentrations were measured by Fourier transform infrared spectroscopy (FTIR). The rate constant for reaction of the sample compound (ksample) with hydroxyl radical was measured relative to the rate constant for a reference compound (kref), and the atmospheric lifetime was then calculated using the following formula (where tCH4 and kCH4 are known values):
The rate constant for each sample compound was measured (using CH4 as the reference compound and again using CH3Cl) at 298K, and the atmospheric lifetime values were calculated and then averaged. The results of these measurements are shown in Table 5. For comparison, the atmospheric lifetime for several hydrofluorocarbons is also shown in Table 5.
Atmospheric lifetime was also estimated from a correlation developed between the highest occupied molecular orbital (HOMO) energy and the known atmospheric lifetimes of hydrofluorocarbons and hydrofluorocarbon ethers, in a manner similar to that described by Cooper et al. in Atmos. Environ. 26A, 7, 1331 (1992). The correlation differed from that found in Cooper et al. in the following respects: the correlation was developed using a larger data set; lifetimes for the correlations were determined by relative hydroxyl reactivity of the sample to CH3CCl3 at 277K, as described by Zhang et al. in J. Phys. Chem. 98(16), 4312 (1994); HOMO energy was calculated using MOPAC/PM3, a semi-empirical molecular orbital package; and the number of hydrogen atoms present in the sample was included in the correlation. The results are reported in Table 5.
Global warming potential (GWP) was determined for some of the heat transfer media of the present invention using the values for atmospheric lifetime calculated in Example 7 and experimentally determined infrared absorbance data integrated over the spectral region of interest, typically 500 to 2500 cm−1. The calculations were based on the definition of GWP set forth by the Intergovernmental Panel in Climate Change in Climate Change: The IPCC Scientific Assessment, Cambridge University Press (1990). According to the Panel, GWP is the integrated potential warming due to the release of 1 kilogram of sample compound relative to the warming due to 1 kilogram of CO2 over a specified integration time horizon (ITH) using the following equation:
where DT is the calculated change in temperature at the earth's surface due to the presence of a particular compound in the atmosphere [calculated using a spreadsheet model (using parameters described by Fisher et al. in Nature 344, 513 (1990)) derived from Atmospheric and Environmental Research, Inc.'s more complete one-dimensional radiative-convective model (described by Wang et al. in J. Atmos. Sci. 38, 1167 (1981) and J. Geophys. Res. 90, 12971 (1985)], C is the atmospheric concentration of the compound, t is the atmospheric lifetime of the compound (the calculated value described above), and x designates the compound of interest. Upon integration, the formula is as follows:
wherein A1=0.30036, A2=0.34278, A2=0.35686, t1=6.993, t2=71.108, and t3=815.73 in the Siegenthaler (1983) coupled ocean-atmosphere CO2 model. The results of these calculations are set forth in Table 5.
As indicated by the data in Table 5, each of the fluorinated ethers of the present invention has an unexpectedly lower atmospheric lifetime than the corresponding hydrofluorocarbon, i.e., the hydrofluorocarbon having the same carbon number. The fluorinated ethers of the present invention are thus more environmentally acceptable than the hydrofluorocarbons (which have previously been proposed as chlorofluorocarbon replacements).
The physical properties of C4F9OCH3, determined in accordance with the above described methods, are set forth in Table 6.
Thermal Transport Properties of C4F9OCH3
Environmental Properties of C4F9OCH3
The following example illustrates the effectiveness of hydrofluoroethers over other refrigerants in secondary refrigeration systems.
A secondary refrigeration systemw as needed for large events at stadiums and arenas. In order to meet customer demands, the system has to be capable of chilling several cases of plastic bottles of soda from room temperature (85° F.) to serving temperature (34° F.) in less than 15 minutes. The proposed system was rejected as being unfeasible by several refrigeration companies in the U.S. and in Europe.
In one design proposed by a refrigeration manufacturer, a traditional refrigeration system was used to cool a large reservoir of liquid. The chilled liquid was then pumped from the reservoir to a coil in a blast cooler. Air in the cooler was then circulated at high velocity to remove thermal energy from the bottles and transfer it to the cooled coil. In this design, the large reservoir of liquid served as a "thermal flywheel" capable of absorbing a large amount of energy. Upon completion of the blast cycle, the thermal energy is removed from the reservoir at a lower rate with the refrigeration system to prepare for another cycle.
An initial test was performed using a propylene glycol/water mixture (a common secondary refrigerant) in this system. Using the propylene glycol mixture, it took 75 minutes to achieve the required drop in temperature from 85° F. to 34° F., well above the 15 minute period specified.
A second test was performed which was identical to the initial test, except that C4F9OCH3 was substituted for the propylene glycol/water mixture. This time, the system required only 12 minutes to achieve the required temperature drop.
The above description is intended to be illustrative of the present invention, and is not intended to be limiting. Therefore, the scope of the invention should be construed solely by reference to the appended claims.
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Curb the Chaos
This Five-Session Course with Dorothy Breininger that gives you the tools you will need to find out your clutter factor and how the clutter in your life is preventing you from living the life you were meant to live.
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4/1/14 - 12/31/20
Join Michelle Buchanan for this Online Event and learn how Numerology can assist you in making 2014 the best year it can be.
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4/24/14 - 12/31/20
In order for you to connect with the Angelic realm you need to clear your energy and raise your vibration. In this interactive online course, Angel Communicator, Kyle Gray will lead you to the Archangels where you can connect with their presence and protection.
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If you're a parent or have ever transported babies in the car, you know how frustrating it is to have to hold the baby, keep him/her happy, and move the carseat straps out of the way so you can keep the baby happy without having the carseat buckles jab them in the back or have to dig around under them to find the carseat straps and buckles. I'm so glad that the Short Stack Jack team invented hte Carseat Sidekick! This little contraption is safe and easy to use.
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[youtube_sc url="http://www.youtube.com/watch?v=TDW0LYAJpvI" title="carseat%20sidekick"]
You can purchase a Carseat Sidekick at ShortstackJack.com for $17.99. The Carseat Sidekick comes in Boy (blue and green, as shown,) Girl (pink,) or Neutral (orange.) Connect with the Carseat Sidekick company on Facebook.
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I highly recommend this motel. The best feature of it, is that it isn't on the main street like the other motels. Its on a side street which makes it very quiet. The room was clean and well kept. The owner was very pleasant and made you feel welcome.
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"Fuck You Mean?" is the latest collaboration from Meek Mill and Lil Boosie, and will appear on Mill's upcoming album Dreams Worth More Than Money. But despite the new music and the tweet that announced it, Meek Mill is still behind bars, after being sentenced for three to six months back in July. I'm always very impressed when rappers release new… Read more
Rick Ross ft. Jay-Z – Movin Bass
Rick Ross released a new track off his second album of 2014, Hood Billionaire. The single features a hook from Jay Z and production by Timbaland. "Movin Bass" talks about the constant hustle of moving weight, a phrase Ross knows in a new way since he's started CrossFit, (which he calls "RossFit") back in May. The… Read more
Mark Ronson ft. Bruno Mars – Uptown Funk
Grammy winning producer Mark Ronson recently released his first single, "Uptown Funk" from his upcoming album, Uptown Special, out January 27th. The track was co-written and co-produced by Bruno Mars, who also worked with Ronson on 2012's hits, "Locked Out Of Heaven" and "Gorilla." Uptown Special, Ronson's fourth studio album, will feature musical contributions from Tame Impala's Kevin Parker,… Read more
R3hab & NERVO ft. Ayah Marar – Ready For The Weekend
On R3hab & NERVO's latest banger, Ayah Marar sings, "If you're ready for the weekend, You gotta let yourself go," which I would argue is not the best way to prepare yourself for the weekend. Monday through Friday you gotta eat right and work out if you wanna be able to pick up dudes on the weekend,… Read more
Selena Gomez – The Heart Wants What It Wants
In her latest single, "The Heart Wants What It Wants," Selena Gomez draws inspiration from her highly publicized relationship troubles. The new track is off her upcoming For You compilation album. The singer has had a rocky year, which started with a stint in rehab, but she's feeling more powerful lately, telling Seventeen magazine, "I questioned the way I looked, acted,… Read more
Kendrick Lamar – i
"i" is Kendrick Lamar's first single off his forthcoming third studio album. The feel-good single finds Lamar rapping about loving yourself over a sample of the Isley Brothers' "That Lady." In a recent interview with Fader, Kendrick Lamar "covered" Taylor Swift's "Shake it Off," gushing that he "loves that song." This shout-out was given in return… Read more
Run The Jewels ft. Zack de la Rocha – Close Your Eyes (And Count To Fuck)
Hip hop duo Killer Mike and El-P, collectively known as Run the Jewels, released "Close Your Eyes" as their third single off their latest album, Run The Jewels 2. The track features former Rage Against the Machine frontman Zack de la Rocha, who works overtime providing a rap verse as well as vocals for the song's looping production. The… Read more
Dillon Francis ft. Twista & The Rejectz – All That
"All That" is my personal fave from Dillon Francis's debut album, Money Sucks, Friends Rule. Enjoy it below. However, I would like to take this opportunity to point out another track off the same album: "Not Butter" is a festival-ready song that extols the versatility of "I Can't Believe It's Not Butter!®" a "food," which, Francis… Read more
Dirty South ft. Sam Martin – Unbreakable
This song is infinitely better if you change the chorus to "Where we're going? We don't know, Like tomatoes, we will grow." What's sexier than song about gardening? "Unbreakable" is the lead single from Dirty South's upcoming sophomore album, With You, out November 4.
Nicki Minaj ft. Drake, Lil Wayne & Chris Brown – Only
"Only" is Nicki Minaj's third single from her upcoming Pinkprint album, which has been delayed again, from November 24, to December 15. The new song features verses from Drake & Lil Wayne, Chris Brown on the hook, and production from by Dr. Luke, Cirkut, and J Mike. Throughout "Only" each rapper makes it abundantly clear that none… Read more


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Summer in Brewster Arts and Craft Festival
Sat, Jul 26 - Sun, Jul 27, 2014
Times: Saturday 10-5 / Sunday 10-4
Venue: Drummer Boy Park
799 Main Street, Brewster, MA 02631Contact:
Terry Mullen
1 people saved this
The Brewster Summer Arts and Craft Festival will be held at Drummer Boy Park on Route 6A, in Brewster, MA on July 26 & 27, 2014.
Over 75 Juried Craftsmen and women will display and sell their American made works including Fine Jewelry, Original Watercolors, Fleece, Embroidery, Steam Punk Accessories, Fiber Arts, Blown Glass, Quilting, Oil Paintings, Wearable Art, Shell Craft, Ceramics, Tile,
Fine Art Photography, Scarves, Painted Antiques, Wall Hangings, Hats, Stained Glass, Soap, Folk Art, Custom Signs, Pet Gifts, Turned Wood, Sea Salt Scrubs, Floral Design, Flags, Bears, Basketry, Pottery, Herbal Dips, Gourmet Cookies, Jams, Jellies and much more.
Specialty food sampling, craft demonstrations and live musical entertainment complete this perfect summertime event.
Festival Hours Saturday from 10am to 5pm, Sunday from 10am to 4pm.
Directions: From Route 6 take Exit 9B onto Route 134, to, follow to Route 6A.
Free Admission, free parking and held rain or shine.
For more information call 603-332-2616 or visit www.castleberryfairs.com
5 Creative Ways to Celebrate Thanksgiving in Massachusetts
The clocks are pushed back. There's a chill in the air. And eyes are...
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Property to rent in Llanbrynmair
£375 pcm (£87 pw)
2 bed end terrace house to rentBrynmair, Dolfach, Llanbrynmair, Powys SY19
Traditional 2 Bedroom End Terraced Village Cottage. 1 mile from Llanbrynmair. Manageable garden. Oil fired central heating. UPVC double glazing. Sitting Room, Kitchen/Dining Room, 2 Bedrooms, Bathroom. No DSS. No cats, dogs considered. Non smokers. ... More details
Note: Distances are straight line measurements
- Caersws (9.3 miles)
- Machynlleth (10.6 miles)
Marketed by Morris Marshall & Poole, SY16. Call 01686 639059
Latest Llanbrynmair property to rent
Zoopla is one of the UK's leading property portals, helping you to find property for sale and to rent and make smarter decisions when buying and renting homes in the UK. Discover information on homes in Llanbrynmair by researching Llanbrynmair property values, Llanbrynmair house prices paid, our Llanbrynmair property market overview and find Llanbrynmair agents.