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organic farming jobsSubscribe to RSS Feed
|Job Title
Featured Job Postings from the Web
|Nov 22
|Crew Leader
|Cure Organic Farm
|Boulder, CO
Job DescriptionCure Organic Farm is seeking a Crew Leader beginning in February 2014. The ... experience of 2 full season in commercial organic vegetable production as well as... more
|Nov 22
|Cure Organic Farm
|Boulder, CO
Job DescriptionAt Cure Organic Farm, interns are involved in all aspects of the farm and work closely with the farmers. Interns will learn to use the tractors and equipment,... more
|Nov 20
|Hawaii organic farm & restaurant team members needed
|Beyond Organic Consulting
|Hawi, HI
in the recently published book, Beyond Organic...Growing for Maximum Nutrition ... at janabogs.com). We need an experienced organic farm manager who has successfully run... more
|Nov 19
|Red Dog Farm Assistant Crew Manager
|Red Dog Farm
|Chimacum, WA
on market vegetable farm. Familiarity with organic production systems.Knowledge, Skills ... many other aspects of diversified vegetable farming, including but not limited to... more
|Nov 09
|Organic Farm Worker
|Brothers Farm
|Hemet, CA
I need one experienced organic farm worker for my 9 acres new organic farm. The worker must can operate tractor, install irrigation parts, responsible and honest. I will provide... more
|Nov 09
|DeLano Farms CSA Crew
|Kalamazoo Nature Center
|Kalamazoo, MI
and Skills Required:? Knowledge of organic or ecological vegetable production? Strong work ethic? Ability to work quickly, multi-task and be flexible on a daily basis? Ability to... more
|Nov 08
|organic worker
|David Renck
|La Belle, MO
Seeking person or couple to help start & run organic farm from ground up, some knowledge in vegetable gardening, organics, fruit trees, and existing small orchard. Pay amount... more
|Nov 08
|Food Production Shift Lead - Plant Based - Organic
|Project Juice
|South San Francisco, CA
Food Production Shift Lead Rapidly expanding organic juice company based in South San Francisco is hiring a food production lead to manage its production of grab 'n go meals for... more
|Nov 07
|Farm and Flower Intern
|Talmar Gardens and Horticultural Therapy Center
|Parkville, MD
Learn about organic gardening with vegetables and flowers. Our nonprofit works with all ages and disabilities to promote recreational, physical and mental health. We are looking... more
|Nov 06
|Organic Research Farm Manager
|Clements Agricultural Research Institute
|Morristown, NY
Organic Garden and Crop farm, with B&B and Organic Restaurant owned by CARI.org located ... and experience to plan, direct and train Organic farmers to produce and market to... more
|Nov 05
|Organic Farm Horticulture Team Member
|Featherstone Farm
|Rushford, MN
or more qualified individuals to join its organic vegetable horticulture team. This is ... working directly with field production of organic vegetables. Academic background in... more
|Nov 04
|Live in farm work on small orchard, produce, goat dairy
|Kauai Kunana Dairy
|Kilauea, HI
acres of fruit orchards, 1 acre of intensive organic vegetables, and various value added production lines. Part of the compensation is a living space in a small, modest cottage... more
|Oct 30
|Retail Associates & Smoothie Baristas - PROJECT JUICE - Local, Organic Cold Pressed
|Project Juice
|San Francisco, CA
about us here - www.projectjuice.com We use organic and local ingredients and scratch make everything at our certified organic production kitchen in South San Francisco. We are... more
|Oct 28
|Organic Farm & Garden Manager
|Clements Agricultural Research Institute
|Lisbon, NY
Manager of all agricultural operations, including commercial gardens, field crops, poultry and as we add animals, sheep and lamb, pigs and beef all grass fed: includes planning of... more
|Oct 08
|Lean Six Sigma Black Belt
|Organic Valley/cropp Cooperative
|La Farge, WI
You probably know Organic Valley Family of Farms as a trusted source of delicious and ... will be able to continue the tradition of organic farming into the next generation. more
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|Nov 26
|Nanny/Mother's Helper Needed For 1 Child Organic Farm Lifestyle
|Carpinteria, CA
and caring relationship. We live on a large organic ranch and there will be lots of ... ethic and emotional bond is established. Organic food and farm surplus can work as a... more
|Nov 17
|Organic Vegetable Farm Manager
|Crown Point Ecology Center
|Bath, OH
with CSA/diversified vegetable farming Experience with basic organic farming ... philosophy, methods and tasks of organic farming. Multi-tasks, delegates jobs and... more
|Nov 05
|Outside Sales Rep - Organic Farm
|Farm Fresh To You
|Anaheim, CA
our sales Team in Orange County. We are an Organic Farm that delivers to the home. If you want to "Change Peoples Lives one Box at A Time" by helping people eat better...and also... more
|Oct 09
|Organic Culinary Farm Looking for Interns
|Three Sisters Farm
|Homestead, FL
future employment. Three Sisters Farm is an organic (very soon to be certified) culinary ... Interns will learn natural farming/planting techniques and have an opportunity to observe... more
|Oct 06
|4 Graduate Research Assistantships - Organic Cropping Systems
|Pennsylvania State University
|University Park, PA
reduced-tillage production constraints in organic grain systems in the Mid-Atlantic ... in cover crop based, reduced-tillage organic grain systems. Integration among student... more
|Sep 29
|Organic Certification Director
|Northeast Organic Farming Association of New York
|Binghamton, NY
to local organic a NOFA-NY Certified Organic, LLC, a USDA-accredited organic ... Some experience working in organic certification or with a certified organic farming... more
|Sep 04
|Perdue Farms
|Milford, DE
*Description/Job Summary* This position is responsible for ensuring all organic product is ... organic production in Milford. Maintain all organic poultry in channel. 2. Coordinate... more
|Sep 01
|Sous Chef for a Farm-to-Fork Restaurant
|Tender Greens, A Farm To Fork Restaurant
|San Francisco, CA
that uses ingredients that are organic and fresh, who has experience with kitchen leadership, solid technique, is driven to learn and mentor, and has ambition to grow as a chef... more
|Aug 02
|Future Opportunities Organic Farm Farmhand
|Canandaigua, NY
Title: Future Opportunities Organic Farm Farmhand Location: NY-Canandaigua-CANANDAIGUA,345 ... job: As a Seasonal Support Employee at the Organic Research Farm, you will work closely... more
|May 09
|Organic Category Manager
ID:J0914-0190 Job Type:Permanent Full Time Organic Category Manager Summary: Organic ... the Organic category including; sourcing of organic milk and cheese, organic milk... more
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Displaying all posts for News
Guest Artists, Ben Verdery and Eliot Fisk to perform tonight!
by Kris Frantz September 23, 2014
Opening Event: Seis Miradas por latinoamérica – Homage to Pablo Neruda, tonight at 5PM!
by Kris Frantz September 22, 2014
Hear WFDD Radio interview Professor Borwick…
by Kris Frantz August 12, 2014
Scroll down to her interview after clicking link: http://wfdd.org/programs/radio-camp?page=5
The Passing of a Beloved Friend, Mentor, Colleague – Lucille Sawyer Harris
by Kris Frantz August 7, 2014
We received the sad news that Lucille Harris, Instructor Emerita of Music, passed away at Salemtowne Retirement Community on 2 August 2014. Lucille taught piano at Wake Forest from 1957 to 1991. The Department's annual Giles-Harris Competitions in Music Performance honor her many years of service to the Read more »
ASOP receives rave review for opening night — Mozart's The Magic Flute —
by Kris Frantz June 13, 2014
Review of opening night, Mozart's The Magic Flute: http://cvnc.org/article.cfm?articleId=6879

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Cache Creek, Canada
1209 Highway 97, V0K1H0 Cache Creek, Canada – Show map
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9 properties in Cache Creek
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Cache Creek Inn's staff speaks: English, German
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Outdoor Pool (seasonal)
Fitness Center, Game Room
Food & Drink
WiFi is available in all areas and is free of charge.
Free public parking is available on site (reservation is not needed).
Vending Machine (drinks), 24-Hour Front Desk, Baggage Storage, Souvenir/Gift Shop
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All older children or adults are charged CAD 10 per person per night when using existing beds.
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Featuring a restaurant with a private dining room, this motel is located 2 kilometers from Semlin Valley Golf Course. Free Wi-Fi access is available.
Score from 80 reviews Good
Canada's Best Value Desert Inn & SuitesJust 13 km from Historic Hat Creek Ranch, this Cache Creek motel features a seasonal heated outdoor pool. Free Wi-Fi is included in all guest rooms. Ashcroft Museum is 15 minutes' drive away.
Score from 50 reviews Good
Located on Highway 97, this Cache Creek motel provides free Wi-Fi and a refrigerator in rooms. A seasonal outdoor heated pool and a garden with BBQ facilities are offered. Kamloops is 84 km away.
Score from 105 reviews Good
Featuring an on-site restaurant and pub, this Cache Creek Hotel provides free Wi-Fi. A cold beer and wine store and a fitness centre are also offered. The Historic Hat Creek Ranch is 12 km away.
Score from 38 reviews Review score
Place was not cleaned properly and there was some type of bug in our bed scratched all night. Advertised as just renovated failed to see the renovations that took place. Wondering where the ratings for this place came from.The carpets might of been changed but that was it.
Subway Breakfeast in the morning
there is nothing to do at Cache Creek
Green stains on bath
Location was good, breakfast voucher to subway next door ok, although they had major fruit flies.
Needs major cleaning, very dusty, major vacuuming and under the beds. My room was dark, 3 light bulbs were out, light shade can easily catch on fire as they were all cracked from heat of lights, no fire sprinklers, the bathroom taps leaks, the shower head is corroded, back door curtains honestly pathetic and hung poorly. No safety locks. Sheets & blankets should be replaced as they are in poor, poor condition. The outside also needs lots of tlc. Office, should be more attending and cleaned as well.
It was clean, nice to have a fridge and coffee pot.
The beds were not that comfortable and the linen was well worn.
The room, while clean was quite dated looking. The facilities were run by seemingly only one person, and she was busy between a subway restaurant, and the motel. The towels were ratty, there was no place to hang clothing in the room, the hairdryer was almost useless, and there was no anti slip mat in the shower. Even though the price was quite reasonable, we still didn't feel that it was good value at that price.
Free breakfast coupon. Receptionist employee very friendly. Pool was clean. Motel next door to Subway which was convenient.
Room door hard to open. Sheets clean but paper thin.Blanket had no warmth.Continuous "squeaking" from ceiling above. Very loud.Renos are Band-Aid solutions. Styrafoam glasses?
Friendly staff Subway on-site for breakfast
Everthing, except location.
After a hot day of travel, the pool was refreshing and clean.
The air conditioner was very noisy.
needed a little work !!
location. price clean room
room was rundown. property has a small pool, but no deck chairs. noisy air conditioner. bed rock hard
-the convenience of the location -no sign of bedbugs -breakfast was good
-wall was torn apart in bathroom -floor was sloping -bed was hard as a rock but slept well as had spent day walking in the bush geocaching -little flat pillows need improving
Was not very clean. The sheets felt awful.
not clean, couldn't look front door, kitchen functionally but not clean, smell from a restaurant in all rooms,
Very little
The room was not tidy. A gap between the door frame and the outside elements was very apparent. Generally this is a facility we would never go back to due to its unclean, untidy and poor condition
subway sandwich and coffee for breakfast.
Lack of quality, no toilet paper on huge commercial roll holder. Inadequate locks, had no safety chain lock, had to put chair to keep feeling fairly safe.
Quiet, beds were comfortable.
Needs air conditioner repair, needs door handle/lock replacement and just a general overhaul.
Room was clean
Very noisy air conditioner not fitted correctly, "renovations" cheaply undertaken.
pool was clean and refreshing staff very cooperative and receptive
fridge didn't work AC was very noisy Windows don't open, had to leave doors open to get fresh air. Had to change rooms, first one smelled of smokers and air freshener.
Place was very dirty , dirt on heat register as you walk not just dust looked like someone had spilled pop on it and was dry been there a long time. Tube and shower , tube had hole just at seam meets dry wall been there a long time had mold around it. Also there was a used bar of soap on top ledge of shower was there when checked in and still there when left two days probably still there. Would not recommend not worth what I paid.
It had a decent TVso we could watch the world cup , bed was comfortable
The whole place was run down, needed a good wash, dodgy stairs, unloved, the town was the same.
The house keeping was very poor;every day I left the room I would put a tissue in the toilet and close the lid;at night I would come back and the tissue was still in the toilet which means my toilet was never cleaned for a week.Some days they would forget to put face cloths in my room.The towels were so thin that you could see through them.I don't think that they have a check list for the house keeping staff.
Old and decrepit.
Room was run down, washroom was filthy, beds were old and hard, AC was loud; overall it's a run down dirty motel.
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1. A process for hydroformylating an olefin having from 3 to 16 carbon atoms, in the presence of a rhodium catalyst, wherein the rhodium catalyst comprises rhodium and at least one diphosphine ligand of formula
R=3,5-C6H3F2 ; �C 6F5; 2,4,5-C6H2F3, 3,5-C6H3(CF3)2; 3,5-C6H3(CH3)2 or 3,4,5-C6H2F3, and the n/i selectivity of the aldehydes obtained by said hydroformylating is above 85:15.
2. The process as claimed in
3. The process for hydroformylating an olefin as claimed in
4. The process as claimed in
This application is a DIV of 10/471,748 Sep. 25, 2003, which is a 371 of PCT/EP 02/02989 Mar. 19, 2002.
The present invention relates to an improved process for preparing diphosphines such as bis(diarylphosphinomethyl)arenes.
Phosphines have many applications in industry. They have industrial importance as antioxidants, metal extractants, flame retardant impregnants, stabilizers for olefins, starting materials for Wittig reagents and, in particular, as ligands for transition metal catalysts.
A review of the important homogeneous catalysts containing phosphine ligands may be found, for example, in B. Cornils, W. A. Herrmann, Applied Homogeneous Catalysis with Organometallic Compounds Vol. 1 & 2, VCH, Weinheim, 1996. Within the group of phosphines, chelating phosphines, in particular diphosphines, are of particular importance as ligands for metal complexes. This is due to the fact that diphosphines form more stable complexes with the appropriate central metal atom and therefore have a more lasting influence on its catalytic properties. Among the known chelating diphosphines, bis(diarylphosphinoalkyl)-1,1′-binaphthyls as constituents of carbonylation catalysts and telomerization catalysts are of industrial interest. EP 0 653 432, EP 0 673 944 and JP 7939059 describe the preparation of bis(diarylphosphinoalkyl)-1,1′-binaphthyls by reaction of 2,2′-dimethylbinaphthyls with a brominating agent to form 2,2′-bis(bromomethyl)-1,1′-binaphthyl, subsequent reaction with an alkyl diphenylphosphinite and subsequent reduction of the bisphosphine oxide formed by means of an organodichlorosilane. This process has a number of fundamental disadvantages: to introduce the phosphorus groups into the target molecules, the latter firstly have to be brominated, and the bromine atoms are then replaced by phosphorus groups. This requires the use of expensive and toxic bromination reagents and results in the formation of superstoichiometric amounts of bromide waste. The bromination of the starting compounds generally leads to product mixtures whose handling is problematical since the arylalkyl bromides formed are lacrymatory substances which are hazardous to health. In addition, the reaction with alkyl diphenylphosphinites leads to the phosphine oxide which has to be reduced in a further step. Starting out from 2,2′-dimethylbinaphthyls, 4 steps are thus necessary to obtain the desired ligands.
Similar syntheses or partial syntheses having the same and sometimes further disadvantages are also described in the literature (M. E. Jung et al., Tetrahedron Lett. 1988, 29, 6199; H. J. Bestmann et al., Chem. Ber. 1974, 2926; T. Hayashi et al., J. Am. Chem. Soc. 1988, 110, 8153).
In EP 0 704 449, unsymmetrically substituted bis(diarylphosphinoalkyl)-1,1′-binaphthyls are prepared from 2,2′-bis(bromomethyl)-1,1′-binaphthyl via corresponding phosphonium salts. This process has the abovementioned disadvantages and is not advantageous for the preparation of symmetrical bis(diarylphosphinoalkyl)-1,1′-binaphthyls since the phosphorus groups have to be introduced into the target molecule in two steps and large amounts of salt waste are formed.
For the above reasons, there is a need to develop a new process for preparing bis(diarylphosphinoalkyl)-1,1′-binaphthyls which does not have the abovementioned disadvantages, can be carried out simply and safely and makes it possible to obtain the desired product in a high yield and purity.
This object is achieved by a process for preparing diphosphines of the formula I
The process of the invention is of particular interest since the routes described in the past for obtaining the ligands of the formula I were always via benzyl halide intermediates. The process of the invention enables diphosphines to be obtained in good yields and high purities directly from the compounds of the formula II.
Bases which can be used for the reaction of compounds of the formula II in process step a) are any bases which can deprotonate benzylic CH3 groups. Typical examples of such bases are alkyllithium and aryllithium compounds such as butyllithium and methyllithium, alkali metal hydrides or alkaline earth metal hydrides such as sodium hydride and potassium hydride, alkali metals or alkaline earth metals such as sodium or potassium in liquid ammonia, and also alkali metal or alkaline earth metal hydroxides or alkali metal or alkaline earth metal alkoxides, for example potassium tert-butoxide.
The process of the invention for preparing diphosphines can be illustrated by way of example by the following reaction scheme for the synthesis of 2,2′-bis(diarylphosphinomethyl)-1,1′-binaphthyls:
As N-substituted aminophosphorus halides in process step a), it is possible to use alkylaminophosphorus or arylaminophosphorus chlorides, bromides or iodides, where alkyl is a hydrocarbon radical selected from the group consisting of methyl, ethyl, propyl, isopropyl, butyl, isobutyl, hexyl, 2-ethylhexyl, octyl, isooctyl, nonyl or isononyl radicals and/or these radicals can have a covalent bond between them and/or alkylamino is an aliphatic heterocyclic radical having from one to 6 carbon atoms and/or aryl is an aromatic radical having from one to 14 carbon atoms, where these radicals may bear up to seven substituents selected from the group consisting of (C1-C8)-alkyl, O-alkyl-(C1-C8), O-phenyl, phenyl, fluorine, chlorine, CN, COOH, CHO, SO3H, SO2-alkyl-(C1-C6), SO-alkyl-(C1-C6), CF3, COO-alkyl-(C1-C8), COO-phenyl, PO-phenyl2, PO-alkyl2(C1-C4), PO3H2, PO(O-alkyl-(C1-C6))2, SO3-alkyl-(C1-C4).
An alkylamino radical can be an aliphatic heterocyclic radical such as piperidine or pyrrole and/or an aryl radical can be an aromatic radical such as phenyl, naphthyl or benzyl. Preference is given to using bis(dialkylamino)phosphorous chlorides. For all compounds, the N�P bond has to be able to be cleaved by means of acid.
More Detailed Description of the Formula I
The radicals R1 and R2 can be identical or different and can be aromatics having up to 14 carbon atoms and be able to bear up to eight substituents selected from the group consisting of (C1-C8)-alkyl, O-alkyl-(C1-C8), O-phenyl, phenyl, fluorine, chlorine, CN, COOH, CHO, SO3H, SO2-alkyl-(C1-C6), SO-alkyl-(C1-C6), CF3, COO-alkyl-(C1-C8), COO-phenyl, PO-phenyl2, PO-alkyl2-(C1-C4), PO3H2, PO�(O-alkyl-(C1-C6))2, SO3-alkyl-(C1-C4).
Furthermore, the radicals R1 and R2 can be identical or different and be heteroaromatics having a five-, six- or seven-membered ring and nitrogen, oxygen or sulfur atoms in the ring, where further aromatic, heteroaromatic and/or aliphatic rings may be fused onto the ring and the rings may bear up to seven substituents selected from the group consisting of (C1-C8)-alkyl, O-alkyl-(C1-C8), O-phenyl, phenyl, fluorine, chlorine, CN, COOH, CHO, SO3H, SO3-alkyl-(C1-C6), SO-alkyl-(C1-C6), CF3, COO-alkyl-(C1-C8), COO-phenyl, PO-phenyl2, PO-alkyl2-(C1-C4), PO3H2, PO�(O-alkyl-(C1-C6))2, SO3-alkyl-(C1-C4).
In addition, the hydrocarbon radicals R1 and R2 can be identical or different and be cyclic or acyclic alkyl radicals which contain up to 10 carbon atoms and may bear up to seven substituents selected from the group consisting of (C1-C8)-alkyl, O-alkyl-(C1-C8), O-phenyl, phenyl, fluorine, chlorine, CN, COOH, CHO, SO3H, SO2-alkyl-(C1-C6), SO-alkyl-(C1-C6), CF3, COO-alkyl-(C1-C8), COO-phenyl, PO-phenyl2, PO-alkyl2-(C1-C4), PO3H2, PO�(O-alkyl-(C1-C6))2, SO3-alkyl-(C1-C4).
In these cases, the radicals R1 and R2 can also be joined by one or more covalent bonds and thus form, for example, a biphenyl, naphthyl or other cyclic system.
Ar can be a phenyl, naphthyl, anthracenyl or phenanthrenyl radical, a 1,1′-biphenyl unit or a 1,1′-binaphthyl unit, which may each bear up to eight further substituents selected from the group consisting of (C1-C8)-alkyl, O-alkyl-(C1-C8), O-phenyl, phenyl, fluorine, chlorine, CN, COOH, CHO, SO3H, SO2-alkyl-(C1-C6), SO-alkyl-(C1-C6), CF3, COO-alkyl-(C1-C8), COO-phenyl, PO-phenyl2, PO-alkyl2-(C1-C4), PO3H2, PO�(O-alkyl-(C1-C6))2, SO3-alkyl-(C1-C4) or one or more fused-on benzene rings.
As an alternative, Ar can be a heteroaromatic comprising a five-, six- or seven-membered ring having nitrogen, oxygen or sulfur atoms in the ring, where further aromatic, heteroaromatic and/or aliphatic rings may be fused onto the ring and the rings may bear up to six substituents selected from the group consisting of (C1-C8)-alkyl, O-alkyl-(C1-C8), O-phenyl, phenyl, fluorine, chlorine, CN, COOH, CHO, SO3H, SO2-alkyl-(C1-C6), SO-alkyl-(C1-C6), CF3, COO-alkyl-(C1-C8), COO-phenyl, PO-phenyl2, PO-alkyl2-(C1-C4), PO3H2, PO�(O-alkyl-(C1-C6))2, SO3-alkyl-(C1-C4).
Organometallic reagents used for converting compounds of the formula IV into the target compounds of the formula I in process step c) are transition metal arenes or aliphatic or aromatic alkali metal or alkaline earth metal compounds. Preference is given to using aliphatic or aromatic Grignard reagents, alkylzinc or arylzinc reagents, alkyllithium or aryllithium reagents and/or arylcopper compounds. The organometallic reagents are generally prepared separately prior to the reaction, but they can also be prepared in situ in the reaction.
Solvents used in the individual process steps a), b) and c) of the process of the invention are inert organic solvents. Without making any claim as to completeness, examples which may be mentioned are polar aprotic solvents, aliphatic ethers, aromatic or aliphatic hydrocarbons, aromatic and aliphatic halogenated hydrocarbons, alcohols, esters, amides and mixtures thereof. Naturally, the solvents must not undergo any chemical reactions with the reactants.
The process steps a), b) and c) are preferably carried out at temperatures of from −80 to 200� C.; in most cases, it has been found to be useful to employ temperatures of from −30 to 180� C., particularly preferably from −20 to 160� C.
The particular advantage of the process of the invention is that no toxic benzyl and alkyl bromides are prepared and that no reduction of phosphine oxides has to be carried out.
Owing to the stability of the intermediates of the formulae III and IV, it is possible to purify these intermediates by simple crystallization so that complicated purification methods such as chromatography are not necessary. The compounds of the intermediate IV has made it possible for many new ligands which are of interest in catalysis to be obtained in a simple manner. For producing a ligand library of the ligands prepared according to the invention, the process of the invention is considerably more convenient than previously known processes.
The diphosphines prepared according to the invention can be used as ligands in metal-catalyzed reactions, in particular hydroformylations of olefins in the presence of rhodium catalysts. Preferred olefins are octenes and butenes, in particular those having high degrees of branching and/or internal double bonds.
The use of diphosphines as ligands in hydroformylation reactions is known. Thus, U.S. Pat. No. 4,694,109 describes diphosphine ligands having a BISBI structure which are used, inter alia, in the hydroformylation of olefins having internal double bonds without discussing the selectivity to the product and the activity of the catalyst.
In Angew. Chem. Int. Ed. 1999, 38, 336-338, L. A. van der Veen, P. C. J. Kamer and P. W. N. M. van Leeuwen report modified XANTPHOS ligands which convert 2-octene into n-nonanal at an n/i ratio of 9:1 and a turnover frequency (=TOF) of 112 h−1. The TOF is defined as the ratio of mole of aldehyde to mole of rhodium per h after a 20-30% conversion.
EP 0 653 432 describes the preparation of diphosphines analogous to NAPHOS, some of which contain fluorine-containing substituents. These ligands can be used in the hydroformylation of olefins. Here too, nothing is said about the selectivity and activity of the catalyst.
The ligands prepared according to the invention, in particular the fluorine-containing ligands analogous to NAPHOS, in metal complexes are surprisingly highly selective and active catalysts which display the highest activity known hitherto in the selective hydroformylation of olefins having internal double bonds to form the terminal aldehydes. Table 1 in the examples gives an overview.
The invention likewise provides a process for the hydroformylation of olefins having from 3 to 16 carbon atoms in the presence of rhodium catalysts, wherein the ligands used for the rhodium are diphosphines of the formula
Furthermore, turnover frequencies (TOFs), i.e. activities, of more than 150, preferably more than 300, can be achieved in the process of the present invention using the specified ligands.
The hydroformylation can be carried out in a customary manner, for example as described in J. Falbe et al �New Syntheses with Carbon Monoxide�, Springer Verlag 1980, pages 93-123.
As olefins, preference is given to using those having internal double bonds, e.g. 2-butene, raffinate I or raffinate II, pentene and/or octene, in each case in isomerically pure form or as a mixture of isomers.
Raffinate I and raffinate II are C4 mixtures obtained by cracking and comprise mixtures of butanes, butenes and butadienes.
The following examples illustrate the process of the invention without restricting the process to them.
1. General Procedure for Preparing the Diphosphines:
Solvents: All solvents used are dried by known methods and distilled and stored under argon.
a) Preparation of 2,2′-bis[bis(diethylamino)phosphinomethyl]-1,1′-binaphthyl
The major part of the solvent is removed from 33.2 ml of n-BuLi solution (1.6 M in hexane, 53 mmol) under reduced pressure with gentle warming. After cooling in an ice bath, 25 ml of ether and 7.9 ml of tetramethylethylenediamine (53 mmol) are added. A solution of 5 g of 2,2′-dimethyl-1,1′-binaphthyl (17.7 mmol) in 30 ml of ether is slowly added dropwise while stirring and cooling. The reaction mixture is allowed to stand for 24 hours at room temperature and subsequently for a few hours at 0� C. The supernatant solution is decanted off and the precipitate obtained is washed twice with 25 ml each time of hexane.
The deep red precipitate is admixed with 50 ml of n-hexane and cooled to −70� C. A mixture of 7.5 ml of chlorobis(diethylamino)phosphine (35.4 mmol) and 25 ml of absolute n-hexane is added dropwise to the stirred suspension. After the mixture has been allowed to warm slowly to room temperature, it is stirred for another 12 hours. The solution is filtered and the precipitate is extracted twice with 50 ml of toluene. The combined filtrates are freed of solvents and of excess chlorobis(diethyl-amino)phosphine under reduced pressure (10−3 torr) with warming to 80� C. The residue comprises the target product in good purity and can be used without further purification for the further reactions, e.g. to form 2,2′-bis[(dichlorophosphino)methyl]-1,1′-binaphthyl.
M=514.59 g/mol.
31P-NMR (δ[ppm], C6D6): 88.4
1H-NMR (δ[ppm], J[Hz], C6D6): 0.45 t(=triplet), J=7 (6H); 0.55 t, J=7 (6H); 2.5 q (=quartet), J=7 (4H); 2.6 q, J=7 (4H); 2.85 d (=doublet), J=3 (4H); 6.7-7.0 m (=multiplet) (6H); 7.6 d, J=8 (2H); 7.7-7.8 m (4H).
b) Preparation of 2,2′-bis[(dichlorophosphino)methyl]-1,1′-binaphthyl
The 2,2′-bis[bis(diethylamino)phosphinomethyl]-1,1′-binaphthyl present in the residue from the reaction described under 1a) (see above) is taken up in 150 ml of hexane. While stirring and cooling in an ice bath, gaseous HCl is passed in until the mixture is saturated (about 1 h). The mixture is filtered and the residue is washed twice with 25 ml of hexane. The combined filtrates are evaporated to about 50 ml. At −30� C., 2.9 g of 2,2′-bis[(dichlorophosphino)methyl]-1,1′-binaphthyl crystallize out.
M=484.12 g/mol
Yield: 2.9 g (44% yield based on the 2,2′-dimethyl-1,1′-binaphthyl used in 1a))
31P-NMR (δ[ppm], J[Hz], CDCl3): 180.00
1H-NMR (δ[ppm], J[Hz], CDCl3): 3.4-3.6 m (4H); 7.0 d, J=8.5 (2H); 7.2 m (2H); 7.43 m (2H); 7.6 d, J=8.5 (2H); 7.86 d, J=8.3 (2H); 7.94 d, J=8.5 (2H)
13C-NMR (δ[ppm], J[Hz], CDCl3): 0.3 d, 1JPC=45.8 (P�CH2); 126.4 d, J=5.7; 126.5 d, J=6.7; 126.9 s; 128.1 s; 128.4 d, J=2.9; 129.0 s; 129.6 d, J=5; 133.0 d, J=16.2; 135.0 d, J=2; 135.6 s.
c) General Procedure for the Synthesis of Ligands of the Formula (I):
302 mg (12.4 mmol) of elemental magnesium are mixed with 10 ml of absolute diethyl ether under argon in a 100 ml three-necked flask provided with a magnetic stirrer. At room temperature, 12.4 mmol of the appropriately substituted bromine compound (dissolved in 10 ml of diethyl ether) are slowly (over a period of about one hour) added dropwise by means of a dropping funnel to this mixture. If the Grignard reaction does not start, a drop of 1,2-dibromoethane is added to the reaction solution. When the Grignard reaction is complete (complete reaction of the magnesium) after about 1 hour, this solution is transferred to a dropping funnel.
1.5 g (3.1 mmol) of 2,2′-bis[(dichlorophosphino)methyl]-1,1′-binaphthyl are dissolved in 25 ml of absolute THF under argon in a 150 ml three-necked flask.
At room temperature, the Grignard solution is slowly (over a period of half an hour) added dropwise to the solution of the 2,2′-bis[(dichloro-phosphino)methyl]-1,1′-binaphthyl.
The solution is subsequently heated to boiling and stirred for another two hours to complete the reaction. The solution is subsequently evaporated to dryness under argon on a rotary evaporator. The residue is dissolved in 50 ml of absolute and/or degassed toluene and admixed with 20 ml of degassed water. The mixture is stirred for half an hour. The aqueous phase is separated off and the organic phase is dried over sodium sulfate.
The sodium sulfate is subsequently filtered off, washed with 25 ml of toluene and the organic phase is evaporated to dryness under reduced pressure. The residue is recrystallized from acetone/EtOH, acetone/MeOH or toluene/hexane, or purified under argon by column chromatography on a 40 cm column (kieselguhr G 60) using absolute toluene as eluant.
The following ligands were prepared by the process of the invention.
2.) Examples of Ligands Prepared According to 1c):
a) 2,2′-Bis[bis(2,3,4,5,6-pentafluorophenyl)phosphinomethyl]-1,1′-binaphthyl
M=1010.54 g/mol
Yield: 2.3 g (73.4% of theory)
31P-NMR (δ[ppm], J[Hz], CDCl3): −46.3 qui (=quintet), 3JPF=11
1H-NMR (δ[ppm], J[Hz], CDCl3): 3.6 d, J=13.8 (2H); 4.1 d, J=13.8 (2H); 6.3 d, J=8.4 (2H); 6.85 t, J=17; 7.25 t, J=10.8 (2H); 7.65 d, J=8.6 (2H); 7.7 d, J=8.1 (2H); 7.94 d, J=8.6 (2H).
M=794.66 g/mol
Yield: 2.05 g (83.2% of theory)
31P-NMR (δ[ppm], J[Hz], CDCl3): −8.99
1H-NMR (δ[ppm], J[Hz], CDCl3): 3.05-3.1 m, (4H); 6.3 tt (=triplet of triplets), J=6, J=2.2 (4H); 6.53 tt, J=8.9, J=2.2 (2H); 6.65 m, (6H); 6.88 d, J=8.5 (2H); 7.1 tt, J=7, J=1 (2H); 7.2 d, J=8.5 (2H); 7.31 t, J=7.1 (2H); 7.78 t, J=8.5 (4H).
M=866.62 g/mol
Yield: 1.3 g (48.4% of theory)
31P-NMR (δ[ppm], J[Hz], CDCl3): −28.8 d, J=23.6; −29.1 d, J=25.0
1H-NMR (δ[ppm], J[Hz], CDCl3): 3.26 d, JHH=14.1 (2H); 3.45 dd, JHH=14, 2JPH=3.2 (2H); 6.33 m (2H); 6.55 d; 8.7 m (2H); 6.6-6.8 m (6H); 6.92 td (=triplet of doublets), J=6.9, J=1.2 (2H); 7.26 t, J=7.4 (2H); 7.43 dd, J=8.5, J=2.2 (2H); 7.7 d (J=8.1 (2H); 7.76 d, J=7.7 (2H).
M=762.95 g/mol
Yield: 1.9 g (80% of theory)
31P-NMR (δ[ppm], J[Hz], CDCl3): −11.4
1H-NMR (δ[ppm], J[Hz], CDCl3): 2.1 s, 2.2 s, 2.3 s (24H); 3.1 dd, JHH=14.2, J=2.5 (2H); 3.3 dd, JHH=14.2, 2JPH=2.2 (2H); 6.6 d, J=7.5 (4H); 6.9 m (6H), 7.1-7.2 m (6H); 7.35 dd, J=8.5, J=2 (2H); 7.4 t, J 7 (2H); 7.8 d, J=8.5 (2H); 7.85 d, J=7.9 2H).
M=866.62 g/mol
Yield: 2.3 g (85% of theory)
31P-NMR (δ[ppm], J[Hz], CDCl3): −8.5
1H-NMR (δ[ppm], J[Hz], CDCl3): 3.1 m, (2H); 3.05 dd, JHH=13.8, 2JPH=2.7 (2H); 6.3 q, J=6.7 (4H); 6.7 m (6H); 7.05 td, J=6.7, J=1.3 (2H); 7.3 m (4H); 7.8 t, J=8.9 (4H).
M=1126.72 g/mol
Yield: 3.1 g (88.7% of theory)
31P-NMR (δ[ppm], J[Hz], CDCl3): −10.5
1H-NMR (δ[ppm], J[Hz], CDCl3): 3.2 m, (4H); 6.95 d, J=8.5 (2H); 7.05-7.15 m, (4H); 7.25 d, J=4.7 (4H); 7.33 t, J=7.3 (2H); 7.47 d, J=4.5 (4H); 7.65 s, (2H); 7.7 d, J=11.1 (2H); 7.8 d, J=16.5 (4H).
3. Description of the Hydroformylation
The hydroformylation experiments were carried out either in a 100 ml autoclave (Parr Co.) provided with a magnetically driven propeller stirrer or in a 160 ml autoclave (Parr Co.) provided with a magnetic stirrer.
The hydroformylation procedure is described below by way of example for the autoclave experiment No. 1 (see table 1):
isooctane (2 ml as internal standard) and 1-pentene (8 ml, 73.0 mmol) are added to a solution of 1.88 mg of Rh(CO)2acac (7.3 μmol) and 44 mg of ligand 2.f) (M: 1127, 36.5 μmol) in anisole (30 ml). After the mixture has been transferred to the autoclave, the autoclave is brought to 5 bar by means of synthesis gas (CO:H2=1:1). The autoclave is then firstly heated to 120� C. to allow the pressure to increase slowly and the pressure is subsequently adjusted to 10 bar. After 16 hours, the autoclave is switched off automatically, cooled in an ice bath and depressurized to atmospheric pressure. A GC sample is taken directly from the autoclave and measured.
A catalyst formed using NAPHOS, namely the parent molecule without fluorine-containing substituents, likewise displays high selectivities but give low activities, as can be seen from the TOF values in the following table.
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November 28, 2014
STEAMBOAT SPRINGS, Colo. (AP) -- Authorities are praising a 14-year-old boy for saving his mother and another resident from a house fire in Steamboat Springs.
The Steamboat Pilot & Today (http://bit.ly/OvX5gh ) reports firefighters were called to the fire at about 7 a.m. Saturday.
Chief Mel Stewart says the boy was awakened by a smoke alarm and found flames in a hallway in the basement apartment. The teen's mother was asleep in her room, but the fire made it impossible for him to get directly to her.
Stewart says the boy went outside, banged on the bedroom window to wake up his mother and then helped her out through the window.
The tenant upstairs also was alerted and got out of the house, which suffered moderate damage.
Stewart says he gives the boy "a lot of credit."
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Book your room at GuestHouse Inn & Suite
Standard Room, 1 Queen BedMax Occupancy: 2 guests (up to 1 child, 1 infant)
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South Gate motel with a seasonal outdoor pool
Situated in South Gate, this motel is close to The Bicycle Casino. Area attractions also include Citadel Outlets and Watts Tower.
Property Features
GuestHouse Inn & Suite provides complimentary wireless Internet access, free self parking, meeting rooms, and RV/bus/truck parking.
Room Amenities
Televisions come with cable channels. Guestrooms also feature complimentary wireless Internet access, safes, and hair dryers.Information missing or incorrect? Tell us!
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A complimentary breakfast is offered. Public areas are equipped with complimentary high-speed wireless Internet access. Event facilities measuring 750 square feet (70 square meters) include meeting rooms. This South Gate motel also offers a seasonal outdoor pool and RV/bus/truck parking. Complimentary self parking is available on site.
- Total number of rooms - 49
- Number of floors - 2
- Free breakfast
- Meeting rooms
- Conference space size (feet) - 750
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- RV, bus, truck parking
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Available in all rooms: Free Wi-Fi
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Guests are offered a complimentary continental breakfast.
The recreational activities listed below are available either on site or nearby; fees may apply.
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To make requests for specific accessibility needs, complete the "Special or Accessibility Requests" section of "Trip Preferences" when you book your hotel.
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The fine print for GuestHouse Inn & Suite
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Check-in time starts at 1 PM
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Check-out time is 11 AM
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- POSTED: 03 Sep 2014 23:40
- UPDATED: 03 Sep 2014 23:46
Recipients recognised at the awards included rescuers, fire fighters and paramedics who helped perform CPR or defibrillation.
SINGAPORE: Time is of the essence for victims of cardiac arrest and every minute is crucial. The efforts of those who rendered help at that critical moment were recognised during the Survivor Awards ceremony on Wednesday (Sep 3).
Nurse Amanda Tan never thought that her mother would be the first person she applied cardiopulmonary resuscitation (CPR) on. Last year, 61-year-old Mdm Mary Ann Lee suddenly lost conscious and had no pulse. That was when her daughter stepped in to help.
Ms Tan, a recipient of the Survivor Awards Singapore 2014, recalled: "The paramedics advised us to carry her onto a flat surface. When I noticed that my dad was about to perform CPR, which he has no idea how to do, I said 'I have to take over, because I know how to perform CPR'. From then on, it just came quite naturally. Fortunately, I know how to perform CPR, so that was actually really not much of an issue."
Other recipients recognised at the awards included rescuers, fire fighters and paramedics who helped perform CPR or defibrillation, which involves using a device to give an electric shock to the heart. They received certificates of commendation from Health Minister Gan Kim Yong.
Every year, there are more than 1,500 cardiac arrest cases in Singapore that happen away from hospitals. Whether the victims are at parks, swimming pools or even in their own homes, the difference between life and death can be a matter of minutes.
"Sudden cardiac arrest can occur to anyone at anytime. And basically, your chances of survival would decrease by 10 per cent for every minute that nothing is done," said Associate Professor Marcus Ong, organising chairperson of the Survivor Awards Singapore. "However, our research has shown that if someone starts CPR at the patient's side, your chance of survival will double or even triple.
"At the moment, the CPR bystander rate in Singapore is only 20 per cent, and we hope this event will raise awareness about out-of-hospital cardiac arrest and the difference we can all make as bystanders."
- CNA/ms


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I am currently non-exempt and qualify for overtime when there is only a business need, last year I made a significant amount due coworker leaving on maternity leave I was asked to cover for her. The 1st QTR of this year I made some overtime, however it was only for brief time and I have gone back to working normal hours. Now for year 2011 I only made 1,100 in overtime, for 2012 I made 24K in overtime, and YTD, during 1st QTR I made 5K, my base is 66K. Given that the extra hours are not garaunteed what can I show courts to prove this so magistrate uses my base 66K as opposed to my 2012 W2 which shows a huge jump because coworker was on maternity leave. If they use my 2012 W2 to calculate and since I no longer work those hours I will be in a huge deficit, how I prove this in court?
Court uses last year's income for child support including overtime. If there is a big change, then it may use The current year to date to see if it is different than last year's income. Have an experienced child support lawyer help you.
Overtime does generally count in the calculation of child support, as the court will consider ALL income in the calculation. That said, to avoid assessment of the 2012 income, you're best advised to get a letter from your employer that your overtime in 2013 has been reduced through no fault (or request) of your own. In any event, I highly encourage you to schedule a follow-up consultation with a NYC Child Support attorney.
NO I DONT THINK SO. NYS law imposes a lawful obligation for parents to support their children under the age of 21 and calculations for child support are based on income. You made about $90K with overtime last year. The court will likely use that amount to calculate your child support obligation under the law. If next year you turn out making less overtime, you can petition the court for a change of the child support order based on this new income change. You must comply with an order of the court to support the child you created.
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Jr./Sr. Play Public Performance
Thursday, November 20th, at 7:00 p.m. in the HS auditorium. Admission is $2.
ASVAB Testing
All juniors will take the ASVAB on November 25th from 8:15 - 11:30.
Thanksgiving Break
November 26 - 28
End 2nd Quarter
December 18th
Christmas Break
December 19th - January 4th. School resumes January 5th.


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Governor's Community Garden
Advantages: Beautiful gardens, peaceful, large, various sections of the gardens to see
Disadvantages: Probably quite unknown to visitors unless they actually pass the garden entrance
...Introduction and History
Governor's Community Garden is a public garden, located on the Isle of Portland, Dorset, England. It is found within The Grove village within the Tophill part of the island. It sits opposite the site of the Young Offenders Institution HM Prison Portland, and close to the East Weares area.
The opening of the prison was in 1848, when a prison was chosen for Portland...
08.09.2013 11:22 ·
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Ciao members have rated this review on average very helpful
Review of Governor's Community Garden
Gardeners' Question Time
Advantages: Fabulous views and free entrance
Disadvantages: A bit of a trek out from the old city
...When and where to Plant
The Menara Gardens in Marrakech provide one of the city?s classic iconic views which most people who?ve ever visited the city will recognise. Photos show an old tile-roofed building reflected in a calm pool of water with snow-capped mountains in the distance. It?s almost as ?Marrakech? as photos of the Koutubia Mosque or the Jemaa el Fna square. So far so ordinary you...
21.03.2014 13:39 ·
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Review of Menara Gardens, Marrakech
TLC for gardeners
Advantages: Moisturises and softens
Disadvantages: None
...I bought this Opal gardeners hand cream when I ordered some other goods from them, as the delivery was free if I spent over £40.00 and as I had spent £36 it was worth buying something to make the order up to save me paying £4.95 delivery. I have had quite a few Opal products over the last few years and have found them to be very good quality and quick delivery.
I like to keep a hand cream in...
22.03.2014 14:25 (22.03.2014 14:27) ·
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Review of Opal London Gardeners Hand Cream
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McQ Alexander McQueen Burlesque butterfly-print canvas pumps
Unfortunately, this product is no longer available
Details & Fit
- McQ Alexander McQueen black, army-green and chartreuse Burlesque pumps
- Burnished-gold heel measures approximately 130mm/ 5 inches with a 35mm/ 1.5 concealed platform
- Butterfly-print canvas
- Almond peep toe
- Buckle-fastening ankle strap
- Only available in full sizes, go up to the nearest whole size if you take a half size
- Those who are full sizes may wish to take their normal size
- Italian sizing
Need advice? Contact Customer Care
Product code: 460390
Designer Information
Streetwear, tailoring, cocktail dresses and knitwear - McQ's subversive collections draw "on the rich design archive of Alexander McQueen". Under the direction of Alistair Carr and Sarah Burton, the label's versatile, easy-to-wear pieces are a hit with style setters and the A-list alike.
Delivery & Returns
If you need to send it back, you have 28 days to exchange or return your item. Plus, we'll come and collect from your home, work or alternate address.
Please note, items purchased in our Clearance sale and Weekend Shop-In are FINAL sale and cannot be exchanged or returned.


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We are located in the LNCO building
Suite 1400
Salt Lake City, UT 84112
Copeland Johnston
For an advising appointment
For information on the Graduate Certificate in Conflict Resolution offered through the Department of Communication, click here.
Have you ever asked "what will I do with my degree?" The vocational outcome of one's academic career is a vital and serious consideration. Peace and Conflict Studies Majors and Minors will have a wide breadth of talent to offer any employer, but how does one demonstrate that in the interview process? PCS 5900 "The Integrative Seminar" is a 1 credit class offered to all majors and minors to help students in the transition from academe to the professional world. Read Dr. David Derezotes' letter about this new class. [read here]
We have hired a new advisor, Copeland Johnston, who will be advising for Peace and Conflict Studies, Religious Studies, and the BA Language Requirement. He is located in Languages and Literature in LNCO 1400. When you make an appointment
check in at the front desk of Languages and Literature.
Keaton from Utah P&CS on Vimeo
Lauren from Utah P&CS on Vimeo
is part of a dynamic and broad-ranging collaborative effort at the University of Utah. The major and minor are housed in the College of Humanities, while also being part of the Barbara L. and Norman C. Tanner Center for Nonviolent Human Rights Advocacy in the College of Social and Behavioral Science.
P&CS enables students to understand the dynamics of peace and conflict and to contribute to the creation of more just and peaceable conditions in the world. Courses focus on conflict theory, war and terrorism, just war theory, the history of peace efforts and non-violent social movements, community-based conflict management and resolution, and human rights.
Our initiative draws upon the support of other colleges as well, including Social Work, Fine Arts, Science, and Law. P&CS thus embodies a cooperative spirit while bringing together many different approaches to the study of conflict resolution, peace studies, and human rights advocacy.


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Ivory Gaya Melon
The Ivory Gaya melon has a unique variegated exterior, as the name suggests the base color of the skin is an ivory cream covered in small lime green speckles and streaks.
Purple Pepinos
The Purple Pepino is entirely edible: skin, flesh, pulp and seeds.
Black Arkansas Apples
Inventory, lb : 0
This item was last sold on : 10/29/14
|Windrose Farm
Black Arkansas apples are available in the mid fall to early winter.
Current Facts
A member of the rose family (Rosaceae), the exact parentage of the Black Arkansas apple is unknown, but it is believed to be a relative of the Winesap apple. Known as one of the best storage apples the Black Arkansas will keep up to four months in cold storage during which time both the flavor and texture of the apple improves.
The skin of the Black Arkansas apple is waxy and vivid red to dark purple in color. Its flesh is golden hued and juicy with a fine-grained and crisp texture. Its highly aromatic and sweet-tart flavor mellows and becomes more palatable with storage. The flesh as well will soften with storage, when first harvested the Black Arkansas apple is extremely hard, almost to the point that many would find it difficult to eat out of hand.
Nutritional Value
Black Arkansas apples are a great source of soluble fiber, which helps to reduce cholesterol and prevent cardiovascular diseases. In addition they contain insoluble fiber, which promotes healthy digestion. They are also a good source of vitamin C and A and contain some potassium and iron.
The firm texture of the Black Arkansas apple makes it an excellent cooker. It can be baked, sautéed and roasted. Try baked into a pie or bread pudding. They can also be slow cooked and pureed to make soups and sauces. Its aromatic juice lends itself to ciders and jams. The flavor of the Black Arkansas pairs well with by winter squash, pecans, cranberries, vanilla, thyme, sage, cinnamon and cardamom.
The Black Arkansas apple is believed to have originated in the 1870's from a Winesap seedling in an orchard owned by Mr.Brathwaite in Benton County, Arkansas. Black Arkansas apples and the apple industry in general thrived in this region until the 1930's when a combination of a moth infestation, drought and the onset of the great depression nearly took out the commercial apple industry in Arkansas. Today Black Arkansas apples are grown in apple growing regions throughout the United States such as California, Washington, Oregon, Ohio and of course Arkansas.
Recipe Ideas
Recipes that include Black Arkansas Apples. One is easiest, three is harder.
|Cook Local
|Bread Pudding with Grand Marnier Sauce
|Doughgirl: Adventures in Baking
|Spiced Black Arkansas Apples and Dumplings
|A Little Zaftig
|Butternut and Black Arkansas Apple Soup
|Food 52
|Roasted Spiced Black Arkansas Applesauce
Recently Spotted
People have spotted Black Arkansas Apples using the Specialty Produce app for iPhone and Android.
Produce Spotting allows you to share your produce discoveries with your neighbors and the world! Is your market carrying green dragon apples? Is a chef doing things with shaved fennel that are out of this world? Pinpoint your location annonymously through the Specialty Produce App and let others know about unique flavors that are around them.


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Find commute times to your work, school, gym and more.
Old Town Creek
Contact this property
Floor Plans
Prices, specials, features and availability subject to change.
Property Features
- Laundry
- Washer & Dryer Connections
- Utilities Included
- Some Paid Utilities
- Other
- 1 1/2 baths
- 5-10 minutes from Fort Lee military base
- Carpeted living/dining combination
- Central A/C
- Central air
- Central gas heat
- Electric range
- Minutes from Fort Lee and shopping
- Minutes from I-95, shopping, and restaurants
- Near Southpark Mall
- Pets Allowed
- Washer/dryer hook-up
- Water, Sewage, & Trash Included
- Water/Sewage & Trash Included
Units may feature
- Amenities
- Air Conditioning
- Cable Ready
- Kitchen
- Refrigerator
Property Details
Old Towne Creek Apartments has it all! We're located just minutes to Fort Lee and offer easy access to I-95 and I-85 which makes commuting to downtown Richmond, VA a breeze! Nearby you'll find shopping, dining, and entertainment as well as Southpark Mall, one of the area's biggest attractions. Old Towne Creek offers large two bedroom apartments and we're pet friendly too! Stop by today and see why you'll want to call Olde Towne Creek home.
Leasing Information
Pet Policy
No Pets. Call for service animal policy.
Our lease terms are: 12 Months. (Please note that lease terms may vary, are subject to change without notice, and are based on availability. Inquire with property staff for complete details).
For more information, please
or check availability.
Office Hours
Monday: 8:00am-5:00pm
Tuesday: 9:00am-5:00pm
Wednesday-Friday: 8:00am-5:00pm
Saturday-Sunday: Please Call
Managed by
Apartment Guide
Check Availability
Call or email the property directly:
Check Availability
Similar Properties
Similar Properties in or near Colonial Heights, VA
Neighborhood Info


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Well I order the Ghost Deck a few days ago. I was scared the shipping would take too long. To my Surprise they were here in less than a week! The...Read More ->
When they sent me the package they refunded me for shipping charges because they found out that my address does not accept Express Mail. I'm really...Read More ->


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The Style Report: The Best-Dressed Men at the Grammys
Music's biggest night usually involves identifying style's worst offenders. But this year a select few got with the program and delivered solid looks on the no rules red carpet. Here are the men who killed in the only way Adele couldn't
February 12, 2012
2 of 10
Wiz Khalifa
Sure, tucking in the shirt wouldn't have killed the guy, to start, but we dig the white shawl collar dinner jacket Wiz pairs with slouchy leather pants and a pair of tassel loafers. Its elegant in its own way and not far off from what we've seen on one or two European runways.
- Tags
- Style,
- Celebrities,
- Grammys,
- Award Shows,
- Music
More Style Profiles:
Food + Travel
- David Chang's Kitchen: Don't Get All "Fresh" with Me
- David Chang's Kitchen: Your Idea of Bologna is Total Baloney
- Chart: The Family Tree of Bourbon Whiskey
- Recipe: Semi-Summer Salad - Chef Jeff Taibe of Oak + Almond
- The Great Franco-Italian Pasta Experiment
- How to Pick from an Overpriced Restaurant Wine List


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(815) 741-9393
2235 W Jefferson St
Joliet, IL 60435-6511
5.0 Miles
(815) 577-8667
3340 Mall Loop Dr Spc 1366, Joliet, IL 60431
Products: Gift Certificates, Hair Care Products, Hair Supplies, Highlights, Walk-ins
Services: Trimming, Beauty Salon Services, Blow Drying, Body Waves, Children, Coloring, Conditioning, Gif...
Latest review: "Had a wonderful experience at Mastercuts. Amanda was my stylist and she was awesome! got a c..."
18.9 Miles
(630) 969-1754
1045 Burlington Ave, Lisle, IL 60532
Latest review: "I am so impressed by the Randall Brent Salon staff! From the darling cutie that greets the ..."
19.7 Miles
(708) 430-4246
9510 S Roberts Rd, Hickory Hills, IL 60457
Latest review: "I look forward to my appointment because I know I will get terrific service, a great color a..."
Fantastic Sams is one of the worlds largest full-service hair care franchises, with salons located throughout North America.
main: (815) 741-9393
Joliet, IL
Complete hair care for men, women & children.
Joliet, IL
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Joliet, IL
Joliet's Premier Color & Hair Salon
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Local Hotels and Motels Directory
Travel > Hotels and Motels
Phone: (02) 4883 7813 | Location: 10A Elmswood Court Bundanoon, NSW 2578, Bundanoon, NSW
Bundanoon Lodge offers families the best pet friendly accommodation in the form of well furnished cottages and dwelling spaces which boasts of all the modern amenities.
Forrest Hotel and Apartments
Phone: (02) 6203 4300 | Location: 30 National Circuit, Forrest, ACT
Located in a quiet street in Canberra's garden district, Forrest Hotel and Apartments is situated in a convenient location, adjacent to Parliament House in the Parliamentary Business District. We are just a stone's throw away from major tourist attraction
Royal Hotel Mirrool
Phone: (02) 6974 1237 | Location: 1 Ariah Street, Mirrool, NSW
The Royal Hotel Mirrool; good food, cold beer and comfortable accommodation, combined with free camping facilities. It makes for an ideal destination.
Azzura Hotels and Resorts
Phone: (07) 5511 5327 | Location: Hope Island Resort, 2 Activa Way, Hope Island, QLD
Designed to serve both leisure and business purposes, Azzura resorts and apartments capture the natural charm and ambience of their diverse locations.
Chaparral Motel
Phone: (03) 6686 3399 | Location: 486 River Street, corner of Riverview Ave, Ballina, NSW
motels, accommodation, budget accommodation
Melbourne's Princes Park Motor Inn
Phone: (03) 9388 1000 | Location: Cnr. Royal Parade & Park Street Carlton North, Carlton North, VIC
When you next visit Melbourne and are searching for good quality family accommodation or superior motel accommodation in Melbourne, why not stay with us at Melbourne's Princes Park Motor Inn? We are located on the north edge of the city of Melbourne along
Punthill Apartment Hotel - South Yarra Grand
Phone: 1300 731 299 | Location: 7 Yarra Street, South Yarra, VIC
Discover stylish and spacious serviced apartment hotel accommodation in an unrivalled location in Melbourne. Whether travelling for business or leisure you'll feel right at home in our great range of flexible serviced apartment options.
Broome Time Lodge Hotels & Resorts Services
Phone: (08) 9194 1700 | Location: 1 Cable Beach Road East, Broome, WA
Broome-Time Lodge offers hotels and resorts services located in the heart of WA. We offers clients a host of unique services that make for an unforgettable and revitalizing experience in any one of our hotels, located in Broome.
Holbrook Skye Motel
Phone: (02) 6036 2333 | Location: 142 Albury Street, Holbrook, NSW
Holbrook Skye Motel is situated on the main street of Holbrook on the eastern side at the Sydney end of the business area opposite Holbook Stores IGA Supermarket carpark and the small submarine park and adjacent to the Hotel Holbrook, and about 200 metre
Macleay Hotel
Phone: (02) 9357 7755 | Location: 28 Macleay Street, Potts Point, NSW
The Macleay Hotel is located in the inner city Sydney precinct of Potts Point and only minutes walk from Kings Cross. The Macleay hotel has one of Sydney's most coveted locations in stylish Potts Point.
Downtown Motel
Phone: (02) 4229 8344 | Location: 76 Crown Street, Wollongong, NSW
motel accomodation
Seymours on Lydiard
Phone: (03) 5332 9966 | Location: 302 Lydiard Street North, Ballarat Central, VIC
We are a 4 star Motel in central Ballarat and offer fully self contained Motel accommodation, perfect for families, couples or corporates. We also have a gorgeous 4 bedroom fully furnished house available for short or long term stays
Travel Western Australia
Phone: (08) 9209 3661 | Location: PO Box 2532, Malaga, WA
Western Australia is home to plenty of extraordinary experiences, the likes of which can only be found right here. WA boasts the largest collection of wildflowers on the planet, some of the whitest beaches in the country and one of only a few places world
Tuck Inn
Phone: (03) 5962 3600 | Location: 2 Church Street, Healesville, VIC
Tuck Inn is a bed & breakfast accommodation located in the heart of Healesville,just an hour's drive from Melbourne with king and queen size bedrooms. We offer a no minimum stay with prices including sumptuous continental & hot cooked breakfast.
Tara Spa Apartments
Phone: (07) 4669 4001 | Location: 18 Milne Street, Tara, QLD
5 Self Contained Apartment Motel in the heart of town. All apartments feature luxurious spa baths & fully equipped kitchens. Off street parking, Inground Salt water pool, Hot 150 Jet Spa, Outdoor undercover gym, bbq, onsite laundry & disabled faci
Jindabyne Hotel
Phone: (02) 6456 2203 | Location: P.O. Box 49 Kosciuszko Road, Jindabyne, NSW
The Lake Jindabyne Hotel is the most famous Hotel in the Snowy Mountains.
Jurien Bay Hotel Motel
Phone: (08) 9652 1022 | Location: 5 White Street, Jurien Bay, WA
Beachside pub, hotel, accommodation, bistro, restaurant
Capertee Royal Hotel
Phone: (02) 6359 0172 | Location: 67 Castlereagh Hwy, Capertee, NSW
Capertee Royal Hotel is a historic hotel situated approximately 160km from Sydney in the small village of Capertee.
Country Rose Motel
Phone: (07) 4661 7700 | Location: 2 Palmer Ave, Warwick, QLD
Warwick's Country Rose Motel has 13 beautifully appointed rooms, All accommodation is self contained and suitable for families and corporate travellers, Please call for all enquiries.
Best Western Lake Inn
Phone: (03) 5338 8344 | Location: 1317 Mair Street, Ballarat, VIC
The new Lake Inn Motel which is part of the Best Western Chain offers 30 suites of luxury accommodation on either ground or 2nd floor levels.
Related terms: Accomadation, Accomidations, Accommodations, Accomodation, Book Hotels, Budget Accommodation, Budget Hotels, Cheap Hotels, Hotel Guide, Lodging, Places To Stay, Where To Stay


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Welcome to the News Center, where you will find news, insights, interviews and publications.
Showing: 1 to 10 of 4 123 news items
Ericsson Honored for Mobile Money project in Peru
Categories: Recognitions & Awards
Increase economic value through experience
The value of experience generates economical value for companies who can provide a platform where experiences are created. The telecom industries main asset, the network, is such a platform.
Ericsson's Thin Layer GSM to meet operators' challenges
Categories: Portfolio
Today, more than 85% of the population is covered by a GSM network. There are four billion GSM only subscriptions and 80% of M2M devices are GSM only. So, how can operators satisfy and grow this base when planning the evolution of their GSM network? Ericsson's new Thin Layer GSM addresses this challenge and opportunity.
Voice and video calling over LTE – securing high-quality communication services over IP networks
Categories: White Papers Technology
VoLTE gives operators the possibility to develop their communication business, while consumers and enterprise users can benefit from richer IP-based communication services available on any devices, anywhere.
IBM and Ericsson collaborate on 5G antenna designs
Categories: Press Releases
Ericsson and Econet Wireless Zimbabwe sign five-year deal to enable faster, more reliable connectivity
Categories: Corporate
- Ericsson has been selected by Econet Wireless Zimbabwe as the sole supplier for its Core network as well as existing RAN in the Harare region
- Econet Wireless Zimbabwe's network to be upgraded to the latest systems and technologies
- This collaboration will allow Econet's customers faster and more reliable mobile services and reduce time-to-market for new attractive services
3 trends transforming what is possible
Categories: Industry Technology
Mobility, broadband and the cloud are fundamentally changing what is possible. Ericsson Executive Vice President Johan Wibergh says companies can seize new opportunities if they act quickly.
451 Research: leveraging data is key to increasing service quality
Research Director at 451 Research Sheryl Kingstone discusses how service providers can leverage their available data to increase service quality and raise net promoter scores.
Customers define service in our Networked Society
Ericsson VP of technology Adan Pope offers insights into the high expectations that today's customers have of their service providers and what this will mean for the future.
Heavy Reading: Using big data insights to turn your customers into your advocates
Principal Analyst at Heavy Reading Ari Banerjee discusses how communications service providers can use customer data to better understand behavior and increase stickiness.


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HZ travel tools > Country codes > Mexico > Puebla
Puebla area code is+52 is the international country code for Mexico and
+52 - 222
+52 - 222
222 is the dial code for Puebla
Puebla current time is : Fri, 28 Nov 2014 04:41 PM
Time difference between Puebla and other cities
Distance from Puebla to other cities.
Traveling to Puebla, Mexico?
Then you may want to see the list of restaurants and hotels in Puebla.


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