text:
Compounds having the structures: ##STR1## wherein B is A or a hydrogen and A is R--X; wherein X is ##STR2## M is a Group II metal cation and R is a hydrocarbyl group having about 1 to 100 carbon atoms.
1. A compound having the structure: ##STR13## wherein B is hydrogen or A and A is R--X--; X is ##STR14## and R is a hydrocarbyl having about 1 to 100 carbon atoms.
2. A lubricating oil composition containing a major portion of a lubricating oil and about 0.1 to 10.0 weight percent of the compound of claim 1 based on the oil.
3. The compound of claim 1 wherein B is X--R wherein X is --NH--.
4. The compound of claim 1 wherein A is ##STR15## and B is --NH--R.
5. The compound of claim 1 wherein A is --NH--R and B is --NH--R.
6. A compound having the structure: ##STR16## wherein M is a Group II metal and A is R--X-- wherein X is ##STR17## and R is a hydrocarbyl group having about 1 to 100 carbon atoms.
7. The compound of claim 6 wherein M is selected from the group consisting of calcium and zinc.
8. The compound of claim 6 wherein A is ##STR18##
9. A lubricating oil composition containing a major portion of a lubricating oil and about 0.1 to 10.0 weight percent of the compound of claim 6 based on the oil.
10. A process for the manufacture of oil soluble compounds comprising reacting a thiadiazole compound and about 0.5 to 3.0 mole equivalents of a monohydroxy compound and about 0.5 to 2.0 mole equivalent of phosphorous pentasulfide to form a first reaction product and then reacting a 0.5 to 4.0 mole equivalents of mercapto neutralizing compound with the first reaction product per mole of the thiadiazole component in the first reaction product.
11. The process of claim 10 wherein the reaction is conducted at a temperature of about 10� C. to about 200� C. for about 1 hour.
12. The process of claim 10 wherein the reaction was conducted at a temperature of from about 80� C. to about 150� C. for about 1 hour.
13. The process of claim 10 wherein the reaction is conducted in an inert solvent.
14. The process of claim 10 wherein the thiadiazole compound is selected from a group consisting of 2,5-dimercapto-1,3,4-thiadiazole and 2-hydrocarbyl mercapto-5-mercapto-1,3,4-thiadiazole.
15. The process of claim 10 wherein said monohydroxy compound contains about 1 to about 20 carbon atoms.
16. The process of claim 9 wherein the mercapto neutralizing agent is selected from the group consisting of amines, olefins, and epoxides, each containing from about 2 to about 100 carbon atoms.
17. The process of claim 14 wherein when the thiadiazole compound is 2-hydrocarbyl mercapto-5-mercapto-1,3,4-thiadiazole, the mercapto neutralizing agent is an alkaline earth metal compound.
18. The compounds of claims 1 or 6 wherein R has 3 to 20 carbon atoms.
This invention relates to derivatives of dimercapto thiadiazole compounds. More particularly, this invention relates to the reaction product of dimercapto thiadiazole compounds, P2 S5, a monohydroxy compound and a mercapto (--SH) (sulfhydryl) neutralizing compound.
There has been considerable interest in recent years in new lubricant oil additive compositions. Many of these new additive compositions are based on phosphorous compounds and sulfur compounds and mercapto thiadiazole compounds. U.S. Pat. No. 2,905,639 discloses adding to an oil about 0.01 to about 5 weight percent of an oil soluble 2,5-dimercapto-1,3,4-thiadiazole derivative corresponding to the formulae: ##STR3##
U.S. Pat. No. 3,914,241 discloses an oil soluble lubricant additive having the structure: ##STR4##
U.S. Pat. No. 3,980,573 discloses lubricant stabilized against wear and corrosion with a substituted thiadiazole having the structure: ##STR5##
It is generally necessary to dissolve additive compositions in lubricant oils to prevent wear and corrosion. The compositions found in the patents cited above suffer from certain drawbacks. The compositions in U.S. Pat. No. 2,905,639 fail to provide substantial anti-wear properties in the lubricant. Although U.S. Pat. No. 3,914,241 discloses that certain dimercapto linked dialkyl dithiophosphate thiadiazole compounds provide anti-wear properties, and U.S. Pat. No. 3,980,573 discloses bis diallyl dithiophosphate thiadiazoles having anti-wear properties, these additives suffer from the disadvantage that they provide marginal anti-wear activity. There is need for compounds having better anti-wear activity. Further, oil additives should impart multifunctional properties to the oil. Other beneficial properties for lubricants are anti-corrosion and anti-oxidant activity.
The prior art does not disclose thiadiazole compositions which have enhanced anti-corrosion and enhanced anti-oxidant, anti-wear properties. Some prior art compounds are thiadiazole having anti-corrosion activity. Others are alkyl dithiophosphoric thiadiazoles having marginal anti-corrosion and marginal anti-wear properties, but lack the enhanced anti-wear, anti-corrosion, and anti-oxidant activity derived from various groups on the composition. Enhanced anti-wear, anti-corrosion properties of thiadiazoles permit treating the oil with smaller amounts of additive for the same level of anti-wear, anti-corrosion, and anti-oxidant activity.
Accordingly, there is a need for thiadiazoles having enhanced anti-wear, enhanced anti-corrosion and anti-oxidation properties.
Therefore, it is an object of the invention to provide a new composition of matter and processes for making the compositions. It is also an object of the invention to disclose a new additive composition having neutralized mercapto groups. It is also an object of the invention to provide new additive compositions and processes to prepare the additive composition which have multi-functional lubricant properties such as anti-corrosion, anti-oxidation, and anti-wear properties provided by the reaction product of a dimercapto thiadiazole and phosphorous pentasulfide and a monohydroxy compound having neutralized mercapto groups.
I have now found that the object of the invention can be attained by the use of the reaction product of a 2,5-dimercapto-1,3,4-thiadiazole compound, P2 S5, and a monohydroxy compound, in which the thiophosphate mercapto groups are subsequently neutralized, constitute a new class of additive compositions suitable for use in lubricant oil. These compounds consist of the neutralized reaction product of 2,5-dimercapto-1,3,4-thiadiazole compound, phosphorous pentasulfide (P2 S5), and a monohydroxy compound. Lubricating oil compositions containing this neutralized reaction product provide anti-wear, anti-oxidation, anti-corrosion properties, and extreme pressure properties to the lubricant oil. Compounds of this invention can be represented by the following structural formulae: ##STR6## wherein B is hydrogen or A and A is a R--X, wherein X is ##STR7## etc.; M is a group II metal cation and R is a hydrocarbyl with 1 to 100 carbon atoms.
Briefly, the compounds of this application can be prepared from a 2-substituted mercapto-5-mercapto-1,3,4-thiadiazole or unsubstituted 2,5-dimercapto thiadiazole compound of the following formulae: ##STR8## wherein X is a radical formed by the reaction of mercapto neutralizing compound and a mercapto group on the thiadiazole molecule. Compounds I or II are then reacted with phosphorous pentasulfide (P2 S5) and a monohydroxy compound to produce an alkyl dithiophosphate thiadiazole compound with a free mercapto group. The resulting mercapto group is neutralized.
As shown above, two types of thiadiazole compounds can be reacted with P2 S5 and a monohydroxy compound to produce compounds useful in this invention. One type is the 2,5-dimercapto-1,3,4-thiadiazole having two unsubstituted mercapto groups. The other is a 2-substituted mercapto-5-mercapto-1,3,4-thiadiazole where one mercapto group is substituted with a radical formed from a mercapto neutralizing compound. For example, 2,-hydrocarbyl-1,3,4-thiadiazole. Examples of mercapto neutralizing compounds which can be used to provide substituents at the mercapto group are olefins, carboxylic acids, carboxylic acid anhydrides, amines, forming ammonium salts, or amides. Formation of these blocking groups can be exemplified by the following illustrative sequences: ##STR9## where R is an aliphatic, unsaturated, or aromatic hydrocarbon, having about 1 to 20 carbon atoms, providing oil solubility. Other reactions for neutralizing mercapto groups reactive other than these types of reactions are well known in the art and other examples of these reactions are found in Methoden Der Organischen Chemie, Houben-Weyl, Band XII/2, George Thieme Verlog (Stuttgart 1964), pages 692 to 812.
The monohydroxy compounds used in the reaction comprise aliphatic branched or unbranched monohydroxy compounds having from about 1 to about 40 carbon atoms, preferably from about 3 to about 20 carbon atoms. Aromatic monohydroxy compounds such as phenol substituted with a C2-40 hydrocarbyl group are also commonly used. Monohydroxy compounds are commonly used whose hydrocarbon radicals are alkyl, cycloalkyl, arylalkyl, or aryl radicals or substantially hydrocarbon radical of similar structure. By "substantially hydrocarbon radicals" is meant radicals containing substituent groups such as ether, ester, nitro, or halogen which do not materially effect the hydrocarbon character of the radical. Specific examples of suitable monohydroxy compounds include methanol, ethanol, propanol, isopropanol, isobutanol, butanol, sec-butanol, t-butanol, hexanol, heptanol, 2-ethyl hexanol, isooctanol, nonanol, decanol, dodecanol, tetradecanol, hexadecanol, octadecanol, eicosanol, buty phenol, octyl phenol, nonyl phenol, dodecyl phenol, polyisobutene substituted phenol, tetrapropylene-substituted phenol, o-octylbutylnaphthanol, cyclopentyl phenol, cyclohexyl phenol, phenol, chlorophenol, o-dichlorophenol, bromophenol, naphthenol, 2-methylcyclohexanol, benzol, chlorobenzol, dichlorophenol, nitrophenol, etc.
Preferred monohydroxy compounds are octanol, isooctanol, isopropanol, isobutanol, nonyl alcohol, phenol, and dodecyl phenol. Phosphorous pentasulfide is a commonly available industrial chemical.
In somewhat greater detail the compositions of this invention can be prepared by the neutralization of the reaction product of phosphorous pentasulfide, the thiadiazole compound and the monohydroxy compound. The reaction can be carried out by forming a mixture in an inert solvent or oil of the three compounds added in any sequence. The reactions can be carried out at a temperature from about ambient temperature 10� C. to 200� C., preferably for ease of reaction and short reaction time at 80� C. to 150� C. At these temperatures the reactions occur readily and are complete within a period of about 30 minutes to 6 hours depending on the monohydroxy compound and the substituents on the thiadiazole compound. Certain side reactions compete with the reaction producing the dithiophosphoric acid derivatives of the mercapto thiodiazole. Principle among these reactions is the production of the dialkyl dithiophosphoric acid. Accordingly, in order to fully utilize the thiadiazole compound excesses of the monohydroxy compound and phosphorous pentasulfide, for each mole equivalent of thiadiazole compound about 0.5 to 3.0 mole equivalents of monohydroxy compound and about 0.5 to 2.0 mole equivalents of phosphorous pentasulfide are used. After the reaction unreacted compounds precipitate and are removed by decanting the reaction product from the solids.
The reaction product is then neutralized by the reaction of the mercapto neutralizing agent with the dithiophosphoric acid substituted thiadiazole compound. The mercapto neutralizing compound is added to the reaction product produced above, the neutralization compound is added dropwise or in small amounts continuously at temperature from ambient to 200� C. Generally the neutralization reaction is exothermic and in that case heating is not needed.
The addition is controlled to maintain the temperature at less than about 200� C. In some neutralization reactions water is generated. This water must be removed by blowing the reaction mixture with nitrogen at a temperature from ambient to 110� C. About 0.5 to 4.0 mole equivalents of the mercapto neutralizing compound is added per mole of the thiadiazole compound. When an unsubstituted thiadiazole compound is used, two mercapto groups are available for neutralization. Accordingly, 0.5 to 4.0 mole equivalents of mercapto neutralizing compound can be used. With a monosubstituted thiadiazole is used generally one mercapto group is available. Accordingly, 0.5 to 2.0 mole equivalents of mercapto neutralizing compound can be used.
Various solvents which can be used in this invention are hydrocarbons, hydrocarbon ethers, or chlorinated hydrocarbon solvents. Preferred solvents are benzene, toluene, pentane, hexane, heptane, octane, petroleum ether, lubricating oils, lingroin, chlorinated hydrocarbons are methyl, methylethyl, diethyl, or other mixed hydrocarbon ethers. ##STR10## is an illustration of the reactions of an unsubstituted or a monosubstituted dimercapto thiadiazole with phosphorous pentasulfide, and monohydroxy compound.
The reaction products of an unsubstituted or a substituted mercapto thiadiazole, P2 S5 and a monohydroxy compound is beneficially reacted with a compound which neutralizes the free acidic mercapto groups. Acidic mercapto groups can exist on the thiadiazole moiety or on the dithiophosphoric acid moiety. Lubricating oils are commonly alkaline substances. This alkalinity neutralizes the harmful acidic by-products of combustion and thereby protects metallic surfaces. The free acidic mercapto groups must be neutralized to prevent neutralization of beneficial alkaline components of the lubricants by the free acidic mercapto groups which would otherwise harm the properties of the lubricating oil. Any compound which will react with and neutralize the mercapto groups in the alkyl dithiophosphate or the thiadiazole may be used. Examples of such neutralizing agents are amines such as primary and secondary amines polyalkene polyamines, tertiary alkyl primary amines, and 1,6 hexane diamines. Epoxides which are available from oxidation of normal olefins or mixed olefin refinery streams may also be used to neutralize the mercapto groups. Olefins also react with mercapto groups. The reaction of a substituted 2,5-dimercapto-1,3,4-thiadiazole thiophosphoric acid derivative with an alkaline earth metal neutralization agent such as calcium oxide, a zinc oxide, or an amine may be illustrated as: ##STR11##
The neutralization reaction of an unsubstituted mercapto thiadiazole with neutralization agents such as amines or olefins such as styrene produce products illustrated as: ##STR12##
The dithiophosphoric acid derivatives of thiadiazole and the neutralized products can be prepared in batch or continuous processes. In batch processes of the solvent solution of the reactant or reactant without solvent may be added to the other reactants in a single vessel. In continuous processing, the two components in solution or solventless can be charged to different zones (countercurrent processes) or the same reaction zone, e.g., the upper end of a vertical zone maintained at a suitable elevated temperature. The product commonly is withdrawn from the other end into purification strippers and filters.
The thiadiazole derivatives of this invention are useful as lube oil additives and various oils such as synthetic, animal, vegetable or mineral oils. Ordinary lubricating mineral oils are usually preferred by reason of their availability, general excellence, and low cost. However, for certain applications other oils are preferred. For instance, synthetic polyester oils are often preferred lubricants. Normally, the lubricant oils are fluid oils the viscosity of which is greater than 4.0 Saybolt Universal seconds at 210� F., preferably greater than 40 Saybolt Universal seconds at 210� F.
This invention also contemplates the presence of other additives and lubricating compositions. Such additives include, for example, viscosity index improving agents, pour point depressing agents, antifoam agents, extreme pressure agents, rust inhibiting agents, and oxidation and corrosion inhibiting agents. The additive of this invention is generally added to lubricating oils in order to improve the corrosion inhibiting properties, oxidation inhibiting properties, and where in extreme pressure properties of said oil. Depending upon the nature of the oil and the intended use thereof and in the intended environment, different amounts of the additive are needed in order to be effective. Generally, about 0.1 to about 10 weight percent, preferably from about 0.5 to about 2 weight percent is used in the oil.
78 grams of isooctyl alcohol (0.6 moles), 30 grams of 2,5-dimercapto-1,3,4-thiadiazole (0.2 moles) and 42 grams of P2 S5 (0.2 moles) were dissolved in 20 grams of 5 weight oil which was stirred and heated to a temperature of 100� C. under an inert blanket of nitrogen in a flask equipped with a reflux condenser. After 15 minutes at 100� C., the temperature was raised to about 130� C. The mixture became clear after about 15 minutes at this temperature. The reaction was allowed to continue for an additional 30 minutes. The hot mixture was poured into a beaker where traces of unreacted solids were precipitated. The liquid product was decanted off the solids and furnished a clear, light yellow liquid. Elemental analysis showed the composition contained 11.7 percent phosphorous, 23.5 percent sulfur, and 4.9 percent nitrogen. Total acid number (TAN) was 126 (milligrams KOH/grams).
20 gm of the product of Example 1 was placed in a flask to which was added 13 grams of a mixed, branched chain alkyl primary amine (0.04 moles) by adding the amine dropwise to the acid while the acid was being stirred.
Example 1 was repeated with 190 grams of isodecyl alcohol (1.2 moles), 60 grams of 2,5-dimercapto-1.3,4-thiadiazole (0.4 moles) and 88 grams of P2 S5 (0.4 moles) in 60 grams of 5 weight oil. The resulting clear, yellow liquid had an elemental analysis of 11.1 percent phosphorous, 23.9 percent sulfur, and 4.2 percent nitrogen. The total acid number was 89.6.
20 gms of product of Example 3 was neutralized in the manner of Example 2 with 12.6 grams of a mixed branched chain primary aliphatic amine (0.04 moles).
30 grams of the composition from Example 3 was neutralized with 16 grams of oleyl amine (0.06 moles) in the manner of Example 2.
20 grams of the composition of Example 3 was reacted with 11.1 grams of a hydrocarbyl epoxide (0.07 moles) which is made from a mixture of C-11 to C-14 alpha-olefins.
a. 104 grams of styrene (1.0 moles) was added dropwise to 150 grams of 2,5-dimercapto-1,3,4-thiadiazole (1.0 moles) dissolved in 50 milliliters of dioxane and a flask equipped with a dropping funnel and a reflux condenser. The mixture was heated to a temperature between 35� to 40� C. for a period of 45 minutes. The mixture is stirred under reflux for 1 hour and a solvent removed by a stream of nitrogen.
b. 156 grams of isooctyl alcohol (1.2 moles), 101.6 grams of the styrene adduct from Example VI and 88.8 grams of phosphorous pentasulfide (0.4 moles) were dissolved in 40 grams of 5 weight oil. The mixture was stirred in a flask equalled with a stirrer, heater, and reflux condenser to a temperature of 100� C. After a reaction time of 30 minutes, the temperature was raised to 132� C. and maintained for 30 minutes. The clear, yellow liquid yielded a viscous oil. The total acid number (TAN) of the product was 84 (milligrams KOH/grams).
46.6 grams of the product of Example VII was added to a suspension of 8 grams of zinc oxide in 25 grams of 5 weight oil over a 10-minute period in a flask at room temperature. During the addition of the acid, the temperature rose from ambient to about 75� C. Complete neutralization was accomplished by the addition of 10 drops of nitric acid in the reaction mixture. The water of neutralization was removed by blowing the reaction mixture with nitrogen. Filtration through diatomaceous earth yielded a clear, light yellow oil whose elementary analysis was 2.9 percent zinc, 1.8 percent phosphorous, 14.9 percent sulfur, and 2.9 percent nitrogen.
20 grams of the composition of Example VII was reacted with 12 grams of Primene JM-T, a tertiary hydrocarbyl primary amine of a molecular weight of about 315.
30 grams of the composition of Example VII was reacted with 11.8 grams of Needox 1114 (0.1 moles). Needox 1114 is a hydrocarbyl epoxide prepared from an oxidized mixture of C-11 to C-14 alpha-olefins.
Many variations from the examples and illustrations found above are possible. Examples and illustrations shown are to describe specific oppositions which are prepared. Those skilled in the art will be ablp to create many other variations similar to those examples found above. These examples should not be used in limiting the scope of the invention.
TABLE I______________________________________TEST FORMULATIONS Corrosion Dis- MgCompound Test per- VI-Im- Sul-Example at % 5 Wt. Oil Solution* sant prover fonate______________________________________1 II @ 1% Balance2 IV @ 1% Balance3 VI @ 1% Balance4 IX @ 1% Balance5 VIII @ 1% Balance6 II @ 0.3g Balance7 IV @ 0.3g Balance8 V @ 0.3g Balance9 IX @ 0.3g Balance10 II @ 1% Balance 5% 5% 1%11 IV @ 1% Balance 5% 5% 1%12 V @ 1% Balance 5% 5% 1%13 VI @ 1% Balance 5% 5% 1%14 IX @ 1% Balance 5% 5% 1%15 VIII @ 1% Balance 5% 5% 1%16 X @ 1% Balance 5% 5% 1%17 0% Balance18 0% Balance19 0% Balance 5% 5% 1%______________________________________ *30 milliliters decalin + 1 milliliter of a 1 weight % sulfur in chloroform solution. The dispersant is a polybutyl phenol, tetraethylene pentamine, formaldehyde Mannich Base; the VIImprover is a polyester polymer of methacrylic acid and a long chain alcohol; the Mg Sulfonate is a polypropyl benzene sulfonate overbased with MgO to a total Base No. (TBN) of about 200.
TABLE II______________________________________FOUR BALL TEST ASTM-2266**LOAD BEARING - ANTI-WEAR TESTTest Formulation Scar Diameter (mm)______________________________________1 0.602 0.603 0.554 0.585 0.4117 (no additive) greater than 2mm after 1 min.______________________________________ **Test Condition 1,800 rmp; 0.5 hours; 30 kg load.
ASTM-2266 is a test which determines the load-bearing properties of lubricating fluids. The testing machine is operated with one steel ball rotating against three balls held stationary to form a cradle. The balls are rotated at about 1770�60 rmp at 65� to 95� F. at a certain kg-load. The test results in Table III show acceptable load bearing anti-wear properties of the anti-wear additive.
TABLE III______________________________________COPPER STRIP CORROSION TEST ASTM D-130***Test Formulation ASTM Rating______________________________________6 1a7 1a8 1a9 1b18 (no additive) 4c______________________________________ ***Modified Test Conditions 3 hours at 212� F.
The modified ASTM method D-130 is a test to detect the corrosiveness of hydrocarbons to copper. A polished copper strip is immersed in a given quantity of sample and test solution, and is heated at a temperature for a time characteristic of the material tested. At the end of the test the copper strip is washed and compared with ASTM Copper Strip Corrosion Standards. In the modified test a test solution is made of 30 milliliters of decalin and 1 milliliter of a 1 weight % sulfur in chloroform solution. 0.3 grams of the test additive is dissolved in the test fluid and the copper strip is immersed in the test fluid for the corrosion testing in other respects the test is the same.
TABLE IV______________________________________OXIDATION TEST Spot Dispersancy (4 � VO) Time,Test Composition Test (%) After 48 Hours Hours______________________________________10 100 15911 100 16512 95 15213 98 15714 100 16015 100 15516 100 17219 (no additive) 43 47______________________________________
Anti-oxidative properties of oil composition were measured by an oil thickening test. In this test 100 grams of test oil are oxidized at 280� F. in an open oxidation tube, while being blown with 60 cc air/minute. Oxidation is catalyzed by the addition of 5 wt% Ford VC sludge oil. Samples are taken periodically and their viscosity determined to give a viscosity-time curve. The time in hours for a four-fold increase in viscosity over the initial viscosity (4 VO) is noted; a long 4 VO indicates resistance to oil thickening by oxidation. Also, a sample of this oil after 48 hours of oxidation is run in the Spot Dispersancy Test which gives a measure of the oil's ability to disperse sludge and varnish. In the Spot Dispersancy Test, 3-10 drops of oil are dropped onto a standard white blotter paper on which is a sludge spot. After 24 hours, the diameter of the sludge spot and the oil spot are measured. Dispersancy is reflected by the ability of an oil to keep sludge in suspension. Thus, dispersancy will be reflected by the difference in diameters of the sludge and oil spots. A rating (SDT Rating) is given by the diameter of the sludge spot divided by the diameter of the oil spot, and multiplied by 100. A high numerical rating indicates good dispersancy.
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Here, the former Jonas Brothers singer—now a burgeoning fashion plate and front row regular—shows you how to up your jacket game... more >
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The Vibe for Fall 2011:
One of the Best New Designer in America nominees last year, Richard Chai continues to up his game every season. This collection had a more structured feel to it, opening with a beautifully tailored grey suit. Chai's color palette and silhouette is effortlessly cool—just like the man himself.
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2013 Contemporary Northwest Art Awards
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Culled from 235 nominations, the six artists in the Portland Art Museum's contemporary awards exhibition represent a wide range—in terms of cities (from Seattle to Jefferson City, Montana), profiles (emerging to MacArthur "Genius"), and styles (color panels of oil and wax to a tower of electric guitars). While it's difficult not to be excited about the decorated Seattle artist Trimpin's imaginative, musical installation sculptures, we're also primed for Isaac Layman's massive genre-pushing photographs and intrigued by Jackson Hole–wildcard, Abbie Miller, whose "Zipped" series—incorporating vinyl, steel, and hundreds of feet of zippers—are glossy, twisted things that look like a cross between a Lady Gaga outfit, salt water taffy, and some sort of alien intestinal tract.
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TALLAHASSEE, Fla. (AP) — Florida State starting defensive lineman Derrick Mitchell Jr. was in the school library Thursday when a 2005 graduate shot and wounded three people before being killed by police. He played in a football game a little more than 48 hours later.
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"I'm the associate dean for academic affairs." "That's impressive. You must have a lot of responsibility." "I'm the dean of student affairs." "Wow. You have a chance to shape students' careers." "I'm the assistant dean for CME." "What's that? I didn't know there was such a position. Did no one else want it?" We may not actually hear these reactions explicitly, but I can tell you, that is what many physicians think. Physicians lack understanding about CME management in part because ...
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This might put Santa on the naughty list.
The e-cigarette company Vapor-Shark is facing backlash after putting up a billboard of a "vaping" Santa Claus in Florida. The Campaign for Tobacco-Free Kids complained the ad was similar to old cigarette ads aimed at children and called it " a new low."
Even e-cigarettes fans said the ad was inappropriate.
"Showing Santa vaping, globally recognized as a children's icon, is irresponsible and is and will be seen as a ploy to appeal to under age customers," said Aaron Frazier, a self-described "vapor," on the company's Facebook Page.
"We disagree … it's a difference of opinion" said Vapor Shark CEO Brandon Liedel of their dissenters. "The only type of kid that would be persuaded by Santa Claus is a 5-year-old. I think a gorgeous woman would be more persuasive for a teenager."


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- 350 CI V-8 engine- 700R4 automatic transmission- Rebuilt stock rear end with Caltrac traction bars- Power disc brakes- 605 box with power steering-... More
To be sold at the Austin 2014 auction, Austin, TX, December 12-13, 2014. To consign a car or to register to bid, visit the... More
- First year Nomad- Concours quality restoration- 265/162 HP OHV V-8 engine- Powerglide 2-speed automatic transmissionTo be sold at the Austin 2014 auction, Austin,... More
1955 CHEVY NOMAD WAGON - SURVIVOR GREEN - INDIA IVORY WHITE WITH GREEN/WHITE INTERIOR. 283 - 230 HP / AUTOMATIC WITH POWER STEERING, POWER BRAKES... More
The 1957 Chevy Nomad remains one of the most iconic vehicles in automotive history. Northwest Classic Auto Mall advertises this vehicle for the owner. If you... More
1955 Chevy Nomad – Full custom – This is the finest example of speed and beauty that can be found anywhere in the world – From the... More
This 1955 Nomad resto comes with only 1,700 miles since frame-off restoration. LT-1/350 Corvette engine producing approx. 350/400 HP, 700 R-4 automatic transmission, power... More
1955 Chevrolet Nomad wagon,a professional,authentic restoration of a solid original car,finished in the factory Cashmere Blue and India Ivory,with the complimenting Blue and White... More
- 265 CI Power Pack V-8 engine- Skyline Blue and India Ivory- Power windows- Power seat- Air conditioning- Power steering- Power brakes- Wonderbar radio-... More
- Eckler's Classic Chevy Platinum Award scoring 996 of 1000, 1st Place Custom and Best Paint Modified Custom Awards- GoodGuys Nationals Way Cool Wagon... More
- SOLD WITH S62.1 trailer- 350/340 HP engine- 700R4 automatic transmission- Custom Phantom delivery body- Dupont Chromabase Bright Aqua Metallic paint- Ultraleather bucket seats-... More


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Search Tags: total workplace
GSA's Total Workplace transforms traditional office environment
Program aims to save agencies money, increase productivity as explained by Chuck Hardy, director of GSA's Total Workplace program to Federal News Radio's Agency of the Month.
Tags: Agency of the Month , General Services Administration , GSA , workforce , Chuck Hardy , technology , Jason Fornicola
GSA declares end to cube farms, unveils new approach to office space
DHS, HHS, Interior and USDA all are on board to try out the Total Workplace initiative that focuses on open spaces, hotelling and mobile employees. GSA Administrator Dan Tangherlini said a new approach to office space will save money and improve how agencies meet their missions.
Tags: management , workforce , GSA , DHS , Dan Tangherlini , Jeff Orner , HHS , Interior , USDA , real property , telework , Jason Miller


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October 21, 2013
Sidney Sherman
July 23, 1805 - Marlboro, Massachusetts
August 1, 1873 - Galveston, Texas
Soldier of San Jacinto
Credited with the battle cry, "Remember the Alamo!"
Republic of Texas Congressman (1842-1843)
Republic of Texas Army Major General
GPS Coordinates
29° 16.392, -094° 49.566
Section C
Lakeview Cemetery
Posted by John Edward Stark at 1:26 PM
1 comment:
- AnonymousNovember 13, 2013 at 10:34 AM
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Height: 6 ft, 0 in
Weight: 175
Turned Pro: 2009
College: University of Florida
Bio: Currently uses Todd Anderson as his golf instructor. Biggest thrill in golf was playing and winning the 2007 Walker Cup. Biggest thrill outside of golf was graduating from the University of Florida in 2009. Favorite golf course played is Royal County Down in Northern Ireland. Never travels without his computer. Favorite professional team is the New England Patriots, Boston Red Sox and Boston Celtics. Superstitions include carrying four tees and a 1936 quarter in his right-front pocket. Favorite TV show is "SportsCenter." Favorite movies are "The Patriot" and "The Hangover." Favorite entertainer is Kings of Leon. Favorite food is steak. Favorite athlete to watch is Tiger Woods. Favorite city to visit is Monterey, CA. Would round out his dream foursome with The Old Red Eye Rugby Group. Read all four Twilight books in two weeks and is a believer in Bigfoot and UFOs. Non-golf-related jobs held include working with his dad in construction. (Bio information from Golfweek research and pgatour.com)
Patrick Reed has found his way into the Hero World Challenge. Reed earned his spot when Jim Furyk withdrew because of a back injury.
Rickie Fowler has committed to play in the 2015 Irish Open, which will be hosted at Royal County Down by Rory McIlroy's foundation.
Brooks Koepka climbed to 35th in the Official World Golf Ranking after his victory at the Turkish Airlines Open.
When it comes to mapping out his season, Chris Stroud puts a big circle around the OHL Classic at Mayakoba � and for good reason. Stroud is one of three players who can say they�ve played in each of the eight editions of this tournament.
New Mexico senior Gavin Green successfully defended his title at the Western Refining College All-America Golf Classic on Sunday in El Paso, Texas.
New Mexico's Gavin Green took the lead at the Western Refining College All-America Golf Classic with a tournament-record 62 in the second round.
Tee times and pairings for the final round of the WGC-HSBC Champions at Sheshan International Golf Club in Shanghai, China.
Graeme McDowell will take a three-shot lead into the weekend at the World Golf Championships-HSBC Champions.
Here are the complete tee times and pairings for the first and second rounds of the WGC-HSBC Champions at Sheshan International in Shanghai, China.
Ryan Moore became the first to defend a title on the PGA Tour since Tiger Woods in 2013 with a win at the CIMB Classic in Malaysia ... that and much more in Golfweek PostGame.
Co-leaders Kevin Na and Ryan Moore will play with World No. 4 Sergio Garcia Sunday in the final round of the CIMB Classic.
Here are the complete tee times and pairings for Saturday's third round of the CIMB Classic at Kuala Lumpur (Malaysia) Golf and Country Club.
We know they play hard for the European Tour come Ryder Cup time, but playing pure European Tour tournaments is another story. Justin Rose, Graeme McDowell and Ian Poulter are in China for the BMW Masters, but it�s just the fourth pure European Tour tournament for each of them.
Beautiful thing, this global golf. You can�t quite make it over to the PGA Tour, just hang tight in your Asian surrounds and guess what? The PGA Tour will come to you.
Here are the complete tee times, pairings for the first and second rounds of the CIMB Classic at Kuala Lumpur Golf and Country Club in Malaysia.
Robert Streb picked up his first PGA Tour victory in dramatic fashion, winning a three-man playoff at the McGladrey Classic ... that and much more in Golfweek PostGame.
Familiar faces returned to the Tour as caddies this week, Jason Dufner is returning to competition and Kevin Streelman is still making birdies.
Ben Martin played his final four holes in 4 under -- birdie, eagle, par, birdie -- for a 3-under 68 that turned his 56th PGA Tour start into his first victory ... that and much more in Golfweek PostGame.
With two rounds complete in Las Vegas, it's Andrew Putnam and Russell Knox tied atop the leaderboard at the Shriners Hospitals for Children Open.
Follow our live blog of the PGA Tour's Shriners Hospitals for Children Open Friday second round.
Your search for "Billy Horschel" didn't return any results.
Our David Dusek breaks down Billy Horschel's winning bag from the Zurich Classic.
Spend the day with Florida senior Billy Horschel, from workouts to classes to practice.


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Welcome to the Science Museum of Virginia!
From the legacy of our grand historic home inside a 100 year old train station to our quirky Rat Basketball team – we undoubtedly have a rich history and a bright future. We've made a few resources available for you here on this page, but if you are interested in writing a story about us, please contact us today.
Science Museum of Virginia Press Kit
Inspiring Virginians to enrich their lives through science.
37th Annual Model Railroad Show at the Science Museum of Virginia
Celebrate an annual holiday tradition Thanksgiving weekend at the Museum.
Overview of the Ebola Epidemic at the Science Museum of Virginia
Dr. Brigette Gleason provides an overview of the Ebola epidemic on November 19.
Virginia Aviation Museum Celebrates over a Century of Flight
The Virginia Aviation Museum invites guests to Just Plane Fun! on November 8.
Worldwide Industry Leaders Convene at the Science Museum of Virginia
Giant Screen Cinema Association members meet in The Dome on October 22.
Science After Dark lights up the Science Museum of Virginia
Turn down the lights and get ready to glow on October 17.
Girls in Science Spend a Night at the Science Museum of Virginia
Middle school girls light up the night with science on October 4.


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How Do You Promote Your Music on the Internet?06 November 2014 | By Michael J. Wyant in Analyse | No Comments Yet
I have been thinking about this because I am sort of in a tight spot if I want to get my band off the ground while I am trying to take college full time. How do you promote your music on the Internet? I have been thinking that one thing is that you want to try to get soundcloud followers. I am not really able to do shows most nights of the week. On thursdays I am in class basically day long, from 9 in the morning until half past six at night. So it is obvious that I can not go out and play a show on that night or on the night before. Read Full Post


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SeptemberFest: Creating Music. Patrons and their Commissions II
Presented by Longy School of Music of Bard College at Edward M. Pickman Concert Hall
September 21, 2013
SeptemberFest: Creating Music
Patrons and their Commissions II
Chamber Works by Barber, Poulenc, Ravel, and Bartók
Free admission, tickets required
Edward M. Pickman Concert Hall
27 Garden Street
Cambridge, MA 02138
Admission Info:
Phone: (617) 876-0956 ext. 1500
Accessibility Information: Currently, no accessibility information is available for this event.
Facebook Comments
Member Reviews
There are currently no reviews/comments for this event. Be the first to add a review/comment , and let folks know what you think!


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Game Questions & Answers (Q&A) service lets you ask questions about video games for game consoles or PC games. So ask your Survivalcraft question for Android and get answers from real gamers or answer questions and share your insights and experience with the rest of the gaming community.
- Developer: Candy Rufus Games
- Publisher: Candy Rufus Games
- Genre: Action General
- Release Date: Nov 6, 2012
- ESRB: Not Set
Question & Answers
Answer from: tapper
Just craft a iron block and a diamond and a gunpowder each of them is 10
Answer from: baloo2013
You can craft guns?!?
Answer from: fox-flight
Make a gun-shapped thing outta something, next, either you can leave a hole or cover it up with a wire through _______. and put that red thing with a ! On it, and connect it with a wire and at the end, put a wire through ____ and put a button at the end. Or leave a hole, connect it with a wire, connect it to a keg. and presto!
Answer from: Fox say
Like a make a house that shape like a gun and something you can do it. I have a superman power like me and a gun powder and a something you know of course im a filipino im here in the philippines you know why so im a superman and superhero with a great power with a super power something iron man 3 tooo so i can fly like iron man. so u have a power too and read a book that you can fly because i invented an iron man suit that is flying
Unanswered Questions
From: Eliopu
Posted on: 11-04-2014
Survivalcraft - Gameplay Video
- Apr 30, 2013, Views: 962
- Swish, (Android)
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- Help Me Jack: Atomic Adventure, (Android)
- Bruce Lee: Enter The Game, (Android)
- Kim Kardashian: Hollywood - Gameplay, (iPhone-iPod)
- Episode: Choose Your Story - Gameplay, (iPhone-iPod)
- How To Train Your Dragon 2 - Ready To Fly Trailer, (Wii)
- The Settlers - Kingdoms Of Anteria - Announcement Trailer, (PC)
- Entwined - Quick Look Trailer, (PS3)
- Blue Estate - Official Launch Trailer, (PS4)
- Goat Commando 3D Simulator - Gameplay, (iPhone-iPod)
- Munin - Official Launch Trailer, (iPad)


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Toyota Owners Club Of Ireland
The #1 Suzuki Intruder Owners Club on the internet and covers ALL models of the Suzuki Intruder / Boulevard / Volusia and Marauder motorcycles from the VL125 to the mighty M1800R / VZR1800R.
suzuki, intruder, club, owner, forum, m1800, #owners, vzr1800, iocuk, iocgb, vl1500, vs700, vs750, vs800, vs1400, c1800, c1800r, m109, m109e, m1800r, boulvard
The award winning number one club, for all MINI and Mini owners in Surrey and the surrounding areas. In fact, it doesn't matter where you're from, come and join in the fun!
Forum for ATOC (http://www. acetrainsownersclub. org. uk) members and anyone interested in all things ACE.
free, trains, #owners, club, forum, atoc, members, anyone, interested, things
The Christine Car Club is an international club where actual movie car, Christine clone owners and enthusiasts, and fans of the 1957 and 1958 Plymouth come together to pay tribute to Stephen King and John Carpenter's masterpieces. Released in 1983, b
christine, club, discussion, forums, movie, 1957, plymouth, 1958, fury, belvedere, savoy, plaza, stephen, king, john, carpenter, arnie, cunningham, lebay
SOUTH COAST COUGARS, The Club for all Ford / Mercury Cougar owners!
south, coast, cougar, cougars, southern, clubs, coups, classics, american, european, english, irish, scottish, welsh, cars, maintenance, servicing, mercury, forum, ford, sports, #owners, club, mondeo, kuga
A forum for Chevy HHR owners and those that want to own them
A forum for all the owners and enthusiasts of GM B-Bodies from 1965-1996, but dedicated to the owners of 1977-1979 Impalas and Caprices. Join up now!
Free forum : A forum for the responsible pickup enthusiast.
Tempat berhimpunnya owner-owner motor SYM VTS/GTS/EVO/BONUS/SYMPHONY untuk membincangkan hal-hal teknikal dan aktiviti.
force, motor, untuk, membincangkan, hal-hal, teknikal, aktiviti, mega, fortune, symphony, bonus, malaysia, otai, smbc, rider
Post-Apocalyptic Earth, the world is dark. Angels and Demons have returned to the Earth. Humans are in hiding, those who can't hide are servants for the immortals.
immortal, gates, post-apocalyptic, earth, world, dark, angels, demons, have, returned, humans, hiding, those, can't, #hide, servants, immortals
Welcome to Fusion-Scapez, owners are: Froep and Jurrian.The forums are made by Redrhodes and owned by Froep and Jurrian.Any Suggestions? feel free to pm us
fusion-scapez, welcome, #owners, froep, jurrian, forums, made, redrhodes, owned, suggestions?, feel, free
In a Colorado town, these shifters hide in plain sight. How long can they keep their secret?
champagne, supernova, colorado, town, these, shifters, #hide, plain, sight, long, they, keep, their, secret?
Harley Owners Guild forum where members can find the latest news about the guild and events.
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Free forum : The Ultimate VW Club in East Anglia Norfolk Cambridgeshire Lincolnshire Suffolk Vw Owners Club
free, dodgy, dubbers, ultimate, club, east, anglia, norfolk, cambridgeshire, lincolnshire, suffolk, #owners


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Region II Area Playoffs: Skyline finds end zone, hits hard; Longview ends McKinney Boyd run
Dallas Skyline's Daleon Ward (5), center, starts an endzone celebration as he is joined by receivers Savon Rollinson (18) and Carlos Strickland (9) following his first quarter touchdown reception in their game against Sachse. The two teams played their Class 5A Division l Region ll area round playoff game at the Cotton Bowl in Dallas on November 23, 2013.
Photo: Steve Hamm/Special Contributor
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Search results
|Your search produced 118 results.
Sponsored listings
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Absolace live at The Music Room
at The Music Room
The Dubai-based metallers – last spotted supporting Megadeth at Gulf Bike Week – play a one-off show
|Bur Dubai
|On Fri, Dec 21
Absolace live at The Music Room
at The Music Room
Dubai-based progressive rock band Absolace will play their last gig before the summer, supported by Anuryzm, the heavy-hitting group that gained much attention when they opened for Avenged Sevenfold in Abu Dhabi
|Bur Dubai
|On Fri, May 25
African Roots Bob Marley Tribute
at The Music Room
To mark the anniversary of Bob Marley's death tomorrow, there's a live musical tribute to the reggae legend tonight
|Bur Dubai
|On Fri, May 10
Amy Winehouse Tribute
at The Music Room
Gyp Kenton is the UK's most authentic tribute to Amy Winehouse! Vocally and visually, she is the Best!
|Bur Dubai
|On Fri, Sep 12
Antarctic Monkeys
at The Music Room
This playfully named tribute act have been playing all the Arctic's hits and misses to audiences of up to 50,000 across Europe since 2006
|Bur Dubai
|On Fri, Jun 15
Apache Indian Live
at The Music Room
Step back into the '90s and watch Apache Indian perform his classic hits including, 'Boomshackalak'
|Bur Dubai
|On Fri, Aug 15
BOOMBOX Presents DJ Yella (N.W.A.)
at The Music Room
DJ Yella (N.W.A.) performs at the Music Room
|Bur Dubai
|On Fri, Aug 23
Beatles Tribute
at The Music Room
Ready to Rock N'Roll with the BEST Beatles tribute in the world
|Bur Dubai
|On Fri, Jun 13
Ben Waters Live
at The Music Room
The UK's number one Rock N Roll pianist and his band come to Dubai to bring their fiery brand of Rock N Roll, Blues and Boogie!
|Bur Dubai
|On Fri, Sep 5
Black Sun Empire and Thelem at The Music Room
at The Music Room
Drum'n'bass giants Black Sun Empire, who recently topped the cross-genre beatport charts with fifth album From the Shadows, go head to head with dubstep talent Thelem for four hours of international bass madness
|Bur Dubai
|On Fri, Dec 14
Bombay Bassment
at The Music Room
'Indian's first live hip-hop band' make their UAE debut
|Bur Dubai
|On Fri, Jun 8
Boombox presents DJ Lord
at The Music Room
Member of rap outfit Public Enemy, DJ Lord will be jetting over to spin an evening of hip-hop tunes
|Bur Dubai
|On Fri, Oct 18
Boombox presents DJ Maseo
at The Music Room
DJ Maseo from hip-hop outfit De La Soul will be spinning classic hits including tracks from the group's album 3 Feet High And Rising along with tracks from A Tribe Called Quest and other rap acts of his era
|Bur Dubai
|On Fri, Sep 20
Boombox presents Hip Operation
at The Music Room
Remi Kabaka, the percussionist in Gorillaz and Banksy and Bobby Womak collaborator will be performing his GSS (Gorillaz Sound System)
|Bur Dubai
|On Fri, Nov 29
Boombox presents Jon Kennedy
at The Music Room
Drummer and Electronic musician
|Bur Dubai
|On Fri, Nov 22
Aks Xclusive
at Mansion
DJ Zubair hosts this new weekly desi night
|Bur Dubai
|DJ: Desi
AfroUrban Connexion – East Africa Edition
at The Music Room
Kenyan rapper DNA (which stands for 'Dreams 'n' Ambitions', apparently) is best known for 2006 hit 'Banjuka'
|Bur Dubai
|On Fri, Aug 31
|DJ: Hip hop, R&B & D&B
BOOMBOX Presents DJ Yella
at The Music Room
DJ Yella from the legendary Straight Out of Compton rap outfit NWA will be spinning his personal favourites
|Bur Dubai
|On Fri, Aug 23
|DJ: Hip hop, R&B & D&B
Bombay Bassment presented by Dream 6
at The Music Room
Bombay Bassment, India's award-winning troupe of hip-hop, rap and reggae artists who've previously opened for Snoop Dogg back home
|Bur Dubai
|On Fri, Mar 21
|DJ: Hip hop, R&B & D&B
Acoustic Jamboree
at The Music Room
Acoustic sets from six UAE acts, including Sam+Kurt and Red House
|Bur Dubai
|On Fri, Apr 12
|DJ: House & techno
Absolace – Friday 13
at The Music Room
Following their successful tour of India, the Dubai-base band will be rocking The Music Room with support from Beat Antenna and Point of View
|Bur Dubai
|On Fri, Sep 13
|DJ: Rock, retro & pop
Avial Live
at The Music Room
True to their name, Avial (a mixed-vegetable delicacy) blends Malayalam poetry with contemporary rock
|Bur Dubai
|On Fri, Aug 22
|DJ: Rock, retro & pop
Benevolent live
at The Music Room
The UAE-based Lebanese brothers will be bringing their brand of rock metal to the stage
|Bur Dubai
|On Fri, Sep 6
|DJ: Rock, retro & pop
Alternative Rock Festival
at The Music Room
A bill of seven promising local bands have been lined up for this night of all things dark and gritty
|Bur Dubai
|On Fri, May 17
|Live rock, retro & pop
Ben Waters Live in Dubai
at The Music Room
One of the UK's leading rock' n' roll pianist and his band will play a mix of rock, blues and boogie
|Bur Dubai
|On Fri, Sep 5
|Live rock, retro & pop
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In pictures: The 40 biggest gigs of the year Take a look back at the most memorable UAE concerts from the 2013/14 season
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There are a lot of Joneses because there have always been a lot of Jons. In the Middle Ages, children were given surnames related to their father's first name, such as Williamson for the son of William, which meant that the surname changed with each generation. Jones fits into this category, modified from the Middle… Read more
If you have a Smith in your family, you have a staggering 81 million records to pore through on Ancestry. Smith has long been the most common surname in both the United States and Great Britain. Each U.S. census lists more and more Smiths, from 274,919 in 1850 to 2,376,206 in 2000. Yet the name… Read more
Once upon a time, some of the greatest medical crises America faced included "tired blood" and "female weakness" — or so many patent medicines claimed. Between the end of the Civil War and the Great Depression, Americans spent millions of dollars on heavily advertised "natural" remedies whose claims of being free of addictive substances overlooked… Read more
You can choose your friends, but you can't choose your family, the saying goes. Throughout history, though, there have been particularly skilled and audacious con artists who've done a darn good job of faking membership in the family of their choosing. A few succeeded in passing as royal heirs to ascend a throne, some used… Read more
If you've been researching your family tree on Ancestry, chances are you've stumbled on a relative or two who has worked in agriculture or experienced the challenges of pioneer life. If you are looking to get a feel for how they actually lived, living history farms and museums scattered all across the U.S. that use… Read more
In German, a surname is called the "Nachname" or "Familienname." The family name gradually started being used during the Middle Ages. Prior to that, people generally used only a given name. As the population increased, though, that population needed a way to differentiate between all those new people. Now, those surnames can help you trace your family… Read more
Neolithic-era teeth found in modern-day Pakistan show evidence of having been drilled — with drills made of flint — and in a "remarkably effective" way, according to modern researchers who studied the 9,000-year-old teeth. Which goes to show that fear of going to the dentist probably predates written history. During the early Middle Ages in… Read more
Normally, the flu is regarded as a winter misery we endure. But the strain that circled the globe at the end of World War I proved one of the deadliest illnesses to strike humanity. "The 1918 flu epidemic puts every other epidemic of this century to shame," observed Gina Kolata in her book Flu. "It… Read more
New York Yankee captain Derek Jeter may have just retired from baseball and likely is heading for a a spot in the Hall of Fame, but before he said farewell to his pinstripes, he investigated his family tree to find out if his skills on the field had anything to do with his genetics. In… Read more
Not every dig into a family's past is going to come up with happy discoveries. Witness Kim Cattrall's episode of Who Do You Think You Are? a few years ago, when she found out that after her grandfather disappeared — leaving behind a wife and three daughters — he started a new family just 40… Read more


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I orderes the Masters Edition deck, a Tally Ho deck, Bobos Modern Coin Magic, and Expert at the Card Table. The prices are awesome. Very cheap. The...Read More ->
I had ordered a trick and when it showed up, it had instructions for a different trick. My first thought was, "Wow, this is going to be pain to...Read More ->


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AVS Club Gold
Join Date: Jan 1999
Location: Florida
Posts: 18,728
Mentioned: 0 Post(s)
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|Thread Tools
|You can notice the additional highs when the speakers are not behind a screen but unless doing a side by side those using an acoustic screen are fine but yes I do notice the difference.
Originally Posted by Tukkis
And how does the imaging sound? Is not having the sounds anchored to the screen noticeable?
Originally Posted by Tukkis
And how does the imaging sound? Is not having the sounds anchored to the screen noticeable?
Originally Posted by sfb
so how can they be blended with a subwoofer?
Originally Posted by sfb
Don't most receivers send everything below 80 Hz to the sub and the rest to the speakers when set to "small"? Seems like these speakers won't work well in this kind of set-up.
"Not throwing my hands up or my dress above my ears don't mean I ain't awestruck." Al Swearengen
Originally Posted by SirJohnFalstaff
I'm interested in a 100" High-Contrast Da-Mat screen for my Infocus 7205. I'm leaning toward the Cinema Contour, but am curious what the difference is between it and the Da-Snap?
Originally Posted by nate358
Has anyone used a HCDaMatte screen. It has a .8 gain and is what I need to bring my ftL down to 15 ftL. I got a sample and blacks look amazing. But I can't tell if it affects color. Thanks
Originally Posted by scottyb
ya get what ya pay for :)
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Romans Chapter 1 (1611 Bible)
Viewing the 1611 King James Version. Switch to the standard Romans Chapter 1 KJV or the Romans 1 KJV parallel comparison.
Why does the spelling look unusual?
View original 1611 Bible scan for Romans chapter 1
(this is a scan from the exact, authentic, original 1611 'HE' King James Bible)
1 Paul a seruant of Iesus Christ, called to bee an Apostle, separated vnto the Gospel of God,
2 (Which he had promised afore by his Prophets in the holy Scriptures,)
3 Concerning his Sonne Iesus Christ our Lord, which was made of the seed of Dauid according to the flesh,
4 And declared to be the Sonne of God, with power, according to the Spirit of holinesse, by the resurrection from the dead.
5 By whom we haue receiued grace and Apostleship for obedience to the faith among all nations for his Name,
6 Among whom are ye also the called of Iesus Christ.
7 To all that be in Rome, beloued of God, called to be Saints: Grace to you and peace from God our Father, and the Lord Iesus Christ.
8 First I thanke my God through Iesus Christ for you all, that your faith is spoken of throughout the whole world.
9 For God is my witnesse, whom I serue with my spirit in the Gospel of his Sonne, that without ceasing I make mention of you, alwayes in my prayers,
10 Making request, (if by any meanes now at length I might haue a prosperous iourney by the will of God) to come vnto you.
11 For I long to see you, that I may impart vnto you some spirituall gift, to the end you may be established,
12 That is, that I may be comforted together with you, by the mutual faith both of you and me.
13 Now I would not haue you ignorant, brethren, that oftentimes I purposed to come vnto you, (but was let hitherto) that I might haue some fruit among you also, euen as among other Gentiles.
14 I am debter both to the Greeks, and to the Barbarians, both to the wise, and to the vnwise.
15 So, as much as in mee is, I am ready to preach the Gospel to you that are at Rome also.
16 For I am not ashamed of the Gopel of Christ: for it is the power of God vnto saluation, to euery one that beleeueth, to the Iew first, and also to the Greeke.
17 For therein is the righteousnesse of God reueiled from faith to faith: as it is written, The iust shall liue by faith.
18 For the wrath of God is reueiled from heauen against all vngodlinesse, and vnrighteousnesse of men, who hold the trueth in vnrighteousnesse.
19 Because that which may bee knowen of God, is manifest in them, for God hath shewed it vnto them.
20 For the inuisible things of him from the Creation of the world, are clearely seene, being vnderstood by the things that are made, euen his eternall Power and Godhead, so that they are without excuse:
21 Because that when they knew God, they glorified him not as God, neither were thankefull, but became vaine in their imaginations, and their foolish heart was darkened:
22 Professing themselues to be wise, they became fooles:
23 And changed the glory of the vncorruptible God, into an image made like to corruptible man, and to birdes, and foure footed beasts, and creeping things:
24 Wherefore God also gaue them vp to vncleannesse, through the lusts of their owne hearts, to dishonour their owne bodies betweene themselues:
25 Who changed the trueth of God into a lye, and worshipped and serued the creature more then the Creatour, who is blessed for euer. Amen.
26 For this cause God gaue them vp vnto vile affections: for euen their women did change the naturall vse into that which is against nature:
27 And likewise also the men, leauing the naturall vse of the woman, burned in their lust one towards another, men with men working that which is vnseemely, and receiuing in themselues that recompense of their errour which was meet.
28 And euen as they did not like to retaine God in their knowledge, God gaue them ouer to a reprobate minde, to doe those things which are not conuenient:
29 Being filled with all vnrighteousnes, fornication, wickednesse, couetousnes, maliciousnes, full of enuie, murther, debate, deceit, malignitie, whisperers,
30 Backbiters, haters of God, despitefull, proude, boasters, inuenters of euill things, disobedient to parents;
31 Without vnderstanding, couenant breakers, without naturall affection, implacable, vnmercifull;
32 Who knowing the iudgement of God, (that they which commit such things, are worthy of death) not onely do the same, but haue pleasure in them that doe them.
View All Romans Chapter 1 Comments...
Divine's Romans Chapter 1 comment about verse 1 on 11/04/2014, 12:36pm...
i read this a verse every day i love this web site thank you
Evangelist Chatauna Robinson's Romans Chapter 1 comment on 10/27/2014, 10:53am...
I would like to add one more comment to my 2 part response. Deuteronomy 25 16 For all that do such things, and all that do unrighteously, are an abomination unto the LORD thy God. In the scriptures you will further find more things that God hat. 1 Corinthians 6 9 10 Know ye not that unrighteous shall not inherit the kingdom of God? Be not deceived neither fornicators, nor idolaters, nor adulterers, nor effeminate, nor abusers of themselves with mankind, Nor thieves, nor covetous, nor drunkards, nor revilers, nor extortioners, shall inherit the kingdom of God.
Evangelist Chatauna Robinson's Romans Chapter 1 comment on 10/27/2014, 10:46am...
Part 2 of 2 Let us first look at what does abomination mean, an abominating great hatred and disgust loathing, anything hateful and disgusting. The adjective of abomination is abominable which mean nasty and disgusting vile loathsome highly unpleasant disagreeable very bad. The word adjective carries the definition of quantity according to Webster Dictionary therefore, meaning any indeterminate bulk a lot . According to the scripture the word abominable are the things many, in bulk that are hateful to God. God hates sin. Even though people want to argue that homosexuality is not listed in Revelation, this still does not negate the fact that homosexuality is listed in bulk with other sins under the word abominable.
Evangelist Chatauna Robinson's Romans Chapter 1 comment on 10/27/2014, 10:40am...
Part 1 of 2 Hello James Linn The act of homosexuality is not the only sin that God does not like. Hebrews 13 4 Marriage is honourable in all, and the bed undefiled but whoremongers and adulterers God will judge. In Revelation 21 8 But the fearful, and unbelieving, and the abominable, and murderers, and whoremongers, and sorcerers, and idolaters, and all liars, shall have their part in the lake which burneth with fire and brimstone which is the second death.
James Linn's Romans Chapter 1 comment about verse 31 on 10/24/2014, 10:29am...
Covenent breakers of today those who divorce their husband or wife outside the boundaries Jesus gave.
Evangelist Chatauna Robinson's Romans Chapter 1 comment on 10/08/2014, 1:29pm...
Hello John, In addition to the comments that I have made which I hope gets printed here is one more. In verse number 20 when God said, And the LORD said, Because the cry of Sodom and Gomorrah is great, and because their sin is very grievous If I can say it like this notice the word sin there is no s on it to indicate plural or many sins. The focused seemed to have been on the one particular sin. That was the desire of men with men. Homosexuality. When the LORD said in verse 21 I will go down now, and see whether they have done altogether according to the cry of it, which is come unto me and if not, I will know . The scripture stated it , referring back to sin being singular. The only thing sin or it focused on that night was those men asking and wanting to have the angels of God which were men. They did not want the women that Lot offered them. They wanted the men. Think about this, if their intentions were honorable why did Lot offer his virgin daughters? This is continue with the next Genesis 19.
Evangelist Chatauna Robinson's Romans Chapter 1 comment on 10/08/2014, 1:18pm...
In addition to my other comment, in Romans Chapter 1 it states Verse 24 Wherefore God also gave them up to uncleanness through the lusts of their own hearts, to dishonor their own bodies between themselves Verse 26 For this cause God gave them up unto vile affections for even their women did change the natural use into that which is against nature. Verse 27 And likewise also the men, leaving the natural use of the woman, burned in their lust one toward another men with men working that which is unseemly, and receiving in themselves that reompence of their error which was meet. I ask again what is Homosexuality? Homosexuality is men having sex with men, women having sex with women. This is what these scriptures are talking about. For this God turned them over to a reprobated mind.
Evangelist Chatauna Robinson's Romans Chapter 1 comment on 10/08/2014, 1:12pm...
Hello John, What is Homosexuality? It is a man having sex with a man. It is a woman having sex with a woman. Homosexuality was used as a punishment for those who corrupted God 's Word and changed the glory of the uncorruptible God. God turned them over to a reprobated mind. A mind that is condemned or a totally lost soul. Romans Chapter 1. So why would God use Homosexuality as a punishment and then turn around and okay it for humans to do? God destroyed Sodom and Gomorrah for this sin. The men of those cities did not want the daughters of Lot, even after Lot offered the daughters to them. They wanted the angles, the men of God. I do not think they wanted to have a conversation with them, because if they did then I sure that the angels would not have blinded them. Read my answer under Genesis Chapter 9.
View All Romans Chapter 1 Comments...
What Do You Think of Romans 1?
Share your own thoughts or commentary here...


text:
Is Bess still around?
Find a Conversation
Is Bess still around?
|Thu, 01-19-2012 - 4:20pm
Just curious....I haven't seen her on the board in a long time and was anxiously awaiting to hear what gender she found out at her ultrasound last month. I hope everything is okay!
|Thu, 01-19-2012 - 9:13pm
There are a few ladies that disappeared around the holidays and I was hoping they would be back once things calmed down.
Check in if you are still around Bess!
Check in if you are still around Bess!
|Sat, 01-21-2012 - 1:15am
Totally wondering about her too....I don't have a computer just a phone so I don't learn everyone name. Because the siggys dont show up. Just their member name. :(
|Sun, 01-22-2012 - 11:28am
I haven't seen here around here but have her on my FB list - I'll give her a nudge to come update. :)
|Mon, 01-23-2012 - 8:26am
Oh Hey Ladies!!!!! Thanks for thinking about me and sorry that I been MIA. Ive just been caught up in stuff and am in groups on Facebook too. I promise to try to pop into here more often again, though. :)
|Mon, 01-23-2012 - 9:53am
Sorry to hear about the girls :( sick kiddos are no hfun.
Hopefully you don't get it.
Yes....please keep us updated! !!!!
Hopefully you don't get it.
Yes....please keep us updated! !!!!


text:
Remember Me
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11/24/2014Despite Signs on Economic Improvement, Consumers Unlikely to Increase Holiday Spending
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The Old Tollgate Hotel & Restaurant
Call us 01903 879 494
Bramber Village • Steyning • Near Brighton • West Sussex
© Old Tollgate Hotel 2014 • Registered in England 1161846 • Registered Office: Old
Tollgate Hotel • The Street • Bramber • Steyning • West Sussex • England • BN44 3WE
The world's biggest hotel family ® • Each Best Western ® branded hotel is independently
owned and operated • bestwestern.co.uk Best Western Rewards
Hotel Near Brighton • Hotels Near Brighton • West Sussex Hotels • Steyning Hotels
• Wedding Reception Venues West Sussex • Wedding Venues West Sussex
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The Old Tollgate is an ideal place to stay when visiting the magnificent South Downs
National Park, where you can walk, cycle or horse ride along the South Downs Way.
Discover more >>>
There is plenty of free parking available at The Old Tollgate.Plan your journey here
Ideally located when visiting:
1 mile
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Enjoy a Main Coursefrom just £6.50 on selected days this monthlunch & dinner. Additional
courses £5.75Grab your Voucher and book a table today....
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BEST WESTERN The Old Tollgate is one of the best located hotels Steyning and West
Sussex has to offer. Set within the quaint sleepy village of Bramber, near Brighton
and on the doorstep of the South Downs National Park and South Downs Way, you can
expect wonderful customer service and comfort whilst enjoying the hotel's old worldly
What does The Old Tollgate Offer?
The Old Tollgate has been awarded the BEST WESTERN International Quality Award. A
global recognition of excellence given to only a few selected hotels throughout the
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AwardedFour YearsRunning


text:
Worked All States Award
The Worked All States (WAS) Award (certificate) is earned by confirming QSOs with all 50 states. It was first introduced in the January 1936 issue of QST. Click here to view a reprint of the original announcement and here to view the first list of Charter Members of WAS as published in April 1936 QST.
Worked all States confirmations can be submitted on paper cards, via Logbook of the World or a combination of both. This combination is called a Hybrid Application. The cost of the award is $10 per award certificate or $15 for a certificate and a WAS pin. ARRL membership is required to receive the Award for all amateurs in the USA and its possessions. For amateurs outside of the USA, ARRL membership is not required. Non-USA amateurs should review the General Certification Rules (GCR) for application WAS card checking in your country. Here are the complete rules for earning the Worked All States award.
Along with the basic WAS Certificate, there are endorsements for any combination of bands and/or modes (excluding 60 Meters). Certificates are available for different bands and modes such as Satellite, 160-meters, SSTV, Digital, Phone and each individual band. Except for Phone and the generic Digital award, all other certificates will be both dated and numbered. Endorsements cost $7.50 and include CW, Novice, QRP, EME and any single bands.If multiple endorsements are all done on the same application only a one-time $7.50 fee applies. Applicants can complete just one application form and note the multiple awards and/or endorsements they are requesting. Applicants should attach a record sheet for each award or endorsement. While endorsement categories are $7.50 applicants can choose to have an endorsement category registered as an award instead of endorsement. In this case, award certificates are $10 each rather than $7.50.
Paper QSL cards can be checked by an approved ARRL HF Awards Manager or DXCC Card Checker. In the event you cannot find a card checker nearby, the WAS application and QSL cards can also be sent to ARRL Headquarters in Newington, Connecticut.
WAS lapel pins can be ordered by checking the appropriate box on the paper application, however, there is no check box for the pin on LoTW applications. If you submit an application via LoTW and you would like the pin, please note, on the lower portion of the 'field check list' form that you would like to add the lapel pin to your order and add the $5.00 for the pin to the credit card you noted for payment. If you are sending a check for payment instead of a credit card, be sure to add an additional $5.00 to your check for the pin.
5 Band Worked All States
A 5-Band WAS Certificate, is available for working all 50 States on the 5 primary amateur bands. Applications for the 5 Band WAS must contain confirmation of 50 states on 10, 15, 20, 40 and 80 Meters. After achieving the initial 5 Band WAS, it can be endorsed on the remaining amateur bands with all 50 states required for each endorsement band.
Cards for 5-Band WAS can be checked by your local HF Awards Manager, DXCC Card Checker or at ARRL Headquarters. The cost for the 5-Band certificate is $10.00. A separate lapel pin is available for this award for $5.00. When doing LoTW application there is a LoTW QSO fee per QSO. A per-QSO fee is not assessed for paper-only applications.
A wall plaque is also available for 5 Band WAS. The cost of the plaque with shipping in the United States is $60.00. For International mailings, the cost is $80.00. A 5-Band WAS lapel pin is also available for $5.00. The order form for the plaque and pin can be found here. Applicants can forward it by postal mail, FAX or even by e-mail.
5 Band WAS cards and applications should be mailed to ARRL Headquarters, at the address below. We strongly recommend a traceable method of mailing.
WAS Award
c/o ARRL HQ
225 Main Street
Newington, CT 06111


text:
Haleiwa Long Term Condo Rentals(9)
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View all 96 Haleiwa Vacation Rentals or all 885 North Shore Oahu Vacation Rentals
Recent Haleiwa Reviews
Great spot for the North Shore
This is a great location if you're planning to spend time in the North Shore, you can pretty much walk to Haleiwa if you'd like to check out the stores and restaurants, or just bring some food in and enjoy it on the balcony overlooking the ocean. It's a great spot for snorkeling, I accidentally almost ran into Slowpoke (I call him that), he's the biggest of 2 turtles that was hanging out every day right at the front of the house. The other guy Speedy is a little smaller and is probably Slowpoke's offspring. This is a good spot to go during the windy months, since there's no AC, but when we were there, the breeze would keep the bedroom side cool and the fans were helpful. The bathrooms looked pretty new, the two beach chairs which you can use is perfect for when you just want to hang out by the beach. There's a lot of utensils in the kitchen and the flooring is just right for you to walk on without having to bring in any shoes. The hallways do carry sound, so the neighbors know to try to stick to the quiet time of 10pm to 8am, or something like that. It was a good place to start our trip.
Slice of Heaven
This condo has everything you need for a get away to Hawaii. The condo is fully loaded with kitchen supplies, beach supplies, technology, laundry and parking. The best was being steps away from the beach and not needing to keep up with a key to the condo. Everything about the property is easy to access. The lovely town of Haleiwa is a treat to explore. Great location to either enjoy the amenities that are right in your back yard or to go exploring.
Guestbook Comment
May 2007. Great condo! Perfect location. We didn't want to leave. I miss drinking my morning coffee on the beach and seeing the turtles swimming. Bob & Suzanne are really great and the food at Spaghettini's was awesome! We would highly recommend staying here!


text:
Urinary benzylmercapturic acid as a marker of occupational exposure to toluene
- Osamu Inoue,
- Etsuko Kanno,
- Toshiharu Yusa,
- Masaei Kakizaki,
- Hirohiko Ukai,
- Satoru Okamoto,
- Kae Higashikawa,
- Masayuki Ikeda
- … show all 8 hide
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Objective: To examine if benzylmercapturic acid (or N-acetyl-S-benzyl cysteine) in urine can be used as a marker of occupational exposure to toluene. Methods: A factory survey was conducted in the latter half of a working week. A group of 46 men, who volunteered for the study, was engaged in ink preparation, surface coating or printing work. Diffusive samplers were used to measure average solvent exposure in an 8-h shift. End-of-shift urine samples were analyzed for benzylmercapturic acid (BMA) by a modification of an HPLC method originally developed for phenylmercapturic acid determination. Results: The workers were exposed primarily to toluene [TOL; 13 ppm as the geometric mean (GM) and 86 ppm at the maximum] together with isopropyl alcohol (<1 and 4 ppm), ethyl acetate (2 and 127 ppm) and methyl ethyl ketone (2 and 142 ppm). BMA in urine correlated closely [correlation coefficient (r) =0.7] with TOL in air, irrespective of correction for urine density. The lowest TOL concentration at which urinary BMA increased to a measurable level was approximately 10 ppm, and urinary BMA could separate the exposed from the non-exposed when TOL exposure was 15 ppm or higher. Conclusions: BMA in end-of-shift urine samples is a good marker of occupational TOL exposure. Urinalysis for BMA is sensitive enough to detect TOL exposure at 15 ppm, and therefore BMA appears to be more sensitive than hippuric acid and possibly o-cresol as a urinary marker of TOL exposure.
- Title
- Urinary benzylmercapturic acid as a marker of occupational exposure to toluene
- Journal
International Archives of Occupational and Environmental Health
Volume 75, Issue 5 , pp 341-347
- Cover Date
- 2002-06-01
- 10.1007/s00420-002-0322-8
- Print ISSN
- 0340-0131
- Online ISSN
- 1432-1246
- Publisher
- Springer-Verlag
- Additional Links
- Keywords
- N-Acetyl-S-benzyl cysteine Benzylmercapturic acid Biological monitoring Toluene Mercapturic acids Urinalysis
- Industry Sectors
- Authors
- Osamu Inoue (A1)
- Etsuko Kanno (A1)
- Toshiharu Yusa (A1)
- Masaei Kakizaki (A1)
- Hirohiko Ukai (A2)
- Satoru Okamoto (A2)
- Kae Higashikawa (A2)
- Masayuki Ikeda (A2)
- Author Affiliations
- A1. Tohoku Rosai Hospital, Japan,
- A2. Kyoto Industrial Health Association, 67 Nishinokyo-Kitatsuboicho, Nakagyo-ku, Kyoto 604-8472, Japan,


text:
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text:
20 level
SodaHead Guru
Spawn of Satan
All of the above.
Schumer throws Obamacare under the bus.
Other (please explain).
Where Do the Ultra-Rich Live?
Los Angeles
What executive order?
I have another idea.
Americans are stupid?? Or are Americans trusting and forgivin...
I think ......
Public school pupils seen but not heard
I have another idea.
Gruber exposes Romney
I have another idea.
Obamacare passed with lies
All of the above.
Smart Growth a Dumb Deal for the PoorMore
Yes. Smart growth isn't so s...
likes & interests
About Me
I served in the Marines and U.S. Navy, a total of 22 1/2 years. I finished up for my bachelor's degree in engineering and math while in the Navy, and completed three years of night law school at my last shore-duty station before retiring. I got my JD (juris doctorate) about six months after I retired and passed the California Bar Exam the first time I took it. I spent 27 years practicing law, mostly defending civil law suits.
Walking, reading, research on subjects that interest me
Favorite Music
NIkki Yanofsky - This little girl from Canada (now 17) has more talent than all of the "American Idol" winners combined. Of course I'm partial to jazz and loved Ella Fitzgerald.
http://www.youtube.com/watch?... (Djsut 12 yrs. old in this one)
http://www.youtube.com/watch?... (2008, I think she's 15 in this one)
http://www.youtube.com/watch?... (Take The "A"Train)
http://www.youtube.com/watch?... (Djsut 12 yrs. old in this one)
http://www.youtube.com/watch?... (2008, I think she's 15 in this one)
http://www.youtube.com/watch?... (Take The "A"Train)
Favorite TV Shows
The Good Wife - most accurate court room trial scenes I've seen.
"Castle" - two very appealing lead actors, with (usually) good stories and scripts
"Castle" - two very appealing lead actors, with (usually) good stories and scripts
Favorite Books
PIllars of the Earth (Ken Follett), Winds of War, War and Remembrance (Herman Wouk)
Favorite Quotes
"A nation trying to spend itself out of poverty is like standing in a bucket and trying to lift yourself up by the handle." Winston Churchill
"If you're not a liberal at twenty you have no heart, if you're not a conservative at forty you have no brain." Winston Churchill
"If you're not a liberal at twenty you have no heart, if you're not a conservative at forty you have no brain." Winston Churchill
Favorite Heroes
Winston Churchill, James Madison, Thomas Jefferson
DJ 2014/11/02 20:33:20I'm delighted to be among your friends.
snell/GOD & COUNTRY-zero cl... 2014/07/04 18:46:57
Force Recon Team ~ Marine Red 2014/05/31 01:28:04 (edited)moderated...
Sheila 2014/04/17 20:09:33
Ken 2014/03/18 01:25:45Same to you - I had my "traditional" corned-beef and cabbage.
56lady☆POTL JLA BTO-t- BCRA... 2014/03/17 23:31:35Happy St. Patty's Day My Friend ♥
Blessings & Hugz ♥
Chi~Cat 2014/02/02 19:59:24LOL@stealth~!
Chi~Cat 2014/02/02 19:34:00Hey, Ken~
Thanks! Again!
remy 2014/01/14 07:21:54Hi Ken! I hope you and yours had a wonderful Christmas and a Happy New Year!
Ken 2014/01/01 05:43:39Thanks to you too, and a Happy and prosperous New Year to you and your family!
snell/GOD & COUNTRY-zero cl... 2014/01/01 03:02:30....thax for all your support over the years - snell
56lady☆POTL JLA BTO-t- BCRA... 2013/12/24 18:42:32
Buster Brown 2013/11/09 23:43:10
Biki~pwcm/potl~ 2013/10/25 19:52:13Thanks for keeping it real here on Sodahead...
3750339 2013/10/13 23:57:10My grandfather hailed from Twin Falls worked the railroad through the Depression.
Drageona 2013/10/13 17:59:37Raved all your photos hope you like some of mine.
snell/GOD & COUNTRY-zero cl... 2013/10/11 20:17:12
AlliePonie 2013/08/17 20:48:17I may not agree with everything you have to say, but I think you are a pretty awesome guy. You were so kind to me and you took the time to explain your points to me rather than using name calling as a way of debate. Truly you are probably one of the nicest people I have met on here. I just wanted to say thanks. It's been a pleasure talking with you. :)
Ken 2013/07/12 17:23:23LOL, in the courts I've tried cases in the judge would be doing more than just instructing him. My partner almost got held in contempt of court for pursuing an objection the judge had overruled.
PrettieReptar 2013/07/12 16:00:51
Lol! Hope you're having a good day Ken...
Areas of Interest
Ken's activity, per category
89% News & Politics
3% Entertainment
3% Living
4% Fun
2011/04/06 21:18:55
1 day ago
August 02
photos & videos
- answered Spawn of Satan
- raved Schumer throws Obamacare under the bus.
- answered Schumer throws Obamacare under ...
- answered Where Do the Ultra-Rich Live?
- 13 replies to question Blatant Media Bias: ...
- answered What executive order?
- 3 shares of This is NO JOKE! Seeking Diversity, ...
- 2 replies to question This is NO JOKE! See...
- replied to question Americans are stupid?...
- shared Say What??? Dumbocrat Sheila Jackson ...


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More Information About Uralsk Travel
KAYAK searches hundreds of sites to find the cheapest flights to Uralsk (Kazakhstan). Get the best price for your airline ticket to Uralsk! Here's how it works. Search KAYAK for a flight to Uralsk. Sort, filter, and compare results on one web page. Then book your flight ticket direct on the airline or travel agent site of your choice!


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Online Round 2 Recipe - Cajun Red Bean and Rice Soup
- Total Time:
- 15 min
- Prep:
- 5 min
- Cook:
- 10 min
- Yield:
- 4 servings
- Level:
- Easy
- 4 cups chicken broth
- 1 teaspoon Cajun seasoning
- 1 teaspoon hot sauce
- Reserved 1 1/2 cups Chicken Jambalaya
- 1 (15-ounce) can red kidney beans, drained and rinsed
- Kosher salt and freshly ground black pepper
- 2 scallions, sliced
In a medium saucepan over medium heat, add the broth, Cajun seasoning, and hot sauce and bring to a simmer. Stir in the jambalaya and beans and cook until hot, about 5 minutes. Taste and adjust the seasoning with salt and pepper. Serve, garnished with scallions.
Recipe courtesy Sandra Lee
CATEGORIES:View All
More Recipes and Ideas
Round 2 Recipe - Chili Tostada
Recipe courtesy of Sandra Lee
Rice and Bean Salad
Recipe courtesy of Food Network Kitchen
Charred Red Onion and Balsamic Vinegar White Beans
Recipe courtesy of Emeril Lagasse


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