text:
Implementation Science is an open access, peer-reviewed online journal that aims to publish research relevant to the scientific study of methods to promote the uptake of research findings into routine healthcare in clinical, organisational or policy contexts.
- Anne Sales, Department of Veterans Affairs and University of Michigan
- Michel Wensing, Radboud University Nijmegen Medical Centre
Founding Editors-in-Chief
- Martin Eccles, Newcastle University
- Brian Mittman, VA Greater Los Angeles Healthcare System
Research funder required research partnerships: a qualitative inquiry
Study protocol
Improving outcomes of hospitalized patients: the Physician Relationships, Improvising, and Sensemaking intervention protocol
Study protocol
Evaluation of a health systems knowledge translation network for Africa (KTNET): a study protocol
Implementation of multidimensional knowledge translation strategies to improve procedural pain in hospitalized children
A complementary marriage of perspectives: understanding organizational social context using mixed methods
Systematic review
Using the Knowledge to Action Framework in practice: a citation analysis and systematic review
Leveraging practice-based research networks to accelerate implementation and diffusion of chronic kidney disease guidelines in primary care practices: a prospective cohort study
Manifestations and implications of uncertainty for improving healthcare systems: an analysis of observational and interventional studies grounded in complexity science
Study protocol
Protocol for the economic evaluation of the diarrhea alleviation through zinc and oral rehydration salt therapy at scale through private and public providers in rural Gujarat and Uttar Pradesh, India
Potential determinants of health-care professionals' use of survivorship care plans: a qualitative study using the theoretical domains framework
- View more articles
Congratulations to all... Delighted to see such an international panel of reviewers -- 18 countries are represented! Best wishes for a productive and scholarly 2014.
Figure 1. Title Please note that the title for Figure 1. should read: Anticipated timeline of the research design: Methodology and sub-aims for each stage of the project.
New reporting statement (CONSORT extension) to guide intervention reporting We read this paper of the reporting of smokingcessation interventions with interest. Of relevance to the Discussion in thepaper, readers may wish to know of a new initiative/reporting statementpublished earlier this year, around the time this paper was under review. Thenew guide is called TIDieR (Template for Intervention Description andReplication) and is aimed at improving the reporting of interventions in anyevaluative study design, particularly randomised trials.TIDieR is an official extension to the CONSORTand SPIRIT statements. The checklist and explanatory paper are freely available(BMJ, 2014, 348:g1687) and a Word version of the checklist can be downloadedfrom the EQUATOR Network (under Reporting guidelines, then TIDieR).
Useful resources
Latest news
A Call for Abstracts has been posted for the 7th Annual Conference on the Science of Dissemination and Implementation, 8–9 December 2014. The deadline for abstracts is 8 August.
We are proud to announce that Martin Eccles, Founding Editor of Implementation Science, received the BioMed Central Editor of the Year Award 2012.
Latest review
Systematic review
Are multifaceted interventions more effective than single-component interventions in changing health-care professionals' behaviours? An overview of systematic reviews
Are multifaceted interventions more effective than single-component interventions in changing health-care professionals' behaviours? An overview of systematic reviews
Implementation Science 2014, 9:152
Nordic Implementation is an interest group promoting knowledge exchange in the field of implementation research and working towards a continuation of the research-oriented Nordic Conference on Implementation of Evidence-Based Practice. Interest group members may disseminate information on their activities via the newly launched website.
Study Protocol Policy
Study protocols describe proposed or ongoing research, providing a detailed account of the hypothesis, rationale, and methodology of the study. The work described should have been funded through competitive external peer review and have appropriate ethics permissions. Systematic review protocols should be submitted to Systematic Reviews.
Editor's profile
Robbie Foy
Robbie Foy is Deputy Editor-in-Chief of Implementation Science. He has been a member of the editorial team since the journal started in 2006.
Robbie is Professor of Primary Care at the Leeds Institute of Health Sciences and a family physician in inner-city Leeds. His research aims to inform policy decisions about how best to use resources to improve the uptake of research findings by evaluating approaches to change professional behaviour. He is also trained in health services research and public health. He was a 2006-7 Harkness and Health Foundation Fellow in Health Care Policy, based jointly between the Veteran's Administration and RAND in Los Angeles.
Indexed by
- EmCare
- PubMed
- PubMed Central
- Science Citation Index
- Science Citation Index Expanded
- Scopus
- Social Sciences Citation Index


text:
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West Ham boss Sam Allardyce believes Diafra Sakho's back injury may have simply been caused by travelling to and from international duty.
Manchester United manager Louis van Gaal has confirmed that Angel Di Maria and David De Gea are fit for Saturday's showdown with Arsenal.
Hull City defender Michael Dawson has urged his former club Tottenham to stick with Mauricio Pochettino – even though it was the Argentine who axed him during the summer.
West Ham manager Sam Allardyce is confident the Hammers will survive a 'demanding situation' in January when his squad will be dismantled.
Read our round-up of the latest transfer news and gossip from around the web.
Louis van Gaal's selection problems have deepened after it emerged Manchester United striker Radamel Falcao will be out for at least a fortnight because of a new injury.
Jack Wilshere claims Arsene Wenger will not allow him to play in his favoured deep-lying midfield role for Arsenal.
Fulham manager Kit Symons has warned West Ham that the Whites do not have to sell anyone with the Hammers keen on Dan Burn.
Les Ferdinand says he is happy to let Harry Redknapp have the final word on QPR's January signings after the manager insisted his role would be "undermined" by someone else choosing his players.
Arsenal face Manchester United in what is one of the most-anticipated games of the season on Saturday. London24 Sport have taken a selection of pictures from past meetings to document the history between the two sides.
Arsenal duo Laurent Koscielny and Mathieu Debuchy have moved a step closer to returning from injury, Arsene Wenger has revealed.
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The club said the reaction following their decision to allow Evans to train had been at an intensity they did not anticipate.
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YouTube star defied gravity as he cycled the 16-feet loop.
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More Videos...
1100hp "Lambo Killer" GT-R 140MPH Ride-along - Texas Invitational
TI DVD/Blu Ray - http://www.1320video.com I've ridden in a lot of cars,
this car rides and pulls soooo smooth for laying down 1100awhp to the
ground. During the Texas Invitational King of the Streets shootouts he was
matched up against two of the Underground Racing TT Lamborghini Gallardo's
and had some luck with one spinning bad around 60-80MPH and the other
mis-shifting, but would have put up a good fight if you notice the MPH on
the 1500hp+ black car.
Car built by http://www.t1racedevelopment.com/
GTR R35 making 1000+whp built by MC-PERFORMANCE
MC-PERFORMANCE Latest 1200HP Setup
Fully built setup making 1000+whp with more Boost this setup will make 1100+whp..
Pump Gas 830whp / Race Gas 1064whp
Nissan GTR R35 Wrapped in Silver Chrome By Impressive Wrap
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Lamborghini Murcielago and Nissan GTR Black Edition
A 2005 Lamborghini Murcielago with secondary cats delete, muffler delete, &
sport filters and a 2012 Nissan GTR Black Edition with a Kreissieg
Valvetronic Exhaust System go for a
little cruise :)
BrianZuk's Facebook Here!
Nissan GT-R R35 acceleration sound - Cars and Coffee, Paris, France
Nissan GT-R R35 acceleration sound - Cars and Coffee, Paris, France
Nissan GTR 545 hp Tuning Nurotag 2013 Miami.
NRTG2KXIII will kick off in Miami and continue to Orlando, Virginia,
Chicago, and will return to Miami to conclude with the nurotag All Star
show in November 2013.
Supercars at Geneva motor show 2014
McLaren P1 with DoctaM3 at Geneva 2014
Bugatti Vitesse Legend 'Rembrandt Bugatti' at Geneva 2014
Maserati Alfieri Concept at Geneva 2014
Alfa Romeo 4C Spider
Aston Martin Centennial Zagato at Geneva 2014
Ferrari California T
Koenigsegg One:1 at Geneva 2014
Lamborghini Aventador Roadster 'Ad Personam' at Geneva 2014
Morgan Plus 8, 3 Wheeler, Aero Super Sport at Geneva 2014
1600hp Mansory Carbonado GT Aventador at Geneva 2014
Porsche 919 Hybrid LMP1 Car at Geneva 2014
TechArt 911 turbo S, Magnum, Grand GT at
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Hamann Nervudo Aventador at Geneva 2014
Nismo GT-R at Geneva 2014
FAB Design McLaren P1 at Geneva 2014
Yellow Pagani Huayra at Geneva 2014
McLaren 650S Spider at Geneva 2014
Mansory Vivere Bugatti Veyron at Geneva 2014
McLaren 650S Coupe at Geneva 2014
Lamborghini Huracan LP610-4 at Geneva 2014
Nimrod Zero Ferrari 458 at Geneva 2014
Red Chrome Gumpert Apollo S at Geneva 2014
Pagani Zonda Revolucion at Geneva 2014
Nimrod AvantiRosso Aventador at Geneva 2014
More news from supercar world
Lamborghini Egoista Concept Unveiled.The Lamborghini Egoista Only Needs One
Seat To Be Amazing.
Lamborghini concludes its 50th anniversary celebrations with the unveiling
of the Apache helicopter-inspired Egoista Concept.
Lamborghini concludes its 50th anniversary celebrations with the unveiling
of the Apache helicopter-inspired Egoista Concept.
This news is so breaking it's not even on Lamborghini's press site just
yet. In celebration of its 50th anniversary, the Italian automaker has just
unveiled the Egoista Concept. It looks amazing but here's the catch: it has
just one seat and its name translates to "selfish" in Italian, hence only
one person can enjoy it at a time. According to Jalopnik, the Egoista's
interior design was inspired by the Apache attack helicopter's single-seat
cockpit layout and the overall design, inside and out, was handled
personally by VW design chief Walter de Silva.
Power reportedly comes from a 5.2-liter V10 that makes around 570 horsepower. Other sources
claim the supercar is extremely lightweight thanks to an abundance of
carbon-fiber and the cockpit canopy can even be removed. No other details
are available just yet but we'll bring them to you as soon as we have them.
In the meantime, enjoy this one official image along with a number of live
shots first posted on the Teamspeed forum.
Lamborghini Egoista - Closing Canopy & Engine Start
More news from supercar world
Supercar Lamborghini Veneno combines jet fighter looks with a 552kW V12
capable of rocketing it from 0-100km/h in 2.8 seconds.
Lamborghini has released its fastest, most powerful road car
ever,Lamborghini Veneno
Lamborghini says it will sell only three of the Veneno supercars, one red,
one white and one green -- each representing one of the colours on the
Italian flag.
Supercar combines jet fighter looks with a 552kW V12 capable of rocketing
it from 0--100km/h in 2.8 seconds.
Now been officially unveiled ahead of its showing at the 2013 Geneva motor
For more visit: http://news.drive.com.au/drive/motor-...
El Lamborghini Veneno que debutará mañana en el Salón de Ginebra 2013 ha
hecho hoy su preestreno en la Volkswagen Group Night, un evento en el que
el grupo alemán ha presentado sus principales novedades. Únicamente se
construirán tres unidades del Lamborghini Veneno
Lamborghini Veneno SOUND - Start Up and REVS!!
Start of the 2013 Gumball 3000 Rally - Copenhagen
Today we were in Denmark at the start of the Gumball 3000 2013 rally 15th
Anniversary. Enjoy the Video! Ballers on the run!
Lamborghini Murcielago vs. Nissan GT-R Street Race
Facebook http://on.fb.me/MvsGTR | Tweet! http://bit.ly/GTRvsM
READ: The other day in Mexico - Me and Amy lined up my Lamborghini
Murcielago (Full Larini Exhaust) vs.
the Nissan GT-R Premium (Cobb Y-Pipe & AccessPort). I was very surprised by
the outcome! I thought it'd be the exact opposite...the GT-R would pull
down low then the Murcielago at higher speeds, but not so.
In terms of production quality I think this is probably one of my best
videos to date. If you enjoyed it definitely let me know so I can create
more like it :)
Facebook: http://on.fb.me/RHPage
Twitter: http://bit.ly/RHTweets
Razzi: http://razzi.me/Robert
Instagram: @RobertHimler
1100whp Nissan GT-R in Dubai
1000+ HP Nissan GTRs in Dubai!
BMW M5 F10 vs Nissan GT-R R35 (both stock)
Info Publikevent på gtboard.com BMW M5 F10 DCT vs Nissan GT-R R35 (both
tuned Nissan GTR with over 1200 HP!
This was a special presentation of that infamous car for the members of the
GTROC (www.gtroc.org) during the GTROC Japan Tour 2012.
The TRUST company was so kind to invite the GTROC to come and visit the
TRUST facility and have a first hand look at the unbelievable GTR 35RX
Just a few days after we stood around the car at the Tokyo Auto Salon we
had this great opportunity to watch the car exclusively...but not only were
we allowed to watch at every detail, no we were even invited to take a seat
in the ultra tight race seat and hit the throttle of that monster.
Thank you very much TRUST/ GReddy!
NEW VIDEO of the Bensopra Revving...watch here:
2014 Nissan GT-R Track Pack vs 2014 Audi R8 V-10 Plus! - Head 2 Head Episode 33
On this episode of Head 2 Head, Motor Trend's Carlos Lago pits the 2014
Nissan GT-R Track Pack against the 2014 Audi R8 V-10 Plus. Performance
wise, both these all-wheel drive monsters represent the cream of the crop
from their respective manufacturers. Nissan's GT-R comes out of the gate
swinging with it's track pack, but the R8 packs a twin-clutch transmission
as well as more power than previous R8's. In between some dynamic testing &
canyon carving, Randy Pobst weighs in with his two cents as he joins Carlos
at the Streets of Willow racetrack. Does Audi's V-10 goliath have what it
takes to topple the legendary "Godzilla"?
Read the full story here:
Head 2 Head appears every other Wednesday on the Motor Trend channel.
Subscribe now to make sure you're in on all the action!
Facebook - http://facebook.com/motortrendmag
Twitter - http://twitter.com/motortrend
Google+ - https://plus.google.com/1018679678590...
Website - http://www.motortrend.com
GTR Owners Make a Kids Dream a Reality
Joash Chung, a social studies teacher at Poe Middle School in Fairfax
County, along with some incredible GTR owners from GTRlife.com team
together to make a young student's dream come true!
⇩⇩⇩⇩Please Look Below to Find Important Information⇩⇩⇩⇩
This is my personal Facebook Fan Page you will find daily updates, photos,
and things you will not see on my Youtube Page.
**My Facebook** https://www.facebook.com/pages/RealMCR12/105645136193326
If you live around Maryland, Virginia, or DC and want to come out to the
events that I go to and see anything from Exotics to Supercars.
Please visit this page.
**http://carlovedc.com/ **
This is a place where I upload random photos
**Photos!** http://instagram.com/realmcr12
Music Provided by:
Royalty Free Music by http://audiomicro.com/royalty-free-music
Sound Effects by http://audiomicro.com/sound-effects
Nissan GTR Almost Hits a Maserati S - Loud Acceleration!!
Tomedelic1 records this tuned Nissan GTR in matte white with black accents
in Cannes. The Owner accelerated very fast leaving a nice sound. But he
came very close to the Maseratie Gran Turismo S who was driving in front
and almost hits it.
Take a look at www.trackandtuner.com for images and info.
I have a second channel for more lovely action video's!
Invite me as a friend and subscribe to my second channel!!
Here's the link: youtube.com / rickadelic1
Thanks a lot!!
NIssan GT-R 2013 Hits the Powder
Nissan's 2013 GT-R is a monster on pavement, but how does it handle on
snow? At the Nissan testing ground in Rikubetsu, northern Japan, we find
Lamborghini Aventador Twin Turbo Startup, Sounds, Acceleration, vs McLaren MP4-12C
Lamborghini Huracan vs McLaren MP4-12C Spider
McLaren 650S vs MP4-12C on the Dyno
GoPro Winner for October 2014 is Brad with a 2007 Volkswagen GTI
Which car is faster?
Similar 1/4 mile timeslips to browse:
1999 Dodge Viper GTS Twin Turbo: 6.963 @ 215.750
Sal Patel, Engine: 576 cid V10, Turbos: Twin Precision 91mm Tires: M/T 315/60/15 Drag Radials
2002 Dodge Viper Jerry Bickel: 7.190 @ 185.780
Ron Siegal, Engine: 540 mopar, Tires: 33 x 17 x 15 goodyear
1998 Dodge Viper Twin Turbo: 7.530 @ 197.650
Lee Saunders,
1998 Dodge Viper GTS: 7.788 @ 169.000
Chris Orthodoxou, Engine: 604, Supercharger: no Turbos: no Tires: goodyear
2001 Dodge Viper Heffner Twin Turbo: 7.996 @ 177.060
Chad, Engine: V10, Turbos: Twin Turbo
2009 Dodge Viper : 8.500 @ 168.000
matt, Engine: 522 ci stroker , Turbos: 76 mm Tires: M/T full slicks
1996 Dodge Viper Stryker TTRS: 8.540 @ 174.000
Ron Misjak Jr. (SVS), Engine: 488cid, Turbos: GTS 76 front mount Tires: Hoosier DOT street
2002 Dodge Viper Heffner Twin Turbo GTS: 8.751 @ 163.420
Gary Javo,
1996 Dodge Viper GTS: 8.780 @ 154.100
T. Darwin, Engine: Pro mod, Tires: Goodyear
2003 Dodge Viper SRT Vert Removeable Hardtop: 8.894 @ 158.320
Nate Montieth, Engine: 522, Supercharger: Paxton Novi 2K Tires: m/t 16
1998 Dodge Viper GTS GT-35s Turbo: 8.900 @ 150.000
Roy, Engine: 488 cu in, Turbos: GT-35s Tires: M/T street radials
Mike Radowski, Engine: 3.0L M52, Supercharger: - Turbos: Precision 71mm Tires: MT ET street
1989 BMW M3 E30 Turbo: 8.949 @ 159.210
Vidar Jodahl, Engine: 2JZ Gte, Turbos: Gtx4294R
1999 Dodge Viper : 9.080 @ 156.810
Hugh Hoard, Engine: V-10, Supercharger: 2 Vortech
1996 Dodge Viper GTS: 9.160 @ 154.320
Ron Misjak Jr. (SVS), Engine: 488ci Viper V-10, Supercharger: no Turbos: Twins Tires: Hoosier (dot slicks)
2003 Dodge Viper SRT: 9.320 @ 150.290
Lyle Larson, Engine: V 10, Supercharger: Yes Turbos: NO Tires: M&H
2001 Dodge Viper GTS: 9.450 @ 157.000
jeff keisner, Turbos: Heffner Twin Turbo
2001 Dodge Viper gts: 9.456 @ 152.000
albert (RSI Rohn), Engine: stroker,
2006 Dodge Viper Supecharged and Nitrous: 9.474 @ 153.180
Nine Ball, Engine: Built Motor, Supercharger: Paxton Novi2000 Tires: Mickey Thompson 345/35-18 drag radial
1999 Dodge Viper RT 10: 9.480 @ 145.220
BIG GUN -SCOTT WIECK, Engine: DODGE V-10, Supercharger: NONE Turbos: NONE
©2014 DragTimes - Disclaimer


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Montana scientists weigh in on the realities of climate changeSubmitted by Theresa Keaveny on July 28, 2014 - 2:21pm
Part of Patriotism is Caring for Environment
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Creagerstown (Frederick County, MD) Change Neighborhood
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Restaurants on Market Street in downtown Frederick, Md. Photo by Jeffrey Porter/ For The Washington Post.
Brewer's Alley on Market Street in Frederick, Md., brews beers in house. Photo by Jeffrey Porter/ For The Washington Post.
Homes in downtown Frederick, Md. Photo by Jeffrey Porter/ For The Washington Post.
Homes on Bear Den Road in Frederick, Md. Photo by Jeffrey Porter/ For The Washington Post.
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Rehoboth Beach's Santa back for 9th year
Dennis Diehl's 6-year-old granddaughter sees his eyebrows and knows the magic is real.
DC Olympic bid touts 'unity' over dysfunction
Place your hands together in just the right way, with thumbs overlapping and the other fingers pointing to the sky, and you've created the symbol for 2024 Olympics in the nation's capital.
East Coast updates: Winter storm brings heavy rain, snow on the eve of Thanksgiving
This storm is packing rain and heavy snow, though it will clear out of the Mid-Atlantic by Wednesday night.
D.C. area updates: Snow and rain may briefly diminish before final late afternoon burst
Snow is making a move into D.C.'s north and west suburbs but may have a tough time penetrating into the I-95 corridor, where accumulation prospects are very iffy.
Va. agency tells APCo to refund $5.8m to customers
State regulators have directed Appalachian Power to refund more than $5 million to Virginia customers.
Winning numbers drawn in 'Pick 4 Midday' game
The winning numbers in Wednesday afternoon's drawing of the Maryland Lottery's "Pick 4 Midday" game were:
Winning numbers drawn in 'Pick 3 Midday' game
The winning numbers in Wednesday afternoon's drawing of the Maryland Lottery's "Pick 3 Midday" game were:
MD Lottery
These Maryland lotteries were drawn Wednesday:
Snow hampers holiday travel in Maryland
Maryland State Police say accumulating snow in western Maryland is contributing to numerous traffic accidents across the region on the day before Thanksgiving.
Maryland man dies after trench collapse
A man pulled from a collapsed trench in Frederick County has died.
Loudoun County crime report
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Loudoun County community calendar, Nov. 28-Dec. 4, 2014
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Loudoun County pet adoption
Dogs, cats and other animals in need of homes are available from the Loudoun County Animal Shelter.
Loudoun County volunteer opportunities
Nonprofit organizations, groups that aid seniors, county agencies and pet rescue groups seek assistance.
Loudoun County Animal Watch
Recent reports received by the Loudoun County Department of Animal Services.
Loudoun will be home to mid-Atlantic's first commercial hops facility
New hops yard, commercial processing facility expected to boost state's fast-growing beer industry.
Loudoun County and Fauquier County home sales
Listings of homes sold recently in Loudoun and Fauquier counties.
Just in time for the holiday, Loudoun charities boosted by unexpected gift
Claude Moore Charitable Foundation awards $70,000 to nonprofit groups that help those most in need.
Autopsy shows Virginia woman was strangled
Patrick County's sheriff says a preliminary autopsy shows a Stuart woman died of asphyxia by strangulation.
Scenes of holiday travel — coffee line longer than security line
As many travel for the Thanksgiving holiday, they share their photos and comments on social media of travel conditions.


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Summer - Unisex - Bath Robes - On Sale
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Sun Dec 16 00:00:00 MST 2012noreenccampbell Rating:5.0
This robes were lovely, thick terry cloth. I bought them on sale as presents and was very pleased with the quality for the price.
Tue Jul 15 00:00:00 MDT 2014gail1943 Rating:5.0
I love the fabric, it like wearing a comfy tee shirt. I love that it has pockets. The sewn on belt solves the problems with a loose belt. The perfect robe!
Mon Dec 31 00:00:00 MST 2012chelseawaters Rating:5.0
Perfect weight for a summer shower 'spa' feeling. Soft and cozy!
Tue Jul 12 00:00:00 MDT 2011nancybrown Rating:5.0
This is a really nice robe. I bought a L/XL for my husband. It shrank a little which was good as he has a 34" waist and it's generous in the wrap! It is a nice lightweight summer robe. I would buy it again.
Wed Jul 31 00:00:00 MDT 2013renokate Rating:5.0
This robe is comfy. Had another robe from another company but it snagged on everything. The sleeves were too short and loose so I got caught on everything. This robe is better fitting. The only thing is because it's thicker material it is also warm, maybe too warm for summer.
Thu Oct 11 00:00:00 MDT 2012dailyalice2 Rating:5.0
Needed a new winter robe--the old terrycloth number was starting to interfere with my balance with its weight--and this turned up on sale. It's a genuine find: soft as my cat's fur, light as a summer garment, and a real augmenter of body heat. Perfect gift as well--who doesn't need a warm robe on a regular basis? (Maybe not my Florida cousins, unless the AC is very high.) And two pockets for those minor items we carry around until we decide to get dressed/go to bed.
Thu Aug 18 00:00:00 MDT 2011tosca9 Rating:2.0
Not a substantial robe -- not full. The man they show in the picture must be 120 pounds for it to wrap around like that. Also, the loop is a little large -- I like a tighter terry. If this is a spa bathrobe, then the spa is from an American 3-star motel (not hotel). It does not feel as if I've wrapped myself into something luxurious. It'll make some good cleaning rags in another year. Should have spent more at a store for a robe on sale.
Tue Jul 06 00:00:00 MDT 2010newbuyer01 Rating:5.0
Bought this robe as a birthday present for my husband and he loves it. I ordered the extra large as he is over 6' tall and stocky. It fits perfectly and looks great. The robe is generously cut, hi quality cotton, but not too heavy for summer. I used standard shipping and it arrived in 2 days.
Wed Jan 09 00:00:00 MST 2013gmax8 Rating:5.0
I was deserate to find an all cotton robe at the last minute. This was perfect and the robe arrived in a matter of days. This was just what my daughter wanter. The price was GREAT for such a high quality robe. None of the stores were having sales on the all cotton robes.
Sat Aug 03 00:00:00 MDT 2013lakewatcher Rating:3.0
I wouldn't call this a spa robe. The material would be equivalent to inexpensive terry bath towels (like the $4 Walmart kind). I'm XL and the robe is really big on me. A fair price might be $35-$40 to my reckoning. The good side is that it is fairly lightweight terry so it dries faster and is cooler for summer use.
Tue Oct 08 00:00:00 MDT 2013anergy913 Rating:4.0
good summer robe. it's pretty lightweight, so I'll probably need a heavier one for the winters but it's perfect for lounging around in during the summer and fall. sizing is generous, I'm 5'10" and 150 lbs and the small wraps around me almost twice.
Sat Aug 09 00:00:00 MDT 2014rsrmohunt Rating:5.0
I love this bathrobe. It's exactly what I wanted. Is the quality superb? No but it's a perfect light weight, unlined, nicely finished summer bathrobe. It is very roomy. The reviews said it would shrink so I bought the lg/xlg. I did wash it and it did shrink. I am 5'4'' 135lbs and after the dryer it is still long and roomy but it is the perfect summer bathrobe.
Fri Jul 25 00:00:00 MDT 2014pstamp54 Rating:5.0
Would like to order more of these, I am waiting for a sale.
Wed Nov 23 00:00:00 MST 2011atlantacarol Rating:2.0
This was advertised as a thick luxurious Turkish robe of superior quality. I took it out of the package, which was lighter than expected, to find that the material was very thin...like a cheap towel. The belt's stitching was frayed down half of one side of the belt. This is a very thin, light type of robe which may be okay for summer, but it did not live up to its description at all and is definitely not a value at a $$$ price. The label in the collar does indicate that it is Turkish cotton and made in Turkey, but honestly I bought a robe for my husband on sale after Christmas at Kohls for about $30 a couple of years ago, and it was far better quality and especially for the price paid. I would not recommend this product, and the description is very misleading. This makes me think of a cheap robe you might pick up somewhere like Walmart for $19.99. I returned it immediately.
Wed Oct 20 00:00:00 MDT 2010littledavid Rating:4.0
A good bathrobe but a bit lighter in weight than I expected. Good for summer nights, a little chilly in the winter, however.
Mon Jul 25 00:00:00 MDT 2011thebushgirl Rating:4.0
I bought the robe for my boyfriend for his birthday. Nice cut, comfortable and light for the summer days.
Mon Jun 30 00:00:00 MDT 2014rumford Rating:5.0
I was very pleased with the quality. I wanted something cooler for summer and these cotton robes are light weight but not too thin. They do run larger. The S/M is definitely a medium/large... Good for me :) If they shrink at all it will be ok. Love the monogram letter too. Got my husband (230 lbs) a L/XL and it fits him well - loose and comfy.
Tue Aug 09 00:00:00 MDT 2011kimdet Rating:5.0
I love my new robe. I had one like it that was several years old and had seen its better days but couldn't find a replacement. Everything else I looked at in stores had a velour feel to it or was lined. I wanted something that was lightweight and just a cotton feel. This fits the bill perfectly! It is a men's small/medium and was a little big for me when I first put it on, but once I rolled up the sleeves a little bit it felt wonderful. It's not too heavy or warm; just what I want for a nice coverup here in Atlanta during the summer!
Thu Jun 13 00:00:00 MDT 2013susierh Rating:5.0
I bought this for my husband. He needed something lighter weight for our 110 degree summers. He loves the robe. It fit hime great. It's well made & had plenty of room to fit his stocky frame.
Oct 9, 2014iowagrannie from Granger, Iowa, Rating:5.0
The workmanship was very good. It arrived quickly and pricing was much better than other places. Very happy.
Nov 22, 2014granny911 from Coker Creek, TN, Rating:5.0
I have been looking for a long robe several years and this was first I was able to find. It is warm and cuddly.
Nov 24, 2014Laura from Loveland, CO, Rating:2.0
Based on the description of the product, I expected a quality product. Unfortunately, this product did not meet expectations. The product looks and feels cheap. It appears to be a very old product that has been stored for years. The plastic bag that the manufacturer put the robe in had disintegrated into lots of small plastic shards when the outer shipping envelope was opened (with care of course). The plastic shards made as mess and are all over the robe as well. On a positive note, the sizing is generous.
Oct 18, 2014Dozer from Washington, Rating:5.0
It was for my wife, I had never done anything like this before but it was easily done and a wonderful robe. I will do this again, thank you Overstock!
Sep 17, 2014sotomomma49 from Albuquerque NM, Rating:5.0
Love it! So plush and cozy. The slippers are really nice. Fits great! Looking forward to wearing it this winter.
View More Recent Reviews
Shop Overstock.com and find the best online deals on everything for your home and your family. We work every day to bring you discounts on new products across our entire store. Whether you're looking for memorable gifts or everyday essentials, you can buy them here for less.OVERSTOCK.COM - IT'S ALL ABOUT THE O™ O.com Prices™


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Top 5 Most Villainous Notre Dame Quarterbacks Of The Past 20 Years
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March 04, 2013 | Discuss
Notre Dame fans take another shot at Bama with t-shirt
The great t-shirt wars between the Alabama Crimson Tide and the Notre Dame Fighting Irish got even more aggressive yesterday when this shirt hit the internet. This follows a tweet that Jimmy Clausen made that offended many Bama fans. This shirt reads: Golden Domers vs Mobile Homers January 7, 2013 South Florida Bama is currently around a 10 point favorite over the Irish. They may...
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December 27, 2012 | Discuss
Jimmy Clausen's 'Catholics vs. Cousins' National Championship shirt
The trash talking has already started for the National Championship game, and I don't think that the Alabama Crimson Tide fans will take too kindly to this latest jab the the Fighting Irish. Hopefully the game lives up to the hype that it is getting.Catholics vs. Cousins BCS showdown RT @jimmyclausen: #GOIRISHSome people have to much time on your hands! It's a shirt people...
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December 17, 2012 | Discuss
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Find records of Olga Printzlau
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Start your workout routine out right with innovative Under Armour. Designed to keep you cool, dry and light throughout any activity, the moisture-wicking technology works with your body to regulate temperature and enhance performance. Style #1236476. Details: Fitted capri length workout pants, approx. 15" inseam, 4-way stretch improves range of motion and dries faster, Hidden zipper key pocket to secure your stuff, Moisture-wicking, stretch polyester. Content: Body: 87% Nylon, 13% ...
Style # W-451 Capri length yoga pants without pockets Rolldown waistband and side slit on hem Stretch cotton Content: Fabric: 90% Cotton, 10% Lycra. Country of Origin: Made in United States
DKNY captures the fast-paced, cosmopolitan spirit of New York City. It's not just lingerie. It's a lifestyle. Style #Y387595. Details: Ultra-comfortable knit capri length pajama pants, Covered elastic drawstring waistband, Bottoms do not have pockets, Approx. 23 inch inseam, Soft, stretch modal. Content: Body: 93% Modal, 7% Spandex. Origin: Made in China
DKNY captures the fast-paced, cosmopolitan spirit of New York City. It's not just lingerie. It's a lifestyle. Style #Y987595. Details: Ultra-comfortable, knit capri length pajama pants, Covered elastic drawstring waistband, Bottoms do not have pockets, Soft, stretch modal. Content: Body: 93% Modal, 7% Spandex. Origin: Made in China
Style # 8240 Fitted capri length pants without pockets Flatlock seams for non-chafe comfort Approx. 16" inseam Moisture-wicking, 4-way stretch polyester Content: Body: 89% Polyester, 11% Spandex. Exclusive of decoration. Country of Origin: Imported
Hard Tail designs are all about chic comfort. The evolution of mobility, spirit, and color has begun. Style #SUP-04. Details: Moisture-wicking, capri length yoga pants, Antibacterial technology eliminates growth of bacteria, Quick Dry feature transitions from workout to night out, Wide, flat elastic waistband with logo on back, Capri does not have pockets, Approx. 21'' inseam, 4-way stretch lycra with matte finish. Content: Body: 90% Supplex, 10% Lycra.Pre-shrunk. Origin: Made in United States
Style #M7420. Details: Capri length workout pants without pockets, Covered elastic waistband with drawstring closure, Approx. 18'' inseam, Cool and comfortable cotton jersey knit. Content: Fabric: 60% Cotton, 40% Polyester. Origin: Made in El Salvador
Style # 817720 Knit pajama pants without pockets Embossed logo on hip Elastic drawstring waistband Capri length, approx. 23'' inseam Stretch cotton Content: Body: 95% Cotton, 5% Spandex. Country of Origin: Imported
Slim, smooth and add style to your wardrobe with Yummie Tummie's chic collection of shapewear for a sleeker silhouette in an instant! Style #YT5-052. Details: Zone control, high-waist capri length shaping leggings, Firm control seamless waist shapes the tummy, Light control zones smoothes hips, thighs and legs, Designed to shape your rear for a natural looking lift, Stay put silicone waistband prevents rolling, Luxurious, fine-gauge stretch microfiber. Content: Fabric: 81% Nylon, 19% ...
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Houzz is the new way to design your home.
Jamie Herzlinger
Interior Designers & Decorators
Interior Designers & Decorators
Jamie Herzlinger
Embodying the romance and sophisticated beauty of Hollywood Regency, Jamie Herzlinger composed an orchestra of strong geometric patterns, period accessories and light fixtures, honed organic motifs, custom furnishings and draperies and her trademark penchant for extensive architectural details like floating second ceilings, 10-inch baseboards and crown molding studded with convex mirrors.
What Houzzers are commenting on:
michalkova added this to michalkova's ideas
April 29, 2012
April 29, 2012
prosklene skrine, pult, svetle seda podlaha


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The present invention relates to new binder combinations comprising
(A) 99-30 parts by weight of OH-functional graft copolymer resins prepared by copolymerization of a polybutadiene having a molecular weight of from 500 to 10000 and containing more than 30% of 1,2-vinyl structure with selected olefinically unsaturated monomers and
(B) 1 to 70 parts by weight of a multifunctional crosslinking resin, preferably a polyisocyanate resin. The new binder combinations are suitable for preparing coatings having a very high level of elasticity and an excellent surface hardness.
1. Binder combinations comprising
(A) 99-30 parts by weight of OH-functional graft copolymer resins prepared by the copolymerization of
(a) 1 to 60 parts by weight of at least one polybutadiene having a molecular weight of from 500 to 10,000 and containing more than 30% of a 1,2-vinyl structure,
(b) 5 to 60 parts by weight of at least one unsaturated aromatic monomer comprising styrene, vinyl toluene, or methacrylic acid ester containing aliphatic C1 -C6 hydrocarbon groups,
(c) 5 to 80 parts by weight of at least one aliphatic acrylic acid ester containing 1 to 12 carbon atoms in the alcohol component,
(d) 10 to 60 parts by weight of at least one hydroxyalkyl ester of acrylic or methacrylic acid containing 2-8 carbon atoms in the hydroxyalkyl group,
(e) 0 to 50 parts by weight of at least one acrylic or methacrylic acid glycidyl ester or reaction products thereof with aliphatic or aromatic monocarboxylic acids and amino compounds,
(f) 0 to 30 parts by weight of acrylonitrile and,
(g) 0.05 to 10 parts by weight of at least one α,β-monoolefinically unsaturated mono or dicarboxylic acid containing 3 to 7 carbon atoms, at least one maleic acid or fumaric acid semi ester containing 2 to 14 carbon atoms in the alcohol group, or both and
(B) 1 to 70 parts by weight of a multi-functional crosslinking resin, the sum of parts by weight of components (A) and (B) and the sum of parts by weight of components (a) to (g) amounting in each case to 100.
2. Binder combinations according to claim 1, characterized in that component (A) consists of
(a) 1 to 55 parts by weight of one or more functional or non-functional polybutadienes having a molecular weight of from 500 to 10,000 and containing more than 35% of a 1,2-vinyl structure,
(b) 5 to 55 parts by weight of styrene, vinyl toluene, methylmethacrylate, butylmethacrylate or mixtures thereof,
(c) 5 to 75 parts by weight of ethyl acrylate, butyl acrylate, 2-ethyl-hexyl acrylate or mixtures thereof,
(d) 10 to 55 parts by weight of 2-hydroxyethyl acrylate, 2-hydroxy propyl acrylate, 4-hydroxy butyl acrylate, 2-hydroxy ethyl methacrylate, 2-hydroxy propyl methacrylate or mixtures thereof,
(e) 0 to 45 parts by weight of glycidyl acrylate, glycidyl methacrylate or mixtures thereof,
(f) 0 to 25 parts by weight of acrylonitrile, and
(g) 0.1 to 8 parts by weight of acrylic acid, methacrylic acid or maleic acid semi ester containing 4 to 8 carbon atoms in the alcohol component or mixtures thereof.
3. Binder combinations according to claim 1, characterized in that the OH-functional monomer of the component (A) is an adduct of at least one monoester of acrylic or methacrylic acid with an alkane diol containing 2 to 4 carbon atoms and ε-caprolactone in a molar ratio of from 1.5:1 to 1:3.
4. Binder combinations according to claim 1, characterized in that the component (A) is modified with ε-caprolactone during or after graft polymerisation.
5. Binder combinations according to claim 1, characterized in that the multi-functional crosslinking resin B is an aminoplast resin.
6. Binder combinations according to claim 1, characterized in that the multi-functional crosslinking resin B is an alkoxylated melamine resin, a melamine-formaldehyde condensation product, a urea resin, a guanidine resin or mixtures thereof.
7. Binder combinations according to claim 1, characterized in that the multi-functional crosslinking resin B is a resol resin.
8. Binder combinations according to claim 1, characterized in that the multi-functional crosslinking resin is a polyisocyanate.
9. Binder combinations according to claim 1 wherein component (A) is 90-30 parts by weight.
10. Binder combinations according to claim 1 wherein component (B) is 10-70 parts by weight.
This invention relates to new binder combinations comprising OH-functional graft copolymer resins and multi-functional crosslinking resins, preferably polyisocyanate resins.
The binders according to this invention are suitable, for example, for use in the motor vehicle sector, especially for coating parts which are exposed to severe impact and bending stresses and severe weathering conditions.
It is known that the properties of plastics may be improved to such an extent by means of lacquering that they become suitable for use in special applications. If, for example, parts made of plastics for the motor vehicle industry are to be used in situations where they are exceptionally exposed to weathering, impacts and environmental influences as, for example, in the region of the lower side parts (sills) and the front and rear parts, these parts must be covered with coatings which have high flexibility and surface hardness.
Plastics surfaces which are particularly exposed to road dirt (sills) must be protected by coatings which not only have the necessary mechanical resistance (resistance to stone chipping) but also a high resistance to salt, fuels, and tar and oil stains. All the coatings must have good optical characteristics as films so that they not only have a high degree of gloss but also retain these optical properties over a period of many years in spite of the influence of weathering.
It is known from DE-OS No. 2 364 736 to coat rubber products with an acrylic lacquer based on styrene, alkyl (meth) acrylic acid esters and hydroxy alkyls (meth) acrylic acid esters in combination with alkylated melamine-formaldehyde resins or polyisocyanates. The highly flexible coatings thus obtained are not always entirely satisfactory, for example in their mechanical properties, in the adherence of the coating to the plastic surface, etc.
Before the rubber surface is coated, it must be surface activated and then primed with two coats of acrylic resin as the coatings only manifest their special properties on pre-treated surfaces of rubber such as an ethylene-propylene copolymer rubber, a styrene-butadiene copolymer rubber, a polybutadiene rubber, a polyisoprene rubber or a butyl rubber.
Films based on polyacrylates which can be coated with a reactive lacquer system based on polyols/polyisocyanate without requiring a preliminary treatment and without problems of adherence are disclosed in DE-OS No. 2 756 708. The elimination of problems of adherence is achieved by adding to the copolymers from 1 to 15% by weight of monomers with functional end groups which are capable of forming a bond with the isocyanate-based reactive lacquer system. Although this process has the advantage of eliminating the special preliminary treatment of the substrate surface, it has the disadvantage that it is only applicable to the special case of films on (meth) acrylate copolymers and cannot be used for coating substrate surfaces based on other polymers.
It has now been found that binder combinations of OH-functional graft copolymer resins and polyisocyanates form firmly adhering films on surfaces which have not been pre-treated, preferably metal or plastics surfaces, after they have been cured. Their excellent overall properties such as elasticity, hardness, chemical resistance and weathering resistance enables them to be used e.g. in the construction of motor vehicles by the composite construction method or for the construction of windows, household implements, etc.
The present invention relates to binder combinations comprising
(A) 99-30 parts by weight, preferably 90-30 parts by weight, of OH-functional graft copolymer resins prepared by the copolymerisation of
(a) 1-60 parts by weight of at least one, optionally functional polybutadiene having a molecular weight of from 500 to 10,000 and containing more than 30% of a 1,2-vinyl structure,
(b) 5-60 parts by weight of at least one unsaturated aromatic monomer such as styrene, vinyl toluene and/or methacrylic acid ester containing aliphatic C1 -C6 hydrocarbon groups, preferably methylmethacrylate,
(c) 5-80 parts by weight of at least one aliphatic acrylic acid ester having 1-12 carbon atoms in the alcohol component, preferably butyl acrylate and 2-ethyl-hexyl acrylate,
(d) 10-60 parts by weight of at least one hydroxy alkyl ester of acrylic or methacrylic acid having 2-8 carbon atoms in the hydroxy alkyl group,
(e) 0-50 parts by weight of at least one acrylic or methacrylic acid glycidyl ester or reaction products thereof with aliphatic and/or aromatic monocarboxylic acids and amino compounds,
(f) 0-30 parts by weight of acrylonitrile, and
(g) 0.05-10 parts by weight of at least one α,β-monoolefinically unsaturated mono or dicarboxylic acid having 3-7 carbon atoms and/or at least one maleic or fumaric acid semi ester having 2-14 carbon atoms in the alcohol group, preferably acrylic acid, and
(B) 1-70 parts by weight, preferably 10-70 parts by weight of a multifunctional crosslinking resin, in particular aminoplast resins such as alkoxylated melamine resins, melamine-formaldehyde condensation products, urea resins, guanidine resins, phenoplast resins or resol resins and, preferably, polyfunctional isocyanates, especially oligomeric isocyanates having a biuret, allophanate, urethane and/or isocyanurate structure,
the sum of parts by weight of components (A) and (B) and the sum of parts by weight of components (a) to (g) amounting in each case to 100.
Preparation of the graft copolymer resins A may be carried out by copolymerisation of the components a-g by conventional processes. Radical polymerisation, either solvent free or in solution, is preferred. In this process, monomeric and oligomeric components are copolymerised at temperatures of from 70� to 160� C. in the presence of radical formers and optionally molecular weight regulators.
Preferred starting compounds for the polyacrylate resins A consist of the following components:
(a) 1-55 parts by weight of one or more, optionally functional polybutadienes having a molecular weight of from 500 to 10,000 and containing more than 35% of a 1,2-vinyl structure,
(b) 5-55 parts by weight of styrene, vinyl, toluene, methyl methacrylate, butyl methacrylate or mixtures thereof,
(c) 5-75 parts by weight of ethylacrylate, butylacrylate, 2-ethyl-hexylacrylate or mixtures thereof,
(d) 10-55 parts by weight of 2-hydroxyethyl acrylate, 2-hydroxypropylacrylate, 4-hydroxybutylacrylate, 2-hydroxyethylmethacrylate, 2-hydroxypropylmethacrylate or mixtures thereof,
(e) 0-45 parts by weight of glycidyl acrylate, glycidylmethacrylate or mixtures thereof, optionally after a reaction with saturated and/or unsaturated aliphatic and/or aromatic monocarboxylic acids, which reaction is carried out before or, preferably, after copolymerisation at temperatures of 80� to 160� C., using conventional catalysts,
(f) 0-25 parts by weight of acrylonitrile, and
(g) 0.1 to 8 parts by weight of acrylic acid, methacrylic acid or maleic acid semi esters having 4-8 carbon atoms in the alcohol component, or mixtures thereof.
Any polybutadienes containing 1,2-vinyl double bonds in side positions are suitable in principle as starting materials (a) for the graft copolymer resins according to the invention.
Polybutadienes containing more than 30% of vinyl double bonds are particularly suitable. The other double bonds may be composed of any proportions of cis 1,4- and trans 1,4-structures. A product containing more than 80% of 1,2-vinyl double bonds in side positions is a particularly suitable starting material.
Isomeric mixtures of polybutadienes would generally be used, e.g. polybutadienes containing 30 to 90% of vinyl double bonds and 10 to 70% of mixtures of cis-1,4 and trans-1,4 double bonds. The polybutadienes may also carry functional groups, e.g. hydroxyl groups, carboxyl groups, etc. Polybutadienes of this type with different configurations are known; see e.g. "Makromolekule" by H. G. Elias, 4th edition, publishers Huthig and Wepf-Verlag, Basel, Heidelberg, and New York, pages 676 and 744-746 and 1012 etc.
The monomers and oligomers a-g are incorporated in the graft copolymer in substantially the same proportions in which they were used for polymerisation. The incorporated units may be in substantially random distribution.
Suitable solvents for the preparation of component A include, for example, aromatic solvents such as benzene, toluene, xylene or chlorobenzene, esters such as ethyl acetate, butyl acetate, methyl glycol acetate, ethyl glycol acetate, or methoxypropyl acetate, ethers such as butylglycol ether, tetrahydrofurane, dioxane, ethylglycol ether or diethyleneglycol dialkyl ethers, ketones such as acetone, methylethyl ketone or methylisobutyl ketone, and halogenated solvents such as methylene chloride or trichloromonofluoro ethane.
The preparation of graft polyacrylate resins A may be carried out continuously or batchwise. The monomer mixture and the initiator are generally dosed continuously and at a uniform rate into a polymerisation reactor and the corresponding quantity of polymer is at the same time continuously removed. Chemically virtually uniform copolymers may advantageously be produced by this method. Copolymers which are chemically almost uniform may also be produced by running the reaction mixture into a stirrer vessel at a constant velocity without discharging the polymer.
The graft copolymerisation is generally carried out at a temperature range of from 70� C. to 160� C., preferably from 100� C. to 150� C., at a pressure of 103 to 2�104 mbar. The initiators are used in quantities of 0.05 to 15% by weight, based on the total quantity of monomers.
Suitable initiators for the preparation of the polyacrylate resins of component A include the usual radical starters, e.g. aliphatic azo compounds such as azodiisobutyric acid nitrile, azo-bis-2-methyl-valeronitrile, 1,1'-azo-bis-1-cyclohexane nitrile and 2,2'-azo-bis-isobutyric acid alkyl esters; symmetrical diacyl peroxides, such as acetyl, propionyl or butyryl peroxide, benzoyl peroxides substituted with bromine, nitro, methyl or methoxy groups, and lauroyl peroxide; symmetrical peroxydicarbonates such as diethyl, diisopropyl, dicyclohexyl or dibenzoyl peroxydicarbonate; tert.-butyl peroctoate, t-butyl perbenzoate or tert-butylphenyl peracetate and peroxy carbonates such as tert-butyl-N-(phenylperoxy)-carbonate or tert-butyl-N-(2-,3- or 4-chloro-phenyl peroxy)-carbonate, hydroperoxides such as tert.-butylhydroperoxide, cumenehydroperoxide, and dialkylperoxides such as dicumylperoxide, tert.-butyl-cumyl-peroxide or di-tert.-butyl-peroxide.
The usual molecular weight regulators may be used for regulating the molecular weight of the acrylic resin of component A, e.g. n-dodecyl mercaptan, mercapto ethanol, diisopropyl xanthogen disulphide or di-(methylenetrimethylol propane)-xanthogen disulphide. Mercaptoethanol is preferred. The regulators are added in quantities of 0.1 to 10% by weight, based on the monomer mixture.
The flexibility of the coatings produced from the graft copolymerisation resins A according to the invention may be further increased with comparatively little loss of hardness by modifying the graft copolymerisation resins A with lactones, in particular with butyrolactone and ε-caprolactone.
The reaction of the graft copolymerisation resins A with the lactones is suitably carried out at temperatures of 100� C.-160� C. in the presence of catalysts, either after or during radical polymerisation. The catalysts used for the ring opening polymerisation of the lactones which takes place side by side with the radical polymerisation may be metal compounds, for example titanates or preferably organic tin compounds such as dibutyl tin oxide, dibutyl tin dilaurate, dibutyl tin diacetate, tin dioctoate, etc.
The catalysts are used in quantities of 0.01-0.2% by weight, based on the weight of the lactones put into the process.
Such lactone modifications may also be carried out by using lactone modified monomers for the preparation of the graft copolymer resins.
The polymer resins according to this invention are valuable binder components for 2-component lacquers. The term "two-component lacquers" is used in this context to include "one pot systems" and "two pot systems". Since the polymer resins according to the present invention are binder components for 2-component lacquers, the lacquers contain a hardening component in addition to the polymer resins according to the invention (and optionally other polyhydroxyl compounds). If the hardener is a polyisocyanate containing free isocyanate groups, for example, then the coating compounds must be made up ready for use shortly before they are to be applied by mixing the components together. Such a product would be a "two pot system". If, however, the hardener is a compound which will only react at an elevated temperature with the polymer resins according to the invention, e.g. polyisocyanates carrying blocked isocyanate groups, then the hardener may be combined with the polymer resin at room temperature to form a "one pot system" which can be stored at room temperature.
The reaction components B for the hydroxyl-containing graft copolymer resins according to the invention used for the preparation of lacquer binders for films and coatings may be crosslinking agents which harden the coatings according to this invention by chemical reactions with the hydroxyl-containing graft copolymer resins. Examples of such crosslinking agents include suitable melamine derivatives such as alkoxylated melamine resins or melamine-formaldehyde condensation products (e.g. FR-PS 943411, by D. H. Salomon in "The Chemistry of Organic Film formers", pages 235-240, John Wiley & Sons, Inc., New York, 1974) as well as conventional crosslinking agents such as epoxides which are capable of reacting with alcoholic hydroxyl groups, carboxylic acid anhydrides, phenoplast resins, resol resins, urea resins, guanidine resins or mixtures thereof.
Conventional commercially available lacquer polyisocyanates (e.g. U.S. Pat. Nos. 3,124,605, 3,358,010, 3,903,126, 3,903,127, 3,976,622, 3,183,112, 3,394,111, 3,645,979, and 3,919,218; GB-PS Nos. 1060430, 1234972 and 1458564) such as lacquer polyisocyanates which contain biuret groups, urethane groups, allophanate groups or isocyanurate groups are preferred reactants B for the OH-functional graft copolymer resins according to the invention used for the preparation of lacquer binders for films and coatings.
The polyisocyanates containing urethane groups are preferably adducts of aliphatic triols and tetraols, e.g. trimethylol propane, glycerol, pentaerythritol and aromatic or cycloaliphatic diisocyanates such as 2,4- and/or 2,6-toluylene diisocyanate, 2,4'- and/or 4,4'-diisocyanatodicyclohexyl methane, isophorone diisocyanate, etc. One hydroxyl group of the polyol generally reacts with one mol of diisocyanate.
The polyisocyanates containing isocyanurate groups may be cyclotrimerisation products of the above mentioned aliphatic and aromatic diisocyanates, in particular of tolylene diisocyanate and hexamethylene diisocyanate.
The hydroxyl-containing graft copolymer resins and the polyisocyanates used for crosslinking are put into the process in the proportions required to provide from 0.5 to 2, preferably 0.7 to 1.3 isocyanate groups to one hydroxyl group.
The usual auxiliary agents and additives used in lacquer technology may be added when the products are used for the purpose according to this invention, e.g. solvents, pigments, viscosity regulating substances, anti-foamants, catalysts for the NCO/OH addition reaction, UV absorbents, antioxidants and other substances which prevent degradation of the polymer, e.g. sterically hindered amines, etc.
When polyisocyanates are used as crosslinking agents, the coating compounds according to this invention are preferably cured at temperatures of 0� C. to 130� C. The coatings obtained under these conditions combine very high stretchability with great hardness and excellent resistance to weathering and chemical resistance.
They are therefore particularly suitable for coating articles which are exposed to weathering, e.g. metallic objects such as motor vehicles, roof gutters, railings, bicycles, domestic appliances, etc.
The lacquers are applied by the usual methods such as spraying, casting, immersion, spread coating, spraying or roller application. The lacquers are generally used in the quantities required to produce dry film thicknesses of the lacquers of 0.005 to 0.1 mm.
All percentages given are percentages by weight and all "parts" are parts by weight.
The quantity of solvent shown in Table I is introduced into a reactor equipped with reflux condenser and heating, cooling and dosing devices and heated to 120� C. A mixture of the monomer indicated in Table I and the molecular weight regulator is added at this temperature under a nitrogen atmosphere in the course of 2 hours. At the same time, the initiator indicated in Table I dissolved in the given quantity of solvent is added separately in the course of 2.5 hours.
The reaction mixture is then stirred for 3 hours at 120� C. and the polymer is removed by pressure filtration. The characteristic data of graft copolymer resins 1-9 and comparison examples V1 and V2 are shown in Table II.
800 parts of 8a or 9a, respectively, 160 parts of ε-caprolactone and 0.1 part of tin dioctoate are stirred together for 6 hours at 130� C. in a reaction vessel equipped with reflux condenser. The resulting product is then removed by pressure filtration.
The quantities given in Table I are parts by weight.
TABLE I__________________________________________________________________________ Example 1 2 3 4 5 6 7 8a 9a V1 V2__________________________________________________________________________Xylene 900 900 900 700 700 600 600 700 700 600 600Polybutadiene Nisso G-1000.sup.(1)R 195 195 195 175 175 175 117Polybutadiene Lithene PL.sup.(2)R 189 189Styrene 98 130 120 139 120 130 187 124 190Methylmethacrylate 98 124Butylacrylate 453 453 448 578 533 622 571 481 481 674 4802-Ethylhexylacrylate 97 2522-Hydroxyethylacrylate 220 220 220 270 292 363 365 327 327Butanediolmonoacrylate 325 362Acrylic acid 10 10 10 12 12 13 13 16 16 12 12Mercaptoethanol 30 30 36 43 43 46 46 43 36t-Butylperoxy-2-ethylhexanoate 14 14 14 17 17 19 19 17 26 49 49Xylene 80 80 80 75 75 80 80 75 72 90 90__________________________________________________________________________ .sup.(1) Molecular weight about 1,400, OH content about 2.5%, >90% 1,2vinyl double bonds .sup.(2) Molecular weight about 900, 40-50% 1,2vinyl double bond, 30-40% 1,4trans-double bonds, 15-25% 1,4cis-double bonds.
TABLE II__________________________________________________________________________ Example 1 2 3 4 5 6 7 8a 8b 9a 9b V1 V2__________________________________________________________________________Solids content (%).sup.(1) 49.4 50.2 50.3 60.1 60.3 65.4 65.6 60.4 65.3 59.8 66.5 65.9 65.3Viscosity (20� C.) (mPa.s) 1079 831 911 2853 2016 1923 1598 2580 2941 1300 1494 1360 1610Acid number 4 4 4 5 5 5 5 6 5 6 5 5 5(mg KOH/g of substance)Hydroxyl number 71 72 74 88 86 87 87 110 90 108 292 79 80(mg KOH/g of substance)Colour number (APHA)* 70 50 40 10 15 50 60 10 30 10 35 45 15__________________________________________________________________________ .sup.(1) % by weight of nonvolatile constituents
Results of tests carried out on white lacquers prepared by the new graft copolymerisation resins and the comparison examples according to the following formulation.
______________________________________% by weight of solvent free constituents______________________________________ 44.4 graft copolymer resin or comparison example 0.1 zinc octoate 1.2 tinuvin 9001 0.6 bentone 382 36.8 titanium dioxide (Kronos 2160) 16.9 Desmodur N (hexamethylene diisocyanate biuret)100.0______________________________________ Solids contents of substances worked up: 46% by weight in a 54% by weight solvent mixture of xylene, methoxypropylacetate, ethyl acetate and methylethyl ketone. 1 � Tinuvin 900: ##STR1## UV absorbent, dialkylsubstituted hydroxyphenyl triazole, Ciba Geigy .sup. � Bentone 38: Laminated magnesium sillicate of Kronos Titan GmbH.
__________________________________________________________________________ Example 1 2 3 4 5 6 7 8b 9b V1 V2__________________________________________________________________________Storage time at room temperature (h) approx. 2.8 4.4 4.4 14.4 12.8 15.8 13.6 2.7 7.1 22 14.7Drying time rec. (h) approx. 3.6 3.7 3.0 5.6 3.9 5.3 3.5 2.3 2.4 7.1 2.3Gloss (60� Gardner) 86 85 84 92 93 93 92 91 93 90 92Pendulum hardness (after 14 days) 105 123 98 137 122 90 88 76 78 104 77Solvated by* (1 Min. action)Toluene 0 0 0 0 0 1 0 0 0 2 1MPA 0 0 0 0 0 0 0 0 0 1 1EA 1 1 1 0 0 1 1 1 0 3 2Acetone 2 2 2 0 1 2 1 1-2 1 3 2Tar resistance* Action of DB tar solution1 h 0 0 0 0 0 0 0 0 0 1 13 h 0 0 0 0 0 0 0 1 1 1 124 h 1 0-1 1 0 1 1 1 1 1 2 2Bending test 1 inch* (on Bayflex 91) 0� C. + + + + + + + + + + + -5� C. + + + + + + + + + +-10� C. + + + + + + + + + - +-15� C. + + + + + + + + + - --20� C. + + + + + + + + + - --25� C. - - - - + - + + + - --30� C. - - - - - - - + + - -1 Inch: 2.54 � 10-2 m__________________________________________________________________________ *0 = best possible result 4 = least favourable result MPA = methoxypropyl acetate EA = ethyl acetate DB tar solution = solution of tar in organic solvents (Daimler Benz) .sup.(R) Bayflex 91 = PUR integral foam (Bayer AG) APHA = unit of measurement of colour number according to Hazen
A Bayflex work piece measuring 3 mm in thickness, 15 mm in width and 100 mm in length and lacquer coated with white lacquers 1 to 9 and V1 and V2 is placed on a mandrel 1 inch in diameter (2.54�10-2 m). The lacquered workpiece is then bent through 180� over the mandrel.
+: coating undamaged
-: coating cracked.
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Police Officer Accused of Using Excessive Force in Five Cases
According to a report by WPRI , Detective Robert Kramer has used excessive force in multiple incidents dating back to 2007 that led to dropped charges more than once, and a lawsuit settlement payout
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The Underground Mansions of Billionaires
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finger pointing will end in suspension.
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Word of the Day: Maillard Effect
Sep 27, 2011 12:31 pm
Building up your kitchen vocab arsenal
While there are a number of important "effects" in this world, Doppler or domino for example, Food Republic would like to share our favorite with you. It's the Maillard Effect, straight from France, and it's responsible for how delicious your steak-frites are.
When foods are heated, their flavors change. Some, like beef and potatoes, form a crisp, caramelized outer coating when directly exposed to high heat. The Maillard Effect is the complex scientific process of how the tastes of certain foods develop in a way that most people find highly pleasing. Mmm, caramelization.
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CATCHING UP WITH BJ PENN - FIGHT WEEK: BJ Makes The Rounds In Seattle watch video >>
Finalists from The Ultimate Fighter 19 and headliners BJ Penn and Frankie Penn weigh-in before capping off International Fight Week with a great event on Sunday. watch video >>
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http://www.fightnetwork.com - Fight Network's John Ramdeen and Robin Black take an interesting twist on the game "6 Degrees of Kevin Bacon" by substituting UFC legend BJ Penn as the main subject. The theory goes that any fighter with at least two UFC appearances can be connected to Penn in six steps or less. Watch as John and Robin put the theory to the test. Join in the conversation yourself by trying the game out and posting your results in the comments section, or see if you can find a rare n watch video >>
http://www.fightnetwork.com - Fight Network's John Ramdeen and Robin Black look ahead to UFC Fight Night 35, where Luke Rockhold takes on Costa Philippou in the main event. Robin takes another shot at breaking down Luke Rockhold's dynamic kickboxing skills. John and Robin also have a spirited round of "6 Degrees of BJ Penn," where they test the theory that just about any UFC fighter can be tied back to BJ Penn in no more than six steps. Robin then drops in on The Ultimate Fighter: Nations compet watch video >>
This week on "Catching Up With BJ PENN" BJ gets personal about his MMA career and training for his upcoming fight against Rory MacDonald at UFC on FOX, Dec. 8. watch video >>
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A candid look inside the final hours of fight week with headliners BJ Penn and Nick Diaz. watch video >>
http://fightnetwork.com/ - This week Robin Black takes a look at Frankie "The Answer" Edgar by the numbers using Reed Kuhn's Fightnomics, revealing an intriguing tactic in the evolution of Edgar ahead of his critical fight against Cub Swanson at UFC Fight Night 57: Edgar vs. Swanson. For additional coverage of MMA, boxing and pro-wrestling check out http://fightnetwork.com/ or follow us on Twitter at https://twitter.com/fightnet or find us on Facebook at https://www.facebook.com/FightNetwork watch video >>
Former DREAM fighter Abel Cullum makes a return to MMA after almost 3 years away against Ulysses Gomez. Cullum is set to fight again at RFA 19 October 10th on AXS TV. AXS TV is Your Home for MMA every Friday Night! Find AXS TV HERE: http://bit.ly/WtTUDr watch video >>
Former TUF Winner Jonathan Brookins Returns to MMA after more than 2 years away at Legacy 29 against Cody Fuller. Watch Brookins in action again August 29th at Legacy 34 on AXS TV! AXS TV is Your Home for MMA every Friday Night! Find AXS TV HERE: http://bit.ly/WtTUDr watch video >>


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Syracuse shuts downs Indiana at both ends of the floor
Mar 29, 2013, 4:00 AM EST
WASHINGTON, D.C. — Syracuse was not supposed to be in the Elite Eight. Not with No. 1-seed Indiana, not on a court in which they were blown out by 22 points less than a month ago. But thanks to a career-high 24 points from Michael Carter-Williams, the Syracuse Orange advanced to the Elite Eight with a 61-50 win over the Hoosiers on Thursday night.
Syracuse's patented 2-3 zone gave the Hoosiers fits, as Indiana finished just 16-for-48 from the field and 3-for-15 from beyond the arc. Heading into the contest the key match-up top watch for was how Indiana would combat Syracuse's length on the perimeter, both offensively and defensively. It took less than 20 minutes to figure out that Indiana didn't have many answers on either end of the court. By the end of the game, Yogi Ferrell failed to score any points, had just one assist and committed four turnovers. Jordan Hulls didn't fare much better. He too finished with zero points, but dished out three assists to just two turnovers.
But Indiana's struggles were not exactly their fault. Much of their demise can be credited to the play of Syracuse, who as a team finished with 10 blocks and 12 steals.
The way to beat a 2-3 zone is by inserting the ball into the high-post, then either a quick pass to the wing or down to the low block. Syracuse's length forced Indiana to make inaccurate entry passes, and the Orange's size down low was too much for Cody Zeller to deal with. This was one of the few times all season where he looked vulnerable. He struggled with high-percentage shots and had difficulty going up strong against the big Syracuse front line.
Jim Boeheim was extremely pleased with the way his role-players were able to stymie the Hoosiers' frontcourt. "I thought Baye (Moussa-Keita) was tremendous and (Jerami) Grant made an unbelievable block. He gave us a plus 8 in 10 minutes he had an unbelievable block on Sheehey, those are the contributions that you have to have and he gave them to us tonight."
From the opening tip Indiana looked tentative against the length Syracuse had on defense. "They were just long and active. We just didn't take care of the ball like we should have," said Victor Oladipo, who finished with a team-high 16 points. "In the first half we got a little too anxious, catching the ball, moving out the ball, not having the ball secure in our hands, and our shots weren't falling at the same time."
Syracuse made Indiana feel uncomfortable all night long. The Hoosiers struggled to handle the ball, we're hesitant to finish strong around the basket and became gun-shy once they realized their shots weren't falling.
Syracuse's James Southerland knew Indiana would have issues with their zone. "At first they looked confused, slowing the ball down seeing what they could get. We just do the a good job of talking out there and recovering if they get penetration, but it's tough. One thing they don't see is how long we are until they approach our zone."
But it wasn't just the Orange's length on defense that gave Indiana trouble. The Orange ran their fast break to perfection, and used their size advantage on offense. The length and size of Syracuse's guards made it difficult for Indiana to match-up defensively. Jordy Hull, at 6-foot-1, was not athletic enough to guard Brandon Triche, who at 6-foot-4, was the smallest player for the Orange on Thursday. "We felt like we had an advantage size wise finishing at the rim and that's what we did," said Triche, who finished with 14 points on 6-for-12 shooting.
Much of the Orange's offensive game plan was focused on isolating Victor Oladipo and having the off-ball players go to the basket. When Oladipo guarded Michael Carter-Williams, Brandon Triche exploited the defense. When he covered Triche, Carter-Williams did the same.
"Victor is a very good defender and through the first half he was pretty much guarding James, so Mike had a field day against the basket and I also contributed a few points," said Triche. "Once he started guarding Mike, I felt like I had an advantage and once he got off Mike know, I felt like he had an advantage shooting but he also scored points on him well. We just did a great job getting into the lane and getting them in foul trouble."
Carter-Williams had his best game in an Orange uniform, scoring a career-high 24 points and added five steals and four rebounds. The 6-foot-6 guard was too much for the undersized Indiana defense to handle.
Boeheim knew that Carter-Williams would be the difference-maker on offense, and was more than pleased with the result. "This was the best he's played all year. He was tremendous tonight, he was the difference in the game on offense, clearly."
With the win, the Orange are just one game away from a spot in the Final Four. But they will have to defeat a Marquette team that exposed the Orange's zone early in the year en route to a 74-71 victory. The No. 3-seed Golden Eagles will face off against the No. 4-seed Orange on Saturday at 4:30 p.m. at the Verizon Center in the East Regional Finals.
You can contact Troy Machir on Twitter at @TroyMachir.
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I hope his joke doesn't make people ignore the fact the he really felt bad about this.
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We get some good gauge games on Tuesday night.
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- Maryland upsets No. 13 Iowa State as fearless freshmen mix with gritty veterans for balanced effort 3
- Rondae Hollis-Jefferson's selflessness during the Maui Invitational will help No. 3 Arizona in the long run 0
- Player of the Year Power Rankings: A familiar face on top, but a few surprises behind him 0
- Ricky Doyle secures 70-63 win for No. 19 Michigan over Oregon in Legends Classic 0
- Villanova's win is evidence of why VCU may have peaked as a basketball program 13
- Mike Brey was excited about Notre Dame's loss because the Irish have their closer back 1
Most Commented
- Poll: 54 percent of people think Kentucky beats the 76ers, 54 percent of people are dumb (31)
- Villanova's win is evidence of why VCU may have peaked as a basketball program (13)
- Rick Pitino on blow out win: 'We played four white guys and an Egyptian' (7)
- Michigan's John Beilein rips ESPN for late tip time during Tuesday's loss (7)
- College Basketball Talk's latest top 25: Kentucky reigns, but how far will Kansas, Florida slide? (5)


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Goldman scoops $1.6bn emerging markets mandate
27 June 2013
Goldman Sachs Asset Management has scooped a $1.6bn mandate to invest in emerging market bonds – one of its biggest sub-advisory business wins in Europe in recent years – illustrating investors' continued appetite for these assets despite the recent market sell-off.
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