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Melissa & Doug Play time Wooden Vegetables Play Set
Shop for Cooking and Housekeeping from PlayKitchens.com! Tempting your child to eat veggies will be much easier once he plays with these fresh-from-the-farm veggies! This vegetable playset will show him how much fun good-for-you foods can b...e. Seven garden-fresh vegetables are packed in a wooden storage crate: you get a tomato cucumber red pepper potato onion carrot and an ear of corn. Now your little chef can create well-balanced pretend meals for the whole family. Recommended ages 3-8 years. Read More
Melissa & Doug Smoulder the Dragon Puppet
Melissa & Doug Maggie Leigh Magnetic Dress-Up
The Melissa and Doug Sketch Pad includes 50 sheets of premium, heavy-weight, white bond paper. Your little artist will have a blas...t drawing, sketching, painting, and coloring beautiful masterpieces! The Sketch Pad is perfect for pencils, markers, paints, and crayons! Read More
Melissa & Doug Plush Alligator is a soft, friendly chum from the "wild kingdom"! It's amazing! Over six feet long, this fabulous s...tuffed alligator will inspire lots of affectionate hugs. Every wrinkle and ridge adds to the allure and interest of this reptilian friend. With its excellent quality construction, it will withstand lots of friendly wrassling. Measures 10 x 67 x 26". Fun-inspiring gear from Melissa & Doug to YOU! Order Now! Melissa & Doug Plush Alligator Read More
Meet Maya, the squishable, snuggle-able feline friend with a colorful flair all her own. Unlike other cats, Maya is happy to share... countless hugs and even serve as a comfy nap pillow. Also unlike other cats, she sports rainbow stripes in a cool faux-woven pattern and keeps on smiling through a cycle in the washing machine. Like all Melissa & Doug Beeposh toys, this cool cat is made for comfort and has style galore! Read More
Press & Spin games fit in little boxes - but they're big fun on game night! Melissa & Doug Press and Spin Game - Birthday Bear fea...tures a four traceable pictures of a festive teddy, plus a press-and-pop spinner and colored pencils. Game instructions include multiple ways to use this colorful game set, so it can be enjoyed by preschoolers and their older siblings too! Read More
With her "naturally" curly mane and tail, this unicorn comes straight out of the Land of Make Believe. Over 20" long, she can wrap... around your neck or ride on your shoulder. Make someone special's dream come true with this fantastical unicorn with her soft pink body, sparkling silver horn and sweet expression.Features include: This silky-soft unicorn is everything you imagined, and then some High quality, smooth, polyester plushSurface washableMeasures 21" longFor all ages Read More

Melissa & Doug Cotton Candy - Blue

Brenna Bunny's floppy rabbit body lists endearingly, while her wired ...ears stay strong in any position you choose. Embroidered features, a fluffy tail and a pretty polka-dot bow will make this stuffed animal hop to the top of the toybox.

Product Dimensions: 22 x 8 x 5

Recommended Ages: 6 months & Up

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9161 Features: -Gender:Girl -Gender:Boy -Product Type:Play Animals -Product Type:Rattles And Teethers -Age:9 - 18 Months -Age:Birt...h - 9 Months -Car Seat Toys:Yes -Stroller Toy:Yes -Age Start:5 Months -Age End:2 Years. Dimensions: -Overall Height - Top to Bottom:12.5 -Overall Width - Side to Side:6.25 -Overall Depth - Front to Back:1.5 -Overall Product Weight:0.35 Read More
Find microphones at Target.com! Rise above the din! Use the dynamic microphone from emerson to amplify your voice in a studio, wit...h a pa system, for a karaoke party with your friends or for your own personal home recordings. The sleek mic comes with a... Read More
Find televisions and combos at Target.com! Lg s 55ln5200 delivers stunning picture quality. with led backlighting you get amazing ...brightness, clarity and color detail. and full hd 1080p has almost double the pixel resolution of standard hd so you see... Read More
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Find televisions and combos at Target.com! With its 1080p hd picture, led backlight, dts trusurround, audio and multiple av inputs..., the 50me314v features superb audio and video quality and an affordable versatile design. Read More


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Serbian fighters fight side by side with pro-Russian separatists in eastern Ukraine. According to Belgrade, they're not the only ones active in Ukraine, either.
An unruly beard, army fatigues and an automatic weapon are part of Bratislav Zivkovic's image. The 39-year-old is the leader of the Serb Chetnik militia in eastern Ukraine. He was in Crimea in March where he "defended the Russian brethren."
Now Zivkovic and his comrades are again making headlines. According to the pro-Russian separatist "People's Militia" in the self-proclaimed region of "New Russia" in eastern Ukraine, Serb volunteers fended off an offensive by the Ukrainian army near Luhansk.
The separatists declared that two tanks - including the crew - and other military equipment were destroyed in the fight.
Participants in Crimea
The media has reported that Russian, Chechen and Cossack mercenaries are supporting the pro-Russian fighters in Ukraine. Russia's RIA Novosti news agency wrote that even two "anti-fascist" Spanish and one Czech volunteer showed up.
The Chetnik unit in Ukraine has 46 members, including Russians and a Bulgarian, according to Zoran Andrejic, deputy president of the Serbian Chetnik movement. Serbian guerillas fought in WWII under the name Chetniks, as did Serbian paramilitary troops in the Yugoslav wars in the 1990s.
Andrejic claims that his comrades flew to Moscow in mid-July, from where they supplied Luhansk with humanitarian aid.
"At the Ukrainian border, our men received weapons to protect the convoy," he told DW. "At Luhansk airport, the entire convoy came under massive artillery fire and three of our comrades were injured."
As a result, they decided to create the "New Russian People's Militia." The Chetniks never received money for their operation, Andrejic said, adding they also never demanded payment.
The Chetniks in Luhansk are battle tested, with many having fought in the bloody Yugoslav Wars. "We didn't send inexperienced boys to Ukraine," Andrejic said.
He added that many Russian and Cossack volunteers "defended Serbian lands" in the past. The former military leader of the self-proclaimed Donetsk People's Republic, Igor Girkin, is said to have fought for the Serbs in the Bosnia War, where he met his present Chetnik comrades. Better known by his nom de guerre "Strelkov," Girkin quit his post on Thursday.
Mercenaries on both sides
But Belgrade-based security expert Zoran Dragisic said the mercenaries are more interested in money than in ideals.
"They are after all mercenaries that are recruited worldwide for wars," Dragisic told DW. "At the start of the century, they marched through war zones in Africa - today, they are headed to Syria, Iraq and Ukraine."
Serbian mercenaries are often referred to as "war dogs". But the security expert argues that Serbia's difficult economic situation isn't to blame for the mercenary movement, since even prosperous nations like Germany and the Netherlands grapple with "war tourism."
"It's indoctrination that draws young people – some of them almost children - to war," Dragisic said.
Ninety-nine percent of the Serbian fighters in Ukraine are mercenaries, Serbian Prime Minister Aleksandar Vucic told reporters in Belgrade. Several dozen are fighting on the side of the separatists, Vucic said, adding that several dozen are also fighting for the Ukrainian army.
"They should go back home and take care of their families instead of fighting for third parties' interests – even if they make 2,100 or 6,500 US dollars, depending on what side they're on," the prime minister said, without commenting on his source for the above information.
Belgrade plans to pass a law that penalizes participation in a foreign war. The draft law is aimed at Serbian fighters in Ukraine as well as Muslim Serbs fighting alongside jihadists in the Mideast. Until the law takes effect, Serbian mercenary fighters can return home without having to fear penalties.
Chetnik Bratislav Zivkovic is already planning his return to Serbia – because he expects the fighting to come to an end soon.
Russians appear to be calling the shots among the separatists in Eastern Ukraine. Men from Moscow occupy many of the key positions in the People's Republics of Donetsk and Luhansk. (31.07.2014)
The British prime minister has promised a European course he can't hold and is paying the price. Instead of defending the EU, he undermines it, which will not help in his struggle against UKIP, argues DW's Barbara Wesel.
French President Francoise Hollande has become the first leader from the Western world to visit West Africa since the outbreak of the deadly Ebola disease. In Guinea, he has pledged support from France.
Many Syrians use Bulgaria as a stepping stone to the heart of Europe, although EU rules say refugees are meant to stay put. Krasimir Yankov reports on a Syrian refugee making his way from Sofia to Eisenhüttenstadt.

subset: commoncrawl


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Our last day in San Antonio
... what you are supposed to do when you retire - relax!!!!
We visited the Riverwalk a number of times, visited the Alamo, Historic Market Square, River Center Mall, Gruene, museums, double decker buses, river rides, trolley rides, saloons, great restaurants (Rita's on the River, Tony Roma, Lone Star, Pat O'Brien's, etc.). We were able to have some time on our own and Sandy got to ...
... at LOWES. It should fit in the space without difficulty. It will be delivered to TRS while we're gone and then we will make an appointment to have them install it. We purchased a 3 yr service agreement, but now I wonder how it will be serviced since it will basically be built in. Oh well, hopefully we won't have to worry about ...
Another leak
It rained a little last night and today we found another leak. However, it wasn't from the rain! This time it was the ice maker. There was a large puddle of water at the bottom edge of the refrigerator. We finally found the water turn off, so now we have to buy ice until we decide on the residential refrigerator we want installed. Really would like to get that completed before our New Year's trip. We'll just keep ...
San Antonio, Texas!!
... taken what is essentially a drainage canal, and turned it into this gorgeous walking path with trees, shops and boat cruises. We had dinner on an outdoor patio and watched the people go by.
Our day ended with live music and Texas-sized hurricanes (the drink, not the weather) at Pat O'Brien's. With just one night to spend in San Antonio, I think we did it up right!
Trains, Planes, and Automobiles
... to LHR (London Heathrow). Sit next to English gentleman who lives in Munich and who is on his way home for 3-week holiday. Listen to him say that the Germans have no sense of humor and do not know how to queue up in an orderly fashion. Stifle giggles.
9 AM Sat, London/2:00 AM Sat, San Antonio - Arrive at LHR. Proceed to American Airlines (AA) desk to see if our upgrade to Business Class went through. Answered ...


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TechNavio's analysts forecast the Global Packaged GaN LED market to grow at a CAGR of 12.1 percent over the period 2012-2016. One of the key factors contributing to this market growth is the increased adoption of packaged GaN LEDs in the Lighting segment. The Global Packaged GaN LED market has also been witnessing the miniaturization of packaged GaN LEDs.However, the demand and supply imbalance of packaged GaN LEDs could pose a challenge to the growth of this market. TechNavio's report, the Global Packaged GaN LED market, has been prepared based on an in-depth market analysis with inputs from industry experts. The report covers the Americas, and the EMEA and APAC regions; it also ... Click here for more details
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U.S. auto regulator Orders Expansion of Takata Air Bags Recalls
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Telecom Italia Expresses Interest in Buying Stake in Metroweb
Italian telecommunications company Telecom Italia has expressed its desire to buy a controlling stake in Metroweb – Italian fiber optic provider. Telecom Italia is looking to increase its investments in faster networks and is being met with stiff competition from rival Vodafone who is also reportedly courting Metroweb. Metroweb is owned by F2i, an infrastructure fund. F2i spokesperson informed the media that Metroweb had been getting investors for quite some time but the company h
Baker Hughes to be taken over by Halliburton
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Native advertising is having its big moment. When done right, it has tremendous pull with consumers. According to Nielsen, native ads produce as much as an 82% in brand lift. An infographic from MDG Advertising says 70% of individuals reported that they would prefer "to learn about products through content rather than through traditional advertising."
Dec 19, 2003
PureEdge Solutions Inc., a provider of automation for form-based business processes, has been awarded a contract to provide secure, browser-based eforms for the grants.gov egovernment initiative. With this deal, PureEdge XML eforms will be used for grants.gov's grant applications. It is projected that 15,000 users will submit grants through the portal during the system's first year of operation.
The grants.gov portal is part of the President's egovernment initiative and is intended to provide a single, secure, and reliable source for applying for Federal Grants online. Applicants will download and fill out forms offline, and then submit them with proper authentication. By offering an electronic means of submitting grant applications, grants.gov intends to improve service delivery methods while creating internal efficiencies by streamlining processes and eliminating redundancies.
PureEdge technology is based on document-centric, XML-based architecture to provide organizations with the power to manage the lifecycle of business processes, including creation, routing, management, and archiving. With PureEdge, grants.gov users will have the ability to digitally sign documents, use both ad hoc and structured routing, work remotely, move data in and out of corporate systems, and store all elements of a process in one file. This integration of PureEdge's front-end technology with grants.gov's existing backend architecture is intended to create a complete content management solution.


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The Beacon
The Dirty Weather Report
Between regular 100-year storms, record heat waves and epic droughts watching the weather channel has certainly become more interesting of late. This is "dirty weather" according to the Climate Reality Project, that is, weather that is increasingly influenced by carbon dioxide pollution from burning fossil fuels. That's why starting at 8pm tonight they are airing their Dirty Weather Report, a 24-hour live online broadcast hosted by former vice-president and Nobel laureate Al Gore and featuring comedians, musicians and experts to bring light to the many different ways a changing climate is changing the world around us.
Make sure to tune in and learn more about climate change and what you can do to help.
Most Viewed
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- Ocean Roundup: Dolphins Use Whistles as Names, Conservationists Call for Removal of Queensland Shark Nets, and More Posted Mon, November 24, 2014
- ICCAT Moves to Properly Manage Bluefin Tuna, but Doesn't Take Action for Sharks and Swordfish Posted Wed, November 26, 2014
- Oceana in Chile Submits Recommendations for Lowering Common Hake Catch Quotas Posted Mon, November 24, 2014


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It's time for some mini golf!! The kids can pretend they aren't really back in school and the adults can pretend they did the whole course in 12 swings. Never mind it is 18 holes...
Stay for pizza afterwards to chat if you can. This event will be weather permitting like always.
I have to admit that cfi impressed me as populated by socialist atheists, which are very common. But I can probably meet some Capitalist atheists. Not to sound Objectivist or condescending. I have to admit to being staunchly capitalist. But not intolerant.
0 · September 19, 2013
I'm surprised by the level of growth I've seen since becoming an organizer, it's given me more confidence in my abilities.
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Fundraisers ramp up the red for vital heart charity
Last updated at 16:38, Thursday, 13 February 2014
"BRITISH Heart Foundation saved my life."
By Mark White and Lucy Grosvenor
Kathleen France had heart surgery and benefited from the British Heart Foundation's services, and is in no doubt of the importance of last Friday's BHF Ramp Up The Red day.
"I had a mechanical valve fitted and the BHF were fantastic," said Kathleen, a sales advisor at Dixons in Whitehaven, where a fundraising day was held.
"I had the choice between having a pig's valve or a mechanical valve and, without the BHF, I would never have had the choice.
"The pig's valve would have had to be replaced after 10 years so it was a really important choice.
"They helped me through everything and even now they still offer support and I get their magazine which is where I found out about doing the event."
Moved by Kathleen's story, the staff at the Dixons store, Whitehaven all bought T-shirts, had a raffle and have offered a quiz to customers, all to raise money for BHF's Ramp Up The Red.
"This charity really does make a difference to people's lives and until you're involved in something they do, you don't appreciate just what an amazing job they do.
"They are so important to so many people and I'm glad that we can give something back," said Kathleen.
Michelle McAvoy, fashion manager at Dixons, added: "Not only are we hoping to raise money for the cause but we also want to raise awareness by wearing our T-shirts and with the other things going on in the store.
"It's a great cause because I think everyone knows someone who has had heart trouble, so it's a cause that almost everyone can relate to and we're really hopeful we can raise lots of money and do our bit."
Dixons raised £100.
An event at Kells Rugby League Football Club also saw red for the BHF day. Members of the Fit4Life outreach cardio rehab class, at Kells ARLFC, made exercise fun with red wigs and cakes.
Instructor, Becky Scott, said: "It is so important that we look after our hearts. Many of the people who use the cardio rehab service have suffered heart problems in the past so it really is a cause that many feel grateful to."
Beverly Foulder, another instructor, said: "Heart problems are still the biggest killer in the UK so we need to keep raising awareness."
Albert Adams, 72, uses the service. He said: "I was in a car accident in 2006 and in hospital for nearly a year after.
"I constantly need to be looking after my heart so I'm happy to ramp up the red for today. The services offered by Fit4Life cardio rehab are vital to people like me."
The Fit4life event raised £58.
First published at 11:08, Thursday, 13 February 2014
Published by http://www.whitehavennews.co.uk
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Marussia said Bianchi will drive at Barcelona on Saturday and Sunday, the final two days of winter testing before the new Formula One season starts in Melbourne on March 17.
"We have found ourselves in a situation where we have had to terminate our contract with Luiz Razia," said Marussia team principal John Booth.
"Having made clear the basis on which we must operate in 2013, and given the steps we had taken to put that new structure in place, we had no alternative but to remain true to the principles which we had identified as being key to securing our long-term future." Razia told www.autosport.com that he was stunned by losing the Marussia drive.
"I'm in a kind of shock, because you expect to be in F1, you are there, announced, testing, and then you are out -- and not because of a driver fault," he said.
"I did everything right in what I could do, but it was really just a circumstantial thing that happened, and that was it."
He added: "I could be angry. I could be very selfish, but I am not. I am really tolerant with these things.
"I understand the position of Marussia and I like the team. They treated me very nicely there and, to be honest, they were trying to sort out the situation for me. They chose me because they wanted me there in the first place, so there are no hard feelings.
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Photography Equipment Reviews
Buying the right camera, lens, accessory or software to suit your photography is really important. Our product reviews offer independent views with hands-on opinion and honest verdicts aimed to give you all the important information you need to make the best buying decisions.
Nikon 45mm f/2.8D ED PC-E Micro Lens Review
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Sigma 17-70mm f/2.8-4.5 Macro DC lens test
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text:
Nothing but light eminates from her heart. Yes that is what I said , her heart.
As sensitive as a dandelion, blow on it and she desperses beauty and warmth
to every heart that opens to her. (Report) Reply
Ellias Anderson C.A ( Known as captain A)
For Unwritten soul_ a limerick
There is a phenomenon named Soul,
A super human with a light core,
Unwritten with an infinite kind
A soul with a beautiful mind
A friend with a big lore.
Ellias Anderson C.A ( Known as captain A)'s Other Poems
Read this poem in other languages
This poem has not been translated into any other language yet.
I would like to translate this poem »
Poet's Notes about The Poem
Comments about this poem (For Unwritten soul_ a limerick by Ellias Anderson C.A ( Known as captain A) )
Thomas A Robinson (7/14/2013 4:39:00 AM)
Nothing but light eminates from her heart. Yes that is what I said , her heart.
Nader Baheri (6/29/2013 4:21:00 AM)
you really have a generous heart. you can place soul in your heart.even it s unwritten.
let soul be soul and still unwritten and still new for all of us.
fabulous~nb (Report) Reply
Captain Cur (6/21/2013 10:53:00 AM)
Great write, you captured the soul of Soul
in this fine poem. (Report) Reply
Anthony Di''anno (6/21/2013 9:13:00 AM)
Lovely Elias :) A spontanious heartburst for the whole world to see. You and Unwritten Soul are both beautiful spirits. (Report) Reply
Poetheart Morgan (6/20/2013 1:46:00 PM)
Dear Poet a great homage to a poet friend. Very well written! ! ! ! (Report) Reply
Unwritten Soul (6/20/2013 2:14:00 AM)
Love it, you always my lil quack! of course you are my lil sibling too...thanks dear Ellias_Soul (Report) Reply
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MRTI: Pro Mazda plus some other MRTI drivers in action this weekend
Jun 26, 2014, 10:14 AM EST
Following a month-long break since the Freedom 100 (Indy Lights Presented by Cooper Tires) and the Night Before the 500 at Lucas Oil Raceway (Pro Mazda Presented by Cooper Tires and the Cooper Tires USF2000 Championship Powered by Mazda), the Mazda Road to Indy resumes starting this weekend with two different elements.
Pro Mazda is in action to support the Verizon IndyCar Series at Houston, while some other MRTI past or present drivers are in action at Watkins Glen for the TUDOR United SportsCar Championship Sahlen's Six Hours at the Glen.
After his double win at the Grand Prix of Indianapolis weekend and a runner-up finish at the Night Before the 500, Scott Hargrove has closed the gap on Spencer Pigot to just three points (180-177). Pigot went four-for-four to open the year before Hargrove and Garett Grist have won the last three races.
The Hargrove-Pigot battle isn't limited to open-wheel, as both were in action last week in the Ultra 94 Porsche GT3 Cup Challenge Canada by Michelin at Calabogie. Hargrove took a win in the second race of the weekend for his third triumph in four starts there; he currently leads that points table by four points over Chris Green, with Pigot third in the standings (78-74-54 the gaps there).
At Houston last year, Pigot had one second in Pro Mazda and Hargrove one third, so both seek their first wins on the treacherous and bumpy street circuit this weekend.
The battle isn't limited to these two, though. Grist and Andretti Autosport teammate Shelby Blackstock look to break through. Blackstock's had a whirlwind couple of months where he's raced in Pro Mazda, the Continental Tire SportsCar Challenge with the GS class Fall-Line Motorsports BMW M3, and also in the Nurburgring 24 Hours last weekend.
Respective teammates for Pigot (Juncos Racing) and Hargrove (Cape Motorsports with Wayne Taylor Racing), Kyle Kaiser, Jose Gutierrez and Julia Ballario (Juncos) and Neil Alberico (Cape) have shown flashes of brilliance this season and look for their first wins of the year.
There's two new drivers as well with USF2000 drivers Clark Toppe and Felipe Donato moving up to Pro Mazda for the weekend with JDC Motorsports and M1 Racing, respectively. The two races are at 1:05 Saturday and 1:00 Sunday.
The 55-car field for the TUDOR United SportsCar Championship round features a number of Mazda Road to Indy alumni in the field, and the current Indy Lights points leader.
Gabby Chaves steps in once again to the DeltaWing coupe in Prototype, which he's raced at both Daytona and Sebring and now shares solo with Katherine Legge this weekend. Chaves has also been involved in a couple tests for the team, where he's continued to learn and develop as a driver.
Elsewhere recent Indy Lights alumni Gustavo Yacaman (No. 42 OAK Racing), Sage Karam (No. 01 Chip Ganassi Racing), Tristan Vautier (No. 07 SpeedSource), David Ostella (No. 38 Performance Tech Motorsports), Martin Plowman (No. 88 BAR1 Motorsports) and Rusty Mitchell (No. 08 RSR Racing) will be in the field in the P and PC classes. There are other Indy Lights graduates who raced in the 1990s and early 2000s; the numbers get higher the longer back you go.
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Iowa Hawkeye News, Links, and Chatter
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About Me
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Tuesday, March 15, 2011
Hawkeye Links | Hoops Gain a Commit Lose Out on Another
It was an interesting day yesterday on the Hoops recruiting trail. Hawkeye basketball picked up a commitment for 2012 from Kyle Meyer. Meyer is a 6'10" forward from Georgia.
Scott Dochterman, of the Cedar Rapids Gazette, writes that Meyer considers himself a
forward despite the size
for the center position.
He is the first member of coach Fran McCaffery's 2012 recruiting class and he
hopes to help turn things around
Jon Miller's Hawkeye Nation posted a video and has
more on Meyer committing here
Well, the Lord giveth, the Lord taketh away. Cezar Guerrero caused quite a buzz around Iowa City when he made his visit. The body language experts were out in full force watching his every move and expression. From that perspective things looked good for the Hawks but it goes to show you can't try to read the minds of 17 year olds. Guerrero ended his recruitment with a
commitment to Oklahoma State last night
. The Hawkeyes finish second, again.
That means it's time to move on to "next man in," to steal a mantra from the football team. Anthony Hubbard visited Iowa City the same weekend Cezar was in town. Could he be next? Hubbard, if you recall, was the recruit with a bit of a past.
Pat Harty discussed Hubbard
a bit yesterday and had more details about Hubbard's arrest and reason for four years spent in jail.
Eli Carter's
name has been listed by recruiting sites as interested in Iowa. Rob Howe, of Hawkeye Insider, wrote that Carter still has Iowa in the mix back in February. Nothing new on that front has emerged recently.
Another name that Hawk fans might want to keep an eye on,
Tyler Harris
. The 6'8" forward chose NC State over Iowa but NC State's coach Sidney
Lowe is rumored to be fired soon
, possibly today. If that happens perhaps Harris would look to open back up his recruitment?
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Miami-Dade Dolphins stadium referendum could be May 14
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Miami-Dade Commissioners could hold a special meeting as early as Wednesday to discuss a proposed agreement with the Miami Dolphins to help fund $390 million in stadium upgrades.
Miami-Dade Mayor Carlos Gimenez told WIOD-AM (610) that Dolphins owner Stephen Ross and team CEO Mike Dee met with him Sunday to finalize the details of the agreement, which would propose to raise the county's mainland hotel bed tax to 7 cents from 6 cents. A referendum is proposed for May 14 to give county residents the ability to weigh in on the funding, according to The Miami Herald. The National Football League is set to announce future Super Bowl host cities on May 22.
On Friday, the Florida Division of Election ruled that the team could cover the $5 million tab for the referendum, a cost the team has already committed to pay.
The county's contribution could be as much as $120 million, with the state potentially providing $47 million through a tax rebate over 30 years. The team would pay the balance, and might be eligible for financing through the NFL.
The team has committed to paying back both the state and the county for its principal investment after its 30-year agreement sunsets.
All the state legislative committees vetting the Dolphins stadium bills that provides for a state subsidy have approved it, so far. Legislators go home May 3.
Throughout the Dolphins campaign to get the subsidies, auto dealer Norman Braman has maintained that the county's contribution to help fund upgrades for a private stadium is tantamount to welfare for billionaires.
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Novel synthesis of flavonoids of Scutellaria baicalensis Georgi.
ABSTRACT A concise and efficient total synthesis of the flavonoids baicalein, oroxylin A and wogonin was described. Intramolecular oxidative cyclization followed by demethylation of chalcone 1, readily prepared from trimethoxyphenol, afforded, depending upon the controlled conditions, baicalein or oroxylin A in excellent yields. Demethylation of 1 yielded 3, which, by oxidation with I(2)/dimethyl sulfoxide (DMSO), was readily converted to oroxylin A and wogonin after column chromatography.
Article: Synthesis of chromone carboxamide derivatives with antioxidative and calpain inhibitory properties.[Show abstract] [Hide abstract]
ABSTRACT: The overactivation of μ-calpain can cause serious cell damage in several diseases. Furthermore, cell death in a number of neurodegenerative disorders is linked to the overproduction of reactive oxygen species. Therefore, antioxidants and μ-calpain inhibitors could have the therapeutic potentials to treat cell death related diseases. New chromone carboxamide derivatives 3 were synthesized to provide alternative μ-calpain inhibitors to compound 2, a conformationally constrained structural variant of MDL 28,170. Compounds 3h and 3l exhibited the most potent μ-calpain inhibitory activities (IC50=0.09-0.10 μM), and were comparable to 2 in this respect (IC50=0.07 μM). Compound 3i showed both potent μ-calpain inhibitory activity (IC50=0.28 μM) and antioxidant activities in DPPH scavenging and lipid peroxidation inhibition assays.European Journal of Medicinal Chemistry 02/2011; 46(5):1721-8. · 3.43 Impact Factor
Article: Structural Alterations of Wogonin Significantly Reduce the Inhibitory Activity against COX2 Catalyzed PGE 2 Production from LPS-Induced RAW 264.7 CellsBiomolecules & Therapeutics - BIOMOL THER. 01/2009; 17(4):418-421.
Article: Protective Effect of Baicalein Extracted from Scutellaria baicalensis against Lipopolysaccharide-Induced Glomerulonephritis in Mice[Show abstract] [Hide abstract]
ABSTRACT: This study was to evaluate the therapeutic effect of baicalein, extracted from Scutellaria baicalensis , on lipopolysaccharide (LPS)-induced glomerulonephritis in mice. For this purpose, bacterial LPS (2.5 mg/kg/day) was injected intraperitoneally (i.p.) for 14 days to induce glomerulonephritis; then mice were treated with baicalein (150 mg/kg/day) by oral gavage for 14 days. In comparison to samples from mice receiving only LPS injection, oral administration of baicalein significantly attenuated the rise of serum levels of blood urea nitrogen and creatinine, prtoeinuria, kidney wet-to-dry weight ratio as well as renal glomerular cell proliferation induced by LPS. Moreover, treatment with baicalein decreased the urine NOx (nitrite+nitrate) concentration and serum levels of proinflammatory cytokine including tumor necrosis factor-α, interleukin-1β and interleukin-6 accompanied by suppression of inducible nitric oxide synthase and cyclooxygenase-2 expression and prostaglandin E2 production in renal tissue relative to LPS-injected alone mice. Similarly, the LPS-induced increase of urine 8-iso-prostaglandin F2α, a marker of reactive oxygen species, was also markedly inhibited by baicalein. The present results demonstrate that baicalein possesses antiinflammatory and antioxidant properties that may be of benefit against the deleterious actions of LPS in glomerulonephritis.International Journal of Pharmacology. 01/2010;
Page 1
Baicalein, oroxylin A and wogonin are the three major
flavonoids of Scutellaria baicalensis GEORGI, a traditional
Chinese herb used since the ancient time, characterized by
possessing a very broad spectrum of biological activities, no-
tably anti-oxidant.1)In literature, there have been no appro-
priate approaches available for a facile synthesis of those
structurally similar flavonoids. Our interests in their unique
pharmacological properties prompted us to pursue a perti-
nent route toward the very efficient preparation of such
highly prized targets.
In general, procedures for laboratory synthesis of
flavonoids are still based today on the approaches originally
developed by Robinson2)or exerted by the Baker–Venkatara-
man rearrangement,3,4)synthesis via chalcones,5)and synthe-
sis via an intramolecular Wittig reaction.6)At the outset, we
followed the reported methods specifically for the synthesis
of baicalein,7,8)oroxylin A9)and wogonin.10)However, we
found that they all suffered either from involving a number of
steps giving too low overall yields or from encountering con-
siderable challenges due to irreproducible workout. Attempts
to synthesize baicalein from trimethoxyphenol by either the
modified conventional Baker–Venkataraman approach11)
proved to be impractical (below 10% yield) or the Wittig
strategy6)completely failed. Therefore, our strategy for syn-
thesis of baicalein turned to employing chalcone 1 as the
starting material while the demethylation was performed at
the last stage.
Our approaches (Chart 1) for construction of baicalein,
oroxylin A and wogonin relied on the preparation of flavone
March 2003Notes
Chem. Pharm. Bull. 51(3) 339—340 (2003) 339
* To whom correspondence should be addressed.e-mail: firstname.lastname@example.com © 2003 Pharmaceutical Society of Japan
Novel Synthesis of Flavonoids of Scutellaria baicalensis GEORGI
Wen-Hsin HUANG, Pei-Yu CHIEN, Ching-Huey YANG, and An-Rong LEE*
School of Pharmacy, National Defense Medical Center; Taipei, Taiwan.
Received October 15, 2002; accepted December 12, 2002
A concise and efficient total synthesis of the flavonoids baicalein, oroxylin A and wogonin was described. In-
tramolecular oxidative cyclization followed by demethylation of chalcone 1, readily prepared from trimethoxyphe-
nol, afforded, depending upon the controlled conditions, baicalein or oroxylin A in excellent yields. Demethyla-
tion of 1 yielded 3, which, by oxidation with I2/dimethyl sulfoxide (DMSO), was readily converted to oroxylin A
and wogonin after column chromatography.
Key words
baicalein; oroxylin A; wogonin
Chart 1
Page 2
2 and chalcone 3 as penultimate targets derived from chal-
cone 1, readily prepared by treatment of easily accessible
trimethoxyphenol with excessive acetic acid in the presence
of BF3–Et2O,12)followed by a Claisen-Schmidt condensation
with equimolar benzaldehyde,3,4)best catalyzed by KOH, in
66% overall yield. Alternatively, a better yield (90%) was
achieved by direct acylation of trimethoxyphenol with
equimolar cinnamoyl chloride, also in the presence of
One of the most common methods in preparation for
flavonoids such as 2 involves an intramolecular oxidative cy-
clization of chalcone,5)i.e. 1. However, formation of the pre-
requisite flavone 2 triggered by SeO2/EtOH7,13)or Pd(OAc)2/
AcCN14)consistently led to extremely low yields (below
10%). This difficulty of cyclization, the phenyl ring bearing
polyphenols (more than 3 OH's) later turned out to be the
culprit, made us turn to non-metal oxidants. Among them,
I2/dimethyl sulfoxide (DMSO)15)proved to be the most
promising and the reaction proceeded smoothly and ended up
with 2 in a much superior yield (87%). Surprisingly, at-
tempted demethylation of 2 to obtain baicalein in a solution
of 47% HBr/AcOH (1:2) at reflux for 2h gave, after isola-
tion, an unexpected yet desired product oroxylin A (88%) ex-
clusively, validated by fruitless acetonidation in addition to
spectroscopy.16)Further reaction under the same condition
over 12h yielded baicalein (81%). Alternatively, a straight
18-h hydrolysis of 2 proceeded in the same methodology also
afforded baicalein in excellent yield (89%).
In a similar fashion, demethylation of 1 in a solution of
47% HBr/HOAc (1:2) at reflux for 2h gave 3 (91%) which
was susceptible to oxidation with I2/DMSO to procure a mix-
ture of oroxylin A (46%) and wogonin (24%), readily sepa-
rated by flash chromatography.
In conclusion, we have successfully attained an extremely
efficient route for the preparation of baicalein, oroxylin A,
and wogonin. To our best knowledge, for total synthesis of
these three pharmacologically diversified flavonoids, our ap-
proach is the only practical path featuring in beginning with
a common starting material, using affordable reagents and
proceeding under mild conditions and thus suitable for large-
scale pilot-plant synthesis. Various flavone derivatives are
now being prepared in our laboratory by the above-men-
tioned methodology with a view to extensively evaluating
their biological activities. The experimental details and bio-
logical data will be published shortly.
Melting points were determined on a Buchi-530 melting point apparatus
(uncorrected). IR spectra were recorded on a Perkin-Elmer FT-IR 1600 se-
ries FT-IR spectrophotometer. 1H-NMR spectra were determined on a Varian
Gemini-300 NMR instrument. Mass spectra were recorded on a Finnigan
MAT TSQ-46 or Finnigan MAT TSQ-700 mass spectrometer. UV spectra
were recorded on a Shimadzu UV-160A spectrophotometer.
1-(2,3,4-Trimethoxy-6-hydroxyphenyl)-3-phenylpropen-1-one (1)
mixture of 3,4,5-trimethoxyphenol (3.7g, 20mmol) and cinnamoyl chloride
(3.7g, 22mmol) was dissolved in BF3–Et2O complex (20ml) and heated to
reflux for 15min, and then quenched with excess of water. Filtration and re-
crystallization from hexane:EtOAc (3:1) gave chalcone 1 (5.6g, 90%) as
reddish-yellow crystals. Alternatively, 1 could be prepared by acylation of
3,4,5-trimethoxyphenol12)and, without further purification, followed by con-
densation with benzaldehyde in the presence of KOH3,4)(66%): mp 98—
100°C. 1H-NMR (CDCl3) d: 3.82 (3H, s), 3.96 (3H, s), 4.03 (3H, s), 6.34
(1H, s), 7.45—7.48 (3H, m), 7.67 (2H, d, J?9.3Hz), 8.06 (2H, d, J?15.5
Hz), 8.33 (2H, d, J?15.5Hz). IR (KBr) cm?1: 3419, 1608. MS m/z: 315
5,6,7-Trimethoxyflavone (2)
dine (200mg) in DMSO (25ml) was refluxed for 2h, and then carefully
poured onto crushed ice (200g). The precipitate was filtered and washed
with 20% Na2SO3. Purification by flash column chromatography (SiO2,
hexane:EtOAc?3:1) yielded 6.3g (87%) of 2 as white crystals, which
turned into pale yellow after standing for about one month, and recovered
0.8g (2.5%) of 1: mp 146—147°C (lit.17)164—165°C). 1H-NMR (DMSO-
d6) d: 3.93 (3H, s), 3.97 (3H, s), 3.99 (3H, s), 6.72 (1H, s), 6.83 (1H, s), 7.50
(3H, m), 7.88 (2H, d, J?8.7Hz). IR (KBr) cm?1: 1633. MS m/z: 313
Oroxylin A
A solution of 2 (0.20g, 0.64mmol) in 47% HBr (5ml) and
glacial acetic acid (10ml) was refluxed for 2h, and then carefully poured
onto crushed ice (200g). The resulting yellow precipitate was filtered and
collected. Recrystallization from ethanol afforded 160mg (88%) of oroxylin
A as bright yellow crystals: mp 203—204°C. (lit.9)195—197°C). 1H-NMR
(DMSO-d6) d: 3.91 (3H, s), 6.94 (1H, s), 6.98 (1H, s), 7.59 (3H, m), 8.10
(2H, d, J?6.3Hz), 8.77 (1H, s), 12.49 (1H, s). IR (KBr) cm?1: 3435, 1667.
UV lmax(EtOH) nm (loge): 322 (4.12), 278 (4.35), 216 (4.42). MS m/z: 285
Baicalein, as bright yellow crystals, was prepared by the
modified procedure outlined above either from oroxylin A (reflux, 12h) or 2
(reflux, 18h) in 81% and 89% yield, respectively: mp 258—260°C (lit.7)
263—264°C). 1H-NMR (DMSO-d6) d: 6.61 (1H, s), 6.92 (1H, s), 7.56 (3H,
m), 8.05 (2H, d, J?8.1Hz), 8.81 (1H, s), 10.57 (1H, s), 12.65 (1H, s). IR
(KBr) cm?1: 3411, 1654. UV lmax(EtOH) nm (loge): 326 (4.17), 276
(4.42), 215 (4.49). MS m/z: 270 (M?).
Pure 3 (0.52g, 1.8mmol), prepared by the procedure outlined
above (reflux, 2h) from chalcone 1 (0.62g, 2.0mmol) in 91% yield, was
subject to oxidative cyclization as previously described. Purification by flash
chromatography (silica gel, CH2Cl2®hexane/EtOAc (3/1)®CH2Cl2/EtOAc
(5/1)) and then recrystallization from ethanol gave oroxylin A (238mg,
46%) and bright yellow crystals of wogonin (124mg, 24%), respectively.
Chalcone 3: mp 121—122°C. 1H-NMR (DMSO-d6) d: 2.78 (1H, d, J?13.4
Hz), 3.82 (3H, s), 5.56 (1H, d, J?13.4Hz), 6.27 (1H, s), 7.40—7.54 (5H,
m), 8.21 (1H, s), 11.72 (1H, s). IR (KBr) cm?1: 3445, 1666. FAB-MS m/z: 287
(MH?); Wogonin: mp 198—199°C. (lit.10)203°C). 1H-NMR (DMSO-d6) d:
3.81 (3H, s), 6.30 (1H, s), 7.00 (1H, s), 7.37 (1H, s), 7.64 (3H, m), 8.10 (2H,
d, J?6.3Hz), 12.51 (1H, s). IR (KBr) cm?1: 3445, 1667. UV lmax(EtOH)
nm (loge): 321 (4.15), 276 (4.36), 216 (4.44). FAB-MS m/z: 285 (MH?).
A mixture of 1 (7.2g, 23mmol) and io-
NSC 91WFE0100105 and 91WFE0100114 supported in part from the Na-
tional Science Council of the Republic of China.
We gratefully acknowledge the research grants
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340 Vol. 51, No. 3


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Baby Geniuses is a 1999 family-oriented comedy film directed by Bob Clark. It stars Kathleen Turner and Christopher Lloyd.
Baby: Secret of the Lost Legend is a 1985 American adventure fantasy film directed by Bill L. Norton and starring William Katt, Sean Young, Patrick McGoohan, and Julian Fellowes. The story is based on rumors about dinosaur-like creatures (called Mokele-mbembe) purported to exist in Africa.
Baby's Day Out is a 1994 American family comedy adventure film, written by John Hughes, produced by Richard Vane and John Hughes, and directed by Patrick Read Johnson. The film stars twins Adam and Jacob Worton as Baby Bink with co-stars Joe Mantegna, Joe Pantoliano and Brian Haley as the film's three incompetent antagonists. The plot centers on a wealthy baby's kidnapping by three incompetent villains, his escape and adventure through a big city while being pursued by the three kidnappers.
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Northern District of California Cases
Cases filed
Cases 1 - 10 of 75,161
Operating Engineers' Health and Welfare Trust Fund for Northern California et al v. Jacobson Excavation, LLC, a Utah Limited Liability Company
as 3:2014cv05173
Cause Of Action: E.R.I.S.A.: Employee Retirement
Type: Labor > Labor: E.R.I.S.A.
Nieves v. County of San Mateo
as 3:2014cv05160
Cause Of Action: Fair Labor Standards Act
Type: Labor > Labor: Fair Standards
Nationwide Biweekly Administration, Inc. v.Jan Lynn Owen
as 5:2014cv05166
Cause Of Action: Federal Question: Other Civil Rights
Type: Civil Rights > Civil Rights: Other
Brown-Seals v. Allman
as 5:2014cv05152
Cause Of Action: Petition for Removal- Civil Rights Act
United States of America v. Walnut Private Equity Fund L.P.
as 3:2014mc80324
Type: Other Statutes > Other
Rutherford et al v. Palo Verde Health Care District et al
as 3:2014mc80326
Type: Other Statutes > Other
Mitsui O.S.K. Lines, Ltd. v. Whale Logistics (Shanghai) Co., Ltd.
as 3:2014cv05163
Cause Of Action: Shipping
Type: Contract > Contract: Marine
Beta Soft Systems, Inc. v. Modis, Inc.
as 3:2014cv05169
Cause Of Action: Diversity-Other Contract
Type: Contract > Contract: Other
Plaintiff v. Defendant
as 4:2014cv05175
Cause Of Action: Fair Debt Collection Act
Type: Other Statutes > Consumer Credit
as 5:2014cv05174
Cause Of Action: Diversity-Breach of Contract
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Summer Design Coconut cocktail on the beach under palm trees Coconut milk cocktail with hibiscus flower Coconut palm tree and stars Beach bar on holiday or beach bar in the Club
This great product in royal blue from our department Kids & Babies and T-Shirt category can be printed just for you in the size and style you like. The design Coconut cocktail on the beach under palm trees was created by namo and uploaded to Spreadshirt for you to have printed on a T-Shirt. Next to a host of other great designs, you can find this Coconut cocktail on the beach under palm trees design in Spreadshirt's Miscellaneous category. If you are interested in topics like Beach or Bär, then you'll love Coconut cocktail on the beach under palm trees designs by namo. Spreadshirt also offers a huge selection of personalised T-shirts, hoodies and accessories for the category Miscellaneous as well as top alcohol clothing. namo's designs have already impressed many of our customers, so we are sure that we've got right stuff for you! Spreadshirt is your shop for great designs of all kinds – whether it's Beach, Bär or alcohol. We are sure that you will find something nice in our shop, there are many amazing personalised Miscellaneous T-shirts, jumpers or accessories for you to find! Tags: Design ID: 11960156
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Hello to you here on Audiko.net! You can easily download a free Hans Rotmo ringtones for your iPhone or mobile. Select your favorite line from your favorite thing - Hшvlerivisa, Laustenn, Laustennern, or any other track. Then download the prepared Hans Rotmo ringtones to your gadget, and enjoy Norwegian music by Hans Rotmo every time your phone rings. If you prefer Norwegian or maybe Rock and Norsk music, then you will probably like terje tysland, Sie Gubba, or Åge Aleksandersen as well. For all who want a free Hans Rotmo ringtone, we also recommend listening to Christmas, Viser, and Party. Depending on a phone model, you can download your tone both in the MP3 and m4a formats, supported by both mobile phones and iPhones. Just select a track, and choose free Hans Rotmo ringtones download option.
Download Hans Rotmo Ringtones
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|Vårres jul
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Hans Rotmo
30 Nov 2002
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30 Nov 1989
Hans Rotmo
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John Harris
President and CEO
Coulson Oil Inc.
North Little Rock
Age: 50
John Harris
John Harris was promoted to CEO of Coulson Oil in 2013 after the resignation of David Zakrzewski, who remained on the board of directors.
Harris had previously done several jobs at the company, including manager of environmental compliance, manager of petroleum services and, immediately before his promotion, vice president and chief operating officer. Coulson Oil ranked at No. 16 on Arkansas Business' most recent list of the state's largest private companies with revenue of $606.3 million in 2013.
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