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US 4210687 A Abstract A method for the coating of glass surfaces in order to prevent the scattering of glass particles upon bursting, with a transparent, duroplastic protective coat by depositing a paste of hydroxy group-containing 1,2-epoxy compounds with at least one 1,2-epoxide group in the molecule and a lower melting point of more than 40 hardening agents, and hardening the overlay at higher temperatures; which comprises first treating the clean glass surface with an aqueous or alcoholic silane skim coat, drying said surface if necessary and thereafter warming said surface to a temperature up to 120 coating the glass surface with said paste of hydroxy group containing 1,2-epoxy compounds and hardening said paste with further addition of heat, wherein said hardening agents are polyisocyanates blocked with cyclic amidines of the general formula ##STR1## wherein the R's are the same or different substituents selected from the group consisting of hydrogen, alkyl-, cycloalkyl-, arylalkyl- and aryl, wherein the hardening agent is added in an amount of 2-15% by weight, calculated with respect to the amount of 1,2-epoxide compounds.
Claims(9) 1. A method for the coating of glass surfaces, in order to prevent the scattering of glass particles, with a transparent, durpolastic protective coat by depositing a paste of hydroxy group-containing 1,2-epoxy compounds, with at least one 1,2-epoxide group in the molecule and a lower melting point of more than 40 hardening the overlay at higher temperatures, which comprises
first treating the clean glass surface with an aqueous or alcoholic silane skim coat, drying said surface if necessary and thereafter warming said surface to a temperature up to 120 coating the glass surface with said paste of hydroxy group-containing 1,2-epoxy compounds and hardening said paste with further addition of heat wherein said hardening agents are polyisocyanates blocked with cyclic amidines of the formula: ##STR4## wherein R's are the same or different substituents selected from the group consisting of hydrogen, alkyl-, cycloalkyl-, arylalkyl-, and aryl, wherein the hardening agent is added in an amount of 2-15% by weight, calculated with respect to the amount of 1,2-epoxide compounds. 2. A method for the coating of glass surfaces according to claim 1, wherein said cyclic amidine-blocked polyisocyanate is a diisocyanate compound of the formula ##STR5## wherein, n=0 or 1; X=0, S or a NH-group, R can be the same or different radicals selected from the group consisting of hydrogen, alkyl-, cycloalkyl-, aralkyl- and aryl radicals; R' is an alkylene-, cycloalkylene, or arylene radical and R" is a saturated or unsaturated alkylene radical with 2-18 C-atoms which if necessary may contain one or more oxygen- or sulfur atoms in the hydrocarbon chain, and which can be if necessary substituted by one or more alkyl radicals, whereby more than one radical can mutually join to a cycloaliphatic ring, or R" is cycloalkylene radical.
3. A method according to any of claims 1 or 2, wherein the coated glass surface is hardened at a temperature in the range of 130
4. A method according to any of claims 1-2, wherein soluble dyes are added to the coating pastes.
5. A method according to any of claims 1-2, wherein coating of the glass surfaces is carried out with powder-forming coating pastes by vortex-sintering or electrostatic vortex sintering.
6. The glass surfaces coated with a transparent, duroplastic protective coat, prepared according to the methods of any of claims 1-2.
7. A method according to claim 1 wherein said glass surface is a glass bottle.
8. The glass bottles prepared according to claim 7.
9. The method of claim 1 wherein said hydroxy group-containing 1,2-epoxide compound is a polymer of 2,2-bis-(4-hydroxyphenyl)-propane and epichlorohydrin.
Description The 2-phenylimidazoline-blocked IPDI was worked up to coating powders with the determined epoxy resin as well as a small amount of a flowing agent in the following ratio: Solid epoxy resin on the basis of an adduct of 2,2,-bis-(4-hydroxyphenyl) propane (DIAN) and epichlorohydrin, which showed HCl-splitting and was further treated with Dian and which according to specifications of the manufacturer has an epoxide-equivalent weight of 900-1000 which yields an epoxide value of 0.10-0.11 and a melting range of 90 C.: 89.4 Parts by wt. 2-Phenylimidazoline-blocked IPDI according to Example A: 9.8 Parts by wt. Vehicle, which commercially is designated Modaflow This formulation was contacted at 200 and hardened for five minutes at 180 following tests were carried out: a. Visual Examination: The surface showed a polished, smooth appearance. b. Thickness of the overcoat: 60-70 μm. c. Bursting Pressure: The bottles exploded at an inner pressure of 22-26 atmospheres with formation of small splinters. The synthetic coating maintained the thus formed splinters fully united. d. Test in the washing machine: The test washing lye was formed from a solution of calgonite was allowed to interact for five minutes at 85 bottles. The total time of flow through the machine was about 30 minutes. The synthetic coat showed thereafter no negative changes. e. Test in line Simulator Bottle Temperature 80 were filled at 80 10 minutes in a water bath at a temperature of 80 the heated bottles were tested for one minute in the line simulator. On the surface of the bottle-body there were, after the test, no worn spots on the synthetic overcoat. 5 mentioned test was repeated five times. Damages were not detected. f. Impact Test (Splintering Cohesion): The impact test was carried out with an impact energy of 73 kg cm. A steel ball of 80 mm cross section fell from a height of 350 mm on a perpendicularly lying empty bottle at a meeting angle of 120 the impact, but remained whole without any glass splinters spreading to the outside. g. For the determination of the resistance of the coating agent to piercing, it was tested according to DIN 53 373 "Piercing Test with Electronic Measurement Determination". This test allows the determination of the flexibility and resistance of a synthetic film. The coating thickness of the films were between 150 and 138 μm. The following test conditions were utilized: Test form: flat film Machine: dynatester Test Temperature: 24 Relative Humidity: 70% Piercing Body: half bullet Results from ten tests: Damage force F.sub.s : 14.17 kp Damage work W.sub.s : 2.67 kpcm Piercing work W.sub.ges. : 4.05 kpcm Damage deformation L.sub.s : 5.08 mm 2-phenylimidazoline blocked IPDI-adduct according to Example B.b. was mixed with the given epoxide resin as well with a small amount of a flowing agent in the following ratios to give a coating powder: Solid epoxide resin (according to Example 1): 90.0% by weight 2-Phenylimidazoline blocked IPDI-adduct: 9.2% by weight Flowing agent (according to Example 1): 0.8% by weight This formulation was brought on to glass bottles which at the moment of coating were at a temperature of about 240 was carried out. The tests on the coated bottles were carried out as in Example 1 and the results from Example 1 were also obtained. With 2-phenyl-4-methylimidazoline blocked IPDI according to Example C was prepared by addition of the epoxide resin as well as a small amount of a flowing agent in the following ratios, a coating powder: Solid epoxide resin (as in Example 1): 89.3% by weight 2-phenyl-4-methylimidazoline blocked IPDI: 9.9% by weight flowing agent (according to Example 1): 0.8% by weight This formulation was brought on to glass bottles which were heated to 200 carried out thereafter: a. Visual Inspection: The surface showed a smooth, blank appearance. b. Coating thickness: 70-80 μm c. Bursting pressure: The bottles exploded at an inner pressure of 20-24 atmosphere with formation of fine splinters. The synthetic coating held these splinters together. d. Test in the Washing Machine: The test was carried out according to Example 1d. After the given time there was no appearance of negative changes on the synthetic coating. e. Test in Line Simulator, Test according to Example 1e: The synthetic coating composition only showed minimal wear portions. After 5 minute running time no further damages were observed. f. Impact Test (Splinter cohesion) Test according to Example 1f: The bottles broke and were deformed through the impact, but remained whole. With 2-phenyl-4-methylimidazoline blocked IPDI/diethyleneglcyol adduct, prepared according to Example B, was prepared with the given epoxide resin as well as a small amount of a flowing agent in the given amounts a coating powder. The blocked polyisocyanate gave a white powder with a melting range of 95 (DTA) of 60 150 Solid Epoxide resin (according to Example 1): 88.7% by weight 2-Phenyl-4-methylimidazole blocked IPDI/Diethyleneglycol-Adduct: 10.5% by weight Flowing agent (according to Example 1): 0.8% by weight The properties of the coated glass bottles were the same as those in Example 1. With 2,4-dimethylimidazoline blocked IPDI according to Example D were mixed with the given epoxide resin as well as a small amount of the vehicle in the given amounts to form a coating powder: Solid Epoxide Resin (according to Example 1): 93.0% by weight 2,4-dimethylimidazoline blocked IPDI: 6.2% by weight Flowing agent (according to Example 1): 0.8% by weight The properties of the coated glass bottles were the same as those in Example 1. With 2,4-dimethylimidazoline blocked IPDI/diethyleneglycol-adduct according to Example E was prepared by addition of epoxide resin as well as a small amount of a flowing agent in the following ratios a coating powder: Solid epoxide resin (according to Example 1): 88.6% by weight 2,4-dimethylimidazoline blocked IPDI/diethylene glycol-adduct: 10.6% by weight flowing agent (according to Example 1): 0.8% by weight These formulations were coated onto bottles which had been heated to 120 Thereafter these coatings were hardened for 10 minutes at 200 and the following tests were undertaken: a. Visual Examination: The coating surface showed a smooth, blank appearance b. Coating thickness: 60-80 μm c. Bursting Pressure: The bottles exploded at a inner pressure of 20-24 atmospheres with formation of fine splinters. The synthetic coat did not allow any of the splinters onto the outside. d. Test in the Washing Machine: Test according to Example 1D. No negative changes after the testing time. e. Testing in the line simulator according to Example 1E: Besides of a very light wear, the coating composition was fully recovered. After 5 minute running time the synthetic coats did not show any further damages. f. Impact Test (Splintering Cohesion) Test according to Example 1F: The bottles broke and were deformed through the impact, but remained whole. Having now fully described this invention it will be apparent to one of ordinary skill in the art that many changes and modifications can be made thereto without departing from the spirit or scope of the invention set forth herein. 1. Field of the Invention The present invention relates to a process for the coating of glass surfaces, especially glass bottles with a strongly adhering homogeneous and transparent synthetic coat. 2. Description of the Prior Art The coating of glass surfaces, especially glass bottles with a strongly adhering, homogeneous and transparent synthetic coat, bestows upon the bottles an extraordinary safety upon their filling with carbonic acid containing beverages, such as mineral water, beer, fruit juices, etc., as well as prolonging the durability of multi-way bottles. Upon the influence of strikes and impacts, and also upon heating under the sun or by other heat sources, unprotected bottles have readily exploded in the past, resulting as a consequence in various severe bodily injuries, especially eye injuries on humans. Some of the previously known coatings used for these purposes have the disadvantage, that the coating overlay becomes turbid after repeated cleanings, which effect can be attributed in thermoplastic materials possibly to a post-crystallization effect of the synthetic material. Such bottles convey a negative impression optically and are therefore psychologically undesirable from the viewpoint of marketing. Various coating materials have the disadvantage of being susceptible to oxidation, which leads to embrittlement of the overlay coat and therefore, especially in the case of multi-way bottles to a loss in the ability to protect against splintering. It has now been found, that glass surfaces, especially glass bottles, can be coated without these and other disadvantages, when one employs a method for the coating, and for the prevention of scattering of glass particles upon bursting, whereby a transparent, duroplastic protective coat of preferably more than 50 microns is formed by depositing a paste of hydroxy group-containing 1,2-epoxy compounds with at least 1,2-epoxy group in the molecule and a lower melting point of more than 40 hardening agents as well as usual processing agents and hardening of the overcoat by higher temperatures wherein the clean glass surface is first treated with an aqueous or alcoholic silane skim coat, the glass surface if necessary is dried, it is then warmed to a temperature up to 120 wherein as hardening agents one uses polyisocyanates blocked with cyclic amidines of the general formula ##STR2## wherein, R's can be equal or different substituents selected from the group of hydrogen, alkyl-, cycloalkyl-, aralkyl- and aryl radicals, wherein the hardening agent is added in an amount of 2-15% by weight, relative to the amount of 1,2-epoxy compound; and upon further addition of heat, said coating paste is hardened. The cyclic amidine-blocked polyisocyanate can, in the case of a diisocyanate, be described by the following general formula: ##STR3## wherein, n equals 0 or 1, X equals oxygen, sulfur or a NH group, R can be equal or different radicals selected from the group of hydrogen, alkyl-, cycloalkyl-, aralkyl- and aryl radicals, R' is an alkylene-, cycloalkylene- or arylene radical, and R", if necessary, can be a substituted, by 1 or more alkyl radicals, whereby more than one radical can mutually join to a cycloaliphatic ring, saturated or unsaturated alkylene radical with 2-18 atoms, which can optionally contain one or more oxygen- or sulfur atoms in the hydrocarbon chain, or R" can be a cycloalkylene radical. The hardening agents of the present invention are excellently compatible with most epoxy resins and yield at higher temperatures homogeneous melts, which are very appropriate for the preparation of coating pastes. The hardening mixtures of the present inventions are storage-stable at room temperature; the hardening times lie, according to the hardening temperature in the range of 5-25 minutes. The hardening mechanism is apparently complex. On the one hand, the homopolymerization of the 1,2-epoxy groups is catalyzed by the basic N of the compounds of the present invention, on the other hand during hardening, there occurs a deblocking of the hardening agent into cyclic amidines and polyisocyanates. The thus freed amidines catalyze the homopolymerization of the 1,2-epoxy groups, while the freed NCO-groups undergo reaction with the OH-groups of the epoxy resin in order to form urethanes therewith. The formation of oxazolidones by reaction of the NCO-groups with epoxide groups is possibly not negligible either. The hardened coatings and overlays, are characterized by very satisfactory chemical and mechanical properties. For the preparation of the compositions of the present invention, which can be utilized as coating pastes, it is particularly appropriate to use hydroxy group-containing 1,2-epoxy compounds with more than one 1,2-epoxy group in the molecule and with a lower melting point of higher than 40 characteristics, such as on the one hand polyepoxide compounds, which are solid at 40 weight compounds (so called solid resins) and such compounds which on account of their symmetrical construction or by the size of the hydrocarbon systems which are bound to the 1,2-epoxy groups are solid; and on the other hand, such compounds, which by reaction of liquid 1,2-epoxy compounds with more than one epoxide group per molecule, will give adducts with primary or secondary amines, wherein the amines are used in such amounts that the adduct at least contains on the average still more than one 1,2-epoxy group per molecule. The 1,2-epoxy compounds can be saturated as well as unsaturated aliphatic, cyclo aliphatic, aromatic and heterocyclic. They can further contain such substituents, which under mixture- and reaction conditions will not yield any interferring side reactions. No interferring side reactions are given by alkyl- or aryl- substituents, ether groups and the like. Of the solid resins, it is preferred to use for this purpose, 1,2-epoxy compounds with more than one epoxy group in the molecule, which have an epoxy equivalent weight between 500-2000. These are the solid, polymeric polyglycidylpolyethers of 2,2-bis-(4-hydroxyphenyl)-propane, which are for example obtained by the reaction of 2,2-bis-(4-hydroxyphenyl)-propane with epichlorhydrin in a mole ratio of 1:1.9-1.2 (in the presence of an alkali hydroxide in aqueous medium). Polymeric polyepoxides of this type can also be obtained by the reaction of a polyglycidyl ether of 2,2-bis-(4-hydroxyphenyl)-propane with less than the equimolecular amount of a bifunctional phenol, preferably in the presence of a catalyst, such as a tertiary amine, a tertiary phosphine or a quarternary phosphonium salt. The polyepoxide can also be a solid epoxidized polyester, such as those for example obtained by reaction of a multi functional alcohol and/or a multi basic carboxylic acid or an anhydride thereof with a low molecular weight polyepoxide. Examples of such polyepoxides with low molecular weight are liquid diglycidylethers or 2,2-bis-(4-hydroxyphenyl)propanes, diglycidylphthalates, diglycidyladipates, diglycidyltetrahydrophthalates, diglycidylhexahydrophthalates, diglycidylmaleates and the 3,4-epoxycyclohexylmethyl ester of 3,4-epoxycyclohexanecarboxylic acid. Mixtures on the basis of solid polyepoxides can also be used if necessary, for example, a mixture of a polyepoxide, with a melting point between 120 between 60 according to the mercury method of Durrans). Appropriate mixtures contain between 30 and 50% by weight of a solid polyglycidyl ether of 2,2-bis-(4-hydroxyphenyl)-propane with an epoxy equivalent weight between 1650 and 2050 and a melting point of from 120 and between 50 and 70% by weight of a solid polyglycidyl polyether of 2,2-bis-(4-hydroxyphenol)-propane with an epoxy equivalent weight between 450 and 525 and a melting point of from 60 The cyclic amidine-blocked polyisocyanates of the present invention wherein said cyclic amidine is described by the above mentioned general formula, can be prepared by a reaction at temperatures of from 0 the polyisocyanate and the cyclic amidines are added in such amounts that to one isocyanate group, corresponds 0.5-1.1, preferably 0.8-1.0 moles of cyclic amidine. The appropriate reaction temperature should be below the decomposition temperature. The reaction can be carried out either in solvents, in the melt, and also in an excess of polyisocyanate. As starting materials which can be used for the blocking with cyclic amidines, it is appropriate to use polyisocyanates, especially diisocyanates such as aliphatic, cyclo aliphatic, araliphatic, that is aryl substituted aliphatic, and/or aromatic diisocyanates, such as the ones described for example in Houben-weyl, Methods of Organic Chemistry, volume 14/2, pages 61-70, and in the article of W. Seifken in Justus Liebigs Annalen der Chemie, 562, 75-136, such as 1,2-ethylenediisocyanate, 1,4-tetramethylenediisocyanate, 1,6-hexamethylenediisocyanate, 2,2,4- or 2,4,4-trimethyl-1,6-hexamethylenediisocyanate (TMDI), 1,12-dodecanediisocyanate, ω,ω'-diisocyanatodipropylether, cyclobutane-1,3-diisocyanate, cyclohexane-1,3- and 1,4-diisocyanate, 3-isocyanatomethyl-3,5,5-trimethylcyclohexylisocyanate, which is also named as isophorondiisocyanate and abbreviated as IPDI, 2,5- or 2,6-bis-(isocyanatomethyl-)bis cyclo-[2.2.1]-heptane, decahydro-1,4-methano-naphthalene-2 (or 3) 5-ylendimethylene-diisocyanate, hexahydro-4-7-methanoindane-1- (or 2) 5-(or 6)-ylendimethylenediisocyanate, hexahydro-1,3- or 1,4-phenylene-diisocyanate, 2,4- and 2,6-hexahydrotoluylendiisocyanate, perhydro-2,4' and/or -4,4'-diphenyl-methane-diisocyanate, ω,ω'-diisocyanato-1,4-diethyl-benzene, 1,4-phenylenediisocyanate, 4,4'-diisocyanato-diphenyl, 4,4'-diisocyanato-3,3'-dichloro-diphenyl, 4,4'-diisocyanato-3,3'-dimethoxydiphenyl, 4,4'-diisocyanato-3,3'-dimethyl-diphenyl, 4,4' -diisocyanato-3,3'-diphenyl-diphenyl, 4,4'-diisocyanato-diphenylmethane, naphthalene-1,5-diisocyanate, toluylenediisocyanate, toluylene-2,4- or 2,6-diisocyanate, N,N'-(4,4'-dimethyl-3,3'-diisocyanatodiphenyl)-uretdione, m-xylylenediisocyanate, and also triisocyanates such as 2,4,4'-triisocyanato-diphenylether, 4,4',4"-triisocyanato-triphenylmethane, tris-(4-isocyanatophenyl)thiophosphate, as well as appropriate mixtures of these components. Further appropriate isocyanates can be found in the above-mentioned articles in the Annalen at pages 122 and following. Especially appropriate in the state of the art are the easily available aliphatic or cyclo aliphatic diisocyanates and especially the 1,6-hexamethylenediisocyanate, the 3-isocyanato-methyl-3,5,5-trimethylcyclohexylisocyanate and 2,4-hexahydrotoluylenediisocyanate as well as isomeric mixtures thereof. Besides of the monomeric polyisocyanates, it is possible to use as starting materials for the blocking with the below specifically described imidazolines obviously dimers and trimers of said polyisocyanates, such as uretdiones, biurets, isocyanurates and urethane adducts, which can be prepared by known methods. Under polyisocyanates, in the sense of the present invention it is also understood that those can be used which before the blocking with imidazolines, can undergo a molecular enlargement with chain elongators known in isocyanate chemistry, such as water, polyols, polyamines, and the like, wherein the bi- or trifunctional chain elongation agent, that is, such which contain groups such as hydroxy- and/or amino groups, which are reactive towards isocyanate groups, is used in such amounts that the resulting new isocyanate contains on the average at least two isocyanate groups. Upon use of water as the chain elongation agent, the resulting polyisocyanate contain one or more ureido groups. Appropriate polyols are for example diols and triols, such as for example ethylene glycol, propylene glycols, such as 1,2- and 1,3-propanediol, 2,2-dimethylpropanediol-(1,3)butanediols, such as butanediol-(1,4), hexanediols such as for example hexanediol-(1,6), 2,2,4-trimethylhexanediol-(1,6), 2,4,4-trimethylhexanediol-(1,6), heptanediol-(1,7), octadecene-9,10-diol-(1,12), thiodiglycol, octadecanediol-(1,18), 2,6-dimethyl-2-propylheptanediol-(1,3), butane- or butynediol-(1,4), diethyleneglycol, triethyleneglycol, trans- and cis-1,4-cyclohexanedimethanol, 1,4-cyclohexanediol, glycerine, hexanetriol-(1,2,6), 1,1,1-trimethylolpropane, 1,1,1-trimethylolethane, and the like. It is also possible to use mixtures of the above mentioned compounds. As appropriate chain elongating agents or molecular enlargening agents such as polyamines, it is possible to use for example ethylenediamine-1,2, propylenediamine-1,2 and -1,3, butylenediamine-1,2, -1,3 and 1,4 as well as hexamethylenediamines, which contain one or more C.sub.1 -C.sub.4 -alkyl radicals, such as 2,2,4- or 2,4,4-trimethylhexamethylenediamine-1,6 and the like, and 3-aminomethyl-3,5,5-trimethylcyclohexylamine, which is abbreviated as IPD. Appropriate imidazoline derivatives in the sense of the present invention which are those described by the above-mentioned formula are, for example, those with optionally containing aryl-substituted alkyl radicals, with optionally containing alkyl substituted aryl radicals, such as 2-methylimidazoline, 2,4-dimethylimidazoline, 2-methyl-4-(n-butyl)-imidazoline, 2-ethylimidazoline, 2-ethyl-4-methyl-imidazoline, 2-benzyl-imidazoline, 2-phenyl-imidazoline, 2-phenyl-4-methyl-imidazoline, 2-phenyl-4-(N-morpholinylmethyl)-imidazoline, 2-(o-tolyl)-imidazoline, 2-(p-tolyl)-imidazoline, and the like. It is also possible to use mixtures of said imidazoline-derivatives according to the present invention. This is particularly useful when it is necessary to use blocked isocyanates with lower melting points or -ranges. The reactive imidazoline-derivatives of the present invention can be prepared according to known methods from substituted diamines and aliphatic or aromatic mononitriles if necessary in the presence of elementary sulfur or sulfuryl chloride as catalysts. The blocking reaction can, as already mentioned, take place in solvent. As solvent for this reaction it is possible to use those solvents that do not react with polyisocyanates, such as for example ketones such as acetone, methylethylketone, methylisobutylketone, cyclopentanone, cyclohexanone and others; aromatics such as benzene, toluene, xylene, chlorobenzene, nitrobenzene and others; cyclic ethers such as tetrahydrofuran, dioxane and others; esters such as methylacetate, n-butylacetate and others; aliphatic chlorohydrocarbons such as chloroform, carbon tetrachloride and others as well as aprotic solvents such as dimethylformamide, dimethylacetamide, dimethylsulfoxide and the like. When the blocking agent is added in a ratio ≧1 to the number of isocyanate groups, then the reaction mixtures are kept at the determined temperatures as long as necessary until the NCO-content of the reaction mixture falls to a value of less than 0.2% NCO, and for ratios <1 until the achievement of a constant NCO-value. It is also possible to use in the present invention blocked isocyanates which can be obtained by the additional reaction of a group of blocked polyisocyanates, namely those wherein less than stochiometric amounts of cyclic amidines have reacted therewith, that is, where the ratio of cyclic amidine to isocyanate group was <1:1, with the same chain elongation agents which earlier had been described as agents for the molecular enlargement. The reaction takes place at temperatures in the range of 0 still below the deblocking temperature of blocked polyisocyanate. Through these blocked polyisocyanates it is possible to prepare coating agents, which fulfill practical requirements within very broad limits. This variant of the method is preferably of interest for polyisocyanates with differentially reactive NCO-groups. It is therefore possible to obtain by a change in the sequence of adduct formation/blocking, blocked polyisocyanates with different reactivity, melting range and structure. The amount of the hardening agent which is added to the cyclic amidine-blocked polyisocyanate can interestingly be varied within wide ranges. It is possible to obtain excellent results upon utilization of 2-15 parts by weight, preferably 6-12 parts by weight of hardening agent, calculated on the basis of the added solid 1,2-epoxy compound. Higher additions are unnecessary from practical and economical standpoints. For the improvement of the flowing properties of the coating pastes, it is possible to add at preparation so called flowing agents. These agents can be various chemical compounds or their mixtures belonging to a variety of different chemical areas; for example polymeric or monomeric compounds; acetals, such as polyvinylformal, polyvinylacetal, polyvinylbutyral, polyvinylacetobutyral or Di-2-ethylhexyl-i-butyraldehyde-acetal; Di-2-ethylhexyl-n-butyraldehyde-acetal; Diethyl-2-ethylhexanol-acetal, Di-n-butyl-2-ethyl-hexanol-acetal; Di-i-butyl-2-ethylhexanol-acetal; Di-2-ethylhexyl-acetaldehyde-acetal and others. Ethers, such as polymeric polyethylene- and polypropyleneglycols, mixed polymerizates of n-butylacrylate and vinylisobutylether, ketone-aldehyde-condensations resins, solid silicon resins and also mixtures of zinc soaps of fatty acids and aromatic carboxylic acids and other can also be used. For this purpose, it is also possible to use commercial products such as Modaflow is unknown to the users and of which it is known that it is a complex, polymeric, useful liquid. Such flowing agents can be added in amounts of from 0.2-5% by weight taken on the basis of the total amount of the coating paste. The other components of the heat hardening coating pastes, such as pigments, soluble dyes, fillers, thixotropic agents, UV- and oxidation stabilizers and others, can be added on the basis of the 1,2-epoxy compounds within a relatively wide range. The added amounts also depend on the requirements of the quality of the overcoats. The preparation of the overcoat paste takes place in that one mixes the solid 1,2-epoxy compounds and hardening agents, and if necessary after addition of the known lacquer additives, in the mentioned proportions and extrudes them at a temperature at least 30 temperature of the hardening agent, and additionally grinds them by addition of powdery lacquers to a grain size smaller than 0.25 mm, preferably <100μ, and a grain maximum size between 20 and 60μ, preferably between 30 and 50μ, and if necessary the coarser fraction is separated by sifting. According to the present method, a clean glass surface, such as for example a glass bottle, is first treated with an aqueous or alcoholic silane skim coat. For this treatment, silanes are used which contain radicals of two different correlated functional groups. These are first lower alkoxy groups, especially ethoxy or methoxy radicals, which are reactive with the OH-groups of the glass surface and second, organic radicals with such functional groups which are reactive either with the 1,2-epoxy compounds, such as amino groups or with the hardener, such as for example epoxy groups, glycidyl radicals and others, such as γ-aminopropyl-trimethoxy-silane, γ-aminopropyl-triethoxy-silane, glycidyl oxypropyl-trimethoxy silane, glycidyl oxypropyl-triethoxy-silane, etc. It is also possible to use mixtures with similar functional radicals, that is mixtures which contain reactive groups reactive with epoxide groups or with hardening agent reactive groups. The treatment of the glass surface can for example be done by an immersion in or by a spring with the skimming coat medium. These so treated bottles can then be additionally separately dried. This drying can be simultaneously carried out by warming the bottle to a temperature up to 120 during the cooling process in bottle manufacturing. The coating of the above described coating paste on the warmed glass bottles occurs according to known methods, that is when using powdery lacquers, through electrostatic powder spraying, through vortex sintering or electrostatic vortex sintering etc. or by melts for example through enveloping the rotating bottles with the molten film. The appropriate deposition method is dependent on the glass body to be coated. The immediate melting of the powder which is in the melting range of 100 After the deposition of the coating mass according to one of the described methods, the lacquered glass surfaces are in order to bring about hardening by heating to temperatures of from 130 preferably 140 possess the described advantages. The coating thicknesses of the hardened coats can be adjusted according to the requirements of the glasses to between 50 and 250 μm. The thus deposited protective coat is highly elastic and possesses and excellent adhesion, so that during breaking of the glass or explosion of the bottle the glass splinters cannot force themselves out. The bottle shape remains fully preserved after destruction of the glass bottle. The appearing kinetic energy is transformed through the stretching and heating of the synthetic coating. A special advantage of the coating is its resistance against hot, alkali-containing wash lyes, with which the bottles are cleaned prior to their filling with beverage. This is particularly relevant to multi-weight bottles which are subject to an intensive cleaning prior to each filling operation. The advantage of the coatings of the present invention lies in that even after repeated washing in hot, alkaline washing lye, they undergo no softening of the material and no loss in adherence. Optically there are no changes either. The glass bottles coated with the synthetic coating material of the present invention can be used without further precautions as containers for carbonic acid-containing beverages, since there is no danger of explosion upon their breaking. The lifetime of a coated bottle when used as a multi-way bottle is longer than that of an uncoated bottle, which on account of the rubbing against sharp edges which occurs during the movement and on account of the washing operations in hot solutions, are strongly worn on the surface and can be damaged. Another object of the invention are the glasses, glass bodies such as bottles which are coated with a transparent, duroplastic protective coat. Having generally described this invention, a further understanding can be obtained by reference to certain specific examples which are provided herein for purposes of illustration only and are not intended to be limiting unless otherwise specified. Uncoated and clean glass bottles or glass plates of 5 mm strength were coated with an aqueous or alcoholic γ-amino-propyl-triethoxy-silane solution (1.5% by weight) at room temperature so as to give a monomolecular coating and were thereafter dried. The utilized 1,2-epoxy compounds with the special characteristics, which in the practice are in general described as epoxy resins, were mixed with the cyclic amidine-blocked polyisocyanate as well as with the crosslinker and also the hardener, and the flowing agent in the given weight proportions, extruded and thereafter ground. The particle size of the powder composition was <100 μm. The frequency distribution of the particle sizes was in the range of from 30-50 μm as a maximum. These finally particular mixtures were then deposited on the previously warmed glass surfaces through electrostatic powder spraying and thereafter were dried at the given temperatures and times. The properties of the obtained coats were then determined by the tests described further on. To a mixture of 222 parts by weight isophorondiisocyanate (IPDI) and 300 parts by weight of water free acetone, was added at room temperature slowly 292 parts by weight of 2-phenylimidazoline, which had been dissolved in 500 parts by weight of water free acetone. After the addition of 2-phenylimidazoline was ended, the mixture was heated for one hour at 50 were separated by drying the reaction product at 60 dessicator. The thus 2-phenylimidazoline-blocked IPDI is a white powder with a melting range of 98 point (DTA) of 63 of 0.2% by weight. It has a splitting temperature of about 120 a. To 444 parts by weight IPDI were added with good stirring at 80 C. slowly 106 parts by weight of diethyleneglycol. After finishing the addition of diethyleneglycol, the mixture was still heated for two hours at 80 showed 15.1%. b. To 556 parts by weight of the adduct prepared under a from 2 moles of IPDI and 1 mole diethyleneglycol, were added at 120 portions, 292 parts by weight of 2-phenylimidazoline in such a way that the temperature never rose above 125 addition of 2-phenylimidazoline, the reaction mixture was still heated for a further hour at 120 powder with a melting range of 100 point (DTA) of 70 splitting temperature is about 140 To a melt of 320 parts by weight 2-phenyl-4-methylimidazoline were added in dropwise fashion 222 parts by weight of IPDI in such way that the temperature in the reaction flask never rose above 120 to carry the reaction to completion, the reaction mixture was held for three hours at 120 complete reaction. The reaction product is a white crystalline powder with a melting range of 95 65 temperature was about 140 To 222 parts by weight IPDI were added dropwise at 80 by weight of 2,4-dimethylimidazoline in such way that the temperature never rose above 90 2,4-dimethylimidazoline, the reaction was still heated for one further hour at 100 melting range of 104 75 splitting temperature was 160 To 556 parts by weight of the adduct described under B.a. from 2 moles of IPDI and 1 mole diethyleneglycol, were added dropwise at a 100 196 parts by weight of 2,4-dimethylimidazoline in such a way that the temperature never rose above 110 2,4-dimethylimidazoline was ended, the reaction mixture was further heated for two hours at 110 not possible to show any traces of NCO. The reaction product is a colorless powder with a melting range of 100 softening point of 60 about 170 Patent Citations
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Jewel Beach Pro
By Boy Howdy Technology LLC
Open iTunes to buy and download apps.
Stranded on an island, the sun and the moon are your only friends. But then you start to see beautiful sparkling jewels in the sky... Are you hallucinating, or is solving this puzzle the key to your salvation?
Eye candy
✭ Lickable graphics and tasty sound effects!
✭ Automatic hints help you out when you get stuck!
Score Tracking
✭ Jewel Beach keeps track of your best score so you can show off to your friends!
✭ Post your scores to Facebook to challenge far away friends!
What kind of fun do you want to have?
✭ Challenge mode strengthens your mental agility!
✭ Relax mode soothes your stress away...
✭ Automatically saves your progress if you take a call or push the home button!
(Graphics and Sounds courtesy of Mika Halttunen, used under MIT License, http://www.mhgames.org/jewels/)
What's New in Version 1.12
✭ Bug fixes
Thanks for playing!
Come see us at http://boyhowdytechnology.com
iPhone Screenshots
- 1,79 €
- Category: Games
- Updated: 15 April 2013
- Version: 1.12
- Size: 3.4 MB
- Language: English
- Developer: Boy Howdy Technology LLC
- © Boy Howdy Technology LLC
Compatibility: Requires iOS 3.0 or later. Compatible with iPhone, iPad, and iPod touch.

subset: commoncrawl


text:
Are PC's dead?
Now for a little background on this post and who Jay is. Jamil is for better use of the word a genius. He is my go-to man when I need advice on purchases or tech advice. So, I had something on my mind. After seeing so many reports on the news and statistics about PC sales slumping and the PC as we know it dying, I asked Jay, are PC's dead? Here was what his answer was to the question. …Anywa... »


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On February 2nd, 2011, a team of emergency responders from Resolve Marine Group and Pacific Environmental Corporation (dba PENCO)/American Marine Corporation, demonstrated their marine fire fighting capabilities in Honolulu Harbor. The trained crew of locally and internationally recognized professionals conducted an equipment deployment exercise, utilizing pumps and fire fighting monitors stored at the PENCO/American Marine facilities on pier 13, and operated from the deck of the M/V American Islander. Resolve Marine Group and PENCO/American Marine Corporation, in conjunction with firefighting teaming partner T&T Bisso, provide marine firefighting capabilities in the 14th Coast Guard District. The equipment and capabilities have been accepted by the USCG for citation in OPA 90 tank vessel response plans covering the 14th district.
Kobelt announced today the hiring of Lance Lidstone and Sylvain Robitaille as Business Development Managers. Both will report directly to David Bockhold, CEO, and
Capt. John Nadeau, Commanding Officer, and Cdr. Peter Gooding, Chief, Engineering Division, with the Coast Guard Marine Safety Center visited The Shearer Group, Inc.
Seafarers' charity Apostleship of the Sea (AoS) has paid tribute to its women port chaplains and ship visiting volunteers ahead of International Women's Day 2014.
By Jesse Leon Guerrero, U.S. Navy The U.S. Navy, in partnership with the U.S. Coast Guard and civilian contractors, safely removed 49 55-gallon drums filled
Deep-ocean exploration company Odyssey Marine Exploration, Inc., has been awarded the exclusive contract to conduct an archaeological excavation and recover the
Lessons are still not being learnt when it comes to preventing engine room fires according to Braemar SA (Braemar Incorporating The Salvage Association). Following


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Match.com is the best place to search The Sunshine State for online singles. Start searching for Florida singles looking for love just like you. Match.com is how people know you're located in Wekiva Springs, Florida and ready to meet the right one. Want to know how Harry met Sally? She found him in a personals ad on Match.com's Wekiva Springs personals Web site.
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Home > Online Dating > Florida > Wekiva Springs Singles > Selfemployed Singles


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Lake front custom log home with unbelievable views of lake hiwassee and the national forest mountains,no detail is missed,profes......
Neighborhood: Murphy
Subdivision: Bear Paw
Murphy, NC 28906
Price Reduced Real Estate
Reduced by $25,000 (2.63%) on 06/23/13
5 Bedroom, 3.5 Bath 0 sq.ft.
Single Family Home
Top of the world custom log home estate, total privacy, 360 views, everything you come to the mountains for!!!! Gourmet kitchen,......
Subdivision: None
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Lakefrontcustom home, everyarchitectural detail, such as cherry built-in cabinets,granite counters,walk in closets,window seats,......
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Grand mountain home with long range views. This 3 bedroom/3. 5 bath custom home on 2 acres has everything you could want. Very p......
Reduced by $20,000 (4.18%) on 08/30/13
Custom log home on the hiawassee river! This beautiful 3/2 ranch style log home with a garage & workshop is a dream. Listen ......
Subdivision: Highland Creek
Reduced by $40,000 (9.09%) on 11/19/13
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This home has the wow factor. Beautiful & custom. Two w/b rock fireplaces. Fr has cathedral t&g walls and ceilings w/mas......
Subdivision: N/a
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Remarkable riverfront home with all the upgrades! Granite counter tops, media room, finished basement, huge garage, room to rela......
Reduced by $33,500 (8.41%) on 05/31/13
Fantastic log home with lake appalachia frontage, great lake and mountain views. Home has metal roof, wood floors, exposed beams......
Subdivision: Lake Apalachia Acres
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Wow! Views! Custom home! 4bd/4. 5ba with finished daylight basement with extra large family room, 2+ car attached garage. You'll......
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A beauitful real log home right on wells lake! It sits amoungst the trees and has a stunning view of the big body of water. An o......
Subdivision: Wells Lake
Reduced by $14,100 (4.16%) on 01/10/13
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Nicholas Dove~ Lost-Heroes FormName: Nicholas DoveAge/Birthday: 16 November 13thHeight/Weight: 5' 9" 120 lb.Species (If their DNA was altered, please put the percentage of animal/plant/whatever): 92% human 8% Red-Tailed HawkAppearance: Curly, shoulder-length strawberry-blond hair. Sapphire-blue eyes. Dimple on right cheek. Left ear pierced with diamond stud. Lean and tall. Prefers clothes that are loose and easy to fly in and hide wings when in public.Power: Fly with wings of 11 feet span.Weakness: Has a weak heart and becomes sick easily. Timid and hates violence. Often picked on by others.Occupation: StudentPersonality: Timid at times but is quite bright. He is hesitant to make friends but does his best to fit in. He has a very curious nature, which often gets him in trouble. Loves animals. Has incredible knowledge in technology and astrology.Likes: Sweets and fruit.Dislikes: Dry and spicy foods.Bio: Nicholas (or Nicky, as he likes to go by) had a normal life with his mother, fat
Kari Dove~ Lost-Heroes FormName: Kari DoveAge/Birthday: 21 June 10thHeight/Weight: 5' 11" 140 lb.Species (If their DNA was altered, please put the percentage of animal/plant/whatever): 92% human 8% Red-Tailed HawkAppearance: Layered, chest length, auburn hair, green-blue eyes, pale skin, faded freckles. Wears loose jeans and plain t-shirts, not a fashionista. Likes big sweatshirts to hide wings when in public.Power: Fly with wings of 13 feet spanWeakness: Cannot fly extreme heights due to injury in left wing. Can become emotionally detached.Occupation: Sister and guardian of little brotherPersonality: Very motherly, loves children. Can be quiet at times and has difficulty trusting others. Keeps to herself, but holds a special towards animals like her brother. Often finds herself staring endlessly at the night sky.Likes: Fruits and dairyDislikes: Sweets ( i.e. Chocolates, hard candy, licorice, etc.) Bio: Kari lived with her family that consisted of her mother, father, twin broth
Collaboration Opportunities~ Possible Partnership?An Angel Called KanjiRebirth of The Being TsubasaThe Moon's DaughterThe Secret Behind the Atlantian Stone
Task 6: Part 1"I can't believe I let you talk me into this," Alistair grumbled.Kazuko giggled as she placed in her favorite flame-shaped hair-clip. She then turned to Alistair and smiled.Alistair was wearing dark denim jeans with a gray shirt and an unzipped black leather jacket, the drawstring pouch that held Kiro's egg tied to his belt. Kazuko had on a blue denim jean skirt that went just barely past her knees and a frilly off-white, long-sleeve blouse. Her pouch that held Hikaru's egg was safely tucked away in her blue shoulder bag."You promised you would get out more, and what better way of doing so then going to a Gokon?" Kazuko stated.Alistair rolled his eyes. "Why couldn't we have at least been put in the same group?""I told you already; our names were all put in a randomizer, so there was a slim to none chance we would be in the same group. Besides; don't you want to meet the other students from the other classes?" Kazuko gave her friend a mischievous nudge and headed towards the front
You Decide: Story IdeasStory Idea #1An Inuyasha fan-fic I've been playing around in my head for a while nowSummary: Inuyasha and the gang are in pursuit of Naraku and the Sacred Jewel shards when they come upon a strange village that is protected by a goddess with agents that appear in the form of wolves. Residing in the castle of the village is a mysterious girl who seems to be quite interested in Kagome, but never reveals herself to the group. Who is she, and what connection does she hold with the supposed guardian of the land?Story idea #2I actually started this years ago, but never posted it here. I'd love to hear what you guys think about it^^Summary: Grace Marks has always loved the ocean, but she never thought she would live in it! Tom and Olivia Marks are marine biologists/rescuers who were assigned to the underwater dome-city known as Dolphin City to uncover the truth behind the strange disappearances of several marine mammals. As an animal lover
Regrets of an AngelIn life, we all hold regrets, no matter how much we deny it. We may regret not going to that concert when your friends offered to bring you along. Or perhaps not taking that flu shot and now lying sick in bed. Perhaps even not asking that cute girl or guy in Economics to the Spring Fling. Most of these we forget later on in life, but some remain heavy in our hearts like a stone sunk to the bottom of a lake.For me, my one true regret is not getting to know a wonderful person who walked into my life and ended up flying away in an instance. He was a kind friend and an artistic genius who's life was cut too short. His heart was full of love and was always there for his superfriend (I'll explain later.) Now he stands beside God, watching over us from Heaven on wings of snow-white.I never met him in person. He was a friend of a friend here on deviantART who's character was in a comic series my friend is working on. He was witty and had a hilarious personality, so was one of the most highly
The Dance.You and I dance as life and death,unbroken and ever going,circling and never ending.As the music dies,and the song stops,where our dance is paused.My sight goes gray,the light in my eyes dims,and I fall down forever back.Your face is the last thing,I saw and remembered so I take great comfort,that you're forever there before me as I fall down.So the music revives,and the song restarts,where our dance is unpaused.The music is all around us and surround us,like the lives we make and take,and the dance is going faster to bring life and disaster.
The Memory of a Dead Man WalkingSuchlike the will of brimstone beasts,Is the will of a dead man walking,In each step is left the prints of carelessness.Holding the half empty glass with a crack in the side,stumbling around the dunes in the long wait to becomea savage before the credits roll.A happy ending was for another tale for another man wayoff back in the mirage of the desert that harbors thosedunes as he lies six feet under with a smile by rigormortis and a silent song in the beatless heart, therebeneath a tombstone that read,here lies a memory.Come Hell or high Heaven, the dead man walkingwalks on without a goal or care for the world,a bottle of dried up whiskey hanging looselyin hand, gathering sand from the winds of thatcoming storm. Illusive would have been hislaughter to sober eyes in that wasteland.The Memory looks on as a shade beyond the grave,staring straight at a man of woe, watching thoseapathetic trails disappear. The glass fell intothe bosom of those lands beyond greener pastur
Heart SongI am conscious ofGetting everything in my body going.I can control everything in it as I need itAnd perceive in it every single touch.I love my heart as it is.I am certain of loving it.In my spiritual hand I take it gentlyAnd I always pay attention to it.It bounces and flutters in my hand,Almost up to its edge.My heart is beating incredibly wildAnd I give it a calming picture.With loving words I talk to it:In a relaxed, peaceful tranquility may you serve my body.I am full of gratitude in me,All this love belongs to you.You have always provided my body goodAnd I admire your everlasting courage.In all fears, in all frightYou have been always awakened.Through my body you pump the blood,Even at very extreme anger.All that always in love to me,For this I thank thee.I need all my lifeYour everlasting song.Until I have accomplished my work on EarthAnd my soul will set out.Please accompany me with all your strength,Until the path is reached.Till then, I will join
AubadeSerenaded are the vultures past thesilence of calm demeanor,where only leaves fall in a quiet Autumn.The gusts of haunted winds run through achilled air that even ghosts choose toevade in the darkest hours.No Sunlight had touched the soils belowin any matter of time,though it had given first light to growth.Though that canopy cannot keep away thehowls and screams of undead scavengerswhich only muffled the sounds of betterbirds who sang for the sun.Third eyes were stitched shut and feetwere bound by illusive chains. How littlethe closed treasure chest could ever hold,where when opened it would have overflowed,blotting out the haunted sounds and usingthe limited light within darkness.The vultures search only to find with eyelesssockets, the lively canopy of those growing woods.Time and all of space could never have grazed thosesoils, however wet or dry. Whatever was let in wasby the canopy that guards and shelters.There were paths in those woods, where many feet h
Passage to the Catacombs of TimeWhen day becomes emptyIn the dusk,When time without pictures begins,Lonesome voices combine –Animals are nothing more than huntersOr being hunted –Flowers are only fragrance –When everything becomes nameless like in the beginning –You will go down to the catacombs of timeThat will open to thoseWhose end is near –There where the heart seeds grow –Deep into dark contemplationYou will sink –Already passing deathThat is only a windy passage –And freezing from the exitYou will open your eyesIn which already a new starHas left its reflection.
baby stepsit was probablyvalentine's: evencelsius met fahrenheit in a sloppy french kiss on frozen ground.after all the walking,the skin of my hands started to crack and bleed;silence, i decided,was the solution and the cure. i dippedmy hands into its glowing broth:warmth suffused my body strugglingto sit still.on marched the sun,a salesman, piligrims.
You're just a puppetI am everything,I am nothing.I am everywhere,I am invisible.I'm in your head and won't let go.You beg for my approval,My forgiveness,my glance.I am light,but you will never see me.But you will never know me.You don't know yourself.You are lost.And scared.You know what i allow you to know.You're just a puppet, who thinks he's aliveYou're just a puppet.
RevolutionChains and chains of hopeless bind the system togetherNo one feeling like they can change the worldNo one feeling like our very existence is just vanityNo one feeling like there is anything to live forMillions and millions of confusion in the air tonightFills the blue skies and enters into our heartsConfusion and vanity is what the world runs byBe this, do that, give this, believe that; all I can do now is raise my fist in the skyAs I raise my fist high in the sky, I shout a battle cry of lifeThere is only one voice that still stands out through the generationsI shout a battle cry with my fist in the sky; words that brings the world to lifeWords that brings light back into the hearts of people from young to oldRevolution; time to end the miseryRevolution; time to show the world the true meaning of lifeRevolution; time to show the world that true love exists beyond our understandingRevolution; time to cry out into the heavens for love to come downRevolution; time to rise
Message to Gaia.Time have passed above my headI remember when from my diary I read,"Before timeI used to look into your eye."Your eyeMy dear, is the only thingThat still keeps me alive.Can you recallThose memoriesWhich we call our own,Where you and IUsed to hideTo become one with All?Those memoriesI still cry them backWhen I stargaze and look above,When I hug your precious love,When you give me companionsTo forget the sadness of a lonely heart.
We Are All ConnectedWe are all connected.We share one light,But we all share one darkness.However,Darkness is nothing to fear,For without it,There can be no light.We would be lost,With no place to call home.You should not fear the darkness,And instead accept it.Even though it may scare us,It is nature's way of rebirth.But we must be aware of it,For if left uncheckedOur light will vanish.Nevertheless,No matter how far apart we are,Just remember this one thing,As long as you have faith,Our hearts will always find each other.
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text: Support 88Nine And This Artist: Buy On Amazon Buy On iTunes Lonnie Rashid Lynn, Jr. (born March 13, 1972 in Chicago, Illinois), better known by his stage name Common (previously Common Sense), is a Grammy award winning rapper, author and actor known for lyrics that focus on love and spirituality. Signed to Kanye West's G.O.O.D. Music, many people describe him as being a conscious hip hop artist who makes songs that send a message. He debuted in 1992 with the album Can I Borrow a Dollar? and maintained a significant underground following into the late 90s, after which he gained notable mainstream success through his work with the soulquarians. Read more about Common on Last.fm. User-contributed text is available under the Creative Commons By-SA License and may also be available under the GNU FDL. Tracks We Played THE CORNER itunes THE CORNER The Corner EP Last Played on December 07, 2013 11:50am BREAK MY HEART itunes BREAK MY HEART Finding Forever Last Played on August 09, 2013 7:05am Love Is... itunes Love Is... Be Last Played on April 27, 2013 12:53am The Light itunes The Light Like Water For Chocolate Last Played on March 20, 2013 10:59pm COME CLOSE REMIX (CLOSER) itunes COME CLOSE REMIX (CLOSER) Come Close EP Last Played on August 29, 2012 7:06am RESURRECTION itunes RESURRECTION Resurrection Last Played on August 28, 2012 7:05am SOUL BY THE POUND itunes SOUL BY THE POUND Can I Borrow A Dollar? Last Played on August 27, 2012 7:06am I Used To Love H.E.R. itunes I Used To Love H.E.R. Resurrection Last Played on August 03, 2012 4:54am COLD BLOODED itunes COLD BLOODED Like Water For Chocolate Last Played on July 05, 2012 2:07pm Testify itunes Testify Be Last Played on May 16, 2012 12:28am THEY SAY itunes THEY SAY Be The Food The Food Be The Corner The Corner Be CHI-CITY itunes CHI-CITY Be Be Be Be Ressurection Ressurection Resurrection THE PEOPLE itunes THE PEOPLE Finding Forever View the discussion thread.


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Matted prints are extraordinarily versatile. They are the Swiss army knife of the wall art world. Whether you're planning on self framing for your home, needing to store professionally presented prints, or holding exhibitions this is our product ying to your purpose yang.
Cunningly designed to fit your image within a standard mat to work with our gorgeous solid timber Reusable Frames: 406mm x 508mm / 16" x 20" (includes mat dimensions)
robot, robots, sci fi, science, fiction, parody, parodies, spoof, who, geek, geeks, wedding, marriage, romance, love
Vectormutt on Facebook


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The No. 23 University of Iowa women's basketball team advanced to the Big Ten Tournament championship game with a 77-73 victory over Ohio State on Saturday in Indianapolis.
The University of Iowa advanced seven wrestlers to the semifinals of the 2014 Big Ten Championships on Saturday at the Kohl Center. The Hawkeyes recorded four major decisions and three pins in the opening and...
The University of Iowa baseball team dropped its second-straight game, falling 5-2 at Kansas State on Saturday afternoon at Tointon Family Stadium.
No. 24/25 Iowa (20-10, 9-8) hosts Illinois (17-13, 6-11) Saturday in its regular season finale. Tipoff is slated for 7:36 p.m. (CT) in Iowa City.
Gametracker | Game Notes | Listen Live | Watch Live
The University of Iowa diving team will travel to Minneapolis on March 10-12 for the 2014 NCAA Zone D Diving Championships, hosted by the University of Minnesota.
HAWK TALK MONTHLY The official online magazine of the Iowa Hawkeyes
RANDOM THOUGHTS A big win triggered by Fran's 'bigs'
Watch the construction
of the Operations Center


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I love kitchen islands. I would like to purchase an island/bar ready to set up without feeling like I'm putting an addition in my kitchen. Where in Toronto can one buy a functional kitchen island, ready to go?
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Cook Time:
15 mins
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MMMmmm... My 2 most favourite things--all in one muffin!! Recipe can also be made into 2 medium-sized loaves, if you wish. ENJOY!!!
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Serving Size: 1 (1999 g)
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text: Results 1–10 of 129 for "Curriculum"X related to "American Psychological Association..." Refine Your Search Refine Your Search TopicEducation (107)Personality (11)HIV & AIDS (10)Children (6)Race (6) 13 more... [+] Testing issues (6)Learning & memory (5)Sleep (4)Law & psychology (2)Schizophrenia (2)Anxiety (1)Bullying (1)Death & dying (1)Depression (1)Emotional health (1)Suicide (1)Teens (1)Women & men (1)Hide detailsDocument TypeCurriculumXYear2011 (2)Author/ContributorBenjamin, Ludy T. Jr. (3)Dwyer, Carol (2)McEntarffer, Rob (2)Nogare, Mario A. (2)O'Leary, Ann (2) 43 more... [+] Puente, Antonio E. (2)Arnold, J. David (1)Bernstein, Douglas A. (1)Bowleg, Lisa (1)Brabeck, Mary (1)Britton, Paula J. (1)Carey, Michael P. (1)Davidson, Margaret (1)Dollinger, Stephen J. (1)Eagleston, Jean R. (1)Engle, T. L. (1)Ernst, Randal M. (1)Fernald, L. Dodge (1)Fernald, Peter S. (1)Forsyth, Andrew D. (1)Freeman, James (1)Fujitsubo, Lani C. (1)Graham, Sandra (1)Greider, Jack J. (1)Jeffrey, Jill (1)Kain, Craig (1)Kalichman, Seth (1)Kasschau, Richard A. (1)Kennedy, Darlene (1)Kerber, Kenneth W. (1)Kratochwill, Tom (1)LaVoie, Allan L. (1)Leal, Linda (1)Lucariello, Joan (1)Matsumoto, David (1)Mausner, Bernard (1)McCombs, Barbara (1)Moffett, Mary Margaret (1)Renner, Michael J. (1)Rhodes, Nancy (1)Russo, Nancy Felipe (1)Semrud-Clikeman, Margaret (1)Snellgrove, Louis (1)Watson, David L. (1)Weseley, Allyson (1)Whitcomb, David H. (1)Woods, Paul I. (1)Zimbardo, Philip G. (1)Hide details Results 1–10 of 129 Previous 1 2 3 ... Next Relevance Title A-Z Title Z-A Newest First Oldest First Sort by: 1.Procedural Timeline for PersonalityA timeline for the lessons, including the psychosocial family tree, assessment and tests, research issues and function of personality theory, ethical principles and dilemmas in the practice of psychology and the psychoanalytic model.Curriculum 2.Motivated Reasoning Teaching Tip SheetTips for teaching the role of motivation in cognitive processes such as decision-making and attitude change as emphasized by Ziva Kunda (1990) and Hart and Gerrard (1997). These studies cast doubt on the utilitarian, "rational" models of behavioral decision making upon which research regarding Sexually Transmitted Disease (STD) and other health promotion/disease prevention currently rests.Curriculum 3.Activity 2.4: Relating Body Temperature and Circadian RhythmsStudents rate themselves on an alertness scale each time a temperature reading is recorded, examining how a psychological variable fluctuates in comparison to body tempature.Curriculum 4.Teaching Tip SheetsTeaching tip sheets by Ann O'Leary, Craig Kain, David Whitcomb, Lisa Bowleg, Paula Britton, Seth Kalichman, Michael P. Carey and Andrew D. Forsyth on cognitive dissonance, motivated reasoning, loss and AIDS-related bereavement, flexible therapeutic frames, social support networks, attitudes and behavior change, self – efficacy, counselor attitude bias, and stigma and prejudice.Curriculum 5.APA Classroom Management ModulesCPSE developed two module videos detailing instructional strategies for PK-12 teachers. The first video covers recommendations for general classroom management. The second focuses on dealing with disruptive classroom behavior, including students who leave their seats without permission, talk back to teachers and show physical aggression.Curriculum 6.Sample Response to D.1. — Course Content Requiring CitationsThe demonstration of program credibility can include citations to relevant peer-reviewed research and reference to broader, recognized traditions of research and theory.Curriculum 7.Personality: Day TwoA lesson covering assessment techniques, organization of tests, traits vs. situations, and ethical dilemmas.Curriculum 8.Teaching Tip Sheet: Attitudes and Behavior ChangeThere are several teaching strategies that psychologists who teach the study of attitudes can use to update and enhance their courses to reflect what social scientists have learned from HIV/AIDS-related research.Curriculum 9.Self-Efficacy Teaching Tip SheetAn individual's belief in his or her capacity to execute behaviors necessary to produce specific performance attainments, self-efficacy reflects confidence in the ability to exert control over one's own motivation, behavior, and social environment. HIV/AIDS Self-Efficacy Theory (SET) is assessed frequently in HIV prevention research.Curriculum 10.Activity 2.3: Ethical Principles and Dilemmas in the Practice of PsychologyUsing high-probability statements taken from an astrological source, this classroom demonstration illustrates the willingness of students to believe bogus personality assessments.Curriculum Previous 1 2 3 ... Next Relevance Title A-Z Title Z-A Newest First Oldest First Sort by: ADVERTISEMENT Results 1–10 of 129 for "Curriculum"X related to "American Psychological Association..."


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Truth & Rumors > NFL
Chiefs, Jags in the running for No. 1 pick
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11:42 AM ET 11.06 | The Kansas City Chiefs and Jacksonville Jaguars lead the way for the No. 1 overall pick in the 2013 NFL draft. Both teams sit at 1-7 at the season's midway mark while the Chiefs' opponent winning percentage gives them the current tiebreaker. Rounding out the top five are the Cleveland Browns, Carolina Panthers and St. Louis Rams (via Washington Redskins). With an extra pick from the Redskins, the Rams could be threatening two top 10 picks by the end of the season.
They both need something that resembles a QB. Is there a "franchise" one in next year's draft class?
Matt Barkley? Probably not.
Yeah that's what I have been hearing, that Barkley has all the makings of another USC bust.
Knowing these two teams, they might as well grab him
I never understood why Vince Young was never looked at by the Jags as a potential backup. Chad Hene...Vince Young???? Front office must know somethig we don't know.
The Rams with 2 top 10 picks? That sounds like a ray of hope for QB Bradford. Surely they could find at least 1 decent O lineman.
They both need something that resembles a QB. Is there a "franchise" one in next year's draft class?
The media will find someone to inflate after Thanksgiving.
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The Chiefs will get it and draft some defensive lineman from Tulane, because he has good measurables and could one day become disruptive (he won't)
DENARD ROBINSON...HaHaHaHaHaHaHaHaHa!!!!!!!!!!!!!!!!!!!!
Made me laugh...
Total Comments (40504)
Yeah that's what I have been hearing, that Barkley has all the makings of another USC bust.Knowing these two teams, they might as well grab him
I bet Barkley is starting to wish he???d left school a year sooner.
Time to fold in the season, in a magnificent style....NEXT!
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Truth & Rumors
Report: Phil Jackson 'real close' to taking Knicks job
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Report: Texans interested in Ryan Mallett
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How long will Stars be without Kari Lehtonen?
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Red Sox owner's beef with Marlins goes way back
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Will Devils extend Jaromir Jagr?
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I know having a man is not all about how much money he has (unless you're a gold-digger, and I'm not judging), but it sure wouldn't hurt to have one who can buy you things like a $300,000 car. Alicia Keys received an all white Aston Martin DBS from her … Continue reading
Monthly Archives: January 2011
Two and a Half Men On Hiatus While Charlie's in Rehab
Charlie Sheen will be in rehab for 3 months, bringing his show, Two and a Half Men, to a halt. The series still has 8 more episodes to film this season, and sources tell TMZ that the cast and crew of the show is worried about the amount of compensation they will get. … Continue reading
Warner Bros. Announces New Superman
Henry Cavill, known for his role on 'The Tudors,' has been cast as the title role in the next Superman movie. The next movie will be directed by Zack Snyder of Warner Bros. Pictures. "I also join Warner Bros., Legendary and the producers in saying how excited we are … Continue reading
Will Ferrell Joins Dunder Mifflin
As The Office prepares for the departure of Steve Carell, they are bringing out some big guest stars to bid him farewell. Will Ferrell is set to guest star on several episodes this season. Ferrell–who co-starred with Carell in Anchorman–will play a Dunder Mifflin/Sabre manager who visits the Scranton branch. … Continue reading
Sofia Vergara launches collection with Kmart!
Renowned actress Sofia Vergara announces her contemporary lifestyle collection Sofia Vergara! Sold exclusively through Kmart, the collection will embody the "Modern Family" star's signature style of glamour and sexiness with an air of approachability. The collection, which will include sportswear, dresses, handbags, jewelry, and footwear, is designed to offer young, … Continue reading


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Flats to let in Northampton - 1 bedroom
£500 pcm (£115 pw)
Leicester Street, Northampton NN1
Flat to rent - 1 bedroomsUnfurnished: A very large second floor one bedroom apartment located a short walk away from the town centre. The internal accommodation comprises; entrance hall, large open plan living area incorporating kitchen and appliances, one double bedroom and ...
Marketed by Ashby Lowery Residential, NN1. Call 01604 318044
£500 pcm (£115 pw)
Cambridge Court, Southbridge, Northampton NN4
Flat to rent - 1 bedroomsModern one bedroom second floor flat.
Marketed by Howkins & Harrison, NN1. Call 01604 318022
£515 pcm (£119 pw) Just added
Lunchfield Lane, Moulton, Northampton NN3
Flat to rent - 1 bedroomsWell Maintained First Floor Flat with Allocated Parking. Unfurnished. Communal Entrance. Spacious Hall. Living Room and opening through to Kitchen with oven/hob. Double Bedroom and Bathroom with shower over bath. No smokers. No pets. Council Tax Band ...
Marketed by Chelton Brown, NN1. Call 01604 726333
£525 pcm (£121 pw)
Blisworth Close, Northampton NN4
Flat to rent - 1 bedroomsWell presented one bedroom first floor flat located within easy reach of local routes. The property is available on an unfurnished basis end of feb. Call today
Marketed by Taylors Estate Agents - Northampton Lettings, NN1. Call 01604 808949
£525 pcm (£121 pw)
County Chambers, Town Centre, Northamptonshire NN1
Flat to rent - 1 bedroomsSoon to be available one and two bedroom flats right in the centre of northampton town that are undergoing refurbishment. The accommodation will briefly comprise of: Communal entrance, entrance hall with intercom, large lounge, fitted kitchen with ...
Marketed by J.P. Lettings and Property Management, NN1. Call 01604 318069
£525 pcm (£121 pw)
Broad Street, Northampton NN1
Flat to rent - 1 bedrooms1 bed unfurnished apartment situated on the 5th floor of the desirable Centro development. With designer kitchen and bathroom, this is an excellent option for tenants who require a certain standard of accomodation. Allocated parking for 1 Appliances: ...
Marketed by Belvoir, NN1. Call 01604 300019
£525 pcm (£121 pw)
Watkin Terrace, Northampton NN1
Flat to rent - 1 bedroomsWilliam H Brown are delighted to offer for rent this very well presented one bedroom apartment with fantastic views over Northampton's Racecourse. The accommodation comprises lounge, kitchen, bedroom, bathroom and communal rear garden. The property ...
Marketed by William H Brown, NN1. Call 01604 866184
£525 pcm (£121 pw)
The Drive, Abington, Northamptonshire NN1
Flat to rent - 1 bedroomsA large one bedroom first floor flat located in a quiet residential area. The accommodation briefly comprises: Entrance hall, large lounge and dining area, fitted kitchen with built-in oven and hob, large double bedroom with built-in cupboard, ...
Marketed by J.P. Lettings and Property Management, NN1. Call 01604 318069
£535 pcm (£123 pw)
Bluebell Rise, Grange Park, Northampton NN4
Flat to rent - 1 bedroomsA first floor one bedroom flat in good condition throughout unfurnished comprising of: Hall, living room with access to kitchen, gas hob and electric oven, space for fridge/freezer and washing machine. One double bedroom and bathroom with shower. Gas ...
Marketed by Chelton Brown, NN1. Call 01604 726333
£540 pcm (£125 pw)
St. Georges Avenue, Northampton NN2
Flat to rent - 1 bedroomsUnique! A completely redecorated and spacious one bedroom exclusive apartment set opposite the Racecourse. This unfurnished property has been done to a high specification and comes with its own private entrance, feature fireplaces and stripped ...
Marketed by Martin & Co Northampton, NN1. Call 01604 318598
£550 pcm (£127 pw)
Stockley Street, Northampton NN1
Flat to rent - 1 bedroomsA refurbished one double bedroom apartment located close to Northampton Town Centre and General Hospital. Accommodation comprising of security entrance, entrance hall, living room, refitted kitchen, refitted bathroom w/c, one double bedroom. Outside ...
Marketed by Your Move - Hobin Roberts, NN1. Call 01604 866269
£560 pcm (£129 pw)
St Crispin Cresent, St Crispin, Northamptonshire NN5
Flat to rent - 1 bedrooms• one bedroom first floor apartment • allocated parking • **25% off tenants fees for march 2014 move in** • kitchen with appliances • popular location • double bedroom • unfurnished
Marketed by Harrison Murray, NN4. Call 01604 318148
£575 pcm (£133 pw)
Oak Grove, Weston Favell, Northampton NN3
Flat to rent - 1 bedroomsUnfurnished: A superbly presented and appointed first floor one bedroom apartment in this attractive crescent shaped apartment block. The accommodation comprises; open plan living/kitchen area, bedroom and luxury bathroom. Outside there is an ...
Marketed by Ashby Lowery Residential, NN1. Call 01604 318044
£575 pcm (£133 pw)
Town Centre, Northampton NN1
Flat to rent - 1 bedroomsLuxury Apartment in Town Centre location close to local Amenties
Marketed by Lets Get Moving, NN1. Call 01604 318323
£575 pcm (£133 pw)
Stockley Street, Abington, Northampton NN1
Flat to rent - 1 bedroomsFantastic find! New to the market! Close to town centre!
Marketed by haart Estate Agents - Northampton, NN1. Call 01604 318034
£600 pcm (£138 pw)
Abington Avenue, Abington, Northampton NN1
Flat to rent - 1 bedroomsThis much larger than average one double bedroom first floor apartment within a Victorian conversion retaining many original features. Comprising of exceptionally large lounge with feature fireplace, beautiful fitted oak effect kitchen with granite ...
Marketed by Connells, NN1. Call 01604 318133
£628 pcm (£145 pw)
St. Andrews Road, Northampton NN1
Flat to rent - 1 bedrooms** Deposit Warranty scheme ** Kingswood sale and lettings are please to offer for rental this one bedroom first floor flat. £145 per week all bills included
Marketed by Kingswood Sales and Lettings, NN7. Call 01604 866188
£650 pcm (£150 pw)
Abington Avenue, Abington, Northampton NN1
Flat to rent - 1 bedroomsLuxury apartment... Spacious apartment comprises of a communal entrance hall leading to the first floor. Once through the front door there is a neat entrance hall with doors to the large lounge and kitchen/diner. On the other side is a genorous ...
Marketed by haart Estate Agents - Northampton, NN1. Call 01604 318034


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Turquoise & Moonstone Bracelet
Succumb to the dreamy depths of mysterious moonstone and turquoise on our captivating bracelet from the mountains of Nepal. The lightweight cuff design accommodates most wrists for a perfect fit.
A portion of the proceeds for this product goes to Kipoo Newa English School in Kathmandu, Nepal, which offers young children an education in their home language (Nepal Bhasa).
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Love Tesco online shopping
I have done a lot of online shopping with Tesco and I cannot fault their service. There has been a few occasions where they don't have the item I have asked for and they give a subsitute. On most occassions the substitute has been acceptable, the times it has not the driver just took the item back and the money was credited back into my account. The drivers are always friendly and arrive in the time I have asked for. Would recommend this type of grocery shopping for anyone too busy to go to the supermarket or like me just hate going into supermarkets.


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Me to. I intend to continue my work this year.
Last I checked, every item in the vending machine already has that same information printed on the label. How much nanny-care do we need?
Glad to see you have such infinite insight. I guess maybe people need to elevate you to godhood since you have infinite wisdom and knowledge.
You are limiting your understanding of life by your own perceptions. Is it not possible that other forms of life exist somewhere in this limitless universe? Assuming that is possible, could this other life take a form that we, in our limited ability and understanding, can not even comprehend? Geez, a couple hundred years ago everyone was sure the world was flat. They were unable to understand how anything else could be plausible. Are you just as limited in your scope?
What's it to you how others want to believe the universe came into being? If someone wants to believe in the Great Pumpkin, how does that impact your lack of any belief? I just can't understand these activist atheist any more that I can understand radical religious zealots. As long as the guy next door is not trying to force me to believe what ever he believes, why should I care if he worships turnip if he wants to?
I supported Phil's right to speak his mind. I also supported A&E's right to fire and/or hire whoever they wanted to. I still support A&Es right to hire or reinstate Phil and acknowledge just how stupid they were in allowing this idiotic fiasco to snowball in the first place. Ain't the free market grand?!? BTW, suck it up GLAAD.
Then why are you in the US? If Germany and Denmark are such havens of joy and pleasure, why remain in this desolate pit of despair? Leave, no one here will miss you.
BTW, I am also widely traveled and I have seen poverty and misery that is indescribable in almost every nation. Least of that is in the US. Our poorest are wealthy beyond the dreams of almost everyone else in the world. Our closest trading partners in Europe and Asia are at least 10 years behind the US in technology, medicine and nutrition. If libs like you would get out and go to one of your utopic dream countries, maybe we could stay that way.
Access to knowledge? What, exactly is that? Any list put out by the UN is suspect at the start.
Not only that, but when labor costs rise significantly, like doubling, business will find alternate ways to decrease those labor costs, like using automation instead of manpower. As long as labor cost are relatively low, automation is far to expensive. When labor costs sky rocket automation becomes viable. With automation comes fewer humans doing a job, therefore less jobs. Also, these idiot burger flippers screaming for 15 bucks an hour are not likely going to get those jobs maintaining the high tech machinery. In essence, they are protesting themselves out of jobs.
Yes, of course. All those people that have lost their insurance, I'm sure they fell very much at peace.
If a private company were run like this, people would be in jail!


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NCAA Tournament:
Sign Up To Play The Bracket Challenge | NCAA Tournament Coverage | Twitter Wall
Tumbling Flower Beetle
Officials At Port Of Baltimore Stop Invasive Beetle That Could Have Damaged Md. Environment
It's got a cute name– the tumbling flower beetle. But it's got a nasty appetite, and fortunately, it was stopped in time at the Port of Baltimore.


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New arrest warrants have been ordered for two women from Mexico, who failed to appear for arraignment on charges of money laundering.
The defendants were alleged to have smuggled hundreds of thousands of dollars in drug money through Hunt County on Halloween.
Whenever Nabil Alejandra Rojas-Gallegos and Marlene Elizabeth Najera-Perez are again arrested, they will be held without bond, according to an order from 354th District Court Judge Richard A. Beacom.
Beacom revoked the bonds for both defendants Thursday, after they did not attend the arraignment hearing, and ordered that new bonds be denied in each case.
Najera-Perez, 23, and Rojas-Gallegos, 25, both of Monterrey, Mexico each received one indictment from the Hunt County grand jury in December for money laundering of the value of more than $200,000.
Najera-Perez and Rojas-Gallegos were arrested by the Greenville Police Department on the morning of Oct. 31, 2012.
According to a police report, an officer making a routine traffic stop on Interstate 30 observed suspicious modifications to the suspects' vehicle. The officer was reported to have asked for and received permission to search the vehicle, during which the officer discovered $215,000 hidden inside the automobile. In addition, the U. S. Immigration and Customs Enforcement (ICE) was contacted because of the immigration status of the two suspects.
The charges were filed as first degree felonies, punishable upon conviction by a maximum sentence of from five to 99 years to life in prison and an optional fine of up to $10,000.
Local News
New warrants issued in money laundering case
- Local News
- City lot goes unsold
- Trial starting in kilo of cocaine possession case
Custody hearing today for seized dogs, cats
A hearing is scheduled in Greenville this morning, to determine whether the Society for the Prevention of Cruelty to Animals (SPCA) of Texas will gain custody of dozens of animals were seized last week from a residence near Royse City.
Council to accept two buildings at airport
City officials and L-3 Mission Integration are working together on another project at Majors Field, the City of Greenville Municipal Airport.
Sentencing set for man's fifth armed robbery
Sentencing is scheduled this week for a local man who pleaded guilty to his fifth armed robbery.
Council, chamber at odds again over tourism funding
Some members of the Greenville City Council are prepared to take action this week to strip tourism funding from the Greenville Chamber of Commerce/Convention and Visitors Bureau.
Settlement expected in raceway lawsuit
A lawsuit filed by Hunt County and State of Texas officials against a Caddo Mills drag strip is expected to be settled in the near future.
City making plans to buy new fire truck
The City of Greenville is about to buy a new fire truck, and thanks in large part to an anonymous donor, it will be paid for in cash.
County jobless rate dips again
The local unemployment rate dipped again in January, even though Hunt County lost more than 260 jobs to start the year.
Court reporter leading the way in preventing child abuse
Cher Perry is leading an initiative to end child sexual abuse in Hunt County.
- More Local News Headlines


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Iran hangs two spies working for Israel and U.S.: report
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DUBAI (Reuters) - Iranian authorities executed two men on Sunday convicted of working for Israeli and U.S. spy agencies, Iran's Fars news agency reported.
Mohammad Heidari, accused of passing security-related information and secrets to Israeli Mossad agents in exchange for money, and Kourosh Ahmadi, accused of gathering information for the U.S. Central Intelligence Agency, were hanged at dawn, it said.
The sentence for their execution was handed down by Tehran's Revolutionary Court and confirmed by the country's Supreme Court. The report did not say when the pair were arrested nor when their trial took place.
Iran has in the past said it had successfully detected and dismantled spy networks operating inside the country. It has blamed the assassinations of scientists associated with its disputed nuclear program on Western spy agencies, especially Mossad.
The United States has denied any role in the killings. Israel has not commented.
(Reporting by Yeganeh Torbati; Editing by Alison Williams)
- Police hunt for motive as search for Malaysian jet spans hemispheres |
- Crimeans vote on union with Russia as Moscow pours in troops |
- Malaysian PM says lost airliner was diverted deliberately |
- Democrats seek ways to limit Obamacare fallout after Florida defeat
- Ukraine, Russia agree Crimea truce until March 21-Ukraine minister


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Local News
Quinn to Talk to Lawmakers About Police Resources
CHICAGO (AP) - Gov. Pat Quinn says he plans to talk to the Legislature about making sure state police have enough resources at their disposal to deal with a backlog of applications for gun ownership.The Illinois State Police continues to struggle with a backlog of applications for gun ownership. So it remains to be seen how they can handle an influx of requests for permits to carry concealed weapons. The department has 49,000 applications for Firearm Owners Identification cards awaiting approval. Police estimate there will be 400,000 applications for "carry" permits in the first year.
Quinn says he wants to make sure police are able to do their jobs. In July Illinois became the last state in the nation to allow residents to carry concealed weapons.
See other LocalNews news:
Centralia City Council Seeks Public Input on Street Solcititation OrdinanceAlma To Seek Grants To Buy Storm Shelter
Security Breach For First Concealed Carry Applicants
Three Face New Felony Charges Following Weekend Arrests
Police Beat for Tuesday, March 11th, 2014


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Ubisoft's debut trailer for Assassin's Creed III. The setting, a complete twist from previous franchise installments, takes place in Revolutionary War time America (late 1700s).
Check out a new behind-the-scenes look at Da Vinci's Demons: Season 2, including new footage.
World of Warcraft subscriber numbers rose to 7.8 million by December 30, 2013, Blizzard has announced.


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Breve historia de Simón Bolívar
Roberto Barletta Villarán
This book is available for download with iBooks on your Mac or iOS device, and with iTunes on your computer. Books can be read with iBooks on your Mac or iOS device.
Bolivar's heroic achievements are a product of his personal nature and character, traits that made him a legend even after his death. His obsession for glory perhaps represented the most important aspect of his life. This book starts with the early education of Bolivar and the shaping of his personality, as well as the events that helped influence his distinct nature: relations with teachers, with women such as his wife Maria Teresa and Manuelita Saenz, and with other great men of his period. It goes on to describe his vision for the Americas, his independence yearnings, and his growth as a military officer and politician. For this part, the book examines the alliances and conflicts that played a role in his integration project, the battles through which he achieved great glory, and the relationships that left an impression in his adult life. The work concludes by analyzing the ongoing influence of Bolivar in the modern world.
- $7.99
- Category: Latin America
- Published: Nov 08, 2011
- Publisher: Nowtilus
- Seller: BookMasters, Inc.
- Print Length: 288 Pages
- Language: Spanish