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High Protein Meals That Can Help Lower Cholesterol, Dietitian Approved
Limit saturated fats and take in a properly-balanced food plan to decreased your cholesterol.
If your cholesterol (and exclusively your LDL cholesterol) is as well large, you are at greater hazard of
coronary heart condition
and stroke.
By lowering saturated fats in your diet, you can decrease your cholesterol.
Saturated fats are normally hard, strong fat, Campbell mentioned. They are uncovered in fatty meats and fat this kind of as butter, lard, palm oil, coconut oil, cream, pies, and pastry.
Campbell endorses minimizing these and taking in healthier fat these kinds of as rapeseed oil, olive oils, oily fish, nuts, seeds, and avocado.
Ingesting a well balanced, fiber-loaded food plan which includes lots of fruit, veggies, beans, pulses, and total grains can help handle cholesterol. Oats are also useful due to the fact they include a material known as beta glucan which "mops up" cholesterol and lessens its absorption, Campbell explained.
Protecting a healthy physique weight and currently being physically active also aids retain cholesterol concentrations in examine, but genes play a function also, Campbell said.
Campbell shared 7 meals that can assist decreased cholesterol levels, from crimson chili and bean soup to cauliflower dal.


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Supreme Member
- Joined
- May 12, 2011
- Messages
- 1,419
- Reaction score
- 438
- Website
- www.backkicks.com
I am trying to buy domains on Afternic. In my understanding it is a 'broker', but I am having a hard time receiving reasonable counter offers. Most counter offers are way above the 'buy now' price and I am receiving countless calls from them on my mailbox where they offer 'to work for me to get the domain'. They are really annoying. Anybody have recent experience with them in buying domains? I am worried the actual seller will not sell the domain when I 'buy now'. Will they refund my money or just keep it as credit in my account?

subset: commoncrawl


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There were at least eight fatalities on Minnesota roads over the weekend, the deadliest Memorial Day holiday in 10 years. Mike Hanson, director of the state Traffic Safety Office says:
"While overall crash numbers are down, the severity rate is up, and what's driving that severity rate up is speed. The speeds that the officers, troopers and deputies are seeing out there are really horrific."
At the same time, D-W-I arrests over the Memorial Day weekend were 25 percent less than last year — Hanson says probably because bars and restaurants remain closed until June 1st under the governor's COVID order.
Hanson says reduced traffic due to COVID-19 is one possible reason motorists are making a dangerous decision to drive faster…
"There's less congestion out there, there's more available lane space, so people probably are tempted to push it maybe a little bit faster than they would during more typical traffic conditions."


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ФЕДЕРАЛЬНОЕ ГОСУДАРСТВЕННОЕ БЮДЖЕТНОЕ ОБРАЗОВАТЕЛЬНОЕ УЧРЕЖДЕНИЕ ВЫСШЕГО ПРОФЕССИОНАЛЬНОГО ОБРАЗОВАНИЯ «САМАРСКИЙ ГОСУДАРСТВЕННЫЙ АЭРОКОСМИЧЕСКИЙ УНИВЕРСИТЕТ имени академика С. П. КОРОЛЁВА (НАЦИОНАЛЬНЫЙ ИССЛЕДОВАТЕЛЬСКИЙ УНИВЕРСИТЕТ) »
САМАРА Издательство СГАУ 2012УДК СГАУ: 42ББК 81.2
© Самарский государственный аэрокосмический университет, 2012
AN-12VocabularyT u r b o p r o p , cantilever, double-slotted flap, stressed skin, dihedral tippanel, pressurized compartment, engine shutdown.
UNIT 2 AN-24Vocabulary Auxiliary power plant, nacelle, double-slotted flap, wing root, ventralfin, hydraulically-retractable three-strut landing gear, ram, cockpit, rivetjoint, adhesive-bonded joint, integral fuel tank, engine air intakes cowling. The aircraft was developed in mid-sixties. It is powered by AI-24 jet-prop engines. The performed tests and aircraft operation revealed that it isfeatured with a good stability and easy controllability, capable to continueone engine inoperative takeoff. AN -24 is equipped with RU-19A300auxiliary power plant of 800 kgf-thrust mounted in the RH turbopropnacelle. This engine improves the aircraft take-off performance. An-24 is configured as a cantilever monoplane with high-mounted wingequipped with extended Fouler flaps. The double-slotted flaps are externallyfitted at the engine nacelle and single-slotted flaps are installed at the wingroot. The tail unit has a traditional design; aircraft is completed with aventral fin. The aircraft is provided with reliable wing and tail unit anti-icingsystems. The fuselage is of a semi-monocoque type. The hydraulically-retractable three-strut landing gear has double wheelsat each strut, steerable nose wheels, providing pressure inside tires to beadjusted on the ground. The landing gear construction and mechanicaldesign ensure its extension by gravity or by ram air even if any system fails.The main landing gear struts are installed in the engine nacelles and areretracted against ram air into special compartments. The nose wheel isinstalled at the fuselage front end and is retracted into compartment underthe cockpit. The nose strut is a pedal-controlled unit that significantlyimproves the aircraft mobility on the ground. The landing gear wheels withlow-pressure tires allow landing at wet unpaved aerodromes.
4 The adhesive bonded joints were for the first time applied for An-24 inthe practice of world aircraft construction. More than 67% of rivet jointswere replaced with adhesive-bonded joints that resulted in the increasedstructure fatigue, considerable labor performance saving and production costreduction. The aircraft wing consists of centre-section, two middle sections and twotip sections. The wing middle sections are fitted with double-slotted flaps,while the centre-section is fitted with single-slotted flaps. Each root aileronis fitted with a trimmer and balance tab. The centre-section incorporates foursoft fuel tanks; the middle section chambers are made as pressurized integralfuel tanks. The aircraft is equipped with communication aids and all facilitiesrequired for day and night flights in adverse meteorological conditions anyseason of the year. The aircraft altitude equipment produces and maintainspressure and air temperature required for the crew and passengers normalvital activity when flying at high altitudes. In icing conditions the wing leading edge, tail unit and engine air intakescowlings are heated with hot air taken from the engine compressors. Thepropellers, cockpit windshields, pitots, batteries containers are provided withelectrical heating. If required, An-24 can be easily converted either to a cargo-passenger orcargo version. An-24 aircraft is one of the best world examples of aircraftsfor its reliability and operating life.
2620 знаков.
NOTES: Pitot = Pitot gage = трубка Пито, питометр
II. Read the text and write a brief heading for each paragraph. III. Translate the second and the third paragraphs in a written form. IV. Make up a summary of the text. 5UNIT 3 Mi-8 Transport Helicopter
3400 знаков.
2700 знаков
Many passengers are interested in the matter what AC they will fly in thenearest future. Really, that good and safe AC TU-134 and TU-154 graduallyinferior on their technical characteristics should be changed. It is possible topurchase an old Boeing or Airbus but what for should we support the foreignproducers when the new AC for short and medium range is creating now? Itis more comfortable and safe than the other AC of this modification and themain reason is that this AC is a Russian one. The name of the firstling ofnew Russia's aviation industry is TU-334. The history of this AC began in 1985 when the Ministry of CivilAviation of the USSR expressed the wish to obtain AC of 100 seats tochange TU-134 in future. The construction of the AC was charged to theTupolev design bureau because they had an experience in creation of thesimilar AC. It was the first time when they decided to join 2 projects together TU-204 and TU-334. It was done in order to avoid further operational problems.There was nothing like this in Russia before. The construction of a fuselage,navigation system and the other units were similar but TU-334 had a littleshorter fuselage. The new AC should be more comfortable than the oldversions because nowadays the air companies pay great attention topassenger comfort. Moreover this AC should comply with all the noiserestrictions. The AC should be fitted out with the most modern equipment.The crew cabin of TU-334 is like the traffic control console. In pilots'disposal there are several monitors that can show different information aboutthe flight from the map to the fuel quantity instead of a great number ofcompasses, speedometers and altimeters. TU-334 is one of the first RussianAC equipped with the number of crew members reduced to two people: thecaptain and the co-pilot. The duties of navigator, flight engineer and radiooperator are performed by the technique. The equipment does not allow thepeople to make a mistake because the computer controls every pilot action. The weather is not the barrier for TU-334. It can take off and land inpoor visibility when the cloud ceiling is less than 10 meters. The first flight of the TU334 took place in 1999. From this time this ACflies all over the world surprising the visitors of aviation salons with its lownoise characteristics. Really taking off of this AC is practically noiseless.
10 Several modifications were worked out on the basis of main project.They differ from each other in seat capacity, in range and in engine model.There are several modifications with Rolls-Royce engines. It means thatforeign companies will also purchase TU-334 because it is not inferior toBoeing -717, and the price of TU-334 is only a half of the Boeing's price.And it does not mean that our AC is worse than Boeing. Our engineers cansave on everything except the passenger comfort and safety. First of all this economy is based on the similarity of the different ACtypes. Now all the world aviation enterprises do the same but Tupolevbureau does it in better way. In 1996 the Tupolev bureau created a project of transport regional ACTU230. The new AC is practically the copy of TU-334. The 75% of themain units for the both AC are similar. What does it mean? It means that in10 years we will be able to forget about the delays on technical reasonsbecause it will be easy to change any unit. And there will be more comforts and conveniences for the passengersbecause the seats in TU-334 are wider and there is extra space for legs. Alsothere will be the system of video monitors which allow the passengers towatch movies and video clips. This AC attracts attention of VIP-companieswhich operate business flights. The Tupolev bureau suggested the VIP-layout of TU-334 with wide seats, comfortable sofas with a study and ashower with computers and telephones. It will be mobile office in the sky.By the words, the cost of this office will not exceed the 30 million dollarsbut for the west analogues you should pay 100 million dollars.
3300 знаков
I. Read the text and summarize the main idea of each paragraph.
II. Read the text and answer the question. What provides low cost ofthis airplane?
11UNIT 6 Su-27
2700 знаков
III. Read the text and entitle each paragraph of the text.
UNIT 7 Su-30
5800 знаков.
UNIT 8 MiG-31 FOXHOUND
16being mechanically directed the radar beam is moved electronically. Thisallows the full fuselage diameter to be used for the antenna, a considerableadvantage since antenna diameter and effective operating range are directlyrelated. Electronic steering of the radar beam is faster than can be performedmechanically, and it is also more accurate. All signal processing is digital. 3. The radar ensures simultaneous search and attack of several targetsusing long-range missiles and makes possible to interact within a group. TheMiG-31 interceptor-fighter can intercept air targets in all weather conditions,day and night and in continuous and discontinuous field of control andguidance commands (solo and in group), or regardless target defensivemaneuvers. 4. The aircraft avionics enables the use of missiles with radar- and IR-homing heads. The FOXHOUND carries the long-range air-to-air missiles,and can engage 4 different targets simultaneously with the M-9. 5. The airframe was extensively redesigned for supersonic flight at lowaltitude, with the welded nickel steel content reduced from the Mig-25's 80%to 49%, with 16% titanium, 33% aluminium alloy and 2% composites. Thewings of the aircraft are high-mounted and swept-back with square tips and anegative slant. There are four underwing pylons. There are two turbofanengines in the fuselage. The aircraft is powered by two D-30F6 turbofansdeveloping a takeoff thrust of 15,500 kgf each. The mixed-flow turbofan isfitted with an afterburner and fully-variable flapped jet nozzle. The newSoloviev D-30F6 engine was specified for the MiG-31 in order to improverange, the key performance parameter for which an improvement over theMiG-25 was demanded. There are rectangular and diagonal cut air intakeson the sides of the fuselage. The exhausts extend beyond the tail plane. Thefuselage is rectangular from the intakes to the exhausts and has a long, sharpnose. The aircraft has a bubble canopy. The tail fins are back-tapered withangular tips and canted outward. The stabilizers are swept-back and taperedand mid- to low-mounted on the body. 6. Two specialized MiG-31Ds were built in 1987 as carriers for anantisatellite missile, in imitation of a contemporary US program that used aMcDonnell Douglas F-15. These two Foxhounds featured triangular"webbed feet" wing endplate fins, like those fitted to some MiG-25prototypes, in this case intended to provide improved flight stability at highaltitudes for missile launches. A single large missile was to be carried underthe fuselage, and a special upward-looking radar and associated interceptfire-control system was to be fitted to production machines.
17 7. The Mig-31M is an improved version of the basic Mig-31. The key tothe MiG-31 M's effectiveness is the SBI-16 Zaslon fixed phased arrayantenna radar which is said to be the world's most powerful fighter radar.The cockpits were upgraded in the Mig-31M with a number of Cathode RayTubes (CRT) and an increased number of missiles. 8. The MiG-31E export model provides facilities for vectoring up tothree fighters, types MiG-21-93, MiG-23, MiG-25, MiG-29, Su-27 to ensurea covert attack. A group of four MiG-31E fighter-interceptors is capable ofinterchanging data in the automatic mode on presence of air targets in thezone up to 800 km wide. MiG-31E fighter-interceptor is designed forinterception and destruction of aerial targets flying at altitudes of 50 to 28000m in front and rear hemispheres including those under normal andadverse weather conditions, the target maneuvering and enemy deployingactive and passive countermeasures. 9. Aerial targets can be intercepted by a single MiG-31E aircraft or by agroup of up to 4 MiG-31E aircraft. Interception can be performed with theaid of guidance by ground automated control system or autonomously withoptimum target distribution among the members of the group.
4000 знаков.
UNIT 9 F-22 Raptor
18 The Lockheed Martin/Boeing F-22 Raptor is a single seat, twin-enginefifth-generation fighter aircraft that uses stealth technology. It was designedprimarily as an air superiority fighter, but has additional capabilities thatinclude ground attack, electronic warfare, and signals intelligence roles.Lockheed Martin Aeronautics is the prime contractor and is responsible forthe majority of the airframe, weapon systems and final assembly of the F-22.Program partner Boeing Integrated Defense Systems provides the wings, aftfuselage, avionics integration, and all of the pilot and maintenance trainingsystems. Lockheed Martin claims that the Raptor's combination of stealth, speed,agility, precision and situational awareness, combined with air-to-air air andair-to-ground combat capabilities, makes it the best overall fighter in theworld today. The F-22 Raptor is a fifth generation fighter that is considered a fourth-generation stealth aircraft. Its dual afterburning Pratt & Whitney F119-PW-100 turbofans incorporate pitch axis thrust vectoring, with a range of ±20degrees. The maximum thrust is classified, though most sources place it atabout 35,000 lbf (156 kN) per engine. Maximum speed, without externalweapons, is estimated to be Mach 1.82 in supercruise mode. The absence ofvariable intake ramps generally limits speeds to approximately Mach 2.0.Such ramps would be used to prevent engine surge resulting in a compressorstall, but the intake itself may be designed to prevent this. The true top speed of the F-22 is unknown to the general public. Theability of the airframe to withstand the stress and heat is a further key factor,especially in an aircraft using as many composites as the F-22. However,while some aircraft are faster on paper, the internal carriage of its standardcombat load allows the aircraft to reach comparatively higher performancewith a heavy load over other modern aircraft due to its lack of drag fromexternal stores. It is one of only a handful of aircraft that can sustainsupersonic flight without the use of afterburner augmented thrust (and itsassociated high fuel consumption). This ability is now termed supercruise.This allows the aircraft to hit time-critical, fleeting or mobile targets that asubsonic aircraft would not have the speed to reach and an afterburnerdependent aircraft would not have the fuel to reach. The F-22 is highly maneuverable, at both supersonic and subsonicspeeds. It is extremely departure-resistant, enabling it to remain controllableat extreme pilot inputs. The Raptor's thrust vectoring nozzles allow theaircraft to turn tightly, and perform extremely high alpha (angle of attack)maneuvers such as the Herbst maneuver ,Pugachev's Cobra, and the Kulbit. 19The F-22 is also capable of maintaining a constant angle of attack of over60°, yet still having some control of roll. The F-22 cockpit is a glass cockpit design without any traditional analogflight instruments and represents a marked improvement on the cockpitdesign of previous advanced aircraft. The leading features of the F-22cockpit include simple and rapid start-up, highly developed HMI, lighthelmet, large anthropometric accommodation and highly integrated warningsystem. Other main features include large single-piece canopy, side stick andimproved life support systems. All internal displays are designed to be used with night vision gogglesbecause the aircraft lacks optical or IR vision devices. The YF-22A prototype and production F-22A are sometimes confused inpictures, often at angles where is difficult to see certain features. Severalsmall design changes were made from the YF-22 to the F-22A. Swept-backangle on the wing's leading edge was decreased from 48 degrees to 42degrees, while the vertical stabilizer area was decreased 20%. To improvepilot visibility, the canopy was moved forward 7 inches (178 mm) and theengine intakes were moved rearward 14 inches (356 mm). The shape of thewing and stabilator trailing edges was refined to improve aerodynamics,strength, and stealth characteristics. Also, the vertical stabilizer was shiftedrearward. The airframe also features three internal weapons bays on thebottom and sides of the fuselage.
3600 знаков.
5300 знаков
I. Read the text and write a brief heading for each paragraph.
25UNIT 12 Energia-Buran Reusable Space System
27 Учебное издание


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GANDIA Blasco
- Material
- ABS, aluminium, polycarbonate.
- Dimensions
- Ø 17 cm - H. 14,9 cm
- Illuminant included
- no
Suspended light fitting. Body in varnished aluminium sheet, shade in photo-etched optical polycarbonate. Internal reflector in photo-etched ABS. Orientable body. Powered directly from mains. The LED can be dimmed with a «Triac for Led» dimmer approved by Flos.Flos does not respond in case of wrong electrical connection system installations. The cable has a useful length of 9 meters and thus the lamp can be suspended 3 meters from the ceiling. Multiple rose with capacity to connect up to 5 Aims also available.
The beginnings of Flos (meaning "flower" in Latin) blossomed from a brilliant idea: to create objects, starting with a light bulb, that would change the way of life for both the Italian market and the foreign markets. Dino Gavina and the small Eisenkeil manufacturing facility in Merano, had already been creating furniture alongside design masters such as Achille and Pier Giacomo Castiglioni, Afra and Tobia Scarpa.
Complete the look


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To celebrate their new Can't Look Away: The Lure of Horror Film exhibit — that they obviously curated just for me — the EMP is throwing a huge partay on Saturday night {10/1} called the Fashionably Undead Bash: A Totally Killer Dance Party. Starting at 9pm, there will be beer & cocktail specials, a costume contest, and music from The Talking Deads (a zombie cover band of The Talking Heads. what), the always entertaining Head Like a Kite, and, I quote: "iconic horror-themed jams from DJ Severed Hans". hee.
Some lovely stylists and makeup artists from VAIN will also be on hand to assist with scary-hip looks. What does all this awesomeness cost, you might ask? Why, a mere $10 for EMP members, and $18 for everyone else.
Fashionably Undead Bash
Saturday, 10/1, 9pm-1am
EMP Sky Church
$10 members/$18 non
get tix online at Brown Paper Tickets


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PEV Grow is proud to present the Fast Bud 2 Auto from the Sweet Seeds seed bank, a true icon that shows that great perfumes always come in small bottles. Its genetics is predominantly Diesel, which undoubtedly conditions its organoleptic properties, which will delight those who love the traditional flavors of cannabis.
What does Fast Bud 2 (Auto) look like?
Fast Bud 2, is an autoflowering marijuana strain of 3rd generation presented to the public by Sweet Seeds in 2013, and is the result of research and development, which has improved both the terms of production and the quality of this herb. It is a small plant, perfect for indoor crops or to go unnoticed in an outdoor garden, perfect for a guerrilla crop.
Which is the taste of Fast Bud 2 (Auto)?
Its flavor is acid and strong, with clear notes to Diesel, that without a doubt will be loved by the old lovers, avid in these last times of flavors that evoke those marvelous years 90, where the cannabis of truth was appreciated, the one that to each puff has a brutal punch that without a doubt you will love.
Which is the effect of Fast Bud 2 (Auto)?
A great genetic always entails great effects, and Fast Bud 2 Auto was not going to be less, very active mental effects, with a very strong initial climb, accompanied by a very intense descent that leads to a maximum body relaxation, perfect for a good night's sleep, while your mind flies to the farthest corners of your imagination. Medical marijuana users use it for its impressive medicinal benefits against insomnia, episodes of stress and anxiety crises.
How can I grow Fast Bud 2 (Auto)?
In indoor crops, its small size makes it a perfect option to make the most of the m2, for which I recommend you use 7-litre pots, as you will not need more, and you will be able to place up to 14 specimens per m2. Place it at 20 hours of light from the beginning, with a LEC lighting system of 315w, with which you can collect between 450-500 gr per m2, some wonderful buds that give off a bestial aroma, so you must arrange a good charcoal filter to avoid attracting the attention of your neighbors.
In outdoor crops, is perfect for growing in the city because it will go unnoticed thanks to its small size, only needs a good dose of sunlight, and nature takes care of the rest. It is a very good option for those who seek a good production in record time, since, in just 60 days from germination, will be ready to collect up to 55 grams per plant, and you can also make several crops a year, Why wait for a variety of season?
At PEV Grow, we work every day so that your satisfaction is complete, and so that in our online Growshop you can find everything you need, and one of the big ones couldn't be missing. Buy now Fast Bud 2 Auto strain from Sweet Seeds, at the best price in the market, in your trusted online Growshop!


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Starry Pines – Adult Only Paint Event @ Avenida Cantina
June 22, 2022 @ 6:00 pm - 8:00 pm$29.00
Find your inner Picasso!
Your host will guide you through this painting step-by-step. We provide all the supplies you need including an apron to protect your clothes, or wear something you don't mind decorating with a bit of paint.
Paint with us at Avenida Cantina and enjoy great tacos and fun vibes! Come early to grab your seat and check out their menu for fantastic food and drink specials!.
The ticket price doesn't include drinks or food and no outside food or drink is allowed.
Buy a ticket to four separate events and the fifth event is on us!
Who's Attending
15 people are attending Starry Pines – Adult Only Paint Event
- Kelsey H.
- Shelbi W.
- MacKenzie B.
- Heidi G.
- Tina W.
- Darlene F.
- Jenna R.
- Rian D.
- Maritza D.
- Tonya S.
- Tracy L.


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CBD Oil and Pregnancy — secure for usage or a Hazard?
It's true what people say — everything modifications when you conceive. Some things become inconsequential, while some, like health, become paramount. Consequently, it is just normal to make sure everything health-related whenever carrying a kid.
One of the more questions that are common ladies have actually about CBD oil is if it is suitable for maternity. CBD is a remedy that is known sickness, headaches, and anxiety. Consequently, it seems like a solution that is fantastic many pregnancy-related problems like early early morning nausea or conditions that are even severe like hyperemesis gravidarum. But, before usage, it is just normal to Do your research and there find out everything is to learn about CBD oil and maternity.
CBD oil and maternity — a topic that is controversial
There's been large amount of speak about CBD oil and maternity. Sadly, very few scientific tests have now been done this far. Therefore, experts still aren't 100% certain that CBD is completely safe for the fetus.
Scientific studies haven't favorably concluded that CBD is safe to utilize during maternity. Nonetheless, there is sufficient research that determined the possible lack of correlation between CBD oil usage and problems during birth, congenital anomalies, or stillbirths.
Exactly How CBD might have a visible impact in the maternity therefore the fetus
The truth is, the results that CBD oil may have, both in the mom additionally the fetus, rely on the endocannabinoid system. Similar to with ladies who aren't expecting, the consequences CBD may have change from individual to individual.
Additionally, there's still some concern concerning the development that is neurological associated with fetus, and exactly how CBD might influence it. One faction advocates the application of CBD oil and claims it encourages neurogenesis. But, other people question the possible advantages and declare that, since mind development straightincludes cannabinoid receptors, CBD can negatively influence the neurogenesis.
The debate is ongoing, however the hopes are that the answer that is definitive soon happen. THC happens to be the focus of several studies on the years, while CBD just recently arrived to the limelight. More particular studies bringing particular responses may happen quickly. Nevertheless, for the present time, you can find definitive responses.
Vomiting and nausea
It's a fact that is well-known CBD oil might have an array of healing advantages. The main topic of CBD oil and maternity is place in viewpoint for all anticipating mothers as soon as sickness and start that is vomiting. CBD, an understood treatment for sickness among chemotherapy clients, can really help women that are pregnant combat also serious issues, like hyperemesis gravidarum.
Contractions and labor that is premature
According to one study that is promising CBD can really help stop preterm contractions. Which comes page as very good news for expecting moms that have a risk that is high of premature labor. What's more, CBD can be a muscle that is excellent aswell. Consequently, it may provide a hand that is helping contractions females experience while pregnancy, plus the pain that accompanies them.
But, this summary is dependent on the extensive research done on cells away from your body. Consequently, the research continues to be into the initial phases, but the outcomes are promising.
Soreness management
Another known good thing about CBD oil is discomfort management. CBD oils that don't contain THC are nevertheless not advised by physicians, but only since they can't guarantee positive results. Moreover, there hasn't been a longitudinal research to depend on with regards to prescribing the technique of usage and dosages.
But, CBD oil is reasonably safe to make use of during pregnancy as a discomfort management device, it doesn't as it doesn't require vaping or smoking and include ingesting THC.
Anxiousness and blood circulation pressure
Tall blood force and anxiety are normal during maternity. Being a known analgesic and anxiolytic, CBD will help battle discomfort, raised blood pressure, and anxiety during maternity.
But, take into account that CBD is not a substitute that is proper any medicine prescribed with a medical professional. It is essential that expectant mothers consult their doctor before utilizing any CBD items while holding a young child.


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White chocolate cups. Can be used as chocolate dessert cups, moulds are even chocolate shot cups.
Please note that the pattern/design on the bottom of the cups may vary. The round cups are hollow, ready for piping in the filling of your choice.
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DD's Jewelry: Turning a Hobby into a Business
As students strive to find a hobby that will help them cope with the stressors of everyday life, some might find relief in playing a sport such as basketball or soccer, while others immerse themselves in the freedom of writing, painting and photography. For junior Dainelys Ledesma, her pastime takes the form of ornate beads and colorful string that eventually transform into bracelets and necklaces. Behind each one of Ledesma's creations is an inventive vision she brings to life, through the art of jewelry making.
Ledesma's journey to jewelry making began two years ago when the world shut down, due to the pandemic back in 2020. While carefully managing her responsibilities with her academics during her eighth-grade year, she decided to take on a hobby to help make time pass by.
Watching several videos online, she found inspiration from people who had lost their jobs during the pandemic's shutdown and decided to take matters into their own hands by opening small businesses from home. There, she saw entrepreneurs create bracelets and necklaces from merely beads and threads. She then began perfecting the art of jewelry crafting by creating unique pieces to brighten people's days. What initially began as a hobby quickly turned into a business venture for Ledesma, as she established DD's Jewelry.
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"I saw a lot of people starting small businesses at home and I saw it as an opportunity to be a little more independent. I started around august 2020, I love making jewelry. I like being able to turn an idea into something physical, it's therapeutic for me," junior Dainelys Ledesma said.
While Ledesma often sells her handmade jewelry on social media such as Instagram, her business mainly thrives in her mother's nail salon. There, she puts her bracelets and necklaces on display to catch the attention of customers. In addition to her ready-made bracelets, Ledesma routinely makes made-to-order bracelets for her clients who request specific color combinations or gems. To accommodate the various requests from her customers, Ledesma sources her materials primarily from Amazon to ensure that she can complete her orders quickly and efficiently.
"I like to think of it as a hobby that I enjoy doing so I don't take the fun out of it. I just want it to make people smile even if it's by making something simple that looks cute," junior Dainelys Ledesma said.
Although DD's Jewelry has given Ledesma financial independence alongside a creative outlet, balancing her business and her academic career can prove to have its difficult moments. As a result of many of her clients often ordering several bracelets at a time, becoming overwhelmed with orders is not an infrequent occurrence for Ledesma. Fortunately, she navigates this by managing her time diligently, making sure to reserve jewelry crafting for the weekends.
"Dainelys is the type of student that will go far beyond. She is always willing to help her peers in class and she uses her talent of creating jewelry to teach others how to create bracelets and necklaces. Hopefully as the school year goes on, she will be able to create a lesson plan since she is in my Teaching Academy class, for students to learn how to make the pieces and ultimately inspire others to use their hobbies for something more," Ms. Passwaters said.
Ledesma strives to continue viewing the hobby as a method of destressing rather than as a chore or stressor. With this no-pressure mentality, Ledesma hopes to expand DD's Jewelry and utilize this talent of hers to help those who are interested in learning how to make jewelry while striving for success in her academics, extracurriculars and personal life.
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Lorena Acevedo is a junior in the Design Education and Hospitality program at Coral Gables Senior High. Entering her second year in CavsConnect, she hopes...
Jacqueline Rodero is a senior in the International Baccalaureate program. This is her second year as a CavsConnect staff writer. As she closes her time...


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Official Wikipedia Android app finally lands in the Market
It's been a long time coming, but Wikipedia has finally released an official Android app, sneaking it into the market a few days ago. It's kind of ironic timing given that Wikipedia is blacked out today in protest of SOPA and PIPA, but everything seems to be working on the mobile version.
Features of the app include:
- Save for later for offline use
- Search articles nearby
- Share articles
- Multiple language support
- Full screen search
It's great to finally see an official Android app from Wikipedia. Alternatives that we've used have been decent, but it's nice to have one straight from the Wikipedia developers. The free app is available in the Android Market. We've got links to it after the break.
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I like irony.
Is it blacked out today too? :)
How is this better than Google Search?
Another useless app to consume phone memory.
It makes the pics bigger! http://tinyurl.com/cend4gm
I prefer Wapedia over this...
Wapedia has a dark theme option.
Agreed. Wapedia supports Wiki Travel, for one thing.
As amusing as it is to see this today of all days, it looks like it was actually released 5 days ago. So no, they didn't release it on the SOPA blackout day...that's just when AC wrote about it. :-)
I just book marked the mobile site...::shrug::
Google's search in the Market leaves something to be desired. I typed in Wikipedia, and the actual official app was something like 12 items down. I've seen this strange ranking on other app searches as well. I wonder what their criteria is.
Actually, mobile Wikipedia was not blacked out at all. I used it several times today. Although through a "desktop" browser, it is. Anyway, I don't see the need for yet another "app" that is just a wrapper around a perfectly usable website. But, to each their own!
Very nice and at quite an appropriate time!
Very nice. Works well and has some nice features. Kudos!
No widget, no care
If you've got the NoScript extension for Firefox, Wikipedia works just fine today anyway.
Been using Wiki Encyclopedia Pro (paid app) for sometime and its great. You can get it free from getjar gold apps.
Can't be moved to my SD card so I immediately uninstalled it without even opening the app.
I'm getting pretty bad screen blinking after scrolling on the Verizon Galaxy Nexus.
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Talia Brookshire
Vice President, Marketing and Community Outreach, Sky Zone Indiana
A sports marketing executive for nearly 15 years, Brookshire is currently the Vice President for Marketing and Community Relations at Sky Zone Parks in Indianapolis. Developing and managing marketing campaigns for NASCAR, Ford Racing, USA Swimming and USA Track & Field have provided Brookshire with a unique portfolio that has heavily emphasized community outreach and partnership management. In her role at Sky Zone, Brookshire oversees marketing, public relations, social media, special events, communications, partner relations and sales. A graduate of Central Michigan University, Brookshire has lived in Indiana for seven years. She currently resides in Lawrence with her husband and three daughters.


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If you are fortyish lesbian living in Toronto who's been to bed with every other fortyish lesbian living in Toronto, some of whom reside with cats, you can finally experience yourself on screen thanks to the efforts of Christina Zeidler and John Mitchell with Portrait of a Serial Monogamist (POSM).
Self-described as a "fresh coming-of-middle-age rom-com," POSM is indeed a straightforward tale of a self-involved female Lothario that shovels out all of the well-worn woman-on-woman clichés with an enervated panache. Just imagine Trainwrecked without Amy Schumer, without the sexcapades, and without any riotous hahas.
The film begins with Elsie Flacks (Diane Flacks), a Jewish, cultural TV producer, breaking the fourth wall while frying bacon: "It sucks to be dumped. That's why there are so many songs about heartbreak. But how come there aren't more songs from the point of view like 'Time to Call It a Day'?"
She then explains why she became such a shady, backstabbing Lothario. When she was a mere lass, she notes, her best girlfriend played kissing games with her. Well, one day the pecking games stopped, and a crushed Elsie decided no other woman in her life would ever again have the upper hand.
Immediately after that reminiscence, Elsie dumps Robyn (an engaging Carolyn Taylor), her latest live-in lover. Yes, the gal's ready to move on because this current romance has experienced some rough patches after five years. No Dr. Phil for her. If something needs fixing, why bother when a new model is available. But as Elsie quickly learns, being over 40 has its challenges. The Internet is for teens, and she's outgrown bars. What's a single gal to do? Dog walkers in the park are a good possibility if they are walking the right kind of canine. Forget Labradors. Or how about having sex without commitment? Or having no dalliances at all for five months to clean out her palate?
Sarah (Sabrina Jalees) advises Elsie on which dog walker to cruise.
(Courtesy of Wolfe Video).
But then the attractive, ununsettled, hetero-flexible Lolli (Vanessa Dunn), a DJ/barista, wins over our heroine's heart, but does Lolli even want that heart?
What follows are several conversations with Elsie's friends, ex-lovers, and her mom, who describes herself as "just a nice Jewish girl from Montreal."
Ma: "I don't understand your behavior. In my day, if a woman your age was single, we'd call her an old maid."
Elsie: "Which is just a euphemism for a lesbian."
Ma: "Well, I don't know what you call it. I just don't want you to be alone for the rest of your life."
Amidst these chit-chat encounters, there are scenic shots of Elsie bicycling around Toronto, Elsie walking about town with Lolli, coffee-shop rituals, an art-gallery opening, a memorial service for a pet, and so forth. As the moments tick by, our heroine nears the revelation that "in order to feel love, you have to be open to heartbreak." Even Neil Sedaka's paean to uncoupling misery, "Breaking Up Is Hard to Do," is saluted verbally. Inclusion of the actual tune, of course, would have been financially prohibitive. Instead, we get some rather appropriately titled songs such as Summer Eves's "Let's Quit While We're Still Ahead," Light Fires's "Let's Get Divorced," and Rae Spoon's "When I Said There Was an End to Love I Was Lying."
Never less than pleasant, it's hard not to imagine that if POSM had been released in the early 1990s, it might have been greeted as daring and filling an abyss that a film such as Rose Troche's Go Fish (1994) did back then. But in a year with Todd Hayne's Carol, the gals in Transparent going at it, and with Chantal Akerman's recent departure to remind us of her groundbreaking love scene in Je Tu Il Elle (1974), a pleasant comedy without any teeth doesn't seem to be enough anymore.
(Portrait of a Serial Monogamist was released on DVD/VOD last week.)


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Lucky leprechaun scratch
The Lucky Leprechaun Scratch slot game is one of Microgaming's newest creations. The theme of this Irish-themed game is based on the popular Irish folk tale, Lucky Leprechaun. The lucky leprechaun, a symbol of luck and luckiness, can be found on three rows and five reels of this video slot. Players can wager up to 20 credits per line and 750x their bet size. Regardless of how large of a bet you make, you should be able to win a lot of money.
The Lucky Leprechaun Scratch slot machine is part of the Lucky Leprechaun Slot series. This game features various Irish symbols including a violin, pipe, pint, pot of gold, clover, and the game logo. As with most other Microgaming slots, the game's icons are unique and fun to see. While the graphics aren't the best, the sound quality of the Lucky Laprechaun Scratch slots is great.
The Lucky Leprechaun Scratch slot game has five reels, three rows, and twenty non-selectable paylines. While this game does not have the bonus features and free spins that other Microgaming slot games offer, it still offers an enjoyable playing experience. The unique theme of this slot makes it an excellent choice for Irish themed parties. In addition to being a fun conversation starter, it can also be used as a drawing giveaway at your next event.


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After just taking a look at the brand's new magnetic wood desktop accessories, we now have an exclusive offer for 9to5 readers on the Oakywood iPhone 13 cases. In fact, today's promotion applies to everything Oakywood sells sitewide, whether that's its felt iPad sleeves we reviewed previously or its handmade oak and walnut monitor stand shelf, everything is now 15% off with our special code. Shipping prices vary by order and delivery location and start at around $5 or so. Head below for more details, deals on the new Oakywood iPhone 13 cases, and our exclusive promo code.
Exclusive Oakywood iPhone 13 case and accessory deals:
All 9to5 readers can now use code 9to5 at checkout to knock 15% off the new Oakywood iPhone 13 cases alongside everything else you'll find on the brand's official site. Deals on Oakywood's handcrafted, natural accessories don't come around very often, so now's a great time to score yourself a new wooden iPhone 13 case or some high-quality desktop gear with a rare discount attached.
The new Oakywood iPhone 13 Walnut or Cherry Wooden MagSafe Case, for example, currently fetches the same $45 it launched at last month. But using our exclusive discount code above, your total will drop down to $38.25, the lowest price we have ever tracked on the latest MagSafe-ready models.
Available in real walnut or cherry wood finishes, each purchase will get one tree planted and yield a high-quality, natural cover for your precious new Apple handset. Learn more about the latest iPhone 13 cases from Oakywood in our launch coverage right here.
And remember, the code will also apply on the brand's felt MacBook and iPad sleeves, the previous-generation iPhone cases, its felt wool AirPods cases, this handmade oak and walnut monitor stand, and everything else you'll find on the brand's official site.
More on the Oakywood iPhone 13 Wooden MagSafe Case:
A wooden MagSafe case for iPhone 13 will perfectly complement your device and protect it against damage. With the wooden MagSafe case designed by Oakywood, you will take full advantage of the possibilities offered by your favorite device – and at the same time add a touch of natural charm to it. Durable walnut wood, precise fit of the case to all iPhone 13 models, compatibility with Apple accessories
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Journal Article — Go West Young Turk: Personal Encounters with Kemalism — by Khaldoun Samman
My research can be described as a comparative-historical analysis of what I define as three modes of identities found in the Middle East: Occidentalizing, Modernizing, and Orientalizing nationalist identities. My main concern is this overlapping question: How did Palestinians and Arabs come to be seen as distinct from the Jews, Greeks, and Turks of this once symbiotic civilization, all presumed to be in need of separate national "homes" (i.e., the containers called nation-states)? Here I focus on the impacts that modernity has had on the identities of this world and myself.
Recommended Citation
Samman, Khaldoun. 2004/2005. "Go West Young Turk: Personal Encounters with Kemalism." Pp. 183-192 in Sociology of Self-Knowledge: Course Topic as well as Pedagogical Strategy (Human Architecture: Journal of the Sociology of Self-Knowledge: Volume III, Issues 1&2, 2004/2005). Belmont, MA: Okcir Press (an imprint of Ahead Publishing House).
Section url: https://www.okcir.com/product/journal-article-go-west-young-turk-personal-encounters-with-kemalism-by-khaldoun-samman
The various editions of Sociology of Self-Knowledge: Course Topic as well as Pedagogical Strategy can be ordered from the Okcir Store and are also available for ordering from all major online bookstores worldwide (such as Amazon, Barnes&Noble, and others).
Free-Access Okcir Library ReadingSamman-human-architecture-ssk-topic-strategy


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I used my ira to pay what i owed in tax year 2015, do i get any credits?
I used my ira to pay what i owed in tax year 2015, do i get any credits?
Sorry, no there are no exceptions to the early withdrawal penalty for paying taxes unless it's in response to an IRS levy.
For your reference, here are all the exceptions:
#. – Exception Description
01 Qualified retirement plan distributions (does not apply to IRAs) you receive after separation from
service when the separation from service occurs in or after the year you reach age 55
(age 50 for qualified public safety employees).
02 Distributions made as part of a series of substantially equal periodic payments (made at least
annually) for your life (or life expectancy) or the joint lives (or joint life expectancies) of you and
your designated beneficiary (if from an employer plan, payments must begin after separation
from service).
03 Distributions due to total and permanent disability.
You are considered disabled if you can furnish proof that you cannot do any
substantial gainful activity because of your physical or mental condition. A medical determination
that your condition can be expected to result in death or to be of long, continued, and indefinite
duration must be made.
04 Distributions due to death (does not apply to modified endowment contracts).
05 Qualified retirement plan distributions up to the amount you paid for unreimbursed medical
expenses during the year minus 10% (or 7.5% if you or your spouse were born before
January 2, 1952) of your adjusted gross income (AGI) for the year.
06 Qualified retirement plan distributions made to an alternate payee under a qualified domestic
relations order (does not apply to IRAs).
07 IRA distributions made to certain unemployed individuals for health insurance premiums.
08 IRA distributions made for qualified higher education expenses.
09 IRA distributions made for the purchase of a first home, up to $10,000.
10 Qualified retirement plan distributions made due to an IRS levy.
11 Qualified distributions to reservists while serving on active duty for at least 180 days.
12 Other (see Other next). Also, enter this code if more than one exception applies
See the following link to Form 5329 for more details:
Found what you need?Start my taxes
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When Safin first started training with Nick he was an unranked junior struggling to win matches at the men's open level. In this series, you can watch if Nick can improve his game in less than a year to the level of a D1 college player. Some of these lessons have been featured on the Intuitive Tennis YouTube channel. Here you will find uncut extended versions with behind-the-scenes footage.
Body involvement is an integral part of any stroke but especially the forehand and serve. Safin was lacking power and was trying to generate it the wrong way leading to mistakes.
Safin's movement is lacking explosiveness. The first few steps are so crucial when it comes to reacting to an incoming ball. Nick diagnosed this issue from the first time he saw Safin play. In this episode, he outlines a plan on how to improve Safin's explosiveness around the court. Furthermore, ...
Safin approached Nick about a new thing he tried on his serve. Nick was ok with the technical change, however, the serve is still lacking power.
One of the biggest problems junior tennis players and their parents face is unrealistic goal setting. Through Nick's extensive experience working with high-level junior players, he has seen disastrous results when players and parents set unrealistic goals. Safin's goals throughout his junior care...
For high-level players that possess technical fundamentals of all strokes, it is very important to play matches. Junior players often don't play enough matches due to various reasons and consequently, their development is halted. Safin does not have enough high-level matches under his belt and th...
After losing some matches where Safin held match points he was discouraged and feeling down. Nick explains his theory on tennis equilibrium and how understanding it can help Safin get through these tough times.
In a recent loss at a tournament, Safin double-faulted more than usual. He was concerned whether there is something wrong with his second serve technique.
After another heartbreaking loss, Safin's confidence is down. Nick encourages him to overcome his struggles and gives him another chance against Milan.
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text: Homeowners InsurancePersonal Insurance Buying Homeowners Insurance for the First Time Purchasing your first home is as exciting as it gets. But it can also be nerve-wracking since it's among the most significant investments you'll make during your lifetime. You've decided on the perfect CNY location and a house that sits exquisitely on the lot. The seller accepted your offer, and you have a closing date. But before finalizing a mortgage with your preferred lender, you must supply them with a truckload of information. Somewhere in that list is homeowners insurance—sometimes called hazard insurance—which you'll purchase due to a lender underwriting requirement. Though the requirement prepares you for unforeseen repair and…Daniel J. MiddletonJanuary 10, 2023


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It's time to end the zombie apocalypse.
In both Television and also The movies, there's a subject matter which has carried out well during the past couple of years: Zombies. This idea has made for some extremely captivating, majorly excellent, as well as award-winning shows as well as motion pictures. Having said that it's all fiction, right?
Well, possibly not. Given that I suggest that zombies have been around for quite a while. And consequently I feel that you've identified them with your own eyes. You've seen them where you work in the break area preparing their third carafe of coffee for the day. You've perceived them out during the nighttime with their small kids. They were the parent or relative that could barely have their head up from a very long day of work. You've viewed them in the classroom as well as on college campuses, sleeping with their noggin on the work desk. You've spotted them on the bus, and moving down the street, barely alert as they go to and from work. Personally I think that you've spotted a zombie. And worse yet, maybe you are a zombie. Affordable Mattress Lakeland Fl
We need sleep, right?
If you have lived for virtually any timeframe, it's no doubt that you have heard an individual tell you exactly how vital rest is. It's quite likely that you've come to realize this lesson on your own, and it's also possible that you've already heard from many others that definitely have understood it too. Without shut-eye, we truly feel like… well, zombies.
As if feeling worn-out isn't already sufficiently of a predicament, there's even more to the narrative. When we are lacking sleep, our brain really malfunctions. That just means our brain is unable to operate well. Truth be told, our human brain really starts shutting down specific areas as well as functions that are not required for your survival. And so to be lacking sufficient sleep is not just a feeling, it is really a bodily impaired state of having to live.
Lots of things occur resulting from this. We certainly have difficulty committing things that we have experienced as well as learned that day into long-term memory. Drowsiness slows down our reaction time and attentiveness. We turn out to be considerably less coordinated and also alert, triggering an increase in accidental injuries and also errors. Our mood fluctuates to a greater degree and more significantly than it needs to. When a severe lack of sleep carries on over an extensive period of time, even our hormone production is completely thrown out of harmony. Affordable Mattress Lakeland Fl
Making issues more intense, long-term sleep disruption results in over production of cortisol. Cortisol in it's correct quantity facilitates us to experience some pressure and urgency to get things undertaken. However when it's overproduced, it results in us to feel stressed, anxious, as well as concerned at all times. This can potentially bring about even deeper medical related issues of anxiety and depression. Obviously, a severe lack of sleep is very bad for any individuals.
You are not alone.
We've all had the experience. Frequently, our everyday life require so much from us. We supply so much of our time and energy to our work as well as careers, our family members and friends, and also our pastimes as well as activities. Typically, it feels like there can be hardly any left, and it is usually hard to take it easy and also recharge.
And yeah, almost certainly we could all use extra sleep. Nevertheless, what happens if we could do greater than snooze longer. What if you can easily snooze better?
The sleep of your dreams.
Welcome to the cloud. DreamCloud is a revolutionary hybrid luxury mattress. They have an easy objective: To create the ultimate hybrid mattress experience. What does this mean?
It indicates that they've taken the cushion experience to the next degree by utilizing innovation new materials and innovations. It implies that they have actually integrated the best of standard mattress design that has coils, and incorporated it with the best contemporary design of advanced foams, textiles, as well as materials. It implies they've developed a premium bed mattress with the very best of everything.
If you feel like you or a loved one might be a zombie, it's very likely because of poor quality of sleep. Maybe you hurt whenever you get out of bed in the morning. DreamCloud addresses this on quite a few levels. It starts with using the most modern breakthroughs in mattress as well as fabric technologies, and the best of traditional mattress coil technology (read on for more information about that), and fusing those together in a singular product. And don't be worried about having to determine what level of firmness to buy and hope that you chose well. DreamCloud has engineered their mattress to a level of firmness that stabilize the give and take of your body weight while you lie in several positions during the night, which gives you the perfect level of comfort and support. Which means you can rest assured (no pun intended) that whichever position you are resting in, it's the right choice.
But there's a whole lot more to it than that. Perhaps you don't just feel painful or uncomfortable any time you wake up. Perhaps your neck, spine area, shoulder muscles, hips, and/or legs hurt. Not any more. Should you lie on your back, DreamCloud mattress offers the correct amount of firmness to support the natural curvature of your spine. Any time you lay on your side, you would like your spine to stay in a straight line. Other mattresses are either too firm, so they push against that natural curvature, or perhaps too soft and allow your spine sink an excessive amount. Either way, both of them are completely wrong, because your spine is forced in either case out of alignment. DreamCloud handles this issue, and the benefits are just as much of a breakthrough as the design of the mattress itself. DreamCloud has truly refined the degree of firmness and also support to a breakthrough degree.
Speaking of breakthrough, DreamCloud has engineered breathing as well as coolness which are unequaled. A lot of this is as a consequence of the breakthrough materials as well as design that the mattress is produced with. When mattresses don't breathe effectively, you will find 2 issues that arise. The first is temperature. Whenever you sleep, the mattress will get hot and is unable to cool-down. Consequently, sooner or later you become very hot, covered with sweat, and not comfortable. Generally, you certainly will eventually wake and have to shift your position and readjust. This is definitely a substantial disruption that would draw you out of a deep sleep, and it takes your body a little while to go back there. This distraction adds a great deal to lacking a high quality nights sleep, despite the fact that you may be sleeping the time-frames you must. This is exactly an immense reason DreamCloud mattresses help you to sleep better. Affordable Mattress Lakeland Fl
You have an additional problem that goes wrong when mattresses don't breathe well as well: moisture. Every time air flow doesn't circulate in a mattress, it accumulates moisture from the air that comes in yet is unable to let it out. This significantly minimizes the life duration of a mattress, because the stagnant moisture begins to make the materials in the mattress deteriorate. It additionally extensively lessens the comfort, given that the broken down materials in the mattress will no longer perform as they ought to. The mattress results in being uncomfortable, as well as remains uncomfortable over its cut down life span. What a waste!
So what exactly is the main difference between DreamCloud and Traditional Mattresses?
We inhabit a world that is certainly always changing. DreamCloud is a paradigm shift in the process a mattress is designed. You see, mattresses have been around generations. And much like cars and households, the method in which one is assembled now a days is different than it was years in the past. Across just about all industries, people are often exploring and making ground-breaking discoveries. From developing and additionally employing innovative components, to enhancing on a design or even establishing a completely new one, the way that we do things shifts as time passes.
Traditional mattresses are made up of a set of box spring and a mattress. The box springs go underneath the mattress, offering an added layer of support to the mattress. The mattress is made with columns of coils all throughout to grant support. Then on top the coils is some sort of "topper". In the old days, this topper was filled with numerous sorts of stuffing or padding, and in more contemporary years different layers of foam. There are lots of companies who have been manufacturing mattresses for a long time such as Serta, Sealy, Jamison, Sleep Number, as well as Amerisleep.
What changed?
The design of traditional mattresses were greatly improved upon across decades. Nevertheless, with a mattress like DreamCloud, instead of being an improvement to manufacturing a traditional mattress, it is actually a completely new type of mattress in general. With modern technology, the continuing development of superior quality foams and gel layers changed just about everything. These kinds of mattresses are a different strategy produced on fresh discoveries throughout the last several years. Foam began making its way into traditional mattresses in the "topper" layer. Remember all of the the rage when Memory Foam first came around? At the time, fresh technology was beginning to trickle into traditional mattresses. But today, DreamCloud has launched a whole new mattress, manufactured totally different from traditional mattresses. You will find absolutely no coils. The mattress is created with foam that is certainly tough, long lasting, comfortable, and breathable, coupled with gel layers that provide stunning support for a brand new age of mattress. And whilst there are more manufacturers like Casper, Purple, Leesa, Tempurpedic, and also Puffy who are creating foam mattresses additionally, all you need to do is try out a DreamCloud mattress to truly feel the distinction (Please read on to learn about the amazing manner in which DreamCloud enables you to do this). Affordable Mattress Lakeland Fl
The best of both worlds.
As specified previously, DreamCloud is hybrid luxury mattress. Now that you know all about traditional cushions as well as the improvements in foams, it's easier to recognize just how DreamCloud brings both of these together to develop an item as well as experience that are absolutely distinct. Let's check out those improvements as well as just how they are present in the amazing and comprehensive construction of the bed mattress.
DreamCloud is built with 8 layers from top to bottom. The top layer is a Truetufted Cashmere Polyester blend. This provides both breathability and also softness. The breathability is important to you sleeping cool and prolonged life of your cushion. And the coolness is essential to a top quality nights sleep.
The second layer is Gel Infused Memory Foam. This supplies contouring assistance that conforms to your body. This layer is in charge of giving coolness as well, as well as it's likewise a significant contributing factor the unbelievable assistance that DreamCloud offers.
The third layer is Super Soft Quilted Memory Foam. As you lay on the bed mattress, the top 2 layers sink right in to this layer, which supplies an extremely soft give that you feel instantaneously. It becomes part of the design that gives simply the right amount of firm support while also offering soft qualities and comfort.
The fourth layer contributes to the very same aspects as the third. It's Supreme Natural Latex, as well as it is hypoallergenic. It includes cushioning as well as bounce, while additionally assisting the mattress support the all-natural contouring of your body.
The 5th layer is Dreamplush Supporting Memory Foam. This luxurious, high thickness memory foam includes a hidden degree of support to the cushioned layers above it. In this way, while you feel the gentleness and also sink as quickly as you lay on the bed, beneath that is this layer returning assistance to you too. It's a game of give and take. And DreamCloud wins at both. Affordable Mattress Lakeland Fl
The 6th layer is Super Dense Super Soft Memory Foam. That's not a typo. It's a layer of foam that is very dense, yet additionally returns support. This enables you to locate the comfort of "sinking in", while likewise being supported and also held in positioning, whatever position you favor to sleep in.
The seventh layer is Patent Pending BestRest Coils. This is where DreamCloud's foam modern technology combines with standard spring innovation. It is a compression system made from micro coils. These micro coils are enclosed in foam, and also have 5 zones of give and take. So as you move, shift, and settle in, these are there all throughout the mattress, regularly supplying the best foundation that you need for a high quality nights rest consistent with resting on a cloud.
And lastly, the eight layer at the very bottom is the foundation of everything. Its a High Density Super Soft Memory Foam layer. And also once more, that's not a typo. It's a layer that dense enough to give you all the assistance you need, however soft enough to let all the comfort as well as gentleness that you need be ever-present. Every layer is vital to the unrivaled comfort that DreamCloud gives, but this is the foundation of all of it.
All these technical components total up to one thing: You will certainly fail to remember that you are really sleeping on a mattress because your body will certainly think you're on a cloud.
Comfort, quality AND value?
It truly is not uncommon for comfort and quality to go arm in arm. Yet they come with a price tag. Well, in most cases. Although not right now.
DreamCloud has comfort together with support in accordance with mattresses that charge $3,000-5,000+. With that top quality, you may be honestly hoping that they are at the low end of that asking price, at around $3,000. Or it could be you may have your fingers crossed merely wishing that they are really only $2,500, or even closer to $2,000. But nevertheless do not stop reading at this point. Because you will not even be paying that.
They don't cost $3,000 . They don't cost $2,000. All of DreamCloud mattresses start off around $1,000. They are all in the $1,000's, even for a California King! At that price point , any person at your house could rest superior for the value of just one traditional mattress. And, they will bring it to your home, set up, and take all of the packaging and your old mattress out for you. For free.
The only solution to know that you enjoy a product is to try it for yourself.
Definitely. It's one thing when a product sounds superior in writing or even in a commercial, but it's a different to definitively experience something for yourself. And with DreamCloud, it is possible to. Not only does DreamCloud offer a remarkable value, in addition to that they back it with an unbelievable guarantee.
How many times can you actually get to try out a mattress for even one night before buying it? You don't get to experience it for you until you've actually purchased it and transported it home. I really hope you made the perfect decision! Affordable Mattress Lakeland Fl
However with DreamCloud, the game has completely totally changed. Because they will deliver it absolutely free to your house, and you can try it for a night. And you can give it a go for a week. And you can test it for a month. And even 2 months. And three months. Where am I going with this? With DreamCloud, you can try it risk free for a year! You get a 365 night home trial. They deliver it to you for free. If you are not 100% pleased, they will come and pick it up for free. However I doubt you will need them to.
Ok, what's the catch?
It does not have any catch. There's simply DreamCloud. Well, there is far more than that. There is certainly a better mattress with amazing value. There's a completely new paradigm in making a mattress, with advancement at each and every turn. There is the comfort and support that you simply deserve. There is incredible quality as well as value. There is an impressive product, reinforced by a magnificent guarantee. There is an end to the zombie apocalypse.
So you wanna give DreamCloud a try? Go ahead. Do it for a year. And do it worry free.
Try DreamCloud today. Don't just sleep more. Sleep better. Try it today, and start getting the sleep of your dreams.


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kebidumei 36dB Signal Amplifier Antenna Booster Tuner 200Mile Digital Indoor HDTV Antenna Satellite Receiver TV Antenna for DVB-T DVB-T2
Name: Adjustable signal HDTV antenna amplifier
Material: ABS
Frequency: 45-862 MHz
Cable length: about 80cm / 31.50in
LNA gain: 36dB
Output degree: 100dBuV
Noise mother: less than 4dB
Energy supply: external adapter DC 6V 100mA or USB power supply DC 5V.
Suitable for any non-amplified/passive TV antenna.
Package included:
1x HDTV antenna amplifier
A new generation of graphic design indoor TV antenna with a thickness of only 0.6 inches.
Especially compatible with various digital terrestrial (for DVB-T, forISDB-T, for DMB-T/H, forATSC) and for DAB/FM radio HDTV.
Two signal modes, short range (0-80 miles) and long range (80-200 miles), select the appropriate mode to find more channels.


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The Double8 is a ranked and timed event from 23 to 82km. It is perfect for amateur riders but also for those who like long distance runs.
In the shape of a double 8 or 4-leaf clovers, there are 4 circuits of varying difficulty on the basis of a "stop or keep going" format.
The race is available in 2 versions: MTB & MTB-AE. Each race is available in individual format or in a relay team of 2.
The base camp for departures / arrivals will be established at Plagne Bellecôte, participants will set off on the 1st loop and will be able to prolong the pleasure according to their state of form by engaging on the following loops, all equipped with new points of interests with varied landscapes between forests and high mountains.
So you have the choice between 23km, 46km, 71km or 82km!
The following order of loop is mandatory:
Circuit 1 – Plagne-Montalbert sector – 23 km – 989m elev. gain
Circuit 2 – Montchavin-Les Coches sector – 23 km – 861m elev. gain
Circuit 3 – Champagny-en-Vanoise sector – 25 km – 1139m elev. gain
Circuit 4 – Tour of the Saint Jacques – 11 km – 699m elev. gain
Participants who complete all 4 circuits for a total of 82km and 3688 elevation gain will be considered as finishers!
The classification categories for the Double8:
Ranked by the number of circuits completed: 1 circuit or total time for 2 circuits or total of 3 circuits or total of the 4 circuits (finisher, podium and prize money for the winners) with a women's / men's ranking for each of the categories.
MTB relay in teams of 2 :
3 ranking categories women's / men's / mixed ranking for each.
Handover after each circuit.
eMTB Individual :
Ranked by the number of circuits completed: 1 circuit or total time for 2 circuits or total of 3 circuits or total of the 4 circuits.
2 categories for rankings: 500Wh battery & 600Wh battery with a women's / men's ranking for each.
Participants must have 2 batteries of 500Wh minimum to be charged in rotation between each circuit.
eMTB relay in teams of 2 :
3 ranking categories based on total battery power (1000Wh / 1100 – 1200 Wh / over 1200Wh) with a women's / men's / mixed ranking for each.
Handover after each circuit.
The team must have 2 batteries of 500Wh minimum to be charged in rotation between each circuit.
The base camp :
The base camp in Plagne Bellecôte is the place where everything happens: the start and finish lines for the 4 circuits, a refreshment point to recharge your (physical) batteries, a battery charging stand (supervised), a washing station and repair stand are available there.
E-mountain bike competitors (individual and relay teams) must leave their spare battery at the recharging stand with its charger, where it will be left to charge during the race and exchanged for the empty battery after one circuit, and so on for the 4 circuits. Charging will be the competitor's responsibility and the time required for the changes must be taken into account for respecting the time barriers (see course and rules).


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4 Easy Ways to Reduce the Amount of Sugar You Consume
What steps can you take to help reduce the amount of sugar you consume? Discover simple steps — and see why cutting sugar can help you feel healthier and lose weight.
5 Unexpected Foods That Are Full of Sugar
Even foods that seem health (ahem: yogurt) can be surprisingly packed with sugar. Find out the biggest suspects — and how to avoid buying high-sugar foods.
5 Nutritional Myths About the Thyroid
With thyroid diseases on the rise, there are many misconceptions swirling around about what, if any, foods affect the disease. Find out the most common misconceptions.
Coach Rachel Talks About How to Break Free from Your Sugar Addiction
Get the facts on sugar addiction from Coach Rachel – and see how a Guided Reboot can help you banish cravings.
10 Anti-Aging Foods to Eat Daily
Having the nutrients in these foods can help slow down your body's aging process and boost your wellness.
Sugar and Your Brain: Why Sugar Is So Very Addictive
Studies show that sugar lights up the same exact area of our brain that is stimulated by drugs.


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Since 2019 Vedia has been one of the participants in the CEF-funded FEDeRATED project. Here Vedia and several other public and private actors are developing future data-sharing models and semantics for multimodal logistics. This work has been a great opportunity to establish preparations for future eFTI legislation. Such legislation will integrate public actors into paperless supply chains. Vedia has been an active pioneer in this new eFTI regulation and is now joining forces with collaboration partners from the EU and particularly Baltic countries. (See more)
In case you have not heard about eFTI, here you have a short summary:
eFTI is a new EU-level act, which will require public actors to approve cargo documents in digital format. eFTI covers all modes of transportation and comes into force in 2024-2025. In short, eFTI is built upon these 5 components:
- eFTI Platform, to be used by private actors
- Systems to be used by public actors to access and process the data made available by private actors on the eFTI Platforms, which may also contain:
- Access Points (AP) for the specific cases
- National Access Point (NAP)/eFTI gate
- Authentication mechanism(s) for private and respectively public actors
- Authorization mechanism(s) for private and respectively public actors
- eFTI Search Mechanism.
When the FEDeRATED project first started, Vedia made the decision that it will study a variety of options for agile and sophisticated data-sharing models in the transport and logistics sector. As a result of these studies, Vedia started to participate in IATA One Record development in collaboration with IATA and Finnair Cargo. One Record is a new initiative for the internet of logistics which has already achieved the necessary maturity to enable actors to build businesses within it. In short, One Record is a data-sharing model, which builds upon the following leading principles:
- The One Record concept is based on 3 pillars enabling to define: WHAT, HOW and with WHOM data can be shared
- One Record is a data-centric model that provides transparency and visibility for all actors in the logistics chain
- The One Record model specifies the used data model, used APIs, and used security model
For Vedia, One Record offers a huge opportunity to jump into the internet of logistics. Now that Vedia is operating its own One Record server and has adapted the One Record data model to its own semantics and architecture, Vedia can offer you access to this modern world of paperless supply chains for third parties. Currently, Vedia is making preparations for future eFTI implementations, where Vedia's interest lays in utilizing One Record as a foundation for eFTI platforms. This work is already ongoing and we are always open to discussing more potential collaboration.
Lasse Nykänen
Project leader


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Seriously, I've been on the true crime podcast bandwagon for too long. I needed something healthier and happier to listen to, that also appealed to my interests. Chris has great guests, and is always talking about one of my biggest passions: travel! I love learning more and more from this podcast.
May 13, 2022 by AlexMakesHomes on Apple Podcasts


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Our Mentor :
Amma – Smt Shashikala Kaikini The happiness of others, this is Amma's happiness. The security of others, this is Amma's security. The rest of others, this is Amma's rest. This is Amma's vision. And it is this vision that Amma's life has always been dedicated to music and mankind.
There is one Truth that shines through all of creation. Rivers and mountains, plants and animals, the sun, the moon and the stars, you and – all are expressions of this one Reality. Smt Shashikala Kaikini is one such reality, unanimously and living called as Amma. Amma, has been a friend philosopher and trusted guide to all of us and has been a driving force for all of us. We thank you for your endless support, love and blessings that you have bestowed upon us.


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Gisele Bündchen is happy to namastay right at her healer's office.
The former Victoria's Secret Angel was spotted visiting her Ayurvedic physician, Dr. Ewa Wieruszewska Lierle, on Friday for the second time as she continues to grapple with her seemingly broken marriage to Tom Brady.
The Brazilian model hinted that she and the rapper are…
The visit seemed to be a more casual one, as Bündchen was spotted carrying an Amazon Prime box out of the office while the doctor held a Tupperware container of what appeared to be split pea soup.
The Brazilian model and Wieruszewska Lierle wore similar beaded necklaces during their visit, which concluded with Bündchen getting into her car while participating in a serious phone conversation.
Once again, the supermodel left her wedding ring at home.
Bündchen stopped by the spiritual healer's office a couple of weeks ago when Wieruszewska Lierle cleansed her car with a smudge stick.
It's unclear how much there is left to cleanse, but according to the physician's website, she believes "in the power of healing through natural and healthy alternatives or complements to western medicine."
It doesn't seem like the Tampa Bay Buccaneers quarterback, 45, and Bündchen have made much progress in reconciling, as the pair have both hired divorce attorneys.
What began as an "epic fight" over Brady's decision to un-retire from the NFL seemingly has spiraled into a full divorce, with Bündchen seen exiting a building filled with attorneys' offices at the end of last week.
"I don't think there will be any coming back now," a source told Page Six. "They both have lawyers and are looking at what a split will entail, who gets what and what the finances will be," including their unfinished mega-mansion located in the upscale Indian Creek Country Club community.
The troubled pair have been married since 2009 and share Benjamin, 12, and Vivian, 9, plus Jack, 15, who is Brady's son with ex Bridget Moynahan.
Read More: World News | Entertainment News | Celeb News


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1Deepali Singh,1Priyadarshini Singh,1Nidhi Roy,1Saumitra Mukherjee
Icarus (in Press) Link to Article [https://doi.org/10.1016/j.icarus.2021.114757]
1School of Environmental Sciences, Jawaharlal Nehru University, New Delhi 110067, India
Copyright Elsevier
The present study investigated an inter-crater depression, which is hypothesized to have been hydrologically active in the past. Mineralogical analysis of the putative lake was carried out to examine the presence of secondary minerals and decipher its aqueous alteration history. The basin was observed to be predominant in mono- and polyhydrated sulfates and hydrated silica with intermittent exposures of Al phyllosilicates such as montmorillonite and beidellite. Later, mineral profiling of the surrounding terrain was also carried out to infer the origin of these minerals. We recorded signatures of Mg-rich smectite (saponite) and Fe/Ca‑carbonate in crater rims and ejecta here, in addition to the minerals previously identified within the basin. Spectro-morphological examination of the entire region helped in understanding the emplacement of the minerals and construction of the life cycle of the lake. The contrasting environmental conditions required for the formation of these minerals suggest that the basin witnessed multiple hydrological cycles and that it was active for a long period of time. We propose the basin to be an endorheic playa with geologically complex terrain which may hold good biosignature preservation potential for future exploration missions. Finally, our preliminary exploration of the area highlights the importance of inter-crater depressions on Mars and their significance in water budgeting, even if a small percentage of them were hydrologically active.
Investigation of mineral assemblages in a newly identified endorheic playa near Huygens basin on Mars and their astrobiological implications
1Deepali Singh,1Priyadarshini Singh,1Nidhi Roy,1Saumitra Mukherjee


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Congratulations to Week 3 winner, Ryan Hollingshead, with a run away 63% of the vote for his performance against Philly. Kudos to Tesho Akindele and Victor Ulloa for 2nd and 3rd place respectively.
A big home game against Seattle Sounders was probably the most anticipated match of the first month, but it turned out to be sort of a mixed bag. Both teams were missing key players. A young mistake by Kellyn Acosta meant FCD played the majority of the game a man down. Regardless, FC Dallas managed a clean sheet, no easy feet against a talented Seattle squad with an advantage.
It's a long season - even at home, a draw is not always the worst result.
After the red card, who stepped up and made sure that FCD's defense would stay strong? Who covered lots of ground, played out of position, and sweated to keep that point within grasp? Who was the unsung hero of the match for FC Dallas? Who was your Workhorse of the Week?
Cast your vote below. Share your thoughts in the comments section.
This Week's Strong Candidates
Victor Ulloa
I'll just let Drew Epperley do the talking from his "What We Learned" article:
Victor Ulloa also may have had his best game this season out there. The fight, the hustle, the energy he brought for the 90 minutes on Saturday was something else for a young player like him. I continue to be blown away by his ability on and off the ball. His game isn't anything that typically shows up in the stat sheet but to me that is the definition of a guy in his midfield position. Do the dirty work, keep the pressure off the back four and find ways to move the ball forward. He did all three against Seattle.
A vote for Ulloa is a damn fine vote.
As I watched the drama unfold, I figured that Michel would be brought off fairly early into the second half. He's not the fastest player on the field, and I guessed that FCD would have to try to find an equalizer or just go ahead and push for the win. Bringing Barrios on for Michel seemed like a sensible move. Instead, Michel went the full 90 and was arguably our most dangerous asset. It is weird that a free kick that hits the crossbar is not counted as a shot on target, but whatever. Michel was a rock for this team and slid all over the place to fill space during key moments when our defense was being stretched.
Ryan Hollingshead
Get used to this name here. The kid did not have the flashiest game, but he worked hard. While he did not go the full 90, one of Pareja's tweaks was to slot him into the left back position. Hollingshead was forced to deal with former teammate, Andy Rose, throughout the match and did well. His versatility and athleticism is a huge boon to the team in situations like this. I do wish he could have generated a little more of an offensive spark, but with a man down, no one expects the second year player to be a miracle worker.


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Jacobs wins $75.8 million contract for delivery of USAF Patriot Excalibur software and systemsNews
March 28, 2019
DALLAS. Technical professional-services firm Jacobs has won the Patriot Excalibur (PEX) contract from the U.S. Air Force Life Cycle Management Center. The $75.8 million, five-year contract calls for Jacobs to deliver a unit-level software toolset that enables Air Force, Joint Service, and foreign military unit personnel to conduct accurate and real-time operational tasks and track readiness status, connecting functional areas within a unit.
PEX supports both flying and nonflying ground intelligence, surveillance, and reconnaissance, along with special mission units and Air Force major commands integrated across multidomain operations.
Work under the terms of the contract will be performed at more than 30 Air Force locations. Jacobs will continue to maintain the PEX software, deliver systems-engineering services, and support training and field implementations for the length of the contract.


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Dairy-free eaters will rejoice at the sight of this Vegan Cocoa Espresso Mousse. This decadent dessert may be free of any animal-based products but it still carries a great flavor all can enjoy.
Vegan Cocoa Espresso Mousse is a popular dessert found at Jill's Restaurant in the St. Julien Hotel and Spa. The Colorado-based eatery serves a line of delicious dishes, but what vegans find most enjoyable is this smooth and creamy mousse.
Developed by chef Laurent Mechin, this dessert is as easy to make at home as it is to buy. In place of the usual dairy products, this vegan mousse uses coconut milk. Another unusual ingredient in this dairy-free dessert is ripe avocado, which adds to the creamy texture.
Laurent Mechin's Vegan Cocoa Espresso Mousse is a Dairy-Free Hit
Malika Renee Butss — July 6, 2015 — Lifestyle
References: foodrepublic


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This season I'm looking forward to my church's theme for Advent season: Calm and Bright. It is a celebration of the 200th anniversary of the hymn "Silent Night." In the busy-ness of this season, "calm and bright" is already a place I want to dwell in. Since I've started this blog, I've become a middle school teacher. So in addition to the extra family events, shopping, and my younger daughter's birthday this month, I'm also busy preparing students for their finals. I'm more 'stressed and cloudy' than 'calm and bright.' But I know with God's help I can shift that.
When I think of the song Silent Night, I'm reminded of when my youngest was born. It was after the Christmas season and she was NOT a good sleeper. My nights were filled with the sound of her crying out in the dark. I would fumble around, sleep-deprived and do whatever I could think of to get her back to sleep. My go-to lullaby became Silent Night. My prayer was for a few hours of a silent night. All I needed was one peaceful, restful night and then I would be better able to face the next day. During those hours of jarring cries waking me in the dark, I relied on God to give me patience and peace in spite of my sleep deprivation. I began to remind myself that these extra moments in the night were precious. That soon I would no longer have a small, cuddly baby, but a squirmy, running toddler. I am thankful to have my quiet, peaceful nights back, but I am also thankful for those sweet memories ingrained in my sleep-deprived brain of cuddling her in the dark, calm of 2, 3 or 4am.
In the midst of our stress, may we find calm and bright this season. God sent the Christ child into a world of darkness and chaos to bring us peace and light. May we find gratitude in our struggles and may God open our eyes to the perspective they can bring to us.


text: If you were not excited before, we promise you will be by the time you are done reading this page, you will be. The first rule to success is to provide the widest range of tinting services possible. This means that our clients can rest assured we can handle anything they can throw at us. Add to this that we have managed to instill a level of consistency across the board, and you will quickly begin to understand why we are the best. We refuse to sacrifice an ounce of quality, no matter what. If you would like to get a better idea of what our most popular services are. Please take a look below. You may just be blown away by what we have to offer.


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The Kentucky Supreme Court
granted a hearing
to a death row inmate that will determine whether he should get additional DNA testing on evidence from the 1979 murder he is convicted of.
An Ohio judge
could grant a new trial
to a death row inmate after reviewing a police report that focuses on an alternate suspect in a 1997 murder.
A rally in New York
called for the creation
of a statewide Innocence Commission to evaluate cases of possible wrongful conviction and consider reforms to prevent future injustice.
Police in St. Petersburg, Florida
will reevaluate a policy
on exchanging information for reduced sentenced for confidential informants. The U.S. Supreme Court ruled Thursday that
police must take steps
to ensure that children are aware of their rights during an interrogation.
Massachusetts' Attorney General wrote
a letter to the Boston Herald editor
in response to criticism about Dennis Maher' exoneration.
Blood tests in a Michigan drunk driving case
were ruled inadmissible
because the margin of error was not disclosed by the crime lab's chief toxicologist.


text:
eCite Digital Repository
Two-stage catalysis in the Pd-catalyzed formation of 2,2,2-trifluoroethyl-substituted acrylamides: oxidative alkylation of PdII by an IIII reagent and roles for acetate, triflate, and triflic acid
Canty, AJ and Ariafard, A, Two-stage catalysis in the Pd-catalyzed formation of 2,2,2-trifluoroethyl-substituted acrylamides: oxidative alkylation of PdII by an IIII reagent and roles for acetate, triflate, and triflic acid, Organometallics, 41, (3) pp. 293-300. ISSN 0276-7333 (2022) [Refereed Article]
Copyright Statement
Copyright © 2022 American Chemical Society
DOI: doi:10.1021/acs.organomet.1c00644
In the synthesis of 2,2,2-trifluoroethyl-substituted acrylamides, two-stage palladium-catalysis is indicated experimentally, including oxidative alkylation of PdII to PdIV by [IIIIMes(CH2CF3)]+ (Besset et al., Chem. Commun., 2021, 57, 6241). For N-(quinolin-8-yl)-2-(phenyl)acrylamide [LH2 = H2C═C(Ph)C(O)NH∼N], studied by density functional theory herein, the first stage involves palladium acetate-promoted NH-deprotonation and concerted metalation-deprotonation CH-activation for Pd(OAc)2(LH2), followed by the transfer of [CH2CF3]+ from IIII to give a PdIV intermediate that undergoes reductive elimination to form the acrylamide-CH2CF3 linkage. The second stage employs [Pd(LH)(NCMe)]+ as the catalyst, with steps including outer-sphere CH-activation by triflate and crucial roles for PdIV, acetonitrile solvent, and N-protonation of the product by triflic acid to form [LH2(CH2CF3)]+. In an apparently unique process, the first stage is faster than the second and produces the catalyst, but the second stage is catalytic to provide high yields of the product.
Item Details
|Item Type:
|Refereed Article
|catalysis, DFT, computation, palladium catalysis, acrylamide synthesis
|Research Division:
|Chemical Sciences
|Research Group:
|Inorganic chemistry
|Research Field:
|Transition metal chemistry
|Objective Division:
|Expanding Knowledge
|Objective Group:
|Expanding knowledge
|Objective Field:
|Expanding knowledge in the chemical sciences
|UTAS Author:
|Canty, AJ (Professor Allan Canty)
|UTAS Author:
|Ariafard, A (Associate Professor Alireza Ariafard)
|ID Code:
|Year Published:
|Web of Science® Times Cited:
|Deposited By:
|Deposited On:
|Last Modified:
Repository Staff Only: item control page


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We all know, that today is the first day of spring! Also the first of March is "The day of being grateful". That is why we want to congratulate everyone! Accirding to this wonderful holiday of our country all members of "Salauat" Debate club of Semey Medical University organized celebration named "Be healthy with Salauat DC". The main aim of this celebration was to give students of SMU useful information about heathy lifestyle and about advantages of vitamins, fruits, especially nowadays, when avitaminosis and hypovitaminosis already started, also one of the main aims was to give everyone wonderful mood! That is why members of "Salauat" DC gave students of SMU as a present fruits, which contain a lot of vitamins, also they checked knowledge of our students, how well they know about advantages of vitamins. Also, we want to tell, that not only students of SMU took part in this celebration, but also stuff of SMU were very happy to celebrate this day with us. Everybody were very thankful for having such an amazing and unforgettable gay!
Category: Students
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It is now beyond any doubt that some officials and supporters of Be Forward Wanderers have lost their confidence in this team as it is not doing well in TNM Super League of this season.
The general secretary Mike Butao of this team is one of officials that has been driven into a ditch of confusion and doubts. Following Butao's desperate for knowing the cause of their bad lucky, he has pointed out that a problem lies behind their poor management in technical Panel.
According to Butao, said that after every match, technical panel is good at reshuffling players and playing system for next game but to no avail. This shows that the technical panel does not know what to do but rather than keeps on searching what befit.
However, it seems that Butao contradict himself as he is also rather a director of such technical panel.
Wanderers has played 7 games and managed to gain only 8 points in Super league. Its last matches where a team had a trip to northern region have come back with only 2 points out of their potential 6.


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"The best dentist ever!! She is a wonderful woman and a true professional. Funny and kind and explains procedures and needs for treatment. Also has added service plan which provides a very generous discount on services. Always gives her patients all possible attention. Wouldn't think of going to anyone else. Carol for president!!!!
OH!!!! And my new hygienist Amy is fabulous. Can't wait til my next appointment!!!"
"Starting with making my appointment the office contact was professional and warm. COVID precautions and the protective procedures were spelled out.
My preventive exam was thorough as was my cleaning. I noticed the polishing portion changed slightly to prevent aerosol disbursements. My hygienist checked my gum health and took xrays. All during that part of this appointment my treatment was most competent and caring.
Dr Hipps came in and discussed my dental health. She always does aN oral cancer exam.
I recommend this dental practice. Unlike the corporate business practices where your dentist and hygienist and staff frequently change you are a person or family cared for in a personal manner."
"The appointment started on time and the service was outstanding.
I was a bit apprehensive when the Doctor brought out the 3 ft needle for numbing."
"Dr Hipps, dental hygienist, and other staff are attentive and welcoming."
"Pleasant and professional staff."
"Great service as always!"
"Friendly, efficient, skilled people"


text: Happiness seems elusive sometimes, doesn't it? I've had a challenging week. (Read more about that here). I don't feel happy. I'm a recovering chronic worrier and have anxiety as well. Sometimes these two things work against me and sabotage true happiness. Our circumstances sometimes really have the ability to weigh us down, don't they? This … Continue reading 3 Ways to Maximize Happiness


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Product Highlights:
Black Leaf's Hybrid Glass Barrel Dab Rig is the perfect method for smoking herbs, essential oils and even concentrates. It's perfect for the smoker who has or wants it all, and it's one of the smoothest methods for smoking herbs around.
Borosilicate glass is the penultimate material when it comes to the construction of high-quality pipes. The process starts by adding boric oxide to standard glassmaker's frit. That one singular addition creates a much stronger glass than standard glass, and it's more durable too. Additionally, it's chemical-resistant and heat-resistant. These features combine to make it the perfect material for crafting glass pipes of the highest quality. Smokers who aren't into chemicals will be glad to know that borosilicate is so safe, it's even used in medical implants, which is a testament to it lending itself to the purity that barrel rigs are known for.
This barrel dab rig from Black Leaf features a curved mouthpiece, which creates a more ergonomic smoke experience. Meanwhile, the showerhead style diffuser creates tiny little bubbles that produce a high level of smoothness while maintaining the flavor of whatever it is you're smoking. The barrel is another secret to this rig's ultra-flavorful mouth feel; smoke builds up and concentrates inside, enhancing the flavor and feel of the hit, without all the harshness. When you want a smooth smoking experience, you can't beat this rig.
The Black Leaf barrel rig comes with the glass nail included, so you have all the ingredients you need for a level yet potently powerful smoking session.
© Copyright 2023 Sky High Smoke Shop


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GT872 Owl Bookmark Sterling Silver Ari D Norman
Ari D. Norman is world famous for our quality Silversmith creations and this meticulously made hallmarked sterling silver bookmark is enhanced with a unique owl figure. This delightful bookmark would make a wonderful gift for men women or children to keep track of their bedtime or travel reading.
• Sterling silver owl bookmark
• Hallmarked sterling silver / 925 sterling silver
• Dimensions: 86mm (3 3/8 inches)
© 1974-2022