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I want to ask you a question: how is your working relationship with your IT provider, whether you've contracted another business, or you have your own internal department? If you suspect it isn't great, there may be good reason for that.
I want to ask you a question: how is your working relationship with your IT provider, whether you've contracted another business, or you have your own internal department? If you suspect it isn't great, there may be good reason for that.
When a group of people work together in an office, there is a sort of etiquette that forms to help everyone do the most effective work as they can. Of course, with many employees working remotely for some time now, a lot of these behaviors may have slipped. Here, we're reviewing some of the technology manners that your team should keep in mind so that the whole of your business can work productively.
Did you know that over 80 percent, eight-zero, of cyberattacks are the result of stolen access credentials? It's no wonder that the username/password combination that we're all used to is being actively phased out by many tech companies—including Microsoft—in favor of more secure, passwordless authentication measures.
In a word, yes.
While that answer may seem insufficient for such a broad question, you truly should, and there are many reasons why. Let's get right into how trusting your staff can bring your business and its operations some significant benefits.
Today's businesses are looking to build the most efficient processes they can. In order for that to happen, the people that your business depends on will need to know what is expected of them. The only way they will be able to produce the desired results is if they are properly trained. This week, we'll be going over a few training approaches for you to consider adopting as you look to thoroughly educate your employees.
As prevalent as cybersecurity threats unfortunately are today, many users tend to overlook major threats that they just aren't focused on nearly as much: social engineering attacks. Social engineering attacks are just another means for a cybercriminal to reach their desired ends, and so need to be protected against.
When so much to do with business nowadays relies on collaboration, it only makes sense that the solutions that enable this kind of cooperation would be seen as assets. Take video conferencing solutions - while many of their benefits may seem obvious, they have additional impacts that may not be initially apparent. Let's review some of these benefits.
Habits are hard to break - but there are some habits that simply have to be broken if your business is going to be secure. Many of these habits may have been developed by your employees, which means that it is important that you recognize them.
Machine learning and artificial intelligence have enabled us to accomplish great things with the computers we have access to today. However, it is equally true that these same innovations have also produced a great number of threats. One threat that is particularly dangerous in today's day and age is the presence, and growing prevalence, of "deepfakes" in the media.


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It weighs less than a few ounces and has a cloth sweatband instead of a leather one. The reason for the cloth sweatband is twofold. One so that it can be folded and put in a coat pocket without destroying the stiffer leather sweatband, and two in order to make it even lighter. Currently I only know of two others in existence. Below are some more interior photos of this fine, rare hat from the 30s. And, yes, it IS slanted as you can see. Only a few seem to be still around.
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· There is a rule of thumb regarding dating soft felt hats (what we now call fedoras) at just a glance, which postulates that hats with taller crown plus narrower brims are from the s to mids or so, whereas hat crowns slightly lowered but brims grew wider from roughly the lates through the s into the
Partly cloudy with warmth from the sun made for a great day to be out on the UDR. It was a mixed bag for our boat today with a nice 18 inch 'bow, three browns up to 15 inches and a few smallmouth bass. This fish was one of three wild trout that Robert caught this afternoon! Welcome back to the Big D – Rich Toohey! Here's Rich with a chunky 15 inch river smallmouth bass caught late in the trip north of Hollister's. Bluebird skies, gin clear water, sunny and dry – and nobody else out on the river.
Plenty of bass with a double limit and a huge bass on a Senko midway through our river adventure was icing on the cake! Bill Conley nailed this hawg a wee bit south of Masthope Rapids on this afternoon's float trip. Bill's buddy, Joe Paucillo, is on the left. Here's another shot of that great looking smallmouth bass with Bill and yours truly. Let's revive and put that big guy back so that we'll have a better bass fishery in the future!
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Cavanagh Hat Dating Services, — Hats. Again, not all hats from this time period may have had these labels. If I feel healthy — bright eyed and glowing skin, good hair day — then I feel my
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But I find that the moment in the book that may have given me the most pleasure is a minor, almost parenthetical one—even though it involves the best known of all PT-boat men. He is doing so on the opposite page. The young President politely greeting his predecessor is in fact surreptitiously helping out a Navy buddy. Al stood back to observe the effect. The next day he greeted former President Eisenhower at Camp David and thereafter sent Al a picture of the great occasion: It showed Kennedy leaning forward, his right hand extended; in his left hand he held a hat, the lining facing out toward the camera.
The Cavanagh Hats label was plainly visible! He told the curator what he wanted and why. The man was delighted.
Antique Cavanaugh Fedora Hat in Original Box
Hat-Dating Guides Hatting Notes There is a rule of thumb regarding dating soft felt hats what we now call fedoras at just a glance, which postulates that hats with taller crown plus narrower brims are from the s to mid s or so, whereas hat crowns slightly lowered but brims grew wider from roughly the late s through the s into the early s. From the mid s onward to the present day, crowns typically tend to be lower and brims are very narrow. While there is some validity to this rule of thumb due to the changing nature of fashion over the decades, hats of all these styles can be found in all periods, so internal clues to dating hats are needed to make more accurate estimations of age.
Cavanagh Hats in particular are notorious for hiding their age regarding their style. Cavanagh had a clientele that was typically older and more conservative, fashion-wise, than the other brands. As such, they often stuck to a style for decades, and thus one could find a Cavanagh hat from that looks nearly the same, externally, as one from
· The Dobbs name positioned on a upward slant and debossed into the leather of sweatbands is a common denominator throughout the entire history of Dobbs hats, and isn't as useful to help in dating, but will be briefly covered here for reference
Her feast was recorded in the Acta Sanctorum May With the death of her husband, she finally removed to Scotland to reside near her children She finally moved into a nursing home, Annfield House, Stirling , after a fall. She held the distinction of being the oldest person in Scotland June, — Dec, and the oldest person in the United Kingdom April, — Dec, Her many plays included the historical drama Stanislaw i Bogomil Stanislaw and Bogomil , and she also produced a series of critical essays concerning the Polish born author Joseph Conrad, Szkice o Conradzie Sketches of Conrad Maria Dabrowska died May 19, aged seventy-five, in Warsaw.
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· WHEN Kelly Cavanagh couldn't find hats and fascinators she liked in Gladstone, she decided to start making her own. "I attend a lot of race days and
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Cavanagh Hats, New York. This hat is labeled "Cavanagh Edge" (see history details below about this, dating this hat to as early as the mid 's). A little interesting history about Cavanagh Hats
Stetson Sovereign Quality from the year Nutria Felt A nutria is a horrid, rat-like animal that is not native to the United States. It is a nasty, invasive species, for sure. But its fur does make a very, very strong fur felt for hats. Cowboys in the late s and early s loved the nutria hats Stetson made because they wore like iron. They held their shape like concrete, the weather never seeming to have any detrimental effect on them.
I would guess that this is why so many early Stetson cowboys hats that exist today are nutria fur felts! This Stetson nutria is from a hat made between and or so. A nutria logo from the early s. Another 30s era nutria logo. So, What is my Old Fedora Worth? Now, many of you may be wondering what your hat is worth. This is a very, very difficult question to answer because there are so many factors involved in assaying a hat that it is hard to address them all.
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Learn how to make a cupcake liner butterfly using a clothespin, glitter, and glue! It's a great idea for magnets.
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England's twelfth man back for Ashes tussle with Australia
By Peter Hayter
England's hopes of winning the Ashes Down Under for the first time in nearly a quarter of a century have been boosted by Cricket Australia's decision to allow Barmy Army musician Bill Cooper to blow his own trumpet at the five Tests.
Four years ago, England's 5-0 defeat began with Steve Harmison's infamous opening ball of the series in Brisbane which ended up nearer to Perth.
But the Barmy Army became convinced the cause was all but lost when Cooper was ejected from the ground later that afternoon for disturbing the peace.
Back in business: Bill Cooper, the Barmy Army Trumpeter, poses at the Pig and Whistle pub after being ejected from the Gabba in 2006
Now Cooper, a 31-year-old musician from Kent, has been given permission to carry on playing the rousing tunes - Jerusalem and The Great Escape among them - that former Ashes skipper Michael Vaughan said is 'like having an extra man'.
Cooper, recalling the moment he was silenced after playing the theme tune from Neighbours, said: 'I thought it had gone down pretty well with the locals but the next thing I knew I was being bundled out of the ground by six policemen and told I was disturbing the peace.
'They handed me a banning order preventing me from going within 500 metres of the ground for the remainder of the match.'
Now Cooper, who recently took part in the English National Ballet's performance of Swan Lake at the Royal Albert Hall, will be free to carry on giving England his musical support.
Barmy Army founder Paul Burnham said: 'We've been in discussion with the Australian authorities to ensure that, unlike last time, the Barmy Army can sit together so that the only people being disturbed by Paul's trumpet-playing will be those who want to hear it.'
Last night a Cricket Australia official confirmed: 'Special arrangements are in hand to allow the trumpeter to play as part of the "live entertainment" on the grounds he'll be contributing to the Ashes atmosphere.'
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So you have begun your private company yet what does it take to be fruitful in the present business world? To start you should have an item that is needed or required, and it must be evaluated fittingly, it is only a start. So as to have an effective business, you should rehearse these things if your business systems coming up short on it's an ideal opportunity to fix it.
Think beyond practical boundaries! There are no restrictions to how great you can become or how high you can ascend aside from the cutoff points you put on yourself. — Brian Tracy.
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African swine fever can last a long time
wild boar African swine fever was detected for the first time in Germany. (Photo: dpa) Greifswald After the first outbreak of African swine fever in … Read more
wild boar African swine fever was detected for the first time in Germany. (Photo: dpa) Greifswald After the first outbreak of African swine fever in … Read more
According to US researchers, wearing masks in public could help immunize the population. They presented this hypothesis to the public in the New England Journal … Read more
With the power of nature against corona. There are no specific herbal remedies yet, but researchers around the world are trying to determine the benefits … Read more
Coronaviruses like SARS-CoV-2 not only infect the nasopharynx and the airways. In addition to the intestines, kidneys and liver, even the reproductive organs are affected, … Read more
The number of active cases is falling again! The health authorities in Germany reported 1256 new corona infections within one day. An estimated 1,500 people … Read more
August 22, 2020 – 11:00 pm 2020-08-22 By: Carlos E. Climent The advances in the knowledge of modern medicine, parallel with the proliferation of subspecialties, … Read more
China has suffered in recent months a succession of catastrophes comparable to the 10 plagues with which the Hebrew god punished Egypt. The beginning of … Read more
Dhe corona pandemic, which has meanwhile more than 3.1 million officially identified infected people, has not only almost displaced other epidemics from the focus of … Read more
Like all viruses, corona viruses are constantly mutating. There are said to be several thousand mutations of SARS-CoV-2 worldwide. Now researchers have found that a … Read more
A plague of desert locusts from Paraguay, it settled in the Argentine northeast and threatens to advance to Brazil, reported the delegation of the United … Read more


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At the corners of Maple and Lyman Streets in Holyoke now stands the former site of Mater Dolorosa church.
Demolition on the more than 115 year old parish, built by Polish immigrants, began last week..
Parishioners appealed to the Vatican after the Springfield Diocese closed the church in 2011, but the decision was upheld due to debt and an unsafe steeple.
On Monday family members of those same immigrants who built this church watched as demolition began on its steeple.
"It was a staple of Holyoke," said Brian McKinnon, a former student of Mater Dolorosa. "Lot of memories here. There's many generations, my grandmother went here."
One woman who grew up in the church said she was hopeful they'd keep it as a landmark for Polish history, but an application to turn the building into a historical district was denied.
"Right before Christmas it really hurts you, it hits you really hard," said Lidia Lech, who was baptized and confirmed at the church. "Going to other churches it's not the same thing."
Springfield Diocese Spokesman Mark Dupont told 22news taking down the steeple is a delicate process.
"The procedure we're following is actually the safest methodology to remove the steeple," said Dupont. "So we needed to create a larger parcel.. an envelope a work envelope to do the demolition."
Dupont said they hope to have most of the demolition done by the holidays.


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GOP & Democrats spar over UN Disability Treaty in US Senate
Can Tran
Nov 27, 2012 in
Senate Republicans, led by Utah Senator Mike Lee, are voicing opposition to the ratification of the UN disability treaty called the Convention on the Rights of Persons with Disabilities.
As the 112th United States Congress will come to an end soon, there are still plenty of things for the Republican and Democratic parties to spar on. Currently, the 112th US Congress is in a lame-duck session. This Congress will conclude on January 3, 2013. On that same day, the 113th US Congress is scheduled to convene. However, there's still a little over a month before the 112th US Congress ends. In regards to the United States Senate, which Democrats managed to keep control of after the 2012 US Elections, there is a spar going on between both parties in regards the
UN Disability Treaty
known as the Convention on the Rights of Persons with Disabilities.
Back in 2006, this was signed under the administration of then-US President George W. Bush. It was modeled after the 1990 law known as the Americans with Disabilities Act. Current US President Barack Obama signed the convention back in 2009. The Convention on the Rights of Persons with Disabilities is said to be signed by a little over 150 nations. 126 of those nations have ratified the UN Disability Treaty.
Harry Reid of Nevada, the Democratic Senate Majority Leader,
asked the Senate
to consider ratifying this treaty. So far, it seems highly unlikely that this treaty will get ratified. Republican Senators have voiced their opposition to the treaty.
Leading the opposition
is GOP Senator Mike Lee of Utah. Lee said that he had concerns about this treaty. He said that that ratifying the UN Disability Treaty would subject the United States laws to a United Nations bureaucracy. Lee was backed by GOP Senator Jim DeMint of South Carolina. According to DeMint, conservatives complain would allow the federal government to force parents that have special needs children to be placed in public schools.
GOP Senator Orrin Hatch of Utah, through a spokesman, supports the objective of the treaty; but, he objects to the method the treaty uses to achieve the objective. In this respect, he respects the treaty but opposes it on the grounds that it could endanger the sovereignty of the United States.
Also, Rick Santorum
went and weighed in on the treaty as well
and voiced his opposition. Santorum is a former GOP Senator. For the 2012 US Presidential Election race, Santorum competed in the GOP primary. The nomination eventually went to former Massachusetts governor Mitt Romney. Romney was defeated by Democratic incumbent Barack Obama.
Santorum gave his reasons for opposing the UN Disability Treaty. He said that the treaty would take authority away from the parents when deciding what's best for the children. Santorum said that unless the parents are unfit to make decisions, they ultimately have the decision making authority. He said that this has been clear throughout history of the United States. Santorum compared the treaty to opening Pandora's Box.
Democratic Senator John Kerry of Massachusetts led support for the UN Disability Treaty. Currently, Kerry is the head of the Senate Foreign Relations Committee. In 2004, Kerry was the Democratic nominee for the 2004 US Presidential race. He had lost to GOP incumbent George W. Bush. Kerry, in his defense of the treaty, said that the UN can only give recommendations for changes. Also, the UN cannot force nations to change laws.
Dana Milbank, in a Washington Post
opinion piece
, said that opposition to the treaty comes out of conspiracy theories. He points out if the treaty had bad intentions, it wouldn't have gotten strong support from veteran and disabilities groups. One name Milbank mentioned was GOP Senator John McCain of Arizona. McCain was the GOP nominee in the 2008 US Elections.
The opinion piece does mention the "fiscal cliff" which is the major economic talk in Congress. Milbank questioned if the Congress cannot move forward on a treaty that protects the disabled, how are they going to agree on how to deal with the fiscal cliff. This opinion piece was named "Santorum's new cause: opposing the disabled." From the name of the entry, this piece took specific pot shots at Santorum.
This is proof that, even after the elections and in a lame-duck session, Democrats and Republicans still have plenty to spar about.
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oh, christmas
Ausiello has some spoilers for next week's hour-long episode.
( Collapse )
( Collapse )
a couple months ago someone posted a link to the pics taken during the christmas 2005 party ep. does anyone have that handy? it's not the gallery at nbc.com. that's the gift exchange. there were a couple icons i wanted to make. but can't find it now. thanks!


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👉 Confirmation within 24 Hours
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A true, wonderful and incredible story.
It's about ZHU as well as you and me.
The right word for this story of youth is probably
It's a story about here.
The things that are changing so rapidly.
Faith. Emotions. They keep evolving.
All that shines is nothing more than a dream.
No one stays lucky forever.
People come and go. Yet inside, they will live on forever.
A few words from Da Zhu (ZHU Fengwei)
"If we will never make it there, should we get drunk and forget about it for a while…"
Many of the coincidences in life may turn into everlasting memories. Ordinary but irreplaceable. Dance pieces can be grand as well as delicate and sensitive. What I wish to achieve is to tell a story that recalls the broken love in you. You feel the sadness, but it's the sadness that doesn't hurt. On the contrary, it's rather nice. It's crude. It's choking. It's not splendid. Neither is it plain.
The creation of Once is closely related to Da Zhu's life experience, but it's not a real story. It is the epitome of the youth of everyone. It could be Da Zhu's story or yours or mine.
Once? What Once?
This time we turned the theatre into a black box.
For this dance piece, the performance area and audience seats are both set on the stage. Normally, there is a certain distance and height difference between the auditorium and the stage. In order to better appreciate the performance, we build the stage into a black box. With the stage as the centre and surrounded by three sides of the seats, the audience will be very close to the dancers and feel more engaged in the performance.
The auditorium will be divided into three zones, namely A zone, B zone and C zone. You may purchase the ticket by choosing one of the three zones according to your preference. There will be no seat number, you may sit on any of the available seats in your correspondent zone.
Even the torrent of time can not wash away the touching story from the youth that are filled with emotions and deeply engraved in the memory.
This story from the past brings with it a different sense of time. It's crude. It's choking. It's not splendid. Neither is it plain.
Choking. Sentimental. Nice.
You often see him as the leading dancer in YANG Liping's dance drama. This time, he is a director coming from the countryside.
As a dancer, Da Zhu has been working as the leading dancer of YANG Liping's dance dramas. He has been known as "the priest" in "The Rite of Spring" and "the prince" in "Pingtan Impression". He is a unique existence among the new generation of star dancers. He is wild and free in nature. The TV show Dance Storm in 2019 has made him known to more audience. The 360-degree camera shots of his dance pieces portrayed him as the most powerful dancer among all dancers. With his inspiring and characteristic performance, he won the place of top eight in the show.
The dance theatre Once is his maiden work as a choreographer.
"It's so hard to be a choreographer!" Da Zhu once said. "You only need to care about yourself when you're just a dancer, but now you have to pay attention to every dancer and think over every detail of the work."
Art comes from life. Da Zhu has always been considered as a wild and urban person. Yet, he grew up in the countryside. From there he moved to the county, and then to the big city.
Countryside. That is the place where he grew up and where most of his emotion lie.
"That's why I created a piece that has a strong sense of countryside."
Life is full of ups and downs, just like every coin has two sides. While dance can talk about big topics such as man and nature, it can also touch upon delicate feelings. What Da Zhu wish to achieve is to tell a story that recalls the broken love in you. You feel the sadness, but it's the sadness that doesn't hurt.
Dear audience,
If you don't know much about dance theatre, this piece of work may be a good starter. Here's the invitation. We are waiting for you in the Karaoke box of the 1980s.
The term "dance theatre" was first proposed by Pina Bausch, the master of contemporary dance. The purpose of establishing this concept is to express the theme of dance more freely through various forms. To speak or not to speak, to dance or not to dance, and to use props at will are all up to the choreographer. Pina once said, "I care about what people do, not how they move."
Besides the pure art of body movement, Da Zhu uses props and plot to present the most true feelings in a most realistic environment. In a word, Once is highly suitable for anyone who wishes to know more about dance theatre.
Creative Team
Director: ZHU Fengwei
Artistic Instructor: YANG Liping
Artistic Director: GAO Chengming
Production Supervisor: GONG Zhonghui
Light Design: CHEN Fenghua
Costume Design: Little Bug
Film Director and Editor: HUANG Youpin
Commissioned by Shenzhen Dance Talent Program 2020
Special Support from Yi Space and Gaga Dance Company
Dancers: LV Chengliang, GAO Wei, YANG Hao, CHEN Jiale, ZHU Fengwei
ZHU Fengwei is a dancer and choreographer. He was the resident dancer of Beijing Modern Dance Company from 2014 to 2017, performing in "Blooming of Time", "Oath Midnight Rain", "The Rite of Spring" and "Chinese Zodiac". During this period, he went along with Beijing Modern Dance Company to perform in overseas countries such as Germany, Canada, Egypt, Croatia, etc. In 2017, he performed in GONG Zhonghui's "Gazebo" and CHEN Sian's "Foodie" as an independent dancer.
He has worked with artists like YANG Liping, YE Jintian and HE Xintian, taking the main role in dance dramas such as "The Rite of Spring", "Winter of Peacock", and "Pingtan Impression". Over the years, he has shown up at various theatres and international festivals such as London's Sadler's Wells, Brisbane Art Festival, Melbourne Art Festival, etc.
Light Design
CHEN Fenghua graduated from Shanghai Drama Institute under the tutoring of the prominent stage designer, professor Wang Lvwei. In 2013, he went to the Odin Theater in Denmark to further his studies. In 2014, He attended the Beijing International Art Biennale. In 2015, he continues his studies in America. His stage design works "Anna Is in the Tropics" and "Henry V: the battle of Agincourt" were chosen in the exhibition of China's Stage Art in A Decade with the former winning the Shanghai Stage Art Academy Award. His experimental art piece "maiden work" was chosen into the Artist Support Program of Shanghai International Art Festival. It is the first exhibition workpiece commissioned by the Artist Support Program of Shanghai International Art Festival. He was also the light design of the stage art department at Zhejiang TV Station, and the director of lighting operations of the immersive drama "Sleep No More" and "Secret Cinema".
Stage Director
HE Huan used to work for Nantes National Dance Center and Renne Dance Museum in France. She cooperated with choreographers such as Maud Le Cadec, Boris charmatz, yvann Alexandre, etc. and participated in the Lyon Dance Biennale, Vienna Dance Festival, etc. She is now a member of the Gaga Dance Company and teacher of the college of music of Guizhou Normal University.
LV Chengliang graduated from Beijing Dance Academy, majoring in modern dance, and is now the choreographer of Shenzhen Opera & Dance Theatre Company. During school years, she took an exchange program to the State University of New York at Purchase. She was the rehearsal instructor and stage director of HUA Xiaoyi's dance drama "Every Moment". She toured in YANG Liping's "The Rite of Spring". She won the gold prize for the teenager group of the 7th Seoul International Dance Competition and first award for women in the youth group B of the classic dance of the 9th Taoli Cup. Her personal works include "The Chanting of Fan", "Early Spring", "Apple". "Yi" and "Take Care" are her choreography works.
GAO Wei graduated from Guizhou Normal University, majoring in the department of dance, and is now the dancer of Gaga Dance Company. He performed in the premier show of GONG Zhonghui's "Gazebo" at the multi-functional theatre of National Centre for the Performing Arts. He also danced in YANG Liping's "Under Siege" and "The Winter of Peacock" while performing in Tokyo and at Lincoln Center as well as during the global tour. As he stays at Gaga Dance Company, he participated in the creation of "Inner Structure" and the group performance with Yishenshu, Local, Nashan Culture, Organic Music Radio. He also performed for GGDC's creation of "The Hole".
YANG Hao graduated from Guizhou Normal University and is now the dancer of Gaga Dance Company. He attended the TV program "Dance in Step", performed in GONG Zhonghui's work "You Sheng" as well as Aduo's Future Ethnic Music Show "The Land of Birth". He also danced in Gaga Dance Company's creation of "Parallel World — Blue" and "Inner Structure", the group performance with Yishenshu, Local, Nashan Culture, Organic Music Radio and GGDC's creation of "The Hole".
CHEN Jiale graduated from Guizhou Normal University, majoring in the department of dance and is now the dancer of Gaga Dance Company. He performed in works like "Sheng Xi", "Feng Yin", "Miao" and "Dirt". He also performed in Gaga Dance Company's creation of "Inner Structure", the group performance with Yishenshu, Local, Nashan Culture, Organic Music Radio and GGDC's creation of "The Hole".
2020.11.12 - 2020.11.14 @ 19:30
2020.11.14 - 2020.11.15 @ 14:00
Duration: 60 minutes
Price: 150 RMB/180 RMB


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2 edition of Density Functional Theory I found in the catalog.
Density Functional Theory I
1996 by SPRINGER-VERLAG .
Written in English
|The Physical Object
|Number of Pages
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This will result in less computational time to compute properties. The book therefore offers several features that have proven to be helpful in enabling students to master the subject, including: Problem sets in each chapter that give readers the opportunity to test their knowledge by performing their own calculations Worked examples that demonstrate Density Functional Theory I book DFT calculations are used to solve real-world problems Further readings listed in each chapter enabling readers to investigate specific topics in greater depth This text is written at a level suitable for individuals from a variety of scientific, mathematical, and engineering backgrounds. The present book is a rigorous and detailed introduction to the foundations up to and including such advanced topics as orbital-dependent functionals and both time-dependent and relativistic DFT. It lays the groundwork for reducing the many-body problem of N electrons with 3N spatial coordinates to 3 spatial coordinates, through the use of functionals of the electron density. Let us illustrate that for ethane. The many-body Hamiltonian H fixes the groundstate of the system under consideration, i.
In fact, the primary role of the core electron wave functions is to ensure proper orthogonality between the valence electrons and core states. Here is an example of getting the center of mass from an Atoms object using ase. DFT is among the most popular and versatile methods available in condensed-matter physics, computational physics, and computational chemistry. The formal results are complemented by selected quantitative results, which primarily aim at illustrating strengths and weaknesses of a particular approach or functional. For more details on how to take advantage of this service, or to recommend the title to your librarian, please Contact us or Recommend to your Librarian Table of contents.
The simplest approximation is the local-density approximation LDADensity Functional Theory I book is based upon exact exchange energy for a uniform electron gaswhich can be obtained from the Thomas—Fermi modeland from fits to the correlation energy for a uniform electron gas. We use ase. Consequently, small changes in the energy can dramatically change the occupation numbers, resulting in instabilities that make it difficult to converge to the occupation step function. This book represents an attempt to present examples on the utility of DFT for the understanding of the chemical reactivity through descriptors that constitute the basis of the so called Conceptual DFT sometimes also named as Chemical Reactivity Theory as well as the application of the theory and its related computational procedures in the determination of the molecular properties of different systems of academic and industrial interest. Its use relies not only in the ability to calculate the molecular properties of the species of interest but also provides interesting concepts that allow a better comprehension of the chemical reactivity of t
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Its use relies not only in the ability to calculate the molecular properties of the species of interest but also provides interesting concepts that allow a Density Functional Theory I book comprehension of the chemical reactivity of t In this solution, the step function is replaced by a smoothly varying function such as the Fermi-Dirac function at a small, but non-zero temperature Kresse The first problem is easily solved by centering the atoms in the unit cell.
There are typically three moments of inertia, although some Density Functional Theory I book be zero depending on symmetry, and others may be degenerate. There is a particular difficulty in the calculation of the electronic structures of metals compared to semiconductors and molecules.
We compute these vectors as the difference in positions of two atoms. To get these quantities, we have to define a calculator and attach it to an ase. Further, Density Functional Theory I book kinetic energy functional of such a system is known exactly.
The downside of including spin polarization is that it essentially doubles the calculation time. In many cases the results of DFT calculations for solid-state systems agree quite satisfactorily with experimental data. Furthermore, the contributions of the core electrons to bonding compared to those of the valence electrons is usually negligible.
The same applies to some basic notions of solid state theory, as, for instance, the Fermi surface. This title will be released on.
Journal of the American Chemical Society 8 : — One rotates the molecule an angle in radians around a vector, but you have to choose whether the center of mass should be fixed or not.
The effective potential includes the external potential and the effects of the Coulomb interactions between the electrons, e. To calculate the Density Functional Theory I book between two atoms, you have to specify their Density Functional Theory I book, remembering that the index starts at 0.
The authors show how the widespread availability of powerful DFT codes makes it possible for students and researchers to apply this important computational technique to a broad range of fundamental and applied problems.
The spin-polarized solution is sensitive to the initial guess, and typically converges to the closest solution. However, DFT was not considered accurate enough for calculations in quantum chemistry until the s, when the approximations used in the theory were greatly refined to better model the exchange and correlation interactions.
In metals, however, the density of states is continuous at the Fermi level, and there are typically a substantial number of states that are close in energy to the Fermi level. The final prices may differ from the prices shown due to specifics of VAT rules Rent the eBook Rental duration: 1 or 6 month low-cost access online reader with highlighting and note-making option can be used across all devices About this book Density Functional Theory DFT has firmly established itself as the workhorse for the atomic-level simulation of condensed matter phases, pure or composite materials and quantum chemical systems.
Here is how that is done for a CO molecule Figure fig:co-origin. However, there are still an infinite number of discrete k points that must be considered, and the energy of the unit cell is calculated as an integral over these points.
This will result in less computational time to compute properties. The use of these k point setups amounts to an expansion of the periodic function in reciprocal space, which allows a straight-forward interpolation of the function between the points that is more accurate than with other k point generation schemes PhysRevB.
In the next example, we utilize functions in numpy to perform the calculations, specifically the numpy. This book gives an updated presentation of non-relativistic and covariant energy functionals, single- and multi-reference methods, and techniques to describe small- and large-amplitude collective motion or nuclei at high excitation energy.
Within the framework of Kohn—Sham DFT KS DFTthe intractable many-body problem of interacting electrons in a static external potential is reduced to a tractable problem of non-interacting electrons moving in an effective potential.
The oxygen triplet state is lower in energy than the oxygen singlet state, and thus it corresponds to the ground state for an oxygen atom. Although the theoretical underpinnings of DFT are quite complicated, this book demonstrates that the basic concepts underlying the calculations are simple enough to be understood by anyone with a background in chemistry, physics, engineering, or mathematics.
Let us illustrate that for ethane. This database contains a broad set of atoms and molecules for which good experimental data exists, making them useful for benchmarking studies.
In either case, the pseudopotential function is generated from an all-electron calculation of an atom in some reference state.Density functional methods form the basis of a diversified and very active area of present days computational atomic, molecular, solid state and even nuclear physics.
A large number of computational physicists use these meth ods merely as a recipe, not reflecting too much upon their logical basis.
Condensed-Matter-Laboratory (CML) is an application for simulating solids and nanostructures and calculating different properties of them by density functional theory and using Green's function theory in tight-binding approximation to calculate phononic and spin dependent or independent electronic properties of different systems.
Furthermore. Density Functional Theory (DFT) has firmly established itself as the workhorse for atomic-level simulations of condensed phases, pure or composite materials and quantum chemical systems. This work offers a rigorous and detailed introduction to the foundations of this theory, up to and including.Density Functional Theory.
The pdf functional theory (DFT) treats the electron density as the central variable rather than the many-body wavefunction. This conceptual difference leads to a remarkable reduction in difficulty: the density is a function of three variables, i.e.
the three Cartesian directions, rather than variables as the full.Among these methods is density functional theory (DFT), which permits one to solve the equations of quantum mechanics more efficiently than with any related method.
The present volume represents the most comprehensive summary currently available in density functional theory and its applications in chemistry from atomic physics to molecular.Density Functional Theory ebook DFT for short) is a potent methodology useful for calculating and understanding the molecular and ebook structure of atoms, molecules, clusters, and solids.
Its use relies not only in the ability to calculate the molecular properties of the species of interest but also provides interesting concepts that allow a better comprehension of the chemical reactivity Cited by: 1.


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The Associated Press has been honouring college football's best with an All-America team since 1925. This season, the AP released its first preseason All-America team and its first midseason team. The full three-team All-America selections are unveiled in December. The ninth installment of the weekly All-America watch features West Virginia's "Touchdown Jesus," Auburn's surging workhorse and Washington State's "Continent."
tap here to see other videos from our team.
AP All-America Watch: 'Touchdown Jesus;' Auburn's surging RB Back to video
Will Grier, QB, West Virginia
Baker Mayfield of Oklahoma is going to be tough to beat for the first-team quarterback spot when the AP All-America team comes out in December. But there are second and third teams, and the shaggy, swashbuckling Grier should be in the mix for some recognition. The Florida transfer nicknamed "Touchdown Jesus" is second in the country in TD passes with 34 and ranks in the top 10 of just about every significant quarterback stat.


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Obama Rejects Reality as "Politics of the Moment," Embraces Politics of FearJuly 21, 2009Listening to President Barack Obama and other top Democrats on the subject of health care, one could be forgiven for thinking commercial medicine itself is on the verge of collapse, and that most of us soon will be completely unable to access decent medical treatment. In response to criticisms from GOP lawmakers and gloomy CBO projections, Obama re-emphasized what he insists is a need for immediate, drastic reform. He dismissed the illumination of the fiscal insanity of his prized health care plan as the "politics of delay and defeat" and "politics of the moment" and said, "The need for reform is urgent and it is indisputable." It is impossible to arrive at the...
House Dems Would Ban New Private Health InsuranceJuly 17, 2009"Except as provided in this paragraph, the individual health insurance issuer offering such coverage does not enroll any individual in such coverage if the first effective date of coverage is on or after the first day" of the year the legislation becomes law.
Regulation of the Day: The Color of StitchesJuly 16, 2009The federal government regulates which colors may be used in surgical stitches.
Health care taxes -- devastating effects for NYCJuly 16, 2009
Lead headline on the Drudge Report today – "Terrifying 57% tax looms for biggest earners in NYC." It links to a NY Post article that points to the "job-killing effects" of the proposed tax surcharges to pay for the Democrats health care plan. As the Post noted,
That means New York's top earners, small-business owners and most...
Government health care monopoly--not in consumers' interestsJuly 9, 2009Regina Herzlinger, chair of Harvard Business School, in National Review takes on health care and the Obama Administration's arguments that a government-run plan would increase competition, provide more choice, and lead to greater cost efficiencies:
But before we get swept away, let us remember that these health-insurance markets would be monopolies run by government, two characteristics that normally do not enhance consumer welfare. Picture the efficiency of your Division of Motor Vehicles, for example. Also consider government-...
Stepping Up the Class WarJuly 7, 2009On both of the most salient issues of the day, health care reform and climate change, proponents of the corresponding legislation are setting their sights on the rich to pay for these expensive measures. The massive government health care bill in the House involves a very expensive restructuring of the health care system in the United States--so expensive, in fact, that Democrats are proposing a tax increase on the rich, that is, in addition to the one that will occur when the Bush tax cuts expire in 2011. They are calling it a "surtax"--a yet-undetermined slice of the incomes of those earning over $200,000 per year, which would be used to help pay for the implementation of the health care overhaul. At the same time, a...
Washington Post Sells White House Access to Lobbyists, and Misreports Obama Health-Care FactsJuly 2, 2009Until it was publicly-exposed, the Washington Post was selling its access to the White House to lobbyists. As Politico reported, "For $25,000 to $250,000, the Washington Post is offering lobbyists and association executives off-the-record, nonconfrontational access to 'those powerful few' — Obama administration officials, members of Congress, and the paper's own reporters and editors. The astonishing offer is detailed in a flier circulated Wednesday to a health care lobbyist, who provided it to a reporter because the lobbyist said he feels it's a conflict for the paper to charge...
"If you like public housing, you will love public health care"July 1, 2009Best line this week -- should be a slogan for health care debate: "If you like public housing, you will love public health care." Read the opinion piece "Parsing the health reform arguments" by George Newman in the Wall Street Journal today for concise rebuttals of oft-repeated claims about government health plan.
Hearings Open on Coercive and Counterproductively Costly Health Care BillJune 23, 2009Congressional Democrats are pushing hard to complete their health care bill before next week's recess, but their hopes for a quick passage and the fulfilling of Obama's goal of signing by October look increasingly bleak--especially since the drafting was done without Republican input, leading, of course, to a political firestorm. The bill would mandate health insurance coverage for all Americans at enormous taxpayer expense and require major employer contributions, though there is not yet full agreement on the specifics of the burdens that will ultimately be imposed on employers. All that is clear so far is that...
FDA Tobacco Regulation May Harm Public Health By Blocking Healthy AlternativesJune 23, 2009FDA regulation may actually undermine public health by making it harder to market to smokers other tobacco products, like snus, that are not as lethal as cigarettes.


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Repeals a state corporate income tax deduction to allowable income for federal tax purposes for investment property held for at least seven (7) years.
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KC O`Douwd is a German singer-songwriter, composer and producer based in
Switzerland. From sassy club anthem 'B*tch' (2016) to heartfelt new single 'Private Dancer'
(2020), KC is known for his versatile and eclectic style that slides between a variety of
genres including pop, soul, funk, dance and house.
Having performed around Europe, America and Africa, KC is no stranger to the stage.
The artist grew up in a musical family where his grandmother, a renowned music teacher,
taught him how to play the piano at aged six, and his aunt – a successful soprano – helped
him land his first stage experience. KC has been dazzling global audiences ever since.
KC's artistic talent showed up early, manifesting itself in music, designing clothes, and
taking pictures. He began classical vocal training in his late teens, with an intensive and
formative five-year apprenticeship. From then, his creative career blossomed. He began
producing – including the 2-hour show 'Electricity' (1998) with Terrel Woodbury and Guido
Bernard which ran for over three years, 'Black and White' (2000-2006) which toured
around Europe and led to guest appearances on Potsdamer Platz, radio and TV.
In 2006, after separating from 'Black and White', KC began nurturing his solo career. He
produced original songs in German and English, composed for other artists and directed
video productions. In 2016, he performed 'Soulmates' live – a collection of songs he wrote
and composed along with piano accompaniment. In 2018, KC incepted "The Vision Tour"
with young Swiss musicians – a stage show that showcased original and cover songs.
These tracks were recorded at Switzerland's renowned Power Play Studios, known for
working with artists like Lady Gaga, Lenny Kravitz and Prince.
Influenced by iconic artists like David Bowie, Eurythmics, Mick Hucknall, Culture Club and
Tina Turner – as well as contemporary peers and friends such as Clean Bandit, Alvaro
Soler, Kunz, Conchita Wurst and Boy George – the singer-songwriter says that music is his
entire life: "I wake up and I have music in me."
Keep an eye out for KC O'Douwd's next release. Follow the pop artist for updates.
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I feel more relaxed about [public speaking]; maybe even a little excited to try some things out. I used to think there was an absolute way of doing a speech right, but now I see that there are probably infinite ways of doing a speech right.
I picked up some good pointers and feel I will be more confident next time I need to give a talk in public.
Your course helped me to understand a better way to approach [public speaking] and it makes me feel more at ease. You made it more down to earth and easier to understand.


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A pair of divers have taken part in a daring photoshoot with the biggest great white shark on the planet after it was spotted swimming near Hawaii.
The enormous predator known as 'Deep Blue', believed to weigh around 2.5tons and measure up to 20 ft in length, was first seen by diver and photographer Mark Mohler and Kimberly Jeffries on Sunday last week.
And the pair soon leapt into the water to take a closer look at the creature as she fed on a dead sperm whale, around nine miles from the coast off the Hawaiian island of Oahu.
Remarkable video shot nearby by Jeffries shows a swarm of Tiger sharks swarming around the dead sperm whale, before Deep Blue's dramatic arrival.
The predator was reportedly identified as 'Deep Blue', which is believed to be around 50 years old, because of a tag placed on it by scientists during an appearance over 20 years ago off the coast of Mexico.
Mohler wrote on Facebook: 'Deep Blue, possibly the biggest White Shark identified, coming in at nearly seven meters, was last spotted in Mexico.'
He said she had come to Hawaii for an 'all-you-can-eat vacation.'
Mohler wrote that fellow diver Jeffries was the first to see her on 13 January, and the pair confirmed Deep Blue's identity with the white shark authority.
Deep Blue became an icon several years ago during Shark Week on the Discovery Channel, through her remarkable size and age. She is 20 feet long and thought to be 50 years old. Pictures show the pair getting remarkably close to the deadly animal
It's likely that Deep Blue grew so big simply because of her age. Before being spotted in Hawaii, the great white was caught on video in July 2018 near Guadalupe Island, off the west coast of Mexico. It was spotted feeding on the carcass of a whale
Divers could identify her as 'Deep Blue' thanks to a tag she was implanted with when she appeared off the coast of Mexico two decades ago.
Video shot by the same photographer Kimberly Jeffries shows a group of tiger sharks feeding on the dead sperm whale before Deep Blue arrived.
A shark believed to be 'Deep Blue' was last spotted in footage captured by shark researcher Mauricio Hoyos Padilla off Mexico's Guadalupe Island in 2013
Padilla's remarkable footage from 2013 shows the stealthy predator lurking in the deep while attempting to catch prey
The video also shows the enormous apex predator swimming near researchers in steel cages, with one bold enough to be swimming outside the protection


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BEST DEAL IN NEW YORK CITY! Priced to sell today. Do you like to put your own signature on your home? This is your opportunity to own and renovate a great and flexible two bedroom plus maid's room and designated office space. But wait, there's more. We all know that your home begins even before you pass through the threshold into your new residence.
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New York City is the birthplace of modern Theosophy, begun officially on November 17, 1875, by H. P. Blavatsky, William Q. Judge, and Colonel Henry S. Olcott. Theosophy Hall NYC is the home of The United Lodge of Theosophists, an association of students independently devoted to the cause of Theosophy, and unattached to any Theosophical organization. ULT Meetings are free and open to all without distinction of race, creed, gender, condition or organization. Weekly classes in The Secret Doctrine (http://www.theosociety.org/pasadena/sd/sd-hp.htm) are offered plus other classes featuring original teachings of Theosophy recorded in the writings of H.P. Blavatsky and William Q. Judge. We are a lively exchange place where ancient Wisdom Teachings are studied in the context of a modern-day conversation. Students explore the fundamental concepts and core ideas in religion, science, and philosophy, then and now, and are encouraged to bring and ask questions. Our friendly dialogues are open to students young and old, new to Theosophy, just beginning, or returning for more. Please check the meetup schedule for free classes offered on Sunday mornings, Sunday nights, Monday and Wednesday nights. For more Theosophy pure and simple, check out the blog, at www.theosophywatch.com (http://theosophywatch.com/), on www.Facebook.com/theosophywatch, and Twitter @theosophywatch.phone 646 398 9613
347 E 72nd St
Embracing both the scientific and the religious, Theosophy is a scientific religion and a religious science. Although it contains by derivation the name God and thus may seem at first sight to embrace religion alone, it is the science of sciences and therefore has been called the wisdom religion.
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Students enjoy studying the articles of Helena P. Blavatsky and William Q. Judge on Zoom. Please let us know if you would like to be on our weekly email reminder list at [masked] or put into your calendar. The Zoom ID stays the same for this class.
Please check Theosophywatch.com for class discussions.
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Zoom class till we reopen, so pls email us at [masked] to send you the links and passwords to get in.
Tonight's class will be on karma, esp. collective karma.