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Hotels & Resorts Munich, Germany - The Best Western Hotel Cristal is conveniently located in the city centre and near the central station with public transportation. The main shopping area
Hotels & Resorts Munich, Germany - DERAG Max Emanuel - 3 stars - located in city center district Haidhausen - 328 rooms & fully equipped apartments - restaurant - specialized in extended
Hotels & Resorts Munich, Germany - This Holiday Inn is located approximately 20 miles from Munich Airport and one mile from the Octoberfest fairgrounds and Olympic Park.
Hotels & Resorts Munich, Germany - Located in the city center, about 5 minutes from Munich Central Station, between the Octoberfest field and the New European Patent Office, the hotel is
Hotels & Resorts Munich, Germany - TOP CONRAD-HOTEL de Ville Munich, 4 stars, is located in the heart of Munich The hotel features 89 rooms, a restaurant, 2 meeting rooms, and is Mediterranean
Hotels & Resorts Munich, Germany - The contemporary Design-Hotel Innside by Melia Muenchen Parkstadt Schwabing is located in the northern part of Munich at the foot of the Highlight-Towers
Hotels & Resorts Nuremberg, Germany - The outstanding facilities will satisfy the most discerning guests and ensure a pleasant stay in a tranquil ambience.
Hotels & Resorts Nuremberg, Germany - You can expect a unique atmosphere with romantic details in the history of this building which dates back to 1675.
Hotels & Resorts Rostock, Germany - At the heart of the historic centre of Rostock  thatÂs not a bad location for a start. The city port with its unique Hanseatic city style and wealth of
Hotels & Resorts Rostock, Germany - The Radisson Blu Rostock is located in the heart of Rostock, features 251 rooms, and is approximately 21 miles from Rostock-Laage Airport.
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Find great deals on quality hotels & resorts in Germany, or indulge at one of our luxury resorts. Take advantage of the many amenities that can be included with your stay such as in-room internet access, wifi, room service, fitness center, pool, hot tub, steam room, and shuttle services to and from the airport. Browse our hotels and resorts in Germany and plan your Germany vacation today!
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What Creatures Can You Identify In This Fossilized Sea Floor?
A fossilized piece of the sea floor is a glimpse into an ecosystem long-gone, if only you know how to look at it. Read on to learn about the long-dead bryozoans, crinoids, brachiopods, gastropods, and even trilobites in this rock. »

subset: commoncrawl


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Police Remind Public To Care For Pets In Cold Weather
It's so cold that state police are warning that troopers will file criminal charges against anyone who fails to provide shelter for their pets.
Animal Friends Rescues 55 Cats & Dogs As Part Of Annual Event
A total of 55 cats and dogs were greeted at Animal Friends today ending 2013 much differently than they were supposed to.
Furry Tails: Extended Family
Rosie and Camellia have been so important in my life, but they aren't the only dogs to touch my heart. Long before I got my very own dog, my extended family introduced me to what it was like to love animals.
Rescued Dogs From Virginia To Get Veterinary Checks
Volunteers from a local group jumped into action this weekend to save nearly three dozen dogs from a shelter in Virginia.
Local Volunteers Organize Mission To Rescue Puppies Set To Be Euthanized
A plane carrying 30 special passengers landed in Pittsburgh Saturday night, and they're all headed to new homes.
Five Forbidden Foods You Shouldn't Feed Your Furry Friends
We know we're not supposed to feed our dogs table scraps but so many of us do it anyway, but there are five specific things you really need to be concerned about, some even veterinarians didn't know about until recently.
Vets Issue Warning About Increased Tick Population
Right now, ticks are enjoying a fall resurgence of substantial proportions and local vets have their hands full and pet owners need to be on the alert.
Furry Tails: Lamb Chop & Froggy
Does your pet have a favorite toy? Something he or she carries around the house, plays fetch with, maybe uses as a pillow. It's probably slobber soaked and smells something awful, but you'd never dream of trying to pry it from the paws of your furry friend.
Coyotes Kill 2 Baby Alpacas, Attack Other Animals In Westmoreland Co.
People living near the Humming Valley Alpaca Farm in Washington Township are on edge after numerous coyote attacks in recent months.
Pittsburgh Pooches Dog Paddle Through Dormont Pool
The little dogs gathered early in the heat of late summer, for the Labor Day Doggy Dip in the Dormont Pool.
Andrew Fillipponi: Dogs Could Play Baseball
At PNC Park Pup Night earlier in the week, Andrew found himself in the middle of a spirited debate about if a dog could be taught to tag up from third and score on a flyout.
"Lost Dogs Pittsburgh" Helps To Reunite Wandering Pups With Owners
Seven-year-old Zeus does not want for anything after his return home.
Emergency Dog Food Drive
A local animal rescue group jumped into action to help collect dog food for a shelter in southern West Virginia.
Dog Rescued After Suffering Severe Heat Stroke
The recent heat wave has not only been leaving lots of people hot, but animals as well.
Oxygen Masks Tailored For Pets Donated To Beaver County Emergency Services
Firefighters and first responders do their best to revive family pets overcome by smoke inhalation.


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A day after the U.S. Department of Transportation (DOT) announced more than $2 billion in funding for high-speed intercity rail projects, officials of Alstom Transport detailed the company's effort to support new jobs created by upgrades to America's transportation network. In the last year, Alstom invested more than $3 million to enhance its 150,000-square-foot rail signaling manufacturing facility in West Henrietta, N.Y., enabling the site to accommodate approximately 200 new jobs.
The announcement was made during an event at Alstom's Rochester facility that included remarks from U.S. DOT Deputy Secretary John Porcari, New York State Transportation Commissioner Joan McDonald, regional labor leaders and a representative of the Apollo Alliance — a national coalition of labor, business and community leaders that support investments in mass transit and other infrastructure projects that create jobs and keep America competitive in the global transit marketplace.
In addition to benefits realized through job creation linked to projects throughout the U.S., New York received several direct investments through the recent round of federal rail funding. These included $295 million to alleviate delays for trains traveling the Northeast Corridor in and out of Manhattan; $58 million to upgrade tracks, stations and signals along the state's Empire Corridor; and $1.4 million for a new intermodal station in Rochester.
Over the past six months, Alstom secured several large-scale transportation projects valued at well over $300 million. Among these are an upgraded signaling and train control system for the Metropolitan Atlanta Rapid Transit Authority, as well as a complete overhaul and modernization of 120 railcars for the Delaware River Port Authority's PATCO system.
Alstom also marked several recent milestones in its North American signaling activities, including receipt of the first Federal Railroad Administration type approval for U.S. deployment of a fully-functional positive train control (PTC) system. The investments announced this week will enhance the company's ability to deliver these projects and others for which it is currently bidding.
The train wreck, which occurred in the early morning of March 24, 2014, when the operator allegedly fell asleep, injured more than 30 people and caused roughly $9 million in damage. The lead railcar had to be cut up to remove it from the escalator.
The vehicle, which was a designed and built by Brookville Equipment Corp., will be the first streetcar in the U.S. that utilizes wireless traction power.
Opened in 1935, Newark Penn Station is listed on both the State and National Registers of Historic Places. The station was originally designed and still operates as an intermodal facility serving pedestrian, taxi, bus and private vehicle traffic generated by the more than 50,000 transit customers who use the station each day.
Part of the problem is an aging fleet, according to officials. Calgary Transit placed a $200-million deal in 2013 to buy 60 new light rail vehicles; however, those vehicles will not be operational until 2016.
The new trains for Hermann-Hesse railway line will be completely emission-free. In times of increasing energy costs and higher level of pollution, the development of this technology is essential.
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SteamWorld Dig hits PS4, PS Vita in March
I can't say enough good things about SteamWorld Dig, a platformer centered around mining that first launched on the 3DS eShop. It's since come to Steam in high definition, and that expanded version was excellent. Now, Image & Form has its sights set on PlayStation Network.
SteamWorld Dig will be out on PlayStation 4 and PS Vita in March for $9.99/€8.99. While I think the latter system will be the way to go here, the game does support Cross-Buy (pay once for both versions) so that's not even going to be an issue.
SteamWorld Dig will have a cross-buy discount in Europe, but not in North America
11:30 AM on 08.27.2014
Steamworld Dig is better on the Wii U
3:30 PM on 08.25.2014
Delve into SteamWorld Dig on Wii U next week
7:30 PM on 08.19.2014
Creators of SteamWorld Dig looking into Cross-Buy promotion
10:30 AM on 07.21.2014
SteamWorld Dig dated March 18 for PS4 and PS Vita
9:30 AM on 03.04.2014
SteamWorld Dig hits PS4, PS Vita in March
4:30 PM on 02.14.2014
PC Port Report: SteamWorld Dig
2:00 PM on 12.05.2013
SteamWorld Dig coming to PC/Mac in HD next month
7:00 PM on 11.21.2013
Review: SteamWorld Dig
5:01 PM on 08.21.2013
SteamWorld Dig Updates, Screenshots, & Videos
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Terraria: Otherworld's GDC trailer drops more hints about its alternate universe
5:30 PM on 03.12.2015


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The Beatles, Coming to a Video Game Console Near You
While my plastic guitar gently weeps
By Amy Phillips on October 30, 2008 at 11:55 a.m. EDT
Video game makers MTV Games and Harmonix-- aka the people behind "Rock Band"-- announced today that they have formed a partnership with Apple Corps Ltd. to bring the music of the Beatles to Xboxes the world over. That's right-- just a few taps on that fake drum pad, and you're as good as Ringo! (We kid because we love.)
The parties are in the process of developing a new game that will serve as "an unprecedented, experiential progression through and celebration of the music and artistry of the Beatles," according to a press release.
It's unclear right now if the game will be a new version of "Rock Band" or something else entirely, but we'll find out when it hits shelves next year. UPDATE: According to Billboard.com, it's not a new version of "Rock Band", but something else entirely.
This is a big deal because it's the first time the Beatles have allowed their tunes to be used in an interactive game. Also, any time you get Sir Paul McCartney, Ringo Starr, Yoko Ono Lennon, Olivia Harrison, and Giles Martin (son of George Martin) working together on something, it's a big deal.
Requisite fawning quotes from the press release:
Paul McCartney: "The project is a fun idea which broadens the appeal of the Beatles and their music. I like people having the opportunity to get to know the music from the inside out."
Ringo Starr: "It gives me great pleasure to be part of the Beatles/Apple and Harmonix/Rock Band partnership. The Beatles continue to evolve with the passing of time and how wonderful that the Beatles'
legacy will find its natural progression into the 21st century through the computerized world we live in. Let the games commence."
Yoko Ono Lennon: "It's cool. I love it and hope it will keep inspiring and encouraging the young generation for many decades."
Olivia Harrison: "People are having so much fun playing Rock Band. Combined with the Beatles tracks, it is a great way to either listen or participate. If you like the music, it doesn't take much persuasion to get you to play."
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Child's play for a good cause
December 2, 2014 Submitted Photo Dunkirk City School No. 3 was the place to be on a recent Friday afternoon. more »»
Reader submissions sought
December 1, 2014 For an upcoming special section, the OBSERVER is asking readers to submit memories of their Christmas past — stories, photos or both. more »»
Empty Bowls event Saturday
December 1, 2014 This is a scene from the Empty Bowls 2013 fundraiser. This year, the event will be held Saturday, Dec. 6 from 11 a.m. to 2 p.m. at Blessed Mary Angela (St. Hedwig's) Social Center, 324 Townsend St. more »»
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European Contrast Piped Skirt
- No Longer Available -
Create your own three-piece crib set with any bumper, crib sheet and crib skirt, and receive a 10% savings.
Discount Applied in Cart. Terms and Conditions Apply.
Solid pastels and dove or chocolate piping on bed skirts pair beautifully with sheets of any stripe (or dot).
- 240-thread-count percale gathered bed skirt
- Yarn-dyed, loomed and tailored at a family-owned mill in Portugal
- Crib skirt has a 14½" drop; bed skirt has a 15" drop that accommodates most boxsprings and bed frames
- 100% cotton
- Made in Portugal
- Machine wash
- In petal, lilac or cloud with dove piping, or petal, silver sage or cloud with chocolate piping
- Oeko-Tex® Certified
- View bedding dimensions
Shown in lilac with dove piping
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Stanford IT Learning - The Training division of CIM Technologies, Inc. (formerly CIM Training Center) is an AUTODESK AUTHORIZED ADVANCED TRAINING CENTER in Manila, Philippines, who is one of the pioneer in introducing CAD training in the country. Stanford IT Learning caters to students and professionals in the fields of Architecture, Engineering, Construction, Multimedia and Manufacturing. It has been in the industry for more than 20 years and most of the major companies trust their trainings to Stanford IT Learning.
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help fast i'm scared!
after reading vic's very informative post there is no way in two kinds of hades i am putting a potato in my soil...lets start there! some things are just better off not known! I feel a little silly just having fungus knats and asking a home remedy to take care of them, as i feel vic may have to call in the marines...who the hell grows bugs like that, what is wrong with you! anyway i am now feeling better about this bugs flying around aggravating the horse crap out of me, but i would still like to get rid of them...can i mix a concoction and spray the soil down with it...like the alcohol and water mix for spider mites? again i realize that my problems at this point are minut, but i am just a selfish little brat that way, if someone could help me out here. i could not see all the pics by the way vic put in the post...i saw what the hell is this pic, that was a plenty. bout like i saw a pic on here of someone taking and finding a big snake in their kitchen one morning...that's when you know you woke up on the wrong side of the bed :).
sorry lol i was reading vic's and rhizo's discussion on the things she was finding in her soil, cracked me up. it was late and i was a little tired apparently and slap happy :). grrr i am never buying peat again i mixed it with potting soil, cause you know i found it cheap and it doubled the amount i had to pot things in. i can grow things but i sure have a lot to learn about what to pot them up in to really make them grow well. now i am aggravated with myself, i knew i had never had knats in my soil before and that is the only thing that has changed. i was buying the ripped bags of things at walmart for half off and i just put those two together in my big trash can i keep my dirt in. i need to really research different soils and potting mediums and see what my best options are. problem here is i have like 70 some houseplants am i going to have to repot everyone of them? not all of them are in peat but maybe all of them have got infested with these knats. i really need some good help and advice now!
I used a potting soil with alot of peat in it the year before last and had an issue with gnats myself. They are so annoying!! I ditched the peaty soil and I haven't had many problems since- just watch your watering. I like to keep it on the dry side- that also helps.
As for the repotting- I love repotting! It's one of my favorite parts of growing plants! I get to see the roots and make the plant happier in it's new fresh dirt!
But that's just me. Repotting would be a good option too


text: etd@IISc Collection: http://hdl.handle.net/2005/12 2015-03-25T04:21:43Z 2015-03-25T04:21:43Z Understanding Solvent Effect On Triplet State Structure Of Thioxanthone And Its Derivatives Using Time-Resolved Resonance Raman Spectroscopy Pandey, Rishikesh http://hdl.handle.net/2005/2307 2014-05-01T07:00:30Z 2014-04-30T18:30:00Z Title: Understanding Solvent Effect On Triplet State Structure Of Thioxanthone And Its Derivatives Using Time-Resolved Resonance Raman Spectroscopy Authors: Pandey, Rishikesh Abstract: It has long been recognized that course and efficiency of a chemical reaction is largely mediated by the short-lived transient species (excited state or radicals) which are formed as reactive intermediates during a chemical reaction. Subtle changes not only in the bonding and electronic distributions but also in the conformations and geometries of these intermediates have a dramatic influence on the reactivity. A detailed understanding of the structural and dynamical aspects of electronic excited states is therefore essential towards unraveling photoinduced natural processes and for designing novel photonic materials. Time-resolved techniques have been widely used to study the transient species (or intermediates) formed during photochemical and photophysical reactions for better understanding of the reaction mechanism and dynamics. Time-resolved absorption spectroscopy is a promising tool to study the temporal dynamics and the kinetics of photophysical processes. But the absorption spectra of species in solution usually consist of broad spectral band revealing little or no information about the structure of the transient species under investigation. Time-resolved resonance Raman (TR3) spectroscopy, on the other hand, is a potential sensitive modality, which not only allows one to study the dynamics but also provides the vibrational structure of the transient species of interest in microsecond to picosecond time scale. Moreover, by choosing the wavelength of excitation one can selectively probe the particular transient species from a complex molecular system especially a biological molecule. Thioxanthone (TX) is well known for its dramatic solvatochromic behavior and has drawn enormous attention in the recent years. The objective of present thesis has been to understand the solvent-induced structural changes on the lowest excited triplet state of TX and its derivatives. We have primarily employed nanosecond TR3 spectroscopy, a pump-probe technique, to investigate structure of the lowest excited triplet state. Transient absorption experiments have also been carried out to study the excited electronic states. In order to substantiate our experimental findings and also to get more insight into the triplet-state structure, we have performed density functional theory (DFT) calculations. The polarizable continuum solvation model has been employed to account for the solvent effect into the computation. Time dependent (TD) -DFT calculations have also been performed to get the energy and the structure of the excited states. The present thesis has been divided into eight chapters. Chapter 1 gives brief literature review on photochemistry and photophysics of TX and the introduction to the TR3 technique. In this chapter we have briefly introduced key concepts which form the basis of the thesis. Chapter 2 covers the experimental and theoretical methodologies used in the present thesis work. The major components of the TR3 spectrometer as well as the important technical aspect of the TR3 technique have been discussed in detail. In the section of the theoretical method, basic concepts of the computational method, density functional theory and key concepts related to the solvation are briefly discussed. Chapter 3 focuses on a systematic vibrational study of the ground and lowest triplet states of TX. TR3 experiments have been carried out and the observed vibrational frequencies have been assigned. It has been observed that electronic excitation distorts the molecule, enabling the increased electron delocalization in the central ring keeping the ground state symmetry intact. The largest structural reorganization is observed in the central ring of TX, consisting of an oxygen atom. Normal mode analyses show that the normal mode composition is significantly influenced by the electronic excitation. The C=C stretching and C=O stretching modes are coupled to a greater extent in the triplet state as compared to the ground state. In the ground state, the two high-frequency modes can be assigned almost exclusively to the C=O stretching and C=C stretching, whereas in the triplet state, both of these coordinates have comparable contributions to the two totally symmetric modes. Chapter 4 deals with a very unique observation of simultaneous detection of two triplets. This is the first time when two triplet states have been simultaneously deleted using TR3 experiments. We have performed TR3 experiments in wide variety of solvents differing in their polarities and hydrogen atom donor abilities. The transient Raman signal has been observed from both n - π∗ and π - π∗ triplet states simultaneously. The population ratio of the two triplet states has been found to be dependent on the solvent polarity. Additionally, the excitation wavelength study has revealed that the relative ratios of the transient Raman peaks (assigned to two different triplet states) change with the excitation wavelength. Our claim of simultaneous detection of two triplets has been reconfirmed by triplet quenching experiments carried out at different temperature. It has also been observed that the CO bond length is very sensitive to the solvent polarity and specific interactions play an important role in determining the structure of lowest triplet-state. In Chapter 5, we focus on the understanding of the effect of chlorine substitution on the lowest excited triplet state of TX. TR3 spectroscopy has been used as an experimental tool to study the vibrational structure of 2-chlorothioxanthone (CTX). TR3 results indicate the coexistence of two lowest triplet states in the thermal equilibrium akin to the parent compound. The above observation has been further substantiated by probe wavelength dependent study. The configuration of the T1 state has been assigned to π – π∗, whereas the T2 state has been ascribed as n - π∗. The population ratio of 3n - π∗ to 3 π - π ∗ triplet states has been found to be more for CTX as compared to TX which has been substantiated by the flash photolysis experiments. Chapter 6 highlights the influence of solvent effect on lowest triplet state structure of CTX. Transient absorption spectroscopy has been employed to understand the triplet state electronic structure; whereas solvent induced changes in the structure of the lowest triplet state have been studied using TR3 spectroscopy. Time-resolved absorption measurements show that solvent polarity has dramatic dependence on the wavelength of T1 - Tn absorption maximum. A good correlation between the wavelength of T1 - Tn absorption maximum and ET(30) value of the solvent is observed. TR3 experiments carried out in solvents of varying polarities indicate that the contribution of n - π∗ character to the lowest excited triplet state increases with the increase in the solvent polarity. Both transient absorption and TR3 studies reveal that specific solvent effect is more pronounced in comparison to the nonspecific solvent effect. Chapter 7 of the thesis deals with the study on the triplet state structure and solvent effect on 2-trifluoromethyl Thioxanthone. Flash photolysis in tandem with TR3 spectroscopy has been employed to understand both the electronic and the vibrational structures of this pharmaceutically important thioxanthone derivative. Experiments have also been carried out in solvents of varying polarities to study solvent-induced changes in the triplet-state electronic spectra. We have observed the coexistence of two lowest triplet states alike the parent compound. The T1 state has been assigned to π - π∗ state, whereas n - π∗ configuration has been attributed to the T2 state. The wavelength of triplet-triplet absorption maximum of the lowest triplet state has been found to be sensitive to the solvent polarity and good correlation has been observed with the ET(30) value. The transient Raman results indicate that the CF3 substitution leads to increase in the population ratio of n - π∗ and π - π ∗ triplet states. Finally, Chapter 8 contains overall summary of the thesis and future directions of the present investigation. 2014-04-30T18:30:00Z Conformational Reorganization Of Hyperbranched And Linear Polymers And Functionalized Porous Polymer Films Samuel, Ashok Zachariah http://hdl.handle.net/2005/2300 2014-04-22T09:34:01Z 2014-04-21T18:30:00Z Title: Conformational Reorganization Of Hyperbranched And Linear Polymers And Functionalized Porous Polymer Films Authors: Samuel, Ashok Zachariah Abstract: The main focus of the research work presented in the thesis is the understanding of structural and conformational reorganizations in hyperbranched and linear polymers. The thesis includes three different investigations: a) the design, synthesis, conformational reorganizations and self-assembly of hyperbranched polymers (HBPs), b) the Raman spectroscopic studies of the melting of polyethylene glycol (PEG), and c) the preparation of functionalized porous polymer films. HBPs are structurally imperfect analogues of the defect-free branched polymers called dendrimers. Dendrimers prepared using a stepwise polymerization methodology will carry all the unreacted B groups at the periphery and therefore modification of these peripheral units with suitable linear segments (e.g. PEG) would naturally generate a core-shell structure. On the other hand, in the case of HBPs, that contain a large number of linear defects, the B groups are distributed throughout the highly branched backbone, and hence modification of these units may not generate a core-shell configuration. However, our earlier studies have demonstrated the unimolecular micelle type behavior (core-shell) of PEG-ylated aromatic HB polyethers in solution. Hence, even though the PEG segments are randomly placed throughout the HBP backbone, the polymer achieves a core-shell configuration through conformational reorganizations; this suggests that the core of HBPs may be flexible and adaptable. In order to further examine this issue, we have investigated the self-assembly of these PEG-ylated HBPs. These polymers were found to organize into uniform nano-aggregates (Figure 1). More interestingly, these aggregates were found to restructure on mica surface when exposed to solvent vapor. This study confirmed the formation of core-shell domains in the PEG-ylated HBPs and the ability of the HB core to reconfigure. Figure 1. Restructuring of nano-aggregates formed from PEG-ylated HBPs on mica surface. As mentioned earlier, the precise control of the placement of functional groups would be impossible in the case of hyperbranched polymers (HBPs); most approaches would result in random placement of the functional entities as the growth of the polymer occurs in a statistically governed manner. Hence, creating Janus hyperbranched structures appears a daunting task. Janus is the name given for facially amphiphilic systems, such as a sphere made by joining a hemisphere with a hydrophobic surface and one with a hydrophilic surface. Since we have demonstrated that the HBP backbone is adaptable, it would be interesting to test the possibility of generating a Janus configuration through reorganization of peripheral segments. Peripherally "clickable" HB polyesters were synthesized using the transesterification polymerization methodology. The peripheral groups were modified with two dissimilar segments, PEG and docosyl (C22 alkyl, DOCO) chains, by azide-yne click reaction using the corresponding azides. The immiscibility of the chains along with the tendency of alkyl chain to crystallize was expected to cause self-segregation of segments at the periphery aided by the reconfiguration of HB core. Melting transition associated with alkyl segments was evident in the DSC thermogram. In addition, the melting enthalpies, normalized with respect to the weight of alkyl segments, were close to that of the C22 alkyl chain for three HBPs with different compositions of DOCO and PEG. This suggests complete phase segregation of segments at the periphery. The behavior of these HBPs at the air-water interface was also investigated. In this experiment a single layer of molecules, deposited at the air-water interface, is compressed and decompressed at a predetermined rate. The surface pressure variation during the compression-decompression cycle reveals the molecular organization at the surface. Stable and reversible isotherms were obtained for these HBPs; which suggested their Janus nature with PEG chains solvated in water and alkyl chains projecting out into air. A change in slope was observed in the isotherm and we have ascribed this to the crystallization of docosyl segments. In order to verify the assignment, quasi-static compression (QSC) experiments were performed. In QSC experiment, the monolayer was rapidly compressed to a required surface area and the drop in surface pressure, as a function of time at this fixed surface area, was recorded. During the rapid compression the molecules may not have adequate time to organize optimally and therefore, holding the area constant often leads to a drop in surface pressure with time. The total pressure-drop after the compression reflects the extent of molecular reorganizations; this, for example, could be due to the crystallization of alkyl segments. In the present study, the extent of pressure drop scaled with the composition of alkyl chains; this proves the assignment and supports the self-segregation of the peripheral segments to generate a Janus configuration (Figure 2). AFM images of the transferred monolayer allowed the estimation of monolayer height, which was roughly in agreement with the expected single molecule dimension. Small angle X-ray scattering experiments (SAXS) on HBPs demonstrated existence of a lamellar morphology in the solid state. Janus structures may be expected to exist as bilayers in the solid state. As expected, the lamellar dimensions estimated were twice the monolayer height observed in AFM images. This confirms the bilayer structure and the Janus configuration of HBPs. We have also investigated the self-assembly of these Janus HBPs in solution and it was found that disk-like aggregates were formed in methanol, whereas vesicles were formed in water by systems that had the appropriate balance of hydrophilic and hydrophobic segments. Figure 2. a) The structure of Janus HBP. b) A cartoon depiction of reconfiguration of randomly functionalized HBP to Janus. c) DSC thermograms showing clear melting and crystallization peaks. d) Langmuir isotherms for Janus HBPs. The change in slope is indicated by orange arrow. e) Quasi-static compression isotherms. The extent of pressure drop for different HBPs (inset). f) The SAXS pattern suggesting lamellar structure in the solid state and a proposed model (inset). It was clear from the study that the incompatibility between segments is the primary reason for the reconfiguration. In order to test the generality of the approach, we have prepared two other types of HBPs: one with PEG and fluorocarbon (FC) and the other with DOCO and FC. These segments were chosen because of their mutual incompatibility. In both these systems, the formation of Janus configuration was similarly confirmed by DSC, SAXS and Langmuir isotherm studies. We have extended these studies to HBPs functionalized with three different immiscible segments (tripod HBPs) namely, PEG, DOCO and FC; in the case of PEG two different molecular weights were used: PEG350 and PEG1000; the latter exhibits a strong tendency to crystallize. Melting transition associated with each of the segments was observed in the DSC experiments. The normalized melting enthalpy of the docosyl domain was found to vary substantially depending on the composition and configuration of HBPs (Janus or tripod). Considering the variation of these values it was concluded that the presence of an immiscible amorphous segment, like PEG350, enhances the phase separation and crystallization of DOCO by providing more flexibility to the core. The presence of one or more immiscible but crystallizable segments (e.g. FC or PEG1000), on the other hand, lead to less effective crystallization. Interfacial behavior of the tripod HBPs, that carry the hydrophilic PEG units, were also studied using Langmuir trough. The tripod HBPs formed clear monolayer at the air-water interface at higher surface pressures (40 mN/m); where the hydrophobic segments, FC and DOCO, oriented away from water into air and PEG segments remained solvated in water. Due to the incompatibility between FC and DOCO, it may be anticipated that these segments also form phase segregated domains. While the AFM images allowed the estimation of monolayer thickness, these domains could not be resolved in the images. Interestingly, the transferred monolayer appeared smoother after thermal annealing. To investigate the reason, contact angle (CA) measurements were performed. It is widely accepted that the contact angle is very sensitive to the structure and chemistry of a few angstrom thick region of the top surface of a monolayer. The water CA on the monolayer before thermal annealing was 84˚ while it increased to 104˚ after annealing. This behavior was attributed to the effective phase segregation and crystallization of FC and DOCO domains. The crystallization causes CF3 end groups to orient normal to the surface and hence increases the water contact angle. The receding contact angle, on the other hand, was found to be substantially smaller (45˚); this large contact angle hysteresis could be indicative of chemical heterogeneity on the surface, and it has been suggested that the presence of small domains of low surface free energy could indeed result in such large contact angle hysteresis. Interestingly, when the film was aged under ambient conditions for 12 h, the contact angle dropped to the initial value of 84˚; re-annealing the film at 75˚C for 12 h again raised the contact angle back to 104˚. This reversible annealing-aging behavior reveals dynamic nature of the monolayer that permits gradual restructuring at the surface (Figure 3). Self-assembly of these tripod hybramers resulted in the formation of unique aggregated structures. Morphology of these aggregates, observed in AFM images, were different from those formed by Janus hybramers. These results provide a clear evidence for the segregation of all the three segments into individual domains -the hypothesized tripod hybramer configuration. Figure 3. AFM images of transferred monolayer of tripod HBP before and after thermal annealing. Contact angle (CA) measured on the corresponding monolayers are shown in the inset. A model proposed for explaining the variation in the appearance of the monolayer (image) and the CA is also provided in the figure. Effective phase segregation of FC and DOCO is proposed the reason for the change. Another interesting question we have investigated as a part of the thesis is the molecular mechanism of melting of PEG. Crystallization of polymer is hypothesized as polymer chains moving down the free energy landscape though sequence of conformational reorganizations into an ordered crystalline (lamellar) state. Such conformational reorganizations also occur during melting. We have attempted to probe conformational dynamics in PEG during its melting using Raman spectroscopy, polarized optical microscopy, DSC and DFT calculations. Single crystal X-ray and vibrational spectroscopic studies have demonstrated helical configuration of PEG chains in the solid state with a gauche O-C-C-O, trans C-C-O-C and trans C-O-C-C conformations. There are three ways in which the PEG-helix can change during heating; one where C-O single bond rotates, second where the C-C rotates and third where both rotate, but the barriers to these rotations are different, as was established by earlier NMR studies. The intensity ratio of two Raman bands, I2880/2850, was found to be sensitive to the configuration about O-C-C-O units along the polymer backbone. An invariant I2880/2850 ratio of ~0.78 was ascribed to the consistent C-C dihedral angle (gauche configuration) during melting. This agrees with the well-known "gauche effect" in ethylene glycol. Prominent spectral changes were also observed in the methylene rocking region (~800 cm-1). In order to gain insight into the new conformers formed during melting, we carried out Gaussian calculations using model conformers. Among helical models considered the heptamer and tetradecamer helix models were found to be most suitable for the solid state helical structure of PEG. The Gaussian calculations using different model conformers revealed that the Raman band at 810 cm-1 corresponds to CH2 rocking vibrations of the gauche C-C-O-C units along the polymer chain; while the band at ~1500 cm-1 region was characteristic of O-C-C-O trans conformer. This agrees with the earlier assignment of 1500 cm-1 band to CH2 scissoring vibrations of PEG in an all-trans configuration. Interestingly, no peak was observed in the 1500 cm-1 region of the Raman spectrum during melting of PEG, but new peaks appeared in the 810 cm-1 region (Figure 4). Hence, it was concluded that C-C bond rotation does not occur during melting of PEG. Thus, our study confirmed that C-O single bond rotation is the molecular mechanism of PEG melting. Figure 4. a) Raman spectra of PEG at different temperatures. b) helical model considered for the study. c) Comparison of the Raman spectrum of molten PEG (2) with calculated spectra of two different models. The dynamics of a system, where the successive changes occur as a function of external perturbation, can be studied using 2D correlation spectroscopy (2D-CoS). 2D-Raman Correlation spectroscopy was employed to study the molecular structural dynamics during the melting of PEG. Conventional rules of 2D-CoS were used to retrieve the order in which the vibrational bands respond to temperature. Vibration at 934 cm-1 corresponding to the amorphous domain of PEG solid state was found to respond to temperature first. As the temperature of the system rises, CH2 rocking (1280 cm-1), CH2 wagging (1472 cm-1) and CH2 scissoring (1124 cm-1) vibrations becomes active and this provides flexibility to the chain. As the polymer chain gains adequate energy (at particular temperature) bond rotation takes place resulting in the transformation of a few TGT segments to GGG segments. On increasing the temperature further more C-O bond rotations occur, leading to destruction of lamellar domains and eventually PEG melts. The final study presented in this thesis deals with the generation of functionalized porous polymer films. Condensation of water droplets during solvent evaporation from a polymer solution, under humid conditions, is known to generate uniformly porous polymer films. We have investigated the possibility of pore formation through water phase separation strategy (Figure 5). In the presence of added surfactants (SDS and CTAB in the present study), the interface of phase separated water droplets and the polymer would naturally become lined with the surfactants and consequently the internal walls of the pores generated, upon removal of the water, could become decorated with the hydrophilic head groups of the surfactant molecules. The size of the pores and their distribution were examined using AFM and IR imaging methods. We have demonstrated that the ATR-IR imaging is an efficient method for analyzing a few nanometer thick surface section of the polymer film (Figure 5e). It was observed that the presence of surfactant is important for the pore formation and irregular pore formation resulted in the absence of surfactant. In addition, both the surfactant concentration and the relative volume fraction of the surfactant solution were found to govern the size of the pores formed. Cloud point measurements suggested that the occurrence of surfactant facilitated the phase separation of water. Although IR imaging possessed inadequate resolution to confirm the presence of surfactants at the inner surface of pores, exchange of the inorganic counter-ion, such as the sodium-ion of sodium dodecyl sulphate (SDS), with suitable ionic organic dyes permitted the unequivocal demonstration of the presence of the surfactants at the interface with confocal fluorescence microscopy (Figure 5f). Figure 5. Schematic depiction of a homogeneous polymer solution (sky blue) in THF–water; yellow lines with red dots depicts dissolved surfactant molecules. (b) Initial stages of water droplet formation that are stabilized by surfactants. At this stage some polymer precipitation may also occur at the interface (depicted by the dark ring around the droplet). (c) Some droplet coalescence and continued formation of new water droplets leads to a slightly broad size distribution (coalescence and redistribution could be retarded due to the high solution viscosity). (d) Complete removal of THF followed by water generates the internally functionalized porous structures. e) IR spectral Image of the porous film. f) confocal fluorescence image of the porous film where the inner surface was functionalized with Rhodamine B. (For figures pl refer the pdf file) 2014-04-21T18:30:00Z Rotational Specroscopic And Theoretical Investigations Of Non-conventional Hydrogen Bonds Aiswarya Lakshmi, P http://hdl.handle.net/2005/2405 2014-11-12T06:37:48Z 2014-11-11T18:30:00Z Title: Rotational Specroscopic And Theoretical Investigations Of Non-conventional Hydrogen Bonds Authors: Aiswarya Lakshmi, P Abstract: The nature of interactions within a molecule, i.e. chemical bonding, is well understood today. However, our understanding about intermolecular interactions, which has great relevance in nature, is still evolving. Historically there are two types of intermolecular interactions, van der Waals interaction and hydrogen bonding. However, there has been an upsurge of interest in the halogen bonding and lithium bonding during the last decade. The main emphasis of our research is to understand these interactions in detail, in particular non-conventional hydrogen bond acceptors. In this work, weakly bound complexes are studied using Pulsed Nozzle Fourier Transform Microwave Spectrometer, which has been fabricated in our laboratory and various theoretical methods. FTMW spectroscopy in the supersonic beam provides accurate structural information about the near-equilibrium geometry of small dimers and trimers in isolation. The home-built Pulsed Nozzle Microwave spectrometer, having a spectral range of 2-26.5 GHz has been used to record the microwave spectrum of these complexes. The spectrometer consists of a Fabry-Perot cavity, electronic circuit and pumps. Fabry-Perot cavity is the interaction zone of the molecules and radiation. The electronic circuit is used for the polarization and detection of the signal. Mechanical and diffusion pumps are used to maintain the vacuum inside the cavity. The gas molecules of interest are then mixed with a carrier gas and pulsed supersonically inside the cavity through a nozzle of 0.8 mm diameter. The emission from the complexes formed during the expansion is detected by super-heterodyne detection technique and then Fourier transformed. The first chapter of the thesis gives a brief introduction to intermolecular interactions, hydrogen bonding, halogen bonding, lithium bonding and molecular 2 of clusters. The chapter also includes a brief introduction to rotational spectroscopy. The second chapter of the thesis discusses the experimental and theoretical methods. It includes a detailed discussion of the mechanical and electrical parts of the spectrometer and the software used, which is developed in Labview 7.1. The various theoretical methods (ab initio and DFT) and the basis sets are discussed along with Atoms In Molecules Theory and the criteria used to characterize hydrogen bond. In the third chapter, to understand the ability of saturated hydrocarbons to act as hydrogen bond donor and acceptor, interaction of CH4 with H2S is studied using rotational spectroscopy as well as theoretical methods such as ab initio and Atoms In Molecules theory. Three progressions were obtained for the CH4•••H2S complex using microwave spectroscopy. The progressions were independently fitted to a linear top Hamiltonian. Absence of J10 transition in Progression II confirms the presence of higher internal angular momentum state, m=1. This also confirms the internal rotation of the monomers in the complex. Progressions II and III have negative centrifugal distortion constants. Hence both the states are from some excited internal rotation/torsional motion with strong vibrational-rotational coupling. The moment of inertia obtained from the experimental rotational constant confirms the structure in which sulphur of H2S is close to CH4. This also supports the structure in which CH4 is the hydrogen bond donor, if such an interaction is present. AIM analysis and the potential energy barrier for internal rotation show orientational preference and hence hydrogen bonding. The ab initio results show that CH4•••HSH interaction is more favorable than CH3H•••SH2. Ab initio and AIM studies also gave a structure where there is direct interaction between C and S. This is interesting since the electronegativities of C and S are comparable. Experimentally obtained negative distortion constants for the other two states, confirm excited state rotational-vibrational coupling. The experimental data give a floppy structure having internal rotation. In the fourth chapter the complex chosen for investigation is benzene-ethylene. Experiments in condensed phase and theoretical works show evidence of - stacking in benzene dimer, but there is no gas phase spectroscopic evidence available for the same. The lack of permanent dipole moment in the -stacked geometry of benzene dimer is the hindrance in the experimental observation of the same using microwave spectroscopy. Substitution of one of the benzene with ethylene in the -stacked structure will result in a complex having permanent dipole moment. C6H6 C2H4 complex can have, in addition to -stacking, C-H/interaction. There could be a competition between C6H6 and C2H4, either of which can act as H-bond donor. Experiments show the evidence of C-H/interaction, where C2H4 is the hydrogen bond donor. To ascertain hydrogen bond interaction AIM analysis has been carried out. The results show C-H/interaction, where one of the C2H4 hydrogen interacts with the benzene. Even though the aim was to get the -stacked geometry, it could not be obtained. However theory and AIM supports the formation of -stacked complex. In the fifth chapter using theoretical methods the ability of radicals as acceptor of hydrogen, lithium and chlorine bonds are examined with CF3 radical as the model system. As hydrogen bonds are highly sensitive to the environment, the effect of substitution of hydrogen by fluorine is also analyzed. It is found that, even though CH3 and CF3 radicals are topologically different, they interact in a similar fashion. AIM analysis of CF3HY satisfies all the eight criteria proposed by Koch and Popelier for hydrogen bonding. Here the hydrogen bond formed is charge transfer assisted. The interaction energies of the complexes are inversely proportional to the dipole moment of hydrogen bond donors and are proportional to the charge transfer occurring in the complex. Interaction energies from ab initio calculations confirm complexation of CF3 radical with LiY(Y=F, Cl, Br) and ClF. AIM analysis of CF3LiY and CF3ClF complexes show a bond critical point between Li/Cl and the C of CF3 and the condition of mutual penetration is also met. In CF3LiY complexes the interaction energies and charge transferred are directly proportional to the dipole moment of the Li bond donor. In the sixth chapter in order to extend the concept of non-conventional hydrogen bond acceptors to transition metals, complexes of Fe (Fe(CO)5) with HX (X=F,Cl,Br) have been studied theoretically. DFT calculations show that the structure in which the hydrogen of HX interacting with Fe through the sixth co-ordination site is a stable geometry. AIM analysis shows the presence of a bond critical point between the iron and the hydrogen of HX and hence bond formation. Q obtained from NBO analysis shows that there is charge transfer from the organometallic system to the hydrogen bond donor. However the interaction energies of the complexes are proportional to the dipole moment of hydrogen bond donors and are inversely proportional to the charge transfer for these complexes. H-bonding leads to the stabilization of square pyramidal geometry. 'Hydrogen bond radius' of iron has also been defined. Studies on the interaction of Fe(CO)5 with ClF and ClH showed that Fe can also act as a chlorine bond acceptor. Seventh chapter provides the overall conclusion and also discusses future direction. 2014-11-11T18:30:00Z Studies On Lanthanide Complexes Showing Photo-activated DNA Cleavage And Anticancer Activity Hussain, Akhtar http://hdl.handle.net/2005/2428 2015-01-08T05:24:08Z 2015-01-07T18:30:00Z Title: Studies On Lanthanide Complexes Showing Photo-activated DNA Cleavage And Anticancer Activity Authors: Hussain, Akhtar Abstract: This thesis work deals with different aspects of the chemistry of La(III) and Gd(III) complexes, their interaction with DNA and proteins, photo-induced cleavage of double-stranded DNA, photocytotoxic effect on cancer cells, cell death mechanism and cellular localization behaviour. Chapter I gives an introduction to the metal-based anticancer agents with special emphasis on clinically used drugs and the growing field of lanthanide therapeutics. An overview of the current strategies of cancer treatment, especially photodynamic therapy (PDT), is presented. Mode of small molecule-DNA interactions and the mechanistic aspects associated with DNA photodamage reactions and PDT effect are discussed with selected examples of compounds that are known to photocleave DNA on exposure to light of different wavelengths. A brief discussion on the various therapeutic applications of the lanthanide compounds is also made. Chapter II presents the synthesis, characterization, DNA binding, BSA binding, photo-induced DNA cleavage activity and photocytotoxicity of La(III) and Gd(III) complexes of phenanthroline bases to explore the UV-A light-induced DNA cleavage activity and photocytotoxicity of the complexes. Chapter III describes the synthesis, characterization, DNA binding, photo-induced DNA cleavage activity and photocytotoxicity of La(III) and Gd(III) complexes of phenanthroline bases with an aim to improve the design of the complexes to achieve better solution stability and DNA binding of the complexes. Chapter IV presents the synthesis, characterization, DNA binding, and UV-A light-induced DNA photocleavage activity and photocytotoxicity of La(III) and Gd(III) complexes of pyridyl phenanthroline bases with an objective to improve the photoactivity of the complexes by introducing an additional pyridyl group. Cell death mechanism and confocal microscopic studies are also carried out to gain more insight into the PDT effect caused by light in the presence of the complex. Chapter V describes the synthesis and characterization of La(III) and Gd(III) complexes of terpyridine bases and acetylacetonate to study the complexes as a new class of photosensitizers to explore their DNA photocleavage activity and photocytotoxicity in HeLa cells. Effect of attaching a glucose moiety to the acetyl acetone (Hacac) ligand has been studied. The cellular uptake behaviour of the La(III) pyrenyl-terpyridine complexes has also been investigated. Finally, Chapter VI presents the synthesis and characterization of curcumin and glycosylated curcumin La(III) and Gd(III) complexes having terpyridine base with an objective to study the photoactivated anticancer activity of the complexes in visible light. This chapter describes the visible light-induced DNA cleavage activity and photocytotoxicity of the complexes by exploiting curcumin and glycosylated curcumin as the photosensitizer ligands. Study on the cellular uptake behavior of curcumin La(III) complexes having pyrenyl terpyridine ligand is also presented. The references have been assembled at the end of each chapter and indicated as superscript numbers in the text. The complexes presented in this thesis are represented by bold-faced numbers. Crystallographic data of the complexes which are characterized structurally by single crystal X-ray crystallography are provided in CIF format in the enclosed CD (Appendix-I). Due acknowledgements have been made wherever the work described is based on the findings of other investigators. Any unintentional omission that might have happened due to oversight or mistake is sincerely regretted. 2015-01-07T18:30:00Z


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YouTube sensation Alex Tanney accepts invite to Buffalo Bills rookie minicamp
05/04/2012 at 7:31 pm By Gordon Dixon
Heading into this year's NFL draft Alex Tanney's name wasn't frequently mentioned by Mel Kiper, Todd McShay, and Mike Mayock. That doesn't mean he was an unknown commodity. Tanney gained YouTube fame thanks to this video.
But Alex is more than just the "Trick Shot Quarterback".
In 2011 the Monmouth College signal caller completed 71.5% of his passes for 3,867 yards and 38 touchdowns, helping the Fighting Scots to a 10-2 record and their third conference championship in four years. Tanney finished his collegiate career as the NCAA's all-time touchdown passing leader with 157.
After not being selected in the draft Tanney received an invitation to the Pittsburgh Steelers rookie minicamp being held this weekend before deciding to report to the Bills.
"I've been in contact with the Bills' quarterback coach David Lee all along," said Tanney. "The Bills were one of the first teams to contact me after the draft.
"After talking to my agent, we thought this would be a better opportunity for me to earn a roster spot."
"They [Steelers] were OK with it," said Tanney. "My agent also represents (Steelers coach) Mike Tomlin, so they have a good relationship."
In addition to starting quarterback Ryan Fitzpatrick Buffalo also has Tyler Thigpen on the roster as well as multipurpose threat Brad Smith. Vince Young worked out for the Bills earlier this week and while it appeared to go well he left without a contract offer. When Tanney gets his opportunity to show what he can do it's a pretty safe bet that accuracy won't be one of his weak points.
Buffalo's three-day minicamp begins May 11.
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InTurkey it was always1952, in Malaysia1937; Afghanistan was1910 and Bolivia1949. It is twenty years ago inthe Soviet Union, ten in Norway, five in France.It is always last year in Australia and next week in Japan.Paul Edward Theroux
Manuel Rivera-Ortiz's photographs of people living in poor villages in Turkey and Thailand, Bolivia and India don't falsely romanticize their subjects' poverty nor do they explicitly critique the political or economic systems that create such conditions. By focusing purely on the people who populate the poor global villages he visits, he captures the entire range of human emotion: mistrust, fear, curiosity, friendliness, happiness. Social critique may simmer below the surface of his work, but the primary message of Rivera-Ortíz's images seems to be that hope and creativity are not mutually exclusive to poverty.manuel rivera-ortiz
Bolivia does not exist.victoria of the united kingdom
I'm on the border of Bolivia, working for pennies Treated like a slave, the coca fields have to be ready The spirit of my people is starving, broken, and sweaty Dreaming about revolution looking at my machete But the workload is too heavy to rise up in arms And if I ran away, I know they'd probably murder my moms So I pray to Jesu Cristo when I go to the mission Process the cocaine paste, and play my positionImmortal Technique, "Peruvian Cocaine", Revolutionary Vol. 2 (2003).


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Infrequently Asked Questions: Sequenom [View article]Sep 8, 2014. 05:31 PM | 1 Like |Link to Comment
Apple (AAPL) only looks cheap if it maintains its profit margins (35.3% in 2012), writes The Brooklyn Investor. Slapping Samsung's mobile operating margin of 18% on Apple's $181B in expected revenue this year then giving it a 10 multiple and adding back cash yields a value of $370/share. Margins might not decline right away (and revenues may increase to offset), but Apple bulls are fighting the powerful historical tendency (particularly for Apple) of excess margins getting competed away. [View news story]Apr 21, 2013. 04:11 PM | 1 Like |Link to Comment
"High above the Alps my Gnome is hearing a rumor that Apple will announce a stock split at tomorrow's shareholder meeting," tweets Doug Kass. The rumor has led Apple (AAPL +1%) shares to spike higher. Update (2:24 PM): Kass is using the post-rumor spike to sell part of his trading position in Apple. [View news story]Feb 26, 2013. 04:22 PM | 1 Like |Link to Comment
Greenlight Capital/David Einhorn has dropped its lawsuit over Apple's (AAPL -1.6%) Prop. 2, in response to the company's decision to withdraw the proposal and its bundled changes (in the wake of an injunction) prior to Wednesday's shareholder meeting. Apple insisted at the meeting it remains committed to giving shareholders the right to vote on the issuing of preferred stock. [View news story]Mar 2, 2013. 03:25 AM | 0 Likes |Link to Comment


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1 person found this review helpful
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Luana and Scott have channeled their experiences and frequent frustrations into a foundation that works on many levels. They have brought together a unique group of wounded vets who inform our American communities about their war experiences and, more importantly, about how we can all support them as they live with their wounds. It's inspiring for us to learn from these heroes. And it's healing for these vets to tell their stories. I love these guys! Bravo to Tempered Steel!
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Quality Inn & Suites of the Sun Cities
16741 N. Greasewood Street
Surprise, AZ 85374
Phone: (623) 583-3500
Fax: (623) 583-4356
Telephone Pioneers of America Park
First of its kind in the United States, this no-fee park opened in 1988 without barriers for people with handicaps. Privately funded, this facility was built at a cost of $2.5 million. Highlights of this park include a heated therapeutic pool, playground equipment that is wheelchair accessible and two baseball fields. Other amenities include volleyball, tennis and basketball courts. Bring your lunch and use the picnic facilities, which include covered ramadas and grills. Call for further information about special events for the physically challenged.
1946 West Morningside Drive
Phoenix, AZ 85023
+1 602 262 4543
Earn valuable points toward free nights.


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From The CriticsA young, fuzzy-eared bunny happily demonstrates the capabilities of our senses, from hearing birds sing to savoring fruits and vegetables: "Lucky tongue, taste and try this berry pie. It's a blessing!/Cabbage, spinach, bitter or sweet, a joy to eat with salad dressing." Such lively verse and intriguing artwork (a mix of watercolor, ink, and splotchy potato prints) invite children to pay attention to our incredible world. (Ages 2 to 4)
Child magazine's Best Children's Book Awards 2006


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Special Events
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RuPaul's Drag Race Viewing Party8pm. (Untucked 7:20pm)
Host: Dixie Lynn Cartwright
Special #Musical Monday: "Into the Woods" Blu-Ray Release Party 9pm
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MARINA & THE DIAMONDS Album Release Party at PUSH>PLAY
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Making Good Friday…GREAT FRIDAY
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Build a Bonnet Party with Windy City Cylcle Club at Sidetrack
Tuesday, April 7
OUTspoken! LGBTQ Stories. April Edition.
Doors to MainBar open at 6pm. Stories from 7pm.
Saturday, April 11; 5-8pm
Proud to Runway 2015 ... a benefit for Proud to Run Chicago
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CGMC Big Package Auction with Lady Bunny
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Monday, March 30; Open 3pm
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We whip up everything Sidetrack plays and put it on the screens!
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Maria Jeritza
|Maria Jeritza
Maria Jeritza
|Marie Jedličková
6 October 1887
Brno, Austro-Hungarian Empire (now the Czech Republic)
|10 July 1982 (aged 93)
Orange, New Jersey, United States
|Czech [1][2]
|Operatic soprano
Maria Jeritza (6 October 1887 – 10 July 1982) was a celebrated Czech soprano singer,[3][4] long associated with the Vienna State Opera (1912–1935) and the Metropolitan Opera (1921-1932 and 1951). Her sensational rise to fame and spectacular beauty and personality earned her the nickname "The Moravian Thunderbolt".
Jeritza was born in Brno in 1887 as Marie Jedličková. In 1910, she made her debut as Elsa, in Wagner's Lohengrin, at Olomouc. The Emperor Franz Josef heard her and immediately orderded that she be offered a contract at the Imperial Hofoper, Vienna. She created the roles of Blanchefleur in Kienzl's opera Der Kuhreigen (1911), Ariadne in Strauss's Ariadne auf Naxos (1912), the Empress in his Die Frau ohne Schatten (1919), and Hariette/Juliette in Korngold's Die tote Stadt (Hamburg, 1920), though later became famous for her Marietta/Marie, which was also the role in which she debuted at the Metropolitan Opera on 19 November 1921.
On 16 November 1926, she starred in the title role of Puccini's Turandot in its North American premiere at the Metropolitan, where she also created the title or leading soprano roles in Janáček's Jenůfa (1924), Wolf-Ferrari's I gioielli della Madonna (1925), Korngold's Violanta (1927), Richard Strauss's Die Ägyptische Helena (1928), and Suppé's Boccaccio (1931) and Donna Juanita (1932). She was as popular at the Metropolitan as in Vienna, especially as Tosca, Carmen and Massenet's Thaïs. She appeared in an early sound film Grossfürstin Alexandra for which Franz Lehár wrote the song 'Du und ich sind für einander bestimmt'.
After a two-year marriage to a man named Wiener, she married an Austrian Baron, Friedrich Leopold Salvator Freiherr Popper von Podhragy (1886-1953). She married her third husband in 1935, Hollywood mogul Winfield R. Sheehan, who died in 1945. In 1948 she married New Jersey businessman Irving Seery and moved to a mansion in the Forest Hill neighborhood of Newark, New Jersey, where she lived until her death in 1982, at the age of 94. She died in Orange, New Jersey, and was buried at Holy Cross Cemetery in North Arlington, New Jersey. Richard Strauss dedicated his final song Malven to her, but she would not allow the manuscript to be seen by anyone during her lifetime. After her death, the Strauss family allowed it to be performed in public for the first time by Kiri te Kanawa, who has also recorded it.
Jeritza made a number of 78-rpm recordings which testify to the high quality of her voice. Many of these recordings have been released on CD.
- ^ http://bassocantante.com/opera/jeritza.html
- ^ http://books.google.ro/books?id=bLDaqKzJF08C&pg=PT663&lpg=PT663&dq=maria+jeritza+czech&source=bl&ots=wrj9WzUduu&sig=ox19MSEd11s084qyh3zJ1E9U8BE&hl=en&sa=X&ei=HC-GU7e2No2S7Ab5y4GQAw&ved=0CDQQ6AEwAjgK#v=onepage&q=maria%20jeritza%20czech&f=false
- ^ http://bassocantante.com/opera/jeritza.html
- ^ http://books.google.ro/books?id=bLDaqKzJF08C&pg=PT663&lpg=PT663&dq=maria+jeritza+czech&source=bl&ots=wrj9WzUduu&sig=ox19MSEd11s084qyh3zJ1E9U8BE&hl=en&sa=X&ei=HC-GU7e2No2S7Ab5y4GQAw&ved=0CDQQ6AEwAjgK#v=onepage&q=maria%20jeritza%20czech&f=false
External links[edit]
- Maria Jeritza on Find-A-Grave
- Maria Jeritza in the Internet Movie Database
- Erik Eriksson's Brief Biography of Maria Jeritza


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Visit create.airbnb.com »
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community, and it doesn't go unnoticed!
Canadian, living in UK. I am a University lecturer/researcher and an artist at heart, and always have multiple projects on the go... living life fully.
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Anastasia and Jaime have been very good guests. Nice, respectful with a great communication. Highly recommended!
Five stars guest. Kind and clean. Easy communication, positive attitude and, on top of that, I found a perfect apartment when I came back. Defenitely recommended. They will be welcome if they decide to visit Madrid again.
Anastaziya and her family stayed in my apartment over the Christmas and New year's holiday. It was a great pleasure to meet them. They were utterly fantastic guests! Anastaziya was extremely easy to communicate with before and during her stay. She and her family treated my home with the utmost respect, leaving it absolutely spotless. I hope to meet them again and can wholeheartedly recommend them to any airbnb host as perfect guests!
Anastaziya es una chica realmente encantadora, igual que su madre, que la acompañaba.
Un placer haberlas hospedado. Espero que vuelvan algún día y, por supuesto, las recomiendo como huéspedes modélicas.
Just expect to find an amazing guest!Very kind, polite and with a great humor! You will LOVE to have he as a guest!


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Bilstein 5100 questions
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Lifted Cummins Fanatic
Join Date: Feb 2013
Location: Abbotsford, BC, Canada
Age: 22
Posts: 6,235
Gender: Male
Vehicle: 2012 Dodge Ram 3500 CCSB 4x4
Trim Level: Laramie Limited
Color: Mineral Grey Metallic
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Originally Posted by
where can you find the bilstein 5100 shocks for a 2011 2wd model??
Are you looking to use the Bilstein 5100's to level your 2wd? Because that's not possible. I'm not sure what is all out there to level the 2wd's. I think CST makes a 3" level. There's probably few other companies out there as well.
Originally Posted by
Does anyone know what the fronts shocks have to be set at to level out the truck? My truck still sags a little bit in the front
It completely depends on your truck. Not all of them come from the factory at the exact same height. They're all a little bit different. In order to find out exactly where you need them set you should measure your truck front and back and figure out what your rake is. Then you can find out what to set your Bilsteins at. Keep in mind if you set it dead level front and back it will probably look nose high. 0.5" - 1" of rake will look level to the eye.
2012 Ram 3500 Laramie Limited Cummins Build Thread
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iHerb Customer Reviews
Items 1-4 of 4 total
Joint pain
2 people found the following review helpful
Posted by ReviewerIsabella on Feb 09, 2013
My joint pain is more an RSA complaint due to computer overuse etc. I feel this product taken each morning (easy to drink from the fridge) helps sore joints and I like the taste.
1 person found the following review helpful
Posted by Reviewer1192710 on Jul 15, 2013
Very tasty piece. I drink every morning during food. I hope well will strengthen my joints.
good for you
1 person found the following review helpful
Posted by Reviewer1892212 on Oct 20, 2012
but tastes thick - ended up using it in protein shakes so I didn't have to taste it.
Posted by 5674937899721048045 on Apr 18, 2014
Seems to be quite effective and certainly I'm going to buy it again!!!! thank you I-herb!!!
Items 1-4 of 4 total


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Ebola - a year less ordinary
One year on since the Ebola outbreak, Damien Queally, Deputy Regional Director - Programmes for West Africa, reflects on Plan International's evolving response to the crisis.
World Water Day: Making water a priority
19/03/2015 (2.02 mins)
Access to clean water saves lives and is crucial for child and community development. That's why water and sanitation is one of Plan International's top priorities.
Embracing the resilience and strength of India's Daughter
Only by exposing the attitudes and beliefs that result in violence against women can we stop that violence from occurring, blogs Plan's Mary Bridger at the Commission on the Status of Women.
Girls say: Keep my school safe!
Meet some of the girls and women across the world who are working with Plan International to keep their schools safe when disaster hits.
Playing mind games in emergencies
Emotional care should find a central place in disaster settings, blogs Plan's Head of Disaster Preparedness and Response, Unni Krishnan.


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Michael kors watch
New 1.5 ct. Micheal Kors 45 MM Stainless Steel Watch with Custom Set Diamonds never been worn it comes with a box if you need more pictures please contact me ))
New 1.5 ct. Micheal Kors 45 MM Stainless Steel Watch with Custom Set Diamonds never been worn it comes with a box if you need more pictures please contact me ))
Received as a gift already have the same one. Comes with box
Hello friends this is brand new Tag huer watch for sale today . Not a scratch on it . In perfect working condition Most amazing model of ray ban because of its dial . Golden dial just for gold lovers . It has strap instead of chain because of less
Hey everyone, here is my brand new Rado Jubile Watch for sale in black and grey colour . I have 2 watches so you can choose which ever you want. Rado is knows for its reliable and luxury watches. This is Rado jubile and it's very well known and popul
Brand new Michael Kors Silver Ladies Watch - still has the protective seal over the watch. Quick sale needed hence low price Text/ring for enquiries 07956008497 Can I arrange delivery(UK ONLY) or feel free to collect
INCREDIBLE PRICE!!! Rolex Explorer 2 ref.16570 black dial. Year: 2000 It's part of my private collection of luxury watches. This watch is in mint conditions recently serviced and sold with original box, certificate & 2 years warranty start
LAST PIECE!!! INCREDIBLE PRICE!!! Rolex Gmt Master 2 aka Sophia Loren is a fantastic Rolex Model with a very RARE transitional reference number (16760). Rumors say that during the production of this model was used the bigger case of the Sea Dwe
Hi, Up for sale, a Ladies Michael Kors Rose Gold Watch which is Brand New (sorry, no box...can't find it due to recent house move). The protective seal is still on the watch so can be given as a gift. Collect from South East London(Woolwi
New Hublot Watch don't miss out can be posted or collected from woodgreen N22 WhatsApp 07769256986 for instant reply
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Both in good working order, please feel free to drop by and view and contact me any questions, Open to offers
Brand new watch comes with plain gift box. Can be posted or collected from woodgreen N22 WhatsApp 07769256986
Unisex, on-trend, stylish, white watch. Lightweight - makes an excellent gift/stocking filler. Watch Specifications: Brand Name LTD Watch Part Number LTD-0201PB Item Shape Round Display Type analogue Clasp Type Fold-over Clasp C
New Rolex -- Automatic -- Boxed with Papers Rolex Watch With papers and box 100 Can be posted or collected from woodgreen N22 WhatsApp 07769256986
GOOD CONDITION AND FULLY WORKING IT USED BUT STILL IN GOOD CONDITION IT COME WITH ORIGINAL BOX Product Specifications Watch Information Brand, Seller, or Collection Name Marc by Marc Jacobs Part Number MBM2020_WW Case material Sta
Sealed box moto 360 SMARTWATCH black colour with receipt can come t to all devices
Hi this is my 2006 men's Rolex date just has all the paper work and box's has the white gold fluted bezel in good condition for its age very nice looking watch
A gorgeous watch, all in working order and no damage. Has been worn about 4 times hence why I am selling it
A collection of 3 Fob Watches and Chains all new and in perfect Working Order. A New Milano Unisex Watch Has yellow silicone rubber Strap a very strong Watch and in perfect working order. A New Miniature Brass Carriage Clock New and in perfect wo
brand new never worn pick up in stratford no box please no time wasters check out my other ads 40 each or 3 for 100
Massive Job Lot for Market Stall Holders or Car Boot Sellers easily Treble your Money. Brand: 5 New Nike Watches & 18 New Xiaoya Cat Watches + 1 New Mauve Milano Watch + 1 New Silver Charm Bracelet All should have Sold for around £10.00 Each they


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Make the most of your screen captures. TinyTake gives you all the tools to capture, annotate, and share screen captures and screen casts for free.
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John Bostock's curator insight, August 26, 2013 6:58 AM
This looks an interesting alternative to Jing, with better tools for annotation.
technologytoteach's curator insight, August 28, 2013 2:15 PM
Will try this out, just downloading so unable to comment on its usefulness
Terheck's comment, September 1, 2013 4:54 AM
You can also try Greenshot : very nice, free and Open Source : http://getgreenshot.org/


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Main Content
This item ships within one business day.
$4.99 flat rate shipping. See other shipping options.
Your mother always told you that if you're on time, you're late — that's why you get to the Blue Jackets game a few hours early! You don't want to miss any of the action on the ice with your gal pals. You can spend more time tailgating and less time worrying about what to wear when you toss on this unbelievably team-spirited First Down crew tee! Featuring a distressed printed team name, the Columbus logo and the team establishment year on the front, this shirt has everything you need to represent your Blue Jackets to the fullest on game day!
- 100% Cotton fabric
- Distressed screen print graphics
- Imported
- Officially licensed NHL product
- Tagless collar
Reviewed by 1 customer
- Quality Construction
- Shows Off Team Pride
- Stylish
Best Uses
- Anytime
- At The Game
- Watching The Game on TV
Comments about Columbus Blue Jackets Ladies First Down Crew T-Shirt - Red:
I'm a huge Jackets fan and I like the use of red for this shirt. The fit is true to size, the material soft, and I like the design on the shirt.
- Sizing:
- Feels true to size
Special event items are produced by manufacturers only after the outcome of a game or event. These are advanced sale items and will ship immediately after they are received in our warehouse.
Manufacturer direct items are shipped directly from the manufacturer. These items are not available for international or expedited shipping.
Customized items can be personalized with options such as your name, your favorite number, and/or designs. Some options may be limited by league rules.


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new pond owner what to do for winter
gdnh(5)October 13, 2012
Built the pond this late summer, 30 square feet, seven goldfish. Have a used pump bio filter system that seems to pour a trickle of water into the pond but keeps water clean. I tried to catch them (fish) to bring inside (before I got the pond they lived for years in large plastic tubs) but no sucsess. I doubt that water flow would continue in the winter as so measly. Should I get a de icer I hear they are very expesnibe? Other options?
gdnh, The small upper pond will likely freez near solid and stop the trickle of water. To winter fish in the pond, you need at least 24 inches of water depth and to maintain a hole in the ice to let gass exchange from the pond water.
Please review the other resent post topic, about deicer question.


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I don't Break the rules, I Modify them.
Fine craftsmanship! I sure it will shoot as good as it looks. Are the Vortex scope rings heavy steel like Warner rings or lighter like Talley rings?
Very nice looking and I like the Vortex scope! Keep us posted on how it shoots!
Looks pretty sweet!
Your the one with a flower next to their new gun! HAHAHA
"Now two flags fly above my land that really sum up how I fee. One is the colors that fly high and proud The red, the white, the blue. The other one's got a rattlesnake With a simple statement made "Don't tread on me" is what it says and I'll take that to my grave. Because this is me. I'm proud to be American and strong in my beliefs. And I've said it before but I'll say it again 'Cause my family's always fought and died to save this land. And a country boy is all I'll ever be."
Nice rifle
Sweet. I really the bell and carlson medalist stock.


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Secretsundaze, the great London soiree devoted to top-shelf (and utterly underground) house and techno, returns to Gotham for another big boat bash, tossed in conjunction with Blkmarket Membership. Secretsundaze residents Giles Smith and James Priestley will be manning the decks, along with talented Berlin musician/producer/DJ Sven Weisemann.
Blkmarket Membership: Secretsundaze Boat Party
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Articles by Lawton Hansen
Oath calls to defend Constitution not Bible
In response to Catherine Jarvis' Aug. 27 letter headlined, "Same-sex marriage a destructive notion:" Jarvis' argument against same-sex marriage and the possibility of the Pentagon granting federal marriage benefits to service members in gay marriages is derived from a combination of numerous citations of the Bible and the conviction that a fundamentalist reading of the Bible is intensely relevant to social issues involving homosexuality. READ MORE
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State Budget
Dewhurst & Williams To Lay Out Budget Draft
Texas Lt. Gov. David Dewhurst and Senate Finance Chairman Tommy Williams are expected to lay out the draft state budget, revealing the Republican leaders' spending priorities for the next two years.
Dewhurst Ready To Tap Rainy Day Fund
Lt. Gov. David Dewhurst said, with the state's population set to double in the next 40 or 50 years, it is time to tap the Rainy Day Fund, which could be nearly $12 billion by 2015.
State Lawmakers Take Conservative Budget Posture
Politicians in Washington may be talking about compromising on the federal budget, but in Texas, Republicans are taking an early, hardline stance on state spending.
State Budget Capped At $77.9B For 2014-15
The Texas Legislative Budget Board set a $77.9 billion cap on state spending Thursday for the 2014-15 budget year, a 10 percent increase above the current discretionary spending limit.
Texas Lawmakers Look At State Finances
Texas lawmakers are meeting Wednesday to take another look at the state's finances ahead of what could be another budget-cutting legislative session that starts in January.
Higher Registration Fee Could Fund New Roads
The Texas Association of Business believes that, if the state raises registration fees by $50 per vehicle, and dedicates that money to road projects, it would create an additional $16 billion.
State Budget Leaders To Get Financial Update
The Texas Comptroller's office is giving budget leaders a rundown of the state's financial picture, just months before what will likely be another lean legislative session.
State Expects $5 Billion In Extra Revenue
The Texas comptroller's office said that it now expects the state to collect at least $5 billion in unanticipated revenue during the present two-year budget cycle.
Straus Calls For Truth In State Budgeting
Texas House Speaker Joe Straus has called for an end to an accounting practice that masks how taxes and fees are really spent.
State Agencies Told To Propose 10 Percent Cuts
State agencies were told to shave costs by another 10 percent, despite growing tax revenues that have raised hopes of restoring freshly slashed services and jobs across Texas.
State Lawmakers Hear Update On Medicaid
Texas lawmakers on Monday will get a briefing on the current status of Medicaid, the health insurance program for the poor and disabled.
Perry In Houston To Deliver Economic Address
Governor Rick Perry is delivering an economic speech he promises will detail key Texas budget principles for next year and beyond.


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Hi Everyone
Picking up a couple of fat bikes in a week or two. We live in the Kawartha's North East of Peterborough, seconds on a bike from the sled trails. Do fellow riders use the sled trails in Ontario? I know it is illegal to 4 wheel on them even when they are on crown land.
Any info would be great, thanks.
Cheers, Bill
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Isn't it time you spent time with people as interesting as you?
Be yourself. You're right where you belong.
He says tomato. She says tomahto. And that's exactly what makes things interesting around here. By embracing everyone's uniqueness, we've created a community where everyone feels like they belong. That's why here at The Reserve at Thousand Oaks, you can choose from Thousand Oaks senior care options including senior living, living that offers assistance with your everyday routine or respite care. Plus our wide range of amenities and adventures means there's always something to inspire, excite, relax or intrigue. Why let another day go by without learning the Argentine tango? Without taking up watercolors? Without seeing Maui? Don't worry, we have the details covered. All you have to do is enjoy.