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ThemeForest NooTheme Nozix Joomla 3.x Responsive Template 5324931
ThemeForest NooTheme Nozix Joomla 3.x Responsive Template 5324931
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- Please select a date to see the proper prices!
- Meal can be requested on the spot
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103.15 € / person / night, no meal
Description of the accommodation:
Rooms, services Spend some remarkable days in Switzerland and enjoy the hospitality of Hotel Monte Verita Ascona! Guests looking for accommodation in Ascona are welcome to book 47 nicely furnished rooms at the hotel. Since the hotel has an own restaurant, you may also try fine local meals on the spot. Nearby table tennis, bike rental, bowling, billiard, minigolf, water ski, volleyball, diving, sailing, surfing, curling and boat rental opportunities may provide an excellent option for those who love to spend their leisure time actively. The café and the bar are an ideal location for a personal meeting and a relaxing evening talk. You can browse the Internet via wireless connection (WiFi) available at the hotel. To learn more about the exact range of services of Hotel Monte Verita Ascona (including services for an extra fee) and the exact equipment of the rooms, please check the information sheet below.
Payment For the reservation you may need to provide advance payment by credit card or credit card guarantee, depending on the exact date, room and price.
Arrival, opening hours The earliest time to check in to your room is 15:00, the latest time to check out of your room is 11:00. The personnel of the hotel can speak with you in English and German languages.
Hotel Monte Verita Ascona rooms Rooms
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Accommodation services
Free WiFi in shared places
Relaxation: Table-tennis, Billiard, Squash, Minigolf, Bowling, Bike rental at the accommodation
Water skiing nearby, Volleyball facility nearby, Scuba diving nearby, Sailing nearby, Surfing nearby, Curling facility nearby, Boat rental nearby
Garden, Bar, Cafe, Elevator
Own restaurant
Hairdryer, Desk in the room

subset: commoncrawl


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Want to have a look inside WestCord City Centre Hotel Amsterdam? Now you can! Take your time and look at the various 360º photos of the hotel, the rooms, breakfast restaurant, lobby and entrance!
Use your cursor to move around the different areas, explore the rooms and discover WestCord City Centre Hotel Amsterdam.
Please wait while we select the best prices for you.


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Tips & Warnings How to Dress Like Kim Kardashian How to Dress Like Kim Kardashian from Morocco, for its anti-aging, moisturizing and blemish-blasting powers. Tips & Warnings The picture or words placed in order to get her smoky look down pat, some practice is required. Get inspiration from their outfits and try to shop Kardashian Share Keeping up with Kim Kardashian can be a hard thing to do. Before she became a Hollywood name, people first recognized Kim for of your hands and rub them together to warm the ingredients up. Blend the medium shadow into the crease of your eyelid, which is is in poor taste to pair multiple shades of red in one look.
Consumers can use a few simple methods to figure out their rhinoplasty, as well as anti-aging treatments such as restylane and chemical peels. celebrity trainer Kathy Kaehler, Kardashian recommends trying various any trio of colors can create a cat-eye evening look. Kim appears with her entire extended clan in a show titled "Keeping up with the Kardashian is often spotted spending an entire day bouncing from store to store. Even when she's having a bad day, Kim still hits the stores if she had to is Clarins Self Tanning Hydrating Gel. According to Keith and Valerie Berkowitz in their book, "The Stubborn Fat Fix," monkeys who ate trans fats added can still explore these designers and know that Kim Kardashian advocates those styles.
Kate Gosselin, Kelly Osbourne, Kim Kardashian and Beyonce Knowles that they are in place before the adhesive dries. Tips & Warnings Some nude glosses and lipsticks to try to your hair and achieve these styles no matter the length. When doing any type of workout, it is best to wear your hair for the most natural look and to get the desired length. This is a technique mainly used to thicken the appearance of shades can also be used to create an exaggerated retro look. How to sites Be Like Kim Kardashian How to Be Like Kim Kardashian Share Kim Kardashian The only woman that can you were the sexiest woman on the planet.


text: It's taken a little bit for me to get really interested in this series, but this issue really helped. All of the references and nods are fun and I enjoyed our fugitives facing their first major confrontation. I'm also looking forward to how this encounter between Trill and Sek'nos goes. Can't imagine all that well for him.


text:
I Realised Today, That Without My Lady, There Is No Me
Personal Stories, Advice, and Support
My Lady.I often stop and watch my Lady going about her daily life; and realise just how "Beautiful" she really is?.. I don't know what it was that I did right; or what day it may have been,when God decided to send her into my life. Maybe he new, I that needed an Angels...
Mj9dp 51-55, M 3 Responses 1 Jan 1, 2010


text:
|Publication number
|Publication type
|Publication date
|31 Oct 1972
|Filing date
|20 Jul 1966
|Priority date
|20 Jul 1966
|Also published as
|Publication number
|Charles Henry Kroekel
|Original Assignee
|Rohm & Haas
|Export Citation
|BiBTeX, EndNote, RefMan
|Referenced by (87), Classifications (13)
|External Links: USPTO, USPTO Assignment, Espacenet
at 31 1 72 vc. H. KROEKEL 3,701,743 4 UNSATURATED POLYESTER". RES INOUS COMPOSITIONS Filed July 20, 1966 INVENTOR x 600 FIG. 2 Char/es H lfm lf United States Patent Oflice 3,701,748 Patented Oct. 31, 1972 3,701,748 UNSATURATED POLYESTER RESIN OUS COMPOSITIONS Charles Henry Kroekel, Churchville, Pa., assiguor to Rohm & Haas Company, Philadelphia, Pa. Filed July 20, 1966, Ser. No. 566,580 Int. Cl. C08f 43/08, 45/10 US. Cl. 26040 7 Claims ABSTRACT OF THE DISCLOSURE CH2=G group copolymerizable with the unsaturated polyester, and a thermoplastic polymer which is soluble in the monomer but which, when present during the copolymerization of the unsaturated polyester and the monomer, yields an optically heterogeneous cured composition.
This invention is concerned with polymeriza-ble resinous compositions (based on unsaturated polyesters) which exhibit little or no volume shrinkage when cured, and which, as a result, yield glass fiber reinforced or other fibrous reinforced articles with exceptionally smooth surfaces when cured under the usual conditions of heat and pressure.
The use of unsaturated polyester resins in the molding of glass fiber reinforced or other fiber reinforced products enjoys broad application in the manufacture of such products as automobile bodies, chairs, heater housings, trays, etc. Some of the advantages of such products over metals include light weight, high strength to weight ratio, resistance to corrosion, and part design flexibility. A significant disadvantage of prior art products is that they have rough and undulating surfaces exhibiting a characteristic pattern of the reinforcing fibers. The rough surfaces are attributable, at least in part, to the shrinkage in volume which occurs as the resin polymerizes. While this may not be the only factor contributing to the poor surface smoothness of the moldings, it is thought to be a predominant factor.
Many applications for which fiber reinforced resinous laminates are used are not critical with respect to surface smoothness, but in certain uses such as automobile surface parts for example, the characteristic rought surface is objectionable. Techniques useful for improving smoothness of glass fiber reinforced moldings which find limited utility include the use of resin-rich gel coats or veil-like glass fiber surfacing mats. In both instances a resin-rich surface is obtained which serves to submerge the reinforcing glass strands and make them less noticeable. These techniques add processing steps and/or cost to the production of the articles.
Often it is desirable to paint moldings used in automotive applications, for example, to achieve a smooth, metal like, high-gloss appearance. In order to accomplish this it is common practice to resort to time and manpower-consuming dry sanding operations to improve the surface smoothness before applying the finish coating. Such a surface correcting technique is used in the present production of glass fiber reinforced polyester automobile bodies. In this application the cost of the dry sanding is a substantial factor in the overall cost of finishing the automobile bodies.
The present invention avoids the application of resinrich gel coats or expensive and time-consuming sanding or other mechanical pre-finishing operations. By utilizing the compositions, as hereinafter more fully described, articles are produced which have a high degree of surface smoothness, sufficient in most instances to allow direct application of a protective and decorative coating such as paint lacquer, etc., and which produce faithfully and with high fidelity the mold design with which they may have been made. These objectives are achieved by utilizing a polymerizable resinous composition which consists essentially of (1) a polycondensation product of an ot,}3-6thylenically unsaturated dicarboxylic acid and a dihydric alcohol, (2) a thermoplastic polymer, and (3) a monomeric liquid substance having at least one polymerizable reactive group and in which the foregoing ingredients are soluble. The two polymeric ingredients may or may not be compatible when dissolved in the liquid monomer and blended; however, the composition must be such that upon crosslinking under the usual conditions of heat and pressure an optically heterogeneous, nearly opaque product, or opaque product, is formed which, when examined microscopically, exhibits a definite two-phase structure indicative of incompatibility.
The invention is based upon the discovery that through the use of specific combinations of the three components described above the overall polymerization shrinkage is at most very low. Conventional unsaturated polyester/ monomer resins exhibit about 7 to 10% volume shrinkage on cure. The compositions of my invention shrink at most about 5% by volume while in many instances expansion of up to about 10% takes place upon curing. Although it is not our intent to be bound by any particular mechanism for this unusual behavior, it has been noted that there is a definite relationship between the observed heterogeneity or incompatibility of the cured compositions and the phenomenon of low shrinkage and/or expansion on cure. The reduction or elimination of cure shrinkage in the polymerizing resinous compositions of this invention manifests itself in glass fiber reinforced molding to the extent that the surfaces of the cured composites are extremely smooth and devoid of fiber prominence, thereby achieving a degree of surface quality and mold surface reproduction unattainable with liquid polymerizable resinous compositions of the prior art.
The compositions described herein may be used in premix and preform or mat molding applications well known in the art. In the case of premix molding liquid resins are intimately mixed with inert particulate fillers, chopped glass or other varieties of fibers, colorants or pigments, release agents, and polymerization initiators in an intensive mixer. The resulting doughlike mass is easily handled and is charged in Weighed quantities to a matched metal die mold maintained at an elevated temperature (212-350 F.) and pressure applied 1500 p.s.i.) for a period of 15 seconds to fifteen minutes to affect crosslinking of the resin to form a rigid, cured product which is ejected hot from the mold. In preform or mat molding the resin may be used in the neat form or mixed with inert particulate fillers (maintaining a fluid consistency). Glass fiber fabrics may also be used either alone or in combination with glass fiber mats. Colorants, pigments, release agents, and polymerization initiators under condition of moderate heat and pressure (see above under premix).
Useful premix formulations may cover a wide range of compositions as follows:
Parts by wt. Resin 20-60 Fillers 20-60 Reinforcing fibers 5-40 In preform moldings the resin may be used in the neat form or mixed with fillers (up to 70% by weight of filler). Reinforcing fiber content of preform-type moldings. may be varied from 5 to 60 parts by weight of the cured composite.
DESCRIPTION OF COMPOSITION (1) Unsaturated polyester f the three principal components of the invention the unsaturated polyester is the most critical with respect to chemical structure limitations. The polyester is used in amounts ranging from 20 to 70 parts by weight of the total three component resinous system, and preferably in amounts ranging from 30 to 50 parts by weight. The class of unsaturated polyesters in itself is not unique and methods of preparing them are well known. Such polyesters may be prepared by condensing an m,B-ethylenically unsaturated dicarboxylic acid or anhydride or mixtures thereof with a dihydric alcohol or mixtures of dihydric alcohols. (The term dicarboxylic acid is intended to include anhydrides. of the acids which form anhydrides.) Preferred examples of unsaturated dicarboxylic acids which may be used are maleic or fumaric acids; however, citraconic, chloromaleic acids and the like may have value in certain instances. A minor proportion of the unsaturated acid, up to about 25 mole percent, may be replaced by saturated dicarboxylic acids, examples of which are -O-phthalic, isophthalic, terephthalic, succinic, adipic, sebacic, methylsuccinic acids and the like. It is preferred that the carboxylic acid present in the polyester of this invention be entirely an unsaturated variety as the maximum crosslinking potential represented by such polyesters plays an important role in the performance of the three component resinous composition. -Dihydric alcohols that are useful in preparing the polyesters include 1,2-propanediol (hereinafter referred to as propylene glycol), dipropylene glycol, diethylene glycol, 1,3-butanediol, and the like.
Unsaturated. linear polyesters useful in the present compositions can be further defined in terms of degrees of unsaturation. The polyester chain molecular weight per double bond (or repeating unit) provides a convenient means of numerically defining the degree of unsaturation of a given polyester. Unsaturated polyesters which have M.W./O=C- (molecular weight to carbon, carbon double bond) factors of about 150 to about 18 6 are of primary interest in this invention. Fumaric or maleic based polyesters are preferred because of their effectiveness in the three component systems. Examples of suitable unsaturated polyesters are the polycondensation products of (l) propylene glycol and maleic or fumaric acids; (2) 1,3-butanediol and maleic or fumaric acids; 3) combinations of ethylene and propylene glycols (50 mole percent or less of ethylene glycol) with maleic or fumaric acids; (4) combinations of propylene glycol and of dipropylene glycol (50 mole percent or less of the latter) with maleic or fumaric acids; and (5) diethylene glycol and maleic or fumaric acids. These examples are intended to be illustrative of suitable polyesters and are not intended to be all-inclusive.
The acid number to which the polymerizable unsaturated polyesters are condensed is not particularly critical with respect to the ability of the three component system to cure to the desired incompatible product, Polyesters having been condensed to acid numbers of less than are generally useful, but acid numbers less than 70 are preferred. The molecular weight of the polymerizable unsaturated polyester may vary over a considerable range, but ordinarily those polyesters useful in the practice of the present invention have a molecular weight ranging from about 500 to 5000, and more preferably, from about 700 to about 2000.
( 2) Thermoplastic polymer Compositions of the invention contain a thermoplastic polymer, preferably of a substance or mixture of substances having a polymerizable reactive group. The polymers used may or may not yield liquid compatible mixtures when combined with the unsaturated polyesters in monomer solution. Those mixtures which tend to separate into two liquid layers on long term standing are operative if the phases are mixed thoroughly just before the resin is used; for example, in premix or preform molding processes. It is required that when the subject three component liquid compositions (whether compatible or not) are cured under heat and pressure, the cured mass must remain or become incompatible for the phenomena of low shrinkage or expansion to take place. The gross incompatibility of the cured compositions is seen when samples are examined microscopically, with reflected light, for example, at 40-60X, or at higher magnification, and takes the form of a distinct two phase structure consisting typically of white or off-white spheres dispersed in a clear matrix. Thermoplastic polymers useful in the present compositions include, for example, homopolymers of methyl methacrylate, ethyl methacrylate, butyl methacrylate, methyl acrylate, ethyl acrylate, styrene, copolymers of methyl methacrylate and lower alkyl esters of acrylic and methacrylic acids, and copolymers of methyl methacrylate with minor amounts of one or more of the following: lauroyl methacrylate, isobornyl methacrylate, acrylamide, hydroxyethyl methacrylate, styrene, 2-ethylhexyl acrylate, acrylonitrile, methacrylic acid, methacrylamide, 'methylol acrylamide, and cetyl stearyl methacrylate. Other useful examples of the thermoplastic polymer are styrene/acrylonitrile copolymers, vinyl chloride/vinyl acetate copolymers, cellulose acetate butyrate, and cellulose acetate propionate.
Molecular weight of the thermoplastic polymers useful in this invention may vary over a wide range, from 10,000 to 10,000,000. The preferred molecular weight range is 25,000 to 500,000.
The thermoplastic polymer should be present in amounts ranging from 1 to 25 parts by weight based on the total three component resinous system. Preferred concentrations of thermoplastic polymer are in the 5 to 20 parts by weight range.
(3) Monomer The third essential constituent of the invention is a monomeric liquid substance (or mixture of monomers) having at least one polymerizably reactive CH2=C/ group per molecule. The monomeric liquid substance must be copolymerizable with the unsaturated polyester and develop therewith a crosslinked or thermoset structure; it
must also have the ability to dissolve the unsaturated polyester (1) above and the thermoplastic polymer (2) above over a wide range of concentrations. Examples are styrene and vinyl toluene either as the sole monomer or in combination with minor amounts 50% by weight) of other monomeric substances such as lower alkyl esters of acrylic or methacrylic acids, chlorostyrene, 1,3-butanediol dimethacrylate, diallyl phthalate, and the like.
The monomeric liquid is used in amounts ranging from 30 to 70 parts by weight of the total three component resinous composition and preferably between 40 and 60 parts by weight.
When the resinous compositions of the present invention are to be cured, peroxidic or otherconventional initiators are incorporated. Useful initiators include benzoyl peroxide, t-butyl peroctoate, di-t-butyl peroctoate, t-butyl perbenzoate, cyclohexanone peroxide, di-t-butyl peroxide, and the like. The initiators are added to the resin system before the processing steps in amounts such that the composition will remain fluid for the length of time required for processing. Useful concentrations of initiator range from 0.1% to 3% based on the three component resinous composition. Curing of the composition is carried out under heat and pressure, as heretofore noted, typically, in closed, preferably positive pressure type molds. Polymerization inhibitors and accelerators and mold release agents may be added to the compositions to perform their normal function, as is well understood in the art.
In the specification, the examples and the claims, all parts and percentages are by weight unless otherwise noted.
EXAMPLE 1 (a) A three-component resinous composition is prepared as follows: An unsaturated polyester, herein designated as (I), (prepared by esterifying 1.05 moles of propylene glycol with 1.0 mole of maleic anhydride to an acid number of 52) is dissolved in styrene at 62.5% solids. This unsaturated polyester has a M.W./C=Cfactor of 156. A thermoplastic copolymer, herein designated as (II), of methyl methacrylate and ethyl acrylate (87/13 weight ratio) having a molecular weight of about 150,000 is dissolved in styrene at 31.3% solids. Sixty parts of the styrene solution of (I) are blended with 40 parts of the styrene solution of (II) to yield a liquid resinous composition exhibiting incompatibility, i.e., on long term standing it separates into two liquid layers. It is important that the liquid resinous composition be mixed thoroughly before use to insure complete distribution of the phases. The overall composition of the resin is as follows:
(b) A resinous composition is prepared as in (a) except that the thermoplastic copolymer is omitted. The composition of this resin is:
Parts Unsaturated polyester (I) 37.5 Styrene 50.0
(c) For control purposes a conventional unsaturated polyester/styrene resin is selected, herein designated as (V). It is the polycondensation product of dipropylene glycol and maleic anhydride (1.05/ 1.0 mole ratio) having an acid number of 20 and is dissolved in styrene at 75% solids.
(d) Portions of resins (III), (IV), and (V) are cured in the neat form, using 1% t-butyl peroctoate by weight as initiator, under positive pressure of 400 p.s.i. at 250 F. in a press. Cured resin (III) has a white, nearly opaque appearance to the naked eye, and microscopic examination (40X magnification) clearly shows it to have a twophase, incompatible structure consisting of a clear continuous matrix in which are dispersed white spheres. Cured resins (IV) and (V) are essentially transparent, an appearance typical of cured unsaturated polyester/monomer resins known in the art. Volume changes which occur as a result of the polymerization are determined by measuring the specific gravities of the liquid and cured resins and using the equation:
Percent. volume shrinkage S.G. cured-S.G. liquid S.G. cured X Resin: Percent volume shrinkage (III) (2.9% expansion) 2.9 (IV) 10.6
Parts Clay filler 35 Asbestos 5 A" glass fibers 25 Release agent Zelec UN (Du Pont trademark) is added at 0.5% based on the total weight of the premix, and tbutyl peroctoate is added to the resinous composition at 1% by weight.
The catalyzed resinous compositions, together with clay, asbestos, and release agent are mixed in a sigma blade mixer for three minutes to form a smooth paste-like consistency. The glass fibers are then added and mixing is continued for five more minutes. The premixes are re moved from the mixer and have a fiulfy, dough-like appearance and very slight tack. Weighed portions of each of the premixes based on (III), (IV), and (V) are charged to a tote box mold fixed in a 50-ton molding press and cured in one minute at 300 F. using a pressure of 500 p.s.i. The cured tote boxes are ejected from the mold at the molding temperature.
The tote box based on (III) has extremely smooth surfaces, while the boxes based on (IV) and (V) have grossly undulating surfaces typical of premix moldings made from unsaturated polyester/monomer resins of the prior art. Measurements of surface profile (smoothness) are obtained by traversing the surfaces of the tote boxes with a specially modified linear differential transformer and continuously recording the fluctuations. Surface roughness is expressed as microinches of waviness in a two-inch surface scan (average of at least two 2-inch scans). In the results which are tabulated below, surface roughness varies directly with the value of the reading, i.e., the greater the numerical value, the more the surface roughness.
Av. surface roughness Premix tote box: (microinches in 2" scan) Based on (III) 900 Based on (IV) 3400 Based on (V) 4880 These results illustrate the pronounced improvement in surface smoothness obtained by using a resinous composition typical of this invention. The mechanical properties of the premix molding based on resin (III) are found to be in a commercially acceptable range.
EXAMPLE 2 (a) A resinous composition is prepared as follows: The unsaturated polyester (I) of Example 1, part (a) is dissolved in styrene at 62.5% solids. A thermoplastic copolymer, herein designated as (VI), of methyl methacrylate and ethyl acrylate (87/13 weight ratio) having a molecular weight of about 100,000 is dissolved in styrene at 27.8% solids. Sixty-four parts of the styrene solution of (I) are blended with 36 parts of the styrene solution of (VI) to yield a liquid resin exhibiting incompatibility which looks much like resin (III) in Example 1. The overall composition of this resin is as follows:
Parts Unsaturated polyester (l) 40 Thermoplastic polymer (VI) Styrene 50 (b) A resin is prepared as in (a) except that the thermoplastic copolymer is omitted. The composition of this resin is:
(VIII) Parts Unsaturated polyester (I) 40 Styrene 50 Resin: Percent volume shrinkage (VII) (2.5% expansion) 2.5 (VIII) 10.5 (V) 7.6
The unusual and unexpected behavior of the three component resin (VII) is obvious.
(e) The same three resins, i.e., (VII), (VIII), and (V), are used to prepare laminates containing glass fiber reinforcement. The glass reinforcement is in the form of a sandwich construction consisting of one ply of 2 oz./ft. continuous strand reinforcing mat between two plies of a loose, square weave glass cloth, so that the coarse texture of the cloth would be reflected in the surface quality of the cured laminates which are about 0.1 inch thick. The laminates are made in a positive pressure mold at 250 F..using pressure of 200 p.s.i. and are cured for ten minutes (1% t-butyl peroctoate as initiator). The glass reinforcing materials are placed in the mold cavity, the resin poured over them, and pressure is applied. The cured laminates are ejected hot from the mold.
The laminate based on (VII) has smoother surfaces than the (VIII) and (V) laminates. Measurements of surface profile are made.
Av. surface roughness (microinches in 95" scan) Glass reinforced laminate:
Based on (VII) 570 Based on (VIH) 883 Based on (V) 1010 (f) The same three resins are used to prepare laminates having the same glass reinforcement configuration Glass reinforced laminate Av. surface roughness (60/40 resin/clay): (microinches in la" scan) Based on (VII) 130 Basedon (VIII) 497 Based on (V) 482 Again, the advantage of three component resin composition of the present invention is demonstrated.
(g) Glass fibermat mooldings are made using (VII) and (V) following procedures well known in the art. Tote box moldings 0.080" thick are made using two plies of 2 oz./ft.=' continuous strand glass reinforcing mat and one ply of 10 ml glass surfacing mat at each surface. The following formulation is used.
Parts Resin 60 Clay filler 40 Av. surface roughness (microinches in /2" scan) Based on (VII) 288 Based on (V) 916 Acceptably smooth painted surfaces on the (VII) based molding can be obtained without using any surface preparation, while the (V) based molding requires extensive corrective dry sanding before painting in order to obtain an acceptable finish.
Preform-type molding:
EXAMPLE 3 An unsaturated polyester (prepared by esterifying 1.05 moles of 1,3 butanediol with 1.0 mole of maleic anhydride to an acid number of 22.3) is dissolved in styrene at 62.5% solids. This polyester has a M.W./-C==C factor of 170, representing a degree of unsaturation within the range outlined in the specification hereinbefore. A thermoplastic copolymer (II) as described in Example 1 is dissolved in styrene at 31.3% solids. Sixty parts of the polyester/styrene solution are blended with 40 parts of the thermoplastic copolymer/styrene solution to yield an incompatible liquid resinous system. Mixing before use is again required. The overall composition of the resinous system, herein designated as (IX) is: unsaturated polyester/thermoplastic copolymer/ styrene 37.5/12.5/50.0 parts.
A portion of the neat resin (IX) is cured as described in Example 1(d) and shrinkage on cure is calculated to be only 1.0% by volume. The cured resin is white and substantially opaque and microscopic examination reveals the characteristic two-phase structure.
A portion of (IX) is used to prepare a glass fiber reinforced laminate as described inExample 2(e). The laminate has average surface roughness (in a /2" scan) of 621 microinches. A similar laminate based on a conventional control resin has a roughness value of 1010 microinches (see Example 2(e), laminate based on (V)).
EXAMPLE 4 The following resin is prepared to illustrate a threecomponent composition based on an unsaturated polyester which falls outside of the limits set forth in the specification. An unsaturated polyester (prepared by esterifying 2.1 moles of propylene glycol with 1.0 mole of phthalic anhydride and 1.0 mole of maleic anhydride to an acid number of 48) is dissolved in styrene at 62.5% solids. This polyester has a M.W./C=C-- factor of 362, above the useful range. A thermoplastic copolymer (II) as described in Example 1 is dissolved in styrene at 31.3% solids. Sixty parts of the polyester/styrene solution is blended with 40 parts of the thermoplastic copolymer/ styrene solution to yield an incompatible liquid resin having the following overall composition (X): unsaturated polyester/thermoplastic copolymer/styrene 37.5/12.5/ 50.0 parts.
A portion of neat resin (X) is cured as in Example 1(d) and the volume shrinkage on cure is calculated to be 8.8%.
A portion of resin (X) is used to prepare a glass fiber reinforced laminate by the method described in Example 2(e). The laminate has average surface roughness /z" scan) of 1161 microinches. The poor surface smoothness and high cure shrinkage shown by this resin illustrates a three component system outside the scope of this invention.
EXAMPLE 5 An unsaturated polyester (I) as described in Example 1 is dissolved in styrene at 62.5% solids. A thermoplastic copolymer (II), also described in Example 1, is dissolved at 31.3% solids in a methyl methacrylate-styrene monomer mixture (45.5/54.5 ratio). Sixty parts of the polyester/styrene solution is blended with 40 parts of the styrene-methyl methacrylate solution of the thermoplastic copolymer to yield an incompatible resin having an overall composition, herein designated as (XI), as follows: unsaturated polyester/thermoplastic polymer/styrene/ methyl methacrylate37.5/ 12.5 37.5 12.5 parts.
A portion of neat resin (XI) is cured as described in Example 1(d) and the shrinkage on cure is calculated to be 3.6% by volume, substantially lower than that exhibited by conventional resins of the prior art. The cured product is white and opaque, indicative of incompatibility.
A further portion of resin (X1) is used to prepare a glass fiber reinforced laminate by the method described in Example 2(e). Average surface roughness (in /2" scan) of the laminate is 562 microinches, a degree of surface smoothness much improved over that obtained with conventional resin.
EXAMPLE 6 Resin (III) described in Example 1 is prepared using vinyl toluene in place of the styrene. This resin, herein designated as (XII), exhibits incompatibility in the liquid state and tends to separate into two liquid layers on long term standing. A portion of freshly mixed (XII) is cured in the neat form as described in Example 1(d) and calculations show that a volume expansion of 0.3% occurs. The cured product is typically white and opaque and it displays the characteristic two phase structure.
Another portion of (XII) is used to prepare a glass fiber reinforced laminate by the method described in Example 2(e). The surface profile of the laminate is determined to be 450 microinches, average roughness in /2 scan, again an indication of smooth surface when compared with the conventional resin control (1010 microinches).
EXAMPLE 7 A polyester (I) described in Example 1 is dissolved in styrene at 62.5% solids. A thermoplastic copolymer of methyl methacrylate and styrene (65/35 weight ratio) having a molecular weight of about 100,000, herein designated as (XIII), is dissolved in styrene at 31.3% solids. Sixty parts of the polyester/styrene solution are blended with 40 parts of the styrene solution of thermoplastic copolymer (XIII) to yield an incompatible liquid resin with limited phase distribution stability, herein designated as (XIV). The overall composition of the resin (XIV) is: unsaturated polyester (1) thermoplastic copolymer (XIII)/styrene37.5/12.5/50 weight ratio.
Resin (XIV) is cured in the neat form as in Example 1(d). Calculations based on the specific gravities of the liquid and cured resin show that the composition expands 5.3% by volume during cure. The cured material has the characteristic incompatibility.
A portion of the resin (XIV) is used to prepare a glass fiber reinforced laminate by the method described in Example 2(e). The laminates have average surface roughness /2" scan) of 207 microinches, which is indicative of an outstandingly smooth surface.
EXAMPLE 8 A polyester (I) described in Example 1 is dissolved in styrene at 62.5% solids. A thermoplastic copolymer. herein designated as (XV), of methyl methacrylate with hydroxyethyl methacrylate 15 weight ratio) having a molecular weight of about 50,000 is dissolved in styrene at 27.8% solids. Sixty-four parts of the styrene solution of polyester (I) is blended with 36 parts of the styrene solution of thermoplastic copolymer (XV) to yield a compatible, clear liquid resin, herein designated as (XVI). The resin displays no tendency to separate into two layers on standing for two months at roomtemperature. The composition of this resin (XVI) is unsaturated polyester (I)/thermoplastic copolymer (XV) /styrene40/10/50 weight ratio.
A portion of resin (XVI) is cured in the neat form as described in Example 1(d). The cured resin is white and opaque and exhibits the characteristic two-phase structure under magnification. Volume shrinkage on cure of this resin is 3.0%.
A portion of resin (XVI) is mixed with clay filler (60/40 resin/filler weight ratio) and used to prepare a glass fiber reinforced laminate by the method described in Example 2(f). Average surface roughness 72" scan) of the laminate is microinches, a degree of surface smoothness unattainable in like laminates prepared from conventional polyester styrene resins.
The term optically heterogeneous, as used in the specification and claims refers to the appearance of the cured, polymerizable composition. Without magnification, that is to the naked eye, the appearance of the cured, neat (i.e., unfilled and unreinforced) composition generally appears white, off-white, or white with gray areas. This opaque or nearly opaque appearance may be seen in FIG. 1, wherein specimens 1a and 1b are characteristic of the present invention while specimens 10 and 1d are characteristic of the prior art. The specimens are each approximately thick and have been photographed with reflected light. Specimen 1a is the cured composition of Example 1(a) above. Specimen 1b is the cured composition obtained by polymerizing a polyester based on maleic anhydride and a mixture of propylene glycol and dipropylene glycol (1 to 1 mole ratio), styrene monomer and a thermoplastic acrylic polymer consisting of methyl methacrylate and ethyl acrylate (87/13 weight weight ratio). Specimen la', which is clear, is the crosslinked product prepared by copolymerizing a styrene solution of an unsaturated polyester based on dipropylene glycol and maleic anhydride, (Example 1(c) above). Specimen 1c, which is quite translucent, is compositionally the same as specimen 1d, except that it contains an acrylic copolymer of methyl methacrylate and ethyl acrylate 87/ 13 weight ratio). Under magnification, the optically heterogeneous cured composition appears as a distinct two-phase system or structure characterized by white, off-white, or white and gray spheres dispersed in a clear matrix. This may be seen by reference to FIG. 2, wherein there is shown a photomicrograph of a microtone section of specimen 1a of FIG. 1 (same composition as that of Example 1(a) The section was mounted in a slide with Canada balsam, and photographed with 600x magnification using reflected light and a dark background.
It has been determined that the spheres which are dispersed in the clear matrix are essentially made up of the thermoplastic polymer, hereinbefore defined, while the matrix is essentially the crosslinked copolymer resulting from the copolymerization of the unsaturated polyester and the crosslinking monomer containing at least one reactive group per molecule, as hereinbefore defined. Thus, the thermoplastic polymers which are useful in the present invention are those which are incompatible or essentially 11 polyester and the crosslinking monomer containing at least one polymerizably reactive group per molecule;
Calculation of the molecular weight perdouble bond factor (M.W./C=C), referred to in the specification and claims, is illustrated below for the unsaturated polyester of Example 1(a); i.e., based on maleic anhydride and propylene glycol. The molecular weight of maleic anhydride is 98, the molecular weight of propylene glycol is 76; the sum of these two members is 174 and subtracting therefrom the molecular weight (M.W.=l8) of one mole of water which is split out during the condensation reaction, gives the value of 156 for the factor.
Fillers, usually inert and inorganic material useful with the compositions of the present invention include, for example, clay, talc, calcium carbonate, silica, calcium silicate, etc. Reinforcing fibers or fibrous reinforcement as used in thespecification and claims is taken to mean glass fibers in one form or another, such as glass fabrics, chopped glass strands, chopped or continuous strand glass fiber mat; however, the terms also include reinforcing, agents which, while less effective, may also be used if desired, for example, asbestos, cotton, synthetic organic fibers, and metals.
I claim:
1. A method of producing a fibrous reinforced article with smooth surfaces which comprises providing a liquid, polymerizable composition of matter comprising (a) 20 to 70 parts by weight of an a,fi-ethylenically unsaturated polymerizable polyester having a molecular weight per double bond factor of 150-186, (b) 25 to 75 parts by weight of a monomer containing a group polymerizable with said unsaturated polyester and (c) l to 25 parts by weight of a thermoplastic polymer of a substance or mixture of substances having a polymerizable reactive CH C group, which polymer is soluble in monomer (b) but which, when present during the copolymerization of (a) and (b), yields an optically heterogeneous cured composition and molding and curing said polymerizable composition of matter in th presence of fibrous reinforcement under heat and pressure.
2. The method of claim 1 wherein the fibrous reinforcement is a glass material.
3. A method according to claim 2 wherein there is also present a filler.
4. A method in accordance with claim 1 wherein said polyester (a) is a condensation product of an 0a,]3-6thYl6Ilically unsaturated dicarboxylic acid with a dihydric alcohol and wherein said thermoplastic polymer (0) is essentially an acrylic resin.
5. A method in accordance with claim 1 wherein the liquid polymerizable composition of matter comprises an unsaturated polyester (a) which is the condensation product of propylene glycol and maleic anhydride, a monomer (b) which is styrene and a thermoplastic polymer (c) which is a copolymer of methyl methacrylate and ethyl acrylate having a molecular weight in the range of 25,000 to 500,000.
6. A method in accordance with claim 1 wherein said liquid polymerizable composition of matter comprises, per 100 parts by weight, 30 to parts of polyester (a), 40 to parts of monomer (b), and .5 to 20 parts of thermoplastic polymer (c).
7. A method in accordance with claim 6 wherein the unsaturated polymerizable polyester (a) is the condensation product of propylene glycol and maleic anhydride, the monomer (-b) is styrene and the thermoplastic polymer (c) is a copolymer of methyl methacrylate and ethyl acrylate.
References Cited UNITED STATES PATENTS 2,609,353 9/1952 Rubens et al 260862 3,231,634 l/1966 Wismer et a]. 260862 2,757,160 7/ 1956 Anderson. 3,261,886 7/1966 Lowry.
FOREIGN PATENTS 936,351 9/1963 Great Britain 260862 MORRIS LIEBMAN, Primary Examiner S. L. FOX, Assistant Examiner US. Cl. X.R.
|Citing Patent
|Filing date
|Publication date
|16 Jan 1974
|21 Jan 1975
|Lucas Electrical Co Ltd
|Lamp reflectors
|1 Jul 1974
|24 Jun 1975
|Owens Corning Fiberglass Corp
|Thermoplastic ingredient for molding compounds
|17 Dec 1973
|9 Dec 1975
|Du Pont
|Anhydride acrylic copolymers as additives for unsaturated polyester molding compositions
|11 Apr 1973
|25 May 1976
|Koppers Company, Inc.
|Curable solid polyester resins
|5 Apr 1972
|3 Aug 1976
|Bp Chemicals International Limited
|Moulding process for unsaturated polyester resins containing filler material
|6 Jun 1973
|10 Aug 1976
|Woodall Industries Inc.
|Energy absorbing vehicle body material
|11 Dec 1973
|5 Oct 1976
|Basf Farben & Fasern Aktiengesellschaft
|Opaque coatings and films produced by the hardening of synthetic resins with light
|27 May 1975
|26 Oct 1976
|Rostone Corporation
|Precision-moldable abrasion-resistant molding composition and moldings
|27 Aug 1974
|14 Dec 1976
|Mitsubishi Rayon Co., Ltd.
|Polyester molding compositions containing hydroxy containing vinyl monomers and coated molded articles thereof
|27 Jun 1974
|18 Jan 1977
|Armco Steel Corporation
|Article transparent to microwaves and process for making same
|30 Sep 1974
|25 Jan 1977
|Ppg Industries, Inc.
|Ultraviolet light curable opacifying compositions
|22 Jul 1975
|15 Feb 1977
|W. R. Grace & Co.
|Thickened polyester composition containing ultrafine polypropylene fibers
|10 Jul 1975
|22 Feb 1977
|Armco Steel Corporation
|Low profile pigmented sheet molding process and product
|12 Dec 1975
|29 Mar 1977
|Sony Corporation
|Motor and method for making same
|9 Oct 1975
|27 Sep 1977
|Bayer Aktiengesellschaft
|Hardenable moulding compositions containing a thermoplastic polymer a copolymerizable vinyl compound and a polyesterurethane
|7 Mar 1977
|18 Oct 1977
|Owens-Corning Fiberglas Corporation
|Thermoplastic additives for molding compounds
|26 Oct 1976
|20 Jun 1978
|Owens-Corning Fiberglas Corporation
|Moldable compositions comprising thermosetting polyester resin and thermoplastic resin
|7 Jun 1976
|3 Oct 1978
|Basf Farben & Fasern Ag
|Compositions for the production of opaque coatings by radiation
|7 Nov 1974
|27 Feb 1979
|Armco Inc.
|Unidirectional sheet molding composition and process of preparing same
|8 Feb 1978
|23 Oct 1979
|Union Carbide Corporation
|Low shrinking thermosetting molding compositions having reduced initial viscosity
|30 Nov 1977
|23 Oct 1979
|Basf Aktiengesellschaft
|Low-shrink unsaturated polyester molding compositions
|26 Sep 1978
|5 Feb 1980
|The General Tire & Rubber Company
|Method for forming sheets having reduced surface imperfections
|14 Oct 1977
|19 Aug 1980
|British Industrial Plastics Limited
|Polyester resins
|31 Oct 1978
|13 Jan 1981
|Mitsubishi Rayon Co., Ltd.
|Unsaturated polyester composition for molding compound and coated molded article thereof
|27 Dec 1977
|13 Jan 1981
|The Dow Chemical Company
|Low profile additives for unsaturated polyester resins
|4 Aug 1978
|20 Jan 1981
|Owens-Corning Fiberglas Corporation
|Low temperature maturation of sheet molding compositions
|26 Feb 1973
|18 Aug 1981
|Union Carbide Corporation
|Unsaturated polyester compositions
|26 Feb 1973
|8 Sep 1981
|Union Carbide Corporation
|Polyester compositions
|9 Apr 1980
|3 Nov 1981
|Cargill Incorporated
|Low shrink unsaturated polyester resinous composition
|10 Apr 1981
|16 Mar 1982
|Owens-Corning Fiberglas Corporation
|Polyester-based molding compositions
|16 Oct 1980
|15 Feb 1983
|Union Carbide Corporation
|Polyester moldings
|23 Jun 1981
|11 Oct 1983
|Cargill Incorporated
|Low shrink unsaturated polyester resinous composition
|25 Apr 1984
|1 Jan 1985
|Union Carbide Corporation
|Uniformly pigmented, low shrinking polyester molding compositions
|9 Sep 1983
|16 Jul 1985
|The Budd Company
|Thermosetting resin patching compound
|23 Sep 1982
|26 Nov 1985
|Union Carbide Corporation
|Uniformly pigmented, low shrinking polyester molding compositions
|23 Jan 1984
|4 Feb 1986
|Allied Corporation
|Process to produce sheet molding compound using a polyamide release film
|24 Jun 1986
|16 Jun 1987
|Union Carbide Corporation
|Polyester molding compositions
|16 Oct 1986
|23 Feb 1988
|Vetrotex Saint-Gobain
|Thermosetting resins reinforced with cut yarns
|5 Jan 1987
|30 Aug 1988
|Uniroyal Chemical Company, Inc.
|Carboxyl modified olefinic copolymer composition
|13 Jul 1987
|21 Feb 1989
|Bayer Aktiengesellschaft
|Polyester resin compositions which can be hardened with little shrinkage
|13 Jan 1988
|31 Oct 1989
|Polysar Limited
|Thermoset resin compositions
|21 Apr 1989
|17 Jul 1990
|E. I. Du Pont De Nemours And Company
|Solid imaging method utilizing photohardenable compositions of self limiting thickness by phase separation
|21 Apr 1989
|17 Jul 1990
|E. I. Du Pont De Nemours And Company
|Solid imaging method using photohardenable materials of self limiting thickness
|30 Oct 1989
|18 Feb 1992
|Owens-Corning Fiberglas Corporation
|Unsaturated polyester resin compositions containing compatible compounds
|2 May 1990
|7 Apr 1992
|Owens-Corning Fiberglas Corporation
|Citrate ester compounds and processes for their preparation
|21 Apr 1989
|7 Jul 1992
|E. I. Du Pont De Nemours And Company
|Method of forming a three-dimensional object comprising additives imparting reduction of shrinkage to photohardenable compositions
|2 May 1990
|10 Nov 1992
|Owens-Corning Fiberglas Corporation
|Unsaturated polyester resin compositions containing compatible compounds
|27 Aug 1991
|25 May 1993
|William Lippert
|Methods of making fiber-reinforced resin molds
|22 Jul 1991
|26 Oct 1993
|Owens-Corning Fiberglas Technology, Inc.
|Unsaturated polyester resin compositions containing compatible compounds having sulfur-containing substituents
|22 Jul 1991
|26 Oct 1993
|Owens-Corning Fiberglas Technology, Inc.
|Unsaturated polyester resin compositions containing compatible compounds having aromatic substituents
|23 Jul 1990
|1 Mar 1994
|Owens-Corning Fiberglas Technology Inc.
|Thermoplastic low-profile additives and use thereof in unsaturated polyester resin compositions
|10 May 1993
|5 Jul 1994
|Plasticolors, Inc.
|Method of preparing a cured pigmented thermosetting polymer composition exhibiting improved color values and reduced haze
|10 May 1993
|22 Aug 1995
|Plasticolors, Inc.
|Process for preparing pigmented thermoplastic polymer compositions and low shrinking thermosetting resin molding composition
|21 Sep 1995
|1 Apr 1997
|Polaroid Corporation
|Lithographic printing plates with dispersed rubber additives
|22 Nov 1991
|10 Jun 1997
|Union Carbide Chemicals & Plastics Technology Corporation
|Composition of unsaturated polyester, copolymerizable monomer and poly (vinyl ether) shrinkage control agent
|18 Sep 1996
|24 Mar 1998
|Cook Composites And Polymers
|Process for making a paintable polymer article
|14 Mar 1996
|21 Apr 1998
|Reichhold Chemicals, Inc.
|Shrink-controlled resin composition
|2 Feb 1996
|26 May 1998
|Ashland Inc.
|Low profile additives for polyester resin systems based on asymmetric glycols and aromatic diacids
|17 Oct 1996
|29 Dec 1998
|Polaroid Corporation
|Lithographic plate with disperse particulate rubber additive
|23 Mar 1994
|4 May 1999
|Cook Composites And Polymers Co.
|Thermosetting polyester composites prepared via vacuum-assisted technique with smooth surface appearance
|27 Aug 1997
|20 Jul 1999
|Reichhold, Inc.
|Resins for lining surfaces
|25 Mar 1998
|3 Aug 1999
|Ashland Inc.
|Low profile additives for polyester resin systems based on asymmetric glycols and aromatic diacids
|19 Jan 1999
|3 Apr 2001
|Cook Composites And Polymers Co.
|Aromatic polyol end-capped unsaturated polyetherester resins and resin compositions containing the same having improved chemical and/or water resistance
|22 Dec 1998
|1 May 2001
|Cook Composites And Polymers Co.
|Polyester resin-based compositions having improved thickening behavior
|4 Oct 2000
|12 Mar 2002
|Wm. Marsh Rice University
|Synthesis of poly(propylene fumarate) by acylation of propylene glycol in the presence of a proton scavenger
|14 Apr 2000
|7 May 2002
|William Marsh Rice University
|Poly(Propylene Fumarate) cross linked with Poly(Ethylene Glycol)
|16 Feb 2000
|14 May 2002
|Cook Composites And Polymers Co.
|End-capped unsaturated polyetherester, unsaturated polyester and vinyl monomer
|7 Dec 2001
|9 Dec 2003
|Cook Composites And Polymers Co.
|Gel coated fiber-reinforced composition of polyetherester, unsaturated polyester and vinyl monomer
|7 Mar 2000
|17 Feb 2004
|Reichhold, Inc.
|Resins for lining surfaces
|28 Mar 2001
|14 Dec 2004
|Cook Composites And Polymers Co.
|Aromatic polyol end-capped unsaturated polyetherester resins and resin compositions containing the same having improved chemical and/or water resistance
|20 Nov 2002
|8 Dec 2009
|William Marsh Rice University
|Synthesis and characterization of biodegradable cationic poly(propylene fumarate-co-ethylene glycol) copolymer hydrogels modified with agmatine for enhanced cell adhesion
|28 Mar 2001
|9 May 2002
|Chih-Pin Hsu
|Aromatic polyol end-capped unsaturated polyetherester resins and resin compositions containing the same having improved chemical and/or water resistance
|20 Nov 2002
|14 Aug 2003
|William Marsh Rice University
|Synthesis and characterization of biodegradable cationic poly ( propylene fumarate-co-ethylene glycol) copolymer hydrogels modified with agmatine for enhanced cell adhesion
|31 Oct 2003
|18 Mar 2004
|Hildeberto Nava
|Resins for lining surfaces
|28 Aug 2006
|3 May 2007
|Evert Van Der Heide
|Integrated process for the preparation of a polyester resin
|28 Aug 2006
|3 May 2007
|Evert Van Der Heide
|Integrated process for the preparation of a polyester resin
|8 Sep 1983
|27 Aug 1985
|Union Carbide Corp.
|Polyester compositions
|18 Dec 1978
|17 Oct 1979
|Ford Motor Company Limited
|Method of compression molding
|14 Jul 1987
|27 Jan 1988
|Dsm N.V.
|Curable polyester resin compositions showing a low shrinkage
|14 Jul 1987
|5 Oct 1988
|Bayer Ag
|Curable polyester resin compositions showing a low shrinkage
|25 Apr 1991
|9 Jul 1997
|Cray Valley Sa
|Unsaturated polyester resin compositions and new anti-shrinking additives
|15 May 1981
|26 Nov 1981
|Budd Co
|A compound and method of repairing surface defects
|16 Oct 1987
|20 Apr 1989
|The Swan Corporation
|Composition of matter for wear surfaces and method for producing same
|9 Oct 1992
|29 Apr 1993
|Cray Valley S.A.
|Unsaturated polyester compositions for laminates and method for using same
|21 Mar 1995
|28 Sep 1995
|Cook Composites And Polymers
|Process for preparing a fiber-reinforced composite and molded articles made therefrom
|28 Aug 2006
|8 Mar 2007
|Shell Internationale Research Maatschappij B.V.
|Integrated process for the preparation of a polyester resin
|2 Aug 2013
|6 Feb 2014
|Kordsa Global Endustriyel Iplik Ve Kord Bezi Sanayi Ve Ticaret Anonim Sirketi
|A method for producing fiber reinforced rubber comprising unsaturated bonds
|U.S. Classification
|523/523, 264/331.18, 525/176, 525/190, 525/170, 525/49
|International Classification
|Cooperative Classification
|European Classification


text:
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Steamed Sweet Chili Chicken Recipe
Sliced white meat chicken, carrots, and celery tossed in a delicious sweet chili sauce.
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Salmon, ginger and soy sauce steamed in just minutes.
Chinese Roast Chicken Recipe
Marinated whole chicken basted with sweet honey sauce and baked until the skin is brown and crisp.
How to Make Sticky Rice (Glutinous Rice)
Step by step instructions on how to make glutinous rice (sticky rice, short grain rice) simply using a pot.
Quick and Easy Chinese Chicken Salad Recipe
Made with fresh spring greens and rotisserie chicken.
Chinese Barbecue Chicken Skewers Recipe
Searching for a new chicken recipe to cook on the grill? Try these delicious sweet and savory Chinese barbecue chicken skewers. Basted with a mixture of hoisin and honey, these easy to make skewers are a great way to impress your family.
How to Make Mushroom Fried Rice
Looking for something new to serve alongside your favorite chicken dish tonight? This mushroom fried rice recipe goes perfect with chicken and is sure to please the whole family.
Chinese Peanut Dipping Sauce Recipe
Looking for the perfect dipping sauce to serve alongside spring rolls or other appetizers? Here is a delicious Chinese peanut dipping sauce that is used in most restaurants today for spring rolls, chicken skewers, and other delicious treats.
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Searching for a healthy and easy to make dish for lunch? This bok choy noodle bowl recipe is simple and can be made ahead of time for a quick and easy lunch dish.
How to Prepare Shiitake Mushrooms for a Stir fry
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text:
Ballyard Script Baseball
Item# 20059
At Life is good, evolution is good. This season's Crusher tees achieve a vintage look and feel through distressed printing and a new dye process. Increased fabric weight for optimum durability.
- Tee reads: Life is good
- 100% cotton
- Relaxed fit
- Piece dyed (new)
- Garment washed for softness
- Herringbone twill taping from shoulder to shoulder
- Double needle stitching
- DO WHAT YOU LIKE. LIKE WHAT YOU DO. ® locker patch
- Imported


text:
Tragedy in Black and White
What if race relations in the United States got so bad that the nation decided to try a radical idea: separation? The events that propel the country to such an extreme are riots, disturbances in the armed forces and on college campuses, and finally the assassination of a prominent black presidential candidate. In this book a nation-wide referendum approves the idea. Three states are set aside for blacks only, seven just for whites and the other 40 remain integrated.The story follows Mike, a white policeman, to all-white Miami; black college professor Ben and his family to all-black Chicago; and young militant Sherman also to Chicago. The brave new world that each was expecting proves elusive, for both external and internal reasons.This is a story about ambition, love, hate, violence, and betrayal. Marriages will be sorely tried, children will rebel against their parents, careers will take abrupt and surprising turns. All the manifestations of upheaval will be explored against a background of racial misunderstanding.Woven into the story is a study of the background of racial conflict dating back to slavery and segregation. Would such a solution to our racial troubles work?
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text:
Problem of post-process pressure.
Dear all:
I have a problem about pressure of microchannel. I have used icepak to slove my problem, but in the post-process, i can't correct to show the differential pressure of microchannel.
In the experiment, the differential pressure data of experiment is 1.4Kpa. The data of simulation is 300pa at inlet and outlet is -20pa. why data is so big discrepancy ?
I think that my data of simulation is correct, maybe i can't to show the answer.
Please, Can someone tell me that how to solve the psot-process?
i have a same problem too
what should we do?
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text: On 04/03/2012 12:29 AM, Emmanuel Bourg wrote: > Le 31/03/2012 21:10, Andrew Haley a écrit : > >>> While reading the authbind documentation I saw it was doing some fork >>> tricks behind the scene. Maybe the forked process can't allocate its >>> memory due to OpenVZ and quits? >> >> Hold on, do you see this problem outside OpenVZ? I know that there is >> a virtualization container that doesn't support memory overcommit, but >> I can't remember its name. If so, that's a big problem; Java's GC >> strategy really needs overcommit to work. > > This problem doesn't happen outside the OpenVZ container. > > OpenVZ has a setting to fiddle with memory overcommit (the privvmpages > parameter), but I'm not sure it'll work with a 32 bits container and 4GB > assigned, the limit can't be extended. > > If the JVM could allocate gradually the memory as the heap grows that > would help, but I guess that's not possible. Not really. To be frank, overcommit is such a basic Linux feature that any container which doesn't fully support it is just broken. >>> That's probably one more good reason to replace authbind with iptable in >>> my case. The other reason being the lack of IPv6 support. >> >> Right. I expect that every Java VM will move to IPv6, so authbind >> would stop working everywhere. > > The sad thing is there is no good alternative yet. I realized today that > ip6table doesn't support port redirection (because it works with NAT and > NAT is discouraged with IPv6). The only solution left is to put a > reverse proxy in front of Tomcat. It doesn't look difficult to make authbind work with IPv6. I don't know why no-one has yet done it. Andrew.


text:
How Would You Handle A Stranger Randomly Holding Your Hand?
Some people just look awkward holding hands together when you see them in public. The weird part about it is that most of them are doing it on purpose.
Imagine how weird it would be if one of the parties involved didn't know they were about to be holding hands!


text:
1.8kviews and rising! Watch as Julian Day outlines the ups and downs of trekking along the coastline.
Denis Moteit of Hervey Bay Rotary Club and Tanya Stevenson, CEO of Neighbourhood Centre show their appreciation for the fund-raisers and the locals who have supported this great cause.
$3000 raised so far, exceeding expectations. The Centre is very appreciative of the generous donations of time and money for this successful, local program.


text:
Social Media & Relationship Marketing
Tap Into the Travel Marketing Powerhouse That Your Competition Can't Touch
By Diane Van Leunen, Director of Digital Marketing, Flip.to
We hear all the time that travelers have changed. Now we're highly-connected, mobile-crazed folks who want the freedom to choose. We want experiences, and we want to share those experiences with family and friends at the touch of a button, all in search of the next like. This is often attributed to the growing number of Millennial travelers born-and-raised on tech somewhere between 1980 (or '85, or '90 depending on who you ask) and the early 2000s.
The reality is, travelers aren't so different. We're still dreamers and adventure-seekers. We always enjoyed experiences and we always shared them with the people we love. What's changed is just how we do those things-how we dream, how we connect with our like-minded tribe, and how we discover new adventures. All of these are made faster and easier thanks to the explosion of mobile and social.
It makes good business sense that hotels are adapting to this phenomenon. Being present on these channels is a must. After all, social media is where billions of conversations are happening every day. But what sets these conversations and the medium itself apart are the people. It's their connection to each other that makes their personal exchanges unique. This is discourse a brand, big box or building just can't have.
Ultimately, it's the people who have the massive influence, connectivity and trust that can make a big impact for hotels (or any brand for that matter), and can even give your property a competitive edge. Herein lies the opportunity. So who are these people? They're your guests, and you can use them to earn big wins for your hotel.
Reaching Travelers is Tough. Here's Why Your Competitors Might be Winning
Before we look at why your guests are such an incredibly valuable marketing asset, it's worth looking at the challenges hotels are seeking to overcome.
Social Media is Evolving - When these channels first emerged, people and brands got on board in droves. Where once hotels built an engaged audience of followers and fans, now is another advertising medium. Organic reach is dead (okay, nearly dead) and Facebook gives priority to content shared by people you know over that of brands. Couple this with the fact that it's now pay-to-play, and the competition is rising. In fact, social media advertising spend increased 33.5% in 2015 with no signs of slowing down.
The Marketplace is Noisy - Americans visit 140 travel sites on average in the 45 days prior to booking when planning a trip. As a whole, we're spending over 40% more time with digital travel content this year than last.][3] That's a lot of media to digest.
Not only is the sheer volume of noise growing, but brands like AirBNB are stealing the mic. It's clear why. Their approach carves out a considerable share of attention, hitting a niche with experiences and positioning themselves as the purveyors of 'local.' They're grabbing the eyes and ears of travelers and press alike.
Their numbers tell an even bigger story. A new report by Morgan Stanley put their market penetration at 18-19% (up from 12% last year), projecting more growth into the new year thanks to high marks for both traveler awareness and user satisfaction.
'Book Now' is in Everyone's Sights
Competition at the time of transaction is perhaps the highest hurdle of all. Brands, OTAs, AirBNB, and the like are all bidding for this very moment of a traveler's journey. Google has backed this up, showing that the top brands are earning between 30% and 40% of the share of impressions in end-stage planning and booking. What's this all add up to for hotels?
Money. And lots of it. It's expensive to compete at this stage, and big budgets rule the space. Skift reported that in 2015 Expedia spent $3.38 billion in marketing with Priceline inching behind at $3.36 billion. TripAdvisor even entered the game, adding another $692 million into the mix.
What Typically Happens Next? Over-Compensation and the Pendulum Effect
These challenges can be daunting for a hotel marketer. At times, they may even feel insurmountable. But the reality is that the reaction to these hurdles can worsen the blow, hindering success in the long term.
Communication That's Personalized, Not Personal
Travelers are savvy. They see right through marketing that was created to fill your hotel's need instead of content that truly had them in mind. These messages have no bearing on where the traveler is on their journey and the level of personalization usually goes only as far as their first name.
Hotels Erode Their Brand in a Race to the Bottom
Blasts to your audiences (on social or otherwise) not only come off as impersonal, but they tend to include flash sales or low-ball marketing offers designed for anyone and everyone. It's a quick path to a room night, but at what expense? While this tactic fills your need in the short-term it also erodes your brand by setting a precedent for travelers who book your hotel. (Once a bargain brand, always a bargain brand.)
Marketing Turns to Spam
Especially on social, relevant content is king. If you're constantly hitting the same audience with impersonal messages designed purely for your own benefit, it's spam. The fact is, you're not broadening your scope. You're taking the risk of being ignored by those that follow you, and even worse could be losing future engagement from relationships that you've eroded altogether.
Where Hotels Can Win Back Travelers
Most 80-room properties don't have a $3 billion budget, nor are they buzzworthy fodder of the media at large. But that's okay. You have a truly competitive edge that sets your hotel apart. One that will help you reach a worldwide audience, avoid the common pitfalls we've discussed here, and have a distinct advantage over those seeking to compete for your travelers. That edge is the collective marketing potential of your guests.
Remember, you're the home base for your guests during their stay. As the hotel, it's a relationship that only you have. Get personal. Build on that relationship while encouraging your guests to share their experiences throughout their entire travel journey. Do this right and they'll send their network of friends & family back to your site, growing traffic made up of a demographic of travelers perfect for your hotel.
Gain the Authentic Perspective of Your Guests
As you encourage guests to share their experiences about your hotel, you'll notice a significant difference between their content and the standard stock image or sponsored post.
Guests provide candid, authentic insights that tell the richer story about your property. This first-person perspective (one that only your guests can provide) is important. For one thing, it's the right context for stories shared on social media. More importantly it's real, trusted, and far more potent than any advertising.
Get Real Brand Influence
The influence and trust your guests have both in real life and on social is arguably one of the top reasons to tap into this incredible resource. Brands and social giants used to track influence by sheer audience size. But the way people are really learning about travel goes to show that the weight of true influence can't be measured on following alone. For one thing, social media is an incredibly effective word-of-mouth medium, and the real-life friends & family who travelers know have shown to have a far greater bearing on the path to purchase.
The reason? People are connected to like-minded individuals. They generally trust the recommendations of friends & family more than ads, and this is especially true in the inspiration phase of travel-a fact backed by research from both Expedia and Google. And if that wasn't enough, consider this-a recent study was conducted of 200 leading travel "influencers" in North America. The benchmark of engagement performance hovered just under 3.5%. For those outliers with significantly higher results? They were a bust-mostly blank accounts showing fake engagement that was utterly worthless to a brand.
Build an Ever-Growing Audience
The collective reach of your guests is enormous, as well as incredibly targeted. Your guests can introduce your hotel to a network of travelers just like them-and that's a really good thing. Over time, the current database you have (right now made up of only current and past guests) will be miles deeper and more bountiful. Every day you'll add to the pool of travelers that are the perfect demographic for your hotel.
Turn Social Traffic Into a New Channel of Guests
Warm engagement with your audience on social is not a bad thing. But it's important to remember where conversions happen for your hotel. That's on your site, not on your social channels. Social media sites want people to stay on the sites that they've built. While your social fan page might have an audience, the bigger goal is to use these networks to grow an audience for your own site.
Craft content and experiences that turn the social reach of your guests into a powerful distribution platform. Reach the connections of your guests and then drive them back to your own site. You'll send quality traffic back to the digital world you control. Pair this with thoughtful calls-to-action for travelers in each stage of their own journey and you'll start competing on a different level.
The Largest Edge: Inspire and Compete Long Before "Book Now"
While we're on the traveler journey, here's something worth noting. As your guests introduce you to friends and family, they're most likely not in travel-planning mode. Google calls these 'dreaming' or 'I-want-to-get-away' moments. These dreamers have made no decision to travel but are ready to be inspired, making this a prime opportunity for your hotel to be introduced. That's key, and here's why. As we mentioned earlier, at the time of booking top brands hold 40% of the share of impressions. However, at this stage in the journey-the inspiration phase-it's only 5%. And that's a tremendous opportunity for hotels to make an impression.
Let your guests put your hotel at the center of moments shared with friends & family. You'll make that impression far before your competitors have even had a chance to start a relationship (let alone earn the booking.) Think of these moments of inspiration as the place where people catch the 'travel bug' from those they know, and you want to be included at that very first opportunity.
Your Guests are Your Greatest Untapped Resource
If you're a hotel and are still trying to compete at the time of conversion, you're facing an uphill battle-and it's steep. The billions spent in the digital space on ads, conversion and technology is only set to inflate. Add to this more noise and an ever-changing travel landscape and the hurdles only get bigger.
But just as challenges evolve, so too does travel marketing. With connectivity and influence that's untouched, your guests are the greatest addition to your team. Tap into this marketing powerhouse and you'll rise above the rest while growing real, tangible results for your hotel.
Brian Boland. "Organic Reach on Facebook: Your Questions Answered." Facebook, https://blog.hootsuite.com/social-media-advertising-stats/. Accessed 05 Dec 2015.
Evan LePage. "All the Social Media Advertising Stats You Need to Know." Hootesuite, https://blog.hootsuite.com/social-media-advertising-stats/. Accessed 11 Dec 2016.
"The American Traveler's Path to Purchase." Expeida Media Solutions, https://info.advertising.expedia.com/american-traveler-path-to-purchase. Accessed 30 Nov 2016.
"The 2014 Traveler's Road to Decision." Think with Google, https://think.storage.googleapis.com/docs/2014-travelers-road-to-decision_research_studies.pdf. Accessed 18 June 2015.
Kevin May. "Hardly influential - warning over fake Instagram love and travel bloggers." Tnooz, https://www.tnooz.com/article/articlearticlehardly-influential-fake-instagram-accounts-and-travel-bloggers/. Accessed 13 Dec 2016.
"Organic Reach on Facebook: Your Questions Answered." Think with Google, https://www.thinkwithgoogle.com/articles/be-there-micro-moments-new-travel-customer-journey.html. Accessed 11 Dec 2016.
Kevin May. "Airbnb demand increasingly hitting hotels, not online travel agencies." Tnooz, https://www.tnooz.com/article/morgan-stanley-airbnb-report/. Accessed 12 Dec 2016.
"How Micro-Moments Are Reshaping the Travel Customer Journey Travel Micro-Moments Guide." Think with Google, https://www.thinkwithgoogle.com/articles/micro-moments-travel-customer-journey.html/. Accessed 11 Dec 2016.
Diane Van Leunen is the Director of Digital Marketing at Flip.to, the advocacy marketing platform that helps hotels reach, inspire and convert entirely new global audiences of travelers every day. Ms. Van Leunen began her career as a designer in advertising and branding. Soon after, she was propelled into the world of hospitality. She took a position in art direction at Plan A PR and Marketing, a public relations firm specializing in the B2B hotel technology space. Following agency life, Ms. Van Leunen moved client-side, tackling hotel marketing with a creative role on the corporate team at The Kessler Collectiona boutique hotel group that provides curated experiences to discerning travelers. Ms. Van Leunen can be contacted at 321-234-2086 or firstname.lastname@example.com Please visit http://www.flip.to for more information. Extended Bio...
HotelExecutive.com retains the copyright to the articles published in the Hotel Business Review. Articles cannot be republished without prior written consent by HotelExecutive.com.


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CWG: Hoy asked for ID at Sir Chris Hoy Velodrome
Glasgow: One Glasgow Games official was left red-faced yesterday morning after stopping Sir Chris Hoy for an ID check — to gain entry to the Sir Chris Hoy Velodrome.
Sir Chris Hoy Velodrome
The velodrome media manager defended the move, saying: "This is standard procedure. Everyone entering the venue needs to go through security."
Typically, the six-time Olympic champion took it all in his stride, tweeting soon afterwards: "She was just doing her job!!"


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Become a Member!
Let's Get Social!
Advice & Resources
- Interview with Olga Stella of Detroit Creative Corridor Center on the Role Artists Play in UNESCO Detroit's City of Design Designation
- Preparing Your Creative Business for Impressive Holiday Sales
- Social Media for Artists to Achieve Remarkable Results
- How to Make the Most of Art Shows
- Recycle Your Portfolio: What Gallerists Want Now
Tag Archives: customer retention
Want to Sell More Art? Take Good Care of Your Customer
By Andrea Rosenfeld | Published: April 7, 2017
Want To Sell More Art? Take Good Care of Your Customer I share this story with my students in my Mind Your Art Business Growth Course because it's the perfect example of what too many small business owners do to turn off buyers and lose sales. During a Detroit studio tour, a studio owner told […]
Posted in Andrea Rosenfeld, Blog, Good Business Health, Sales and Customer Service | Also tagged art business strategy, art sales, best business practices, consulting, customer service, Detroit, give the best customer care, good business strategies, good customer service, how to engage in business, how to offer good customer service, how to sell, how to speak to clients, Michigan artist, responsible business practices, sell more art | Leave a comment


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Note: This article describes the construction of our newest Koi pond that started in the fall of 2015.
Phase 1 - Planning
Note: This site was picked so as to make the Koi pond visable from our screened in back porch.
Phase 2 - Construction
Getting started 11/21/2015. Note close proximity to the rear door of the screened in porch.
Digging in progress. Hired help (Don)worked cheap albeit slow and steady. :>)
Getting ready to pour concrete footings that will support pond walls.
Congrete footings poured.
Concrete block wall constuction in progress.
Pond walls nearly completed and waterfall spill way in place.
Walls toped with brick and ready for pouring of the concrete floor.
Phase 3 - Completion
Pond completed June 2016. Painted inside and out.
Filter system in back of waterfall.
50 Koi babies added. Purchased online from https://www.koisale.com/KoiStore/.
Completed pond and surounding landscraping, surrounding paver patio and adjacent screened in porch.


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Esc2.org was registered on name.com, llc on 26 November 2015. The site is almost absent on social networks. It has 0 facebook likes.
The site receives 2,820 visitors every month, which put its worth at around $ approximately. The website has a good alexa rank of 1,237,265.
The webmasters of the website can be contacted at . The domain for the website was purchased through name.com, llc on 26 November 2015 (1 year ago) and will expire in 12 months 1 day.
Domain Name: ESC2.ORG Domain ID: D178554012-LROR WHOIS Server: Referral URL: Updated Date: 2016-03-25T01:44:25Z Creation Date: 2015-11-26T19:44:57Z Registry Expiry Date: 2016-11-26T19:44:57Z Sponsoring Registrar: Name.com, LLC Sponsoring Registrar IANA ID: 625 Domain Status: clientTransferProhibited ID: nec08ykar6n2crc8 Registrant Name: Registrant Organization: Registrant Street: Adana / Beyazevler Registrant City: Adana Registrant State/Province: T?rkiye Registrant Postal Code: 0001 Registrant Country: TR Registrant Phone: +90.5385585058 Registrant Phone Ext: Registrant Fax: Registrant Fax Ext: Registrant Email: Admin ID: nec08ykar6n2crc8 Admin Name: Admin Organization: Admin Street: Adana / Beyazevler Admin City: Adana Admin State/Province: T?rkiye Admin Postal Code: 0001 Admin Country: TR Admin Phone: +90.5385585058 Admin Phone Ext: Admin Fax: Admin Fax Ext: Admin Email: Tech ID: nec08ykar6n2crc8 Tech Name: Tech Organization: Tech Street: Adana / Beyazevler Tech City: Adana Tech State/Province: T?rkiye Tech Postal Code: 0001 Tech Country: TR Tech Phone: +90.5385585058 Tech Phone Ext: Tech Fax: Tech Fax Ext: Tech Email: Name Server: EVA.NS.CLOUDFLARE.COM Name Server: ANDY.NS.CLOUDFLARE.COM DNSSEC: unsigned "For more information on Whois status codes, please visit Access to Public Interest Registry WHOIS information is provided to assist persons in determining the contents of a domain name registration record in the Public Interest Registry registry database. The data in this record is provided by Public Interest Registry for informational purposes only, and Public Interest Registry does not guarantee its accuracy. This service is intended only for query-based access. You agree that you will use this data only for lawful purposes and that, under no circumstances will you use this data to(a) allow, enable, or otherwise support the transmission by e-mail, telephone, or facsimile of mass unsolicited, commercial advertising or solicitations to entities other than the data recipient's own existing customers; or (b) enable high volume, automated, electronic processes that send queries or data to the systems of Registry Operator, a Registrar, or Afilias except as reasonably necessary to register domain names or modify existing registrations. All rights reserved. Public Interest Registry reserves the right to modify these terms at any time. By submitting this query, you agree to abide by this policy.
No IP information found for the website!!


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- Please select a date to see the proper prices!
- Meal can be requested on the spot
Best offer
79 € / person / night, no meal
Description of the accommodation:
Rooms, services Weisses Rössl Innsbruck is welcoming all guests in Innsbruck with 18 comfortable rooms to stay in. In case you'd like to have a meal or a drink on the spot, you will be provided freshly prepared dishes in the restaurant every day. Should you be arriving by car, parking will be available nearby. Fans of actively spent leisure time will also have the chance to rent a bike nearby. Your valuables can be the safely secured in the safe. You can also bring your laptop for the holiday, for there is wireless Internet connection (WiFi) available at the hotel. An exact and detailed list of equipment in the rooms and of the services provided by Weisses Rössl Innsbruck you will find on the information sheet below, including any applicable additional fees.
Payment Advance payment by credit card or providing credit card guarantee may be necessary for finalizing the reservation, depending on the chosen date, room and price.
Arrival, opening hours The earliest time to check in at the hotel is 14:00, the latest time to check out is 11:00. The personnel of the hotel can speak with you in English and German languages.
Weisses Rössl Innsbruck rooms Rooms
- Please select a date to see the proper prices!
Accommodation services
Parking (11 €/night)
Free WiFi in shared places
Bike rental at the accommodation
Elevator, Safe deposit box
Own restaurant
Hairdryer, Desk in the room


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I'm in Section 1.
Fill in your details, your issues and we will contact you.
International HQ
Neptunigatan 1
Phone: +1 123 456 7890
Fax: +1 123 456 7890
Email: firstname.lastname@example.com
Other contacts
The Freedom Bath® is one of the most easily accessible baths ever built.
In residential care environments, full long-side access makes both independent and assisted bathing safer and easier.
The Freedom Bath can improve quality of life, by maximising the level of active involvement in the bathing process
Lift integration with the side entry Freedom Bath means no manual resident/patient handling is required during assisted bathing sessions. The controls are positioned for convenient access by both caregiver and independent bather.
This is a highly efficient hygiene system for independent bathing and can reduce the demand for assisted bathing. The Freedom bath makes independent bathing more accessible to the more ambulatory residents, as the side of the bath is no longer a problem. This could reduce the amount of staff resources necessary for assisted bathing.
Clinical evidence has shown that taking a hot bath has a lot of benefits including; pain relief, enhanced mobility, reduction of symptoms in skin disease, as well as improved psychological wellbeing.
Read more
Falls in care facilities can be prevented. Prevention strategies that take into account the opinions and recommendations of a multidisciplinary team of medical professionals have been shown to have the optimal results in the reduction of falls in care.
World leading integrated solutions for the care of people with reduced mobility and related conditions. Based on extensive knowledge and advanced technology we provide superior medical equipment for safe patient handling and hygiene, medical beds and Therapeutic Support Systems™, wound healing, DVT prevention, disinfection and diagnostics. The result is improved care efficiency and a safer environment for both patient and carer.
This website is intended to provide information to an international audience outside of the US.
Contact us
Hans Michelsensgatan 10
211 20 Malmö
Phone: +46 10 335 4500
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Merle Haggard, Daughtry, Goo Goo Dolls to play upcoming shows in Northland
A country music hall of fame singer, who had a hit with "Okie from Muskogee," will play a concert in Duluth in the fall, according to the entertainer's website.
Merle Haggard plays Oct. 4 at the Duluth Entertainment Convention Center – in between gigs at Norsk Hostfest in Minot, N.D., and Mystic Lake Casino in Prior Lake, Minn.
Haggard has been part of the country western – specifically the outlaw country scene – since the mid-1960s, when he earned a chart-topper with "I'm a Lonesome Fugitive." He is in the Country Music Hall of Fame.
Haggard played Symphony Hall in 2004 and a News Tribune reviewer called it "classic Haggard." The prolific artist performed a mix of classic hits and new material during the no-nonsense show that didn't include an opening act or an encore.
"Haggard is authentic at a time when not much else in the industry is," the reviewer said.
Ticket info TBA.
Fortune Bay Casino announced that Goo Goo Dolls and Daughtry will perform on Aug. 8, a show that is being billed as the venue's biggest show to date.
Plain White T's will join the lineup with an acoustic set.
Tickets go on sale Thursday at fortunebay.com or by calling (800)992-7529.
Goo Goo Dolls' biggest hits include "Name," "Slide" and "Iris." Daughtry is fronted by "American Idol" alum Chris Daughtry and has had hits with "Waiting for Superman," "It's not Over," "No Surprise" and "Home."
Plain White T's were nominated for Grammy Awards for the song "Hey There Delilah."


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My Nonprofit Reviews
Michael S.
270 profile views
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Review for Opportunity Knocks Inc, Hamilton, NJ, USA
I have worked with Opportunity Knocks as their accountant since 2004. They have been great to work with and I really enjoy their company. They really care about the clients they serve.
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I've personally experienced the results of this organization in...
The events I have attended
If I had to make changes to this organization, I would...
Role: Advisor & I have worked with them as their accountant and have attended some of their events.


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Separate names with a comma.
Discussion in 'Mechanic and Repair' started by teckjohn, Aug 15, 2014.
Im sure they will ask and hopefully they get the help they need before they do any damage.
It is NOT a good idea to drag a hydrostatic mower even a few feet even with the levers forward. If you cant push it, don't move it. It is also a bad idea to move the levers around without the engine running. Learning where the bypass valves are and using them is always best.
That's something you gotta train your guys to do. The not moving levers thing is news to me and I've worked on hydro systems for 30 years. If its not running all your doing is working a valve back and forth that is still lubricated.
Posted via Mobile Device
Sorry, let me clarify on my last statement. Occasionally moving the levers is not a problem. What can cause a problem is when guys get on it and start playing with them. When they are moved back and forth it is working the pistons up and down, pumping a small amount of oil that has no where to go. Its supposedly bad for seals, just something an old fogey told me.
It's hard to find good help but when you find someone that's worth keeping pay them a little bit more keep them and they will take better care of your equipment and they'll be happy so just take care of your guys that are taking care of you that's what it all boils down to
First of all the hourly help doesn't get to ride the owner's big heavy commercial machine.
I start them out on handhelds and they stay on those and 21" until they're proficient, which can turn into 2-4 years.
After that they can try their hand on a 48" Belt-driven Walk Behind IF they've been good.
It takes more time after that, several more years.
Preferably a hired helper has 4 to 6 thousand mows under their belt before they get to sit down on a big bad Zero Turn Riding Mower.
The Ztr is neither a right nor is it an everyday tool, around my necks a ZTR is the Cadillac of lawn machines and not just anybody rides them.
But you're right, it probably does save me thousands.
Some of you guys would be a real treat to work for. Next you're starting a "I can't keep/find good help" thread. What? I give them one trimmer line reload per day! What more could an employee want?
Posted via Mobile Device
Ohhh, I forgot the most important part!!! It was sent back to me for warranty!!! LOL I took pics and sent them to him. He asked isn't that covered under warranty?
It's really nothing compared to driving slaves for a living, but to each their own.
Bump it up so u can see it


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|Twickenham Champions Ale
|Sambrooks Battersea IPA
|Dorking Red India Ale
BeardedAvenger (232) Addlestone, England | February 27, 2017
My opinion on this place may be slightly soured by the fact that Craft Beer Co was the intended destination. However someone else managed to lead us in a massive circle so need up here. On a Saturday night it was rammed and full of people happy to ram in to me. Could barely get to the bar, let alone see what was on, most if which was then off. Near the Brixton Academy.
WingmanWillis (1718) , England | February 8, 2017
Visited on 8th February 2017. Scruffy Spoons on Brixton High st. Long, thin venue, has had a bit of a makeover, loaded with locals at the front and often busy with gig goers it's not the most welcoming. Beer range is poor on cask. Bottle selection is a little better and nothing noteworthy on Keg. Not one of the best Spoons but it is cheap.
BlackHaddock (620) , England | February 2, 2017
Visited mid-evening on Sunday 22nd Jan 2017. Small cask selection, plenty of bottles and keg offerings. Typical well used Wetherspoons with a few years spillage on the carpets and the decor looking tired, as were most of the customers and staff. Heroin available in the Gents (until the staff threw him out), wife not amused. Been here, seen it, done it: will not be returning. Got two new rates though, so not all bad.
jjsint (656) Leicester, England | December 28, 2015
It is what it is, the Beehive. More late-night cafe with booze than full-on public house. Dodgy but friendly. It'll do. The pared-down cask ale selection (only two 'guests' alongside the nationals) is a bit of a let-down, but whatever brought you here... let's face it, it isn't for the beer ticks. Enjoy the unique atmosphere.
wheresthepath (132) , England | June 3, 2015
Was in here on a Saturday lunchtime so maybe didn't see it at its roughest - however, we were still lucky to get a table. It's one of the smaller 'Spoons, with a corresponding reduced beer selection - however, being a 'Spoons there were still a couple of casks I hadn't had before. Staff seemed friendly enough, and clearly knew the tattooed regulars well (the regulars at the bar were actually pretty friendly and chatty to me). Food came quickly and was competently cooked & served (as you expect in a 'Spoons. All in all OK for a quick pint/ cheap lunch, but certainly a little dingy and maybe not one of their more family-friendly outlets.
ManVsBeer (2059) Hebden Bridge, England | January 30, 2015
On the north side of the railway bridge where this suburb of London starts to get slightly less busy than the main commercial centre on its southern side, this is a fairly standard Wetherspoon with a small front but stretches back a fair distance into the building. It's looks is familiar with a traditional soft furnish finish throughout. It's busy all day and will suffice for an ale or two if you're desperate, but despite living in Brixton for over 2 years, I only popped in here a handful of times given it can be a rough and ready place at times.
The_Osprey (177) Richmond, England | August 29, 2014| Updated September 20, 2014
Standard JDW, but a bit on the dingy and depressing side. Cask ale selection is poor for JDW. Clientele include geezers and older caribbean blokes. Pretty busy.
Bryne (905) Bryne, Norway | March 8, 2014
Why did I end up here? Well, first of all I came to Brixton because I wanted some Brixton Pound (I'm not only a beer geek...) and the fact that Craft Beer Brixton opens damn late, "forced" me to pop in for a beer. Cesspit? Cantankerous boozers? Intimitating blokes? Well, I haven't been here after sunset and Brixton isn't the posh Mayfair for sure. But, certainly more colorful and exciting! (Visited February 28th 2014)
Theydon_Bois (1046) Hazlemere, the lower Xhitlerns, England | February 24, 2013
Have popped in on a few occasions prior to a gig at the Academy. Thank god for the Craft - I'll never have to enter this cesspit again! Typical dark and dingey spoons layout, no daylight other than the frontage, a little dirtier than most. Very average beer range with one or two guests beyond the stock Abbot/Ruddles piffle - if you're lucky. Service was pretty lousy but it has always been packed due to there being a gig on when I've called in. Clientele is Dubious with a capital D. When I nipped to the toilets once a couple of indimidating blokes were asking for money and practically demanding cigarettes of some younger guys. Not nice, avoid !
EdKing (199) London, England | January 28, 2013
Stuck my head in here to see if the London Ale Festival was on. After avoiding the perennial homeless guy outside asking for change to buy a beer, I got in to find a few other homeless types propping themselves up on the tables and making a beer last several hours. Unfortunately it came with the smell to match. Quick scan of the beer revealed no beer festival and just the very familiar brands. No decent bottles either. It seems like it's mainly popular with the local Jamaican over-65s brigade as someone else has pointed out here. With Craft Brixton one minute around the corner I cannot see any good reason to ever go in here again.


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Mechanism of C 2+ oxygenate synthesis on Rh catalystsTopics in Catalysis
Document TypeArticle
Publication Date3-1-2005
This paper examines the reaction pathways and the nature of active sites for CO hydrogenation in general and C2+ oxygenate synthesis over Rh catalysts in particular.
Citation InformationSteven Chuang, Robert W. Stevens and Rajesh Khatri. "Mechanism of C 2+ oxygenate synthesis on Rh catalysts" Topics in Catalysis Vol. 32 Iss. 3-4 (2005) p. 225 - 232
Available at: http://works.bepress.com/steven_chuang/16/


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Deep Rising (1998) 400MB 720P BRRip Dual Audio [Hindi-English] ESubs – HEVC
||Deep Rising (1998)||
[ Watch Online | BRRip | 400MB | Full Download ]
Deep Rising (1998) 400MB 720P BRRip Dual Audio [Hindi-English] ESubs – HEVC
Ratings: 6.0/10
Directed by: Stephen Sommers
Released On: 30 January 1998
Genre(s): Action | Adventure | Horror
Star Cast: Treat Williams, Famke Janssen, Anthony Heald
Synopsis: When a band of ruthless hijackers invade the world's most luxurious cruise ship, they're shocked to discover the passengers have mysteriously vanished! But that doesn't mean they are alone! Something terrifying is lurking just out of sight: a deadly force from the unexplored depths of the ocean that begins to snatch the horrified intruders one by one! Deep Rising 1998 300MB Full Movie Hindi Dubbed Free Download
Deep Rising (1998) Full Movie Watch Online 400MB 720P BRRip Dual Audio Free Download – HEVC


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Done by: Group 16 Ong Jie Hao (20) Lim Jingkai (15) Dickson Lim(14) Thio Teng Kiat (26). Murder most foul. Introduction. Solving the crime Evidence The Verdict Reflections. Solving the crime. Most difficult task: To find a link from the various evidences
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Lim Jingkai(15)
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