text:
Needs some tips for a short Melbourne getaway? If you have a travel question, email us at firstname.lastname@example.com.
Q. A few friends and I are heading for a 3 day trip to Melbourne at the end of October. we really don't know what to do to make the most of our time there. I read your article on Stuff and was wondering if you had any suggestions?
A. Name your passion and Melbourne can match it!
The end of October is a great time to travel as the weather is warming up however be aware that Melbourne can experience four seasons in one day. But that's just another great reason to purchase a fashionable coat while you're there!
This is a great city to discover on foot, the city will be particularly abuzz with Melbourne Cup fever in anticipation of the early November festival.
Love to shop? Melbourne is a haven for top designers, boutiques and luxury stores. DFOs are on offer; and for something a bit different then catch the train down to Chapel St or catch a tram (or walk as it's not far) to Fitzroy for new designer options.
Are you a culture vulture? The multiple theatres are alive with musicals and plays, there's always something on.
You're a foodie? There are more restaurants than days in a year. Melbourne is a melting pot of cultures and this is reflected in its restaurants, cafés, bistros and bars, feast on a dizzying spread of the world's great cuisines.
With so many funky laneways to explore, try a laneways tour to discover loads of boutiques, restaurants, cool bars and hole-in-the-wall cafés. Centre Place, Degraves St & Crossley St are some of the most popular.
Or jump on the famous city tram for a quick ride out to some of the cool city fringe suburbs like Brunswick, Fitzroy, Prahran & St Kilda for dining and a spot of shopping.
Plus markets are scattered across the city and are hugely popular. Some favourites include Queen Vic for fresh produce and cheese and South Melbourne Market for amazing food.
Rachel Mancini, Destination Product Manager - Australia, House of Travel.
Do you have any tips to share? Leave a comment below.
If you have a travel question, email us at email@example.com and we'll get the experts at House of Travel to provide the answer. Not all questions will be answered.
- Stuff
Sponsored links
Waitomo Glowworm Caves: New Zealand's greatest rock stars
Patagonia and Torres del Paine: Like nothing else on Earth
Fashion designer Kathryn Wilson: Why I love Queenstown
Nakasendo trail, Japan: A historic trek through the heart of old Japan
Vietnam travel: finding peace with the songbirds of Saigon in Ho Chi Minh City
Best places to eat in Hong Kong: Where the hip hang
The Maharajas' Express: The luxury train that's totally unreal
Beijing: Working up an appetite on the Great Wall of China
Montana: The reason why many Americans don't have a passport
Tourists flock to the world's steepest street to create 'bizarre' optical illusions
Myanmar's fortune tellers have bad news and good
36 hours in Ruapehu: Snow business is only part of the experience
Rio Olympics athletes' village deemed uninhabitable two weeks before opening ceremony
Wellington apartment with makeshift cubicle bedrooms labelled 'unlivable' by students
Massive waves close roads and destroy seawall amid weather chaos in Wellington
Tiger mauls woman to death in Chinese safari park
Faces of Innocents: Lisa Hope was killed the night before she was to be reunited with her mother
International Olympic Committee won't ban Russia from Rio 2016 Olympics
Disgruntled Cathay Pacific passenger rips roof off plane looking for locker space
WikiLeaks email trove plunges Democrats into crisis on eve of Convention
What is your favourite Australian city to travel to?


text:
Manage Subscriptions
Log Out
Log In
View Map »
View Photos »
Upload »
Get Alerts »
Prosecutor: Two Norwood businesses shut down as nuisances
Distributed by Internet Broadcasting. This material may not be published, broadcast, rewritten or redistributed.
Officials found $62,000 in cash stashed in a Colerain Township man's suitcase at the Dayton International Airport, authorities said.
No email address was supplied by
To complete your registration on this site, please supply an address.
Please confirm or modify the email address to which you will have subscription offers sent.
For a more personalized experience, please supply the following optional information.

subset: commoncrawl


text:
Your Financial Future
Today's economic environment presents many challenges. But along with these challenges comes opportunities and potential rewards for those who can identify long-term trends.
Whether you're facing retirement—or looking to better understand certain investment ideas—we can help you address your most pressing money questions.
Our first priority is your overall financial success. We want to learn more about your personal situation, identify your dreams and goals, and understand your tolerance for risk. Long-term relationships that encourage open and honest communication have been the cornerstone of my foundation of success.
Our site is filled with educational videos, articles, presentations, and calculators designed to help you learn more about the world of personal finance. As you search my website, send me a note regarding any questions you may have about any particular investment concepts or products. We'll get back to you quickly with a thoughtful answer.
Investment and financial planning services are offered by Jan Towne through her affiliation with HD Vest.
Helpful Content
A Taxing Story: Capital Gains and Losses
Understanding how capital gains are taxed may help you refine your investment strategies.
A Penny Saved is Two Pennies Earned
Here are some simple and inexpensive energy-saving tips that may help you save money.
A Primer on Irrevocable Life Insurance Trusts
Irrevocable life insurance trusts can be important tools that may accomplish a number of estate objectives.
U.S. Personal Savings Rate
What can be learned from the savings rate?
Options When Your CD Matures
Knowing your options when a CD matures can help you make a sound investment decision.
Building Your Legacy
A four-step framework for building a personal legacy.
Put It in a Letter
A letter of instructions provides additional and more personal information regarding your estate.
Is Term Life Insurance for You?
Term insurance is the simplest form of life insurance. Here's how it works.
Social Security: Five Facts You Need to Know
Here are five facts about Social Security that are important to keep in mind.
View all articles
A Look at Systematic Withdrawals
This calculator may help you estimate how long funds may last given regular withdrawals.
Disability Income
This calculator estimates your chances of becoming disabled and your potential need for disability insurance.
Paying Off a Credit Card
Enter various payment options and determine how long it may take to pay off a credit card.
What's My Potential Estate Tax?
This calculator helps estimate your federal estate tax liability.
Interested in a Fuel Efficient Car?
Estimate how many months it may take to recover the out-of-pocket costs when buying a more efficient vehicle.
Bi-Weekly Payments
This calculator estimates the savings from paying a mortgage bi-weekly instead of monthly.
View all calculators
5 Smart Investing Principles
Principles that can help create a portfolio designed to pursue investment goals.
Retirement Plan Distributions
There are a number of ways to withdraw money from a qualified retirement plan.
An Inside Look at Retirement Living
A number of questions and concerns need to be addressed to help you better prepare for retirement living.
Protecting Those Who Matter Most
The importance of life insurance, how it works, and how much coverage you need.
Your Cash Flow Statement
A presentation about managing money: using it, saving it, and even getting credit.
5 Smart Investing Strategies
There are some smart strategies that may help you pursue your investment objectives
View all presentations
Jane Bond: Scaling the Ladder
Agent Jane Bond is on the case, covering how bond laddering works.
Making Your Tax Bracket Work
Have you explored all of your choices when it comes to managing your taxable income?
Your DNA Test
If you have a family that relies on your income, it's critical to know what their needs would be in the event of your death.
The Cycle of Investing
Understanding the cycle of investing may help you avoid easy pitfalls.
What Can a Million Dollars Buy You?
$1 million in a diversified portfolio could help finance part of your retirement.
An Arm and a Leg
A visit to the hospital can be painful, for both your body and your wallet. Don't let it be more painful than it has to be.


text:
Monday Morning Dump
March 19th, 2012
The weekend is dead. It's monday morning which means it's time to get up wipe the crust from your eyes and stagger to the porcelain throne that is Slacker Network for the most important dump of the week. Our pic dump.
1 Comments / Add Comment
The weekend is dead. It's monday morning
Abum Macho Video Voomed Friday Funnies Funny Sh#t LiveDump Killer Kool Games One Humor BoredTown Heavenly Babes Melted Brain Click Humor Celeb Buzzer Shiny New Want Quotes & Jokes Humor and Fun NYUUZ Adult Humor Save Me From Boredom Viral Videos College Funnie Top 50 Funny Sites Fashionistas Interesting Articles


text:
The only 100% Free Online Dating site for dating, love, relationships and friendship. Register
HERE and chat with other Pitt meadows singles
A great guy to take me off this site?Bios are hard.. As are cover letters, and both are not my forte.I work in public relations, the fluffy kind not the controversial and political kind. I have two kids, I don't have a ton of f
North Vancouver British Columbia fi0na_ 33 Single Woman Seeking Men
Just Another ProfileHey there! So I'm Daniel :) Hungarian-born, Candian raised. School in Europe was intense to say the least.I'm a student in a Drafting and Design program. It's a ton of fun and I'm
Surrey British Columbia DanielRC93 23 Single Man Seeking Women
Looking for Mr RightWill complete later..................Promise ;))
Delta British Columbia pink9443 52 Single Woman Seeking Men
"Don't let the past dictate who you are "I am very outgoing,I love nature ,I love hiking ,and trying new thing.I'm very socialI'm studying to improve my English also so looking forward to go back to school to have a better career <
Tri cities British Columbia Feihl 35 Single Woman Seeking Men
Magic 8 Ball says: Outlook GoodHi there,Some of my hobbies are guitar, music, hockey, snowboarding, squash, movies, board games, and pretty much anything that takes place outside!I have a career, and I own my ow
ABBOTSFORD British Columbia Sunsofdawn 34 Single Man Seeking Women
I'm sorry for all my amazing jokes.Currently working as a 3D Character Animator on a Nickelodeon TV show. Used to be a teaching assistant so im pretty talkative and good at fixing problems. Not all to sure what else to say here...I hav
Vancouver British Columbia CASpike 19 Single Man Seeking Women
Writing the next chapter!About me....42 years old, 6' tall, fit, employed, motivated guy, dad to two amazing kids. Recently separated after many years. Not a player, rather the opposite. Enjoy reading, time with my
Abbotsford British Columbia BlondeScotsman73 42 Single Man Seeking Women
Hey fishies,Hey there---I'm a blue collar guy that works with stone. Been doing that for a couple years. I'm really just looking to meet some new people who are into similar things as me. I really like going
Vancouver British Columbia COLLINDEFELUR 24 Single Man Seeking Women
Looking for a new somethingFor some reason I still live. For some reason I still love. For some reason I will die. For some reason I live on. In my life there are no distractions. I wake up, I live life, I eat, I go t
Delta British Columbia chezdaily 34 Single Man Seeking Women
The only 100% Free dating service. Register HERE to use this Free Dating Service, and start contacting other users for free
Trying this site!Hi there, I cannot guarantee you that we already have a lot in common, but if you read on and find out we do, give me a message!I want someone who will be upfront, honest and I will do the same.
Surrey British Columbia loveitliveit13 38 Single Man Seeking Women
1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30


text:
A Step-by-Step Guide for ParentsMost children are afraid of the dark. Some fear monsters under the bed. But 10 percent of children have excessive fears and worries—phobias, separation anxiety, panic attacks, social anxiety, or obsessive-compulsive disorder—that can hold them back and keep them from fully enjoying childhood. If your child suffers from any of these forms of anxiety, the program in this book offers practical,
$3.99Matt Daly and his father first come to Montana Territory driving a herd of Texas longhorns in the 1880s. They, like many others, are determined to make a living on the lawless frontier. After finding an ideal spot to homestead, they start a ranch, the D Rocking D. Life is hard, but fulfilling, as there is money to be made selling beef to the exploding population back east.When the train comes
$3.99Growing up in Montana, Sky Daly's life is close to perfect. Living on the D, the cattle ranch started by her ancestors in the 1880s, she has almost all she could ever want. Her only cause for discontent is her mother, Ursula, who seems determined to make her life miserable.Once she graduates from high school everything changes. There is no longer a place for her on the ranch. Traditionally girls
Old Bill Miner: Last of the Famous Western Bandits
Last of the Famous Western BanditsBill Miner, the gentleman bandit, enjoyed more popularity in his day than Jesse James or Billy the Kid. He robbed stagecoaches and trains across California, Colorado, Arizona, Georgia, Washington State and British Columbia until just before the First World War, by which point the public actually wanted him to escape the police. Reporters visited him during his time in jail and dubbed him "Old Bill
Wilderness Tales: Adventures in the BackcountryThese true stories of people who work and live in the spectacular mountain wilderness of Alberta and British Columbia are filled with humour, keen observations about man and nature, and memorable human and animal characters. Old-time cowboys Johnny and Cal offer their no-nonsense brand of homespun wisdom. Wasp, the talented saddle horse, teaches his rider more than just horsemanship. From life-and
Bear Child: The Life and Times of Jerry Potts
The Life and Times of Jerry PottsThe West was a lawless domain when Jerry Potts was born into the Upper Missouri fur trade in 1838. The son of a Scottish father and a Blood mother, he was given the name Bear Child by his Blood tribe for his bravery and tenacity while he was still a teen. In 1874, when the North West Mounted Police first marched west and sat lost and starving near the Canada-U.S. border, it was Potts who led them
How I Survived Five Years in the Canadian BushThe view 16-year-old Thomas Osborne first had of Muskoka was at night, trudging alone with his even younger brother along unmarked primitive roads to find their luckless father who, in 1875, had decided to make a new start for his beleaguered family on some "free land" in the bush east of the pioneer village of Huntsville, Ontario. The miracle is that Thomas lived to tell the tale. For the next
Enjoying the Last of the Mountain MenThis book is a celebration of life. Its astonishing view is from the perspective of someone living a simple, isolated life in the Rocky Mountains as a ?mountain man.? Sylvan Ambrose Hart was born in the Oklahoma Territory in 1906. In the 1930's, while still a young man, he walked into the Rocky Mountains and designed a unique life for himself in the wilds - hunting, fishing, trapping, panning gold
Fifty Shades of Grey as Told by ChristianSee the world of Fifty Shades of Grey anew through the eyes of Christian Grey. In Christian's own words, and through his thoughts, reflections, and dreams, E L James offers a fresh perspective on the love story that has enthralled millions of readers around the world.Christian Grey exercises control in all things; his world is neat, disciplined, and utterly empty—until the day that Anastasia
Denny's Trek: A Mountie's Memoir of the March West
A Mountie's Memoir of the March WestLike many other pioneering North West Mounted Police officers, Cecil Denny was a colourful, independent man with a career full of conquests and controversy. He and his comrades played key roles in the taming of Canada's wild and woolly west, and in this compilation of selected writings from his books The Law Marches West and The Riders of the Plains, we get that story straight from the horse's
Gold Fever: Incredible Tales of the Klondike Gold RushIn 1897, tens of thousands of would-be prospectors flooded into the Yukon in search of instant wealth during the Klondike Gold Rush. In this historical tale of mayhem and obsession, characters like prospectors George Carmack and Skookum Jim, Skagway gangster Soapy Smith and Mountie Sam Steele come to life. Enduring savage weather, unforgiving terrain, violence and starvation, a lucky few made


text:
They say you can never be the same once you have seen the sun /moon shine from the other side.
38000 ft above, 1hr 45minutes, that's how long it took to land in Ethiopia where problems of going natural, gaining volume and hair growth all together are a thing of the past. So for a minute I was caught up between the hair and the length.


text:
Bollywood Reports
Kabali 7th day collection total overseas box office earning income &...
Kabali had done amazing world on box office. Kabali 7th day collection is still getting amazing box office earning around the world. Kabali is a...
Hollywood Box office in India
- All
- Bollywood
- Celebs Update
- Featured
- Filmy Wallpapers
- Hollywood
- Kannada Cinema
- Malayalam Cinema
- Marathi Cinema
- Predictions
- Punjabi Cinema
- Tamil Cinema
- Telugu Cinema
Bad Moms movie review, rating & box office collection earning prediction
This is the time to make way for the Bad Moms! Yeah, you read it right. 'Bad Moms' an American movie with a lot...
Disney's The BFG box office collection | Review | Rating |...
Disney's The BFG means the big fat giant is all set to release soon and hit the big screens. The movie is based on...


text:
Ah, what can I say about Hentai Lovers that hasn't already been said by concerned psychiatrists everywhere? How about, people who jerk off to anime are greasy perverts who will grow up to become professional upskirt photographers and snap shots of fat women's underwear at the local mall to upload to hideously designed voyeur websites. I'd bet the farm on it.
The difference between myself and the Japanese is that I walked in on my father watching some black guy drill some dumb blond. Japanese kids walk in on their dads watching some tentacle rape plant monster fuck a schoolgirl in all three inserts.
That's the way!
It should be noted that this guy has attempted to rape little girls but was beat up every single time. Better luck next time buddy.
"Daisuke" needs a good whipping. Get my belt.
I can't believe that a picture of a woman with seven breasts with cocks for nipples that are spewing forth shit could be downloaded 217 times but hey, you learn something every day.
My penis has actually crawled inside of my body and won't come out. Thanks for nothing "yojimboiscool4"!
I'm forwarding this to your mother young man!
I was betrayed by the bernio bros, the cougars, and this guy from back page I hired to keep me from jumping out a window at the DNC.
TOTAL WRECK - crazy-eyed hound is covered in cobwebs, has a vespiary on back, graffiti on side and savage thirst for boat fuel. Frankly, I'm in over my head. He's in room 115 at Motel 6, yours free. 555-2851
Hillary Clinton has a new book! Here are some photo-shops of her, for you to enjoy.
Thirty games and a novel piece of hardware for sixty dollars? This is an insult to my honor.
Selling objects to the past, lighters, weed, etc. Pretty intriguing stuff.
There are hundreds of stories happening on the World Wide Web. Let me tell you, that's a very wide web. Our goal at Weekend Web is to bring you the latest headlines from around the Internet. We go into the very bowels of message boards everywhere and find out what millions of online citizens have to say.
Copyright ©2016 Rich "Lowtax" Kyanka & Something Awful LLC.


text:
Exclusive: Icahn Says Netflix Doubters Are Wrong
Oct. 31 (Bloomberg) -- Billionaire Carl Icahn took a ten percent stake Netflix. He speaks exclusively to Trish Regan on Bloomberg Television's "Street Smart." (Source: Bloomberg)
Most Recent Videos
Bank of England Hints Back Stimulus Expectations
12:26 - In today's "Morning Must Read," Bloomberg's Tom Keene highlights comments on expectations for stimulus next month from the Bank of England. He speaks on "Bloomberg Surveillance." (Source: Bloomberg)


text:
Andersen Construction Company, Inc.
250 - 499
20 - 50 Million
Construction/Agriculture->Construction Services
SIC Code:
1531 - Operative Builders
Full company description is available with the free trial.
Additional Info:
Have you been searching for Andersen Construction Company, Inc.'s contact information for hours? Have you been trying to find Andersen Construction Company, Inc.'s domain format email addresses?. Andersen Construction Company, Inc. is a Construction services and is based in Portland, OR and more information like linkedin facts, phone numbers, cfo executives and facebook profiles can be found within the Lead411 profile. If you sign up for our free trial you will see our firstname.lastname@example.com addresses.
Company Background:
Full company description is available with the free trial.
Similar Companies:
A&J Electric
A&J Electric, a business led by CEO , is part of the Construction services industry. A&J Electric email with the @aandj-electric.com format, you can check their Lead411 profile. They hold their main office in Forest Grove, OR and more data like cfo contacts and linkedin data can be found within our profiles. If you sign up for our free trial you will see our firstname.lastname@example.com addresses.
Aadland Evans Constructors Inc
Want to know how to get in touch with them? Lead411 has the email addresses of Aadland Evans Constructors Inc's top officials for the company domain @aadlandevans.com format. Aadland Evans Constructors Inc is a Construction services company centred in Portland, OR and our profiles could include more contact information like cfo people, linkedin contacts, phone numbers and facebook pages. If you sign up for our free trial you will see our email@example.com addresses.
ABC Roofing Co
Lead411 offers quality contact information on a variety of companies including that of ABC Roofing Co's CEO . The company profile also contains facebook info, linkedin accounts, phone numbers, cfo contacts, and ABC Roofing Co email addresses with the domain format of @abcroofingco.com. ABC Roofing Co, is in the Construction services field. If you sign up for our free trial you will see our firstname.lastname@example.com addresses.
Company Directory > Andersen Construction Company, Inc.


text:
Separate names with a comma.
watch her in atlantic city
ariana grande is NOT a singer
it's still better than that pretentious dark night crap
weed's legal where i live but not to buy or sell
ban these stupid airshows. they're way too dangerous. what's the big thrill about watching planes fly in formation or do loops anyway?
ravens won the SB despite being the most penalized team that year
batman (1989) is better than any nolan movie
it was no batman and robin but it was ok
says a garbage poster
ur the moron. why would anyone invade sweden? dumbass
u suck loser
i'm sure that's what everyone says about u
ur an idiot
derp ur so funny derp
she wasn't born rich like Jeb Bush. talk about representing ppl he has nothing to do with
who's that 10 year old?
best thread title ever
why should we go to war cause 2 other countries are at war?
i'm sure ur gonna sign up for the army as soon as we invade iran right?
ur a fucking moron
yeah we should invade and take over their country and every other country with nuclear reactors
if u don't want to live in a country where all ppl are equal them move. dickhead
so only liberals care about animals being tortured? what kind of dick are u?
don't tell me what to do asshole
u didn't like looking at jennifer lawrence's butthole?
woohoo 100th post
construction workers?
he hates everybody. the end
they don't need a military at all. no one is going to invade sweden. u watch too many action movies. that shit ain't real
wes anderson sucks
ur a fucking retard
cut back on social programs that allow them to have a high standard of living just in case of some fictional invasion that would never happen? ur a...
ur a fan of a rapist?
he's got the fastest receiver in the league and he still sucks
no abortions ever but guns for everyone!
no ur embarrassing
too bad u weren't aborted
ESPN covers foosball now? must be a slow news day
wrong, moron
OP is an idiot
hell no
any malt liquor
I'm 44 u fucking retard
right now jenner's an it
the truth about whitewater is that republicans wasted alot of taxpayer money and found out nothing incriminating in the whitewater real estate case
that's conservatives who whine about violent video games and dirty lyrics
all hip hop is garbage not just the past 6 years


text:
Researchers at ITbM developed a new nickel catalyst with a "Kabuto-like" structure that catalyzed the cross-coupling reaction between carbonyl compounds and readily available phenol derivatives, to form α-arylketones, which are found in many biologically active compounds.
Researchers at ITbM, Nagoya University developed a new nickel catalyst with a "Kabuto-like" structure that was found to catalyze the cross-coupling reaction between carbonyl compounds and readily available phenol derivatives, to form α-arylketones, which are found in many biologically active compounds (Kabuto = a helmet worn by Japanese samurai).
Nagoya, Japan – Professors Kenichiro Itami and Junichiro Yamaguchi of the Institute of Transformative Bio-Molecules (WPI-ITbM) and graduate students Ryosuke Takise and Kei Muto of Nagoya University have succeeded in developing a novel nickel catalyst to catalyze the cross-coupling reaction between carbonyl compounds and phenol derivatives.
Phenol derivatives are known to be readily available starting materials, and this reaction has enabled the facile generation of α-arylketone compounds (aryl = aromatic ring; ketone = a carbonyl (C=O functionality with a carbon oxygen double bond) bonded to two other carbon atoms), which constitute the framework of many pharmaceuticals and organic materials.
The study published online on May 20, 2014 in Angewandte Chemie International Edition, is expected to become an important tool in synthesizing biologically active molecules and a range of versatile organic materials containing the α-arylketone framework.
Cross-coupling reactions catalyzed by transition metals enables direct formation of carbon-carbon bonds, which is widely utilized in the formation of a vast number of organic frameworks. This strategy that won the 2010 Nobel Prize in Chemistry extends to α-arylation reactions, which allows incorporation of aromatic rings into carbonyl compounds through carbon-carbon bond formation, mainly using palladium as a catalyst. Many organic molecules such as amino acids contain carbonyl groups.
Thus, α-arylation, which links carbonyl compounds to aromatic rings present in an array of organic molecules, has been used as one of the main reactions to create the organic backbone of many pharmaceuticals and organic materials. Professors Itami and Yamaguchi along with co-workers have been working to develop a new economical catalyst to conduct α-arylation reactions using readily available phenol derivatives as starting materials. This reaction system is envisaged to lead to the facile production of α-arylketones on an industrial scale.
Conventional methods for α-arylation have used palladium as a metal catalyst. "Since 2009, we have been looking at the potential of nickel as a cross-coupling catalyst, which is a more economical catalyst relative to palladium", says Professor Yamaguchi, one of the leaders of this research, "through our endeavors to develop improved conditions, we have found that phenol derivatives can act as readily available aryl coupling partners", he describes. Aryl substrates have mainly utilized aryl halides, which are halogenated compounds resulting in toxic wastes. Phenol derivatives on the other hand are usually less toxic and are more readily available compared to aryl halides.
Itami and his group have been working on the development of new generation cross-coupling methods using nickel as a catalyst. They have already reported various cross-coupling reactions including those between aromatic compounds and phenol derivatives, C-H coupling reactions using esters along with reactions linking aromatic rings and alkenes. These pioneering studies have been accomplished by enhancing the reactivity of nickel through tuning of various ligands. One of the effective ligands discovered in 2011 is the dcype (1,2-bisdicyclohexylphosphinoethane) ligand, which is used with nickel to activate phenol derivatives. However, the nickel(dcype) catalyst was insufficient to initiate the cross-coupling between carbonyl compounds and phenol derivatives.
"We have screened various ligands and found that dcypt (1,2-bisdicyclohexylphosphinothiophene), which bears a thiophene (a 5-membered heterocycle containing sulfur) unit, acts as an effective air-stable ligand to improve the reactivity of nickel and bring about this reaction in high yield. Moreover, we were able to use a weak base to carry out this reaction, which improves the substrate scope of this reaction", explains graduate students Takise and Muto who carried out the experiments.
Development of this new nickel catalyst has enabled the creation of a variety of α-arylketone compounds, including an estrone derivative and an amino acid tyrosine derivative, both bearing the phenol moiety. Professor Itami elaborates, "Many natural products and bioactive compounds contain the α-arylketone framework. Our relatively low-cost nickel-dcypt catalyst has exhibited high activity to couple readily available phenol derivatives in high yield. This system has the potential to be applicable in the synthesis of molecules that can control biological systems of plants and animals, which is one of the main research themes running in our new institute (ITbM)."
This article "Nickel-Catalyzed α-Arylation of Ketones with Phenol Derivatives" by Ryosuke Takise, Kei Muto, Junichiro Yamaguchi and Kenichiro Itami is published online on May 20, 2014 in Angewandte Chemie International Edition.
DOI: 10.1002/anie.201403823
About WPI-ITbM (http://www.itbm.nagoya-u.ac.jp/)
The World Premier International Research Center Initiative (WPI) for the Institute of Transformative Bio-Molecules (ITbM) at Nagoya University in Japan is committed to advance the integration of synthetic chemistry, plant/animal biology and theoretical science, all of which are traditionally strong fields in the university. As part of the Japanese science ministry's MEXT program, the ITbM aims to develop transformative bio-molecules, innovative functional molecules capable of bringing about fundamental change to biological science and technology. Research at the ITbM is carried out in a "Mix-Lab" style, where international young researchers from multidisciplinary fields work together side-by-side in the same lab. Through these endeavors, the ITbM will create "transformative bio-molecules" that will dramatically change the way of research in chemistry, biology and other related fields to solve urgent problems, such as environmental issues, food production and medical technology that have a significant impact on the society.
Author Contact
Professor Kenichiro Itami
Institute of Transformative Bio-Molecules (WPI-ITbM), Nagoya University
Furo-Cho, Chikusa-ku, Nagoya 464-8601, Japan
E-mail: email@example.com
URL for Group Homepage: http://synth.chem.nagoya-u.ac.jp/
URL for ITbM Homepage: http://www.itbm.nagoya-u.ac.jp/
Public Relations Contact
Dr. Ayako Miyazaki
Institute of Transformative Bio-Molecules (WPI-ITbM), Nagoya University
Furo-Cho, Chikusa-ku, Nagoya 464-8601, Japan
E-mail: email@example.com
Nagoya University Public Relations Office
E-mail: firstname.lastname@example.com
Ayako Miyazaki | Research SEA News
Further information:
Pathogenic bacteria hitchhiking to North and Baltic Seas?
22.07.2016 | Alfred-Wegener-Institut, Helmholtz-Zentrum für Polar- und Meeresforschung
Unconventional quasiparticles predicted in conventional crystals
22.07.2016 | Max-Planck-Institut für Chemische Physik fester Stoffe
Munich Physicists have developed a novel electron microscope that can visualize electromagnetic fields oscillating at frequencies of billions of cycles per second.
Temporally varying electromagnetic fields are the driving force behind the whole of electronics. Their polarities can change at mind-bogglingly fast rates, and...
Breakup of continents with two speed: Continents initially stretch very slowly along the future splitting zone, but then move apart very quickly before the onset of rupture. The final speed can be up to 20 times faster than in the first, slow extension phase.phases
Present-day continents were shaped hundreds of millions of years ago as the supercontinent Pangaea broke apart. Derived from Pangaea's main fragments Gondwana...
Scaffolding and specialised workers help with the delivery – Heidelberg biochemists gain new insights into biogenesis
A type of scaffolding on which specialised workers ply their trade helps in the manufacturing process of the two subunits from which the ribosome – the protein...
Scientists at the Helmholtz Zentrum München have developed a new mass spectrometry imaging method which, for the first time, makes it possible to analyze hundreds of metabolites in fixed tissue samples. Their findings, published in the journal Nature Protocols, explain the new access to metabolic information, which will offer previously unexploited potential for tissue-based research and molecular diagnostics.
In biomedical research, working with tissue samples is indispensable because it permits insights into the biological reality of patients, for example, in...
Chemists at the University of Basel have succeeded in using computer simulations to elucidate transient structures in proteins. In the journal Angewandte Chemie, the researchers set out how computer simulations of details at the atomic level can be used to understand proteins' modes of action.
Using computational chemistry, it is possible to characterize the motion of individual atoms of a molecule. Today, the latest simulation techniques allow...
GROWING IN CITIES - Interdisciplinary Perspectives on Urban Gardening
15.07.2016 | Event News
SIGGRAPH2016 Computer Graphics Interactive Techniques, 24-28 July, Anaheim, California
15.07.2016 | Event News
Partner countries of FAIR accelerator meet in Darmstadt and approve developments
11.07.2016 | Event News
Hey robot, shimmy like a centipede
22.07.2016 | Information Technology
New record in materials research: 1 terapascals in a laboratory
22.07.2016 | Physics and Astronomy
University of Graz researchers challenge 140-year-old paradigm of lichen symbiosis
22.07.2016 | Life Sciences


text:
and slime
and slime
why is
Originally Posted by thelastgreatman
1/18 Volcano Choir - The Fonda
1/22 Vampire Weekend - USC
2/14 Spiritualized - Ace Hotel
3/8 Mark Kozelek - First Unitarian Church
3/18 Kraftwerk - Walt Disney Concert Hall
3/19 Kraftwerk - Walt Disney Concert Hall
Just remember if you headline coachella and don't get played on kroq then you're not a rock band
Just remember, you're functionally uncultured and noticeably less intelligent than most people here.
7/22-24: Sunset Campout @ Belden Town
7/25: Ultimate Painting @ The Chapel
7/29: Woods, Gun Outfit, Cian Nugent @ The Chapel
7/29: Lucy @ f8
7/30: Robag Whrume, Sassmouth, Solar @ Mighty
8/3: Margo Price @ Gundlach Bundschu
8/25: Gold Panda @ The Independent
Am I seeing things or did Vigo just make 4 posts in a row? Why can't he say what he has to say in one post so I don't have to keep scanning through his ignored posts?
it's summer, baby.
you're all skantz
Truth: I enjoy Vigo's posts almost 100 times more than I enjoy Amy'zz.
6/27 - Anderson Paak - The Theatre at the Ace Hotel - LA
Your out of your fucking mind.
what you don't like stories about kids?
For those of you just tuning in, the thread has slowly turned into a long, uncomfortable holiday dinner, played out over several days.
In other news, hey! Rocket from the Crypt is touring again.
Coachellas attended: 2007-present
My ignore list is growing exponentially this week. Thanks, guys.
it's summer, baby.
Coachellas attended: 2007-present
July 16 - Cough
July 19 - Dragged Into Sunlight
July 29 - Inter Arma
August 12-14 - Migration Fest
August 16 - Monolord
August 26-28 - Psycho LV
September 7 - Cobalt
September 12 - Kraftwerk
September 17 - Melvins
September 20 - Wolves In The Throne Room
September 21 - Kanye West
September 30-October 2 - ACL wk.1
October 7-9 - ACL wk.2
October 11 - Failure
October 21 - Sleep
October 22 - Sleep
October 23 - Sleep
November 6 - Sia
November 12 - Black Sabbath
They sure did.
Not every band is going to have a radius clause. I certainly don't see why a band playing at the fucking Troubadour of all places would make them ineligible from playing Coachella.
Upcoming shows
Facebook // Twitter // Blog // Tumblr // Instagram
Coachella: 04,06,07,09,10,11,12(1&2),13(1&2),14(1&2),15(1&2), 16(1&2)
We Have To Go Back: The LOST Concert w/ Michael Giacchino 9/22, Tegan and Sara 10/1, Kanye West 10/22
SDCC 7/21-24, OSL 8/5-7, FYF Fest 8/27&28, Coachella 2017 WK 2


text:
7 photos
$2,800,000 206.54 acres 1901 CR 248, Georgetown, TX 78633 - Williamson County
Chalk Mountain Ranch
206 Ares of Amazing Topography with Chalk Mountain Point at about 1100' Elevation to View the Beautiful Countryside of Williamson County. 1960's Cabin about 1608 sq. ft located on property with full utilities. Abundance Fauna & Flora! Located just off of Ronald Reagan near the Williams Drive intersection offers convenient access to Highly Desired Austin, Texas! This property has been in cattle operation for many years possessing Williamson County Agricultural Status for lower property taxes. If you seek a Serene and Private Ranch to Call Home or looking for that Perfect Recreational Ranch not far from town; This is the PLACE for you! Land can be a Lucrative Investment. Williamson County continues to be one of the fastest growing co
Norma Carleton, ALC Consult Carleton - Keller Williams Realty


text:
Bulk Food
- Snack Foods
- Crackers
- Oyster Crackers
- Nabisco Premium Soup and Oyster Cracker
- Last products viewed
Nabisco Premium Soup and Oyster Cracker Product ID: OT521355 Nabisco
- "Thank you for being able to supply my order. I was completely satified with the items. Please continue to stock this item, and please let me know of any specials/sales. --I will definitely be ordering again in the future.
- "I have loved Girards Original French Salad Dressing since I was a kid growing up in California. While our local Safeway sometimes has the Italian dressing, they have never gotten the French in, even when we requested it. I was delighted to find a source for this old favorite. My order got here quickly after I placed it, and in great shape. Thank you!!!
Nabisco Premium Soup and Oyster Cracker
Product Id: OT521355
Sold as: Case of 12Weight: 6.75 lbs
List Price: $60.42Savings: $10.77
DescriptionSpecial Order Item No ReturnsFood Item No ReturnsNabiscoMfg#: 02477
Premium Soup and Oyster Crackers are light, crisp little crackers that bring out the best in stews, soups, chowders and chiles.
Premium Soup and Oyster Crackers - 9 Ounce -- 12 per case.
INGREDIENTS: Unbleached Enriched Flour (Wheat Flour, Niacin, Reduced Iron, Thiamine Mononitrate [Vitamin B1], Riboflavin [Vitamin B2], Folic Acid), Soybean Oil*, Salt, Partially Hydrogenated Cottonseed Oil*, Yeast, Baking Soda. Contains: Wheat. *Adds A T
Food items cannot be returned.
Hot products
Welchs Strawberry Jam Portion Pac product id: OT435561 Jams and Jelly
McCormick Red Food Color product id: OT394115 Baking Ingredients
Our commitment to you
We are so glad you stopped by FoodServiceDirect.com. We stock over eighty thousand foodservice products including Nabisco Premium Soup and Oyster Cracker. If you need any info about Nabisco Premium Soup and Oyster Cracker or any of our other items call us at 757-245-7675 Join our group of 230,000 satisfied customers! Whether you are a restaurant owner or a consumer - you can count on FoodServiceDirect.com to be a reliable supplier of Oyster Crackers.


text:
- Services
- 3rd party Integration, Accessibility, Content strategy, Data migration, Deployment, Design, Development, E-commerce, Front-end Development, Information architecture, Mobile App Development, Mobile Site Development, Multilingual websites, Multisite installations, Performance Tuning and Optimization, Project Management, Quality Assurance, SEO, Support, Theming, Upgrades
- Sectors
- Community, E-Commerce, Education, Enterprise, Government, Non-profit, Publishing, Technology
- Locations
- Sweden
- Headquarters
- Gothenburg
Kodamera is a web development company specializing in open source with expertise in the implementation of all types of web projects. They offer solutions for any size or purpose of project - from simple corporate sites to advanced systems for web-based applications and integrations.
Kodameras diverse and experienced teams takes care of all the elements in the development of new sites and systems - providing tailor-made solutions with superior design and programming. We offer:
- Strategy, concepts and ideas
- Web architecture and graphic design
- Implementation
- Support, service and optimization
If you have any questions you'd like to ask us about your website or project, please feel free to contact us!
Första Långgatan 16
413 28 Gothenburg
+46 (0)31-252501
Drupal contributions
Kodamera has contributed to the Drupal community in many ways:
Outreach - we market Drupal to our clients and other organisations in Sweden
As sponsors of DrupalCon Barcelona 2007 and DrupalCamp Stockholm 2009
Arranging local Drupal meetups
By writing patches for contrib modules and core
By maintaining these modules:
Video Filter (co-maintained by Blackdog)
Twingly (maintained by Freakalis)
Printfriendly (maintained by anon)
Domain User Edit (maintained by Blackdog)
Doman Node Options (maintained by Anon & Blackdog)
LinkIt (maintained by anon)
By being one of the maintainers of the Swedish Translation Project and the Swedish Translation Server
Projects supported
On Drupal.org for 9 years 2 months
On Drupal.org for 8 years 7 months
Contributor to Webform Simple Quiz
On Drupal.org for 6 years 4 months
Contributor to Video Filter
On Drupal.org for 6 years 3 months
On Drupal.org for 6 years 1 month
On Drupal.org for 6 years 1 month
Contributor to Hide blocks
On Drupal.org for 5 years 11 months
On Drupal.org for 5 years 6 months
On Drupal.org for 5 years 2 months
On Drupal.org for 4 years 10 months
On Drupal.org for 4 years 4 months
Contributor to Fb Comments Admin, Simple Cookie Compliance


text:
For our third annual list, we sought to highlight literature that exposes readers to cultures and ways of life that may be different from their own...
Condition: Standard
All Product Details
Lieutenant Robin Lefler: An eternal optimist, Lefler ocassionally asks the wrong question at the wrong time...and yet this time it may lead the Excalibur crew to unexpectedly shocking answers.
Commander Elizabeth Shelby: Walking the fine line between duty and conscience, Shelby may find that she must decide between the life she loves and the man she once loved.
As the Thallonian homeworld faces catastrophe, Captain Calhoun must confront his own bloody past in a life-or-death struggle for survival and honor. But when the planet's ultimate secret is revealed, only Captain Calhoun and the U.S.S. Excalibur can save the last remnants of the Empire from total destruction!
Help | Security | Shipping | Guarantee | Newsletters
Contact Us | About Us | Careers | Partners | Sitemap


text:
Dead Babies
How much fun can one have with dead babies?
Brink of Alienation
Machine gun aliens to death in this frantic run and gun series!
Neurotically Yours
The immensely popular series about Germaine and her squirrel Foamy!
i give all five stars! it was perfect and i hope there will be another!
movie good!!
The movie and epilogue -Stunning. Thats all i can say.
to read the text
Awesome looks like a movie!


text:
The average salary of a(n) Dental Assistant in Allentown, Pennsylvania is $41,380.
The average hourly rate of a(n) Dental Assistant in Allentown, Pennsylvania is $19.89.
The average bonus of a(n) Dental Assistant in Allentown, Pennsylvania is $679.00.
Heartland Dental, LLC
Dental Assistant – DA/General Dental Assistant. Dental Assistant Functions. Additional requirements for the Dental Assistant include:....View job on Indeed.com
St. Luke's Hospital & Health Network
Graduate from an ADA-accredited dental assisting program or dental assisting experience of 3 years +;...View job on Indeed.com
Suburban Dental Associates
We are looking for an experienced dental assistant to work with our specialists. If you have experience with Perio, Oral Surgery and Orthodontics, we would love...View job on Indeed.com
Dental Dreams
Completion of a Dental Assistant program. Dental Dreams is now hiring a Dental Assistant to join our talented and dedicated team....View job on Indeed.com
Spark Orthodontics
Dental experience required. Is a growing orthodontic practice seeking full-time Orthodontic Assistant. Spark Orthodontics, P.C....View job on Indeed.com


text:
Contact Us
"Imagination Interactive Counting Coloring Book" is designed to help children develop their imaginations and sense of personal accomplishment, according to the book's creator.
After almost six years of serving local residents coffee, lunch and community fellowship, Square Perk Café has closed its doors starting Friday.
At a luncheon held in her honor, Josephine B. Brown, the Executive Director of Newton County Senior Services, symbolically turned over the keys to her ...
State, county and local dignitaries turned out early Thursday to celebrate the groundbreaking for the new terminal at the Covington Municipal Airport.
As the two grand finales of fireworks went off simultaneously during the 2015 Independence on the Square in Covington, some spectators staring up at the ...
Several cities in Newton County are hosting celebrations for the 2016 Independence Day holiday. Check below for events in Covington, Oxford, Porterdale and Social Circle.
Several Special Weapons and Tactics (SWAT) Team members of the Newton County Sheriff's Office (NCSO) have completed or will complete specialized training at Barrow ...
A "one of a kind, massive, film, TV, music and video gaming production site" is close to coming to Covington.
Flint Hill Elementary School and Alcovy High School have been identified by the Newton County School System (NCSS) as potentially eligible schools for school choice.
It may just look like someone got creative with a spray can of paint, but law enforcement sees graffiti as a possible sign of gang ...
Robert Aiken, who lives in a home across the street from the Future Farmers of America (FFA) Camp, spoke to the board of commissioners about ...
The Hampton Inn Covington has received a 2016 TripAdvisor Certificate of Excellence Award. Now in its sixth year, the achievement celebrates hospitality businesses that have ...
Newton County Senior Services is the proud recipient of a new shuttle bus that will soon hit the road to transport senior residents to and ...
The 286th Graduation Class of the Georgia Public Safety Training Center-Athens Academy held their graduation on June 10 at the Winder Community Center.
Newton County Sheriff's Office Captain Keith Crum suggested that if parents start seeing gang symbols on their child's school, the need to pay ...
Page 4 of 8
Local defense attorney Stephanie R. Lindsey has announced her plans to run for superior court judge of the Alcovy Judicial Circuit.
A local economic development specialist was selected to sit on the board of directors of the Georgia Piedmont Foundation, a move that fits into the technical college's greater inclusion of Newton County.
For those who found themselves at their lowest point in life and had nowhere to turn and no one to turn to, Archie Shepherd must have seemed like a godsend.
The death penalty case of Rodney Renia Young is still scheduled for next month, but Pablo Fernando Maldonado's case has been postponed until the spring.
More than 45,000 children in Georgia were homeless at some point during 2010, several hundred of whom were in Newton County, according to national and local homeless advocates.
Emergency room visits continued to mount in 2011, as Newton Medical Center saw 3,000, or 6.7 percent, more visits than in 2010.
The youngest of a group charged in the September beating death of 59-year-old Fred Layne Beeler has been granted a bond, although he has yet to post the amount needed to earn him freedom from the Newton County Jail.
While the previously proposed downtown civic center sits in limbo, officials are wondering if a new airport terminal building could be the city's premier conference center.
When Jim Weadick speaks, his words are chosen with the precision of a lawyer and his eyes have the attentiveness of an administrator, but his spontaneous and boisterous laugh is one of his most defining characteristics.
The Georgia Cattlemen's Association honored Ted Wynne at the Georgia Association of County Agricultural Agents meeting with the Outstanding County Agent of the Year award.
A 35-year-old Newton County man remains in jail after being charged with beating his girlfriend and keeping her from calling 911 for help early Wednesday morning.
The Happy Meal has gotten even happier for one Covington man. Christopher Hamilton, 26, won $52,000 when he scratched a Georgia Lottery instant ticket at a McDonald's drive-thru.
Newton Medical Center CEO Jim Weadick was honored with the R.O. Arnold Award at Thursday's night chamber annual meeting for his lifetime of community service to Newton County.
The 112-year-old Monticello Street home that caught fire Wednesday afternoon may be a total loss, according to Covington Fire Captain Tony Smith.
A night out with friends turned ugly after a fight between two women turned into a fight between their boyfriends as well and ended in one man getting shot in the head.
Page 388 of 641


text: Yankees dates to remember Caption / Share FEB. 25 Yankees vs. Florida State The Yankees' first game of the spring. Also notable because Heisman Trophy winner Jameis Winston pitches and plays outfield for the Seminoles. Could he be on the mound to face the Yankees? | (Credit: AP) 1 of 16 0 SHARES http://www.amny.com/sports/yankees-dates-to-remember-1.7147107 Key dates to watch for as the Yankees' 2014 schedule unfolds. http://cdn.newsday.com/polopoly_fs/1.7147825.1392919072!/httpImage/image.jpg_gen/derivatives/display_600/image.jpg SHARE Sports Yankees dates to remember 12:59 PM February 20, 2014 Key dates to watch for as the Yankees' 2014 schedule unfolds. More sports photos SHARE NYC, in your inbox. Sign up for NYC news plus the scoop on things to do, see and eat. submit More like this Pineda, pen help Yanks edge Astros Yankees trade Chapman to Cubs Sandy Alderson: Mets won't deal away top chips Comments


text:
Utahn battles raunchy TV online
'CleanTV' site will let e-mailers file complaints
As CBS and MTV continue to take heat from irate Super Bowl viewers over Janet Jackson's breast exposure last Sunday, a Utahn wants to help stoke the fires of discontent over TV obscenity at home and nationwide.
Steven DeVore, an entrepreneur whose past ventures include a yet-to-be released feature-length film on the Book of Mormon and lucrative mass distribution of audio books, said he plans to launch a new Web site on March 1 dubbed "CleanTV."
He decided to enter the fray over deteriorating network television standards after top leaders of The Church of Jesus Christ of Latter-day Saints, to which he belongs, urged their members to get personally involved last fall during the faith's semiannual general conference.
Elder M. Russell Ballard challenged Latter-day Saints to "stand up and say enough is enough, and recommended that we send e-mails to TV stations and advertisers," DeVore remembers, in the belief that if enough people speak up, things will change. That, coupled with admonitions by LDS Church President Gordon B. Hinckley and other leaders to shun degrading media, "just kind of got me thinking."
When he searched the Internet for groups that actively oppose raunchy TV, he found a few targeting major networks and the Federal Communications Commission, but nothing that got to what he believes is the real change agent local television stations and advertisers. He says they're analogous to the "clay feet" of the colossus described in the biblical book of Daniel, and he sees them as the "weak point" that the networks and major corporate advertisers rest on.
Local station affiliates are "paid to run network programming, and at same time they allocate spots for local advertising. They're able to take the ratings that network programs bring in and charge local advertisers to advertise on those ratings."
DeVore said his Web site www.cleantv.net will be configured so disgruntled viewers can pressure local stations and their advertisers with a few keystrokes, rather than navigating the "cumbersome and confusing" maze he said he encountered trying to register individual complaints on several other Web sites.
The e-mail program lets users select the names of stations, networks and both local and national advertisers, then simultaneously send them personalized e-mails "through the simple click of a submit button." According to the Web site, the e-mail will: "identify the shows the advertiser sponsored; highlight the specific offensive material in the shows; ask them to stop supporting the offensive programming; and tells them you will not purchase their products or services as long as they support the programming."
DeVore said he's now gathering volunteers from across the country who are willing to serve as "program monitors" charged with logging program content and getting residents in their areas involved in the e-mail campaign. After last week's Super Bowl incident, DeVore wrote a column about his efforts that was posted online in Meridian Magazine, a Web site geared toward Latter-day Saints. In the days since, he said he has received more than 100 e-mails from people across the country who logged on to his nearly completed CleanTV Web site and expressed interest in volunteering.
If TV stations and advertisers don't respond to the e-mail campaign, DeVore said, "we'll organize picketing" at the local locations. "We're looking at 280-plus media markets across the U.S. If you get this going, the affiliates will begin to put pressure on the networks."
His quest began shortly after hearing LDS leaders, when he focused on programming being aired on KSL-TV. Though the station made headlines when it refused to air the controversial sitcom "Coupling," DeVore said his survey of network TV found NBC, of which KSL is an affiliate, led the pack in offensive language and situations. He put up a Web site focused on KSL's programming.
- 2 homes, 3 other buildings damaged in...
- Author, activist speaks at Theodore Roosevelt...
- Why Pioneer Day is so important to Utahns
- 7 habits of mentally strong people
- 'None of it matters': Family grateful after...
- 'Catastrophic' arson fire destroys 10 Tooele...
- West Valley man killed in motorcycle crash...
- Applications being taken for justice court...
- Utah delegates finally stand and cheer... 93
- Utah GOP delegates finally fired up... 74
- The day after: Lee defends Cruz at GOP... 32
- Should mountain biking be allowed in... 28
- Local government board fostered... 16
- 2 charged in attack on gay men;... 16
- Utah Democrats headed to 'historic'... 16
- Can police-community relations be... 14


text:
John Coltrane Concert in Japan [1973] (Live)
1 rating
15 copies available
|List Price:
|You Save:
|$1.39 (10% Off)
Available: Usually ships in 1-3 business days
Format: CD
sku: G272
Brand New
Related products:
- by John Coltrane ~ Cosmic Music ~ $12.56
- by John Coltrane ~ Om ~ $11.68
- by John Coltrane ~ Sun Ship: The Complete Session (2-CD) ~ $26.98
CD Details
- Released: February 7, 2012
- Originally Released: 2012
- Label: Impulse Records
Song previews provided courtesy of iTunes
Product Description:
Personnel: John Coltrane (saxophone, percussion); Alice Coltrane (piano); Pharoah Sanders (bass clarinet, saxophone, percussion); Rashied Ali (drums).
Liner Note Author: Alice Coltrane.
Recording information: Koseinenkin Hall, Tokyo, Japan (07/22/1966).
Illustrator: Honeya Barth.
This single-disc Concert in Japan by John Coltrane's 1966 quintet is a reissue of the original double LP that was released as IMR 9036C in 1973. Its three selections include two long instrumental pieces and a spoken introduction of the musicians in Japanese. These performances are compiled from two Tokyo dates. This set is not to be confused with the four-disc document that includes both Tokyo concerts in their entirety. The band here performs a 25-minute "Peace on Earth," a ballad that Coltrane wrote especially for the tour, to express his empathy and sympathy for the nuclear destruction Japan experienced during WWII. The tune moves outside, but stays well within the realm of spiritual boundary-pushing that the band was easily capable of. Alice Coltrane's piano (she is introduced as "Alice McLeod" by the announcer at the beginning of the recording) is utterly lovely and keeps both Coltrane's and Pharoah Sanders' (who plays an alto on this tune) solos in check. Drummer Rashied Ali and bassist Jimmy Garrison show an almost symbiotic interplay. The longer piece is a medley of "Meditations" and "Leo," and it begins as intensely and fiercely as it does on the album of the same name. Lasting nearly 45 minutes, the piece is a free-for-all with both horn players shoving one another to the limits of improvisation with their chosen instruments, and on percussion. Alice's piano phrasings are less percussive that McCoy Tyner's were, but they are equally far-reaching in timbre, color, and texture. She, Ali, and Garrison manage to just barely tether this group to the earth. The remastering job comes directly from analog tapes, so the sound is warm, rich, and full. No Coltrane fan -- who doesn't possess the box anyway -- should be without this fine recording. ~ Thom Jurek
Jazz Way Out [Bonus Tracks] (CD)
$4.98 on SALE
View Details
Out of StockSave for Later
Classic Jazz: Jazz Masters (CD)
View Details
$5.98 on SALE
Leapin': His Best Tunes (CD)
View Details
Out of PrintSave for Later
The Complete Paul Chambers Sessions (2-CD)
View Details
$8.09 Super Savings
Thelonious Monk With John Coltrane (CD)
$9.90 Super Savings
View Details(47)
Coltrane Plays The Blues (CD)
$9.06 Super Savings
View Details(19)
Passages (CD)
View Details
$15.39 Super Savings
Levels and Degrees of Light (CD)
$10.77 Super Savings
View Details(2)
Things to Come From Those Now Gone (CD)
$10.77 Super Savings
View Details(2)
Young at Heart / Wise in Time (CD)
$14.26 Super Savings
View Details(3)
Lunghorn Twist (CD)
View Details
$15.16 Super Savings
Titration (CD)
View Details
$14.32 Super Savings
Adams: Nixon in China (CD)
View Details(21)
Pod (2-CD)
View Details
$14.18 Super Savings
Music Lovers' Ratings & Reviews:
Be the first Music Lover to write an online review of this product!
Similar Products:
Music Categories:
Product Info:
- Sales Rank: 45,620
- Shipping Weight: 0.19/lbs (approx)
- International Shipping: 1 item
Possibilities (DVD + Music CD)
99¢ on SALE
View Details(18)
Oh Girl / Somethin' Sanctified (CD)
$2.98 on SALE
View Details(7)
Fine And Mellow - Golden Classics (CD)
$2.98 on SALE
View Details(3)
Toast To Golden Classics (CD)
View Details
$2.98 on SALE
...Hello There, Universe (CD)
$2.98 on SALE
View Details(4)
High Voltage (LP)
View Details
$1.99 Super Savings
All Of You: The Last Tour 1960 (4-CD)
View Details
$15.69 Super Savings
History of Rock (10-CD Set)
$19.98 on SALE
View Details(6)
WJMK 104.3 - Great Ladies of Rock & Roll - The 60s (CD)
$2.98 on SALE
View Details(15)
History of Rock - JukeBox Giants, Volume 2 (CD)
$2.98 on SALE
View Details(11)
Summer Hits: 47-Song Collection (3-CD)
$8.98 on SALE
View Details(2)
The Best of Little Bitty Tear (CD)
View Details
$2.98 on SALE
Country Top Hits of the 50s, 60s, 70s and 80s (4-CD)
$19.98 on SALE
View Details(5)
Summer Fun: 43-Song Collection (3-CD)
View Details
$8.98 on SALE
History of Rock - JukeBox Giants, Volume 1 (CD)
$2.98 on SALE
View Details(6)


text:
Contact Us
Browse by:
Method for producing oxodicyclopentadiene
Method for producing oxodicyclopentadiene
Patent Drawings:
Ogasawara, et al.
Date Issued:
May 4, 1999
July 8, 1998
Ogasawara; Kunio
(Sendai, JP)
Taniguchi; Takahiko
(Sendai, JP)
Chisso Corporation
(Osaka, JP)
Primary Examiner:
Barts; Samuel
Assistant Examiner:
Keys; Rosalynd
Attorney Or Agent:
Browdy and Neimark
U.S. Class:
Field Of Search:
International Class:
U.S Patent Documents:
Foreign Patent Documents:
0 428 302; 08113544
Other References:
Takano, Seiichi et al., "Enantioconvergent route to alpha-cuparenone from dicyclopentadiene.", J. Chem. Soc. Chem. Commun., pp. 271-272(1989)..
Takano, Seiichi et al., "Expedient preparation and enantiomerization of optically pure dicyclopentadienone (tricyclo[5.1.0.sup.2,6 ]deca-4,8-dien-3-one)." Synletters, pp. 636-638 (1991)..
Tanaka, Keigo et al., "An expedient route to optically pure 3-endo-hydroxydicyclopentadiene.", Sythesis, pp. 1237-1239 (1995)..
Taniguchi, Takahiko et al., "Lipase-triethylamine-mediated dynamic transesterification of a tricyclic acyloin having a latent meso-structure: a new route to optically pure oxydicyclopentadiene.", Chem. Commun., pp. 1399-1400 (1997)..
Miller et al., Synthesis and Characterization . . . J. Org. Chem., vol. 41, No. 7, pp. 1221-1228, Apr. 1976..
Trost et al., Stereocontrolled Approach . . . J. Org. Chem., vol. 43, No. 24, pp. 4559-4564, Nov. 1978..
Optically active oxodicyclopentadiene is produced by adding lipase into ketoalcohol (1) and vinyl acetate, stirring them to obtain optically active acetate, and methylating and oxidizing to cleavage the reactant, and treating the product under basic conditions. ##STR1##
We claim:
1. A new method for producing an optically active ester represented by the following general formula (2): ##STR9## wherein R indicates straight or branched alkyl, alkoxy, alkenyl oralkenyloxy, comprising reacting an acyloin compound as a starting material represented by the following formula: ##STR10## with an acylating agent in the presence of lipase, and obtaining either (+)-or (-) of the esters represented by the above formula(2).
2. A method for producing an optically active ester claimed in claim 1, wherein the lipase is derived from Pseudomonas.
3. A method for producing an optically active ester claimed in claim 1, wherein the acylating agent is a vinyl ester.
4. A method for producing an optically active ester claimed in claim 1, wherein the lipase is derived from Pseudomonas and the acylating agent is a vinyl ester.
1. Field of the Invention
The present invention relates to a new method for producing optically active oxodicyclopentadiene which is an intermediate of pharmaceutical products and the like.
2. Description of the Prior Art
The optically active oxocyclopentadiene is very useful for starting materials of physiologically active materials such as pharmaceutical products. For example, it is known that the compound is a starting material of Aphanorphine having analgesiceffect (J. Chem. Soc. Chem. Commun., 290 (1990)).
However, a well-known methods for producing the optically active oxocyclopentadiene uses optical resolution (J. Chem. Soc. Chem. Commun., 271 (1989), Synlett., 636 (1991), and Synthesis, 1237 (1995)), so that one of the enantiomers becomesuseless. Accordingly, to use the one, it should be reacted via several steps to obtain the antipode.
The present inventors earnestly studied a method for producing only one of the enantiomers of optically active oxodicyclopentadiene, and the present invention has been completed by finding a method for producing optically activeoxodicyclopentadiene represented by formula (4): ##STR2## comprising reacting an acyloin compound as a starting material represented by formula (1): ##STR3## with an acylating agent in the presence of lipase, and obtaining either (+)-or (-) of the estersrepresented by formula (2): ##STR4## wherein R indicates straight or branched alkyl, alkoxy, alkenyl or alkenyloxy, further, introducing a methyl group to obtain a new optically active diol represented by formula (3): ##STR5## using the diol as anintermediate, and obtaining optically active oxodicyclopentadiene represented by the above formula (4).
The present invention is represented by the following reaction formula. For convenience sake, the case for obtaining a (-) material is shown: ##STR6##
Compound (1) of the starting material can be introduced via bistrimethylsiloxy compound (7) from endo-2,3-dicarbomethoxybicyclo[2,2, 1] hepta-5-ene (6) which is easily available by a method of Miller et al (J. Org. Chem., 41, 1221 (1976)). ##STR7##
The resulting compound (1) is then reacted with an acylating agent in the presence of lipase. Commercially available lipase may be used. As embodiments of the lipase, Lipase PS (manufactured by Amano Pharmaceutical Co., Ltd.), Toyoteam LIP(manufactured by Toyobo Co., Ltd.), Novozyme 435 (manufactured by Novo Nordisk) and the like can be exemplified.
Moreover, it is possible to use dry microorganisms and protein as it is extracted and refined from a culture solution. As the kind of lipase, particularly, the material derived from Pseudomonas is preferably used.
As acylating agents, fatty esters, acid anhydrides, triglycerides, trichloroethyl ester, vinyl esters can be exemplified. Particularly preferred agents are vinyl esters, such as vinyl acetate, vinyl propionate, vinyl capronate and vinylstearate. Further, isopropenyl acetate also can be used.
As reaction solvents, hexane, heptane, cyclohexane, benzene, toluene, 1,2-dichloroethane, dioxane, diethyl ether, diisopropyl ether, dibutyl ether, t-butylmethyl ether, THF, acetone, acetonitrile and DMSO can be exemplified. As additives,triethylamine can be added, and the rate is 1-30%, and preferably 10%.
The reaction temperature is suitably 10-100.degree. C., and preferably 20-45.degree. C. The reaction time is 1-1000 hours, and preferably 30-50 hours.
Such obtained compounds (2) are methylated with methyl magnesium iodide or dimethyl copper lithium which is a common methylating agent to obtain methylated compound (3).
Compound (3) is cleavaged in the presence of periodic acid to obtain ketoaldehyde represented by formula (5). ##STR8##
After the resulting aldehyde (5) is exposed to, for example, an aqueous alcohol solution containing sodium hydroxide and the like and treated under basic conditions, it is able to obtain compound (4).
By using the production method of the present invention, useful intermediates represented by formula (3) can be prepared, and from the compound (3), optically active oxodicyclopentadiene useful as a starting material for synthesizing manyphysiologically active materials can be obtained.
The following Examples are intended to further illustrate the present invention and not to limit the invention by these Examples.
Synthesis of (-)-ketoacetate (2)
To a THF solution (80 ml) of ketoalcohol (1) (4.5 g, 30 mmol), Et.sub.3 N (0.4 ml, 3 mmol) and vinyl acetate (3.3 ml, 36 mmol), and then Lipase PS (4.5 g, manufactured by Amano Pharmaceutical Co., Ltd.) were added, and the mixture was stirred atroom temperature for 48 hours. After completing the reaction, the reaction solution was filtered with Celite, and the solvent was distilled off under reduced pressure. To the residue water was added and the mixture was extracted with Et.sub.2 O, theorganic layer was washed with a saturated aqueous solution of NaCl and dried with MgSO.sub.4, and the solvent was distilled off under reduced pressure.
The residue was purified by silica gel chromatography (eluent: Et.sub.2 O/hexane=1/3 v/v), and colorless solid (-)-ketoacetate (2) (4.3 g, 75%) was obtained. Then, ketoalcohol (0.4 g) of the starting material was recovered.
[.alpha.].sub.D.sup.24 -120.7.degree. (c2.0, CHCl.sub.3), mp 28.degree. C. (Et.sub.2 O/hexane); IR (nujor, cm.sup.-1) 1786, 1743; .sup.1 H-NMR (300 MHz, CDCl.sub.3) d 6.14 (dd, J=5.5, 3.0 Hz, 1H), 6.01 (dd, J=5.5, 2.7 Hz, 1H), 5.35 (dd, J=8.8,3.3 Hz, 1H), 3.63 (ddd, J=7.4, 5.5, 3.3 Hz, 1H), 3.39 (ddd, J=8.8, 5.5, 4.7 Hz, 1H), 3.23-3.17 (m, 1H), 3.15-3.09 (m, 1H), 2.08 (s, 3H), 1.77 (br d, J=8.5 Hz, 1H), 1.53 (br d, J=8.5 Hz, 1H); HRMS m/z C.sub.11 H.sub.12 O.sub.3 (M.sup.+) calcd 192.0786,obsd 192.0828.
To an anhydrous THF solution (13 ml) of ketoacetate (2) (0.6 g, 3.1 mmol), a MeMgI solution (15.5 ml, 1.0M in THF) solution was added at a temperature of -78.degree. C., and the mixture was stirred at the same temperature for 2 hours. Aftercompleting the reaction, the reactant was diluted with Et.sub.2 O, added H.sub.2 O under ice cooling, and stirred for 5 minutes. The organic layer was washed with a saturated aqueous solution of NaCl, dried over MgSO.sub.4, and the solvent was distilledaway under reduced pressure.
The residue was purified by silica gel chromatography (eluent: AcOEt/hexane=1/5 v/v), and colorless solid (-)-diol (3) (0.43 g, 83%) was obtained (eluent: AcOEt/hexane=1/5 v/v).
[.alpha.].sub.D.sup.26 -15.7.degree. (c0.6, CHCl.sub.3), mp 107.degree. C. (AcOEt/hexane); IR (nujor, cm.sup.-1) 3394; .sup.1 H NMR (300 MHz, CDCl.sub.3) d 6.39-6.34 (br s, 2H), 3.87 (br d, J=7.1 Hz, 1H), 3.03-3.00 (m, 2H), 2.86-2.80 (m, 1H),2.62 (ddd, J=6.9, 4.9, 1.9 Hz, 1H), 2.20 (br s, 1H), 1.99 (br s, 1H), 1.47 (d, J=8.0 Hz, 1H), 1.32 (s, 3H), 1.11 (d, J=8.0 Hz, 1H); HRMS m/z C.sub.10 H.sub.14 O.sub.2 (M.sup.+) calcd 166.0993, obsd 166.1019.
To a THF-H.sub.2 O mixture solution (2:1 v/v, 3 ml) of (-)-diol (3) (80 mg, 0.5 mmol), NaIO.sub.4 (0.5 g, 2.5 mmol) was added under ice cooling, and the mixture was stirred for 2 hours. After completing the reaction, the reactant was dilutedwith Et.sub.2 O, the organic layer was washed with H.sub.2 O and a saturated aqueous solution of NaCl, and dried over MgSO.sub.4, and the solvent was distilled away under reduced pressure to obtain crude ketoaldehyde (5). The product was used for nextreaction without purification.
To an EtOH solution (3 ml) of the above-mentioned crude ketoaldehyde (5), an aqueous solution of 2% NaOH (1 ml) was added, and the mixture was stirred for 12 hours. After completing the reaction, an aqueous solution of 1% HCl was added under icecooling to neutralized the reactant, and the solvent was distilled away under reduced pressure. Water was added to the residue, the mixture was extracted with Et.sub.2 O, the organic layer was washed with a saturated aqueous solution of NaCl and driedwith MgSO.sub.4, and the solvent was distilled away under reduced pressure. The residue was purified by silica gel chromatography (eluent: Et.sub.2 O/hexane=1/3 v/v), and colorless solid (-)-oxodicyclopentadiene (4) (38 mg, 54% for 2 steps) wasobtained. The spectral data were agreed with values of references.
[.alpha.].sub.D.sup.26 -154.degree. (c 1.0, CHCl.sub.3), mp 74.degree. C. (hexane); referenced value [.alpha.].sub.D.sup.29 -158.5.degree. (c 1.0, CHCl.sub.3), mp 76.degree. C.
* * * * *
Recently Added Patents
Projection illumination system for EUV microlithography
Garden tool handle
Ion beam system and method of operating ion beam system
Information processing apparatus and update information obtainment method
Display fixture for highlighting products
Light-emitting device package and method of manufacturing the same
Systems and methods for optimizing capital structure of a financial institution
Randomly Featured Patents
Machine for extracting centrifuged pipe
Ultrasonic densitometer device and method
Thin-film transistor display devices having composite electrodes
Trench capacitor and corresponding method of production
Mapping uplink acknowledgement resource based on downlink control channel
Memory device containing a static ram memory that is adapted for executing a self-test, and integrated circuit containing such a device as an embedded static ram memory
Process for preparing zeolite Y with increased mesopore volume
Ultrasonic transducer for measuring the travel time of ultrasonic pulses in a gas
Cable connector
Transfer printing method
© 2006-2011. PatentGenius.com All Rights Reserved.


text:
Login or register to post comments
As a parent who walks that fine line in schools of also being an educator, I stumbled into a new parental frustration as my teenager hit high school. He had already begun to strategically avoid discussing school with his mom. In addition, parent access to information from the school about topics of study and homework assignments was becoming less and less available.
In just a few weeks, a group of educators will gather at Downers Grove North High School, a school located in the suburbs of Chicago. This event would not, at first glance, seem to be cause for celebration, much less notice. After all, there is probably a meeting in progress at every moment of every single school day in nearly every location throughout the globe.
view all
Contact Us Press
Privacy Policy Terms of Use


text:
Winnipeg's Assiniboine Park in the WinterNikon D30011-16mm Tokina f2,813mmf4ISO 800Handheld
Winter ScenesSunsetsThe PrairiesBlue
colorful winnipegger centre ggbphoto wide 1116 stage january2009 center magichour zoom 11mm16mm canadian ultrawideangle pavillion setting dslr sunset january field lyric blue f2 snow 8 winter very park jan purple ultra artist manitoba sun winnipeg ice tokina canada wideangle heart 16mm colour geoff color d300 11 2009 assiniboine vivid geoffrey
Very pretty!!!!
Thank you very much Yool :)
Thanks :)
Beautiful….fantastic capture Geoffrey :)
Thanks Orphie :)
lovely composition, amazing view
Thank you very much Antanas :)
That sure is a beautiful scene. love the backdrop of that sky
thanks Mel :)
I am from Minnesota. And you captured the cold blue of a day like this beautifully. Well taken.
Yeah, it's the clear blue sky of the deep cold. I've lived in many places a lot warmer, but I need the sun, even if it's cold :)
Fantastic winter scene!
Thanks, I'm looking forward to spring :)
yes it is, gorgeous!
10% off
for joining the Redbubble mailing list
Receive exclusive deals and awesome artist news and content right to your inbox.
Free for your convenience.


text:
The Minnesota Vikings have been in prime position to grab a playoff spot with a strong finish down this closing stretch of daunting games.
In their first test, they dropped the ball.
A lot.
The Vikings (6-5) emerged from an ugly 28-10 loss at Chicago still tied with Seattle and Tampa Bay for the second NFC wild card spot, but they've lost to both of those teams and thus must finish ahead of them. The loss to the Bears (8-3) on Sunday put a big dent in Minnesota's goal of becoming the surprise winner of the NFC North, too, leaving the Vikings in third place with little margin for error remaining.
They play at Green Bay (7-4) this Sunday and host Chicago again the week after that, with top-level performances required to win. And if they can't catch Christian Ponder's passes, well, the production by the rest of the team might not even matter.
Drops aren't an official NFL statistic, but anyone who watched the Bears game could've conservatively credited their receivers with at least six, including three for Jerome Simpson.
"The number of dropped passes we had yesterday was really unacceptable in our league," said coach Leslie Frazier, whose criticism of his players is usually limited and muted. "It's hard to continue drives when you don't catch the football, and that's a part of what you have to be able to do as a wide receiver in our league.
"The drops were not good. They hurt our continuity, our ability to move the football. So we have a lot of work to do. A lot to get done. I have a lot to do to get our team back, refocused on the task at hand for this next ball game."
Ponder had his share of erratic throws, including one that sailed past Devin Aromashodu for an interception that Chicago followed with a touchdown on the next play. Ponder finished 22 for 43 and again had little success with the deep ball. But his receivers did him no favors, with star Percy Harvin back in Minnesota still healing from a sprained left ankle.
"It's tough. You want to see everybody making plays and contributing," wide receiver Michael Jenkins said. "Nobody wants to drop a ball or have a bad play. Guys just have to bounce back and make the next one."
Frazier said he couldn't recall a game with so many drops by his team.
"We'll go back and do some drills and do some different things to try to help our guys to hold on to the football," he said, adding: "When your teammates see those opportunities disappear, it affects the entire team. It affects the guys on the field, affects the guys on the sideline."
Adrian Peterson lost a fumble, too, that directly led to a Chicago touchdown, and the defense can't escape blame, either. The first half was a collective failure, with a nonexistent pass rush and too many productive runs by the Bears on third-and-short. For the afternoon, they converted 11 of 19 third downs.
Chicago was coming off a 32-7 loss at San Francisco last Monday. But with a short week of preparation, the sting of that nationally televised shellacking and a slew of injuries on their offense despite the return of quarterback Jay Cutler, the Bears weren't deterred.
The Vikings will face a Packers team this Sunday under similar circumstances. Aaron Rodgers has taken more sacks than any other quarterback in the NFL, and they're coming off a 38-10 loss to the New York Giants.
"It's pretty simple. The Bears played better than we did. The things that went wrong are totally correctable. The Bears game is behind us now. The tape's done," center John Sullivan said. "We're focused on going out and beating the Packers."
Vikings dropped the ball (often) vs. Bears
Bear Report Top Stories
Under-the-Radar Bears: RB Jacquizz RodgersWhile everyone focuses on running backs Jeremy Langford and Jordan Howard, it's veteran ball carrier Jacquizz Rodgers who could have the biggest impact for the Chicago Bears this…
Bear ReportFriday at 8:51 AM
Bears secondary will be better than you thinkThere is a lot of trepidation concerning the Chicago Bears secondary heading into 2016 training camp, yet there are a number of reasons why this unit will play better than most…
Bear ReportThursday at 12:12 PM
Bears sign former Panthers G Amini SilatoluThe Chicago Bears have signed former Carolina Panthers interior offensive lineman Amini Silatolu.
Bear ReportWednesday at 1:34 PM
Bears Training Camp Preview: CornerbackOur pre-camp break down of the Chicago Bears cornerbacks, a positional unit filled with question marks, as well as some legitimate potential.
Bear ReportWednesday at 9:47 AM


text:
|$16.66 ($0.12 / Count) & FREE Shipping
Usually ships within 3 to 4 days. Ships from and sold by Connect Buy.
Other Sellers on Amazon
+ $5.99 shipping
+ Free Shipping
+ Free Shipping
Dixie Perfectouch Insulated Paper Hot Cup, Coffee Haze Design, 140 Count
- 16 ounce capacity
- 1 pack of 140 cups
- Comfortable, sturdy, non-slip feel
- Coffee Haze design
- Insulation reduces the need for an additional sleeve
Frequently Bought Together
Customers Who Bought This Item Also Bought
Product Description
Product Details
Size: 140 Count
Important Information
Actual product packaging and materials may contain more and different information than what is shown on our website. We recommend that you do not rely solely on the information presented and that you always read labels, warnings, and directions before using or consuming a product. Please see our full disclaimer below.
Customer Reviews
Top Customer Reviews
well insulated, exactly as described, great value!
Most Recent Customer Reviews
- I try not to use much Styrofoam or plastic because they can leach chemicals especially in hot drinks - so these are perfect.
- Great for hiding mixed drinks in public
It goes right into my face hole, and I can toss it if i want.Published 11 months ago by Graysen Harnwel
Great Quality Cups . Just As Good Or Better Than Your Famous Coffee Shops. Also It Has Good Insulation To Keep Your Hands From Feeling The Heat.Published 12 months ago by Busisiwe
Always have good luck with these..Good bargain and good quality..Published 14 months ago by TERRI HOLTERHAUS
Great price for 140 cups, it was delivered the next day! Awesome!Published 16 months ago by San Juana Gutierrez
All the coffee lovers in the office love these 16 oz insulated cups that keep the coffee hot.Published 17 months ago by CHRISTINE


text:
Crazy Substitute Teachers
Enjoy, NG4.04 / 5.00 1,432 Views
Vacuum Salesman
This dude and his Megazord vacuum cleaner3.98 / 5.00 2,404 Views
Markiplier Animated | Mark Of The Survey Corps
This took far too long to make...3.93 / 5.00 3,760 Views
LOL. This is a useless review.
Very nice sir
I've gotta say, that was incredibly entertaining. The drawing was nice, and it fit well with the voice acting. A bit short, but other than that, very nicely done.


text:
I was very satisfied with my purchase from MisterArt.com. It certainly won't be my last -- the delivery was on time, and there were no mistakes made in my order. Very refreshing!
More Testimonials »
Looking Glass Mirror-Like Paint
From $9.11
Magnetic Paint
Up to 54% Off
Make It Stone Faux Finishing Spray
From $8.21


text:
DIY: How to Start Your Home BusinessPosted by ivanpw under Startups
From http://www.smbceo.com 884 days ago
Made Hot by: SJC on February 23, 2014 6:57 am
In recent years, more people have decided to go into business for themselves, and many of them do it from their own homes. How to start one yourself?
Who Voted for this Story
Top BizSugar Users
This week's most active BizSugar users. Join Them!
Written by lyceum
881 days ago
881 days ago
Ivan: Great to hear! We have to have a talk soon... ;)
Written by lyceum
882 days ago
882 days ago
Ivan: Can you mention some do it yourself home businesses that you have come across during the years?
Written by ivanpw
882 days ago
882 days ago
I'm all into online business :D
Copywriting, online publishing, graphic design... the sky's the limit ;)
Copywriting, online publishing, graphic design... the sky's the limit ;)
Log in to comment or register here.
This Could Be One of the Most Underestimated Employee BenefitsJuly 20, 2015
What's more important than salaries at your small business? Small business owners and entrepreneurs sometimes believe they …Sponsored By Aflac
Fred Leo: BizSugar "Contributor of the Week"
Are you eligible to be our BizSugar "Contributor of the Week" on Facebook? Fred Leo is! So give him a big … MoreMore Contributors
Editor's Picks
Ti Roberts
Ti Roberts is an Internet marketer & blogger with over 7 years experience. On her blog, she enjoys teaching her following how to generate traffic via Blogging, Social …


text:
Austal announced an expansion of its European service presence with the establishment of a maintenance hub on the Strait of Gibraltar. Based in Southern Spain and Northern Morocco, the new operations will support the extensive fleet of Austal and non-Austal high speed craft currently operating on the Strait of Gibraltar. Austal Managing Director Bob Browning said "This strategic move positions Austal near a region with high demand for vessel maintenance and management services."
The new operations will support the ports of Algeciras and Tarifa in Spain, and Tanger Ville and Tanger Med in Morocco, and will be staffed by members of Austal's existing maintenance team as well as local personnel.
The announcement follows last month's contract for the maintenance of seven large high speed craft with Oman's National Ferries Company. Austal recently established service hubs in Egypt and Oman, with a regional office in the United Arab Emirates to open in coming months.
Maritime Today
The Maritime Industry's original and most viewed E-News Service
Singapore oilfield services company Swiber Holdings Ltd said on Friday it has applied to place itself under judicial management instead of liquidation.
A ceremony will be held July 29 at Cenac Marine Services headquarters in, Houma, La. To commemorate the christening of its newest vessel, M/V Quincey Cenac, as
Facing a "gradually deteriorating market," Sweden based tanker shipping company Concordia Maritime said it was able to post a profit in Q2 2016 based on high vessel
In June 2016 Horizon Shipbuilding, Inc. of Bayou La Batre, Ala. delivered the M/V Marty Cullinan, a 120' towboat with a retractable pilot house, to its home port of New Orleans, La.
The North Carolina Department of Transportation recently took delivery of a new, fully customized cutter suction dredge, which it christened the Dredge Manteo in a ceremony held April 28,
Elomatic Ltd and Deltamarin Ltd have signed a tri-party engineering contract with shipbuilder MV Werften for the design of Star Cruises' new Global Class "mega passenger ship,


text:
Professor accused of rape remanded in judicial custodyStaff Reporter The city police on Monday recorded the arrest of Azeez Tharuvana, an assistant professor at Farook College, who was charged under section 376 (punishment for rape) of the IPC. The professor, accused of raping a 20-year-old degree student of the ... The Hindu, 1 day ago
615 images for farook
Admission on for PG courses
Applications have been invited for admission to postgraduate courses in Farook college, Kozhikode. The applications can be submitted through the website www.farookcollege.in till June 23. The provisional rank list will be published on June 25 ...The Hindu, 1 month ago
What Mirwaiz told Sri Sri Ravi Shankar
What Hurriyat (M) chairman Mirwaiz Umar Farook told spiritual guru Sri Sri Ravi Shankar during their recent meeting makes an interesting case study in how subjectivity and addressing a problem in parts can distort reality. To understand this there ...Kashmir Observer, 1 month ago
Orlando shooting: For Republicans, it's easier to ban Muslims than guns
In December last year Syed Rizwan Farook and his wife Tashfeen Malik armed themselves with AR-15s - the same type of weapon used to kill 50 people in Orlando - and , in what was soon classified as a terrorist attack. The following day Republicans ...Sydney Morning Herald, 1 month ago For Republicans, it's easier to ban Muslims than guns WA Today, 1 month ago
Businessmen in fray: MLAs prefer Ramamurthy to Farook
The attempt of JD(S) to again send a businessmen to the Rajya Sabha failed with its candidate B M Farook facing defeat in the elections held on Saturday. Farook, a Mangaluru-based businessman, secured the least number of votes among the five candidates who ...Deccan Herald, 1 month ago
3-day meet on migration
A three-day conference on migration, development and society will begin a Farook College near Kozhikode on Friday. Amit Shovon Ray, Director of Centre for Development Studies, Thiruvananthapuram, will open the conference, which will mark the second ...Business Line, 2 months ago
Farook Mahmood elected president of FIABCI
Farook Mahmood, Chairman and Managing Director of Silverline Realty, a Bengaluru-based real estate broking firm, has been elected president of FIABCI. FIABCI is an international real estate federation and is a business network of real estate professionals ...Business Line, 2 months ago
California: Brother of San Bernardino shooter and two others arrested
The FBI have arrested three people, including the older brother of San Bernardino shooter Syed Farook, on charges of marriage fraud and lying to investigators The post California: Brother of San Bernardino shooter and two others arrested appeared first on ...First Post.com, 2 months ago 3 linked to California terror attack arrested Business Standard, 2 months ago Three linked to California terror attack arrested Business Standard, 2 months ago
Farook regains title at CU arts fete
Winners all:Students of Farook College with the overall championship trophy at the conclusion of the Calicut University inter-zone arts festival on Monday. —Photo: Special ArrangementThe Hindu, 2 months ago
FBI paid under a million dollars to unlock San Bernardino iPhone: sources
The Federal Bureau of Investigation (FBI) paid under $1 million to unlock the iPhone 5C used by Syed Rizwan Farook.DNA, 2 months ago hackers for a large sum The Hacker News, 1 month ago
Realtime News
on your WebpageAdd Widget >Get your members hooked!


text:
...I also have worked at three universities, in both academic and administrative positions. Throughout my career, I have worked as a tutor and have over fifteen years of experience. As a tutor, I have had the opportunity to work with a wide range of students, meeting a variety of goals.
Schaumburg, ILView Tutor
...I have tutored Geometry to many high school students. I have worked with many students who have difficulty understanding how to write out proofs using the different shapes and figures. I have also tutored students who have taken advanced courses as well.
Palatine, ILView Tutor
...DavidI have always enjoyed reading, for pleasure and for growth. The more I've lived and taught, I have come to regard books and reading as a central experience necessary for the fully realized life. Few things give me pleasure as much as seeing my students become excited when they discover the...
Lincolnshire, ILView Tutor
...My background is in critical care, as well as pre and post-op (PACU). I would love to help you with your nursing education! I am ACLS certified, so the critical stuff is right up my alley! I live in Addison.
Addison, ILView Tutor
...I do feel that English as a First Language is underrated. No subject is more important. Without knowing how to express oneself in proper English, how can anybody succeed in life?
Skokie, ILView Tutor


text: These Arcade Games Have Seen Better DaysLuke Plunkett8/15/12 1:00amFiled to: ArcadesTotal Recall17EditInvite manuallyPromoteDismissUndismissHideShare to KinjaToggle Conversation toolsGo to permalink This is where the machines go after the arcades close down: a basement, or storage dump, where they're left to rot and gather dust. Sad, but then, such is life. Ashes to ashes, etc. Retro Arcades [Chris London, via it 8-bit] Reply17 repliesLeave a reply


text:
Login | Sign Up!
Stitchless TV sewing channel ... HOW TO MAKE A DETACHABLE COLLAR BELOW IS LINK FOR YOUR FREE TEMPLATE TO PRINT THIS COLLAR.How to make a unique collar. An easy sew project for beginners. Free download of printed collar template ready to prin
by Origami Türk
by thefrugalcrafter Lindsay Weirich
by wrenhousevideos
by Woolpedia
by eHowArtsAndCrafts
by MyFroggyStuff
by MarloomZ Creations


text:
Ontario politician launches letter drive to draw Quebec doctors unhappy with charter
CTVNews.ca Staff
Published Sunday, September 15, 2013 12:55PM EDT
Last Updated Sunday, September 15, 2013 3:08PM EDT
A municipal councillor from Richmond Hill, Ont., is trying to turn Quebec's contentious charter of values into a recruitment drive, saying any doctors unhappy with the province's proposed ban on religious clothing and symbols are more than welcome in his hometown.
Carmine Perrelli says he has mailed out approximately 200 letters to doctors employed in various Quebec hospitals, asking them if they would consider relocating due to the Parti Quebecois's so-called "values charter."
If the proposed charter is adopted, public-sector workers -- including doctors, teachers and police officers -- would be banned from wearing religious clothing and symbols such as hijabs, turbans, kippas and large crucifixes while at work.
"If there is going to be anything out there that is going to make people choose between where they live and how they practice their faith, and they decide that they want to move somewhere else, Richmond Hill is welcome to have them,"the politician told CTV's News Channel on Sunday.
Perrelli says he is also launching a website, called Richmond Hill Wants You, to help Quebecers relocate to his town, located just north of Toronto.
"I welcome anyone, from any community, where they have to leave for whatever reason…and we'll do anything we can to facilitate their move to Richmond Hill or the GTA area," he said.
The website is set to go live Sunday afternoon.
Perrelli -- who has lived in Richmond Hill for more than 30 years -- described his community as an "inclusive" one.
"To improve our economic situation in Richmond Hill, I welcome these people," he said.
Perrelli said he hasn't received any responses to his letters yet, but plans on mailing out more next week to engineers, teachers and other public-sector workers.
"We're more concerned with what's in their hearts than anywhere else."
When asked on his thoughts on Quebec's proposed charter, Perelli was very critical of it, saying: "I know racism when I see it."
Perrelli's campaign comes on the heels of a similar effort last week, when Lakeridge Health in Oshawa, Ont. put out ads on social media and in Montreal's McGill student newspaper seeking doctors and nurses unhappy with the proposed charter.
The ad shows a woman wearing a pink hijab and a stethoscope around her neck, with the slogan: "We don't care what's on your head, we care what's in it."
More News from Canada
- It must be mental illness, psychiatrist says of accused election night shooter
- Man accused of stabbing soldiers at Toronto military centre found fit to stand trial
- 'It's not over 'til it's over': The hunt for a tiny dragonfly to stop a big dam
- SCC: Circumstantial evidence can be enough for child pornography cases
- N.S. judge gives jail time to aboriginal man for gun crime despite background


text:
Choose your preferred language. We speak English (US) and 41 other languages.
Most often used by people in the United States
All languages
Select your hotel from the list. Or search for hotels on the City page of Vinh
Hotels with Pools
Muong Thanh Song Lam Hotel
Muong Thanh Phuong Dong
Saigon Kim Lien Hotel
Vinh Plaza Hotel
Avatar Hotel
Duy Tan Vinh
Lam Giang Hotel
Media Hotel
Muong Thanh Vinh Hotel
Thuong Hai Vinh Hotel
Victory Hotel
Xanh Hotel
Anh Quan Hotel
Asean Vinh Hotel
Gold Vinh Hotel
Quyet Thanh Hotel
Vuong Hoan 1
Vuong Hoan 2
Yên Dung (1)
(0.8 miles)
Lóc Ða (0.8 miles)
Yên Ðũng Thương (0.8 miles)
Yên Thinh (1) (1.7 miles)
Yên Vinh (1.7 miles)
Xuân Ðài (1.7 miles)
Yên Lưu (1.8 miles)
Yèn Ðung Hạ (1.8 miles)
Bến Thủy
(1.8 miles)
Ðức Mỹ (1.8 miles)
Ngô Xa (1.9 miles)
Duc Thinh (1.9 miles)
Yên Tho (1) (2.3 miles)
Trung Lộc (2.4 miles)
Yên Xa (2.4 miles)
Van Chan (2.4 miles)
Xóm Ngoai
(2.8 miles)
Phúc Long (2.8 miles)
Xóm Cư Phú (2.8 miles)
Lộc Chấu (2.9 miles)
Gia Hòa (2.9 miles)
Phú Vinh (3 miles)
Ngô Xa (3 miles)
Văn Trạch (3 miles)
We've negotiated with thousands of hotels to get the very best deals. We call them Secret Deals and they only last for a limited time.
You can get these deals for free by subscribing to our newsletters. You can even choose your favorite destinations to receive personalized deals.
Get started now by entering your email address. We'll instantly send you a link to our Deal Finder!
Don't worry – your email address is safe with us. We'll never share your private information and you can unsubscribe at any time.