text:
De Kock's 60 pulls Delhi to 138/8Raipur, May 22 (IANS) South African opener Quinton de Kock's matured 60-run knock helped Delhi Dardevils post 138/8 against Royal Challengers Bangalore in a must-win encounter for both sides in the Indian Premier League (IPL) here on Sunday. ... Yahoo! India, 2 months ago
IPL 2016: De Kock's 60 pulls Delhi to 138 - New Indian Express, 2 months ago
IPL 9: De Kock's 60 pulls Delhi to 138/8 - Mid Day, 2 months ago
6 images for delhi dardevils
WATCH IPL 2016: Krunal Pandya's blistering innings of 86 in Mumbai's comprehensive win over Daredevils
Krunal Pandya bludgeoned a 37-ball 86 in his maiden IPL fifty before bowlers took charge as Mumbai Indians pounded Delhi Daredevils by a comprehensive 80-run margin to jump to third spot, here tonight. 25-year-old Pandya combined well with opener ...DNA India, 2 months ago Krunal Pandya's All-Round Show Helps Mumbai Indians Stay Afloat IBNLive, 2 months ago IPL 2016, MI vs DD: Krunal Pandya's fifty helps Mumbai decimate Delhi Firstpost.com, 2 months ago Mumbai Indians Pound Delhi Daredevils to Script 80-Run Victory Outlook India, 2 months ago
IPL 2016: Wily Chahal, clockwork Kohli carry Bangalore into play-offs
Raipur: Royal Challengers Bangalore grabbed the last available spot in the IPL play-offs with a six-wicket win over Delhi Daredevils as Virat Kohli continued with his superlative batting show by hitting a responsible 54-run knock, in Raipur on ...Firstpost.com, 2 months ago IPL PHOTOS: RCB seal second spot by crushing Delhi Rediff.com, 2 months ago RCB qualify for IPL Play-offs with six- wicket win over Delhi Deccan Herald, 2 months ago Virat's unbeaten fifty helps RCB beat Daredevils to qualify for Playoffs ABP Live, 2 months ago
IPL 2016: Road to play offs easy for Mumbai Indians post 80-run win over Delhi Daredevils
25-year-old Pandya combined well with opener Martin Guptill (48) to rattle up a fiery 98-run stand that propelled Mumbai Indians to a commanding 206 for four. Mumbai lost Rohit Sharma (31) after a steady start but Pandya ...Jagran Post, 2 months ago Krunal Pandya, Guptill rake up 206/4 against Dardevils Business Standard, 2 months ago IPL 9: Krunal Pandya dazzles as Mumbai post 206 Asian Age, 2 months ago
More from: , Deccan Chronicle...and 1 other sources
RPS vs DD highlights: Watch Ajinkya Rahane and Adam Zampa steer Pune to a commanding win over Delhi in IPL 2016
Adam Zampa picked three wickets in his spell of four overs against the Delhi Daredevils on Tuesday. Pictured: Adam Zampa of Rising Pune Supergiants during an IPL match between Rising Pune Supergiants and Sunrisers Hyderabad at Dr YS Rajasekhara ...International Business Times India, 2 months ago Zampa stars in Supergiants IPL win Nine MSN, 2 months ago
RPS prevail over DD in rain-hit encounter
Rising Pune Supergiants registered victory over the Delhi Daredevils at the ACA-VDCA Stadium in Visakhapatam on Tuesday. MS Dhoni & co. won the match by 19 runs on D/L method as rain Gods did play spoilsport and halted the game twice during the run ...Nagaland Post, 2 months ago
IPL: Mumbai Indians Thrash Delhi Daredevils by 80 Runs, Move to Third Spot
Krunal Pandya blasted 86 off 37 balls and picked up 2/15 as Mumbai Indians walloped Delhi Daredevils by 80 runs to move to third spot. BCCI Highlights Krunal Pandya bludgeoned a 37-ball 86 in his maiden IPL fifty before bowlers took charge ...NDTV, 2 months ago Mumbai thrash Daredevils by 80 runs Newshence.com, 2 months ago IPL: MI Thrash Delhi Daredevils by 80 Runs, Move to Third Spot NDTV, 2 months ago
Sehwag: The man who made Warner the player he is
Even when Sunrisers Hyderabad were making heavy weather of their chase against Gujarat Lions in Friday's Qualifier 2 at the Ferozeshah Kotla, there was no panic in the dugout. With skipper David Warner dictating terms at the crease, Lions bowlers ...MSN News US, 1 month ago David Warner, once goaded by Virender Sehwag, stoops to conquer again Hindustan Times, 1 month ago
IPL 9: Bangalore spinners restrict Daredevils to modest 138
Virat Kohli celebrates after taking a spectacular catch to dismiss Karun Nair on Sunday. (Photo: BCCI) Quinton de Kock hit a fighting half-century but the rest struggled badly in the virtual knockout game as Royal Challengers Bangalore restricted ...Asian Age, 2 months ago
Zaheer Khan coy over future after IPL exit
Through the nine seasons since 2008, Indian Premier League has been reputed to throw up a host of surprises. One such surprise this season has been Zaheer Khan's exceptional leadership. A new-look Delhi Daredevils benefited from his rather astute ...Cricbuzz.com, 2 months ago
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I was very nervous about using an SEO company but Creare quickly put my mind to ease. They got my campaign started with minimal keywords initially and then when this started to work we increased it to a an amount that I never thought I would go to.
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Tomorrow the 29.Sept. the day of the "Magical Moon" is my mom's 84th Birthday in Germany. I admire her stamina and courage all my life. She flew all the way down to Cape Town in April to be part of Sabines and Tim's wedding.
By Crisman Art
"Happy Birthday"
This is truly my day
Turning things my way.
Honored I am
One year older again
Receiving gifts to my name.
But now comes my personal truth
One year back I wish to move
To sip from the fountain of youth.
All I desire is a "Tickle"
To make my heart-muscle "Twiggle"
Bringing my smile into a "Giggle".
On Earth I am but a drafter
Grateful for my friends' laughter
Gaining happiness thereafter.
Now it's done –
Youth and Truth have won.


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Adventure Talent Agency Inc - North Lauderdale, FL - Phone: (954) 721-7127
South Florida Talent Search Inc - North Lauderdale, FL - Phone: (954) 935-0905
Entertainment bureaus in North Lauderdale are prominent entertainment agencies representing A-list and emerging stars in music, movies, television, and sports. The other types of artists working with such bureaus are: comedians, comedy jugglers, comedy magicians, concert performers, dance headliners, instrumentalists, impressionists (musical and/or comedy), tribute groups, ventriloquists, and vocal entertainers. These bureaus aim to supply the industry with the best in entertainment and programming. As experienced professionals, they seek to help their entertainers focus on delivering the right act for the right audience.
Governor Cuomo Announces First Solar Schools Project At The New York Institute For Special Education In The Bronx
Governor Cuomo's K-Solar Program Increases Use of Renewable Energy in Schools (New York, NY) Governor Andrew M. Cuomo today announced the New York Institute for Special Education in the Bronx will be the site of the state's first solar schools project and will have solar panel arrays installed thanks to a power purchase agreement with SolarCity. This public-private partnership is..


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James Carville Says 80% Of Democrats Are Politically Clueless
James Carville, Democrat political consultant extraordinaire – and former Bill Clinton campaign manager, has astonishingly come out and said what all good Republicans have known for decades: Not onl
By: Airedale | Comments: 61 | Views: 1231 | Votes: 11 | Shared: 7
Location: Philadelphia, Pennsylvania, United States | Leaked: 2 days ago in Politics
Notorius British Cuckold says Trump is leading the US into Tyranny.
I hope he's right! If a british pedophile cuckold hates Trump, then Trump must be doing something right! America Has Never Been So Ripe for Tyranny As this dystopian election campaign has unfolded
By: a salt and battery | Comments: 33 | Views: 3378 | Votes: 1 | Shared: 0
Leaked: May-2-2016 in Politics
Carville: If Republicans Lose 2016 Election, GOP 'Will Be Extinct'
Democratic strategist James Carville told a roundtable on This Week With George Stephanopoulos that the ideological litmus tests the GOP normally enforces during presidential primaries will matter
By: dcmfox | Comments: 98 | Views: 1003 | Votes: 6 | Shared: 0
Leaked: Apr-13-2014 in Regional News, Politics
O'Reilly And Carville Clash Over Wages and Economy
by Josh Feldman 8:56 pm, February 19th, 2013 Bill O'Reilly continued his theme of what the biggest problem facing the country today is with James Carville . Carville cited a general eco
By: dcmfox | Comments: 9 | Views: 693 | Votes: 2 | Shared: 0
Leaked: Feb-20-2013 in Politics
Carville To Cry Baby Krugman: "It's Not The Arrow; It's The Indian"
Carville : "Look, they asked one time Lee Trevino, great golfer, who was having trouble with putting and they asked him if he thought he needed a new putter and he famously said, no, it's not the arro
By: wtfwyt | Comments: 22 | Views: 2451 | Votes: 1 | Shared: 0
Leaked: Oct-7-2012 in Politics
Carville to CNN host: 'I'm not sorry'
Carville tells CNN's John King he won't apologize for a controversial statement he made about Obama.
By: jbpnw | Comments: 24 | Views: 6675 | Votes: 0 | Shared: 0
Leaked: Nov-18-2010 in News
Carville: If Hillary Gave Obama "One Of Her Balls," He'd Have Two
"If Hillary gave him one of her balls, they'd both have two," Democratic strategist James Carville told the Christian Science Monitor at a breakfast on Thursday morning.
By: star53 | Comments: 11 | Views: 7114 | Votes: 1 | Shared: 0
Leaked: Nov-18-2010 in LiveLeaks
Carville's Hillary/Obama Joke
Carville's begin too generous. :)
By: jbpnw | Comments: 2 | Views: 5958 | Votes: 0 | Shared: 0
Leaked: Nov-18-2010 in News
Carville Blasts Obama
Is Carville getting ready for the Democrats to lose big this November?
By: jbpnw | Comments: 30 | Views: 6677 | Votes: 0 | Shared: 0
Leaked: Oct-24-2010 in News
Panicky Schultz Sensing Tea Party Takeover: Axe Axelrod, Bring in Begala-Carville
Ed Schultz calls for David Axelrod to be thrown overboard for being too "soft" and replaced with James Carville and Paul Begala. Don't panic ed, if you get to stressed, there are lots of liberal lose
By: star53 | Comments: 15 | Views: 6039 | Votes: 0 | Shared: 0
Leaked: Sep-16-2010 in LiveLeaks
Democrat James Carville: Airport scanners can 'measure my penis!'
".....Let me buy a pass ... so that they can scan me measure my penis!"...." ********************** ********************** The debate over full body security scans just got a lot more graphic, t
By: Songun | Comments: 29 | Views: 9656 | Votes: 0 | Shared: 0
Leaked: Jan-8-2010 in News
James Carville On The View - 40 More Years Of Democrat Rule
I swear if Joy could have gotten away with it, she would have been giving Carville a hand-shandy under the table. I was going to editorialize about his appearance, but it's really not worth it. Watch
By: MsUnderestimated | Comments: 59 | Views: 9804 | Votes: 0 | Shared: 0
Leaked: May-4-2009 in News
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Palacio de Carvajal
Palacio de Ovando
This 16th-century Renaissance-style palace stands on the Plaza de Santa María and was reformed in the 18th century.
Concatedral de Santa María
This 15th-century Gothic cathedral creates an impressive opening scene for the Ciudad Monumental. Inside, you'll find a magnificent...
Palacio Episcopal
Notable facades on the Plaza de Santa María include the Palacio Episcopal, built between the 13th and 17th centuries and sporting a...
Calle Amargura 1 · interesting places nearby
Palacio de Carvajal information
Just off the northeastern corner of the main Plaza de Santa María stands this late-15th-century mansion. The building was abandoned after fires tore through in the 19th century. Now restored, it houses a modern display on the province's attractions and the helpful regional tourist office .


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Learn more
Colloquial English: A Course for Non-Native Speakers
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About the Author
Gareth King, who is currently working in Further Education, has a background in Linguistics and is an experienced teacher odf foreign languages and English as a Foreign Language. He is author of Routledge's Colloquial Welsh, Basic Welshand Intermediate Welsh Grammar Workbook titles and is the Series Advisor for the Colloquials. He has previously authored material for OUP's Oxford Junior English titles (pub 1999), aimed at EFL learners in secondary schools.
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Flourless Nutella Mug Cake
I'm really excited to share this recipe with you today. I spent a few hours fiddling in the kitchen to make this dessert for FH, and I'm absolutely thrilled with how it turned out.
A flourless Nutella mug cake. It sounds as good as the name. It's super easy to put together. Just five ingredients. A little stir. Microwave for less than 2 minutes. And you're treated to a decadent, moist, flourless Nutella cake.
Sultan Kebab and Baklava revisit
I was supposed to meet up with a few friends at Sultan Kebab and Baklava but our meet up got postponed. All the arranging made me realize I haven't posted about my visit here from back in October. Oops. My first visit can be found here.
Sultan is a Turkish restaurant specializing in kebabs and baklava. We loved our first visit and wanted to try much more on our return.
I ordered a cup of the complimentary Turkish tea which I really like. It's strong but with sweet overtones.
Then we ordered some appetizers. I think it's best to get a small order of several of these appetizers so that they can make a combination plate for you. There was some mix up with our order, a new server they were training, so we ended up getting full size orders of each of the appetizers we requested, rather than smaller amounts.
Antepezme (onion, hot pepper, tomato, chili powder)
I really love the hummus here. It has a very strong olive oil flavor. I could easily eat this every day.
Saksuka (potato, zucchini, eggplant, sweet pepper and tomatoes)
The appetizers are accompanied by their fresh baked lavas bread, a very thin, chewy bread, which you can use to scoop up the different pastes.
Fried Bacon Eggs
Happy Valentine's Day! While Valentine's Day is usually celebrated with a lot of chocolate and flowers, I thought I'd share this savory dish as a possible choice for your loved one.
Soft boiled egg covered in a crispy bacon breadcrumb. Yummy.


text:
...I have reviewed a hundred sample problems and have a background in chemistry and mathematics teaching at the middle and high school level. The Armed Services Vocational Aptitude Battery (ASVAB) is a multiple choice test, administered by the United States Military Entrance Processing Command, use...
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Playstation 2 Games
Increase grip strength for Metal Gear Solid 2: Sons Of LibertyHome / Playstation 2 /
This page contains Metal Gear Solid 2: Sons Of Liberty Hints for Playstation 2 called "Increase grip strength" and has been posted or updated on Aug 8, 2007 by Christine2011.
Boxshot & Details
- Developer: Kcej
- Publisher: Konami
- Genre: Action Adventure
- Release: Nov 12, 2001
- ESRB: Mature
Increase grip strength
Press L2 + R2 one hundred times when hanging on a ledge to do pull-ups.
Report Problem
Please Submit a Problem for any incomplete, non-working or fake cheat listed above.
If you know other secrets, hints, glitches or level guides, then please Submit your Cheats and share your insights with other gamers.
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Get past 12 connecting bridge
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Posted on: 07-12-2012
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Metal Gear Solid 2: Sons Of Liberty - Intro
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text:
Belize City Municipal Airport
|Belize City Municipal Airport
|IATA: TZA – ICAO: none
|Airport type
|Belize City
|Elevation AMSL
|8 ft / 2 m
|17°30′59″N 088°11′30″W / 17.51639°N 88.19167°WCoordinates: 17°30′59″N 088°11′30″W / 17.51639°N 88.19167°W
Belize City Municipal Airport (IATA: TZA) is an airport that serves Belize City, Belize. It is only one mile from the city center, and is therefore more centrally located to the city than is Belize City International Airport. It mostly services travel to Belize's cayes, allowing quicker arrivals to the cayes than by boat or water taxi. It was one of the shortest runways in Caribbean to have commercial flights until it was extended and finally opened in late 2014.[citation needed]
The head office of Maya Island Air is on the second floor of Building #1.[1]
Tropic Air also has a terminal at this airport with multiple flights every day.
Scheduled Service[edit]
|Maya Island Air
|Caye Caulker, Caye Chapel, Dangriga, Placencia, Punta Gorda, San Pedro, Savanah
|Tropic Air
|Belize City-International, Belmopan, Caye Caulker, Dangriga, Kanantik, Placencia, Punta Gorda, San Pedro, San Ignacio
Belize Shuttles[edit]
Belize Shuttles and Private Transfers is the leading transport provider of shared and private shuttles and transfers. Belize Shuttle Service provides regular schedule shared shuttles to Placencia, San Ignacio, Hopkins and Water Taxi from Belize International Airport
- ^ "Contact Us." Maya Island Air. 10 February 2010. Retrieved on May 16, 2012. "Address: Maya Island Air Regional Municipal Airstrip Building #1, 2nd floor Belize City Belize Belize"
External links[edit]
|This article about a Central American airport is a stub. You can help Wikipedia by expanding it.
|This article about a building or structure in Belize is a stub. You can help Wikipedia by expanding it.


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New York, NYUSA
February 22, 2013
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Student looking to meet interesting people.
Help support your Meetup
We are local explorers that venture into our own backyard...the Five Boroughs of New York City. We will visit historical landmarks, forgotten places, well-known places and go off the beaten path. If you love urban exploration or were just curious to see what was in your own town, this group is for you!
Membership is free and all is welcome!
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Written by Jen Finn
Exactly two months after the Northeast groundfishery was acknowledged to have become a statutory disaster for the five New England states and New York, the regional fishery management council digs in today to debate and possibly vote on a suite of changes to the system — none with the potential to provide dramatic relief to an industry in dire straits.
Direct relief has been left to Congress; the congressional delegation has agreed to press for $100 million although no written plan exists for the use of that or any amount that may be included in the resolution of the federal budget and sequestration crisis, a spokesperson for the National Oceanic and Atmospheric Administration said Tuesday.
If anything, the disaster is spreading from the groundfishery — which faces catch limits reduced by between 45 and 73 percent on Gulf of Maine Cod and multiple Georges Bank stocks, unprecedented since the enactment of the Magnuson-Stevens Fishery Conservation and Management Act in 1976 — to the scallop fishery, the nation's No. 1 fishery based on sales value, and a fishery centered in New Bedford.
Read the full story at the Gloucester Times>>
The Northeast Trawl Advisory Panel working group is scheduled to meet Aug. 2 in Boston to discuss using commercial fishing vessels to supplement current stock assessment surveys conducted by the Northeast Fisheries Science Center.Read more...
Pat Fiorelli, the long-serving public affairs officer for the New England Fishery Management Council, will step down at the end of July.Read more...


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Tip: Once a week, toss in a few frozen cubes of white vinegar and turn on your disposal. The vinegar will get in all the moving nooks and crannies that are otherwise hard to get to and the ice will sharpen your blades.
My favorite neutral paint colors for 2014! Sherwin Wiliams Crushed Ice, Benjamin Moore Quiet Moments, Benjamin Moore Nimbus Gray, Pratt and Lambert Cloud of Winter, Sherwin Williams Topsail, Benjamin Moore Revere Pewter, Benjamin Moore Secret
from Cambridge Pavers - firepit seating area outdoors patio garden walkway green pillows Fire Pit With Wall of Seats
paint a canvas the colors you choose.put the sticker letters where you want.paint it all black, and then peel the stickers off.
good thing to keep in mind!
walk-in shower - still private & no door to clean!
Stove-top potpourri kits. Cute neighbor gift idea: one orange, 1/2 c cranberries, 1 Tbs whole cloves, 3 sticks cinnamon, a bit of grated nutmeg. Instructions: "Quarter the orange, place all in a small saucepan filled with water and simmer on lowest setting. Refill water as needed."
Reading Net for Kids
Remove fake drawer under sink and install paper towel holder.
Your dishwasher washes all the food off your dishes. But who washes the dishwasher? You can, by pouring 1 cup of vinegar into the bottom of the tub and running it through a cycle without any dishes. Doing this once every month or two will remove built-up soap residue and keep it in squeaky clean shape.
Just print off any picture you want, then spray paint a piece of wood black, cut the picture to match the size of the wood. Using Mod podge coat the wood then lay the picture on top. Once it has dried thoroughly, use sandpaper to rough up the edges, then put a layer of mod podge over the picture. paint some eye hooks and use pretty ribbon as a hanger and voila #diy #crafts #arts
Is your bathroom lacking storage? If so, we show you how to make these adorable storage wall cabinets.
Building a fire pit
Natural weed killer: 2c white vinegar + 1T dish soap + 1T. salt. Blend and pour into a spray bottle. Will kill anything!
App that lets you take a photo of your room and then try paint colors on them to see what you like best ....
Use ice cubes to release furniture indentations in the carpet + other great cleaning tips
Good old Martha taught us that rather than buying those ridiculously expensive anti-slip mats for a rug, just turn it over and run a few lines of acrylic-latex caulk every 6 inches or so. Let dry and flip over and your rug wont be going anywhere!
Storage Shed
16 Amazing Do It Yourself Home Ideas
Never let the fear of striking out keep you from playing the game.
Be the Good.
lattice screen
PVC Pipe Toothbrush Holders. Brilliant! Gets them off the counter and put of the germ zone.
How to remove permanent marker from everything! Clothes –hand sanitizer Walls –toothpaste or hairspray* Carpet –white vinegar Wood –rubbing alcohol *don't scrub too hard with hairspray, you don't want to remove the paint!
Under-cabinet knife block drawer - Away from the kids reach and off the counter!


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Where a defendant attorney has filed a counterclaim asserting that the plaintiff's efforts to collect a debt allegedly owed under a revolving line of credit memorialized by a promissory note violated the Fair Debt Collection Practices Acts and its Massachusetts ...Read More »
Employment – Gender discrimination – Correctional officer
Where a plaintiff has alleged gender discrimination, her complaint is sufficient to withstand a motion by the defendants, the Department of Correction and the Massachusetts Executive Office of Public Safety and Security, to dismiss count 1 (G.L.c. 151B) and 2 ...Read More »
Taxation – Corporate excise – Indebtedness
Where the Commissioner of Revenue denied an application for an abatement of corporate excise for the tax year ending March 31, 2002, the denial must be affirmed because the taxpayers did not meet their burden of proving that interest paid ...Read More »
RICO – Class certification – Anti-depressant drugs
Where a plaintiff third-party payor has moved for class certification in a RICO suit over anti-depressant drugs, the motion should be denied based on the predominance factor. Background "This case arises out of the marketing and sales of the related ...
Tagged with: Class certificationRead More »
Retirement – Rescission
Where (1) a plaintiff resigned from his employment with the town of Saugus after an anonymous letter was sent to the fire chief threatening to make allegations of sexual misconduct public unless the plaintiff resigned and (2) the plaintiff sought ...Read More »
'Purest on earth' not an illegal claim
A seller of Himalayan pink salt could not be held liable over its tagline, "the purest salt on earth," a U.S. District Court judge has ruled. A competitor brought a claim of false advertising, alleging that "the word 'purest' may ...Read More »
Search and seizure – Traffic stop – Marijuana – Odor
Where state troopers found marijuana in a vehicle that had been pulled over for speeding and for making an erratic lane change, the marijuana was correctly suppressed in District Court because neither the nervousness of the driver nor the detectable ...Read More »
Bankruptcy – Inheritance – Modified plan
Where the Chapter 13 trustee filed a motion for modification of a confirmed plan after the debtor inherited $120,000 from her mother, the motion must be allowed because at the time the trustee filed the motion the debtor had not ...Read More »
Criminal – RICO – Second-degree murder – NECC
Where defendants affiliated with New England Compounding Pharmacy, doing business as New England Compounding Center (NECC), have moved for dismissal of two RICO counts and/or the striking of the 25 incorporated racketeering acts involving alleged second-degree murder, the motion must ...Read More »
Criminal – Mayhem – Intent – Disfigurement
Where the defendant contends that (1) the trial judge erred in instructing the jury only on self-defense by means of deadly force, without also providing an instruction on self-defense by means of nondeadly force; (2) there was insufficient evidence to ...
Tagged with: MayhemRead More »


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Hearing Test
Pure-tone audiometry is the basic hearing examination which determines the degree of hearing loss
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Pure-tone audiometry is the basic hearing examination which determines the degree of hearing loss
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Test different aspects of your hearing with this application. Two easy and precise tests
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❤Welcome to the best video call app---JusTalk! All FREE JusTalk is very easy to use. You can enjoy FREE video call & voice call just like Skype & WhatsApp. You'll experience the most clear video call, voice call, internet call and group chat. You can start JusTalk by Facebook account or mobile phone number. You also can invite your 'iPh…
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outside sales representative jobs near Miami, FL
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Outside Sales Representative - UniFirst
UniFirst - Miami, FL
From Sales Representative to Sales Manager. Any sales experience. Highly ethical sales process that works. Do it!" – Leslie, UniFirst Sales Manager....
Outside Sales Representative
Lifestyle Publications - Miami, FL
The *Sales Representative*. The Sales Representative is responsible for client account management, including all required documentation and paperwork....
Outside Sales Representative
MARKY'S Gourmet - Miami Gardens, FL
Outside & Inside Food Sales:. , Miami, FL is looking for organized, enthusiastic and computer-savvy OUTSIDE & INSIDE sales executives with exceptional sales and...
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HBL Haircare - Miami, FL
The core objective for a USP, LLC Outside Sales Representative is to offer complete "direct to salon" sales, service and brand advocacy in their market....
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Empire Today LLC - Miami, FL
Outside Sales Representative (In Home Sales)*. Here's why our Outside Sales Representatives choose us! As our Outside Sales Representative, you should have a...
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National Outside Sales Representative - B2B, Travel
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i will love to win to help my familiy.my mother to care of all 8 children wen my dad dead a long time.is... - read more
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Is this attraction wheelchair accessible?
Do you recommend this attraction for luxury travelers?
Do you find this attraction suitable for young children?
Do you recommend this attraction for thrill seekers?
Is this attraction free to the public?
Would this be a good rainy day activity?
Do you recommend this attraction for beach lovers?
Thanks for helping!
Beautiful little town, near airport and not so far from Dubrovnik..
were would be easy to make day trip. water taxi,buss, taxi..
choose water to get Dubrivnik and get normal taxi...
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Beautiful little town, near airport and not so far from Dubrovnik..
were would be easy to make day trip. water taxi,buss, taxi..
choose water to get Dubrivnik and get normal taxi to get back after long day,
Cavtat is beauty,peacefully little town with own attractions.
Took a easy bus ride to this gorgeous coastal town that's only a quick 30 minutes south of Dubrovnik. You can purchase tickets from the bus driver or there is also a ticket booth at the bus stop which is directly adjacent to where you board the cable car. We absolutely loved Dubrovnik, but it can certainly get a bit...
Caveat is a picturesque small harbour that offers a relaxed reprieve from the hussle of Dubrovnik. Lots a restaurants to choose from, and luxury launches to admire. Lovely rocky beaches, but no life guards anywhere. My kids enjoyed the aqua trampoline park in the next bay.
Charming old town that isn't too busy during the daytime, but is hustle-bustle at night. Make sure you take a slow walk and stop for lots of pictures of the water and the side streets. Some excellent hand-crafted souvenirs to be had from the shops too.
Amazing place with lots of cafe bars and beautiful restaurants.
Lots of amazing yachts sail in on a daily basis. Lots of boutiques selling jewelry, bags, clothes and household items.
You can eat out for as little as expensive as you like as there is lots of choice.
We loved it!
We first visited Cavtat eight years ago, by boat from Dubrovnik, and were enchanted by the place. It felt like the South of France! Things have changed a bit; it is more developed, with a marina welcoming some large 'gin palaces' - just like the South of France! The variety of restaurants remain excellent however, and the town is a...
Beautiful place! Very upmarket. Enjoyed the walk around the cost. Fabulous yachts in the harbour. Nice shops :)
This little sharming old town is marvellous! I stay there every summer for one or two weeks. Cavtat is the best place to stay in the summer ever!
We walked into the town at night to see all the sites and visiting ships , the bars and restaurants where amazing the town is very busy and the bars are buzzing but in a relaxed way . No mad music or discos about all very calm and relaxing .
The local people are beautiful and so helpful
Cavtat and the drive from Dubrovnik are both lovely.
The place is small and reasonably friendly. Shopping and places to eat are OK.
Worth a visit.
Is Cavtat safe for gay men
Can anybody tell me what beers are sold in the bars and restaurants in cavtat? There are some fantastic beers brewed in Croatia by all accounts.
Pan Pivo has been bought out by Carlsberg so I hope that isn't the only one I can get. Has anybody seen any Velebitsko on sale??
Just planning my week in dubrovnik in September with my parents (70yrs old), is there enough in Cavtat Old town to warrant a full day of sightseeing?
thanks, Matt
Hi Beverley, I see you have recently been in Cavtat, we are here now, and wonder if they have a day with a street market, do you know please? Thank you for any advise on what is good to do/see here, please?
Traveling in July; I plan to spend my last afternoon in Cavtat on way to airport. Is there a place to secure luggage at the bus station for several hours? Thanks
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From the July 2016 Issue
Destination Maternity: Destination Automation
Running short of space in its old facility, Destination Maternity Corp. built a new, highly automated DC driven by an integrated warehouse management and execution system. The result is a strategic weapon helping to drive the business forward.The automation tool kit in action at Destination Maternity 2016 Software User Survey: Sales are looking "Slightly Questionable" ADC: Turning data capture into decisions Top 20 supply chain software suppliers, 2016 more from this issue
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Pittsburgh, Pennsylvania 15205
United States 1 (412) 787-9750
1 (800) 888-9750


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|Publication number
|Publication type
|Application number
|Publication date
|May 31, 1983
|Filing date
|Apr 16, 1982
|Priority date
|Apr 16, 1982
|Fee status
|Also published as
|Publication number
|Harry K. Bjorkman, Jr.
|Original Assignee
|Energy Development Associates, Inc.
|Export Citation
|BiBTeX, EndNote, RefMan
|Patent Citations (16), Non-Patent Citations (5), Referenced by (5), Classifications (11), Legal Events (5)
|External Links: USPTO, USPTO Assignment, Espacenet
The Government of the United States of America has rights in this invention pursuant to Contract No. DE-AC02-76ET20131 awarded by the U.S. Department of Energy.
The present invention relates to improvements in metal halogen battery systems. More particularly the invention relates to a new multiple stage, multiple filter hydrate store for these battery systems.
The electrical energy storage systems of the type referred to herein (e.g., a zinc chlorine battery system or other metal-halogen battery system) utilize a halogen hydrate as the source of halogen components for reduction at a normally positive electrode, and an oxidizable metal adapted to become oxidized at a normally negative electrode during the normal discharge of the storage system. An aqueous electrolyte is employed for replenishing the supply of the halogen components as it becomes reduced at the positive electrode. The electrolyte contains the dissolved ions of the oxidized metal and the reduced halogen and is circulated between the electrode area and a storage area containing halogen hydrate, which progressively decomposes during a normal discharge of the electrical energy system, liberating additional elemental halogen to be consumed at the positive electrode.
The state of the art in electrical energy storage systems or battery systems of this type is described in the following cited references owned by the same assignee as the present invention, such as Symons U.S. Pat. No. 3,713,888 entitled "Process For Electrical Energy Using Solid Halogen Hydrates"; Symons U.S. Pat. No. 3,809,578 entitled "Process for Forming and Storing Halogen Hydrate in a Battery"; and Bjorkman U.S. Pat. No. 3,814,630 entitled "Filter/Store For Electric Energy Storage Device"; and, in commonly assigned copending Bjorkman U.S. patent application Ser. No. 358,628, filed Mar. 16, 1982, entitled "Metal Halogen Battery System With Multiple Outlet Nozzel For Hydrate."
The specific teachings of the aforementioned cited references are incorporated herein by reference. The new multiple state, multiple hydrate store disclosed herein is particularly useful for application in a battery system of the type described in the copending application referred to immediately above. However, it also has wide application for use in numerous metal halogen battery systems.
The basic operation of a zinc chloride battery system is as follows. In charge, an electrolyte pump delivers aqueous electrolyte to pockets between pairs of porous graphite-chlorine electrodes in a battery stack comprised of a plurality of cells. The electrolyte passes through the porous chlorine electrodes into a chamber between opposite polarity electrodes, flows up between the electrodes, then flows back into the battery sump. Chlorine gas liberated from porous graphite electrode substrates is pumped by a gear pump, otherwise referred to as the gas pump, and before entering the gas pump, the chlorine is mixed with electrolyte chilled by a chiller unit. The chlorine and chilled electrolyte are mixed in the gear pump, chlorine hydrate forms in a process analogous to the water freezing process with chlorine included in the ice crystal, and the chlorine hydrate-electrolyte mixture is deposited in the store. In discharge, chlorine is liberated from the hydrate by decomposition of the chlorine hydrate in the store in a process analogous to the melting of ice, by injection of warm electrolyte for the sump. On development of the required chlorine gas pressure in the store, the chlorine is injected and mixed with and dissolved in the electrolyte, which is then fed to the porous electrodes in the battery stack. The battery stack is then discharged, wherein the electrode dissolution of zinc occurs at the zinc electrode, reduction of the dissolved chlorine occurs at the chlorine electrode, power is available from the battery terminals, and zinc chloride is formed in the electrolyte by reaction of zinc and chlorine to form zinc chloride.
Further discussion of the structure and operation of zinc chloride battery system may be found in commonly assigned copending U.S. patent applications of Fong et al., Ser. No. 310,627, filed Oct. 13, 1981, entitled "Metal Halogen Battery Construction With Improved Tehchnique For Producing Halogen Hydrate"; of Kiwalle et al., Ser. No. 343,904, filed Jan. 29, 1982, entitled "Metal Halogen Battery System," and of Hacha, Ser. No. 357,742, filed Mar. 12, 1982, entitled "Halogen Hydrate Storage Device for Mobile Zinc-Chloride Battery Systems." Such systems are also described in published reports prepared by the assignee herein, such as "Development of the Zinc-Chloride Battery for Utility Applications," Interim Report EM-1417, May 1980, and "Development of the Zinc-Chloride Battery for Utility Applications," Interim Report EM-1051, April 1979, both prepared for the Electric Power Research Institute, Palo Alto, Calif. The specific teachings of the aforementioned cited references are incorporated herein by reference.
During the development of the zinc-chloride battery system, several single stage filter designs for use in the hydrate store have been tested, including a rectangular filter across the top of the store, an L-shape filter across one side and the bottom of the store, a combination of these two filters in a single stage, a basket-type filter seated in the store, and a bag like filter substantially overlying the interior walls of the store (as described in U.S. Pat. No. 3,814,630). The purpose of the filter in the hydrate store is to separate the compressible particulate chlorine hydrate from the liquid used in the hydrate formation process. As the chloride hydrate enters the store, it is in the form of a dilute slurry, of which approximately seven (7) percent is hydrate crystal. However, due to the amount of chlorine gas which is liberated during the charging of the battery, it is not practical to store the chlorine hydrate particles in this dilute slurry. Accordingly, a filter is used to provide a hydrate consentration system for removing as much of the excess liquid as possible. It will be appreciated that the increase in the density of the hydrate particles in the store will result in a decrease in the size and weight of the battery system. This advantageous result is particularly important where the battery system is employed in a battery-powered vehicle.
Accordingly, it is a principal object of the present invention to provide a multiple stage, multiple filter hydrate store for a zinc-chloride battery system which more effectively concentrates the chlorine hydrate particles during the charging of the battery system.
It is a more specific object of the present invention to provide a hydrate store filter design having three separate sections and which operates in three discrete stages to achieve a substantially uniform liquid flow through the store during the charging of the battery system while maintaining a hydraulically compressive load on the hydrate.
It is an additional object of the present invention to provide a multiple stage, multiple filter hydrate store filtration or hydrate concentration system which is adapted to maintain the pressure in the hydrate store within acceptable levels during the charging of the battery.
Additional advantages and features of the present invention will become apparent from a reading of the detailed description of the preferred embodiments which makes reference to the following set of drawings in which:
FIG. 1 is a simplified schematic of a metal halogen battery system employing the present invention, and particularly illustrating a multiple stage, multiple filter hydrate store according to the present invention.
FIG. 2 is a top elevation view, partially in cross-section, of the multiple stage, multiple filter hydrate store illustrated in FIG. 1.
FIG. 3a is a cross-sectional view of the multiple stage, multiple filter hydrate store illustrated in FIG. 1, taken generally along lines A--A of FIG. 2.
FIG. 3b is a partial plan elevation view of the interior side wall of the multiple stage, multiple filter hydrate store, taken generally along lines B--B of FIG. 3a.
FIG. 4a is a cross-sectional view of another embodiment of a multiple stage, multiple filter hydrate store according to the present invention.
FIG. 4b is an enlarged cross-sectional view of a portion of the multiple stage, multiple filter hydrate store embodiment of FIG. 4a, particularly illustrating a technique of securing the filter cloth end in a sealing relationship with the side wall of the hydrate store.
FIG. 5 is a plan elevation view, partially in cross-section, of a valve assembly for the multiple stage, multiple filter hydrate store illustrated in FIG. 1.
The invention concerns an improved hydrate store for a metal halogen battery system wherein a multiple stage, multiple filter means is employed for separating the halogen hydrate from the liquid used in forming the hydrate. The filter means is constructed in the form of three separate sections which combine to substantially cover the interior surface of the store container. Exit conduit means is provided in association with the filter means for transmitting liquid passing through the filter means to a hydrate former subsystem. The hydrate former subsystem combines the halogen gas generated during the charging of the battery system with the liquid to form the hydrate in association with the store. Relief valve means is interposed in the exit conduit means for controlling the operation of the separate sections of the filter means, such that the liquid flow through the exit conduit means from each of the separate sections is controlled in a predetermined sequence. The three separate sections of the filter means operate in three discrete stages to provide a substantially uniform liquid flow to the hydrate former subsystem during the charging of the battery system. The separation of the liquid from the hydrate causes an increase in the density of the hydrate by concentrating the hydrate along the filter means.
Filtration has been developed as a practical art rather than as a science, possibly because the large number of variables involved in any particular type of filtration result in analytical situations that can be solved more economically by experimental rather than theoretical methods (Perry's Chemical Engineer's Handbook, 5th Ed., McGraw-Hill, 1969, pp. 19-57-60). The use of filtration theory is limited by the fact that filtering characteristics must always be determined on the actual slurry in question, as the data obtained on one type of slurry is generally not applicable to another because of distribution and packing characteristics.
Filtration proceeds by the formation of a layer or cake of solid particles on the surface of a porous filter media. Once this layer has formed, its surface acts as the filter media. As solids are deposited, they add to the thickness of the cake and the liquid is filtered-out. The liquid passes partially through a bulky mass of particles of irregular shape and partially through small channels that tend to form in the cake.
The liquid flow through both the packed particle bed and the small channel is laminar. Therefore, the Poiseuille equation, which is the analytical expression applicable to laminar flow, is frequently used as a basis for the semi-empirical characterization of the bedflow parameters. In this instance, parameters that cannot be determined separately are collected or "lumped." The parameters that are known are then applied to the equation to extract the lumped parameters.
Applied to filtration, the Poisuille equation becomes: ##EQU1## where V=Volume of filtrate (solution)
A=Area of filtering surface
p=Total pressure drop across the filter media and the cake deposited on it
μ=Viscosity of filtrate
W=Mass of dry cake solids corresponding to V
α=Specific cake resistance
r=Other resistance losses in the system across which P is the pressure drop.
W is related to V by: ##EQU2## where ω=Mass of dry cake solids per unit volume of filtrate
ρ=Density of the filtrate
C=Mass fraction of cake solids in the slurry
m=Mass ratio of wet cake to dry cake
The symbol α representing the average specific resistance of the filter is a constant for the particulate cake in its immediate condition at a particular operating value of P.
The variable α is related to pressure P by the empirical expression:
α=α'PS (3)
α'=Bed resistance coefficient, a constant determined by particle size and shape
S=Cake compressibility, 0.0 for rigid incompressible particles and 1.0 for very highly compressible cakes
If the pressure is constant, equations 1 and 2 may be combined to give ##EQU3##
If the provision is made to measure the pressure drop across the cake independent of the filter media, the constant r can be neglected to give: ##EQU4## Dividing both sides by t2 and rearranging: ##EQU5## Substituting equation 3 into equation 6 ##EQU6##
Equation 7 is a standard form used to describe continuous filtration where P is the pressure drop across the filter cake. (See, Unit Operations of Chemical Engineering, W. L. McCabe and J. C. Smith, McGraw-Hill, 3rd Ed., 1976, pp. 942-946). The parameters μ, α' and ω are constants. If the volume rate of solids filtration V/t is held constant, measurements of pressure as a function of time can be sued to directly determine the apparent cake compressibility, S.
In experiments conducted to determine the characteristics of chlorine hydrate filtration, the value of the compressibility coefficient S was found to be 0.73 when water was used for the hydrate forming liquid media. This compressibility coefficient value indicates that the hydrate in the store behaves as a highly compressible filter cake. The value of the bed resistance coefficient α' was also found to be approximately 2.73�105 (cm, g, sec.). This bed resistance coefficient value indicates that within the range of hydrate concentration tested (8 to 23 percent), the chlorine hydrate cake is highly porous or channeled. These experiments supported the hypothesis that the previously achieved hydrate storage density could be increased by modifications to the means of filtration in order to take advantage of the cake porosity and compressibility.
Referring to FIG. 1, a simplified schematic of a zinc chloride battery system 10 according to the present invention is shown. The battery system 10 generally comprises a battery stack 12, a sump 14, and a hydrate store 16. The stack 12 comprises a plurality of cells each having a positive electrode and a negative electrode. The detailed description of a typical cell construction may be found in U.S. Pat. No. 4,100,332 to Peter Carr, issued July 11, 1978, assigned to the assignee of the present invention. The sump 14 comprises an electrolyte reservoir which feeds an electrolyte pump 18 used to circulate the electrolyte to all the cells in the battery stack.
During the charging of the battery system 10 chlorine gas is generated or liberated at the positive electrodes in the battery stack 12. The formation of chlorine hydrate in the battery is accomplished by mixing the chlorine gas with an aqueous liquid which has been chilled to a temperature compatible with the formation of hydrate for that liquid (typically between -8� to +6� C.). This liquid or hydrate forming media may be comprised of the battery electrolyte itself, water, or other suitable liquids. In battery system 10 a portion of the hydrate forming liquid is provided by the battery electrolyte via conduit 20, and the remaining portion is provided by the filtered liquid through conduit 22. Conduit 22 includes an orifice 24 which is used to regulate the flow of the liquid through the conduit. The liquid or electrolyte from conduits 20 and 22 combine and flow through a heat exchanger 26 which is used to decrease the temperature of the electrolyte to the level required for the formation of hydrate. In one form of the present invention, the heat exchanger 26 comprises a tube-shell type heat exchanger having on the order of one hundred and fifty thin wall titanium tubes arranged in parallel. A more detailed discussion of this type of heat exchanger may be found in "Development of the Zinc-Chlorine Battery for Utility Applications," Interior Report EM-1051, April, 1979, pp. 15-9, 15-10. The chlorine gas generated in the battery stack 12 is mixed with the chilled electrolyte in conduit 28, and pumped into the hydrate store 16 via a gas pump 30 conduit 32. In one form of the present invention, the gas pump 30 comprises of G-10 gear pump manufactured by Eco Pump, Corp., New Jersey. A detaled discussion of the structure and operation of the G-10 pump may be found in "Development of the Zinc Chlorine Battery for Utility Applications," Interim Report EM-1051, April, 1979, pp. 17-7, 17-8. The heat exchanger 26 and the gas pump 30 comprise the hydrate former subsystem for the battery system 10. The solution of the chilled electrolyte and the chlorine gas is mixed under turbulent conditions to form a finely divided particulate chlorine hydrate by the reaction of
CL2 (g)+H2 O(L)⃡CL2.XH2 O(S),
where x is approximately 6-8 for chlorine hydrate under normal conditions.
At the beginning of charge, the hydrate store 16 is filled with the hydrate forming liquid. Due to its density, the particulate chlorine hydrate expelled from the pump outlets 34 and 36 will normally rise through the liquid until it reaches a top filter section 38. The flow of the newly formed hydrate slurry into the store 16 will cause liquid flow through the top filter section 38 into a top intake conduit 40. The top intake conduit 40 is connected to a manifold conduit 42 which serves (as part of an exit conduit subsystem) to return the liquid used in the hydrate formation process to the heat exchanger 26 in order to the recycled. The battery system 10 also includes a liquid/gas separater 44 which permits any gas leaving the hydrate store 16 to return to the battery stack 12. As will be more fully discussed below, the hydrate filter means accordiang to the present invention is constructed so as to permit gas and liquid flow, but to prevent the particulate hydrate from escaping a store container 45.
As the charging of the battery system 10 progresses, the particulate chlorine hydrate will gradually form as a compressible cake along the top filter section 38. This filter cake will be supported in part by the upward fluid flow and by very small residual attached gas bubbles. As the thickness of this filter cake increases during charge, the pressure drop through the cake increases. The hydrate cake itself becomes a filter, and the cake will compress as the liquid attempts to find its way through the cake under the hydraulic pressure load. This will in turn decrease the pore volume available for flow, thereby adding further resistance to liquid flow and increasing the pressure drop across the hydrate cake. Although a positive pressure in the store 16 will serve to compress and compact the hydrate, at some point in the hydrate bed depth the pressure drop across the hydrate bed or cake will exceed the pratical design limits for the store container 45 and the gas pump 30. Additionally, the liquid flow through the intake conduit 40, and hence the liquid flow to the heat exchanger 26, will gradually begin to decrease as the hydrate cake becomes more resistant to liquid flow. This will, of course, affect the formation of the hydrate by upsetting the balance of liquid to gas flow. This situation is further complicated by the fact that the particle size of the hydrate is believed to be inversely proportional to the concentration of the zinc chloride electrolyte. The sizes of the hydrate particules appear to be much smaller with the 25% zinc chloride solution concentration normally employed at the beginning of the charge. Larger particle sizes occur with the 5% zinc chloride solution concentration normally encountered at the end of the charge. Accordingly, as the zinc chloride concentration in the electrolyte changes during the charge, the particle size of the hydrate will also vary. Additionally, the viscosity of the electrolyte being used to form the hydrate will also vary due to the gradually changing electrolyte concentration during the charging of the battery system.
In order to achieve advantageous results of the present invention, battery system 10 is also provided with a side section filter 46, and a bottom section filter 48. Each of the filters 38, 46 and 48 are completely separate and operate in 3 discrete stages. In the first stage only the top filter section 38 operates to concentrate the hydrate by filtering out the excess liquid. In the second stage both the top filter section 38 and the side filter section 46 are operable, and in the third stage all three of the filter sections are operable. The sequence and timing of these stages are controlled by a pair of relief valves 50 and 52 which are interposed in the manifold conduit 42. In the first stage, the excess liquid from the hydrate store 16 flows freely through the top intake conduit 40 and out to the manifold conduit 42. However, fluid flow through the side filter section 46 and the bottom filter section 48 is prevented by the pressure responsive relief valves 50 and 52. The side filter section 46 is provided with a side intake conduit 54 which has an inlet port 46 disposed in the space between the filter section and a side portion 58 of the store means container. Similarly, the bottom filter section 48 is provided with a bottom intake conduit 60 which has an inlet port 62 disposed in the space between the filter section and a bottom portion of the container. The intake conduit 54 is connected to the mainfold conduit 42 between the relief valve 50 and relieve valve 52, while the intake conduit 60 is connected to the inlet port side of the relief valve 52. The relief valve 50 is adapted to permit liquid flow through the side intake conduit 54 above a first predetermined pressure in the store means container. Similarly, the relief valve 52 operates to permit liquid flow through the bottom intake conduit 60 above a second predetermined pressure in the store means container. In one form of the present invention, the first predetermined pressure lies in a range between 2 psi to 6 psi, with a preferred pressure level of 4 psi in the store container. The second predetermined pressure also lies within a range of 3 psi to 8 psi, with a preferred pressure level of 6 psi.
In operation, the top filter section 38 cooperates with the relief valve 50 in the first stage to concentrate the hydrate along the top filter section of the filter means until the pressure in the store container rises above the first predetermined pressure. This allows compression of the hydrate on the primary or top filter section 38 until such time that the pressure rises to such a point the hydrate cake is optimumly compressed along the top filter section. In the second state the pressure responsive relief valve 50 opens to permit flow through the side intake conduit 54, thereby permitting the side filter section 46 to operate. In this stage, both the top filter section 38 and the side filter section 46 will operate to filter the excess liquid. However, the hydrate will quickly form a cake along the side filter section 46 due to the lower resistance to liquid flow. Accordingly, even though both these filter sections will be operating, the side filter section 46 will become the primary filter doing the substantial portion of the work until the cake forms and compresses to the bed depth along the top filter section 38. In the third stage, both of the relief valves 50 and 52 will open to permit liquid flow through all three of the filter section of the filtering means. However, as in the case of the second stage, the bottom filter section 48 will become the primary filter during the initial portion of the third stage. It will also be appreciated that during the third stage the manifold conduit 42 will operate to receive liquid flow from the first, second and third intake conduits, 40, 54, 60, respectively, and transmit this liquid to the hydrate forming means, that is the heat exchanger 26 and gas pump 30.
The above described operation of the hydrate store 16 achieves several advantageous results over previous single filter or single stage hydrate store designs. Firstly, the multiple stage, multiple filter hydrate store according to the present invention provides a controlled compation or compression of the hydrate in the store during the charging of the battery system. In a single stage filter design little hydrate compaction occurs until a filter cake forms along the entire filter means, whereas in battery system 10 hydrate compaction occurs very quickly along the top filter section 38. Thus, the hydrate store 16 is adapted to maintain a hydraulicly compressive load on the hydrate substantially during the entire charging of the battery system 10. Additionally, the hydrate store 16 also operates to achieve a substantially uniform liquid flow to the heat exchanger 26 during the charging of the battery system by providing for 3 separate intake conduit portions which are operable in 3 distinct stages. It will also be appreciated that this hydrate concentration system is adapted to maintain the pressure in the hydrate store within acceptable levels during the charging of the battery system 10 by providing for 2 controlled pressure relief levels.
Turning now to FIG. 2, a top elevation view, partially in cross-section, of the hydrate store 16 is shown. As is readily apparent from this figure, the hydrate store 16 is generally cylindrical in nature. Accordingly, the store container 45 comprises the generally vertically disposed annular side portion 46, a generally horizontally disposed circular top portion 66, and a generally horizontally disposes circular bottom portion 64. As may best be seen with reference to FIG. 1, both the top portion 66 and the bottom portion 64 are deformed or bowed outwardly to reduce the effective pressure on these portions of the container 46. To prevent the escape of gas or liquid from the store container 45, both the top portion 66 and the bottom portion 64 are secured to the side portion 58 in a sealing relationship. Specifically, a pair of annular collar members 68 and 70 are employed to secure the top portion 66 and the bottom portion 64 to the side portion 58 via a plurality of elongated horizontally disposed bolts 72. However, it should be appreciated that this method of attachment is intended to be exemplary only, and that other suitable methods of attachment may be employed in the appropriate application.
Although the principles of the present invention may be applied to a variety of store container shapes, such as a spherical shape, it has been found advantageous in a cylindrical configuration to provide a predetermined geometrical relationship between the magnitude of the height of the side portion 58 of the container and the magnitude of the diameter of the top and bottom portions 66 and 64 of the container. Specifically, it is preferred that the ratio of the side portion height to the top/bottom portion diameter should be between 0.25 and 0.9. The reason for this specific geometrical relationship is derived from the packing characteristics of the chlorine hydrate. It is believed that a relatively greater side portion height with respect to the top/bottom portion diameter may lead to premature dense packing of the hydrate along that portion of the side filter section nearest to the pump outlets during the second state of operation. This situation could arise because the hydrate cake along the top filter section may form a downwardly projecting column which overlaps the upper portion of the side filter section and impedes the formation of dense hydrate on this portion of the side filter section. Since the densest packing occurs at the filter surface, excessive side portion container heights may result in non-uniform hydrate formation and packing along the side filter section of the filter means. It should also be noted that the heat exchanger 26, the gas pump 30, and the relief valves 50 and 52 are all disposed outside the hydrate store container 45. This is intended to reduce any interference with the packing of the hydrate within the store container 45. However, these components may also be suitably disposed within the container 45 in the appropriate application.
Referring to FIG. 3a, a cross-sectional view of the hydrate store 16 is illustrated, the section being taken generally along line AA of FIG. 2. FIG. 3a particularly illustrates a space 74 between the side section filter 46 and an interior surface 76 of the side portion 58 of the container 45. The filter section 46 is supported by a screen 78 which has a plurality of perferations therethrough to permit liquid flow from the interior of the store 16 to the space 74. A plurality of spacer bars 80 provide a predetermined distance between the screen 78 and the interior surface 76 of the side portion 58. The relative length of the spacer bars 80 may best be seen with reference to FIG. 3b, which is a partial plan elevation view of the interior side portion of the store container 45. The arrows in FIG. 3b indicate that the liquid flow through the side filter section 46 travels vertically around the spacer bars 80 toward the side intake conduit 54. The spacer bars 80 may be cemented, welded or otherwise conventionally secured to the side portion 58 of the container 45 (at reference numeral 80), depending upon the materials used for the container and the spacer bars. The predetermined distance provided by the spacer bars 80 is preferably between 1/8th and 1/4th inches, but this distance may be varied so long as a sufficient distance is provided to permit the necessary gas and liquid flow in the space 74.
As illustrated in FIGS. 1, 3a and 3b, the filter sections 38, 46 and 48 combine to substantially cover the interior surface of the container 45, and it is preferred that the space between the filter sections be minimized in order to provide as much filter surface area as possible within the store container. Each of the filter sections are secured to their respective container portions around the periphery thereof in a particle-tight sealing relationship. It should be appreciated that a gas tight or liquid tight seal is not required as the filter sections need only be adapted to retain the hydrate particles within the store container. One form of securing the filter sections to the container portions is illustrated in the FIGS. 3a and 3b. Specifically, the filter cloth 46 is folded over an end spacer bar 84 and anchored thereto via a plurality of bolts 86.
Referring to FIGS. 4a and 4b, a cross-sectional view of a portion of another hydrate store 88 is shown. These figures particularly illustrate an alternative technique of securing the filter sections of their respective container portions. Firstly, the hydrate store 88 illustrates that a container portion 90 may be provided with a suitable liner 92 which may be operable to both protect the container from corrosion and protect the interior of the store from contamination. With respect to the technique of sealing, an end spacer bar 94 is provided with an inwardly expanding, outwardly opening channel 96 which is adapted to receive the end of a filter cloth wrapped around a resilient, deformable bead 100. During the insertion of the filter section end in bead 100 into the channel 96, the bead 100 will deform and contract to permit the bead and the filter end to be translated past the opening of the channel and become nestingly received within the channel. It will be appreciated that once the bead 100 is received within the channel 96 it will again expand to its normal diameter and operate to retain the end of the filter section 98 within the channel.
Referring to FIG. 5, a plan elevation view, partially in cross-section, of the relief valve 50 shown in FIG. 1 is illustrated. The relief valve 50 generally comprises a housing 102 having an inlet port 104 and one or more outlet ports 106, a ball 108 operably associated with the inlet port 104, and a weighted rod 110 for controlling the position of the ball 108 in response to the pressure at the inlet port 104. When the ball 108 is in its seated position, as shown in FIG. 5, it will sealably engage a seal element 112 preventing any gas or liquid from passing from the inlet port 104 to the outlet port 106. However, when the pressure at the inlet port 104 exceeds the first predetermined pressure the ball 108 will be forced upwardly against the weight of the weighted rod 110 to permit the fluid flow through the outlet port 106. It should be noted that the construction of the relief valve 50 is intended to be exemplary only, and that other suitable relief valve constructions may be employed, such as spring loaded relief valves or electrically operated relief valves. For example, one electrically operated relief valve is exemplified by Model No. DV2-146NCA1, manufactured by the Flourocarbon Company, Anaheim, Calif.
In terms of materials which may be employed for the hydrate stores according to the present invention, it should first be noted that the materials should be chemically resistant or inert to the electrolyte and other chemical entities with which they will come into contact. With respect to the filter section, it is preferred that DuPont Armalon cloth having one of the following model numbers be employed: XT2363, XT2663, E9223-7-1, E9223-17-1, E9223-20. With respect to possible materials for the store container portions and spacer bars, one or more of the following materials may be employed: DuPont teflon, (TFE) polytetraflouroethylene, (FEP) Flouronated Ethylene Propalene copolymer, (PFA) (EPE) Perfluoro alkoxy resin, DuPont Tedlar, (PVF) Polyvinyl Flouride, DuPont Tefyel, (CTFE) Chlorotrifluoroethylene, (Allied) Halar, (ECTFE) Ethylene-Chlorotriflouroethylene, (Pennwalt) Kynar, (PVDF) Polyvinylidine Fluoride, (General Tire & Rubber Corp.) Bolton (PVC) Polyvinylchloride (4008-2124), glass fiber, carbon. With respect to the screen supporting the filter sections, such as screen 78, it is preferred that titanium expanded screen be employed. However, one or more of the above-identified plastic materials may also be employed.
The various embodiments which have been set forth above were for the purpose of illustration and were not intended to limit the invention. It will be appreciated by those skilled in the art that various changes and modifications may be made to these embodiments described in this specification without departing from the spirit and scope of the invention as defined by the appended claims.
|Cited Patent
|Filing date
|Publication date
|Jun 26, 1970
|Jan 30, 1973
|Oxy Metal Finishing Corp
|Process for electrical energy using solid halogen hydrates
|Nov 18, 1971
|Nov 27, 1973
|Occidental Energy Dev Co
|Production of aqueous zinc chloride electrolyte saturated with chlorine
|Nov 18, 1971
|Jan 1, 1974
|Udylite Corp
|Apparatus and method for making chlorine hydrate from high energy density battery electrolyte and chlorine
|Jul 5, 1972
|Feb 19, 1974
|Occidental Energy Dev Co
|Battery including apparatus for making halogen hydrate
|Aug 31, 1972
|May 7, 1974
|Occidental Energy Dev Co
|Process for forming and storing halogen hydrate in a battery
|Nov 18, 1971
|Jun 4, 1974
|Occidental Energy Dev Co
|Filter/store for electric energy storage device
|May 26, 1972
|Jul 9, 1974
|Energy Dev Ass
|Secondary battery comprising means for forming halogen hydrate solid bubble shells
|Mar 20, 1972
|Oct 8, 1974
|Energy Dev Ass
|Stable chlorine hydrate
|Jan 11, 1974
|Sep 23, 1975
|Energy Dev Ass
|Halogen hydrates
|Nov 18, 1971
|Sep 23, 1975
|Energy Dev Ass
|Manufacture of chlorine hydrate
|Jan 3, 1973
|Jan 27, 1976
|Energy Development Associates
|Halogen hydrates
|Feb 7, 1975
|Feb 24, 1976
|Energy Development Associates
|Halogen hydrates
|Oct 29, 1975
|Nov 23, 1976
|Energy Development Associates
|Metal halogen hydrate battery system
|Nov 20, 1975
|Jan 4, 1977
|Energy Development Associates
|System for improving charge efficiency of a zinc-chloride battery
|Dec 23, 1976
|Sep 19, 1978
|Energy Development Associates
|Halogen hydrate formation from halogen and finely divided aqueous droplets
|Jun 15, 1978
|Mar 27, 1979
|Energy Development Associates
|Operational zinc chlorine battery based on a water store
|"45-kWh Zinc-Chloride Load-Leveling Battery Module: Recent Performance Improvements", R. D. Clubb, et al., pp. 1-4 (from the Proceedings of the 29th Power Sources Symposium).
|"50 kW-hr Zinc-Chlorine Hydrate Battery", Peter Carr et al., (from the Proceedings of the 28th Power Sources Symposium), pp. 23-26.
|"Development of the Zinc-Chloride Battery for Mobile Applications", A. Lijoi, Sections 18 and 23, Dec. 1981.
|"Newsweek", Jun. 16, 1980, pp. 75 and 76.
|G+W News Services, "G+W Electric Engine Units Power First Practical Electric Vehicles", Jun. 5, 1980, pp. 1-7.
|Citing Patent
|Filing date
|Publication date
|Jan 21, 1983
|Apr 29, 1986
|Energy Development Associates, Inc.
|Method and apparatus for regulating the hydrate formation temperature in a metal-halogen battery
|Jul 5, 1985
|Jul 7, 1987
|Energy Development Associates, Inc.
|Formation of dense chlorine hydrate
|Oct 22, 2010
|Aug 4, 2015
|Redflow R&D Pty Ltd.
|Recombinator for flowing electrolyte battery
|Aug 16, 2011
|Feb 21, 2013
|Primus Power Corporation
|Flow Battery with Reactant Separation
|Oct 22, 2010
|Apr 28, 2011
|Redflow Pty Ltd
|Recombinator for flowing electrolyte battery
|U.S. Classification
|429/51, 429/105
|International Classification
|Cooperative Classification
|European Classification
|Apr 16, 1982
Owner name: ENERGY DEVELOPMENT ASSOCIATES, INC., 1100 WEST WHI
Free format text: ASSIGNMENT OF ASSIGNORS INTEREST.;ASSIGNOR:BJORKMAN, HARRY K. JR.;REEL/FRAME:004004/0260
Effective date: 19820413
Owner name: ENERGY DEVELOPMENT ASSOCIATES, INC., A CORP. OF D
Free format text: ASSIGNMENT OF ASSIGNORS INTEREST;ASSIGNOR:BJORKMAN, HARRY K. JR.;REEL/FRAME:004004/0260
Effective date: 19820413
|Jan 3, 1984
|Certificate of correction
|Oct 30, 1986
|Fee payment
Year of fee payment: 4
|Oct 23, 1990
|Fee payment
Year of fee payment: 8
|Sep 19, 1994
|Fee payment
Year of fee payment: 12


text:
Tilt & Shitf Panoramas (revisited)
Hi Nikonians.
On this occasion, I am uploading 2 panos that were processed again using this time Nik Plugins (Color Effex Pro 4 and HDR Effex Pro).
The good news is that these 2 pictures are great candidates for studying the effect of the filters, since I maximize DOF by tilting the lens 2 cm downwards while shifting it left, center, right, to get a 3 vertical pano picture.
Both are of Patagonia Argentina, and they belong to Cerro Torre, reflected in Torre Lagoon, surrounded by Adela Range and Great Glacier.
I hiked to the basecamp to stay overnight and visited the area 2:30 hours before sunrise.
The first one was taken at night: 4,40 am (2:20 hs. before sunrise), with my D3, 45 mm pc-e plus Singh Ray Color LB Combo Polarizer, plus Singh Ray 3 stops ND filter. EV: 30'x f5.6 iso 250.
The second one, is the same picture was taken just when the sun hits -for the very first time- the mountain and creates that intense red light on it. It is possible to see the shadows of the light on the lower part of the mountain. It also can be seen the wind on the water (ripples on water) creating a reflection in movement. It was taken at 7.25 am, EV: 2' x f11, iso 200, both Singh Rays filters used.
I launched Nik Color Effex Pro 4 and HDR Effex Pro within lightroom 4 and did some twicks, especially playing with all the contrast buttoms, and detail extractor.
I had to compress these pictures to 30% in order not to exced the maximun size permitted to upload.
Another option to view is my website, here:
I am truly satisfied how well these plugins work with the pictures.
Comments are wellcome.
Jose, nikonian
from Santiago del Estero, Argentina
Visit my Nikonians gallery.
Attachment#1 (jpg file)
Attachment#2 (jpg file)


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Poll: How many points will Brendan Morrison get this season?
Newly acquired center Brendan Morrison is expected to help provide second-line scoring for the Ducks. Morrison had nine goals and 16 assists (25 points) in 39 games last season, which was cut short due to a knee injury.
He averaged 59 points in six seasons prior to that with Vancouver.
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