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Freshman Organic Chemistry II (CHEM 125B)
Discoverers of the structure and biological activity of steroid hormones won seven Nobel Prizes between 1927 and 1975. Studying the steps involved in Woodward's 1951 "total" synthesis of cortisone provides a review of the organic reactions covered this semester. Many steps involved novel insights, others were based on lore from previous work In the area. The overall yield of such sequential syntheses is typically much lower than that of convergent syntheses. Practical syntheses of cortisone were based on modification of related steroids readily available from nature. Milestones in total synthesis include both purely intellectual work with natural products and commercially important synthesis of designed pharmaceuticals. The course ends with thanks to those, young and old, who have taught us all.
00:00 - Chapter 1. Steroids and the Medicinal Activity of Cortisone
07:43 - Chapter 2. Woodward's Total Synthesis of Cortisone
33:27 - Chapter 3. Practical Synthesis of Cortisone
38:59 - Chapter 4. Some Milestones in Organic Synthesis
44:59 - Chapter 5. Thanks to Teachers, Colleagues, Family, and Students
Complete course materials are available at the Open Yale Courses website: http://oyc.yale.edu
This course was recorded in Spring 2011.
Tagged under: cortisone,steroid,hormone,Nobel,Woodward,Michael addition,vinylogous,lore,total synthesis,convergent synthesis,Russell Marker,diosgenin,strychnine,vitamin B12,Eschenmoser,Kishi,palytoxin,Eribulin,
Clip makes it super easy to turn any public video into a formative assessment activity in your classroom.
Add multiple choice quizzes, questions and browse hundreds of approved, video lesson ideas for Clip
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* Whiteboard required for teacher-paced activities
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Team Up
Student teams can create and share collaborative presentations from linked devices
Turn any public video into a live chat with questions and quizzes
Tried out the canvas response option on @SpiralEducation & it's so awesome! Add text or drawings AND annotate an image! #R10tech
Using @SpiralEducation in class for math review. Student approved! Thumbs up! Thanks.
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The Team Up app is unlike anything I have ever seen. You left NOTHING out! So impressed!

subset: commoncrawl


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"The life I love is making music with my friends," is a lyric from "On the Road Again," a popular 1980 hit for Willie Nelson, whose life is celebrated in "Willie Nelson: The Library of Congress Gershwin Prize for Popular Song" (9 p.m., PBS, TV-PG, check local listings). Taped last November, the special honors the prolific, perennially touring singer/songwriter who redefined country music even as he has expanded his audience.
Nelson performs many of his signature hits along with Edie Brickell, Leon Bridges, Rosanne Cash, Ana Gabriel, Jamey Johnson, Alison Krauss, Raul Malo of The Mavericks, Neil Young and Buckwheat Zydeco. He is also joined by fellow Gershwin Prize recipient Paul Simon.
I'm no musician or music critic, but I have always found Nelson's voice and delivery to be utterly distinctive. The moment you hear him sing one note, you know it's Willie Nelson. Nobody else sounds like him. Not unlike Fred Astaire, another unique and distinctive performer, Nelson's delivery often blurred the line between singing and talking.
Even when delivered by more melodic voices, his early songwriting hits had the aura of the confessional, the sound of a lonely soul talking to himself. His first big hit, "Hello Walls," a No. 1 hit for Faron Young in 1961, spoke of the solitary confinement of the lovelorn. "Crazy," a 1961 hit for Patsy Cline, speaks for itself, and Ray Price's cover of "Night Life" has a similar introspective feel.
Nelson is among the many artists to defy the adage that "there are no second acts in American life." His stint as a hit-maker for Nashville gave way to an "outlaw" movement more than a decade later, when Nelson and other artists challenged the country music establishment, often from the friendly confines of Austin, Texas, a place better known for cosmic cowboys than the Grand Ole Opry. By the 1980s, Nelson was crossing over between country and pop, appearing frequently on "The Tonight Show" with Johnny Carson.
Over the course of his career, Nelson the songwriter has never been shy about interpreting the works of others, recording everything from "Blue Skies" by Irving Berlin to Leon Russell's "A Song For You" and Hal David and Albert Hammond's "To All the Girls I've Loved Before."
Perhaps that's why this songwriter's songwriter is way overdue for the Gershwin Prize. You just might say it's high time.
- Fox devotes its Fridays to kitchen duty. In addition to "MasterChef: Junior" (8 p.m., TV-PG), "Hell's Kitchen" (9 p.m., TV-14) enters its 15th season with contestants showing off their signature dishes in Las Vegas.
After so many seasons, viewers have every right to know how these things shake out. The winners of the first challenge get to ride on the world's tallest Ferris wheel, a fate some may wish to avoid. Also-rans are subjected to scullery drudgery - peeling a half-ton of potatoes and peeling and de-veining 50 pounds of shrimp. And everybody is subjected to chef Gordon Ramsay's patented tirades. Now you know what you're in for.
Tonight's other highlights
- Executive vertigo on "The Amazing Race" (8 p.m., CBS, TV-PG).
- Weezer performs on a live episode of "Undateable" (8 p.m., NBC, TV-14).
- A Google legend returns to "Shark Tank" (9 p.m., ABC).
- Too much junk in the trunk on "Blue Bloods" (10 p.m., CBS, TV-14).
Cult choice
"Super Bowl I: The Lost Game" (8 p.m., NFL) cobbles together footage of the first "Super Sunday," a meeting between the NFL's Green Bay Packers and the fledgling AFL's Kansas City Chiefs, held on Jan. 15, 1966. The halftime entertainment consisted of college marching bands.
Series notes
Joe the mechanic (Jay Leno) returns on "Last Man Standing" (8 p.m., ABC) ... Mary needs Gideon's help on "Reign" (8 p.m., CW, TV-14) ... Take your daughter to work day on "Superstore" (8:30 p.m., NBC, r, TV-14) ... Doctor phobia on "Dr. Ken" (8:30 p.m., ABC).
McGarrett's aunt has unfinished business on "Hawaii Five-0" (9 p.m., CBS, TV-PG) ... "Dateline" (9 p.m., NBC) ... Illusionists audition on "Penn & Teller: Fool Us" (9 p.m., CW, r, TV-PG) ... "20/20" (10 p.m., ABC).
Late night
Scott Kelly, Abby Wambach and Maria Bamford appear on "The Late Show With Stephen Colbert" (11:35 p.m., CBS) ... Jimmy Fallon welcomes Ray Romano, Lucy Hale and Brandi Carlile on "The Tonight Show" (11:35 p.m., NBC) ... Kathy Griffin, Aaron Sorkin and the Internet appear on "Jimmy Kimmel Live" (11:35 p.m., ABC, r).
Christian Slater, Retta and Sam Hunt visit "Late Night With Seth Meyers" (12:35 a.m., NBC, r) ... Taye Diggs, Amy Landecker and 5 Seconds of Summer appear on "The Late Late Show With James Corden" (12:35 a.m., CBS, r).


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Land & Construction Loans | A Credit Union for Vermonters | VSECU – Your down payment will go into your project prior to any loan disbursements. After the construction loan period is completed we can refinance your loan into one.
Decoding loan amortization – EMI payments and Loan Amortization Did you know that when you make an EMI payment on your loan, it comprises two items? Firstly, you pay the cost of the loan, i.e., the interest charged by the lender..
horrible credit home loans How to get a home equity loan even with bad credit – How do I qualify for a home equity loan if I have bad credit? Not all lenders have the same standards. chief financial analyst at Bankrate.com. "Lenders have become much more diligent about loans.
New mortgage rules 2018: A practical guide – New rules by Canada's federal financial regulator announced in October mean that even borrowers with a down payment of 20 per. test even if you apply for a mortgage in the new year, said Laird..
How to Finance Your New Construction Home – Down payments below 10 percent may be possible but they require high private mortgage insurance premiums. New-Construction Loan Financing A construction loan is likely to be useful to you if you are building a home yourself as general contractor or working with a custom builder.
Mortgage Calculator – Know Your Options – Estimate your monthly mortgage payments based on the home price. note: calculators display default values. enter new. Payment Info; Loan Info. Monthly .
Construction Loan Interest Calculation – Mortgage News Daily – Construction Loan Interest Calculation. This is your monthly interest only payment.. At time of modification you will be able to pay down the construction loan ( if you are utilizing equity.
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What Is a Home Construction Loan – Process & How to Qualify – Considering a home construction loan to help build your dream house? See how they work, pros & cons, and how you can qualify.. You Will Need to Put Down a Large Down Payment. Typically, 20% is the minimum you need to put down for a construction loan – some lenders require as much as 25%.
How an FHA Construction Loan Works – The Lenders Network – How an FHA Construction Loan Works. BY The Lenders Network. 2 minute read.. FHA home loans are great because of their low credit and down payment requirements. You may be wondering how you can get an FHA construction loan to pay for the project.
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Loan Calculator and Payment Schedule | Not a Toy – Since you may have happened upon this loan calculator to calculate a monthly payment, I'll cut to the chase. You'll only need to enter three numbers, and you can leave the other dozen or so options untouched.. Here's all you need to do.
Construction Loans: Funds to Build and Buy Land – The Basics of Construction Loans to Help You Buy Land and Build . Share. A construction loan is a short term loan for real estate.. (or no payments at all in some cases) based on the amount you've borrowed to-date. As certain milestones are reached, you or your builder will request draw.


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With temperatures soaring to often unbearable levels, keeping cool is priority. Retreat from the heat with our 7 tips, to keep cool and save energy, using your air conditioner and DIY home hacks. Keeping comfortably cool has never been such a breeze!
1. Keep it Clean!
It is important to clean your air conditioner filters regularly – as often as every two weeks. Not only does a regular filter clean improve your air conditioner's efficiency, it also prolongs its lifespan. For a quick how-to guide, check out https://www.mitsubishi-electric.co.nz/materials/Aircon/Info_Guides/QuickCleanKit.pdf
2. Don't Push it to the Limit
Turning down your thermostat by 10°C won't cool the room down any faster than if you turn it down by 2°C – it will simply make your air conditioner work harder for longer. Avoid using more energy than necessary by setting your thermostat to around 22°C.
3. Dry for Some Time
An effective way to keep temperatures comfortable while spending less money on energy bills is to utilise the Dry Mode. When setting your air conditioner to Dry mode, the fan will be running but no temperature is set; creating a cooling effect by removing excess moisture from the room.
4. Draw the Curtains
Simple yet effective, keeping your curtains and blinds closed blocks out the sun; preventing your home from becoming a miniature greenhouse.
5. Drink and Eat Cool
Keep cool as a cucumber by staying hydrated and grabbing your favorite summer treat. Cold food and drink can help keep you cool from within and soothe the summer burn. Avoid spicy foods, up your fruit and vegetable intake and indulge in an ice-cream!
6. Swap the Sheets
Avoid sweaty sleepless nights by changing up your sheets. Stay away from the synthetic blends, and switch to cool cotton; lightweight and breathable, 100% cotton sheets allow for good air circulation.
7. Get the BBQ Going
No-one wants to be standing over a hot stove when it's warm inside. Prevent extra heat build-up by moving the cooking outside. If you don't have a BBQ, keep the heat and moisture from cooking to a minimum by using the extractor fan, opening a window and keeping the lid on your pots and pans.


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IMPORTANT! Due to the Coronavirus (COVID-19) health crisis events on our calendar may be canceled or postponed.
For a List of Rescheduled Events: Click Here
Rivertown Inn is filled with period antiques and the extraordinary details that one would expect at the finest European hotels.
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|X-raying is cheating and is therefore against the rules.
Now. The fact that I even have to point this out seems just crazy to me, the mind boggles. If you think that X-Raying or any other kind of cheating is ok then stop right here, leave the server now and go play single player creative, you aren't wanted here or any other server.
It also occurs to me that some people did not realize (or so they claim) that X-Raying is against the rules which again is just mind blowing so take this as a warning!
Auto Fishing is ALSO a form of cheating and is therefore against the rules.
1) You are not physically playing and possibly holding up a slot on the server.
2) You are bypassing the AFK mechanism which is in place for several reasons including ranking up.
3) McMMO skills are achievements! If you are auto fishing, you have given yourself an unfair advantage over others.
4) Players stock their shops with goods as a way to make an income. They work for their products. When you have dubs and dubs of fish and other McMMO goodies and you sell them, trade them, give them away, you are "cheating" the players who worked hard and spent time collecting those things.
MrT1melord wrote:You WILL be banned for X-Raying or any other way of cheating. You will get no warning and/or explanation for this. We take an awful lot of time to check, double check and triple check the records to see if you really are cheating and we are ALWAYS sure before we act – "I haven't done it" doesn't mean anything. By using any kind of cheats you willingly forfeit your right to play on our server and will therefore never be allowed back.
I hope this makes it clear for everyone what our position on this matter is.


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Health inspectors' £50,000 bill at St Albans four-star hotel
PUBLISHED: 17:00 29 February 2016
A St Albans hotel has had a £50,000 boost after hosting members of the government's health watchdog, who spent up large on accommodation while checking local NHS organisations, an investigation has revealed.
Taxpayers have paid for Care Quality Commission (CQC) inspection teams to stay at the likes of the four-star rated Mercure Noke Hotel in Watford Road.
A response to a Freedom of Information (FoI) request by Archant's investigative reporting unit shows that during a nine-month period, CQC teams spent a total of £95,209 on accommodation in Herts, including five-night stays at four-star hotels.
In one visit alone, an inspection team of 83 racked up a £50,880 bill staying at the Mercure Noke, while checking the Hertfordshire Partnership University NHS Foundation Trust.
Its September 2015 report on the trust, which has its headquarters in Waverley Road in St Albans, gave it an overall rating of 'good' with safety improvements required, including staffing levels at inpatient wards.
Figures obtained through the FoI request show that 172 inspection team members spent a total of 829 nights in hotels in the county, at an average cost of £115 per person per night, between May 2014 and January 2015, while visiting hospitals and NHS trusts.
Questions have been raised as a result of these findings with Katherine Murphy, chief executive of the Patients' Association, saying that while the CQC plays an important role in monitoring standards "they must ensure they offer taxpayers the best possible value for money and carry out their work as efficiently as possible".
However, a spokesman for the health watchdog defended the hotel bill, saying that the CQC's 'new style' inspections involve larger teams than in previous years.
The so-called new style checks allow inspectors to try to "get under the skin of an organisation" to give more detailed pictures - according to the watchdog's website - by using larger and more specialist teams to rate hospitals, community health and mental health services in England.
The spokesman said that CQC teams' visits to areas such as St Albans "last longer so that more time can be spent in observing the care being delivered, in speaking to people who use services and health and social care professionals, and in feeding back initial findings to the providers so that improvements can be made quickly.
"This gives a much more in-depth and detailed assessment of the quality of care, which encourages learning and improvement and can help people make informed choices about their care."
Teams also used hotels for their conference facilities to meet up and discuss findings post-inspection.
The watchdog's budget is due to fall from £249 million this financial year to £217m in 2019-20.
CQC guidelines show teams are barred from staying in five-star hotels or those where fees exceed £95 for bed and breakfast, rising to £145 in London.
• £28,819 was spent at the Hilton Hotel in Watford, £13,703 at the Ramada Hotel in Hatfield and £1,807 at the Best Western Claydon Country House Hotel in Ipswich.
If you value what this story gives you, please consider supporting the Herts Advertiser. Click the link in the orange box above for details.


text: "The money is always in the list!" We've heard this preached for well over a decade and a half in the digital realm and it has been true in other forms of marketing for over a century. But, this statement is only a partial truth. You see, buyers have evolved over the past several years… [Continue Reading…]


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Troubleshooting technical errors and ensuring that your website is always accessible is one of the biggest hurdles to manage when thinking about good SEO practices over time. Subheads help break up the text on a page, making it easier to read. At times, such a process involves rejuvenating or adjusting the image a brand conveys. Have you ever tried to buy artisan Victorian rocking horse round here? Does anyone know where I can find the best organic local fruit delivery ? What happens when you search for leased line quote for instance? A simple search on Bing for SEO York will give you what you need. Another popular language, ASP.NET, is Microsoft's answer to PHP. To calculate a brand's revenue premium, the revenue generated by a particular brand will be compared to a private label brand.
The steps needed for putting quality into action
Based on the marketing objectives and target market, the team develops marketing strategies. The main reason to disavow links is to protect the site from bad links that are harming the its reputation (and thus its rank on the Search Engine Results Page). Make a list of the keywords for which you want to rank highly. Does the content you share on social media and your blog cover those keywords? Zero in on one or two of your most desirable keywords and find ways to make content under those keywords more shareable. All that technical stuff. Be open to targets you wouldn't normally consider.
This could be something as simple and generic as 'coffee'. The average conversion rate for mobile-optimized sites is 3.4 percent compared to 1.6 percent for non-optimized sites. Naturally, the prerequisite to all of that is to have engaging content and a quality product (or service). So, how does Google determine site quality? This kind of evergreen content is usually longer than an average blog post. You have to make sure that the topic, content type, and format resonates with your audience. Your headline has to be catchy, but also relevant.
Be clear, truthful and accurate when it comes to site submissions
Gaz Hall, from SEO Hull, had the following to say: "Try and write blog content for external websites, which will link back to your website and boost your domain authority. Backlinks are the foundation of Google's algorithm." The algorithms used by search engines can be rather complex and include a number of different factors. But before that, let me make you familiar with digital marketing, Seo, and related terms. Now you must dig deep into the site, dissecting it from all angles. To put it briefly, the best way to fix thin content is to expand upon it in the place it is most relevant and to organize it appropriately.
Hummingbird is more about being able to understand search queries better
For user experience, performance, and web development trends, I really like Smashing Magazine, DZone, and Stack Overflow. With so much crap content on the web, Google doesn't want to waste space indexing it. You want a user to click your result in Google, and not need to go back to Google to do the same search that ends with the user pogo-sticking to another result, apparently unsatisfied with your page. Factors that affect a person's values include the individual's personality, temperament, environment, and one's culture. Link popularity is an example of the move by search engines towards off-the-page-criteria to determine quality content.
Answered - your burning questions about keywords
If you're going to undertaken business blogging for SEO purposes, you need to be aware that it takes a lot of time, and that it can be a while before you really start to reap the benefits. It's advised to provide affiliates with the same product feeds that are given to other 3rd party vendors who sell or promote your products. Every week, you should study an analysis of all the traffic from organic search queries to your website. This enables you to determine whether changes from previous weeks or months are having an effect. If you use an imagewithout the proper accreditation, then you could be facing a hefty invoice further down the line. Marketers can enhance relationships when they acquire more in-depth customer information such as hobbies, interests, attitudes, and opinions.


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Hilary Alan: "In 2006 we let go of everything that was familiar to us. … Nothing would ever be the same."
After the first tsunami wave struck, it was followed by a second and then a third. The waves were so deadly that hundreds of thousands of lives were claimed in a matter of minutes. The waves were high enough to knock off the top of a 10-story-high lighthouse. The same waves carried boats that were miles out at sea onto previously dry land. Wave-borne boats crushed homes and people in their paths. A huge 10-megawatt diesel power plant that had been mounted on a barge several miles offshore landed atop several homes in the middle of a village five kilometers inland. It remains there today.
There were people living miles inland who, though unaware of the devastation being wrought along the coast, somehow knew to run. Maybe it was instinct, maybe it was panic and maybe it was divine intervention. Many of them started running even before the deadly invading waters were visible. And those who remained behind, traumatized from the earthquake, soon saw the water racing toward them.
The dangers were mounting, and those who had not followed their instincts to run were now forced to confront what at first appeared to be minor flooding. But within seconds, low-lying areas filled with water, and it kept coming. The water level rose several stories high. People were killed by advancing waters because they had no time to react.
At the time, this province had no tsunami warning or sophisticated communication system to alert the people to what was happening at the coast. In a panic, people responded the only way they knew—they ran for their lives. Men, women, children—old and young—climbed on anything that was above what they anticipated to be flood level. But even those who tried to run were overcome by the explosion of rushing water. In seconds, deadly debris raced into the city as corpses, body parts, vehicles, fragments of buildings, boats and the debris of unidentifiable wreckage was swirling in blackened, poisonous waters. The screams of fleeing city dwellers were suddenly silenced as the waters overtook them.
In a matter of minutes, approximately 230,000 human lives were claimed by the earthquake and subsequent tsunami. And while this cataclysmic, life-changing event took place in Southeast Asia, I was half a world away and completely unaware.
When the Dec. 26, 2004, tsunami hit Southeast Asia, it was still Christmas night in North Carolina. I was safe in my comfortable home, doing what I'd been training all my life to do. I was living for myself.
At the time of the greatest natural disaster of my generation, I was a 41-year-old, upper-middle-class Christian American living a charmed life. The only thing I really cared about was making life as wonderful as possible for my family of four. So while thousands of people were losing their lives on the opposite side of the world, I was packing for a winter vacation in Florida.
The following Monday, news outlets in the West were reporting the horrific events that had transpired in the East. I was traveling south with my family in our Volvo station wagon. Thankful for the car's heated seats and munching on snacks from Whole Foods, my thoughts involved the hope that we would make good time as we headed toward Crystal River, Fla. The four of us were looking forward to swimming with manatees.
In the late morning we took a break at a rest stop just across the state line in South Carolina. It felt good to stretch our legs after driving the first few hours of a 10-hour road trip. It was a beautiful, sunny day in the southeastern United States, and the temperatures were mild for late December. But when I got back in the car, tragedy struck.
My seat belt wouldn't latch.
I tugged and pulled and then yanked on the belt, but it wouldn't click. I wasn't going to ride on I-95 in the front seat of a car without a seat belt, but I didn't want to spend the rest of my vacation riding in the less-comfortable back seat either! There wasn't anything we could do to fix a seat belt at a rest stop in South Carolina, so I climbed into the backseat between my son, Jordan, and my daughter, Molly. Curt got back on the highway, and I started calling Volvo roadside assistance, demanding immediate attention. This was definitely a case where quick action was really needed.
We found a Volvo dealer in Savannah, Ga. The service attendants were polite, even though they were stuck having to work on the Monday after Christmas. For my part I was thankful they were working so they could rescue us when we really needed it.
We were led to a comfortable waiting room where a television was tuned to a news channel. As we pulled lunches out of our cooler, we noticed the TV was showing footage of a disaster on the other side of the world. Since I was the one distributing sandwiches and drinks, I was only half watching and half listening. I was more concerned with getting everyone fed so we could be on our way as soon as the seat belt was repaired. While I ate my lunch and waited for what I considered to be my own little road-trip tragedy, I saw my first images of the Asian tsunami. CNN was covering the disaster, broadcasting from Phuket, Thailand.
"Wow. That looks really bad."
I felt for the people who were suffering as the result of the earthquake and tsunami, but with typical feelings of detachment. None of this was happening within the borders of the United States.
I'll be honest. The distance I felt from what I was seeing was both emotional and physical. I was much more concerned with how much time we would lose due to the interruption of the broken seat belt.
Plus, I had never heard of Phuket, Thailand. To my way of thinking, if a natural disaster wasn't affecting the United States, let alone the interstate highway between North Carolina and Florida, I didn't think it was anything we needed to be overly concerned about.
Just as we finished our lunch, a service technician appeared and said the magic words: "Okay, you're all set!"
It turned out that this stop had not been too inconvenient. And it was so much nicer to eat in a comfortable waiting room rather than a roadside rest stop.
"Wonderful! Let's get to Florida!"


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Compass Cycles is introducing the first-ever 11-speed-compatible René Herse cranks and chainrings. And the first-ever René Herse chainrings with ramps and pins. These are not just any ramps and pins: They're carefully engineered to shift as well as the best cranks from the big manufacturers. We are proud to offer this performance with useful chainring sizes – plus the beauty and light weight of the classic René Herse cranks.
The shifting performance of our new cranks is a bigger deal than it may sound at first, because developing chainrings at this level is a major undertaking. Our engineering team has spent almost 18 months on this project. We tested prototypes for thousands of miles (above) before settling on a final design. (Many readers have wondered how the Firefly's 11-speed drivetrain worked with the René Herse cranks, and why that simple question didn't get a simple answer…)
There are plenty of 'ramped-and-pinned' chainrings out there, because it's not hard to cut a few ramps into chainrings and rivet in some pins. But, the ramps and pins don't do much unless they are carefully aligned with the chain path. To work well, the chain has to hit the pin just right, in the middle of an outer link. Then it gets transported seamlessly to the big ring, and the ramp only acts as a cut-out to provide an easier path for the chain.
Another key element is to treat this as a dynamic system, spinning at 50-130 rpm. When we looked at other chainrings, we quickly discovered that this was the biggest difference between the best-shifting chainrings and those that offer only so-so performance. It became clear that the three big makers understand this, but everybody else seems to design their chainrings as a static system. Here is what 'static' means: When you put a chain half on the small and half on the big ring (above), it fits beautifully. But when you shift while pedaling, the teeth don't have time to snug in between the links of the chain (which is running at an angle during the shifts). As a result, the chain rides up on the chainring and the carefully-planned alignment of the chain path is compromised.
By comparison, the chain seems to fit a little less perfectly on the 'dynamic' chainrings from the big makers – until you are pedaling. Then you are surprised by the smooth shifts. We benchmarked Shimano's Ultegra cranks – widely known as the best-shifting in the business – for the performance that our 11-speed René Herse cranks had to match. Now we feel that we have achieved that goal, and so we are introducing the first 11-speed-compatible René Herse chainrings in a 46-30 combination. And of course, the excellent shifting performance of these rings works with 10- and 9-speed derailleurs, too.
While the upshifts get a lot of attention, the downshifts are just as important with 11-speed, because the distance between the rings is so small that the chain no longer can just be 'thrown' to the inside and then land on the inner ring, as it was with older systems. The new René Herse 11-speed chainrings feature special tooth profiles to facilitate downshifts. The chainrings also are machined specifically to reduce the gap between the rings, so the ultra-narrow 11-speed chains cannot get caught between the rings.
Instead of requiring you to buy completely new cranks, only the outer chainring is new. What this means is that older Compass-made René Herse cranks can be retrofitted. However, the 46-30 ring should be used with a 30-tooth inner ring, otherwise, the chain path doesn't work properly. The small chainrings remain unchanged, because they don't do anything during shifts, except release the chain upward. Because only the outer ring is new, this also means that our 46-30 tandem cranks (below) are 11-speed-compatible, too.
The production chainrings have just arrived, so we don't have photos yet, but rest assured that they match the beautiful finish of our other chainrings. (The photo of the ramped-and-pinned rings show unpolished prototypes.) In the future, we also plan to offer other popular chainring combinations with 11-speed compatibility.
Click here to order 11-speed cranksets or chainrings.
38 Responses to Compass 11-speed Chainrings
Max Sievers November 16, 2017 at 5:04 am #
Wow! Long awaited. My next bike will be equipped with those — of course. Thanks a lot to all involved.
Jan Heine, Editor, Bicycle Quarterly November 16, 2017 at 8:34 am #
That is a popular combination… 🙂
ORiordan November 16, 2017 at 6:07 am #
This looks like a really interesting product. I've wondered why Shimano didn't come up with "super compact" gearing for their latest Ultegra 8000 crankset as I'd have thought this would be in demand with the growth of "gravel" bikes.
A couple of questions:
– you mentioned you looked at "other" chainrings as well as the big 3. Do you mind saying which ones although I understand if you'd prefer not to!
– what cassette combinations did you test with? Did you look at some of the wider range cassettes being produced now, like the Ultegra 8000 11-32T and any observations about how different cassettes worked with the new Compass chainrings?
Jan Heine, Editor, Bicycle Quarterly November 16, 2017 at 8:41 am #
1. I'd rather not list names, but it's obvious that most smaller makers haven't spent a huge amount of engineering on their chainrings. If the big rings don't list for which small rings they are designed, you can assume that the ramps and pins are mostly cosmetic…
2. These days, the cassettes aren't a limiting factor any longer. All cassettes seems to work well with all chains. Apart from that the front of the drivetrain doesn't interact with the rear, so you can mix-and-match as you want. However, modern chainrings are very sensitive to the chain. We tested our rings with Campy chains, and they shift OK, but with the Shimano chain, they work far better. In summary, you can use the new 11-speed René Herse rings with any quality cassette, as long as you use the Shimano Ultegra chain. (Dura-Ace probably works, too, but we haven't tested it.) On my Firefly, the Ultegra chain shifts perfectly with a Campagnolo Chorus cassette…
mattotoole November 16, 2017 at 11:23 am #
Interesting about chains. I'm still running 9sp Ultegra with a triple. While I've found that all brands work fine, KMC have been the best for smooth shifts and quietness. Same with my mountain bikes, with 8 and 9 speed triples. It doesn't hurt that KMC are also the cheapest.
But as you noted, I'm sure 11sp is more finicky. As always, thanks for your analysis and explanation.
Jan Heine, Editor, Bicycle Quarterly November 16, 2017 at 12:14 pm #
11-speed really is way more finicky…
Conrad November 16, 2017 at 12:44 pm #
But to clarify: 11 speed chain must be used on 11 speed cassette, correct? And your Campy Chorus cassette is 11 speed?
Jan Heine, Editor, Bicycle Quarterly November 16, 2017 at 3:54 pm #
You can use these rings with a 10-speed drivetrain and 10-speed Ultegra chain, too. Yes, my Campy Chorus is 11-speed. We haven't tried every possible permutation, but generally, Ultegra chains and our new rings are a great match.
jeffguildblog November 16, 2017 at 6:50 am #
Are you also working on a 1x (narrow-wide tooth) ring?
Frank Toman November 16, 2017 at 7:39 pm #
That's my question as well! Best, Frank.
Jan Heine, Editor, Bicycle Quarterly November 16, 2017 at 9:25 pm #
We've been thinking about a thick-thin ring for the same application. I have been running a 1x combination on my cyclocross bike since the 1990s, but with an old-style set of guard rings that I made by cutting off the teeth off larger chainrings. Advantages in 'cross are that the chain doesn't come off even if you fall, and if it did, you don't have to line up the teeth with the chain to make sure the thicker teeth go into the outer links.
Bryan Willman November 16, 2017 at 8:52 am #
Marvelous. Ironically, you introduce these just as I have dropped enough weight to no longer desperately need them! Campy ought to pay you for fixing their lineup…
Jan Heine, Editor, Bicycle Quarterly November 16, 2017 at 8:56 am #
With a 12-tooth smallest cog, I find that a 46-30 is more than large enough. In fact, I don't think I've used the 12-tooth on either the Firefly or the Weigle yet…
Dr J November 16, 2017 at 9:58 am #
Awesome! Now the next step would be to move to outboard cups BSA bottom bracket and integrated spindle.
But on another note – you mentioned that only the outer chainring is new. Does it mean someone using "old" 30T ring with "new" 46T ring would end up with two chainrings of different teeth width? Does the new 11-speed ring have narrower teeth profile to match 11-speed chains or is it the same as older, 10-speed rings? If teeth profiles are the same – what makes the new rings 11-speed compatible?
Jan Heine, Editor, Bicycle Quarterly November 16, 2017 at 12:07 pm #
An integrated spindle requires a larger crank, so it doesn't work with the René Herse cranks. It's ideal for carbon cranks, which have to be bigger due to the lower strength of carbon, but an aluminum crank with integrated spindle will be heavier and/or weaker than one with a square-taper BB. (Except if you make it hollow.)
As to the tooth width, the big ring always has should have slightly narrower teeth, because the chain runs at an angle across it during shifts. This isn't the case with the small ring. An 11-speed chain runs fine on 10-speed rings – until you shift! (And even then, it usually runs fine. Many riders have used 10-speed rings from various makers, including ours, with 11-speed drivetrains.)
Dr J November 16, 2017 at 12:30 pm #
I understand. Moving to integrated spindle and outboard cups would be a dramatic redesign for sure. But I think you're wrong about weight. Herse cranks are very lightweight but SKF bottom brackets are very heavy. With integrated spindle you would have to add some weight to aluminum cranks but you would also save 200g on a very light bottom bracket. Overall, the complete weight for both systems would likely be very close, but I'm pretty sure that integrated spindle crankset won't be heavier (based on weight of cranks on my bike and data from your website).
Jan Heine, Editor, Bicycle Quarterly November 16, 2017 at 4:36 pm #
I can see the appeal of a René Herse carbon crank, with the small BCD and three-bolt attachment that gives so many chainring choices. Making a more beefy aluminum crank is less appealing – creating room to insert an oversized spindle would make the crank a lot heavier. I doubt there would be 200g savings on the bottom bracket, because even the (admittedly heavy) SKF weighs just 291 g. Even if we can match the weight of the current system, the question would be: What for? A system has to be a lot lighter to make up for the much smaller bearings that need replacing annually, and the lack of flexibility when it comes to fitting cranks to bikes with wider chainstays.
The integrated spindle may turn out to be a dead-end anyhow. As tires get wider, the clearance between crankarms and chainstays is becoming a bigger issue. Right now, 'road' cranks from the major manufacturers don't fit on many allroad and gravel bikes. Mountain cranks work, but their tread (Q factor) is too wide for efficient pedaling – at least for many riders. Being able to dial in the crank position by carefully selecting the BB spindle length is a big plus on these bikes.
For example, 'road' cranks don't fit on my Firefly, but a René Herse crank works great with a 116 mm BB. The tread is 6 mm wider than usual, but at 148 mm, it's actually the same as most modern 'road' cranks. The chainline moves 3 mm outward, but that matches the rear, since the bike uses 135 mm rear spacing. The narrower cranks not only improve pedaling efficiency, but also shifting performance. Fine-tuning the crank position is easy with square-taper BBs, but very hard with integrated BBs.
Ideally, the big makers would offer each crank with different spindle lengths, but good luck with that! Imagine the permutations: Different chainring combos, different lengths, and now different spindles. So what we'll see instead is probably a further increase in tread (Q factor)… unless the pro racers balk at this, in which case the big makers probably would introduce dedicated 'gravel' cranks. But once again, you'll get a 'one-size-fits-all' design, rather than being able to fine-tune things.
Bryan Willman November 16, 2017 at 10:27 am #
Yes, yet all of the cassettes I've bought in the last couple months are 11- something. Why? Some of them for a 1x drivetrain where they make a little more sense, but the "low range" ultegra setup is 34/50 x 11-32. Because 50×11 is something most people need every day???? (Yet somehow few complain about 42×11 as a high gear on a 1x…)
That said, 30-46 x 11-32 should work great, even if a 13-32 would make more sense…
Grego November 16, 2017 at 2:04 pm #
Yes, I want tall gearing every day. It's hilly here, and on my road bike I need a low gear like 36-34 to grind up the steeps; then I want to zoom downhill pedaling something like a 52-11. The FC-5800 mid-compact (52/36) crankset and an 11/34 cassette give me the gear extremes that I need. Before that I was using a triple crankset to get the range, because with the 50/34 cranksets, my legs spin out at way at too slow a speed.
Jan Heine, Editor, Bicycle Quarterly November 16, 2017 at 3:52 pm #
These days, many of us have found that tucking and reducing our air resistance by 30% or more is much faster than pedaling downhill, hence there is less need for ultra-large gears. Of course, if you enjoy pedaling on the downhills, rather than try to go faster, then you'll need larger gears. The down side, for me, is that the 52 is too large to use on the flats, while the 36 is too small. So I constantly shift on the front, which really breaks my rhythm.
ptt November 16, 2017 at 11:04 pm #
Jan, have you found a good way to "tuck" when riding in traffic? I live in a very hilly city, and need to pedal downhill to keep a decent speed when sharing the road with cars. The aero tuck takes my hands away from the brake levers. That doesn't feel safe.
Jan Heine, Editor, Bicycle Quarterly November 16, 2017 at 11:28 pm #
Good point – of course, I don't use the aero tuck in traffic. Seattle's speed limit on big streets is 35 mph (56 km/h), which corresponds to a 46-12 gear on my bike. But realistically, I only reach that speed when going down steep hills, where pedaling makes little difference. There, I am more concerned with braking, especially when I am riding a test bike with sub-optimal brakes… But I understand that many riders are stronger and/or use lower cadences, so we do offer bigger chainrings for our cranks – all the way to a 52. As we expand our offerings in 11-speed chainrings, we'll look at the combinations that are popular, and offer those in 11-speed.
Gert November 16, 2017 at 2:21 pm #
48 – 13 as high gear is maybe appart from some downhill stretches more than enough for me. But 13 as start is uncommon. But Miche and TA Podium cassettes offer a much greater variety and cogs are available separately so you do not have change a cassette every time the middle cogs are worn. So for a new 13-29 cassette. I have ordered extra 15 16 17 18 19 21 cogs.
Rick Thompson November 16, 2017 at 10:30 am #
How much difference would the ramp and pin make for 9 speed shifting? (Since I just received the non-ramp Herse crankset and have not installed it yet).
Jan Heine, Editor, Bicycle Quarterly November 16, 2017 at 12:14 pm #
It won't make a huge difference, if you use good technique when shifting. For example, we've found that 10-speed Di2 works great with our 'standard' René Herse cranks, because the motorized derailleur shifts with conviction, all the way. Bad shifts mostly happen when you don't push the derailleur all the way, and the chain scrapes along the big ring without 'catching.' This can happen with STI, since the huge swing of the lever is an unnatural motion for your wrist.
Rick Thompson November 16, 2017 at 12:29 pm #
Thank you. I will stick with the non-ramp, so I can keep the 26-44 x 11-34. That's plenty of top speed for me, and a walking speed low for loaded tours in the hills.
Conrad November 16, 2017 at 11:54 am #
Maybe we should be talking about what an optimized drivetrain looks like. I still dont see the point of anything over 8 cogs in the back. Above that, the chain gets skinnier, more fragile, more expensive, and less durable. 8 cogs can cover the range that anybody needs. If you can't find the gear you need on an 8 speed cassette, you are not going to find it on an 11 speed cassette. The wider that cassette gets, the worse your chainline is. What is the point, other than the old stuff being deemed obsolete by the big 3 so that you have to pay 100 dollars instead of 10 dollars for a chain? Dont even get me started on the 1X11. There is so much cross chaining in the smallest and largest cogs that it translates to measureable and significant friction losses in the drivetrain. Several top cyclocross pros dont use them for that reason. So far, the primary goal of the products offered by Compass is optimized performance, and you have bucked major industry trends in doing so. So I have to ask, why 11 speed? Is it because it truly works better, or because sensible drivetrain parts are obsolete at this point?
Jan Heine, Editor, Bicycle Quarterly November 16, 2017 at 4:05 pm #
I understand where you are coming from. I have ridden Paris-Brest-Paris three times with 5-speed rears – once on a tandem – and also the Raid Pyrénéen twice, and never felt lacking for gears. That said, for steep gravel roads, I do need smaller gears.
However, the bike industry has moved on. Unless we offer a complete 8-speed drivetrain, our parts need to work with current components. The more you ride, the less feasible it is to run NOS parts that are difficult to replace when they wear out. Our goal is to offer parts for bikes that are up-to-date in every way. That is why we also offer handlebars with 31.8 mm clamps.
Chainlines have got worse not because of 11-speed, but because today's cranks have moved further outward, and front and rear chainlines no longer match. For decades, the 'road' chainline was universally at 43.5 mm from the centerline of the bike. But when I measured a SRAM 1×11, the middle cog on the rear was 42.5 mm from the center, while the front chainring was 46 mm. The issue isn't so much friction losses (Frank Berto tried to measure that and concluded it was negligible), but wear and shifting performance. Replacing the White Industries crank on my Firefly with a narrower René Herse that matches the rear chainline has improved the shifting a lot…
Jacob Musha November 16, 2017 at 6:50 pm #
"Unless we offer a complete 8-speed drivetrain…"
Sounds like Compass's next project! I'll be first in line, as all my bikes are 7 or 8 speed.
Chains are still readily available and cassettes are easy (though only the low-end, heavier ones these days.) Plenty of shifters are out there and rear derailers are easy since Shimano RDs are compatible up to 10-speed. The only struggle is finding good front derailers, since the cages on new FDs are too narrow for the wider 8-speed chain. The choices are hunting down old parts or getting something new that's at the very bottom of the food chain.
marmottz27 November 17, 2017 at 4:35 am #
Industry moving on that's the problem. Getting 10 speed cassettes in certain cog combinations is starting to get difficult. Try finding a not fiendishly expensive square taper bottom bracket in ISO standard if you need a certain length. Etc…
Steve Palincsar November 17, 2017 at 4:35 am #
Certainly 8 can cover the range (so could 5, for that matter) but the steps between gears have to be larger than would be the case if there were more gears to cover that range. 8 and 9 speed cassettes are the same width, and as far as I've been able to tell over tens of thousands of miles there's no wear difference between them.
Conrad November 18, 2017 at 2:17 pm #
I feel like my 9 speed stuff wears out faster than the 8 speed stuff. Regardless, 10 and 11 speed is wider, creating a more asymmetric and weak rear wheel for gears you don't need. I think the optimum number of cogs is between 6 and 8.
Conrad November 17, 2017 at 9:36 am #
Jacob, my thoughts exactly. The front d. is the hardest to track down. There are a lot of old 10 speeds with the suntour cyclone group. That front derailleur is the best shifting I have ever used, gorgeous, and (not that it matters) lighter than a modern Campy derailleur. And it wasn't even Suntours top of the line offering.
Tony November 18, 2017 at 8:49 am #
+1 for an 8-9-10 mini group of hub, derailleurs, and cassettes. I mean, I'll bet you never thought you'd be selling so many tires or cranksets, or sourcing and importing custom tubing. Dream big!
Francisco November 19, 2017 at 3:13 am #
Of the alleged disadvantages of 11-speed chains only the high price is uncontroversial. A look at the specifications will show that 11-speed chains are actually stronger that 8 or 9 speed chainsm probably due to improved metallurgy. Regarding wear, I change my Campy 11s chains at twelve thousand kilometers but could keep them longer if the criterion was elongation.
Regarding 1-by systems I have tried it on one of my bikes and swithced back. The reason was not too much cross~chaining. With properly chosen ratios you spend most of the time in the middle of the cassette of a 1-by system. Poorly selected 2-by gearing on the other hand induces chronic cross-chaining (plus too frequent gear changes on the front).
ed b November 16, 2017 at 5:08 pm #
This is a very good decision to follow the ramps/pins of the big three. I recently went back to my Dura Ace 9000 rings and have not missed a shift. Not a one in thousands and thousands of miles. On PBP 2015 I used Rotor QXL rings 53/39 11 speed. I rarely ever had used the small ring but on the way back from Brest, I got tired a bit some hills demanded the small ring that on the way to Brest seemed less steep. LOL. I had to shift down many times and sometimes the chain would go between the two rings and it was very, very hard to get the chain out. Othertimes, it was jammed into the frame. The benefit was primarily to raise my temperature in 40F Tintineac night and thus, no complaints on my part. When I asked where the toilets were, they always escorted me. Pity must have been a factor. So, I think you made a great decision. Clean hands. Besides they are pretty.
Jan Heine, Editor, Bicycle Quarterly November 16, 2017 at 6:07 pm #
The Spanish brand you mention surprised us during our R&D, because their rings aren't as well-designed as we would have expected from a relatively big player. A friend has had the same issues as you.


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Audition: Illustrations & The Making Artbook (Import) (Korean)
About Audition: Illustrations & The Making Artbook (Import) (Korean)
This hardcover art book contains many unique and beautiful color spreads of the characters of Audition not seen in the individual volumes. From fashion cut-outs, to pictures of everyday life in Seoul, to draft sketches of each character, Ms. Chon has warmly invited all her fans to glimpse into her creative psyche via this art book.
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Art by Kye Young Chon.
- Publisher: DRAMAQUEEN
- Media: Art Books
- Genre: Comedy
- Age Rating: 13+
- Release Date: 6/20/2002
- Page Count: 236
- Dimensional Weight: 1.9


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About us
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Dear Parents/ Carers,
The end of the school year is always a whirlwind in school, you see if coming in the distance for months and suddenly the last few days whizz by and it is the final day of Summer Term and everyone is about to embark on a new adventure – a holiday or a move to a new school.
I have taught the current Year 6 pupils regularly over the years that they have been at Central Primary School and while I am sad to see them leave Central, I know that every single one of them has learnt, developed and grown as a person during their time with us. Our final celebrations with Year 6 in their leaving assembly and brunch are always wonderful ways to say goodbyes. This year is particularly poignant as we say goodbye to the last sibling of some family groups who have been regulars on the Central Primary playground for the last decade and longer.
As with every year this year we are saying goodbye to some of our beloved teachers. Mrs Grigorjevs, Ms Horbury, Miss Davies, Miss Taylor, Miss Lawrence, Miss Maclean, Ms Ahmed, Mrs Wilcox, Miss Moss, and Miss D'Souza are leaving Central this year.
Miss Moss leaves Central after working here for the past 10 years. Everyone who has had their child taught by Miss Moss will know that they have been very lucky. She is persistently kind with a beautiful warm manner with all children. There are few people who persist as a child's favourite teacher overtime as Miss Moss. Personally, I am losing a colleague who I value massively. From the day I started at Central Miss Moss has supported me to help grow and develop the school and I will be forever grateful. Thank you Miss Moss; we will miss you.
Miss D'Souza has always been a ball of energy and laughter. She never fails to raise a smile across the school and her wonderful personality has enriched the lives of everyone she has worked with. Many of your children will have had Miss D'Souza teach them in Nursery and she always helped our children start their Central journeys with such positivity. Thank you Miss D'Souza.
Mrs Wilcox will not be returning to Central following her maternity leave. Instead she has set up her own company working as a consultant for English. For those of you that have had children taught by Mrs Wilcox you will know that she is a phenomenal teacher of English. She makes learning to write a beautiful art-form. Mrs Wilcox is also an excellent teacher of lots of other subjects, but her classes will undoubtedly remember her PE lessons. We will miss you Mrs Wilcox.
Mrs Grigorjevs is another person who has inspired the children she has taught. Mrs Grigorjevs will be moving to Nottingham to take up her new job where she will be much nearer her family. Mrs Grigorjevs always raised the expectations pupils had of themselves and what they could achieve. One of my lasting memories of Miss Grigorjevs was when she taught the children how to share their thanks with each other, and this has endured with these children ever since. Thank you Mrs Grigorjevs.
Miss Taylor has bought so much to our school. She arrived as a student teacher in 2014 and never left. Since she arrived she has delivered spectacular performances across the school, taught the children to believe in themselves and inspired our pupils to explore their ideas creatively through a whole range of art forms. Miss Taylor has never been afraid of a challenge and has been a constant supporter of Central Primary in everything that we have explored over the years. Thank you Miss Taylor.
Miss Davies has a special affinity with pupils. She is able to help them realised their own potential. She is wonderfully patient and kind with them and she has been a wonderful teacher in Forest Class. What Miss Davies does exceptionally well is build the small-steps in learning that enable all pupils to learn really effectively. Thank you Miss Davies and good luck in Birmingham.
Ms Horbury has always had high expectations of everyone she has worked with. She always rose to the challenge of supporting pupils believe in themselves and worked with children to help them believe that they could do things that they initially found challenging. I know Ms Horbury's school will be very lucky to have her.
Miss Maclean comes to life as a teacher when teaching PE and her cheerleading club was a star attraction on the club rota in the summer term. Beloved by Pear Class, Miss Maclean will be missed and we hope she will come back to visit.
Ms Ahmed who has worked part time in our Nursery Class has grown and developed the support that we give children when they start at Central. Her passion for Makaton and pupils signing will be a lasting memory for all the staff and pupils who have worked with her. We will miss you Ms Ahmed and we will miss you delicious cakes.
Miss Lawrence only joined Central this year, but we are very grateful for all her work this year in Year 5 and Year 2. Excitingly, Miss Lawrence is going to be starting her teacher training in September, so we wish her the best of luck.
It is always hard to capture in goodbyes the impact all of the staff have had on the whole school. Central Primary would not be what it is today without the contributions of each of these individuals.
For those of you leaving Central, staff, pupil or parent/ carer, this year, thank you for being part of our community. Please don't be a stranger; we would love to hear how you are getting on in the future.
For those of your coming back in September. Have a wonderful summer and I look forward to seeing you on Wednesday 4th September.
Dr John Mynott


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IMPHAL, Feb 3: Taking serious note of huge NPA (non-performing assets), accumulated due to non-re-paying of loans, State Bank of India has taken up drastic steps like serving of legal notices to borrowers, guarantors and concerned DDOs, filing of suits, seizure of car/auto/tractor etc.
Around 18 seized autos were sold through auction on January 28.
The bank has also served SARFEASI notices for taking possession of the house constructed out of the bank finance in addition to withdrawing ATM facility from the deposit account of the defaulting borrowers.
The bank has applied to the court of law for attachment of salary, said a release.
It further mentioned that the bank has recruited recovery agents who are regularly meeting all the defaulting borrowers.
The bank has also sought the help of State Government machineries for recovery of bad loans.
(Courtesy: The Sangai Express)


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