Solubility: sparingly sol water; sol dil acid, aq CuII; highly sol THF, alcohols, etc.
Handling, Storage, and Precautions: due care should be taken in the synthetic step using hydrazoic acid. N,S-Dimethyl-S-phenylsulfoximine is apparently of low toxicity. The compound, which is stable to acids and bases, as well as to most oxidizing and reducing conditions, maintains chemical and enantiopurity on long term storage.
1. Johnson, C. R. Aldrichim. Acta 1985, 18, 2.
2. Johnson, C. R.; Kirchhoff, R. A. JACS 1979, 101, 3602.
3. Johnson, C. R.; Zeller, J. R. T 1984, 40, 1225.
4. Whitehead, J. K.; Bentley, H. R. JCS 1952, 1572.
5. Johnson, C. R.; Haake, M.; Schroeck, C. W. JACS 1970, 92, 6594.
6. Fusco, R.; Tenconi, F. Chim. Ind. (Milan) 1965, 47, 61 (CA 1965, 62, 10 357h).
7. Johnson, C. R.; Schroeck, C. W.; Shanklin, J. R. JACS 1973, 95, 7424.
8. Johnson, C. R.; Stark, C. J. JOC 1982, 47, 1193.
9. Johnson, C. R.; Shanklin, J. R.; Kirchhoff, R. A. JACS 1973, 95, 6462.
10. Ansell, M. F.; Mason, J. S.; Caton, M. P. L. JCS(PI) 1984, 1061.
11. Bundy, G. L. TL 1975, 1957.
12. Johnson, C. R.; Meanwell, N. A. JACS 1981, 103, 7667.
13. Johnson, C. R.; Barbachyn, M. R. JACS 1982, 104, 4290. (b) Barbachyn, M. R.; Johnson, C. R.; Glick, M. D. JOC 1984, 49, 2726.
14. Johnson, C. R.; Barbachyn, M. R. JACS 1984, 106, 2459.