Of course, they were also sure to make time for some chatting. From this, we learned the following: Madonna thinks her music is rebellious, but her lifestyle is not. She went as far as to call herself a "Julie Andrews" when she gets home. She doesn't drink, smoke, or party. She's also been excommunicated from the Vatican on multiple occasions, and leaned in to kiss Michael Jackson. The lattermost fact isn't one that's well known, she says, because she's never been given the chance to talk about it.
The segment also features what James can only call a "first" in terms of passenger seat dancing (just watch, you'll know what we mean) and a seriously impressive acoustic rendition of "Don't Cry For Me, Argentina." She even taught James how to hold that famous Evita pose — but he knew all the words by heart already.