# 苯酚

## 维基百科，自由的百科全书 IUPAC名
Hydroxybenzene

CAS号 108-95-2 PubChem 996
ChemSpider 971
SMILES
InChI
ChEBI 15882
RTECS SJ3325000
DrugBank DB03255
KEGG D06536

pKa 9.95

NFPA 704 2
3
0
COR

## 结构 ## 化学性质

${\rm {PhOH+NaOH\rightarrow PhONa+H_{2}O\,))$ ${\rm {\ PhO^{-}+CO_{2}+H_{2}O\rightarrow PhOH+HCO_{3}^{-)))$ ${\rm {\ 6PhOH+FeCl_{3}\rightarrow H_{3}[Fe(OPh)_{6}]))$ (紫色) ${\rm {\ +3HCl))$ • 苯环上的亲电取代：苯酚由于结构中有苯环，可以在环上发生类似苯的亲电取代反应，如硝化、卤代等： • 酚羟基上的取代：酚羟基上的氢原子可以被含碳基团取代，生成 ## 制备

$\mathrm {C_{6}H_{5}SO_{3}Na\ +\ 2NaOH\longrightarrow \ C_{6}H_{5}ONa\ +\ Na_{2}SO_{3}\ +\ H_{2}O}$ ${\rm {\ C_{6}H_{6}+H_{2}C\!=\!CHCH_{3}\rightarrow C_{6}H_{5}CH(CH_{3})_{2)))$ ${\rm {\ C_{6}H_{5}CH(CH_{3})_{2}+O_{2}\rightarrow C_{6}H_{5}OH+CH_{3}COCH_{3)))$ 2007年吉林大学化学学院的冯守华等人在 Org. Lett. 期刊上发表文章称，他们用碳酸氢钠和铁粉在仿早期地球环境的条件下进行水热合成（水，200℃，1.9GPa），在产物中得到了产率为0.8%的苯酚。 ## 注释

1. ^ Ge Tian, Hongming Yuan, Ying Mu, Chao He, and Shouhua Feng. Hydrothermal Reactions from Sodium Hydrogen Carbonate to Phenol. Org. Lett. 2007, 9 (10): 2019–2021. doi:10.1021/ol070597o.
2. ^ Shouhua Feng, Ge Tian, Hongming Yuan, Ying Mu & Chao He. Supporting Information for Hydrothermal Reactions from Sodium Hydrogen Carbonate to Phenol (PDF). [2009-08-15]. （原始内容 (PDF)存档于2007-12-15）.

## 参考文献

• 邢其毅等．基础有机化学 第二版．§17.1,3-8,13．北京：高等教育出版社，1994年．ISBN 7-04-004607-5
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