Pali Dome, located north and northeast of Mount Cayley, is an eroded volcano in the central Mount Cayley volcanic field. Like Cauldron Dome, it consists of two geological units. Pail Dome East is composed of a mass of andesite lava flows and small amounts of pyroclastic material. It lies on the eastern portion of the Powder Mountain Icefield. Much of the lava flows form gentle topography at high elevations but terminate in finely jointed vertical cliffs at low elevations. The first volcanic activity likely occurred about 25,000 years ago, but it could also be significantly older. The most recent volcanic activity produced a series of lava flows that were erupted when the vent area was not covered by glacial ice. However, the flows show evidence of interaction with glacial ice in their lower units. This indicates that the lavas were erupted about 10,000 years ago during the waning stages of the Fraser Glaciation. The ice-marginal lava flows reach thicknesses of up to . Pali Dome West consists of at least three andesite lava flows and small amounts of pyroclastic material; its vent is presently buried under glacial ice. At least three eruptions have occurred at Pali Dome East. The age of the first volcanic eruption is unknown, but it could have occurred in the last 10,000 years. The second eruption produced a lava flow that was erupted when the vent area was not buried under glacial ice. However, the flow does show evidence of interaction with glacial ice at its lower unit. This indicates that the lavas were erupted during the waning stages of the Fraser Glaciation. The third and most recent eruption produced another lava flow that was largely erupted above glacial ice, but was probably constrained on its northern margin by a small glacier. Unlike the lava flow that was erupted during the second eruption, this lava flow was not impounded by glacial ice at its lower unit. This suggests that it erupted less than 10,000 years ago when the regional Fraser Glaciation retreated.