Pica Peak is a summit located in the Methow Mountains, a subset of the North Cascades, on the shared border between Okanogan County and Chelan County in Washington state. Pica Peak is situated southeast of Washington Pass, within the Okanogan-Wenatchee National Forest. The nearest higher neighbor is Copper Benchmark, to the southeast, and Blue Lake Peak is set to the west-northwest. Although modest in prominence, relief is significant as the peak rises 2,000 feet above Early Winters Basin in only . Precipitation runoff on the north side of the mountain drains to the Methow River via Early Winters Creek, whereas the south side of the mountain drain into tributaries of the Stehekin River.