The Pilot Knob volcanic complex consists of four small, rounded hills (including Pilot Knob proper) forming the volcano's core area in an area two miles in diameter. The hills are composed of trap rock which is an erosion-resistant, fine-grained mafic volcanic rock. The complex rises above a circular lowland drained by Cottonmouth Creek and is underlain chiefly by volcanic ash and other pyroclastic debris. Several smaller bodies of trap rock occur in the volcanic ash. A topographic rim surrounding the Cottonmouth Creek lowland to the north is formed by sedimentary rock, mainly lithified beach sediments composed of shell fragments and reworked volcanic ash that accumulated in the shallow waters around the volcano.