Following Cipollini's abandonment of the 1994 Tour de France, Poli won the Montpellier to Carpentras stage (the 15th) which featured an ascent of Mont Ventoux. Poli calculated that if he broke away from the peloton by a sufficient margin on the flat run to the base of the climb of the Mont Ventoux, he would reach the summit in front in spite of his relatively poor climbing speed due to his heavy 197 cm frame. In the event, his gap of some 20 minutes was nearly closed, but he crested the climb in front and was not caught by the chasing pack on the run down to the finish of the stage in Carpentras. In that Tour, Poli won the Combativity award.