when did earth's atmosphere change due to living organisms
around 2.45 billion years ago
title: Atmosphere of Earth text: temperature record of Earth – with the exception of one cold glacial phase about 2.4 billion years ago. In the late Archean Eon an oxygen-containing atmosphere began to develop, apparently produced by photosynthesizing cyanobacteria (see Great Oxygenation Event), which have been found as stromatolite fossils from 2.7 billion years ago. The early basic carbon isotopy (isotope ratio proportions) strongly suggests conditions similar to the current, and that the fundamental features of the carbon cycle became established as early as 4 billion years ago. Ancient sediments in the Gabon dating from between about 2,150 and 2,080 million years ago provide a title: History of Earth text: it could be common in the universe." Photosynthetic organisms appeared between 3.2 and 2.4 billion years ago and began enriching the atmosphere with oxygen. Life remained mostly small and microscopic until about 580 million years ago, when complex multicellular life arose, developed over time, and culminated in the Cambrian Explosion about 541 million years ago. This sudden diversification of life forms produced most of the major phyla known today, and divided the Proterozoic Eon from the Cambrian Period of the Paleozoic Era. It is estimated that 99 percent of all species that ever lived on Earth, over five billion, have title: Carbon dioxide in Earth's atmosphere text: carbonate sediments. The production of free oxygen by cyanobacterial photosynthesis eventually led to the oxygen catastrophe that ended Earth's second atmosphere and brought about the Earth's third atmosphere (the modern atmosphere) 2.4 billion years before the present. Carbon dioxide concentrations dropped from 4,000 parts per million during the Cambrian period about 500 million years ago to as low as 180 parts per million during the Quaternary glaciation of the last two million years. On long timescales, atmospheric concentration is determined by the balance among geochemical processes including organic carbon burial in sediments, silicate rock weathering, and volcanism. The net effect title: Atmosphere of Earth text: record of Earth's dynamic oxygenation evolution. These fluctuations in oxygenation were likely driven by the Lomagundi carbon isotope excursion. The constant re-arrangement of continents by plate tectonics influences the long-term evolution of the atmosphere by transferring carbon dioxide to and from large continental carbonate stores. Free oxygen did not exist in the atmosphere until about 2.4 billion years ago during the Great Oxygenation Event and its appearance is indicated by the end of the banded iron formations. Before this time, any oxygen produced by photosynthesis was consumed by oxidation of reduced materials, notably iron. Molecules of free oxygen did not title: Atmosphere of Earth text: start to accumulate in the atmosphere until the rate of production of oxygen began to exceed the availability of reducing materials that removed oxygen. This point signifies a shift from a reducing atmosphere to an oxidizing atmosphere. O showed major variations until reaching a steady state of more than 15% by the end of the Precambrian. The following time span from 541 million years ago to the present day is the Phanerozoic Eon, during the earliest period of which, the Cambrian, oxygen-requiring metazoan life forms began to appear. The amount of oxygen in the atmosphere has fluctuated over the last