BUG: Replacing NaNs with a Series object based on boolean indexing does not replace NaNs
- [x] I have checked that this issue has not already been reported.

- [x] I have confirmed this bug exists on the latest version of pandas.

- [ ] (optional) I have confirmed this bug exists on the master branch of pandas.

---

**Note**: Please read [this guide](https://matthewrocklin.com/blog/work/2018/02/28/minimal-bug-reports) detailing how to provide the necessary information for us to reproduce your bug.

#### Code Sample, a copy-pastable example

```python
diamond_data.isna().sum()

carat        0
cut          0
color        0
clarity      0
depth      691
table        0
x            0
y            0
z            0
price        0
dtype: int64

# Generate random numbers for filling nans

ideal_data = pd.Series(np.random.randint(low=float(diamond_data[diamond_data.cut == "Ideal"]["depth"].min()),
                                         high=float(diamond_data[diamond_data.cut == "Ideal"]["depth"].max()),
                                         size=270)).astype("float")

prem_data = pd.Series(np.random.randint(low=float(diamond_data[diamond_data.cut == "Premium"]["depth"].min()),
                                        high=float(diamond_data[diamond_data.cut == "Premium"]["depth"].max()),
                                        size=192)).astype("float")

vgood_data = pd.Series(np.random.randint(low=float(diamond_data[diamond_data.cut == "Very Good"]["depth"].min()),
                                        high=float(diamond_data[diamond_data.cut == "Very Good"]["depth"].max()),
                                        size=152)).astype("float")

good_data = pd.Series(np.random.randint(low=float(diamond_data[diamond_data.cut == "Good"]["depth"].min()),
                                        high=float(diamond_data[diamond_data.cut == "Good"]["depth"].max()),
                                        size=59)).astype("float")

fair_data = pd.Series(np.random.randint(low=float(diamond_data[diamond_data.cut == "Fair"]["depth"].min()),
                                        high=float(diamond_data[diamond_data.cut == "Fair"]["depth"].max()),
                                        size=24)).astype("float")

# Fill it up
diamond_data.loc[(diamond_data.cut == "Ideal") & (diamond_data.depth.isna()), "depth"] = ideal_data
diamond_data.loc[(diamond_data.cut == "Premium") & (diamond_data.depth.isna()), "depth"] = prem_data
diamond_data.loc[(diamond_data.cut == "Very Good") & (diamond_data.depth.isna()), "depth"] = vgood_data
diamond_data.loc[(diamond_data.cut == "Good") & (diamond_data.depth.isna()), "depth"] = good_data
diamond_data.loc[(diamond_data.cut == "Fair") & (diamond_data.depth.isna()), "depth"] = fair_data
```

#### Problem description
When trying to replace some of the nan values that are spread out randomly on the dataset I'm working on, as shown above through `.loc` indexing, I should get all the values in the`depth` column filled up. Instead, nothing is filled up and running `isna().sum()` shows presence of same missing values.

#### Expected Output
Expected output should be 0 na values for the column `depth`.

#### Output of ``pd.show_versions()``

<details>


INSTALLED VERSIONS
------------------
commit           : 9d598a5e1eee26df95b3910e3f2934890d062caa
python           : 3.7.9.final.0
python-bits      : 64
OS               : Linux
OS-release       : 5.4.0-65-generic
Version          : #73-Ubuntu SMP Mon Jan 18 17:25:17 UTC 2021
machine          : x86_64
processor        : x86_64
byteorder        : little
LC_ALL           : None
LANG             : en_GB.UTF-8
LOCALE           : en_GB.UTF-8

pandas           : 1.2.1
numpy            : 1.19.2
pytz             : 2021.1
dateutil         : 2.8.1
pip              : 20.3.3
setuptools       : 52.0.0.post20210125
Cython           : None
pytest           : 6.2.2
hypothesis       : None
sphinx           : 3.2.1
blosc            : None
feather          : None
xlsxwriter       : 1.3.7
lxml.etree       : 4.6.2
html5lib         : None
pymysql          : None
psycopg2         : None
jinja2           : 2.11.3
IPython          : 7.20.0
pandas_datareader: None
bs4              : 4.9.3
bottleneck       : 1.3.2
fsspec           : 0.8.3
fastparquet      : None
gcsfs            : None
matplotlib       : 3.3.2
numexpr          : 2.7.2
odfpy            : None
openpyxl         : 3.0.6
pandas_gbq       : None
pyarrow          : None
pyxlsb           : None
s3fs             : None
scipy            : 1.6.0
sqlalchemy       : None
tables           : None
tabulate         : 0.8.7
xarray           : None
xlrd             : 2.0.1
xlwt             : None
numba            : 0.51.2


</details>
