DataFrame.set_value() raise Exception
In [97]:df=pd.DataFrame({'x':['A','B','C'],'y':['0','0','0']})

```
x   y
```

0    A   0
1    B   0
2    C   0

In [99]:df.set_value(index=df.x.str.startswith('A'),col='y',value='1')

---

TypeError                                 Traceback (most recent call last)
<ipython-input-99-08195440f2b8> in <module>()
----> 1 df.set_value(index=df.x.str.startswith('A'),col='y',value='1')

D:\winpython\WinPython-32bit-2.7.6.4\python-2.7.6\lib\site-packages\pandas\core\frame.pyc in set_value(self, index, col, value, takeable)
   1572             series = self._get_item_cache(col)
   1573             engine = self.index._engine
-> 1574             engine.set_value(series.values, index, value)
   1575             return self
   1576         except KeyError:

D:\winpython\WinPython-32bit-2.7.6.4\python-2.7.6\lib\site-packages\pandas\index.pyd in pandas.index.IndexEngine.set_value (pandas\index.c:3231)()

D:\winpython\WinPython-32bit-2.7.6.4\python-2.7.6\lib\site-packages\pandas\index.pyd in pandas.index.IndexEngine.set_value (pandas\index.c:3064)()

D:\winpython\WinPython-32bit-2.7.6.4\python-2.7.6\lib\site-packages\pandas\index.pyd in pandas.index.IndexEngine.get_loc (pandas\index.c:3324)()

TypeError: 

In [100]:df.set_value(index=df.x.str.startswith('A'),col='z',value='1')

```
x   y   z
```

0    A   0   1
1    B   0   NaN
2    C   0   NaN

why the parameter 'col' must set as a new column will be ok?
## INSTALLED VERSIONS

commit: None
python: 2.7.6.final.0
python-bits: 32
OS: Windows
OS-release: 7
machine: AMD64
processor: Intel64 Family 6 Model 42 Stepping 7, GenuineIntel
byteorder: little
LC_ALL: None
LANG: None

pandas: 0.14.0
nose: 1.3.1
Cython: 0.20.1
numpy: 1.8.1
scipy: 0.13.3
statsmodels: 0.5.0
IPython: 2.0.0
sphinx: 1.2.2
patsy: 0.2.1
scikits.timeseries: None
dateutil: 2.2
pytz: 2013.9
bottleneck: None
tables: 3.1.1
numexpr: 2.3.1
matplotlib: 1.3.1
openpyxl: 1.6.1
xlrd: 0.9.3
xlwt: 0.7.5
xlsxwriter: None
lxml: 3.3.5
bs4: 4.3.2
html5lib: None
bq: None
apiclient: None
rpy2: None
sqlalchemy: 0.9.4
pymysql: None
psycopg2: None
