BUG: `round()` for 5e5 ms should be `ceil()`
- [x] I have checked that this issue has not already been reported.

- [x] I have confirmed this bug exists on the latest version of pandas.

- [ ] (optional) I have confirmed this bug exists on the master branch of pandas.

---

#### Code Sample, a copy-pastable example

```python
import pandas as pd
test_time = pd.to_datetime('2020-06-09 00:01:14.500000')
print(pd.Series(test_time).dt.round("S"))
```

#### Problem description

If the ms is 5e5, the method of round is floor, but it should be ceil.

#### Expected Output
```
2020-06-09 00:01:15
```

#### Output of ``pd.show_versions()``

<details>

INSTALLED VERSIONS
------------------
commit           : 2cb96529396d93b46abab7bbc73a208e708c642e
python           : 3.8.8.final.0
python-bits      : 64
OS               : Linux
OS-release       : 3.10.0-957.el7.x86_64
Version          : #1 SMP Thu Nov 8 23:39:32 UTC 2018
machine          : x86_64
processor        : x86_64
byteorder        : little
LC_ALL           : None
LANG             : en_US.UTF-8
LOCALE           : en_US.UTF-8

pandas           : 1.2.4
numpy            : 1.20.2
pytz             : 2021.1
dateutil         : 2.8.1
pip              : 21.1.1
setuptools       : 49.6.0.post20210108
Cython           : None
pytest           : 6.2.4
hypothesis       : None
sphinx           : None
blosc            : None
feather          : None
xlsxwriter       : None
lxml.etree       : None
html5lib         : None
pymysql          : None
psycopg2         : None
jinja2           : 2.11.3
IPython          : 7.23.1
pandas_datareader: None
bs4              : None
bottleneck       : None
fsspec           : 2021.04.0
fastparquet      : None
gcsfs            : None
matplotlib       : 3.3.4
numexpr          : 2.7.3
odfpy            : None
openpyxl         : None
pandas_gbq       : None
pyarrow          : None
pyxlsb           : None
s3fs             : None
scipy            : 1.6.3
sqlalchemy       : None
tables           : 3.6.1
tabulate         : None
xarray           : 0.18.0
xlrd             : None
xlwt             : None
numba            : None
</details>
