used to express the number of atoms bound together, rather than a count of molecules. Thus, common chemical conventions apply to the definition of the constituent particles of a substance, in other cases exact definitions may be specified. The mass of a substance is equal to its relative atomic (or molecular) mass multiplied by the molar mass constant, which is almost exactly 1 g/mol. Molar mass The molar mass of a substance is the ratio of the mass of a sample of that substance to its amount of substance. The amount of substance is given as the number of moles in the sample. For most practical purposes, the numerical value of the molar mass expressed with the unit gram per mole is the same as that of the mean mass of one molecule of the substance expressed with the unit dalton. For example, the molar mass of water is 18.015 g/mol. Other methods include the use of the molar volume or the measurement of electric charge. The number of moles of a substance in a sample is obtained by dividing the mass of the sample by the molar mass of the compound. For example, 100 g of water is about 5.551 mol of water. The molar mass of a substance depends not only on its molecular formula, but also on the distribution of isotopes of each chemical element present in it. For example, the molar mass of calcium-40 is , whereas the molar mass of calcium-42 is , and of calcium with the normal isotopic mix is . Molar concentration The molar concentration, also called molarity, of a solution of some substance is the number of moles per unit of volume of the final solution. In the SI its standard unit is mol/m3, although more practical units, such as mole per litre (mol/L) are used. Molar fraction The molar fraction or mole fraction of a substance in a mixture (such as a solution) is the number of moles of the compound in one sample of the mixture, divided by the total number of moles of all components. For example, if 20 g of is dissolved in 100 g of water, the amounts of the two substances in the solution will be (20 g)/(58.443 g/mol) = 0.34221 mol and (100 g)/(18.015 g/mol) = 5.5509 mol, respectively; and the molar fraction of will be . In a mixture of gases, the partial