has validated the hardness predictions; this has been attributed to the difficulty in synthesis and the instability of C3N4. Carbon nitride is only stable at a pressure that is higher than that of the graphite-to-diamond transformation. The synthesis conditions would require extremely high pressures because carbon is four- and sixfold coordinated. In addition, C3N4 would pose problems of carbide formation if they were to be used to machine ferrous metals. Although publications have reported preparation of C3N4 at lower pressures than stated, synthetic C3N4 was not proved superhard. Boron carbon nitride The similar atomic sizes of boron, carbon and nitrogen, as well as the similar structures of carbon and boron nitride polymorphs, suggest that it might be possible to synthesize diamond-like phase containing all three elements. It is also possible to make compounds containing B-C-O, B-O-N, or B-C-O-N under high pressure, but their synthesis would expect to require a complex chemistry and in addition, their elastic properties would be inferior to that of diamond. Beginning in 1990, a great interest has been put in studying the possibility to synthesize dense B-C-N phases. They are expected to be thermally and chemically more stable than diamond, and harder than c-BN, and would therefore be excellent materials for high speed cutting and polishing of ferrous alloys. These characteristic properties are attributed to the diamond-like structure combined with the sp3 σ-bonds among carbon and the heteroatoms. BCxNy thin films were synthesized by chemical vapor deposition in 1972. However, data on the attempted synthesis of B-C-N dense phases reported by different authors have been contradictory. It is unclear whether the synthesis products are diamond-like solid solutions between carbon and boron nitride or just mechanical mixtures of highly dispersed diamond and c-BN. In 2001, a diamond-like-structured c-BC2N was synthesized at pressures >18 GPa and temperatures >2,200 K by a direct solid-state phase transition of graphite-like (BN)0.48C0.52. The reported Vickers and Knoop hardnesses were intermediate between diamond and c-BN, making the new phase the second hardest known material. Ternary B–C–N phases can also be made using shock-compression synthesis. It was further suggested to extend the B–C–N system to quaternary compounds with silicon included. Metal borides Unlike carbon-based systems, metal borides can be easily synthesized in large quantities under ambient conditions, an important technological advantage. Most metal borides are hard; however, a few stand out among them for their particularly high hardnesses (for example, WB4, RuB2, OsB2 and