Hexanitrobenzene, also known as HNB, is a high-density explosive compound with chemical formula , obtained by oxidizing the amine group of pentanitroaniline with hydrogen peroxide in sulfuric acid. Properties The stable conformation of this molecule has the nitro groups rotated out of the plane of the central benzene ring. The molecule adopts a propeller-like conformation in which the nitro groups are rotated about 53° from planar. HNB has the undesirable property of being moderately sensitive to light and, therefore, hard to utilize safely. As of 2021, it is not used in any production explosives applications, though it is used as a precursor chemical in one method of production of TATB, another explosive. HNB was experimentally used as a gas source for explosively pumped gas dynamic laser. In this application, HNB and tetranitromethane are preferred to more conventional explosives because the explosion products and are a simple enough mixture to simulate gas dynamic processes and quite similar to conventional gas dynamic laser medium. The water and hydrogen products of many other explosives could interfere with vibrational states of in this type of laser. Preparation During World War II, a method of synthesis of hexanitrobenzene was suggested in Germany, and the product was supposed to be manufactured on a semi-industrial scale according to the following scheme: (partial reduction) (nitration) (oxidation) Complete nitration of benzene is practically impossible because the nitro groups are deactivating groups for further nitration. Additional properties Chapman-Jouget detonation pressure: 43 GPa Crystal Density: 2.01 See also ONC Tetryl TNT RE factor Notes References Heats of Formation and Chemical Compositions The synthesis and characterisation of halogen and nitro phenyl azide derivatives as highly energetic materials., PhD Thesis, Adam, D; 2001 Nitrobenzenes Explosive chemicals