mine materials during the early stages of a project to determine the potential for AMD. The geochemical assessment aims to map the distribution and variability of key geochemical parameters, acid generating and element leaching characteristics. The assessment may include: Sampling; Static geochemical testwork (e.g. acid-base accounting, sulfur speciation); Kinetic geochemical testwork - Conducting oxygen consumption tests, such as the OxCon, to quantify acidity generation rates Modelling of oxidation, pollutant generation and release; and Modelling of material composition. Treatment Oversight In the United Kingdom, many discharges from abandoned mines are exempt from regulatory control. In such cases the Environment Agency and Natural Resources Wales working with partners such as the Coal Authority have provided some innovative solutions, including constructed wetland solutions such as on the River Pelenna in the valley of the River Afan near Port Talbot and the constructed wetland next to the River Neath at Ynysarwed. Although abandoned underground mines produce most of the acid mine drainage, some recently mined and reclaimed surface mines have produced ARD and have degraded local ground-water and surface-water resources. Acidic water produced at active mines must be neutralized to achieve pH 6–9 before discharge from a mine site to a stream is permitted. In Canada, work to reduce the effects of acid mine drainage is concentrated under the Mine Environment Neutral Drainage (MEND) program. Total liability from acid rock drainage is estimated to be between $2 billion and C$5 billion. Over a period of eight years, MEND claims to have reduced ARD liability by up to C$400 million, from an investment of C$17.5 million. Methods Lime neutralization By far, the most commonly used commercial process for treating acid mine drainage is lime (CaO) precipitation in a high-density sludge (HDS) process. In this application, a slurry of lime is dispersed into a tank containing acid mine drainage and recycled sludge to increase water pH to about 9. At this pH, most toxic metals become insoluble and precipitate, aided by the presence of recycled sludge. Optionally, air may be introduced in this tank to oxidize iron and manganese and assist in their precipitation. The resulting slurry is directed to a sludge-settling vessel, such as a clarifier. In that vessel, clean water will overflow for release, whereas settled metal precipitates (sludge) will be recycled to the acid mine drainage treatment tank, with a sludge-wasting side stream. A number of variations of this process exist, as dictated