The atmosphere of Titan is the dense layer of gases surrounding Titan, the largest moon of Saturn. It is the only thick atmosphere of a natural satellite in the Solar System. Titan's lower atmosphere is primarily composed of nitrogen (94.2%), methane (5.65%), and hydrogen (0.099%). There are trace amounts of other hydrocarbons, such as ethane, diacetylene, methylacetylene, acetylene, propane, PAHs and of other gases, such as cyanoacetylene, hydrogen cyanide, carbon dioxide, carbon monoxide, cyanogen, acetonitrile, argon and helium. The isotopic study of nitrogen isotopes ratio also suggest acetonitrile may be present in quantities exceeding hydrogen cyanide and cyanoacetylene. The surface pressure is about 50% higher than on Earth at 1.5 bars (147 kPa) which is near the triple point of methane and allows there to be gaseous methane in the atmosphere and liquid methane on the surface. The orange color as seen from space is produced by other more complex chemicals in small quantities, possibly tholins, tar-like organic precipitates. Observational history The presence of a significant atmosphere was first suspected by Spanish astronomer Josep Comas i Solà, who observed distinct limb darkening on Titan in 1903 from the Fabra Observatory in Barcelona, Catalonia. This observation was confirmed by Dutch astronomer Gerard P. Kuiper in 1944 using a spectroscopic technique that yielded an estimate of an atmospheric partial pressure of methane of the order of 100 millibars (10 kPa). Subsequent observations in the 1970s showed that Kuiper's figures had been significant underestimates; methane abundances in Titan's atmosphere were ten times higher, and the surface pressure was at least double what he had predicted. The high surface pressure meant that methane could only form a small fraction of Titan's atmosphere. In 1980, Voyager 1 made the first detailed observations of Titan's atmosphere, revealing that its surface pressure was higher than Earth's, at 1.5 bars (about 1.48 times that of Earth's). The joint NASA/ESA Cassini-Huygens mission provided a wealth of information about Titan, and the Saturn system in general, since entering orbit on July 1, 2004. It was determined that Titan's atmospheric isotopic abundances were evidence that the abundant nitrogen in the atmosphere came from materials in the Oort cloud, associated with comets, and not from the materials that formed Saturn in earlier times. It was determined that complex organic chemicals could arise on Titan, including polycyclic aromatic hydrocarbons, propylene, and methane. The Dragonfly mission by NASA is planning to land a large