releases electrons by thermionic emission. The ionization method of creating cathode rays used in Crookes tubes is today only used in a few specialized gas discharge tubes such as thyratrons. The technology of manipulating electron beams pioneered in Crookes tubes was applied practically in the design of vacuum tubes, and particularly in the invention of the cathode ray tube by Ferdinand Braun in 1897 and is now used in sophisticated processes such as electron beam lithography. Discovery of X-rays When the voltage applied to a Crookes tube is high enough, around 5,000 volts or greater, it can accelerate the electrons to a high enough velocity to create X-rays when they hit the anode or the glass wall of the tube. The fast electrons emit X-rays when their path is bent sharply as they pass near the high electric charge of an atom's nucleus, a process called bremsstrahlung, or they knock an atom's inner electrons into a higher energy level, and these in turn emit X-rays as they return to their former energy level, a process called X-ray fluorescence. Many early Crookes tubes undoubtedly generated X-rays, because early researchers such as Ivan Pulyui had noticed that they could make foggy marks on nearby unexposed photographic plates. On November 8, 1895, Wilhelm Röntgen was operating a Crookes tube covered with black cardboard when he noticed that a nearby fluorescent screen glowed faintly. He realized that some unknown invisible rays from the tube were able to pass through the cardboard and make the screen fluoresce. He found that they could pass through books and papers on his desk. Röntgen began to investigate the rays full-time, and on December 28, 1895, published the first scientific research paper on X-rays. Röntgen was awarded the first Nobel Prize in Physics (in 1901) for his discoveries. The many applications of X-rays created the first practical use for Crookes tubes, and workshops began manufacturing specialized Crookes tubes to generate X-rays, the first X-ray tubes. The anode was made of a heavy metal, usually platinum, which generated more X-rays, and was tilted at an angle to the cathode, so the X-rays would radiate through the side of the tube. The cathode had a concave spherical surface which focused the electrons into a small spot around 1 mm in diameter on the anode, in order to approximate a point source of X-rays, which gave the sharpest radiographs. These cold cathode