which the molecule does not have on its own. But when carefully investigating it is mostly possible to get a very good picture of how the molecule adheres to the surface by analysis of normal dipole modes. High resolution electron energy loss spectrometer As the electrons used for HREELS are of low energy they do not only have a very short mean free path length in the sample materials but also under normal atmospheric conditions. Therefore, one has to set up the spectrometer in UHV. The spectrometer is in general a computer simulated design that optimizes the resolution while keeping an acceptable electron flux. The electrons are generated in an electron source, by heating a tungsten cathode, which is encapsulated by a negatively charged so called repeller that prevents stray electrons from coming into the detector unit. The electrons can leave the source only through a lens system, like e.g. a slot lens system consisting of several slits all on different potential. The purpose of this system is to focus the electrons on the entrance of the monochromator unit, to get a high initial electron flux. The monochromator is usually a concentric hemispherical analyser (CHA). In more sensitive setups an additional pre-monochromator is used. The task of the monochromator is to reduce the energy of the passing electrons to some eV due to the help of electron lenses. It further lets only those electrons pass which have the chosen initial energy. To achieve a good resolution it is already important to have incident electrons of a well defined energy one normally chooses a resolution of for the monochromator. This means, the electrons leaving the monochromator with e.g. 10 eV have an energy accurate to 10−1 eV. The beam's flux is then in the orders of 10−8 A to 10−10 A. The radii of the CHA are in the order of several 10 mm. And the deflector electrodes have a saw tooth profile to backscatter electrons which are reflected from the walls in order to reduce the background of electrons with the wrong Ei. The electrons are then focused by a lens system onto the sample. These lenses are, in contrary to those of the emitter system very flexible, as it is important is to get a good focus on the sample. To enable measurements of angular distributions all those elements are mounted on a rotate able table with the axis