sky is usually determined by Rayleigh scattering, an exception occurs at sunset and twilight. "Preferential absorption of sunlight by ozone over long horizon paths gives the zenith sky its blueness when the sun is near the horizon". See diffuse sky radiation for more details. Spectral composition of sunlight at Earth's surface The Sun may be said to illuminate, which is a measure of the light within a specific sensitivity range. Many animals (including humans) have a sensitivity range of approximately 400–700 nm, and given optimal conditions the absorption and scattering by Earth's atmosphere produces illumination that approximates an equal-energy illuminant for most of this range. The useful range for color vision in humans, for example, is approximately 450–650 nm. Aside from effects that arise at sunset and sunrise, the spectral composition changes primarily in respect to how directly sunlight is able to illuminate. When illumination is indirect, Rayleigh scattering in the upper atmosphere will lead blue wavelengths to dominate. Water vapour in the lower atmosphere produces further scattering and ozone, dust and water particles will also absorb particular wavelengths. Life on Earth The existence of nearly all life on Earth is fueled by light from the Sun. Most autotrophs, such as plants, use the energy of sunlight, combined with carbon dioxide and water, to produce simple sugars—a process known as photosynthesis. These sugars are then used as building-blocks and in other synthetic pathways that allow the organism to grow. Heterotrophs, such as animals, use light from the Sun indirectly by consuming the products of autotrophs, either by consuming autotrophs, by consuming their products, or by consuming other heterotrophs. The sugars and other molecular components produced by the autotrophs are then broken down, releasing stored solar energy, and giving the heterotroph the energy required for survival. This process is known as cellular respiration. In prehistory, humans began to further extend this process by putting plant and animal materials to other uses. They used animal skins for warmth, for example, or wooden weapons to hunt. These skills allowed humans to harvest more of the sunlight than was possible through glycolysis alone, and human population began to grow. During the Neolithic Revolution, the domestication of plants and animals further increased human access to solar energy. Fields devoted to crops were enriched by inedible plant matter, providing sugars and nutrients for future harvests. Animals that had previously provided humans with only meat and tools