On November 23, Williams grabbed career-highs of 17 rebounds and 2 steals to go along with 7 points, 3 blocks, and 2 assists on 3-for-10 field goals and 1-of-4 free throws in a win over Gardner-Webb. He had a season-high 14 points, along with 8 rebounds, 1 assist, and 1 steal on 3-for-3 from the field and 8-for-10 from the charity stripe in a win against Northwestern on November 28. On December 7 in an 80-71 win over #18 UCLA, he had 10 points, 15 rebounds, 2 blocks, 1 steal, and 1 assist on 3-of-5 field goals and 4-of-6 free throws. On March 5, 2014, Williams blocked a career-high 5 shots, along with 7 points and 8 rebounds on 3-of-7 field goals and 1-of-2 free throws, in a win over Texas A&M. In a double-overtime win over Texas A&M in the SEC Tournament on March 13, Williams dished out a career-high 4 assists to go along with a double-double (11 points and 15 rebounds), 2 blocks, and 1 steal on 3-of-7 2-pointers, 1-for-2 from 3-point land, and 2-of-2 free throw shooting. Sophomore season Heading into his sophomore year, Williams was expected to shoulder a much larger role for Missouri with the losses of guards Jabari Brown, Jordan Clarkson, and Earnest Ross, who combined to average more than 50 points per game, as well as head coach Frank Haith. Williams was Missouri's top returning scorer, rebounder, and shot-blocker. However, tough times were ahead for Williams as he suffered a partial meniscus tear in his right knee during the preseason of early October 2014. Despite leading Missouri in scoring (11.9 points), rebounding (7.1 rebounds), and shot-blocking (0.6) per game during his sophomore season, Williams was hampered all season by a torn meniscus, and the Tigers finished with the most losses and longest losing streak (13) in school history with a 9-23 record. In the regular season opener in a 69-61 loss to UMKC on November 14, 2014, Williams had a season high of 4 blocks, along with 6 points and 5 rebounds on 3-of-7 field goals. On December 2, he dropped 18 points, 11 rebounds, 1 assist, and 1 block on 5-for-9 field goals and 8-for-14 free throws in a win over Southeast Missouri State. In an overtime loss to Oklahoma State on December 30, Williams scored 22 points, along with 9 rebounds, 1 assist, and 1 steal on 6-of-10 2-point field