to which the relaxation time diverges at the Kauzmann temperature, implying that one can never equilibrate the metastable supercooled liquid here. A critical discussion of the Kauzmann paradox and the Adam–Gibbs model was given in 2009. Data on several supercooled organic liquids do not confirm the Adam–Gibbs prediction of a diverging relaxation time at any finite temperature, e.g. the Kauzmann temperature. Alternative resolutions There are at least three other possible resolutions to the Kauzmann paradox. It could be that the heat capacity of the supercooled liquid near the Kauzmann temperature smoothly decreases to a smaller value. It could also be that a first order phase transition to another liquid state occurs before the Kauzmann temperature with the heat capacity of this new state being less than that obtained by extrapolation from higher temperature. Finally, Kauzmann himself resolved the entropy paradox by postulating that all supercooled liquids must crystallize before the Kauzmann temperature is reached. In specific materials Silica, SiO2 Silica (the chemical compound SiO2) has a number of distinct crystalline forms in addition to the quartz structure. Nearly all of the crystalline forms involve tetrahedral SiO4 units linked together by shared vertices in different arrangements (stishovite, composed of linked SiO6 octahedra, is the main exception). Si-O bond lengths vary between the different crystal forms. For example, in α-quartz the bond length is , whereas in α-tridymite it ranges from . The Si-O-Si bond angle also varies from 140° in α-tridymite to 144° in α-quartz to 180° in β-tridymite. Any deviations from these standard parameters constitute microstructural differences or variations that represent an approach to an amorphous, vitreous or glassy solid. The transition temperature Tg in silicates is related to the energy required to break and re-form covalent bonds in an amorphous (or random network) lattice of covalent bonds. The Tg is clearly influenced by the chemistry of the glass. For example, addition of elements such as B, Na, K or Ca to a silica glass, which have a valency less than 4, helps in breaking up the network structure, thus reducing the Tg. Alternatively, P, which has a valency of 5, helps to reinforce an ordered lattice, and thus increases the Tg. Tg is directly proportional to bond strength, e.g. it depends on quasi-equilibrium thermodynamic parameters of the bonds e.g. on the enthalpy Hd and entropy Sd of configurons – broken bonds: Tg = Hd / [Sd + R ln[(1