Sulfur tetrafluoride is the chemical compound with the formula SF4. It is a colorless corrosive gas that releases dangerous HF upon exposure to water or moisture. Despite these unwelcome characteristics, this compound is a useful reagent for the preparation of organofluorine compounds, some of which are important in the pharmaceutical and specialty chemical industries. Structure Sulfur in SF4 is in the formal +4 oxidation state. Of sulfur's total of six valence electrons, two form a lone pair. The structure of SF4 can therefore be anticipated using the principles of VSEPR theory: it is a see-saw shape, with S at the center. One of the three equatorial positions is occupied by a nonbonding lone pair of electrons. Consequently, the molecule has two distinct types of F ligands, two axial and two equatorial. The relevant bond distances are = 164.3 pm and = 154.2 pm. It is typical for the axial ligands in hypervalent molecules to be bonded less strongly. In contrast to SF4, the related molecule SF6 has sulfur in the 6+ state, no valence electrons remain nonbonding on sulfur, hence the molecule adopts a highly symmetrical octahedral structure. Further contrasting with SF4, SF6 is extraordinarily inert chemically. The 19F NMR spectrum of SF4 reveals only one signal, which indicates that the axial and equatorial F atom positions rapidly interconvert via pseudorotation. Synthesis and manufacture SF4 is produced by the reaction of SCl2 and NaF in acetonitrile: 3 SCl2 + 4 NaF → SF4 + S2Cl2 + 4 NaCl SF4 is also produced in the absence of solvent at elevated temperatures. Alternatively, SF4 at high yield is produced using sulfur (S), NaF and chlorine (Cl2) in the absence of reaction medium, also at less-desirable elevated reaction temperatures (e.g. 225–450 °C). A low temperature (e.g. 20–86 °C) method of producing SF4 at high yield, without the requirement for reaction medium, has been demonstrated utilizing bromine (Br2) instead of chlorine (Cl2), S and KF: S + (2 + x) Br2 + 4 KF → SF4↑ + x Br2 + 4 KBr Use of SF4 for the synthesis of fluorocarbons In organic synthesis, SF4 is used to convert COH and C=O groups into CF and CF2 groups, respectively. Certain alcohols readily give the corresponding fluorocarbon. Ketones and aldehydes give geminal difluorides. The presence of protons alpha to the carbonyl leads to side reactions and diminished (30–40%) yield. Also diols can give cyclic sulfite esters,