terrestrial biomass. Recent rates of global emissions directly into the atmosphere have exceeded the uptake by vegetation and the oceans. These sinks have been expected and observed to remove about half of the added atmospheric carbon within about a century. Nevertheless, sinks like the ocean have evolving saturation properties, and a substantial fraction (20–35%, based on coupled models) of the added carbon is projected remain in the atmosphere for centuries to millennia. Fossil carbon extraction that increases atmospheric greenhouse gases is thus described by the IPCC, atmospheric and oceanic scientists as a long-term commitment by society to living in a changing climate and, ultimately, a warmer world. Man-made chemicals Smaller amounts of man-made petrochemicals, containing fossil carbon, can have unexpected and outsized effects on the biological carbon cycle. This occurs in part because they have been purposely created by humans to decompose slowly, which enables their unnatural persistence and buildup throughout the biosphere. In many cases their pathways through the broader carbon cycle are also not yet well-characterized or understood. Plastics Close to 400 million tons of plastic were manufactured globally during year 2018 with annual growth rates approaching 10%, and over 6 gigatons produced in total since 1950. Plastics eventually undergo fragmentation as a typical first step in their decay, and this enables their widespread distribution by air and water currents. Animals easily internalize microplastics and nanoplastics through ingestion and inhalation, accompanied by risks of bioaccumulation. Biodegradable plastics placed into landfills generate methane and carbon dioxide which cycles through the atmosphere unless captured. A major review of the scientific evidence as of year 2019 did not identify major consequences for human society at current levels, but does foresee substantial risks emerging within the next century. A 2019 study indicated that degradation of plastics through sun exposure, releases both carbon dioxide and other greenhouse gases. Bioplastics with a more natural and rapid carbon cycle have been developed as an alternative to other petroleum-based single-use plastics. Halocarbons Halocarbons are less prolific compounds developed for diverse uses throughout industry; for example as solvents and refrigerants. Nevertheless, the buildup of relatively small concentrations (parts per trillion) of chlorofluorocarbon, hydrofluorocarbon, and perfluorocarbon gases in the atmosphere is responsible for about 10% of the total direct radiative forcing from all long-lived greenhouse gases (year 2019); which includes forcing from the much larger concentrations of carbon dioxide and methane. Chlorofluorocarbons also cause stratospheric ozone depletion. International