as cyanoacetylene, hydrogen cyanide, carbon dioxide, carbon monoxide, cyanogen, argon and helium. The hydrocarbons are thought to form in Titan's upper atmosphere in reactions resulting from the breakup of methane by the Sun's ultraviolet light, producing a thick orange smog. Titan spends 95% of its time within Saturn's magnetosphere, which may help shield it from the solar wind. Energy from the Sun should have converted all traces of methane in Titan's atmosphere into more complex hydrocarbons within 50 million years—a short time compared to the age of the Solar System. This suggests that methane must be replenished by a reservoir on or within Titan itself. The ultimate origin of the methane in its atmosphere may be its interior, released via eruptions from cryovolcanoes. On April 3, 2013, NASA reported that complex organic chemicals, collectively called tholins, likely arise on Titan, based on studies simulating the atmosphere of Titan. On June 6, 2013, scientists at the IAA-CSIC reported the detection of polycyclic aromatic hydrocarbons in the upper atmosphere of Titan. On September 30, 2013, propene was detected in the atmosphere of Titan by NASA's Cassini spacecraft, using its composite infrared spectrometer (CIRS). This is the first time propene has been found on any moon or planet other than Earth and is the first chemical found by the CIRS. The detection of propene fills a mysterious gap in observations that date back to NASA's Voyager 1 spacecraft's first close planetary flyby of Titan in 1980, during which it was discovered that many of the gases that make up Titan's brown haze were hydrocarbons, theoretically formed via the recombination of radicals created by the Sun's ultraviolet photolysis of methane. On October 24, 2014, methane was found in polar clouds on Titan. On December 1, 2022, astronomers reported viewing clouds, likely made of methane, moving across Titan, using the James Webb Space Telescope. Climate Titan's surface temperature is about . At this temperature, water ice has an extremely low vapor pressure, so the little water vapor present appears limited to the stratosphere. Titan receives about 1% as much sunlight as Earth. Before sunlight reaches the surface, about 90% has been absorbed by the thick atmosphere, leaving only 0.1% of the amount of light Earth receives. Atmospheric methane creates a greenhouse effect on Titan's surface, without which Titan would be much colder. Conversely, haze in Titan's atmosphere contributes to an anti-greenhouse effect by absorbing sunlight,