than 2,000 K. For temperatures greater than 2,000 K, a heat shield designer must use a real gas model. Real (equilibrium) gas model An entry vehicle's pitching moment can be significantly influenced by real-gas effects. Both the Apollo command module and the Space Shuttle were designed using incorrect pitching moments determined through inaccurate real-gas modelling. The Apollo-CM's trim-angle angle of attack was higher than originally estimated, resulting in a narrower lunar return entry corridor. The actual aerodynamic center of the Columbia was upstream from the calculated value due to real-gas effects. On Columbias maiden flight (STS-1), astronauts John Young and Robert Crippen had some anxious moments during reentry when there was concern about losing control of the vehicle. An equilibrium real-gas model assumes that a gas is chemically reactive, but also assumes all chemical reactions have had time to complete and all components of the gas have the same temperature (this is called thermodynamic equilibrium). When air is processed by a shock wave, it is superheated by compression and chemically dissociates through many different reactions. Direct friction upon the reentry object is not the main cause of shock-layer heating. It is caused mainly from isentropic heating of the air molecules within the compression wave. Friction based entropy increases of the molecules within the wave also account for some heating. The distance from the shock wave to the stagnation point on the entry vehicle's leading edge is called shock wave stand off. An approximate rule of thumb for shock wave standoff distance is 0.14 times the nose radius. One can estimate the time of travel for a gas molecule from the shock wave to the stagnation point by assuming a free stream velocity of 7.8 km/s and a nose radius of 1 meter, i.e., time of travel is about 18 microseconds. This is roughly the time required for shock-wave-initiated chemical dissociation to approach chemical equilibrium in a shock layer for a 7.8 km/s entry into air during peak heat flux. Consequently, as air approaches the entry vehicle's stagnation point, the air effectively reaches chemical equilibrium thus enabling an equilibrium model to be usable. For this case, most of the shock layer between the shock wave and leading edge of an entry vehicle is chemically reacting and not in a state of equilibrium. The Fay–Riddell equation, which is of extreme importance towards modeling heat flux, owes its validity to the stagnation point