speed (hyperbolic trajectory, lunar return) and has a large nose radius then radiative heat flux can dominate TPS heating. Radiative heat flux during entry into an air or carbon dioxide atmosphere typically comes from asymmetric diatomic molecules; e.g., cyanogen (CN), carbon monoxide, nitric oxide (NO), single ionized molecular nitrogen etc. These molecules are formed by the shock wave dissociating ambient atmospheric gas followed by recombination within the shock layer into new molecular species. The newly formed diatomic molecules initially have a very high vibrational temperature that efficiently transforms the vibrational energy into radiant energy; i.e., radiative heat flux. The whole process takes place in less than a millisecond which makes modelling a challenge. The experimental measurement of radiative heat flux (typically done with shock tubes) along with theoretical calculation through the unsteady Schrödinger equation are among the more esoteric aspects of aerospace engineering. Most of the aerospace research work related to understanding radiative heat flux was done in the 1960s, but largely discontinued after conclusion of the Apollo Program. Radiative heat flux in air was just sufficiently understood to ensure Apollo's success. However, radiative heat flux in carbon dioxide (Mars entry) is still barely understood and will require major research. Frozen gas model The frozen gas model describes a special case of a gas that is not in equilibrium. The name "frozen gas" can be misleading. A frozen gas is not "frozen" like ice is frozen water. Rather a frozen gas is "frozen" in time (all chemical reactions are assumed to have stopped). Chemical reactions are normally driven by collisions between molecules. If gas pressure is slowly reduced such that chemical reactions can continue then the gas can remain in equilibrium. However, it is possible for gas pressure to be so suddenly reduced that almost all chemical reactions stop. For that situation the gas is considered frozen. The distinction between equilibrium and frozen is important because it is possible for a gas such as air to have significantly different properties (speed-of-sound, viscosity etc.) for the same thermodynamic state; e.g., pressure and temperature. Frozen gas can be a significant issue in the wake behind an entry vehicle. During reentry, free stream air is compressed to high temperature and pressure by the entry vehicle's shock wave. Non-equilibrium air in the shock layer is then transported past the entry vehicle's leading side into a region of rapidly expanding flow that causes freezing. The