Structure and composition The Giotto and Vega missions gave planetary scientists their first view of Halley's surface and structure. Like all comets, as Halley nears the Sun, its volatile compounds (those with low boiling points, such as water, carbon monoxide, carbon dioxide and other ices) begin to sublimate from the surface of its nucleus. This causes the comet to develop a coma, or atmosphere, up to across. Evaporation of this dirty ice releases dust particles, which travel with the gas away from the nucleus. Gas molecules in the coma absorb solar light and then re-radiate it at different wavelengths, a phenomenon known as fluorescence, whereas dust particles scatter the solar light. Both processes are responsible for making the coma visible. As a fraction of the gas molecules in the coma are ionized by the solar ultraviolet radiation, pressure from the solar wind, a stream of charged particles emitted by the Sun, pulls the coma's ions out into a long tail, which may extend more than 100 million kilometres into space. Changes in the flow of the solar wind can cause disconnection events, in which the tail completely breaks off from the nucleus. Despite the vast size of its coma, Halley's nucleus is relatively small: barely long, wide and perhaps thick. Its shape vaguely resembles that of a peanut shell. Its mass is relatively low (roughly 2.2 kg) and its average density is about , indicating that it is made of a large number of small pieces, held together very loosely, forming a structure known as a rubble pile. Ground-based observations of coma brightness suggested that Halley's rotation period was about 7.4 days. Images taken by the various spacecraft, along with observations of the jets and shell, suggested a period of 52 hours. Given the irregular shape of the nucleus, Halley's rotation is likely to be complex. Although only 25% of Halley's surface was imaged in detail during the flyby missions, the images revealed an extremely varied topography, with hills, mountains, ridges, depressions, and at least one crater. Halley is the most active of all the periodic comets, with others, such as Comet Encke and Comet Holmes, being one or two orders of magnitude less active. Its day side (the side facing the Sun) is far more active than the night side. Spacecraft observations showed that the gases ejected from the nucleus were 80% water vapour, 17% carbon monoxide and 3–4%