cloud that surrounds Io, or the Io plasma torus, a ring of ionized particles that shares Io's orbit but co-rotates with the magnetosphere of Jupiter. Approximately one ton of material is removed from the atmosphere every second through this process so that it must be constantly replenished. The most dramatic source of are volcanic plumes, which pump kg of sulfur dioxide per second into Io's atmosphere on average, though most of this condenses back onto the surface. Much of the sulfur dioxide in Io's atmosphere is sustained by sunlight-driven sublimation of frozen on the surface. The day-side atmosphere is largely confined to within 40° of the equator, where the surface is warmest and most active volcanic plumes reside. A sublimation-driven atmosphere is also consistent with observations that Io's atmosphere is densest over the anti-Jupiter hemisphere, where frost is most abundant, and is densest when Io is closer to the Sun. However, some contributions from volcanic plumes are required as the highest observed densities have been seen near volcanic vents. Because the density of sulfur dioxide in the atmosphere is tied directly to surface temperature, Io's atmosphere partially collapses at night, or when Io is in the shadow of Jupiter (with an ~80% drop in column density). The collapse during eclipse is limited somewhat by the formation of a diffusion layer of sulfur monoxide in the lowest portion of the atmosphere, but the atmosphere pressure of Io's nightside atmosphere is two to four orders of magnitude less than at its peak just past noon. The minor constituents of Io's atmosphere, such as , , , and derive either from: direct volcanic outgassing; photodissociation, or chemical breakdown caused by solar ultraviolet radiation, from ; or the sputtering of surface deposits by charged particles from Jupiter's magnetosphere. Various researchers have proposed that the atmosphere of Io freezes onto the surface when it passes into the shadow of Jupiter. Evidence for this is a "post-eclipse brightening", where the moon sometimes appears a bit brighter as if covered with frost immediately after eclipse. After about 15 minutes the brightness returns to normal, presumably because the frost has disappeared through sublimation. Besides being seen through ground-based telescopes, post-eclipse brightening was found in near-infrared wavelengths using an instrument aboard the Cassini spacecraft. Further support for this idea came in 2013 when the Gemini Observatory was used to directly measure the collapse of Io's atmosphere during, and its