Hauyne or haüyne, also called hauynite or haüynite ( ), is a tectosilicate sulfate mineral with endmember formula . As much as 5 wt % may be present, and also and Cl. It is a feldspathoid and a member of the sodalite group. Hauyne was first described in 1807 from samples discovered in Vesuvian lavas in Monte Somma, Italy, and was named in 1807 by Brunn-Neergard for the French crystallographer René Just Haüy (1743–1822). It is sometimes used as a gemstone. Sodalite group Formulae: haüyne sodalite nosean lazurite tsaregorodtsevite tugtupite vladimirivanovite All these minerals are feldspathoids. Haüyne forms a solid solution with nosean and with sodalite. Complete solid solution exists between synthetic nosean and haüyne at 600 °C, but only limited solid solution occurs in the sodalite-nosean and sodalite-haüyne systems. The characteristic blue color of sodalite-group minerals arises mainly from caged and clusters. Unit cell Haüyne belongs to the hexatetrahedral class of the isometric system, 3m, space group P3n. It has one formula unit per unit cell (Z = 1), which is a cube with side length of 9 Å. More accurate measurements are as follows: a = 8.9 Å a = 9.08 to 9.13 Å a = 9.10 to 9.13 Å a = 9.11(2) Å a = 9.116 Å a = 9.13 Å Structure All silicates have a basic structural unit that is a tetrahedron with an oxygen ion O at each apex, and a silicon ion Si in the middle, forming (SiO4)4−. In tectosilicates (framework silicates) each oxygen ion is shared between two tetrahedra, linking all the tetrahedra together to form a framework. Since each O is shared between two tetrahedra only half of it "belongs" to the Si ion in either tetrahedron, and if no other components are present then the formula is SiO2, as in quartz. Aluminium ions Al, can substitute for some of the silicon ions, forming (AlO4)5− tetrahedra. If the substitution is random the ions are said to be disordered, but in haüyne the Al and Si in the tetrahedral framework are fully ordered. Si has a charge 4+, but the charge on Al is only 3+. If all the cations (positive ions) are Si then the positive charges on the Si's exactly balance the negative charges on the O's. When Al replaces Si there is a deficiency of positive charge, and this is made up by extra positively charged ions (cations) entering the