Ductile iron, also known as ductile cast iron, nodular cast iron, spheroidal graphite iron, spheroidal graphite cast iron and SG iron, is a type of graphite-rich cast iron discovered in 1943 by Keith Millis. While most varieties of cast iron are weak in tension and brittle, ductile iron has much more impact and fatigue resistance, due to its nodular graphite inclusions. On October 25, 1949, Keith Dwight Millis, Albert Paul Gagnebin and Norman Boden Pilling received US patent 2,485,760 on a cast ferrous alloy for ductile iron production via magnesium treatment. Augustus F. Meehan was awarded a patent in January 1931 for inoculating iron with calcium silicide to produce ductile iron subsequently licensed as Meehanite, still produced . Metallurgy Ductile iron is not a single material but part of a group of materials which can be produced with a wide range of properties through control of their microstructure. The common defining characteristic of this group of materials is the shape of the graphite. In ductile irons, graphite is in the form of nodules rather than flakes as in grey iron. Whereas sharp graphite flakes create stress concentration points within the metal matrix, rounded nodules inhibit the creation of cracks, thus providing the enhanced ductility that gives the alloy its name. Nodule formation is achieved by adding nodulizing elements, most commonly magnesium (magnesium boils at 1100 °C and iron melts at 1500 °C) and, less often now, cerium (usually in the form of mischmetal). Tellurium has also been used. Yttrium, often a component of mischmetal, has also been studied as a possible nodulizer. Austempered ductile iron (ADI; i.e., austenite tempered) was discovered in the 1950s but was commercialized and achieved success only some years later. In ADI, the metallurgical structure is manipulated through a sophisticated heat treating process. Composition Other ductile iron compositions often have a small amount of sulfur as well. Carbon, 3.3–3.60% Silicon, 2.2–2.8% Manganese, 0.1–0.2% Magnesium, 0.03–0.04% Phosphorus, 0.005–0.04% Sulfur, 0.005–0.02% Copper, <0.40% Iron, balance Elements such as copper or tin may be added to increase tensile and yield strength while simultaneously reducing ductility. Improved corrosion resistance can be achieved by replacing 15–30% of the iron in the alloy with varying amounts of nickel, copper, or chromium. Silicon as a graphite formation element can be partially replaced by aluminum to provide better oxidation protection. Applications Much of the annual production of ductile iron is in the form of