paired up with 10 professional singers to compete in a duet-singing showdown in order to impress a panel of judges and the viewing public to survive potential elimination. Paulini was paired up with television presenter Simon Reeve, and they placed sixth in the competition. For the second season of It Takes Two in May 2007, she was paired up with television presenter Lochie Daddo and they were the first couple to be eliminated from the competition. Paulini made her acting debut in the television film Sisters of War, which premiered on ABC1 on 14 November 2010. The film is based on the true story of a group of Australian nuns and nurses held by the Japanese as prisoners of war at the Catholic mission station Vunapope, on the Papua New Guinea island of New Britain in 1942. Paulini played the supporting role of islander nun Sister Marie, who she described as caring and strong. In preparing for the role, Paulini spoke with nuns who had been through World War II experiences and read books on one of the film's other characters, Sister Berenice Twohill. During one scene in the film, Paulini's character sings a Latin requiem in Papua New Guinean dialect while standing beside a huge cross, after death has come to the mission during an aircraft attack. In 2019, Paulini appeared as the Spider contestant in first season of The Masked Singer Australia, being eliminated in finals week. In 2021, Paulini appeared as a contestant on the seventh season of I’m A Celebrity…Get Me Out Of Here! Australia, and was the fifth contestant to be eliminated. Philanthropy Throughout her career, Paulini has supported various charities in Australia. She has also performed at many fundraising events over the years, including the annual Channel Seven Perth Telethon, as well as annual Christmas carols events such as Carols in the Domain, Carols by Candlelight and Carols in the City. Paulini performed at the Olivia Newton-John and Friends Charity Gala Concert, held in September 2008 at Sydney's State Theatre to raise funds for Newton-John's Cancer and Wellness Centre. In 2010, she became an ambassador for The Global Good Foundation, a charity organisation campaigning against domestic violence. That same year, she was part of the Dueting It for the Kids Concert at the State Theatre, where she performed a duet with Leo Sayer. All proceeds from the concert went to The Australian Children's Music