power cogeneration, and for rectification, have been developed. Description The scientific aspects of thermionic energy conversion primarily concern the fields of surface physics and plasma physics. The electrode surface properties determine the magnitude of electron emission current and electric potential at the electrode surfaces, and the plasma properties determine the transport of electron current from the emitter to the collector. All practical thermionic converters to date employ caesium vapor between the electrodes, which determines both the surface and plasma properties. Caesium is employed because it is the most easily ionized of all stable elements. A thermionic generator is like a cyclic heat engine and its maximum efficiency is limited by Carnot's law. It is a low-Voltage high current device where current densities of 25-50 (A/squarecm) have been achieved at voltage from 1-2V. The energy of high temperature gases can be partly converted into electricity if the riser tubes of the boiler are provided cathode and anode of a thermionic generator with the interspace filled with ionized caesium vapor. The surface property of primary interest is the work function, which is the barrier that limits electron emission current from the surface and essentially is the heat of vaporization of electrons from the surface. The work function is determined primarily by a layer of caesium atoms adsorbed on the electrode surfaces. The properties of the interelectrode plasma are determined by the mode of operation of the thermionic converter. In the ignited (or "arc") mode the plasma is maintained via ionization internally by hot plasma electrons (~ 3300 K); in the unignited mode the plasma is maintained via injection of externally produced positive ions into a cold plasma; in the hybrid mode the plasma is maintained by ions from a hot-plasma interelectrode region transferred into a cold-plasma interelectrode region. Recent work All the applications cited above have employed technology in which the basic physical understanding and performance of the thermionic converter were essentially the same as those achieved before 1970. During the period from 1973 to 1983, however, significant research on advanced low-temperature thermionic converter technology for fossil-fueled industrial and commercial electric power production was conducted in the US, and continued until 1995 for possible space reactor and naval reactor applications. That research has shown that substantial improvements in converter performance can be obtained now at lower operating temperatures by addition of oxygen to the caesium vapor, by suppression of electron reflection at