catcher for the 2013 and 2017 squads. In his first classic in 2006, Molina played four games and collected three hits in five at-bats. In a 2009 tournament game against the Netherlands on March 9, Molina's eighth-inning double keyed a rally in which Puerto Rico won 3–1. Speaking the next day, Molina stated that the previous night's double had been a bigger thrill than his two-run homer to beat the Mets in Game 7 of the 2006 NLCS. With Molina as the starting catcher in 2013, Puerto Rico earned the silver medal. Edwin Rodríguez, who had scouted Molina in Puerto Rico before the Cardinals signed him, became the manager for the 2013 squad. Shortly after learning he would be the 2013 manager, Rodríguez contacted Molina for input on constructing the roster. Molina prepared for the Classic by playing 14 games for the winter league team in Puerto Rico Rodríguez managed. Molina was voted on the All-World Baseball Classic team for the first time. In a 2013 semifinal game against Japan, Molina alertly took advantage of a baserunning mistake to record an unusual putout. With Shinnosuke Abe batting for Japan in the top of the eighth inning, and Hirokazu Ibata on second and Seiichi Uchikawa on first, J. C. Romero was pitching for Puerto Rico. Abe took a pitch from Romero inside for a ball as the runners went in motion. However, Ibata retreated to second as Uchikawa charged toward him. Instead of throwing and risking an error, Molina held on to the ball. He then chased Uchikawa, cornered him by positioning himself between first and second and tagged out Uchikawa – an unassisted caught stealing. The Japanese later stated they were attempting to exploit Romero's slow delivery. Puerto Rico advanced the finals again in 2017, falling to the United States 8−0 in earning their second consecutive silver medal, and only loss of the tournament. Molina made a strong case to be named Most Valuable Player (MVP) of the entire tournament, batting .333 with two home runs and a .583 slugging percentage in six games. After collecting three hits and a home run in eight at bats over two games in Pool F competition, he was named that group's MVP. In the semifinal game against the Netherlands, he picked two runners off base in one inning. He was named the catcher of 2017 All-World Baseball Classic team, his second All-WBC honor.