of Air Priestley's years in Calne were the only ones in his life dominated by scientific investigations; they were also the most scientifically fruitful. His experiments were almost entirely confined to "airs", and out of this work emerged his most important scientific texts: the six volumes of Experiments and Observations on Different Kinds of Air (1774–86). These experiments helped repudiate the last vestiges of the theory of four elements, which Priestley attempted to replace with his own variation of phlogiston theory. According to that 18th-century theory, the combustion or oxidation of a substance corresponded to the release of a material substance, phlogiston. Priestley's work on "airs" is not easily classified. As historian of science Simon Schaffer writes, it "has been seen as a branch of physics, or chemistry, or natural philosophy, or some highly idiosyncratic version of Priestley's own invention". Furthermore, the volumes were both a scientific and a political enterprise for Priestley, in which he argues that science could destroy "undue and usurped authority" and that government has "reason to tremble even at an air pump or an electrical machine". Volume I of Experiments and Observations on Different Kinds of Air outlined several discoveries: "nitrous air" (nitric oxide, NO); "vapor of spirit of salt", later called "acid air" or "marine acid air" (anhydrous hydrochloric acid, HCl); "alkaline air" (ammonia, NH3); "diminished" or "dephlogisticated nitrous air" (nitrous oxide, N2O); and, most famously, "dephlogisticated air" (oxygen, O2) as well as experimental findings that showed plants revitalised enclosed volumes of air, a discovery that would eventually lead to the discovery of photosynthesis. Priestley also developed a "nitrous air test" to determine the "goodness of air". Using a pneumatic trough, he would mix nitrous air with a test sample, over water or mercury, and measure the decrease in volume—the principle of eudiometry. After a small history of the study of airs, he explained his own experiments in an open and sincere style. As an early biographer writes, "whatever he knows or thinks he tells: doubts, perplexities, blunders are set down with the most refreshing candour." Priestley also described his cheap and easy-to-assemble experimental apparatus; his colleagues therefore believed that they could easily reproduce his experiments. Faced with inconsistent experimental results, Priestley employed phlogiston theory. This led him to conclude that there were only three types of "air": "fixed", "alkaline", and "acid". Priestley dismissed the burgeoning chemistry of his day. Instead, he focused on