using a light microscope, whereas cryptoperthitic textures can be seen only with an electron microscope. Ammonium feldspar Buddingtonite is an ammonium feldspar with the chemical formula: NH4AlSi3O8. It is a mineral associated with hydrothermal alteration of the primary feldspar minerals. Barium feldspars Barium feldspars form as the result of the substitution of barium for potassium in the mineral structure. Barium feldspars are sometimes classified as a separate group of feldspars, and sometimes they are classified as a sub-group of alkali feldspars. The barium feldspars are monoclinic and include the following: celsian hyalophane Plagioclase feldspars The plagioclase feldspars are triclinic. The plagioclase series follows (with percent anorthite in parentheses): albite (0 to 10) oligoclase (10 to 30) andesine (30 to 50) labradorite (50 to 70) bytownite (70 to 90) anorthite (90 to 100) Intermediate compositions of plagioclase feldspar also may exsolve to two feldspars of contrasting composition during cooling, but diffusion is much slower than in alkali feldspar, and the resulting two-feldspar intergrowths typically are too fine-grained to be visible with optical microscopes. The immiscibility gaps in the plagioclase solid solutions are complex compared to the gap in the alkali feldspars. The play of colors visible in some feldspar of labradorite composition is due to very fine-grained exsolution lamellae known as Bøggild intergrowth. The specific gravity in the plagioclase series increases from albite (2.62) to anorthite (2.72–2.75). Structure The structure of a feldspar crystal is based on aluminosilicate tetrahedra. Each tetrahedron consists of an aluminium or silicon ion surrounded by four oxygen ions. Each oxygen ion, in turn, is shared by a neighbouring tetrahedron to form a three-dimensional network. The structure can be visualized as long chains of aluminosilicate tetrahedra, sometimes described as crankshaft chains because their shape is kinked. Each crankshaft chain links to neighbouring crankshaft chains to form a three-dimensional network of fused four-member rings. The structure is open enough for cations (typically sodium, potassium, or calcium) to fit into the structure and provide charge balance. Etymology The name feldspar derives from the German Feldspat, a compound of the words Feld ("field") and Spat ("flake"). Spat had long been used as the word for "a rock easily cleaved into flakes"; Feldspat was introduced in the 18th century as a more specific term, referring perhaps to its common occurrence in rocks found in fields (Urban Brückmann, 1783) or to its occurrence as "fields" within granite and other minerals (René-Just Haüy,