of Mari||?||1749|| |- |1721||Jean Baptiste Louis Andrault, Marquis of Maulévrier Langeron||1677||1754|| |- |rowspan=2|1722||Louis de Rouvroy, Duke of Saint-Simon||1675||1755|| |- |Philippe Charles, Marquis of La Fare||1685||1782|| |- |rowspan=3|1723||Infante Ferdinand of Spain||1713||1759||later King Ferdinand VI of Spain. Head of the order from 1746 |- |Infante Charles of Spain||1716||1788||later Duke Charles I of Parma, King Charles VII of the Two Sicilies and III of Spain. Head of the order from 1759 |- |Infante Philip of Spain||1720||1765||later Duke Philip of Parma |- |rowspan=13|1724||Nicolás Fernández de Córdoba, 10th Duke of Medinaceli and Feria||1682||1739|| |- |Hyacinthe Boutin, Marquis of Valouse||1671||1736|| |- |||1688||1747|| |- |Mercurio Antonio López Pacheco, 9th Marquis of Villena, 9th Duke of Escalona and Count of Santisteban de Gorma||1679||1738|| |- |Domingo María Carlos de Guzman el Bueno, 13th Duke of Medinasidonia||1691||1739|| |- |Antonio Arduino||?||1731|| |- |Alfonso Fernández Manrique de Lara, 1st Duke of Arco||1672||1737|| |- |José Grimaldi, Marquis of Grimaldi||1660||1733|| |- |Álvaro Benavides Bazán, 7th Marquis of Santa Cruz||?||1737|| |- |Annibal, Marquis of Scotti||?||1752|| |- |Jacques Antoine de Bauffremont||c. 1682||1710|| |- |Louis d'Orléans, Duke of Orléans||1703||1752|| |- |Louis Henri, Duke of Bourbon, Enghien and Prince of Condé||1692||1740|| |- |1725||René de Froulay Count de Tessé||1650||1725|| |- |1727||Francesco de Evoli, Duke of Castropignano||?||1758|| |- |1728||Rodrigo Ignacio de Saa Almeida y Meneses, 7th Count of Penaguiaon||1676||1733|| |- |rowspan=2|1732||José Carrillo de Albornoz, Count (later Duke) of Montemar||1671||1747|| |- |José Patiño||1666||1736|| |- |1734||Marie François Henri de Franquetot, Count of Coigny||1670||1759|| |- |1735||Infante Louis Antonio of Spain||1727||1785||Cardinal Archbishop of Toledo and Seville, later Count of Chinchón |- |rowspan=2|1736||||1706||1777|| |- |Honoré Armand, Duke of Villars and Prince of Martigues||1702||1770|| |- |rowspan=3|1737|||||1696||1757|| |- |Michele Reggio Branciforte||1682||1772|| |- |José Armendáriz, 1st Marquis of Castelfuerte||1665||1749|| |- |rowspan=7|1738||Pedro Cebrián, Count of Fuenclara||1687||1752|| |- |Jaime Miguel de Guzmán de Avalos y Spinola, Marquis of la Mina, Duke of Palata and Prince of Masa||1691||1767|| |- |||1705||1744|| |- |Nicola Sangro||1678||1750|| |- |Louis Jean Marie, Duke of Penthièvre||1725||1793|| |- |Andrés López Pacheco, 10th Marquis of Villena and 10th Duke of Escalona||1710||1746|| |- |Albert, Duke of Saxe-Teschen||1738||1822|| |- |rowspan=4|1739||Louis XV, King of France||1710||1774|| |- |Louis, Dauphin of France||1729||1765|| |- |Louis Pierre Engelbert, Count of la Marck||1674||1750|| |- |Marino Francesco Carriciolo, 7th Prince of Avellino||1714||1773|| |- |1740||||1692||1754|| |- |rowspan=2|1742||Maximilian III, Duke and Elector of Bavaria||1727||1747|| |- |Charles Louis César Auguste Fouquet, Duke of Belle-Isle||1684||1761|| |- |1743||Melchor de Solis y Gante, Duke of Astrito and Marquis of Valladares||?||1752|| |- |rowspan=3|1745||Jean Bonaventure Dumont, Count of Gages||1682||1753|| |- |Domenico Marzio Carafa, 9th Duke of