|- |Philipp Joseph, Count of Künigl||1696||1770|| |- |Ferdinand Charles, Count of Aspremont-Lynden||1689||1772|| |- |||1705||1787|| |- |Rudolf, Count of Korzensky of Tereschau||?||?|| |- |Francis Leopold, Count of Buquoy||1703||1768|| |- |Franz Philipp, Count of Sternberg||1708||1786|| |- |rowspan=9|1765||Jean Charles Joseph, Count of Merode, Marquis of Deynze||1719||1774|| |- |Jean Baptiste, Count of Serbelloni and Castiglione||1697||1778|| |- |Nicholas, Prince Esterházy||1714||1790|| |- |Antonius, Count of Salm-Reifferscheidt||1728||1769|| |- |Franz Wencel, Count of Wallis||1696||1774|| |- |Anthony, Marquis of Litta and Gambolo||1700||1776|| |- |Camille, Count of Colloredo||1712||1797|| |- |Gabriel, Count of Bethlen||1729||1768|| |- |Francis Norbert, Count of Trauttmansdorf||1705||1786|| |- |rowspan=3| 1767||Charles Frederick, Count of Hatzfeld-Gleichen||1718||1793|| |- |Johann Karl Walter, Count of Dietrichstein||1728||1808||later Prince of Dietrichstein |- |Charles Egon, Prince of Fürstenberg||1729||1787|| |- |1768||Archduke Francis Joseph of Austria||1768||1835||later Emperor Francis II (Francis I of Austria). Head of the order from 1792 |- |rowspan=2|1770||Claude, Count of Mercy-Argenteau||1727||1794|| |- |Francis Maurice, Count of Lacy||1725||1801|| |- |rowspan=5|1771||Archduke Joseph Ferdinand of Austria||1769||1824||later Grand Duke Ferdinand III of Tuscany |- |Franz, Count of Esterházy||?||1785|| |- |Franz Josef I, Prince of Liechtenstein||1726||1781|| |- |Franz Ulric, Count of Kinsky||1726||1792|| |- |Charles, 2nd Duke d'Ursel||1718||1775|| |- |rowspan=7|1772||Prince Karl Josef of Liechtenstein||1730||1789|| |- |Karl Josef, Prince of Ligne||1735||1814|| |- |Franz Gundakar, Count of Colloredo||1731||1807|| |- |Ernst Christoph, Count of Kaunitz-Rietberg||1737||1797|| |- |Maximilian, Prince of Salm-Salm and Duke of Hoogstraten||1732||1773|| |- |Louis Frederick, Count of Zinzendorf et Pottendorf||1721||1783|| |- |Josef, Prince of Lobkowicz and Duke of Sagan||1725||1802|| |- |rowspan=2|1775||Bartolomeo, Prince of Corsini and Sismano||1729||1792|| |- |Karl Anselm, 4th Prince of Thurn and Taxis||1733||1805|| |- |1778||Charles Theodore, Elector of Bavaria||1724||1799|| |- |rowspan=7|1782||Karl, Landgrave of Hesse-Rheinfels||1746||1812|| |- |Johann, Prince of Schwarzenberg||1742||1789|| |- |Louis Engelbert, 6th Duke of Arenberg||1750||1820|| |- |Leopold Krakowsky, Count of Kolowrat||1727||180?|| |- |Franz Wencel, Count of Sinzendorf and Thannhausen||1724||1792|| |- |Eugen, Count of Wrbna-Freudenthal||1728||1789|| |- |Karl, Count of Palffy ab Erdöd||1735||1816|| |- |rowspan=6|1785||Johann Franz, Count of Khevenhüller-Metsch||1737||1797|| |- |Antonius Gotthard, Count of Schaffgotsch||1721||1811|| |- |Antonius, Count of Thurn and Valsassina||1723||1806|| |- |Charles des Princes de Albani Savelli||1749||1811|| |- |Francis Joseph, Prince of Gavre||1731||1797|| |- |Johann, Count of Hardegg of Galtz and Machland||1741||1808|| |- |1789||Ferdinand, Count of Trauttmansdorff-Weinsberg||1749||1827|| |- |rowspan=17|1790||Francesco Maria Ruspoli, 3rd Prince of Cerveteri||1752||1829|| |- |Anthony Clement of Saxony||1755||1836||later King of Saxony |- |Archduke Charles of Austria, Duke of Teschen||1771||1847|| |- |Archduke Alexander Leopold of Austria||1772||1792||son of Emperor Leopold II |- |Archduke Joseph of Austria, Palatine of Hungary||1776||1848|| |- |Archduke Francis of Austria||1779||1846||later Duke Francis IV of Modena |- |Karl Josef, Prince of Auersperg||1720||1800|| |- |Alois I, Prince