Maddaloni and Prince of la Guardia||1672||1750|| |- |Louis de Brancas, Duke of Lauraguais||1714||1793|| |- |rowspan=4|1746||Fernando de Silva Mendoza y Toledo, 12th Duke of Alba||1714||1776|| |- |Philippe de Noailles, Duke of Mouchy and Prince of Poix||1715||1794|| |- |Sebastián Antonio de Guzmán y Spinola Enríquez Colonna, 5th Marquis of Montealegre||1683||1757|| |- |||1692||1757|| |- |1747||Infante Felipe, Duke of Calabria||1747||1777||son of King Charles VII of the Two Sicilies (later Charles III of Spain) excluded from succession to the throne due to his imbecility. |- |1748||||1704||1768|| |- |rowspan=2|1749||Infante Charles of Spain||1748||1819||later King Charles IV of Spain. Head of the Order from 1788 to 1808 |- |Clement, Duke of Bavaria and Count Palatine||1722||1770|| |- |rowspan=5|1750||Luca Spinola y Spinola, Count of Siruela||1680||1750|| |- |Zenón de Somodevilla y Bengoechea, Marquis of Ensenada||1702||1781|| |- |, 9th Marquis of Villafranca del Bierzo, Duke of Fernandina and Montalto, Prince of Paternò||1686||1753|| |- |José de Carvajal y Lancaster||1698||1754|| |- |Joaquín Diego López de Zuñiga, 12th Duke of Béjar and Marquis of Gibraleón||1715||1777|| |- |rowspan=2|1751||Ferdinand, Prince of Parma||1751||1802||later Duke of Parma |- |Infante Ferdinand of Spain||1751||1725||later King Ferdinand I of the Two Sicilies (IV of Naples and III of Sicily) |- |rowspan=5|1752||Infante Gabriel of Spain||1752||1788||son of King Charles VII of the Two Sicilies (later Charles III of Spain) |- |Louis Philippe, Duke of Chartres||1725||1785||later Duke Louis Philippe I of Orléans |- |Victor Philip Ferrero Fieschi, Prince of Masserano||1713||1777|| |- |||1684||1758|| |- |Domingo Cattaneo della Volta, Prince of San Nicandro and Duke of Termoli||1697||1782|| |- |rowspan=3|1753||François Jose de Bournonville, Duke of Bournonville||1710||1769|| |- |||1716||1773|| |- |Pedro de Alcántara Alonso Pérez de Guzmán el Bueno, 14th Duke of Medinasidonia and 17th Count of Niebla||1724||1777|| |- |1754||Louis, Duke of Burgundy ||1751||1761||son of Louis, Dauphin of France |- |1755||Lorenzo Colonna, 9th Prince of Paliano and Tagliacozzo, Prince of Castiglione||1723||1779|| |- |rowspan=2|1756||Infante Anthony of Spain||1755||1817||son of King Charles VII of the Two Sicilies (later Charles III of Spain) |- |Pedro Pablo Abarca de Bolea, 10th Count of Aranda||1718||1798|| |- |1757||Infante Francisco of Spain||1757||1771||son of King Charles III of Spain; |- |1758||José Maria de Guzmán Guevara, 6th Marquis of Montealegre and 13th Count of Oñate||?||1781|| |- |rowspan=4|1761||Louis, Duke of Berry||1754||1793||later King Louis XVI of France |- |Charles Philip, Count of Artois||1757||1836||later King Charles X of France |- |||1724||1776|| |- |Etienne François, Duke of Choiseul||1719||1785|| |- |1762||Nicolás de Carvajal y Lancáster, Marquis of Sarria||?||1770|| |- |rowspan=4|1764||||1706||1783|| |- |Luis Manuel Laso de la Vega, Marquis of Miranda and Duke of Arco||?||1768||