electrochemical potential Inside a conductive material, the energy of an electron is affected not only by the average electric potential but also by the specific thermal and atomic environment that it is in. When a voltmeter is connected between two different types of metal, it measures not the electrostatic potential difference, but instead something else that is affected by thermodynamics. The quantity measured by a voltmeter is the negative of the difference of the electrochemical potential of electrons (Fermi level) divided by the electron charge and commonly referred to as the voltage difference, while the pure unadjusted electrostatic potential (not measurable with a voltmeter) is sometimes called Galvani potential. The terms "voltage" and "electric potential" are ambiguous in that, in practice, they can refer to either of these in different contexts. History The term electromotive force was first used by Volta in a letter to Giovanni Aldini in 1798, and first appeared in a published paper in 1801 in Annales de chimie et de physique. Volta meant by this a force that was not an electrostatic force, specifically, an electrochemical force. The term was taken up by Michael Faraday in connection with electromagnetic induction in the 1820s. However, a clear definition of voltage and method of measuring it had not been developed at this time. Volta distinguished electromotive force (emf) from tension (potential difference): the observed potential difference at the terminals of an electrochemical cell when it was open circuit must exactly balance the emf of the cell so that no current flowed. See also Electric shock Mains electricity by country (list of countries with mains voltage and frequency) Open-circuit voltage Phantom voltage References Footnotes External links Electrical voltage V, current I, resistivity R, impedance Z, wattage P Electrical systems Physical quantities