ringwoodite decomposes into bridgmanite (formerly called magnesium silicate perovskite), and ferropericlase. Garnet also becomes unstable at or slightly below the base of the transition zone. The lower mantle is composed primarily of bridgmanite and ferropericlase, with minor amounts of calcium perovskite, calcium-ferrite structured oxide, and stishovite. In the lowermost ~200 km of the mantle, bridgmanite isochemically transforms into post-perovskite. Composition The chemical composition of the mantle is difficult to determine with a high degree of certainty because it is largely inaccessible. Rare exposures of mantle rocks occur in ophiolites, where sections of oceanic lithosphere have been obducted onto a continent. Mantle rocks are also sampled as xenoliths within basalts or kimberlites. Most estimates of the mantle composition are based on rocks that sample only the uppermost mantle. There is debate as to whether the rest of the mantle, especially the lower mantle, has the same bulk composition. The mantle's composition has changed through the Earth's history due to the extraction of magma that solidified to form oceanic crust and continental crust. It has also been proposed in a 2018 study that an exotic form of water known as ice VII can form from supercritical water in the mantle when diamonds containing pressurized water bubbles move upward, cooling the water to the conditions needed for ice VII to form. Temperature and pressure In the mantle, temperatures range from approximately at the upper boundary with the crust to approximately at the core-mantle boundary. The temperature of the mantle increases rapidly in the thermal boundary layers at the top and bottom of the mantle, and increases gradually through the interior of the mantle. Although the higher temperatures far exceed the melting points of the mantle rocks at the surface (about for representative peridotite), the mantle is almost exclusively solid. The enormous lithostatic pressure exerted on the mantle prevents melting, because the temperature at which melting begins (the solidus) increases with pressure. The pressure in the mantle increases from a few hundred megapascals at the Moho to at the core-mantle boundary. Movement Because of the temperature difference between the Earth's surface and outer core and the ability of the crystalline rocks at high pressure and temperature to undergo slow, creeping, viscous-like deformation over millions of years, there is a convective material circulation in the mantle. Hot material upwells, while cooler (and heavier) material sinks downward. Downward motion of material occurs at convergent plate boundaries