to air, silicate rocks undergo weathering reactions which remove carbon dioxide from the atmosphere. These reactions proceed in the general form: Rock-forming mineral + CO2 + H2O → cations + bicarbonate + SiO2. An example of such a reaction is the weathering of wollastonite: CaSiO3 + 2CO2 + H2O → Ca2+ + SiO2 + 2HCO3− The released calcium cations react with the dissolved bicarbonate in the ocean to form calcium carbonate as a chemically precipitated sedimentary rock. This transfers carbon dioxide, a greenhouse gas, from the air into the geosphere, and, in steady-state on geologic time scales, offsets the carbon dioxide emitted from volcanoes into the atmosphere. As of 2003, a precise continental distribution during the Neoproterozoic was difficult to establish because there were too few suitable sediments for analysis. Some reconstructions point towards polar continents—which have been a feature of all other major glaciations, providing a point upon which ice can nucleate. Changes in ocean circulation patterns may then have provided the trigger of snowball Earth. Additional factors that may have contributed to the onset of the Neoproterozoic snowball include the introduction of atmospheric free oxygen, which may have reached sufficient quantities to react with methane in the atmosphere, oxidizing it to carbon dioxide, a much weaker greenhouse gas, and a younger—thus fainter—Sun, which would have emitted 6 percent less radiation in the Neoproterozoic. Normally, as Earth gets colder due to natural climatic fluctuations and changes in incoming solar radiation, the cooling slows these weathering reactions. As a result, less carbon dioxide is removed from the atmosphere and Earth warms as this greenhouse gas accumulates—this 'negative feedback' process limits the magnitude of cooling. During the Cryogenian period, however, Earth's continents were all at tropical latitudes, which made this moderating process less effective, as high weathering rates continued on land even as Earth cooled. This let ice advance beyond the polar regions. Once ice advanced to within 30° of the equator, a positive feedback could ensue such that the increased reflectiveness (albedo) of the ice led to further cooling and the formation of more ice, until the whole Earth is ice-covered. Polar continents, due to low rates of evaporation, are too dry to allow substantial carbon deposition—restricting the amount of atmospheric carbon dioxide that can be removed from the carbon cycle. A gradual rise of the proportion of the isotope carbon-13 relative to carbon-12 in sediments pre-dating "global" glaciation indicates