for a minimum heat transfer pressure may cease decomposition into gaseous reactants if bullet movement decreases pressure before a slow burning propellant has been consumed. Unburned propellant grains may remain in the barrel if the energy-releasing flame zone cannot be sustained in the resultant absence of gaseous reactants from the inner zones. Propellant burnout Another issue to consider, when choosing a powder burn rate, is the time the powder takes to completely burn vs. the time the bullet spends in the barrel. Looking carefully at the left graph, there is a change in the curve, at about 0.8 ms. This is the point at which the powder is completely burned, and no new gas is created. With a faster powder, burnout occurs earlier, and with the slower powder, it occurs later. Propellant that is unburned when the bullet reaches the muzzle is wasted — it adds no energy to the bullet, but it does add to the recoil and muzzle blast. For maximum power, the powder should burn until the bullet is just short of the muzzle. Since smokeless powders burn, not detonate, the reaction can only take place on the surface of the powder. Smokeless powders come in a variety of shapes, which serve to determine how fast they burn, and also how the burn rate changes as the powder burns. The simplest shape is a ball powder, which is in the form of round or slightly flattened spheres. Ball powder has a comparatively small surface-area-to-volume ratio, so it burns comparatively slowly, and as it burns, its surface area decreases. This means as the powder burns, the burn rate slows down. To some degree, this can be offset by the use of a retardant coating on the surface of the powder, which slows the initial burn rate and flattens out the rate of change. Ball powders are generally formulated as slow pistol powders, or fast rifle powders. Flake powders are in the form of flat, round flakes which have a relatively high surface-area-to-volume ratio. Flake powders have a nearly constant rate of burn, and are usually formulated as fast pistol or shotgun powders. The last common shape is an extruded powder, which is in the form of a cylinder, sometimes hollow. Extruded powders generally have a lower ratio of nitroglycerin to nitrocellulose, and are often progressive burning — that is, they burn at a faster rate as they burn.